By Genesis Environment Services Company Limited The Common Cooling water problem Scaling Corrosion Bacteria (include Leginella) Algae and Slime Traditional approach : Chemical Water Treatment The solution BacComber Non chemical water treatment system Cyclic Problem of Chemical Treatment Additional problems Phosphate or nitrite added is also nutrient to algae Fouling changed from hard scale to sticky calcium phosphate film. Add chlorine to kill bacteria… created corrosion problem Add phosphate or nitrate inhibitor… created bacteria problem Cyclic Problem of Chemical Treatment Start of dosing cycle Over Dose Optimum chemical dosing concentration Under Dose End of dosing cycle The Common Cooling water problem ใหผลลัพธไมคงที่ เนื่องจาก - อุณหภูมิ - pH เปนการเพิ่มคา TDS, Conductivity ระเหยงาย ตองควบคุมการเติมสารเคมี Cooling Tower problem Foaming Cooling Tower problem Foaming Cooling Tower problem Corrosion : Chlorine added is corrosive Cooling Tower problem Corrosion : Chlorine added is corrosive Cooling Tower problem Corrosion : Chlorine added is corrosive Cooling Tower problem Corrosion : Chlorine added is corrosive Cooling Tower problem Corrosion : Chlorine added is corrosive Cooling Tower problem Corrosion : Chlorine added is corrosive Cooling Tower problem Scale & chemical deposits in the cooling system The Energy and Water Save Scale and Hardness Remover No Chemical Enclosure for ELCB/MCB Transformer Rectifier Descaler/Magnetite Generator Submersible pump Inductor Coil unit BacComber Descaler Magnetite Generator PVC pipe BacComber Copper Silver Ionizer BacComber Control Enclosure AC Power Supply Cables Electrode chamber 250 mm Descaler ASAL2A530 142 mm 205 mm Transformer Rectifier ALD30V3A03 142 mm 190 mm 147 mm 240 mm. Silver Electrode Copper Electrode Weight 2.5 Kg. approx without cable 80 mm. 1250 mm. 300 mm. 118 mm. Inductor Coil unit CU21CHN dimensions เปนระบบที่ใหประสิทธิภาพสูง ในการบําบัดน้ําโดยไมใช สารเคมี ประกอบดวยระบบอิเลคโตร แมคเนติก (Electromagnetism) และอิออนไนเซชัน่ (Ionization) Electromagnetic water treatment principle Using electromagnetic energy to change the water molecular structures including • hydrogen bonds, • polar bonds, • ions and ionic substances. Water Molecule Electromagnetic Water Treatment Electromagnetic wave to inductor coil 1KHZ-50KHZ Untreated Water Water Hydrogen Bond Activated Electromagnetic Descaler… How it works Direction of water flow Water molecules orientated into larger water clusters after electro-magnetic treatment Water molecule in single random molecule before electro-magnetic treatment A.C. input Electronic controller Electro-magnetic descaler Electro-magnetic field generated Water Cluster Molecules Arrangement Illustration 5.50 kcal/mol 17.10 37.70 122.39 76.01 49.60 48.60 How Water Cluster Trap Ions and Dissolved Gas O O CO2 Fe Cl Ca ระบบสารเคมี • เกิดพลังงานต่ํา • Calcium Carbonate ที่เกิดขึ้น เรียกวา Calcite มีลักษณะแข็ง เกิดขึ้นตามทอ BacComber System • เกิดพลังงานสูง • Calcium Carbonate ที่เกิดขึ้นเรียกวา Aragonite มีลักษณะเปนผง เหมือนฝุน สามารถหลุดออกจากทอไดงาย High frequency electro-magnetic treated cooling water Hard scale – calcite Rhombohedron form crystal Hard scale forming ions remain as ion form in water High bi-polar energy of the electro-magnetic treated water penetrates the hard scale Pipe wall Powdery snow like soft scale – Aragonite orthorhombic form crystal Existing hard Scale Hard scale spalled off by electromagnetic treated water Descaling effectiveness…4 months after BacComber treatment The cooling water pipe as shown by the arrow heat was cut off to facilitate the addition of a new cooling tower. The cooling tower was treated by chemical for the past 6 years and was changed to BacComber treatment 4 months prior to the addition of the new cooling tower. The photos shows the various section of the pipe cut off from the cooling tower. It can be seen in the photos that the scale and chemical deposists in the pipeline are descale off from the pipe wall. The formation of magnetite is also clearly seen forming on the pipe wall. There is also a swction of the pipe showing the thick chemical deposits are cracking and spalling off from the pipe wall. Scales collected at cooling tower strainer Condenser End Box condition 8 months after BacComber treatment This condenser was open up in Feb 2003 for inspection, 8 months after the BacComber treatment. The photos were taken immediately after the end cover was open. The condition of the end box shown in the photos was before washing. The photos clearly show that the condenser was in excellent condition and there were no sign of scaling and corrosion problem after treatment by BacComber system. Magnetite generating effectiveness 4 months after BacComber treatment on chilled water pipe Cooling Water Fe Ion Content - Corrosion Indicator Fe ion ppm Cooling Tower Institute guideline max. control limit 3 ppm 3 2 Typical chemical treatment Fe ion range 1- 2 ppm 1 Typical BacComber treatment Fe ion level, below 0.08 ppm when stabilized 0 Time How BacComber control bacteria growth • Using Copper-Silver ionization to kill the bacteria directly. • Using electromagnetic treatment to indirectly kill and control bacteria growth. Bacteria behavior changes under BacComber electromagnetic treatment Morphology changes Elongation of Bacteria Bacteria count Resultant After Install BacComber System Time (month) BacComber System Applications Control Limits For Cooling Tower Water Parameter Recommended limits PH 6.5 - 9.0 ¾ Unless the make up water exceeded the limit, otherwise there could be addition of unknown chemical or substances Dilution followed by blow down is recommended Conductivity (µs/cm) < 5000 ¾Infrequent Dilution followed by blow down is recommended TDS (ppm) < 2500 Copper ion (ppm) 0.2 - 5.0 Iron ion (ppm) Causative reasons ( If limit is exceeded ) ¾Chemical ¾Infrequent ¾Chemical < 1.0 water changes addition or other contamination water changes addition or other contamination Remedial action ( If limit is exceeded ) Dilution followed by blow down is recommended (>2.0 ppm) Too high level zToo much copper ion discharge from the ionization process zAccumulation of copper ions due to infrequent water changes zCorrosion of copper pipes and fittings (<0.2 ppm) Too low level zFresh water has just recently been top up zCopper electrodes are consumed zToo low current output ¾Dilution ¾Addition ¾Check of unknown chemicals that causes corrosion ¾Accumulation of iron ion due to infrequent water change ¾Repair works on cooling system steel members ¾Rapid descaling is taking place. followed by blow down is recommended ¾Check on-site copper readings and replace electrodes if required ¾Increase current output on-site iron readings ¾Check whether the magnetite generator is working ¾Check any abnormal PH or TDS reading. * The above is just a guideline and common occurrences. Always compare with the previous months test results, It will give a better picture of the trend and more conclusive reasoning may be arrived. This may be followed by remedial action if required. BacComber Descaler-Magnetite Generator installation layout diagram for boiler water treatment Freshw ater supply Condensate return BacComber descalermagnetite generator Feedwater tank Boiler Feedw ater to boiler BacComber Descaler-Magnetite Generator installation layout diagram for boiler water treatment Approximately 30 cm pipe length insulation to be removed for cable coil wrapping. Reinstall the insulation after cable wrapped. Keep a min 5 m distance from motors, pumps or electrical driven machine. Chiller water pipe to building Chiller water pipe to chiller BacComber Electromagnetic Descaler / Magnetite genrator Approximate size: 256 mm height 196 mm width 160 mm depth Weigh : 3 Kg approx. Chiller Wall mounted 6 mm sq. PVC insulated cable Typical BacComber installation inside the cooling tower Typical BacComber installation inside the cooling tower Changes in cooling tower corrosion condition after using BacComber Before After Typical BacComber Installation Layout for Chilled water system Chemical and Sludge Dislodged chemical sludge Dislodged chemical sludge Dislodged chemical sludge BacComber