SINGAPORE INTEGRATED MANUFACTURING SITE Singapore Refinery Singapore Chemical Plant 18 Pioneer Road Singapore 628498 100 Jurong Island Highway Singapore 627867 Tel : 65 6660 6000 Fax : 65 6631 6000 Tel : 65 6586 6000 Fax : 65 6586 6119 WORLD-SCALE INTEGRATED MANUFACTURING SITE SAFETY, HEALTH & ENVIRONMENT ExxonMobil has had a long presence in Singapore. the advantages of a global functional organization The safety of our employees, contractors, and What started out as a kerosene trading house in and co-located manufacturing. communities is the core of our commitment to 1893 is today a multi-billion-dollar manufacturing operations integrity. We remain steadfast in our and marketing business with over US$10 billion in The Singapore Refinery produces primarily goal that Nobody Gets Hurt. Excellence in safety, fixed asset investments and a diverse workforce of gasoline, diesel, jet fuel, propane, naphtha base security, and health in the workplace is a core value over 3,300 employees. oil, asphalt, wax, and lubricants. It also serves as for our company. We manage the risks associated the chemical plant’s primary source of feedstock. with our operations through the implementation The Singapore Refinery is fully integrated with the The Singapore Chemical Plant in turn produces of our Operations Integrity Management System Singapore Chemical Plant to form ExxonMobil’s the basic building blocks for high-performance (OIMS). The OIMS Framework establishes common largest integrated manufacturing site in the world. polymers and specialty chemicals used to make worldwide expectations for addressing safety, Our integration of facilities allows us to upgrade consumer goods such as clothing, upholstery, security, health, environmental, and social risk in each molecule to its highest value as we leverage diapers, food storage and mobile phones. every aspect of our business. 01 WORLD-SCALE INTEGRATED MANUFACTURING SITE Singapore Refinery The Singapore Refinery is a world-scale refining complex. Together with the newly-expanded Singapore Chemical Plant, they form the largest integrated ExxonMobil manufacturing site in the world. The Singapore Refinery boasts two operating sites - one on the mainland (Jurong) and another on Jurong Island (Pulau Ayer Chawan or PAC). This integrated refinery has a crude distillation capacity of about 592,000 barrels per day producing fuels, lubricant basestock and Chemicals feedstock for its customers and sister plants each day. The Singapore Refinery also manufactures industrial and automotive lubricants and aromatics. FACTS & FIGURES: PRODUCTS Workforce Strength Fuels & Chemical Feedstock More than 900 employees - Liquefied Petroleum Gas (LPG) - Motor Gasoline - Naphtha - Kerosene/Jet Fuel - Gas Oil/ Diesel - Heavy Fuel Oil Residuals Total Throughput Jurong : 302,000 barrels per day PAC : 290,000 barrels per day Lubricants & Specialties - Lubricant Basestocks Group I & II - Paraffin Waxes - Asphalt - Solvents Aromatics - Paraxylene - Benzene - Orthoxylene - Toluene 02 SINGAPORE REFINERY • INTRODUCTION SINGAPORE REFINERY Fuels ExxonMobil produces high quality fuels and these are marketed all around the world. The range of fuels is distributed through its business-to-business segments of Industrial & Wholesale, Aviation and Marine. Production: - Fuels: 427 KBD PRODUCTS AND THEIR END USES: Liquefied Petroleum Gas (LPG) Kerosene (Jet Fuel) Uses: Clean fuel for heating and cooking. Uses: Domestic heating and to manufacture solvents. The refined middle distillate version is used as jet fuel. Naphtha Uses: Feedstock for motor gasoline and petrochemical industry such as the production of aromatics and ethylene. What is KBD? This refers to the volume rate of Thousand Barrels per Day. Motor Gasoline Uses: Fuel for motor vehicles. Also called petrol. Gas Oil / Diesel Uses: Motor fuel for compression ignition engine in heavy vehicles and marine vessels. Light heating oil for industrial and commercial purposes. Heavy Fuel Oil Residual Uses: Heating and processing purposes in power plants, commercial buildings and industrial factories. Also used to power marine vessels. 03 SINGAPORE REFINERY • FUELS SINGAPORE REFINERY Lubricants & Specialties Lubricants are specially blended from basestocks, refinery products and additives to give them their unique strengths and properties. ExxonMobil’s Lubricants and Specialties business offers its consumers leading lubricant products carrying the brands of Mobil 1, Mobil SHC and Mobil Delvac. Its premium engine oil, Mobil 1, delivers significant fuel economy benefits while maintaining outstanding engine protection and lower emissions. Production: - Lubricants: 38 KBD PRODUCTS AND THEIR END USES: Basestocks Groups I & II Paraffin Waxes Proprietary Catalytic Innovation Group I basestocks are conventional lubricants made using a solvent refining technique while Group II are derived from hydrocracking and hydro-isomerisation technology. Uses: Industrial greases and oils, automotive lubricants and sealants. The pale yellow or white waxes are residues extracted from Group I Base Lubricants. Uses: Food packaging, water proofing of paper and fabrics, candles and cosmetics. ExxonMobil’s state-of-the-art Group II lubricants plant boasts a proprietary catalyst which produces lubricants with attractive characteristics like greater thermal, volatility and oxidation stability. These lubricants are intended for a market that requires fuel economy, sustained emissions performance, extended lubricant life and greater engine protection. Solvents Common ingredient in paints, glues and enamels. Uses: Household cleaners, anti-freeze, floor polish, nail polish remover and hairspray. 04 SINGAPORE REFINERY • LUBRICANTS & SPECIALTIES TECHNOLOGY FEATURE: Asphalt This solid to semi-viscous hydrocarbon is resistant to most chemicals and weather conditions. Uses: Road surfaces, roofing. SINGAPORE REFINERY Jurong Aromatics Plant Aromatics are hydrocarbons which contain one or more six-carbon benzene rings. The name was derived from the fact that many aromatic hydrocarbons have a fragrant odor. Production: - Benzene: 330 KTA - Paraxylene: 420 KTA - Toluene: 242 KTA - Orthoxylene: 206 KTA What is KTA? This refers to the mass rate which is kilo tonne per annum. PRODUCTS AND THEIR END USES: TECHNOLOGY FEATURE: Paraxylene ExxonMobil Xymaxsm and TransPlussm Technology It is a feedstock used for the manufacture of polyesters and polyethylene terephthlate (PET). Uses: Plastic bottles, clothing, transparent film packaging and screen protectors. Benzene It is a building block for a wide range of intermediate chemicals, such as styrene for polystyrene, phenol for polycarbonates and cyclohexane for nylon production. Uses: Compact discs, polystyrene cups, automotive tyres and water bottles. Jurong Aromatics Plant uses ExxonMobil state-of-the-art xylene isomerization Xymaxsm technology and heavy aromatics transalkylation TransPlussm technology. In addition it also uses Honeywell’s UOP Parex™ and Sulfolane™ technology to recover paraxylene and benzene. Orthoxylene It is the principal precursor to phthalic anhydride, a key raw material to produce plasticizers. Uses: Flexible PVC applications in inflatables, wires, cables and synthetic leather. Toluene This clear liquid, that smells like paint thinner, is used mainly as a solvent and feedstock for the manufacture of polyurethane. Uses: Paint solvents, lacquers, adhesives and octane booster in gasoline. 05 SINGAPORE REFINERY • JURONG AROMATICS PLANT Singapore Refinery Process Overview Liquefied Petroleum Gas (LPG) Motor Gasoline Naphtha Kerosene Naphtha Crude Distillation Units Solvents Aromatics Plant Paraxylene Benzene Orthoxylene Toluene Diesel Aromatic Solvents Heavy Gas Oil Steam Cracker Fuel Oil Crude Oil Lubes Plant Group I Basestock Group II Basestock Asphalt/Wax Fuel Oil 06 SINGAPORE REFINERY PROCESS OVERVIEW Chemical Plant process Refinery process Singapore Chemical Plant Process Overview FEEDSTOCK from ExxonMobil Asia Pacific Refineries C 2 - Ethylene Polyethylene Plant = Polyethylene Sales C 3 - Propylene Polypropylene Plant = Metallocene Elastomers Plant Polypropylene Specialty Elastomers Steam Cracker Sales C4s - Butenes SHU/MTBE * Oxo Alcohol Plant Oxo Alcohol MTBE C5-C8 - LSGHU ** Fuel Oil POX *** Olefins & Aromatics Motor Gasoline Cogeneration Steam Power Fuel Oil Aromatics Plant * Selective Hydrogenation Unit/Methyl Tertiary Butyl Ether ** Lower Sulphur Gasoline Hydrogenation Unit *** Partial Oxidation Unit Benzene Paraxylene Toulene 07 SINGAPORE CHEMICAL PLANT PROCESS OVERVIEW Singapore Chemical Plant The Singapore Chemical Plant (SCP) is ExxonMobil Chemical’s largest integrated petrochemical complex in the world. The plant employs state-of-the-art chemical processing technologies for high performance manufacturing in today’s competitive global chemicals market. It is fully integrated with the refinery, which also provides feedstock to the steam crackers. FACTS & FIGURES: PRODUCTS Workforce Strength - Ethylene - Propylene - Butene-1 - Butenes - MTBE - Motor Gasoline - Polyethylene - More than 900 employees 08 SINGAPORE CHEMICAL PLANT • INTRODUCTION - Polypropylene - Specialty Elastomers - Oxo alcohol - Isopar Fluids - Benzene - Paraxylene - Toluene SINGAPORE CHEMICAL PLANT Singapore Olefins Plant An olefin, or alkene, is an unsaturated chemical compound containing at least one carbon-to-carbon double bond. It is a basic ingredient in many chemical and polymer products. Production: - Ethylene: 1,900 KTA - Butene-1: 100 KTA - Butenes: 450 KTA - MTBE: 85 KTA - Motor gasoline : 950 KTA PRODUCTS AND THEIR END USES: TECHNOLOGY FEATURE: Ethylene The Steam Crackers It is a basic building-block for making a wide variety of chemical and polymer products, including polyethylene. Uses: Detergent, plastic bags, film, paint, cosmetics. Propylene It is a basic building-block for making polypropylene, polymers and other chemicals. Uses: Carpets, upholstery, thermal underwear, yachts and polymer banknotes. Butenes Butenes are used as a feedstock in the synthesis of intermediate alcohols. Uses: Wiring, cabling, vinyl flooring. Methyl Tertiary Butyl Ether (MTBE) It is an additive used in motor gasoline to raise the oxygen content and octane number. Uses: Octane enhancer and anti-knocking agent in motor gasoline. The heart of the chemical plant are two world-scale steam crackers that use proprietary technology to process hydrocarbon feed molecules into basic building blocks such as ethylene, propylene and butene-1. These are subsequently fed into the polymers plants to produce polyethylene, polypropylene and specialty elastomers. Butene serves as a feedstock to the oxo alcohol plant to produce to produce iso-nonyl alcohol and also to the polymers plants as a co-monomer feed. Benzene, which is produced from the steam cracker, is recovered at the aromatics plant. Other by-products from the steam crackers are sent to the cogeneration units to generate steam and electricity for use by the chemical plant. This makes the plant an energy-efficient manufacturing facility. 09 SINGAPORE CHEMICAL PLANT • SINGAPORE OLEFINS PLANT SINGAPORE CHEMICAL PLANT Singapore Polyethylene Plant Ethylene from the Singapore Olefins Plant is the main feedstock to produce polyethylene through a polymerization process. Production: - Polyethylene: 1,900 KTA PRODUCTS AND THEIR END USES: TECHNOLOGY FEATURE: Polyethylene UNIPOL™ Polyethylene Technology This is a polymer of ethylene that is versatile and widely used to make plastic products. Uses: Product packaging, garbage bags, bread wrappers and electrical insulation. The plant is the world’s highest capacity single-line UNIPOL™ Polyethylene Process plant integrated with the world’s highest capacity polyethylene extrusion and pelletising line. The UNIPOL™ Polyethylene Process has, by far, the most throughput capacity of any polyethylene process. Enable™ and Exceed™ Metallocene Polyethylene (mPE) Resins The Enable™ and Exceed™ mPE resin grades are linear low density polyethylene made using metallocene catalysts, which offer tough and high-clarity film applications. Uses: Packaging film, lamination film, heavy-duty sacks. 10 SINGAPORE CHEMICAL PLANT • SINGAPORE POLYETHYLENE PLANT SINGAPORE CHEMICAL PLANT Singapore Polypropylene Plant Propylene from the Singapore Olefins Plant is the main feedstock to produce polypropylene through a polymerization process. Production: - Polypropylene: 930 KTA PRODUCTS AND THEIR END USES: TECHNOLOGY FEATURE: Polypropylene ExxonMobil Polypropylene Technology This propylene polymer is a highly versatile thermoplastic that serves double duty, both as a plastic and a fiber. It is used to manufacture durable and nondurable consumer products. Uses: Plastic containers, carpeting, car seats, sports apparel, diapers and packaging. The plant is among the world’s highest in capacity, using the ExxonMobil Polypropylene Technology for producing homo-polymer and impact co-polymer resins. ExxonMobil also licenses this proprietary innovation, which is a pioneering integration of polypropylene slurry and gas phase technologies. 11 SINGAPORE CHEMICAL PLANT • SINGAPORE POLYPROPYLENE PLANT SINGAPORE CHEMICAL PLANT Singapore Metallocene Elastomers Plant ExxonMobil Chemical has one of the industry’s broadest portfolios of specialty elastomers. The Singapore Metallocene Elastomers Plant is the company’s primary supply point of Vistamaxx™ propylene-based elastomers to customers globally. Production: - Specialty Elastomers: 300 KTA PRODUCTS AND THEIR END USES: TECHNOLOGY FEATURE: Vistamaxx™ Propylene-Based Elastomers ExxonMobil Solution Metallocene Technology This is a propylene-based elastomer with unique attributes of high elasticity, softness, toughness, flexibility and adhesion to various polyolefins. Uses: Diapers, disposable medical and hygiene articles, food containers and packaging, toys and films. The plant uses ExxonMobil proprietary technology, including metallocene catalyst systems, to ensure uniform and consistent polymers for greater strength, better sealing properties and improved clarity. Exact™ Plastomers This is an ethylene alpha olefin co-polymer that bridges the gap between elastomers and plastics, with rubber-like properties and the processability of plastic. Used as a polymer modifier, it provides significantly higher flexibility and toughness than regular thermoplastics. Uses: Car interior trims and bumper, shoe soles, and films. 12 SINGAPORE CHEMICAL PLANT • SINGAPORE METALLOCENE ELASTOMERS PLANT SINGAPORE CHEMICAL PLANT Singapore Oxo Alcohol Plant Oxo Alcohols are obtained by adding carbon monoxide and hydrogen to an olefin to obtain an aldehyde, which is then hydrogenated. Key oxo alcohols are n-Butanol and iso-nonyl alcohol. Production: - Iso-nonyl Alcohol: 345 KTA - Isopar Fluids: 35 KTA PRODUCTS AND THEIR END USES: EXXONMOBIL COBALT FLASH TECHNOLOGY: Iso-nonyl Alcohol Fed by the butylene stream from the steam cracker, the Oxo Alcohol Plant utilises ExxonMobil Cobalt Flash Technology to produce oxo alcohols through hydroformylation. The high quality alcohol products are supplied to customers across Asia, including ExxonMobil’s own plasticizer plants in the region. Feedstock for the manufacture of plasticizers, which provide flexibility and elasticity to many products, including PVC. Uses: Floor and wall coverings, wire and cable insulation, synthetic leathers, automotive applications and healthcare products. Isopar Fluids Carrier fluids for household products. Uses: Aerosol insecticides, printing inks, degreasers and cleaners. 13 SINGAPORE CHEMICAL PLANT • SINGAPORE OXO ALCOHOL PLANT SINGAPORE CHEMICAL PLANT Singapore Aromatics Plant Aromatics are hydrocarbons which contain one or more six-carbon benzene rings. The name was derived from the fact that many aromatic hydrocarbons have a fragrant odor. Production: - Paraxylene: 530 KTA - Benzene: 580 KTA - Toluene: 380 KTA PRODUCTS AND THEIR END USES: TECHNOLOGY FEATURE: Paraxylene ExxonMobil Xymaxsm Technology It is a feedstock for the manufacture of polyesters and polyethylene terephthlate (PET). Uses: Plastic bottles, clothing, transparent film packaging and screen protectors. The plant uses ExxonMobil state-of-the-art xylene isomerization Xymaxsm technology and Honeywell’s UOP Parex™ and Sulfolane™ technology to recover paraxylene and benzene. Benzene It is a building block for a wide range of intermediate chemicals, such as styrene for polystyrene, phenol for polycarbonates and cyclohexane for nylon production. Uses: Compact discs, polystyrene cups, automotive tyres and water bottles. Toluene This clear liquid, that smells like paint thinner, is used mainly as a solvent and feedstock for the manufacture of polyurethane. Uses: Paint solvents, lacquers, adhesives and octane booster in gasoline. 14 SINGAPORE CHEMICAL PLANT • SINGAPORE AROMATICS PLANT SINGAPORE CHEMICAL PLANT Utilities Utilities, such as electricity and steam, are needed to support the production of chemicals in the various units of the Singapore Chemical Plant. Production: - Power generation: 360 MW - Steam: 1650 T/h USES IN MANUFACTURING: TECHNOLOGY FEATURE: Steam is produced for heating purposes and for driving large turbines, while electricity is produced to power electrical motors and product extruders around the plant. Fuel gas is fired in the heaters and furnaces to provide heat energy to the processes. Cogeneration The four large heat recovery steam generators (HRSG) at the plant embrace the concept of co-generation where steam and electrical power are generated at the same time. Fuel and air are first combusted and the hot air produced is used to turn gas turbines to generate electricity. The effluent gas is then sent to the HRSGs where heat energy is recovered to produce steam. Cogeneration enables the maximum amount of energy to be recovered per unit of fuel consumed. This reduces the overall amount of fuel used and lowers greenhouse gas emissions. Excess electricity generated is sold to the Singapore PowerGrid. Waste Water Treatment All waste water treated at site meets the discharge specifications required by the National Environmental Agency (NEA). Waste water treatment uses both the traditional Bio-Oxidation (BIOX) technology, as well as the state-of-the-art Membrane Bioreactor (MBR) technology. Using the MBR technology, the quality of effluent water can be made clean enough to be recycled directly back into the process. This reduces the overall amount of fresh water used in the plant. 15 SINGAPORE CHEMICAL PLANT • UTILITIES ExxonMobil in Singapore Historical Timeline 1999 Official merger of Exxon and Mobil to form ExxonMobil 1949 Stanvac starts to retail gasoline at service stations, with the first station at Outram Road. It also expands into aviation supplies business at Kallang Road 1911 Standard Oil opens an office on the fifth floor of Union Building at Collyer Quay 1906 The Mei Foo kerosene lamp is introduced 1893 Vacuum Oil sets up a trading post at Robinson Quay next to the Singapore River 16 HISTORICAL TIMELINE 1964 First Mobil service station opens at Pasir Panjang 1966 Mobil opens Singapore’s first refinery at Pioneer Road in Jurong 1963 Mobil enters the refining business. Esso starts a chemical operations department which later becomes Exxon Chemical Singapore Pte Ltd. 1961 Bottled gas introduced under the Stangas brand name 1974 Mobil introduces the first synthesized motor oil in this part of the world 1970 Esso’s refinery at Pulau Ayer Chawan starts operations 1986 Esso introduces the convenience store concept to Singapore with the first service station to have a mini-mart at West Coast Road 2003 ExxonMobil and NTUC Fairprice form alliance to introduce new service station retail concept in Singapore 2013 SCP expansion starts up 2004 ExxonMobil commemorates three decades of innovation and leadership in synthetic motor oils with the 30th anniversary of Mobil 1. 2001 Singapore Chemical Plant (SCP) starts up www.exxonmobil.com.sg