Henkel Solutions Medical Electronics 2 | Medical Electronics Overview Accurate diagnostics, improved alternative treatments and patient monitoring are all critical needs of the medical electronics industry. But, none of this is possible without the high-reliability medical devices used to facilitate these objectives. Henkel’s advanced semiconductor packaging and assembly materials are delivering the solutions needed to address the demanding requirements of nextgeneration medical electronics. There’s no doubt that improving access to patients’ data has enabled medical professionals to provide personalized care and has expanded early intervention programs for the treatment of chronic conditions. Technologies such as implantable medical devices and patient monitoring sensors that make this type of patient care possible now require a form factor that is only achieved through advanced electronic devices, materials and assembly methods. Henkel’s technical expertise, low-risk partnership proposition, innovation philosophy, world-class global support infrastructure and history as a leading formulator of market-leading materials ensure that we will enable the future advancement of the medical electronics industry. Medical Electronics | 3 4 | Medical Electronics Index Medical Inks & Coatings Electrically Conductive Inks Silver/ Silver Chloride NonConductive Adhesives Water-Based Electrically Conductive Pastes NonConductive Pastes Dam Fill Glob Tops General LOCTITE ECCOBOND FP 4451TD LOCTITE ECCOBOND FP 4450HF LOCTITE ECCOBOND EO 1060 LOCTITE ECCOBOND FP 4651 LOCTITE ECCOBOND EO 1072 LOCTITE ECCOBOND FP 4802 LOCTITE ECCOBOND FP 4460 PTC Carbon Silver LOCTITE EDAG 6037SS E&C LOCTITE EDAG 452SS E&C Carbon Silver Silver/ Silver Chloride LOCTITE ABLESTIK 84-1LMISR4 LOCTITE ABLESTIK 84-3 LOCTITE ECI 8001 E&C LOCTITE EDAG 109 E&C LOCTITE ECI 1001 E&C LOCTITE EDAG 6038SS E&C LOCTITE EDAG PD 038 E&C LOCTITE EDAG 112 E&C LOCTITE ECI 1005 E&C LOCTITE EDAG PE 428 E&C LOCTITE ABLESTIK CA 3556HF LOCTITE ABLESTIK 2025D LOCTITE EDAG C 932-51 E&C LOCTITE EDAG 479SS E&C LOCTITE EDAG 7019 E&C LOCTITE EDAG PF 021 E&C LOCTITE EDAG C 932-74 E&C LOCTITE EDAG 725A E&C LOCTITE EDAG PE 007 E&C LOCTITE EDAG PF 455B E&C LOCTITE EDAG PF 407C E&C LOCTITE EDAG SS 24600 E&C COB Encapsulants LOCTITE ABLESTIK CE 3103WLV Medical Electronics | 5 Electronics PCB Protection Solder Materials Underfills Conformal Coatings Low Pressure Molding LOCTITE 5293 MACROMELT MM 6208 Pb-Free HalideFree Pb-Free HalogenFree Pb-Free Water Wash SnPb No-Clean No-Clean HalogenFree Water Wash NonReworkable Reworkable LOCTITE ECCOBOND 3128 LOCTIITE 5296 MACROMELT Q 5353 LOCTITE MULTICORE LF 318 LOCTITE MULTICORE HF 212 LOCTITE MULTICORE WS 300 LOCTITE MULTICORE MP 218 LOCTITE MULTICORE MF 388 LOCTITE MULTICORE C 400 LOCITE MULTICORE HYDRO X LOCTITE ECCOBOND E 1216M LOCTITE ECCOBOND UF 3810 LOCTITE ECCOBOND 3707 LOCTITE STYCAST PC 18M LOCTITE STYCAST UV 7993 Liquid Fluxes Pastes LOCTITE MULTICORE HF 250DP LOCTITE MULTICORE MFR 301 Wires Capillary Flow LOCTITE ECCOBOND FP 4531 LOCTITE ECCOBOND XE 1218 Edgebond 6 | Medical Electronics Inks & Coatings ELECTRICALLY CONDUCTIVE-PTC INKS PRODUCT DESCRIPTION LOCTITE ECI 8001 E&C Positive Temperature Coefficient (PTC), screen printable ink designed for applications where self-regulating heaters are required. Formulated to rapidly heat to a specific threshold temperature and then maintain constant temperature for the device. APPLICATION Self-regulating heating elements. CURE SCHEDULE SHEET RESISTANCE OHM/SQUARE/25μ 10 min. @ 120°C 1,700 CURE SCHEDULE SHEET RESISTANCE OHM/SQUARE/25μ ELECTRICALLY CONDUCTIVE-CARBON INKS PRODUCT DESCRIPTION APPLICATION LOCTITE EDAG 109 E&C Carbon ink for flexographic/rotogravure printing on plastic film (PET, PVC) and paper substrates. Bio and medical sensors. 1 min. @ 120°C <30 LOCTITE EDAG C 932-51 E&C Rotary screened and blendable ink. Printed heaters. 4 min. @ 120°C 10,000-15,000 LOCTITE EDAG C 932-74 E&C Rotary screened and blendable ink. Printed heaters. 4 min. @ 120°C <50 LOCTITE EDAG PF 407C E&C Screen printable carbon ink for plastic film and paper substrates. Membrane touch switches and keyboards. Bio and medical sensors. 15 min. @ 120°C <15 LOCTITE EDAG SS 24600 E&C Dispersion of finely divided graphite in a thermoplastic resin that rapidly air dries to form a flexible conductive coating. Bio and medical sensors. Air dries in approx. 10 min. <40 CURE SCHEDULE SHEET RESISTANCE OHM/SQUARE/25μ 10 min. @ 120°C minimum, in convection oven <0.030 15 min. @ 95°C <0.020 ELECTRICALLY CONDUCTIVE-SILVER INKS PRODUCT DESCRIPTION LOCTITE ECI 1001 E&C Screen printable, conductive ink designed for membrane-touch switch and other flex circuit applications. Offers excellent balance of flexibility, hardness and adhesion. PTF circuits, membrane touch switches and flexible circuits. Screen printable silver ink for PET film. Conductive traces in membranetouch switches and other flexible circuitry. LOCTITE EDAG 479SS E&C APPLICATION Medical Electronics | 7 ELECTRICALLY CONDUCTIVE-SILVER INKS PRODUCT DESCRIPTION APPLICATION CURE SCHEDULE SHEET RESISTANCE OHM/SQUARE/25μ LOCTITE EDAG 725A E&C Silver conductive polymer thick film ink is designed for use in the production of low voltage circuitry on polyester film. Conductive traces in membrane touch switches and other flexible circuitry. 15 min. @ 120°C <0.015 SILVER/SILVER CHLORIDE PRODUCT DESCRIPTION APPLICATION CURE SCHEDULE SHEET RESISTANCE OHM/SQUARE/25μ LOCTITE EDAG 6037SS E&C Conductive screen printable ink. Designed for use as an electrode material in medical bio-sensing devices. Bio and medical sensors. Dry 30 min. @ 80°C or 15 min. @ 95°C or 15 min. @ 120°C <0.12 LOCTITE EDAG 6038SS E&C Conductive screen printable ink. Designed for use as an electrode material in medical bio-sensing devices. Bio and medical sensors. Dry 30 min. @ 80°C or 15 min. @ 95°C or 15 min. @ 120°C ≤0.04 LOCTITE EDAG 7019 E&C Screen printable, silver-filled polymer thick film that also contains silver chloride. It is based on a thermoplastic resin and has been formulated to provide excellent adhesion to the wide variety of substrates used in the manufacture of electrically conductive medical devices. Bio and medical sensors. 5 min. flash, 30 min. bake @ 71°C <0.05 Silver/silver chloride ink for flexographic/rotogravure printing on plastic film. Bio and medical sensors. 2 min. @ 110°C <0.100 CURE SCHEDULE SHEET RESISTANCE OHM/SQUARE/25μ UV @ 0.5 joule/cm² <2 x 109 0.5 joule/cm2 >2×109 LOCTITE EDAG PE 007 E&C NON-CONDUCTIVE PRODUCT DESCRIPTION LOCTITE EDAG 452SS E&C Screen printable, UV curable dielectric ink for plastic film and paper substrates. Excellent flexibility. Tail coating membrane touch switches and PC desktop/ notebook keyboards. LOCTITE EDAG PD 038 E&C Screen printable, UV curable dielectric ink for ITO treated PET film and copperetched circuitry. Dot spacer for touch screens and computer/palm-top panels. Spacer for copper-etched circuitry. LOCTITE EDAG PF 021 E&C Encapsulating polymer designed to secure low profile surface mount devices to rigid or flexible substrates. Surface mount devices. 0.4 to 1.0 joule/cm² >1 Screen printable, UV curable dielectric ink for plastic film. Excellent humidity resistance. Crossover dielectric in membrane touch switches and PC desktop/ notebook keyboards. UV @ 0.5 joule/cm² <2 x 109 LOCTITE EDAG PF 455B E&C APPLICATION 8 | Medical Electronics Inks & Coatings WATER-BASED-CARBON INKS PRODUCT DESCRIPTION APPLICATION CURE SCHEDULE SHEET RESISTANCE OHM/SQUARE/25μ LOCTITE EDAG 112 E&C Air-drying graphite coating of unusually high conductivity. It provides excellent static bleed properties and acts as a protective energy absorbing layer. EMI shielding, protective coating on metals and plastics. Air dry 25 min. <50 WATER-BASED-SILVER INKS PRODUCT DESCRIPTION APPLICATION CURE SCHEDULE SHEET RESISTANCE OHM/SQUARE/25μ LOCTITE ECI 1005 E&C Designed to dry rapidly to form a flexible, conductive coating. It is suitable for applications using high speed flexographic printing techniques. RFID antenna, electronic circuitry and bio and medical sensors. 1 min. @ 70°C <0.050 CURE SCHEDULE SHEET RESISTANCE OHM/SQUARE/25μ 15 min. @ 95°C 0.0175 WATER-BASED-SILVER/SILVER CHLORIDE INKS PRODUCT LOCTITE EDAG PE 428 E&C DESCRIPTION Designed for printing on flexible substrates. Suitable for applications using flexographic or rotogravure printing techniques. APPLICATION Body contact pads, medical sensors. Medical Electronics | 9 Adhesives ELECTRICALLY CONDUCTIVE PASTES PRODUCT DESCRIPTION CURE TYPE SHELF LIFE CURE SCHEDULES VOLUME RESISTIVITY LOCTITE ABLESTIK 84-1LMISR4 Conductive adhesive for semi-conductor packaging applications. Ideal for small components or high speed dispense manufacturing. Heat 12 months @ -40°C 60 min. @ 175°C 0.0002 LOCTITE ABLESTIK CA 3556HF One-component, highly flexible, conductive adhesive for applications with large CTE mismatches between substrates. Snap cure capability. Heat 5 months @ -40°C 120 sec. @ 110°C 0.0025 LOCTITE ABLESTIK CE 3103WLV Electrically conductive adhesive with superior contact resistance stability. Pb-free alternative to solder attachment materials. Low viscosity for fine line dispensing. Heat 12 months @ -40°C 10 min. @ 120°C or 3 min. @ 150°C 0.0008 NON-ELECTRICALLY CONDUCTIVE PASTES PRODUCT DESCRIPTION CURE TYPE SHELF LIFE CURE SCHEDULES VOLUME RESISTIVITY LOCTITE ABLESTIK 84-3 Electrically insulative, one-component solvent-free product for die attach applications. Ideal for either auto dispense or screen printing. Heat 12 months @ -40°C 1 hr. @ 150°C 3.5 x 1013 LOCTITE ABLESTIK 2025D A hybrid chemistry die attach adhesive designed for PBGA, FlexBGA and for stacking BGA packages. Heat 12 months @ -40°C 30 min. ramp to 175ºC; hold 15 min. @ 175ºC 1.2 x 1013 10 | Medical Electronics COB-Encapsulants DAM PRODUCT DESCRIPTION RECOMMENDED CURE VISCOSITY cPs Tg °C LOCTITE ECCOBOND FP 4451TD Industry standard material for dam applications in BGA's. Low ionics. Ideal for tall and narrow dam dimensions. 30 min. @ 125°C or 90 min. @ 165°C 300,000 150 PRODUCT DESCRIPTION RECOMMENDED CURE VISCOSITY cPs Tg °C LOCTITE ECCOBOND FP 4450HF High flow, industry standard fill material. Also for use in cavity down BGA applications. Good for use in fine wire and low alpha applications. 30 min. @ 125°C or 90 min. @ 165°C 32,000 160 LOCTITE ECCOBOND FP 4651 Epoxy encapsulant features very low thermal expansion while retaining syringe dispense capabilities. 1 hr. @ 125°C + 90 min. @ 165°C 130,000 150 LOCTITE ECCOBOND FP 4802 High purity, liquid encapsulant for use in applications using lead-free solder. 1 hr. @ 120°C + 120 min. @ 165°C 80,000 50 POT LIFE @ 25°C CURE SCHEDULE Tg °C FILL GLOB TOPS: GENERAL PRODUCT DESCRIPTION LOCTITE ECCOBOND EO 1062 High glob formulation with low CTE and low ionic content. Ideal for more harsh environment applications. 25 days 4 - 6 hrs. @ 125°C 125 LOCTITE ECCOBOND EO 1072 One-component, high performance epoxy encapsulant with high Tg and low extractable ionics. Short cure cycle. 30 days 5 min. @ 140°C 135 LOCTITE ECCOBOND FP 4460 High purity, low stress glob top semiconductor encapsulant with excellent moisture resistance and working life. 2 days 3 hrs. @ 150°C 171 Medical Electronics | 11 PCB Protection CONFORMAL COATINGS PRODUCT DESCRIPTION RESIN TYPE VISCOSITY cPs CURE SCHEDULE LOCTITE 5293 Repairable, solvent-free, medium viscosity, UV/moisture cure silicone suited to brush, dip and selective coating. Silicone One-Component 600 20 sec. @ 70 mW/cm2 + 72 hrs. @ room temperature LOCTITE 5296 Heat cure silicone can be applied with brush, dip, or spray. High reliability for automotive. Clear. Silicone One-Component 200 Heat 7 min. @ 125°C LOCTITE STYCAST PC 18M Flexible solvent-based, one-component urethane coating. Provides good thermal shock resistance. MIL-I-46058C. Urethane One-Component 350 2 hrs. @ 60°C LOCTITE STYCAST UV 7993 Solvent-free , 100% solids, one-component, dual UV cure and secondary moisture cure conformal coating providing excellent protection against moisture and other harsh environments. Urethane Acrylate One-Component 120 5 sec. UV + 4 days @ room temperature LOW PRESSURE MOLDING PRODUCT DESCRIPTION OPERATING TEMP, °C VISCOSITY @ 210°C MPA.S cP SOFETENING POINT, °C Tg °C MACROMELT MM 6208 Moldable polyamide with excellent adhesion to tough substrates. Great flexibility offers incredible strain relief on cables and wires. Ideal for encapsulation of heat producing components in appliance and consumer electronics. UL RTI 95°C. -40 to 130 3,200 150 to 160 -37 193 79 570 MACROMELT Q 5353 Hot melt adhesive for general assembly appications in cable industry, especially for bonding and coating polypropylene and other polyolefins. -20 to 120 10,500 151 to 161 -20 N/A 90 Approx. 400 CTE ABOVE TG SHORE A (PPM/°C) HARDNESS ELONGATION AT BREAK, % 12 | Medical Electronics Solder Materials PASTES-Pb-FREE HALIDE-FREE PRODUCT DESCRIPTION ALLOY METAL LOADING (% WEIGHT) PARTICLE SIZE DISTRIBUTION LOCTITE MULTICORE LF318 A halide-free, no-clean, Pb-free solder paste that has excellent humidity resistance and a broad process window for both reflow and printing. Offers high tack to resist component movement during high-speed placement, long printer abandon times and excellent solderability over a wide range of reflow profiles in air and N2 reflow ovens and across a wide range of surface finishes. 90iSC (Hi-Rel)* 96SC (SAC387) 97SC (SAC305) 88.5 AGS (type 3) DAP (type 4) IPC TACK APPLICATION (g/MM2) 1.8 2.3 Printing 25-150mms-1 IPC/J-STD-004B CLASSIFICATION ROL0 PASTES-Pb-FREE HALOGEN FREE PRODUCT DESCRIPTION ALLOY METAL LOADING (% WEIGHT) PARTICLE SIZE DISTRIBUTION JIS TACK (gF) APPLICATION IPC/J-STD-004B CLASSIFICATION LOCTITE MULTICORE HF 212 Halogen-free, no-clean, low voiding Pbfree solder paste. Excellent wetting to a broad range of metallization. Wide process 90iSC (Hi-Rel)* window for printing amd minimal slump 97SC (SAC305) with abandon time of 1 hour. Optimize for long soak reflow. 88.5 AGS (type 3) DAP (type 4) 62 Printing 40 -120mms-1 ROL0 LOCTITE MULTICORE HF 250DP Halogen-free, no-clean, Pb-free solder paste shows excellent humidity resistance 90iSC (Hi-Rel)* and solderability when reflowed in both air 96SC(SAC387) and nitrogen across a wide range of surface 97SC (SAC305) finishes including OSP copper. 88.5 AGS (type 3) DAP (type 4) DAP+ (type 4.5) 16 Printing 50 -140mms-1 ROL0 PASTES-Pb-FREE WATER WASH PRODUCT DESCRIPTION ALLOY % METAL LOADING IPC TACK (g/MM2) APPLICATION IPC/J-STD-004B CLASSIFICATION LOCTITE MULTICORE WS 300 Flux system specially formulated for lead-free alloys. High performance, water washable solder paste. Residues are easily removed with DI water, without the need for a saponifier. Good open time with excellent print definition and soldering. 96SC (SAC387) 97SC (SAC305) 87 0.8 Printing 25-100mms-1 ORH1 * High reliability. Medical Electronics | 13 PASTES-Sn-Pb NO CLEAN PRODUCT LOCTITE MULTICORE MP 218 DESCRIPTION ALLOY High activity, soft residue, colorless, halidefree, no-clean solder paste that displays outstanding resistance to high temperature Sn62/Sn63/63S4 and humidity environments. Suitable for a (anti-tombstoning) large range of assembly processes, including rheo pump, proflow, large high-den. % METAL LOADING IPC TACK (g/MM2) APPLICATION IPC/J-STD-004B CLASSIFICATION 89.5 1.6 Printing 25-150mms-1 ROL0 LIQUID FLUXES-NO-CLEAN PRODUCT DESCRIPTION SOLIDS CONTENT (%) ACID VALUE (MG KOH/G) APPLICATION IPC/J-STD-004B CLASSIFICATION LOCTITE MULTICORE MF 388 Sustained activity in high preheats for dual wave and lead-free processes. High PTH fill, low residues. High reliability. Solventbased flux may be thinned with IPA. 3.5 20 Spray ROL0 LOCTITE MULTICORE MFR 301 Higher solids, halide-free flux for better wetting on reduced solderability surfaces and to minimize bridging on complex geometries. Fully lead-free and dual wave compatible. Solventbased flux may be thinned with IPA. 6.0 40 Spray/Foam ROM0 WIRES-HALOGEN-FREE PRODUCT LOCTITE MULTICORE C 400 DESCRIPTION Halide-free, no-clean, clear residue, cored solder wire with increased flux content for improved wetting. ALLOY (SnPb) ALLOY (Pb-FREE) IPC/J-STD-004B CLASSIFICATION Sn60 Sn62 Sn63 96SC (SAC387) 97SC (SAC305) 99C (SnCu) ROL0 ALLOY (SnPb) ALLOY (Pb-FREE) IPC/J-STD-004B CLASSIFICATION Sn60 Sn62 Sn63 96SC (SAC387) 97SC (SAC305) 99C (SnCu) ORH1 WIRES-WATER WASH PRODUCT LOCTITE MULTICORE HYDRO X DESCRIPTION High activity, water washable-flux cored solder wire with excellent wetting on difficult substrates. 14 | Medical Electronics Underfills CAPILLARY FLOW-NON-WORKABLE PRODUCT DESCRIPTION VISCOSITY cPs POT LIFE @25°C RECOMMENDED CURE LOCTITE ECCOBOND E 1216M Filler filled non-reworkable, high reliability with 10 mm filler size. 3,252 4 days @ 25 ºC 3.5 min. @ 150ºC LOCTITE ECCOBOND FP 4531 A snap curable lower CTE Uunderfill for flip chip for rigid laminate and ceramic. 10,000 24 hr. @ 25 ºC 7 min. @ 160ºC LOCTITE ECCOBOND XE 1218 Reworkable, snap cure, void free, fast flowing underfill, which also provides excellent adhesion and reliability benefits. 1,100 10 days 10 min. @ 110°C CAPILLARY FLOW-REWORKABLE PRODUCT DESCRIPTION VISCOSITY cP POT LIFE @25°C RECOMMENDED CURE LOCTITE ECCOBOND UF 3810* Reworkable, epoxy underfill for CSP and BGA applications. 394 3 days ≤8 min. @ 130°C EDGEBOND PRODUCT DESCRIPTION CURE TYPE COLOR CURE SCHEDULES VISCOSITY cPs POT LIFE SHELF LIFE LOCTITE ECCOBOND 3128 Drive IC Chip reinforcement after drop test. Heat Cure Black 20 min. @ 80° 60 min. @ 60° 15,000 14 days @ room temperature 1 year @ -40°C LOCTITE ECCOBOND 3707** UV curable edgebond designed for bonding various types of electronic components on a PCB. UV Cure Opaque White >30 sec. @ 100 m/ Wcm2 9,595 < 7 days @ room temperature N/A * High Tg. ** UV cure. Medical Electronics | 15 Across The Board Encapsulants (Dam & Fill) CSP Underfills (Cornerbond) Non-Conductive Pastes Potting Compounds Electrically Conductive Pastes Gasketing Conformal Coatings Low Pressure Molding Printed Inks Sealants Surface Mount Adhesives Thermal Management Materials Solder Materials Assembly Film Adhesives AMERICAS ASIA-PACIFIC HEADQUARTERS: UNITED STATES Henkel Electronic Materials LLC 14000 Jamboree Road CHINA No. 332 Meigui South Road WaiGaoQiao Free Trade Zone Shanghai 200131, P.R. China Tel: +86.21.3898.4800 Fax: +86.21.5048.4169 Irvine, CA 92606 USA Tel: +1.714.368.8000 Tel: +1.800.562.8483 Customer Support: +1.888.943.6535 Fax: +1.714.368.2265 Henkel Electronic Materials LLC 20021 Susana Road Rancho Dominguez, CA 90221 USA Tel: +1.310.764.4600 Fax: +1.310.605.2274 BRAZIL Henkel Brazil Av. Prof. Vernon Krieble, 91 06690-250 Itapevi, Sao Paulo, Brazil Tel: +55.11.3205.7000 Across the Board, Around the Globe. www.henkel.com/electronics Henkel Huawei Electronics CO. LTD Songtiao Industrial Park Lianyungang Jiangsu Province 222006 China Tel: +86.518.8515.5336 Fax: +86.518.8515.3801 JAPAN Henkel Japan Ltd. 27-7, Shin Isogo-cho Isogo-ku Yokohama, 235-0017 Japan Tel: +81.45.758.1800 KOREA Henkel Technologies (Korea) Ltd. 6th Floor Dae Ryung Techno Town II 569-21 Gasan-dong, Geumcheon-gu, Seoul 153-771 Korea Tel: +82.2.6675.8000 Except as otherwise noted, all marks are trademarks and/or registered trademarks of Henkel and/or its affiliates in the U.S. and elsewhere. © Henkel Corporation, 2013. All rights reserved. 9786/LT-5892 (1/13) MALAYSIA Henkel (Malaysia) Sdn Bhd Lot 973, Jalan Kampung Baru Hicom Persiaran Tengku Ampuan, Lion Industrial Park Section 26, 40400 Shah Alam Selangor Darul Ehsan Tel: +603-51926200 Fax: +603-51926211 TAIWAN Henkel Taiwan Ltd Room A4, 19F-1, No.6, Sihwei 3rd Rd, Lingya Dist., Kaohsiung, Taiwan Tel: 886-7-335-7970 Fax: 886-7-335-1057 EUROPE BELGIUM Henkel Electronic Materials (Belgium) N.V. Nijverheidsstraat 7 B-2260 Westerlo Tel: +32.1457.5611 Fax: +32.1458.5530