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Safety Data Sheet
Section 1: Identification of the material and the Supplier
Product identifier
Gingivamoll paint liquid
Product use
Professional Epithesis material for use in dentistry.
Distributor information
Company identification
Ivoclar Vivadent (NZ) Ltd
Address
12 Omega Street, Rosedale, Auckland, New Zealand
Telephone Number
0508 486 252
Emergencies within New Zealand
0800 764 766 (National Poison Control Centre)
Section 2: Hazards Identification
Product is classified as hazardous according to the HSNO (Minimum Degrees of Hazard) Regulations 2001
NZ Group Standard &
EPA Approval Code
Flammable
Chronic
Surface Coatings and Colourants (Flammable, [Toxic6.7])
HSR002669
Ecotoxic
Hazard Classification
Hazard Code
Hazard Statement
3.1B
H225
Highly flammable liquid and vapour
6.1E (asp)
H305
May be harmful if swallowed and enters airways
6.6B
H341
Suspected of causing genetic defects
6.7B
H351
Suspected of causing cancer
9.1B
H411
Toxic to aquatic life with long lasting effects
Prevention Code
Prevention Statement
P201
P202
P210
P233
P240
P241
P242
P243
P273
P280
P281
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
Use personal protective equipment as required.
Response Code
Response Statement
P301 + P310
P303 +P361 + P353
P308 + P313
P331
P370 + P378
P391
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower.
IF exposed or concerned: Get medical advice/ attention.
Do NOT induce vomiting.
In case of fire: Use Carbon dioxide (CO2), Foam, Extinguishing powder.
Collect spillage.
Storage Code
Storage Statement
P403 + P235
P405
Store in a well-ventilated place. Keep cool.
Store locked up.
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Disposal Code
Disposal Statement
P501
Dispose of according to Local Regulations.
Section 3: Composition/Information on Ingredients
Mixtures:
Chemical characterization
Mixture of aliphatic hydrocarbons.
Hazardous components:
EC No
CAS No
Index No
REACH No
265-151-9
64742-49-0
649-328-00-1
Chemical name
Classification according to Directive 67/548/EEC
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Naphtha (petroleum), hydrotreated light; Low boiling point hydrogen treated naphtha
Carc. Cat. 2, Muta. Cat. 2, Xn - Harmful R45-46-65
Carc. 1B, Muta. 1B, Asp. Tox. 1; H350 H340 H304
Additional information
Quantity
80-100 %
For the wording of the listed R and H Phrases refer to section 16.
Section 4: First Aid Measures
Description of first aid measures:
After inhalation
Provide fresh air. Medical treatment necessary.
After contact with skin
Wash with plenty of water. Immediately remove any contaminated clothing, shoes or stockings.
Medical treatment necessary.
After contact with eyes
After eye contact: Rinse immediately carefully and thoroughly with eye-bath or water. Consult an
ophthalmologist.
After ingestion
Rinse mouth immediately and drink plenty of water. Induce vomiting when the affected person is not
unconscious. Medical treatment necessary. Seek immediately medical advice. Do not induce vomiting.
In case of spontaneous vomiting take care of an unhindered flow out of the vomit (danger of suffocation).
Most important symptoms and effects,
both acute and delayed
No information available.
Indication of any immediate medical
attention and special treatment needed
Treat symptomatically.
Section 5: Fire Fighting Measures
Extinguishing media:
Suitable extinguishing media
Carbon dioxide (CO2), Foam, Extinguishing powder.
Unsuitable extinguishing media
Water.
Special hazards arising from the
substance or mixture
Flammable. Vapours can form explosive mixtures with air.
Advice for firefighters:
Wear a self-contained breathing apparatus and chemical protective clothing. Full protection suit.
Additional information
Use water spray jet to protect personnel and to cool endangered containers. Suppress
gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do
not allow entering drains or surface water.
Section 6: Accidental Release Measures
Personal precautions, protective
equipment and emergency procedures
Remove all sources of ignition. Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray.
Avoid contact with skin, eyes and clothes. Use personal protection equipment.
Environmental precautions
Do not allow uncontrolled discharge of product into the environment. Danger of explosion.
Methods and material for
containment and cleaning up:
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal .
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
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Section 7: Handling and Storage
Precautions for safe handling:
Advice on safe handling
If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe
gas/fumes/vapour/spray.
Advice on protection against fire
and explosion
Keep away from sources of ignition. - No smoking. Take precautionary measures against static
discharges. Vapours can form explosive mixtures with air.
Conditions for safe storage, including
any incompatibilities:
Requirements for storage rooms
and vessels
Keep container tightly closed. Keep locked up. Store in a place accessible by authorized persons only.
Provide adequate ventilation as well as local exhaustion at critical locations. Keep in a cool,
well-ventilated place. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
Advice on storage compatibility
Do not store together with: Oxidising agent. Pyrophoric or self-heating substances.
Further information on
storage conditions
Keep only in the original container in a cool, dry and well-ventilated place, away from foodstuffs.
Specific end use(s)
Liquid for coating of silicone based epithesis. For use by trained specialist staff.
Section 8: Exposure Controls/Personal Protection
Control parameters:
Exposure controls:
Appropriate engineering controls
If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe
gas/fumes/vapour/spray.
Protective and hygiene measures
Remove contaminated, saturated clothing immediately. Draw up and observe skin protection
programme. Wash hands and face before breaks and after work and take a shower if necessary .
When using do not eat or drink.
Eye/face protection
Wear eye/face protection.
Hand protection
When handling with chemical substances, protective gloves must be worn with the CE-label including
the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a
function of the specific working place concentration and quantity of hazardous substances. For special
purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned
above together with the supplier of these gloves.
Suitable are gloves of the following material: FKM (fluoro rubber) , NBR (Nitrile rubber)
Skin protection
Flame-retardant protective clothing. Wear anti-static footwear and clothing.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Section 9: Physical and Chemical Properties
Information on basic physical and chemical properties:
Physical state
Liquid
Colour
Light yellow
Odour
Gasoline
pH-Value
Not determined
Changes in the physical state:
Melting point
Not determined
Initial boiling point and boiling range
90-100 °C DIN 51356
Flash point
<-21 °C DIN
Flammability:
Solid
Not applicable
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Gas
Not applicable
Lower explosion limits
0,8 vol. %
Upper explosion limits
8 vol. %
Ignition temperature
250 °C DIN 51794
Auto-ignition temperature:
Solid
Not applicable
Gas
Not applicable
Decomposition temperature
Not determined
Oxidizing properties
Not oxidizing
Vapour pressure (at 20 °C)
85 hPa
Vapour pressure (at 50 °C)
560 hPa
Density (at 20 °C)
0,66 g/cm³ DIN 51757
Water solubility
Insoluble
Solubility in other solvents
Not Determined
Partition coefficient
Not Determined
Vapour density
Not determined
Evaporation rate
Not Determined
Other information:
Solid content
Not Determined
Section 10: Stability and Reactivity
Reactivity
Flammable, Ignition hazard.
Chemical stability
The product is stable under storage at normal ambient temperatures.
Possibility of hazardous reactions
Reacts with : spontaneously flammable and combustible materials.
Conditions to avoid
Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Vapours can form
explosive mixtures with air. Higher temperatures advance the formulation of explosive vapour-air
mixtures, therefore don't expose the product to increased temperatures.
Incompatible materials
No information available.
Hazardous decomposition products
No known hazardous decomposition products.
Section 11: Toxicological Information
Information on toxicological effects:
Acute toxicity
Harmful if swallowed.
ATEmix calculated
ATE (oral) 2000,0 mg/kg
CAS No
64742-49-0
Chemical name
Exposure routes
Method
Dose
Species
Naphtha (petroleum), hydrotreated light; Low boiling point hydrogen treated naphtha
oral
LD50
2000 mg/kg
Rat
dermal
LD50
4000 mg/kg
Rabbit
inhalative (4 h) vapour
LC50
54 mg/l
Rat
Irritation and corrosivity
Based on available data, the classification criteria are not met.
Sensitising effects
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
Severe effects after repeated or
prolonged exposure
Based on available data, the classification criteria are not met.
Source
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Carcinogenic/mutagenic/toxic
effects for reproduction
May cause genetic defects. (Naphtha (petroleum), hydrotreated light; Low boiling point hydrogen
treated naphtha) May cause cancer. (Naphtha (petroleum), hydrotreated light; Low boiling point
hydrogen treated naphtha).
Aspiration hazard
Based on available data, the classification criteria are not met.
Additional information on tests
This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP]. Special
hazards arising from the substance or mixture.
Section 12: Ecological Information
Toxicity:
The product is not: Ecotoxic
Persistence and degradability
The product has not been tested.
Bio accumulative potential
The product has not been tested.
Mobility in soil
The product has not been tested.
Results of PBT and vPvB assessment
Not identified as PBT/ vPvB substances.
Other adverse effects
No information available.
Further information
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
Section 13: Disposal Considerations
Waste treatment methods:
Advice on disposal
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of
waste according to applicable legislation.
Contaminated packaging
This material and its container must be disposed of as hazardous waste. Handle contaminated
packages in the same way as the substance itself.
Section 14: Transport Information
UN Number
1268
DG Proper shipping name
Petroleum Distillates N.O.S
DG Class and subsidiary risk
Class 3
Packaging group
II
Hazchem code
3YE
Dangerous Goods-Segregation
This product is classified as Dangerous Goods Class 3, packing group II.
Please consult NZS 5433 Safe Transport of Dangerous Goods for more information.
Flammable liquids
Flammable
Section 15: Regulatory Information
NZ Group Standard &
EPA Approval Code
Surface Coatings and Colourants (Flammable, [Toxic6.7])
HSR002669
HSNO Controls:
Trigger quantities for this substance:
Approved Handler
Location Certificate
Tracking Trigger Quantities
Signage Trigger Quantities
Emergency Response Plan
Trigger Quantities
Trigger Quantity
≥ 250L if container > 5L
≥ 500L if container < 5L
100 L (>5L), 250 L (<5L); 50 L open
Not applicable
250 L (liquid) / kg (solid)
1,000 L (liquid)
Section 16: Other Information
Full text of phrases referred to
under section 3
R45
R46
May cause cancer.
May cause heritable genetic damage.
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R65
H225
H302
H304
H340
H350
Harmful: may cause lung damage if swallowed.
Highly flammable liquid and vapour.
Harmful if swallowed.
May be fatal if swallowed and enters airways.
May cause genetic defects.
May cause cancer
This document has been compiled by Ivoclar Vivadent Ltd on behalf of the manufacturer of the product and serves as the manufacturer's
Safety Data Sheet ('SDS'). It is based on information concerning the product which has been provided to Ivoclar Vivadent (NZ) Ltd by the
manufacturer or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety
and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly
from the manufacturer. While Ivoclar Vivadent (NZ) Ltd has taken all care to include accurate and up-to-date information in this SDS, it does not
provide any warranty as to accuracy or completeness. As far as lawfully possible, Ivoclar Vivadent (NZ) Ltd accepts no liability or any loss, injury or
damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information
contained in this SDS. The information herein is given in good faith, but no warranty, express or implied is made.
Issue date: 13 May 2015
Date Ivoclar Vivadent Ltd prepared: 9 June 2016
Review date: 13 May 2020