Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 Figure 0.1: Sydney’s drinking water catchments Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 2 Table of Contents List of Figures ............................................................................................................................. 7 List of Tables .............................................................................................................................. 8 Executive Summary.................................................................................................................... 9 Highlights ................................................................................................................................... 9 1 Introduction .................................................................................................................... 12 1.1 2 3 This report ............................................................................................................. 13 Overview of the water supply network .......................................................................... 14 2.1 Warragamba system ............................................................................................. 16 2.2 Upper Nepean system........................................................................................... 16 2.3 Woronora system.................................................................................................. 17 2.4 Blue Mountains system......................................................................................... 17 2.5 Shoalhaven system ............................................................................................... 17 2.6 Hawkesbury-Nepean River ................................................................................... 18 SCA’s water monitoring program ................................................................................... 19 3.1 Quality assurance and quality control .................................................................. 19 3.2 Operating Licence ................................................................................................. 20 3.2.1 Raw water supplied for treatment ....................................................................... 21 3.2.2 Storages ................................................................................................................ 21 3.2.3 Catchments........................................................................................................... 21 3.2.4 Picnic area monitoring ......................................................................................... 21 3.2.5 Algal monitoring ................................................................................................... 21 3.2.6 Cryptosporidium and Giardia monitoring ............................................................ 21 3.2.7 Wet weather monitoring...................................................................................... 22 3.2.8 Dam seepage ........................................................................................................ 22 3.2.9 Downstream of storages ...................................................................................... 22 3.3 Water Licences ...................................................................................................... 22 3.4 Future directions ................................................................................................... 22 3.4.1 Picnic taps ............................................................................................................. 23 3.4.2 Vertical profilers ................................................................................................... 23 3.4.3 Autosamplers ....................................................................................................... 23 3.4.4 Campaign monitoring ........................................................................................... 24 3.4.5 Healthy Catchments Strategy projects ................................................................. 24 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 3 3.4.6 Pesticides and SOCs .............................................................................................. 24 4 5 Applicable guidelines / benchmarks............................................................................... 25 4.1 Australian Drinking Water Guidelines (ADWG) 2011 ........................................... 25 4.2 Raw water supply agreements.............................................................................. 25 4.3 ANZECC 2000......................................................................................................... 27 4.4 Benchmarks for storages ...................................................................................... 27 4.5 Benchmarks for catchments ................................................................................. 28 4.6 Benchmarks for downstream rivers...................................................................... 28 4.7 Benchmarks for picnic area supplies .................................................................... 28 4.8 Benchmarks for cyanobacteria ............................................................................. 29 4.9 Benchmarks for Cryptosporidium and Giardia ..................................................... 30 Routine monitoring ........................................................................................................ 31 5.1 Quality Assurance/Quality Control ....................................................................... 31 5.2 Warragamba system ............................................................................................. 32 5.2.1 Catchments........................................................................................................... 34 5.2.2 Storages ................................................................................................................ 34 5.2.3 Water Filtration Plants ......................................................................................... 34 5.3 Upper Nepean system........................................................................................... 35 5.3.1 Catchments........................................................................................................... 37 5.3.2 Storages ................................................................................................................ 37 5.3.3 Water Filtration Plants ......................................................................................... 37 5.4 Woronora system.................................................................................................. 38 5.4.1 Catchments........................................................................................................... 40 5.4.2 Storage ................................................................................................................. 40 5.4.3 Water Filtration Plant ........................................................................................... 40 5.5 Blue Mountains system......................................................................................... 41 5.5.1 Catchments........................................................................................................... 43 5.5.2 Storages ................................................................................................................ 43 5.5.3 Water Filtration Plants ......................................................................................... 43 5.6 Shoalhaven system ............................................................................................... 44 5.6.1 Catchments........................................................................................................... 46 5.6.2 Storages ................................................................................................................ 46 5.6.3 Water Filtration Plants ......................................................................................... 46 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 4 5.7 Algal monitoring .................................................................................................... 46 5.7.1 Warragamba system ............................................................................................ 46 5.7.2 Upper Nepean system .......................................................................................... 47 5.7.3 Woronora system ................................................................................................. 47 5.7.4 Blue Mountains system ........................................................................................ 47 5.7.5 Shoalhaven system ............................................................................................... 48 5.8 Cryptosporidium and Giardia monitoring ............................................................. 48 5.8.1 Catchments........................................................................................................... 48 5.8.2 Storages ................................................................................................................ 49 5.8.3 Water Filtration Plants ......................................................................................... 49 5.9 Picnic area monitoring .......................................................................................... 50 5.10 Dam seepage monitoring ...................................................................................... 51 6 Monitoring for the Water Licences ................................................................................ 52 6.1 Water quality ........................................................................................................ 52 6.2 Water quantity ...................................................................................................... 52 6.2.1 Upper Nepean system .......................................................................................... 53 6.2.2 Woronora system ................................................................................................. 56 6.2.3 Shoalhaven system ............................................................................................... 56 6.3 Thermal impacts of environmental releases ........................................................ 57 6.3.1 Upper Nepean system .......................................................................................... 57 6.3.2 Woronora system ................................................................................................. 58 6.3.3 Shoalhaven system ............................................................................................... 59 7 Targeted and investigative monitoring .......................................................................... 61 7.1 Wet weather inflow monitoring ........................................................................... 61 7.2 Macroinvertebrate monitoring ............................................................................. 62 7.3 Investigative monitoring ....................................................................................... 65 7.3.1 Investigative monitoring for operational decision making .................................. 65 7.3.2 Scientific research ................................................................................................ 66 8 Incidents and events....................................................................................................... 69 8.1 Macarthur storm event ......................................................................................... 70 8.2 Major water quality incidents ............................................................................... 70 8.2.1 Elevated Algae Areal Standard Units in Kangaroo Valley raw water ................... 71 8.2.2 Elevated Algae Areal Standard Units in Prospect raw water ............................... 71 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 5 9 References ...................................................................................................................... 72 10 Glossary .......................................................................................................................... 74 11 Acronyms ........................................................................................................................ 78 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 6 List of Figures Figure 0.1: Sydney’s drinking water catchments .................................................................................... 2 Figure 2.1: Schematic of the water supply system ............................................................................... 15 Figure 5.1: Sampling sites in the Warragamba system (including inset Prospect Reservoir) ............... 32 Figure 5.2: Sampling sites in the Upper Nepean system. ..................................................................... 35 Figure 5.3: Sampling sites in the Woronora system. ............................................................................ 38 Figure 5.4: Sampling sites in the Blue Mountains system. ................................................................... 41 Figure 5.5: Sampling sites in the Shoalhaven system ........................................................................... 44 Figure 6.1: Annual inflows into Lake Nepean, Lake Yarrunga (Tallowa) and Lake Burragorang (Warragamba) since 1996-97................................................................................................................ 53 Figure 6.2: Environmental releases and spills – Cataract Dam ............................................................. 53 Figure 6.3: Environmental releases and spills – Cordeaux Dam ........................................................... 54 Figure 6.4: Environmental releases and spills – Avon Dam .................................................................. 54 Figure 6.5: Environmental releases and spills – Nepean Dam .............................................................. 55 Figure 6.6: Environmental releases – Broughtons Pass Weir ............................................................... 55 Figure 6.7: Environmental releases – Pheasants Nest Weir ................................................................. 56 Figure 6.8: Environmental releases and spills – Woronora Dam .......................................................... 56 Figure 6.9: Environmental releases and spills – Tallowa Dam .............................................................. 57 Figure 6.10: Upper Nepean system temperature profile ..................................................................... 58 Figure 6.11: Woronora system temperature profile ............................................................................ 59 Figure 6.12: Shoalhaven system temperature profile .......................................................................... 60 Figure 7.1: AUSRIVAS ratings for each of the sites sampled in 2013 .................................................... 64 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 7 List of Tables Table 2.1: Characteristics of the SCA’s major delivery systems............................................................ 16 Table 4.1 Health-related water quality characteristics......................................................................... 26 Table 4.2: Raw water supply agreements – Site specific standards(iv) .................................................. 27 Table 4.3: Water quality benchmarks for storages............................................................................... 28 Table 4.4: Water quality benchmarks for catchment streams ............................................................. 28 Table 4.5: Water quality benchmarks downstream of storages........................................................... 28 Table 4.6: Water quality guidelines for specific parameters at picnic areas ........................................ 29 Table 4.7: Cyanobacteria benchmarks throughout the SCA’s area of operations................................ 29 Table 5.1: Warragamba system catchments - percentage of samples exceeding benchmarks ........... 33 Table 5.2: Upper Nepean catchments - percentage of samples exceeding benchmarks..................... 36 Table 5.3: Woronora system catchments - percentage of samples exceeding benchmarks ............... 39 Table 5.4: Blue Mountains system storages - percentage of samples exceeding benchmarks............ 42 Table 5.5: Shoalhaven system catchments - percentage of samples exceeding benchmarks ............. 45 Table 5.6: Picnic areas - percentage of samples exceeding benchmarks. ............................................ 50 Table 6.1: Downstream of storages - percentage of samples exceeding benchmarks ........................ 52 Table 7.1: Number of wet-weather samples from SCA autosamplers 2013–14 .................................. 62 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 8 Executive Summary Under Section 14(1) of the Sydney Water Catchment Management Act 1999 a principal objective of the SCA is ‘to ensure that water supplied complies with appropriate standards of water quality’. The SCA Water Monitoring Program 2010-2015 (WMP) details a comprehensive and integrated monitoring plan covering catchments, reservoirs, intakes to water filtration plants, picnic area sites and downstream sites. The WMP has been developed in collaboration with NSW Health, Sydney Water and other wholesale customers. The program, endorsed by NSW Health, incorporates locations, frequency, benchmarks or guideline values for more than 200 characteristics. The WMP involves routine, event, algal, pathogen and hydrometric monitoring; employing field, laboratory and telemetered ‘real-time’ sampling. The WMP provides timely water quality data and information to inform operational decisions. The Australian Drinking Water Guidelines’ framework for the management of water supplies covers the whole supply chain from source to the consumer to ensure safe drinking water. The SCA is responsible for managing part of this supply chain (catchments, storages and raw water supply system) working closely with upstream stakeholders through to downstream customers so as to ensure the raw water supplied for treatment is of appropriate quality. Raw water is treated by the customers who report on drinking water quality. Monitoring of the water quality through this supply chain provides essential information with regards to the short and long term water quality risks. This report describes the results of the water quality monitoring undertaken by the SCA during 201314. The report is provided to meet the SCA’s statutory obligations in addition to providing stakeholders, students, researchers and the general public with water quality information for waters managed by the SCA. Highlights Guided by the SCA Water Quality Management Framework, the SCA successfully delivered agreed quantities and quality water to customers in full compliance with the Australian Drinking Water Guidelines (ADWG) for health related characteristics. Through proactive source selection, modelling and online monitoring, the SCA avoided or effectively managed water quality incidents to minimise impacts to customers. The 2013-2014 reporting period commenced with many storages operating at full capacity, with total storage volume at 98% on July 1, 2013. Below average inflows and no significant transfers over the reporting period caused total storage volume to fall to 82% by June 30, 2014. Water supplied to water filtration plants maintained very high compliance with raw water supply agreements. Source selection and system planning minimised the impact of elevated true colour on filtration plants supplied by Lake Burragorang and Nepean. Heavy metals, pesticides and synthetic organic compounds remained well below ADWG at all water filtration plant sites with very few detections. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 9 The SCA monitored for E. coli in picnic area supply as a further confirmation of the effectiveness of disinfection as it was difficult to maintain chlorine residual. The monitoring regime and guidelines will be revised from July 2014 in accordance with the NSW Private Water Supply Guidelines. Consistent with recent years, nutrients (nitrogen and phosphorus) and chlorophyll-a regularly exceeded ANZECC benchmarks in catchment sites with significant agricultural or urban development (e.g. Wollondilly and Kangaroo Rivers). In contrast, natural catchments (e.g. Burke and Cataract Rivers) rarely exceeded ANZECC benchmarks and continue to demonstrate the effectiveness of Special Areas in protecting water quality. Following inflows in June 2013, high concentrations of nutrients nitrogen and phosphorus were observed in a number of storages, lakes Burragorang and Yarrunga particularly. Despite the elevated nutrients, algal activity in 2013 was moderate with normal concentrations of chlorophyll-a and no algal toxins detected. Chlorophyll-a concentrations in Blue Mountains storages were significantly higher than previous years. Further analysis identified the non-toxic diatom Urosolenia as the dominant species. Water quality conformance for 2013-14 with regards to Raw Water Supply Agreements and Australian Drinking Water Guidelines was 99.94% and 100% respectively. Monitoring downstream of SCA storages is undertaken as part of the requirements of the Water Licences and Approvals package issued by the NSW Office of Water. The impact of pollutant sources downstream of SCA storages is evidenced by the deterioration of water quality downstream of SCA release points, particularly in the Hawkesbury – Nepean system. While nitrogen and chlorophyll-a regularly exceeded ANZECC benchmarks, potentially toxic algae remained below levels that pose any risk to recreational users. Guided by the Science Strategic Plan, the SCA has continued to initiate a number of scientific research projects through internal and external collaborative arrangements. Notable research projects with a direct influence on water quality management included: effect of chlorination on Giardia in the Upper Canal sources of taste and odour producing compounds in Prospect Reservoir risk assessment of pesticides and synthetic organic compounds characterising catchment risk of pathogens sources and causes of colour in raw water The SCA successfully managed two water quality incidents in accordance with the Raw Water Quality Incident Response Plan in the reporting period: elevated algae areal standard units in Kangaroo Valley raw water elevated algae areal standard units in Prospect raw water In March, 2014, heavy storms over the bushfire impacted Upper Nepean Catchments led to variable water quality in the Broughtons Pass Weir pool. As a result, supplies to the Macarthur Water Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 10 Filtration Plant and the Upper Canal were affected. Macarthur WFP was temporarily shut down while Upper Canal water was diverted to Prospect Reservoir. Sydney Water and NSW Health were satisfied with the SCA’s response to the incident. During 2013-2014 the SCA revised the WMP to incorporate changes in the Australian Drinking Water Guidelines. The program was endorsed by NSW Health and will be implemented from 1 July 2014. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 11 1 Introduction Section 14(1) of the Sydney Water Catchment Management Act 1998 (the Act) states that a principal objective of the SCA is ‘to ensure that water supplied by it complies with appropriate standards of water quality’. The SCA undertakes extensive monitoring within its catchments, storages and raw water supply system and in rivers downstream of storages to meet this objective. The SCA’s Water Monitoring Program 2010–2015 sets out the location, frequency and analytes monitored. Specific and health-related characteristics are determined in consultation with our major customers and the program is endorsed by NSW Health. Monitoring for operations and planning helps the SCA understand the threats to water quality throughout the supply system, including rivers, reservoirs and the delivery system. This information aids the selection of the best source water for our customers and the environment. The SCA’s Water Monitoring Program is informed by pollution source assessment for the four priority pollutants of pathogens, nutrients (phosphorus and nitrogen) and suspended solids. Catchment-totap water quality risk assessments are also undertaken for each supply system in conjunction with NSW Health and customers, and inform the Program to a large extent. The outcomes of risk assessments assist in prioritising monitoring as well as actions to rectify existing threats to water quality within drinking water catchments. Data collected through the Water Monitoring Program is used to: • provide early detection of possible contaminants in raw water to help protect the health of more than four million consumers • to assist in proactive operational decisions • ensure that the raw water delivered to SCA’s wholesale customers meets agreed standards and can be treated to meet the Australian Drinking Water Guidelines • identify and target possible contamination sources in the catchments and storages • identify emerging water quality issues and address them in forward planning The SCA’s compliance monitoring activities are governed by four key drivers: operating licence granted by the Governor of NSW and administered by Independent Pricing and Regulatory Tribunal (IPART) Water Licences and Approvals package granted by the Water Administration Ministerial Corporation and administered by the NSW Office of Water (NOW) raw water supply agreements between the SCA and its wholesale customers Australian Drinking Water Guidelines Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 12 1.1 This report This report describes the results of water quality monitoring undertaken by the SCA during 2013-14 under the Water Monitoring Program 2010-2015 and is a requirement of Sections 2.2.2 and 2.2.3 of the Reporting Manual for Sydney Catchment Authority (IPART, 2013). The report also discusses monitoring of flows and temperatures as required under the Water Licences and Approvals package. As well as meeting the SCA’s statutory obligations, the report aims to provide the community with information on water quality. More specifically, this report includes: a summary of the Water Monitoring Program, including objectives relating to monitoring and guidelines for water quality a summary of the results of the routine, event and investigative monitoring water quality data analysis of system performance relative to the criteria (benchmarks) where relevant water quality criteria are available analysis of catchment water quality against catchment health indicators details of research activities measures planned or taken to manage water quality incidents information on the integrity of the data reported. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 13 2 Overview of the water supply network The SCA collects water from river catchments to the south and west of Sydney and stores it in lakes and reservoirs to supply more than four million people in the Greater Sydney region. It is transported via a network of rivers, pipes and canals to water filtration plants, where it is treated for consumers in Sydney, Illawarra, the Shoalhaven, Goulburn, Blue Mountains and the Southern Highlands. Water is also released from storages as environmental flows to maintain the health of the downstream river systems. The catchments cover an area of approximately 16,000 square kilometres (sq km) — extending from the headwaters of the Coxs River north of Lithgow, south to the source of the Shoalhaven River near Cooma, and from Woronora in the east to the source of the Wollondilly River near Crookwell in the west (Figure 0.1). Raw water is collected from the river systems of five major catchments: Warragamba Upper Nepean Woronora Shoalhaven Blue Mountains. The characteristics of each system are summarised in Table 2.1, including the supply zone and storage capacities. The transfer routes for water around the system and approximate number of people supplied by that part of the system are shown in the schematic water supply system (Figure 2.1). Water is also sourced from the Fish River to supplement Blue Mountains supply. The Australian Drinking Water Guidelines framework for management of water supplies covers the whole supply chain from source to the consumer to ensure safe drinking water. The SCA is responsible for managing part of this supply chain (catchment, storages and raw water supply system) but recognises the importance of this approach and works closely with upstream stakeholders and downstream customers to ensure raw water supplied for treatment is of appropriate quality. Raw water is treated by the customers who report on drinking water quality. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 14 Figure 2.1: Schematic of the water supply system Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 15 Table 2.1: Characteristics of the SCA’s major delivery systems Delivery System Warragamba Upper Nepean Woronora Shoalhaven Blue Mountains * Major Storages Burragorang Prospect Cataract Cordeaux Upper Cordeaux 1 Upper Cordeaux 2 Avon Nepean Woronora Yarrunga Bendeela Fitzroy Falls Wingecarribee Lower Cascade Middle Cascade Upper Cascade Medlow Greaves Total Capacity (ML) 2,031,000 48,200 97,370 93,640 775 1,180 214,360 68,100 71,790 85,500 1,200 22,920 25,880 305 167 1,791 326 301 Operating Capacity* (ML) 2,027,000 33,330 97,190 93,640 Nil Nil 146,700 67,730 71,790 7500 900 9,950 24130 305 167 1,791 326 301 2 Catchment Area (km ) 9,051 10 130 91 Included in Cordeaux Included in Cordeaux 142 320 75 5,750 Included in Shoalhaven 31 40 3 2 2 5 7 The total capacity of a reservoir is the amount of water it can hold when full. Operational restrictions may reduce the amount of useable water (Operating Capacity) that the SCA can supply to its customers. 2.1 Warragamba system The Warragamba delivery system consists of two large diameter pipes which transport water by gravity from Lake Burragorang to water filtration plants (WFP) at Warragamba, Orchard Hills and Prospect. Prospect Reservoir can supply directly to Prospect WFP. Water from the Upper Nepean system is also supplied to Prospect via the Upper Canal. Lake Burragorang, which sits behind Warragamba Dam, is the SCA’s largest reservoir with the capacity to supply up to 80% of Sydney’s water. One quarter of the catchment is a declared Special Area, where public access is restricted to protect water quality, the land here is mostly natural bushland. The rest of the catchment has eight local council areas with several different types of land use. 2.2 Upper Nepean system The Upper Nepean system is fed by four dams - Nepean, Avon, Cordeaux and Cataract. These dams collect water from rivers on the Illawarra Plateau to supply water to Sydney through Broughtons Pass Weir and the Upper Canal. The Macarthur WFP supplies drinking water sourced from the head of the Upper Canal delivery system at Broughtons Pass Weir to the Camden, Campbelltown and Wollondilly local government areas. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 16 The Nepean catchment is mostly natural bushland with some grazing and cropping in the upper Nepean River catchment. Forestry, intensive agriculture and mining also occur within this catchment. The Nepean WFP supplies drinking water to the surrounding rural area and the local townships of Bargo, Thirlmere, Picton and The Oaks. Lake Avon supplies the Illawarra region and comprises mostly highly protected bushland. Water is transported from the upper reaches of Lake Avon by gravity or by pumping to the Illawarra WFP for supply to the Illawarra region. Water from Lake Nepean can also be transferred via a tunnel to Avon Dam to supplement supply to the Illawarra region. Cordeaux and Cataract catchments are mostly Special Areas, containing largely unspoilt bushland. 2.3 Woronora system The Woronora system delivers water via a pipe system from Lake Woronora to Woronora WFP, which supplies approximately 100,000 residents of Helensburgh, Engadine and parts of Sutherland Shire. Lake Woronora is located on the southern outskirts of Sydney on the western side of Heathcote National Park. 2.4 Blue Mountains system The Blue Mountains delivery system is a complex system that can deliver water from both within and outside the Blue Mountains bushland catchments. The system provides water to residents of the middle and upper Blue Mountains from Lake Greaves, Lake Medlow and the three Cascade lakes at Katoomba (five of the smallest reservoirs managed by the SCA). All five lakes contribute to the supply of water to the Cascade WFP, which can also be supplemented with water transferred from Lake Oberon on the Fish River or from the Duckmaloi River at Duckmaloi Weir (both west of the Great Dividing Range). Water from Warragamba Dam (treated at the Orchard Hills WFP) is pumped up the mountains to supplement the system, supplying water to residents of the lower to middle Blue Mountains. 2.5 Shoalhaven system The Shoalhaven system is a network of dams, pumps, canals and pipelines that transfers water from the catchments of the Shoalhaven River via Wingecarribee Reservoir to either the Warragamba or the Upper Nepean systems to supply Sydney and the Illawarra region during times of drought. Wingecarribee Reservoir supplies water to Wingecarribee WFP, operated by Wingecarribee Shire Council to supply drinking water for consumers in the Southern Highlands. Wingecarribee Reservoir can also transfer raw water to Goulburn Mulwaree Council to supplement storage levels in Goulburn Mulwaree’s water supply dams if required. The system is also used by Origin Energy to generate electricity. Power generation involves the regular exchange of stored waters between Lake Yarrunga, Bendeela Pondage and Fitzroy Falls Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 17 Reservoir. Bendeela Pondage is a very small impoundment in the delivery system between Lake Yarrunga and Fitzroy Falls Reservoir. Raw water from Bendeela Pondage is treated at the Kangaroo Valley WFP operated by Shoalhaven City Council to supply drinking water for the residents of Kangaroo Valley. The SCA releases water from Lake Yarrunga downstream into the Shoalhaven River for the Shoalhaven City Council to supply its customers. The major storage is Lake Yarrunga, at the junction of the Kangaroo and Shoalhaven Rivers. The catchment has a variety of land uses, including bushland, dairy farming, beef and sheep production, and rural residential. 2.6 Hawkesbury-Nepean River The Hawkesbury–Nepean River sits below the major storage reservoirs in the Warragamba and Nepean catchments. It is sustained by: flows from local catchments spills from the SCA storages environmental flow and other releases from the SCA storages which help maintain and improve the ecological health of the river flows of treated effluent from Sydney Water’s waste water and recycled water treatment plants. The NSW Office of Water licenses various water extractors along the length of the Hawkesbury– Nepean River for agricultural and some industrial use. Sydney Water also draws and treats water from the river at North Richmond to supply consumers in that area. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 18 3 SCA’s water monitoring program The SCA’s Water Monitoring Program 2010-2015 (WMP) covers routine, targeted, investigative and event-based monitoring over its area of operations. The WMP covers catchments, storages, inlets to water filtration plants, picnic taps, transfer canals and pipelines, as well as rivers downstream of water supply dams and weirs. Monitoring includes physical, chemical, biological, radiological, hydrological and meteorological parameters through online instruments, field sampling and laboratory analysis. A key feature of the WMP is an agreed list of water quality characteristics. The list contains: those characteristics that cannot be modified or removed by conventional treatment and for which Australian Drinking Water Guidelines (ADWG) must be met those characteristics for which ADWG exist but are not applicable to raw water, where the SCA must endeavour to supply raw water so that it can be treated to meet the ADWG. The SCA is subject to a range of statutory requirements and standards set by regulatory agencies. The SCA is also benchmarked against other raw water suppliers to maintain best practice service standards. The principal documents that outline requirements on the SCA with respect to water monitoring are: SCA Operating Licence, Sydney Water Catchment Management Act 1998 (Part 4) SCA’s Water Licences and Approvals Package under Water Management Act 2000 (Chapter 3) - referred to as Water Licences in the rest of this document Memorandum of Understanding (MoU) between NSW Health and the SCA (Parts 5-7) Sydney Water Catchment Management Act 1998 (Part 4) Raw Water Supply Arrangements, Sydney Water Catchment Management Act 1998 (Part 3) Water Act 2007 (C’th). 3.1 Quality assurance and quality control The SCA’s Water Monitoring Program 2010–2015 specifies the requirements for water sample collection and analysis. It describes sampling locations and frequencies, and the parameters to be analysed. Additional samples are collected and analysed for quality assurance and quality control (QA/QC) purposes. The QA/QC program provides confidence in the routine sampling data collected. Water quality data integrity is assured through the design of the routine and QA/QC sampling regimes and the analysis tools used to review data once it is delivered to SCA. The primary goal of field collected QA/QC samples is to identify, quantify and document bias and variability in data that result from the collection, processing and handling of samples. This process also assists in identifying opportunities to improve sampling methodologies. This is particularly important when sampling for parameters that are likely to be present at very low concentrations (due to measurement uncertainty). Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 19 Field collected QA/QC samples include field duplicates and field blanks. Trip blanks are also prepared and taken on designated sampling trips. The SCA’s analytical service providers have management systems that require them to maintain their own internal QA/QC program. These systems are accredited with the National Association of Testing Authorities (NATA) and ISO 17025. The analytical service providers conduct internal quality control analysis per each batch of samples including matrix spikes, duplicates, blanks, replicate analysis and inter laboratory proficiency trials. The service providers’ QA/QC specialists analyse conformance with specified standards of accuracy and precision to identify any contamination, outliers or errors. The collection and analysis of routine and QA/QC water samples is performed by SCA service providers. Service providers are contracted to include requirements for quality assurance practices in the monitoring, sampling, testing and reporting processes. A chain of custody system allows individual samples to be tracked from field collection, through laboratory analysis, to the transfer of results to the SCA’s database. Further details of the QA/QC monitoring for 2013-14 are included in Section 5.1. 3.2 Operating Licence The Operating Licence requires the SCA to: Maintain a water quality management system consistent with the framework for managing water quality as outlined in the ADWG. Maintain a water quality monitoring program (comprising routine monitoring of raw water) to the satisfaction of NSW Health. Conduct a targeted, investigative and event based monitoring program to monitor the occurrence of particular characteristics and contaminants in water. Submit a report to IPART and NSW Health each financial year summarising the monitoring program and performance against applicable guidelines. The ADWG framework recommends monitoring for verification of water quality with short term evaluation of results to enable incident response and corrective action. The ADWG framework also recommends investigative and research monitoring and long term evaluation of results for continual improvement. Routine water monitoring provides information for compliance and operational decision-making. Monitoring in catchments and storages is used to provide early warning of any risks, while monitoring at the inlet of treatment plants is used to verify the effectiveness of controls. Routine monitoring is supplemented by event and investigative monitoring targeting specific issues or knowledge gaps or to assess the effectiveness of management strategies, investigations into incidents or events or research to build knowledge of the water supply system. The outcomes of specific non-routine monitoring projects are also used to inform the review of routine monitoring. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 20 3.2.1 Raw water supplied for treatment Raw water is monitored in the delivery system and at inlets to WFPs prior to the water treatment process. This helps verify that water quality meets the agreed criteria and ADWG for health related characteristics. 3.2.2 Storages The SCA’s storages are monitored at various sites and depths to provide detailed information on lake conditions and processes. Monitoring is supported by modelling that assists in assessing current conditions and predicting possible changes. Profiling of storages (i.e. measuring parameters at discrete depths) is undertaken routinely to assist in selecting optimal supply depth to prevent hazards entering the water supply. 3.2.3 Catchments Routine sampling of catchment streams enables the quality of catchment waters to be assessed and any contamination identified. This allows water quality hazards to be managed within an adaptive management framework. Routine hydrometric monitoring measures rainfall and inflows to storages to help predict major inflow events, flooding and any associated water quality risks. 3.2.4 Picnic area monitoring The SCA supplies chlorinated water to picnic areas at Fitzroy Falls Reservoir (including the National Parks and Wildlife Service’s visitor centre), Cataract, Cordeaux and Avon dams. In 2014, the SCA developed and implemented a Drinking Water Quality Management Plan for Picnic Areas in line with NSW guidelines that include the required monitoring for individual supply areas. 3.2.5 Algal monitoring The SCA routinely monitors algae in major storages to provide early warning of possible bloom conditions. This ensures that raw water supplied to customers can be treated to meet drinking water guidelines. It also helps avoid the contamination of downstream waterways through environmental releases or transfers. A seasonal sampling program (usually conducted between October and May) applies in storages with a history of algal activity. Monitoring frequency is increased in response to triggers specified in the SCA’s Cyanobacteria Response Plan. 3.2.6 Cryptosporidium and Giardia monitoring A consolidated monitoring program for Cryptosporidium and Giardia was implemented in April 2001, following an agreement between the Ministers of NSW Health, Sydney Water and the SCA. This program remained in place for 2013–14. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 21 3.2.7 Wet weather monitoring Wet weather samples provide information on pollutants associated with rain events or large inflows. The collection and analysis of wet weather water samples across the SCA’s catchments is essential in identifying potential pollution sources. The SCA has installed autosamplers at strategic locations in the catchment, which are triggered by changes in river levels. 3.2.8 Dam seepage The SCA is required to monitor the structural integrity of prescribed dams, including seepage in, around and through its structures. Dam seepage monitoring is undertaken to comply with Dam Safety Act 1978. 3.2.9 Downstream of storages A number of sites downstream of SCA storages are routinely monitored in accordance with Water Licence requirements. Sites are maintained as per an agreement with NSW Office of Environment and Heritage and included in the triennial audits of the Sydney’s drinking water catchments. 3.3 Water Licences In May 2012, the NSW Office of Water issued the SCA a new Water Licences and Approvals Package under the Water Management Act 2000, which is a combination of ‘Water Access Licences’ and ‘Water Supply Work and Water Use Approvals’. The Water Licences require environmental flows to be released from reservoirs to help maintain the ecological health of downstream rivers. Water released from reservoirs into rivers can be colder or warmer than the receiving water depending on the level of the water offtake in the reservoir (deeper water is usually colder than surface water) and the time of the year. The SCA undertakes temperature and routine water quality monitoring at a number of downstream sites to assess impacts of SCA operations on downstream river systems. 3.4 Future directions In 2013-14, a full review of the Water Monitoring Program was undertaken to determine the water monitoring requirement for 2015-20. This review was to incorporate changes to the ADWG and the Public Health Act 2010. Both the routine program and the investigative component of the water monitoring program were revised. The revised program was endorsed by NSW Health and captured a number of key changes and future directions including: Updated monitoring program for SCA managed picnic areas Incorporation of static vertical profilers at three new sites in Lake Burragorang and one site in Lake Nepean Continued roll out of the wet weather autosampler program Addition of a targeted campaign monitoring program for Cryptosporidium during wet weather events Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 22 3.4.1 Inclusion of targeted monitoring around Healthy Catchment Strategy Priority Pollutants Programs infrastructure grant projects Updating of pesticides and synthetic organic contaminants (SOCs) monitored at inlet to water filtration plants Picnic taps Amendments to the NSW Public Health Act (2010) and Public Health Regulation (2012) required suppliers of drinking water to have a Quality Assurance Program approved by NSW Health in place by 1 September 2014. While most of the water supplied by SCA is raw water that is treated by our customers, water supplied by SCA at picnic areas is for public consumption. As part of the Drinking Water Management Plan and associated Quality Assurance Plans put in place for drinking water supplied at Avon, Cataract, Cordeaux and Fitzroy Falls picnic areas, changes were made to how we monitor water quality at picnic taps. These changes were guided by NSW Health and the NSW Private Water Supply Guidelines which came into effect in March 2014. These changes were implemented in July 2014 with the commencement of the revised Water Monitoring Program. As such, data presented in this report conforms to the 2010-2015 Water Monitoring Program. 3.4.2 Vertical profilers A vertical water quality profiler installed 500 metres upstream of the dam wall in Lake Burragorang in 2012 has provided highly resolved temporal (every 3 hours) data on temperature, pH, conductivity, turbidity and dissolved oxygen. The data has been very useful in improving our understanding of water quality processes such as stratification/de-stratification and wet weather intrusion events. The data was used to make proactive operational changes and avoid pollutants entering raw water supply. Following the success of this instrument, four new profilers were commissioned in 2014 – an additional three in Lake Burragorang and the fourth in Lake Nepean. The newly installed profilers in Lake Burragorang are located further upstream near the junction of the Wollondilly and Coxs arms and in each arm of the lake. The positions of the new profilers were selected to improve our early warning systems for water quality impacts from inflows and intrusions. A fifth profiler is planned to be installed in Lake Woronora. 3.4.3 Autosamplers In 2013-14 a number of new monitoring sites were installed in the catchment as part of an effort to increase risk-based monitoring in those areas. These sites were selected based on the risk profiles of individual drainage units in the catchment for elevated phosphorus, nitrogen, suspended solids and/or pathogens. This assessment was undertaken using SCA’s GIS-based Pollution Source Assessment Tool. The sites are equipped with telemetered level gauges which trigger autosamplers to capture high flow samples during wet weather events. This program will continue to be rolled out in 2014-15 with the aim to better understand water quality in vulnerable catchment areas and inform catchment actions. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 23 3.4.4 Campaign monitoring A plan has been drafted by the SCA’s Science team for a targeted monitoring program to assess the real risk of Cryptosporidium and Giardia during wet weather events affecting Lake Burragorang and Lake Nepean. This program has been flagged in the Water Monitoring Program2015-2020. The aim of the campaign monitoring is to ensure targeted collection of samples during wet weather events to quantify Cryptosporidium and Giardia risk into and through our lakes during large inflows. Any Cryptosporidium detected will also be assessed for infectivity status and speciated to understand zoonotic potential, i.e. ability to infect humans. The data from this monitoring will inform SCA’s Quantitative Microbial Risk Assessment. 3.4.5 Healthy Catchments Strategy projects As part of the Healthy Catchment Strategy, SCA endeavours to reduce the risk of potentially high risk pollution sources such as sewage treatment plants, householder managed onsite sewage systems, stormwater runoff and intensive livestock management. As part of this process, investigative monitoring programs have been established to monitor how effective our interventions are at reducing nutrients and/or pathogens entering local waterways. Through the Priority Pollution Program component of the Healthy Catchment Strategy, SCA has given out infrastructure grants to a number of councils in the local catchment to undertake improvement projects. Three of these projects have collaborative investigative monitoring projects to provide SCA with the real water quality benefits of different intervention strategies being undertaken in regard to: Sewer line extension for the decommissioning of individual onsite sewage systems, Installation of water sensitive urban design stormwater infrastructure, Sewage treatment plant upgrade to sufficiently mitigate the transfer from land-based effluent disposal to stream based disposal. 3.4.6 Pesticides and SOCs In 2012-13, a collaborative (NSW DPI, SWC, Hunter Water) risk assessment was conducted for pesticides and SOCs across the catchment. From the risk assessment, changes were proposed to the list of pesticides and SOCs routinely monitored by SCA in our water supplied to customers. The recommendations were based on both the likelihood of use in the catchment and the toxicity of chemicals. Pesticide and SOC monitoring in the Water Monitoring Program 2015-2020 have been updated to reflect the recommendations from the 2012-13 review. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 24 4 Applicable guidelines / benchmarks The SCA has adopted nationally recognised standards and guidelines for a range of water quality characteristics in each part of the water supply network. Different guidelines and standards apply to each part of the supply cycle as water passes from catchment waterways into storages, and then into the delivery network or downstream rivers. 4.1 Australian Drinking Water Guidelines (ADWG) 2011 The Australian Drinking Water Guidelines (NHMRC, 2011) apply to any water intended for drinking, irrespective of the source or where it is consumed. The ADWG framework for managing drinking water quality advocates risk management and preventive measures at all barriers from catchment to consumer. For water quality characteristics that have been specified as ‘health related’, including metals, pesticides and synthetic organic compounds (Table 4.1), raw water must conform to the ADWG. As conventional water treatment methods are not designed to remove these compounds from raw water, it is preferable to avoid them in the raw water supply through catchment and storage management practices. Routine monitoring of radionuclides is also performed at water filtration plants. Radionuclides are not presented in the results section of this report, but are included in Appendix Tables A20, A39, A60, A73 and A92. Testing for individual radionuclides is performed in the case of a positive gross alpha or gross beta result. 4.2 Raw water supply agreements The SCA has established terms and conditions of supply with wholesale customers to ensure treated water is not harmful to consumers’ health. Raw water supplied for treatment is required to conform to site-specific standards specified in raw water supply agreements (Table 4.2). These standards are based on the treatment capabilities of the plants and the natural characteristics of the catchment. This ensures that raw water can be treated to meet ADWG requirements. In 2013 the raw water supply agreement with Sydney Water was renegotiated. Key changes relating to water quality were the removal of specifications for temperature and pH of raw water supplied by the SCA. These changes came into effect in October 2013. Compliance for 2013-14 is benchmarked against the updated specifications. ADWG and site specific standards are applied to samples collected in the delivery system. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 25 CHEMICAL/BIOLOGICAL/ORGANIC SYNTHETIC ORGANICS – RADIOLOGICAL - PESTICIDES Table 4.1 Health-related water quality characteristics Specific Water Characteristic Amitrole ADWG (2011) Health Guideline 0.009 mg/L Atrazine 0.02 mg/L Chlorpyrifos 0.01 mg/L 2,4-D 0.03 mg/L 2,4,5-T 0.1 mg/L Diazinon 0.004 mg/L Diquat 0.007 mg/L Diuron 0.02 mg/L Glyphosate 1.0 mg/L Heptachlor 0.0003 mg/L Hexazinone 0.4 mg/L Triclopyr 0.02 mg/L Gross alpha 0.5 Bq/L Gross beta 0.5 Bq/L Benzene 0.001 mg/L 1,2-Dichloroethane 0.003 mg/L 1,2-Dichloroethene 0.06 mg/L Hexachlorobutadiene 0.0007 mg/L Vinyl chloride 0.0003 mg/L Arsenic 0.01mg/L Barium 2 mg/L Boron 4 mg/L Iodide 0.5 mg/L Mercury 0.001 mg/L Molybdenum 0.05 mg/L Selenium 0.01 mg/L Silver 0.1 mg/L Tin N/A Beryllium 0.06 mg/L Escherichia coli Seek advice from NSW Health and liaise with customers if the thresholds for these analytes in Raw Water Quality Incident Response Plan are exceeded Enterococci Clostridium perfringens Cryptosporidium Giardia Toxin producing cyanobacteria Toxicity Cyanobacteria biovolume Notes: 1 Section shaded yellow contains health related water quality characteristics – these characteristics must not exceed Australian Drinking Water Guidelines (NHMRC, 2011) in raw water supplied for treatment. 2 Section shaded blue contains characteristics for which drinking water guidelines exist although these are not applicable for raw water. However, SCA must endeavour to supply the best quality raw water available so that it can be treated to meet Australian Drinking Water Guidelines. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 26 True Colour @400 nm Iron Manganese Aluminium Hardness Alkalinity pH Odour Algae (iv) Turbidity Table 4.2: Raw water supply agreements – Site specific standards NTU CU mg/L mg/L mg/L mg/L as CaCO3 mg/L as CaCO3 pH units Rating ASU 1000(i) Prospect WFP Warragamba WFP 40 60 3.50 1.40 2.60 25.0 – 70.0 15.0 - 60 10 0.60 0.20 0.40 6 – 30 25 0.80 0.25 0.50 1.10 0.30 0.75 1.30 0.35 0.95 50 1.1 0.4 1.4 30 10 70 1 0.1 0.4 2 – 30 15 5.0 1.5 1.0 2 – 35 0.5 – 25 3.0 0.3 0.2 40 30 2000 Orchard Hills WFP 185 - <265 Macarthur WFP 125 - <185 Based on Demand 80 - <125 (ML/day) <80 Illawarra WFP Woronora WFP 50 60 10 Nepean WFP 150 Cascade WFP 15 Kangaroo Valley WFP 20 Wingecarribee WFP Goulburn Mulwaree 40 40 60 6 – 32.20 NA 15 NA 1.1 NA NA 36.5 35 500(iii) Not objectionable 5000 2000 29 70 100(ii) NA 6.5 – 8.5 5000 (i) Maximum for Prospect WFP is 1000 ASU, except if turbidity is greater than 10 NTU or true colour is greater than 30 CU, then the algae maximum will be 500 ASU. (ii) Algal limits for Macarthur WFP (average of 3 samples): 500 ASU small individual cells (<10μm) of filamentous or colonial species or 100 ASU large (>10μm) cells, branching species, and/or gelatinous species (averaged across three samples). Typically Asterionella, Taballaria, Fragillaria, Synedra, Cyclotella, Dinobryan, Elakatothrix, and Volvox. (iii) 500 ASU of small (<10μm) cells, filamentous cells, and/or colonial species (averaged across three samples). Typically Chlorella, Anabaena, Monodus and Melosira. (iv) Upper limits are shown for analytes where ranges are not provided. 4.3 ANZECC 2000 The Australian and New Zealand Guidelines for Fresh and Marine Water Quality (2000) (referred to as ANZECC, 2000) provide a guide for setting water quality objectives required to sustain current or likely future environmental values for natural and semi-natural water resources in Australia and New Zealand. Water quality in the SCA’s storages and catchment waterways are compared against relevant sections of the ANZECC Guidelines. 4.4 Benchmarks for storages Benchmarks for storages are derived from the guidelines for freshwater lakes and reservoirs (ANZECC, 2000) for the 95-99 percent level of species protection (Table 4.3). Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 27 Table 4.3: Water quality benchmarks for storages Analyte pH Chlorophyll-a Dissolved oxygen Total nitrogen Total phosphorus Turbidity Total manganese Total aluminium Units pH units μg/L %sat mg/L mg/L NTU mg/L mg/L Benchmark range 6.5-8.0 <5 90-110 <0.35 <0.01 <20.0 <1.9 <0.055 4.5 Benchmarks for catchments The SCA benchmarks water quality in catchment streams against the ANZECC (2000) guideline ranges for upland rivers (Table 4.4). Table 4.4: Water quality benchmarks for catchment streams Analyte pH Chlorophyll-a Dissolved oxygen Total nitrogen Total phosphorus Turbidity Units pH units μg/L % sat mg/L mg/L NTU Benchmark range 6.5 – 8.0 <5 90 - 110 < 0.25 < 0.02 0 – 25 4.6 Benchmarks for downstream rivers Benchmarks for water quality downstream of SCA’s dams and weirs are derived from lowland rivers ecosystem types (ANZECC, 2000) (Table 4.5). Table 4.5: Water quality benchmarks downstream of storages Analyte pH Chlorophyll-a Dissolved oxygen Total nitrogen Total phosphorus Turbidity Units pH units μg/L %sat mg/L mg/L NTU Benchmark range 6.5 - 8.5 <5 85 - 110 < 0.5 < 0.05 < 50 4.7 Benchmarks for picnic area supplies Benchmarks for the picnic area supplies are based on ADWG (2011) threshold ranges, where relevant (Table 4.6). Some benchmarks are prompts for action, such as chlorophyll-a, which triggers algal monitoring in the picnic area supply. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 28 Table 4.6: Water quality guidelines for specific parameters at picnic areas Analyte Total chlorine residual pH Turbidity Total Iron Total Aluminium Total Manganese E. coli Algal toxins (Microcystin-LR equivalents) Chlorophyll-a Potentially toxin producing algal cells (i) Units mg/L pH units NTU mg/L mg/L mg/L orgs/100mL μg/L μg/L cells/mL Threshold 0.2 - 0.5 6.5 - 8.5 <5 < 0.3 < 0.2 < 0.1 Should not be detected <1.3 <5 (i) <6,500 See cyanobacteria benchmarks in Table 4.7. 4.8 Benchmarks for cyanobacteria The SCA routinely monitors levels of algae in major storages to provide early warning of possible bloom conditions and to ensure that raw water supplied to customers can be treated to meet drinking water guidelines. Algal monitoring is also conducted to avoid contaminating downstream waterways through environmental releases or transfers. Despite Lake Yarrunga and Fitzroy Falls Reservoir being the only SCA storages with recreational access, the SCA applies the National Health and Medical Research Council Recreational Waters Guidelines (NHMRC, 2008) for catchments and lakes (Table 4.7). The raw water and picnic areas benchmarks are from the ADWG. Table 4.7: Cyanobacteria benchmarks throughout the SCA’s area of operations Analyte Catchment and lake sites(i) Microcystis aeruginosa Total cyanobacteria biovolume Toxicity (Microcystin LR toxicity equivalents) Raw water and picnic area water supplies(ii) Microcystis aeruginosa Cylindrospermopsis raciborskii Anabaena circinalis Toxicity (Microcystin LR toxicity equivalents) Toxicity (Cylindrospermopsin) Toxicity (Saxitoxin, anatoxins) Units Threshold cells/mL 3 mm /L μg/L 50,000 4 10 cells/mL cells/mL cells/mL μg/L μg/L μg/L 6,500 15,000 20,000 1.3 1.0 3.0 (i) National Health and Medical Research Council Guidelines for Managing Risks in Recreational Water 2008. (ii) ADWG 2011 specify actions in response to various alert level ranges for Microcystis aeruginosa, Anabaena circinalis and Cylindrospermopsis raciborskii (i.e. >2,000 cells/mL = consider toxicity testing). These triggers are based on cell counts and biovolume. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 29 4.9 Benchmarks for Cryptosporidium and Giardia The ADWG do not contain guideline values for Cryptosporidium and Giardia in raw or treated drinking water. However, ADWG (2011) recommends a multi-barrier approach to minimise the risks of these pathogens. Investigative testing is encouraged in response to events (e.g. heavy rainfall) that could increase the risk of contamination. The SCA implements additional monitoring during high risk events. Cryptosporidium and Giardia monitoring in the catchments is undertaken to provide an early warning function to enable optimal configuration of the raw water supply system in the event of high levels of Cryptosporidium and/or Giardia detections within the storages. Catchment monitoring also contributes to the understanding of sources which can then improve the robustness of risk assessments and catchment actions. The SCA responds to detections of Cryptosporidium and Giardia in raw water supply in accordance with the Raw Water Quality Incident Response Plan (RWQIRP) developed in consultation with NSW Health and wholesale customers. The SCA’s RWQIRP identifies four event levels for raw water: Alert Level: 1 – 10 (oo)cysts (IFA /10 L adjusted for recovery) Minor Incident: 11 – 100 (oo)cysts (IFA /10 L adjusted for recovery) Major Incident: 101 – 1000 (oo)cysts (IFA /10 L adjusted for recovery) Emergency: >1000 (oo)cysts (IFA /10 L adjusted for recovery). Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 30 5 Routine monitoring 5.1 Quality Assurance/Quality Control During 2013-14, 5198 routine samples were collected for testing. There were 537 quality assurance and quality control (QA/QC) samples taken over this period which is equivalent to 10.3% of the routine samples collected. This included 272 duplicate samples (5.2%), 128 field blanks (2.5%) and 137 trip blanks (2.6%). See Glossary for descriptions of types of QA/QC samples. In 2013-14, there were 31 QA/QC samples that had anomalous results, indicating a possible process issue. These issues were logged and investigated by members of the SCA QA/QC working group. In all cases, raw data was checked and verified and the results confirmed with the laboratory before further investigation. Retesting was performed where possible to confirm the result. Of the 31 QA/QC anomalies, six were because of detections in trip blanks (4% of total trip blanks analysed), nine were because of detections in field blanks (7% of total field blanks) and 16 were because of unsatisfactory variation in duplicate sample analyses (6% of total duplicate analyses). The SCA tracks these types of anomalies to determine if any emerging trends warrant corrective action. There was no evidence of this in 2013-14. Trip blanks One trip blank had a detection of filtered aluminium, two trip blanks had detections of dissolved organic carbon, two trip blanks had detections of oxidised nitrogen and one trip blank had a detection of chlorophyll-a, lorenzen and phaeophytin. This anomaly prompted a process audit but no issues or recommendations were identified. In all but the chlorophyll-a anomaly, all detections were very low, just above the limit of reporting and would not significantly impact on the interpretation of sample results. Field blanks In the field blanks, total organic carbon, dissolved organic carbon, total nitrogen, Kjeldahl nitrogen, oxidised nitrogen, ammonia, aluminium, manganese, sodium, chloride and reactive phosphorus were detected on no more than three occasions. Most detections were very low, just above the limit of reporting and would not significantly impact on interpretation of sample results. Duplicates In the sixteen duplicate anomalies, duplicate sample had differences above the laboratory acceptance criteria for algae, chlorophyll-a and lorenzen, E. coli, faecal coliforms, true colour, aluminium, manganese and nitrogen. Duplicate sample variations were infrequent, variable and did not indicate any systematic issues with sampling and/or laboratory quality control and assurance processes. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 31 5.2 Warragamba system Sampling sites in the Warragamba system (including Prospect Reservoir) are shown Figure 5.1 in below. Figure 5.1: Sampling sites in the Warragamba system (including inset Prospect Reservoir) Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 32 Table 5.1: Warragamba system catchments - percentage of samples exceeding benchmarks. 17 20 8 Kowmung River E130 12 33 0 0 0 10 0 Kedumba River E157 12 25 0 0 58 0 0 Gibbergunyah River E203 12 25 0 8 100 91 58 Nattai River E206 12 17 17 8 100 36 8 Nattai River E210 12 42 0 0 55 0 50 Little River E243 12 25 8 0 0 0 8 Wingecarribee River E332 12 83 0 0 100 91 83 Wollondilly River E409 12 75 33 0 100 92 83 Wollondilly River E450 12 33 42 0 100 42 42 Mulwaree River E457 12 50 67 0 100 100 75 Wollondilly River 12 33 42 0 90 50 42 Werriberri Creek E488 E531 12 83 8 0 25 17 17 Tonalli River E551 11 73 18 0 11 56 9 Areal standard unit (algae) 100 20 Manganese total 100 0 Iron total 8 0 Aluminium total Phosphorus total 17 17 True colour at 400nm 25 12 Total hardness 12 E083 Alkalinity E046 Coxs River Number of samples Farmers Ck Site Nitrogen total Chlorophylla Cyanobacteria Turbidity Metals pH Nutrients Dissolved oxygen (% sat) Station code Physico-chemical Catchment (compliance with ANZECC guidelines – refer Table 4.4) Storages (compliance with ANZECC guidelines – refer Table 4.3) Lake Burragorang - Coxs River DWA12 25 46 17 0 80 40 28 0 8 Lake Burragorang - Coxs River DWA15 6 43 14 0 50 17 33 0 50 Lake Burragorang - Kedumba River DWA19 6 50 17 0 50 67 33 0 100 Lake Burragorang - Dam wall DWA2 25 53 5 0 92 32 32 0 16 Lake Burragorang - Coxs River DWA21 6 50 33 0 33 50 17 0 83 Lake Burragorang - Wollondilly River DWA27 25 54 21 0 80 32 36 0 12 Lake Burragorang - Wollondilly River DWA311 6 63 13 0 67 0 33 0 67 Lake Burragorang - Wollondilly River DWA39 6 50 17 0 83 50 33 0 100 Lake Burragorang - The Junction DWA9 25 48 3 0 84 32 32 0 12 Prospect Reservoir RPR1 12 0 8 0 0 25 42 0 18 0 0 0 83 0 39 Prospect Reservoir 6 0 0 RPR6 Water Filtration Plants (compliance with raw water supply agreement site specific standards - refer Table 4.2) Orchard Hills HBR1 13 0 0 0 0 0 0 0 0 Warragamba HWA2 13 0 0 0 0 0 0 0 0 PWFP10 13 0 0 0 0 0 0 0 0 Prospect Where there is no applicable benchmark cells are greyed out. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 33 5.2.1 Catchments As in previous years, nutrients (nitrogen and phosphorus) and chlorophyll-a regularly exceeded ANZECC benchmarks in 2013-2014. Protected natural catchments (Kowmung, Little and Tonalli Rivers) experience much lower concentrations than those catchments dominated by agricultural and urban land-uses (e.g. Wollondilly, Mulwarree and Wingecarribee Rivers). This is particularly evident at sites downstream of sewage treatment plants (Farmers and Gibbergunyah Creeks). Despite regularly exceeding ANZECC benchmarks for nutrients and chlorophyll-a, all sites remained well below algal guidelines (NHMRC, 2008). 5.2.2 Storages Nutrient concentrations in Lake Burragorang peaked in August 2013, following significant inflows in June-July 2013. Despite the relatively large concentrations, algal activity in spring 2013 was moderate with chlorophyll-a concentrations around the seasonal average. Toxins (Microcystin) remained below the limit of detection. Turbidity remained very low throughout the reporting period, despite a number of minor to moderate inflow events. True colour persisted above historical averages, yet below levels of 20122013. The SCA worked with SWC in selecting supply depth to ensure optimal water quality. 5.2.3 Water Filtration Plants For the 2013-2014 reporting period, there were no water sample results outside of the raw water supply agreement (RWSA) standards for raw water supplied to Warragamba, Orchard Hills and Prospect water filtration plants. All water samples were well below ADWG for health related characteristics. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 34 5.3 Upper Nepean system Sampling sites in the Upper Nepean system are shown in Figure 5.2 below. Figure 5.2: Sampling sites in the Upper Nepean system. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 35 Metals Cyanobacteria Areal standard unit (algae) Nutrients E602 12 0 50 0 0 0 0 Lake Avon - Flying Fox Creek E604 13 0 15 0 15 0 0 Lake Cordeaux - Goondarrin Creek E608 12 8 0 0 0 8 0 Lake Cataract - Cataract River E609 12 42 83 0 0 0 0 Lake Avon - Avon River E610 11 18 0 0 9 0 0 Lake Cordeaux - Cordeaux River E680 12 8 17 0 8 8 17 Lake Nepean - Nepean River E697 11 0 0 0 82 27 0 Chlorophyll-a 0 Lake Nepean - Burke River Manganese total 0 25 Iron total 8 58 Aluminium total 0 0 Phosphorus total 0 0 Nitrogen total 92 0 Turbidity 42 12 True colour at 400nm 12 E601 Alkalinity E6006 Lake Nepean - Nepean River Station code Lake Cordeaux - Sandy Creek Site pH Total hardness Physico-chemical Dissolved oxygen (% sat) Number of samples Table 5.2: Upper Nepean catchments - percentage of samples exceeding benchmarks Catchment (compliance with ANZECC guidelines – refer Table 4.4) Storages (compliance with ANZECC guidelines – refer Table 4.3) Lake Avon - Dam wall DAV1 12 33 8 0 0 0 17 0 0 Lake Avon - at offtake DAV7 12 17 8 0 0 17 8 0 8 Lake Cataract DCA1 12 17 42 0 0 8 75 0 0 Lake Cordeaux DCO1 12 25 0 0 0 17 33 0 8 0 64 91 100 0 9 Lake Nepean 11 50 25 DNE2 Water Filtration Plants (compliance with raw water supply agreement site specific standards - refer Table 4.2) Nepean HNED 12 0 0 0 0 0 0 0 0 Illawarra IWFP-R 12 0 0 0 0 0 0 0 0 Macarthur HMAC 12 0 17 0 0 0 0 0 0 Where there is no applicable benchmark cells are greyed out. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 36 5.3.1 Catchments Upper Nepean catchment sites continued to perform well against ANZECC benchmarks and demonstrate the benefit of Special Areas. pH was regularly outside the ANZECC benchmark range but is considered to be the natural condition and the result of local geology. 5.3.2 Storages Water quality in Upper Nepean storages continued high compliance against ANZECC benchmarks. Algal growth remained low despite high nutrient concentrations in some lakes (e.g. Lake Nepean). Much like the catchment sites, local geology results in pH levels outside of the ANZECC range. This is also thought to contribute to aluminium concentrations above ANZECC benchmarks. A bushfire in October 2013 burnt out approximately 14% of the Upper Nepean catchment area. Special monitoring of the most affected storage; Lake Nepean, did not identify any significant impacts to water quality. 5.3.3 Water Filtration Plants For the 2013-2014 reporting period, there were no water sample results outside of the raw water supply agreement standards for raw water supplied to Illawarra and Nepean water filtration plants. There were two instances where water hardness was below the site specific standard in the raw water supply agreement for water supplied to Macarthur water filtration plant. The Upper Nepean storages all have very soft water, particularly Lake Cataract and Lake Nepean and water hardness appears to have declined slightly this year compared to last year in the lakes, leading to the dips below the lower limit of the site specific standards for Macarthur water filtration plant. Low hardness may require minor configuration adjustment at the water filtration plant, but does not pose a health risk. At times, high true colour (primarily from Lake Nepean) and low turbidities resulted in treatment difficulties at Nepean and Macarthur water filtration plants. Both true colour and turbidity remained below RWSA standards. All samples were below ADWG for health related characteristics. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 37 5.4 Woronora system Sampling sites in the Woronora system are shown in Figure 5.3 below. Figure 5.3: Sampling sites in the Woronora system. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 38 Table 5.3: Woronora system catchments - percentage of samples exceeding benchmarks Cyanobacteria 0 8 8 Chlorophyll-a 42 Areal standard unit (algae) 25 Manganese total Lake Woronora Iron total 0 Aluminium total 0 0 True colour at 400nm 0 0 Total hardness 8 0 pH 0 92 Alkalinity 0 42 Station code 17 E677 12 Storages (compliance with ANZECC guidelines – refer Table 4.3) Site Phosphorus total Metals Nitrogen total Nutrients Turbidity Dissolved oxygen (% sat) Number of samples Physico-chemical Catchment (compliance with ANZECC guidelines – refer Table 4.4) Lake Woronora - Waratah Rivulet E6131 12 Lake Woronora - Woronora River DWO1 12 100 0 0 Water Filtration Plants (compliance with raw water supply agreement site specific standards - refer Table 4.2) Woronora HWO1-A 14 0 0 0 0 0 0 0 0 Where there is no applicable benchmark cells are greyed out. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 39 5.4.1 Catchments Water quality at Lake Woronora catchment sites was consistently good with only pH being below the ANZECC benchmark. Much like the catchment of the Upper Nepean system, low pH in the Woronora River catchment is common due to groundwater infiltration from surrounding Hawkesbury sandstone. 5.4.2 Storage Water quality in Lake Woronora remained good, with very high compliance against ANZECC benchmarks. Naturally low pH water from the Woronora River resulted in some samples falling below the ANZECC benchmark. 5.4.3 Water Filtration Plant Consistent with previous years, Woronora water filtration plant was compliant with RWSA standards and ADWG for all samples. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 40 5.5 Blue Mountains system Sampling sites in the Blue Mountains system are shown in Figure 5.4 below. Figure 5.4: Sampling sites in the Blue Mountains system. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 41 Table 5.4: Blue Mountains system storages - percentage of samples exceeding benchmarks 100 0 17 0 0 0 Top Cascade DTC1 13 78 0 0 15 23 8 0 46 Chlorophyll-a 50 0 Areal standard unit (algae) 0 0 Manganese total Aluminium total 0 0 Iron total Phosphorus total 88 67 True colour at 400nm 82 6 Total hardness 12 DLC1 Alkalinity DGC1 Lower Cascade Station code Lake Greaves Site Nitrogen total Cyanobacteria Turbidity Metals pH Nutrients Dissolved oxygen (% sat) Number of samples Physico-chemical Catchment (compliance with ANZECC guidelines – refer Table 4.4) Storages (compliance with ANZECC guidelines – refer Table 4.3) Water Filtration Plants (compliance with raw water supply agreement site specific standards - refer Table 4.2) Cascade HCSR 12 0 0 0 0 0 0 0 41 0 Where there is no applicable benchmark cells are greyed out. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 42 5.5.1 Catchments The Blue Mountains catchments are very small (less than 20 sq km in total) and inflow water quality is represented by water quality in the lakes. There are no routine monitoring sites in the Blue Mountains catchments. 5.5.2 Storages Typical of the Blue Mountains lakes, dissolved oxygen was regularly below the ANZECC benchmark of 90% saturation. In Upper and Lower Cascade dissolved oxygen remained above 70% saturation for most samples, whereas in Lake Greaves, times of low oxygen were experienced due to problems with the destratification unit used to keep this storage mixed and aerated. This is also why Lake Greaves had notable exceedences for aluminium and phosphorus (anoxic conditions promoting release from sediments). Despite low nutrient concentrations, chlorophyll-a concentrations were higher than previous years. Speciation indicated a non-toxic diatom Urosolenia as the dominant species in Top Cascade. 5.5.3 Water Filtration Plants All samples at Cascade water filtration plant were within the raw supply agreement standards. Algal ASU was not an issue despite the increase in algal activity. All samples were below ADWG for health related characteristics. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 43 5.6 Shoalhaven system Sampling sites in the Shoalhaven system are shown in Figure 5.5 below. Figure 5.5: Sampling sites in the Shoalhaven system Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 44 92 8 8 8 0 Lake Yarrunga - Shoalhaven River E847 12 17 8 0 33 25 0 Lake Yarrunga - Shoalhaven River E860 11 0 0 0 18 55 0 Lake Yarrunga - Shoalhaven River E861 10 0 0 0 30 20 20 Lake Yarrunga - Gillamatong Creek E891 10 70 0 10 100 100 80 Chlorophyll-a 50 0 Manganese total 0 17 Iron total 17 25 Aluminium total 25 12 True colour at 400nm 12 E822 Alkalinity E706 Lake Yarrunga - Mongarlowe River Station code Lake Yarrunga - Kangaroo River Site Phosphorus total Areal standard unit (algae) Cyanobacteria Nitrogen total Metals Turbidity Nutrients pH Total hardness Physico-chemical Dissolved oxygen (% sat) Number of samples Table 5.5: Shoalhaven system catchments - percentage of samples exceeding benchmarks Catchment (compliance with ANZECC guidelines – refer Table 4.4) Storages (compliance with ANZECC guidelines – refer Table 4.3) Bendeela Pondage DBP1 7 63 0 0 43 100 86 0 97 Fitzroy Falls Reservoir DFF6 12 0 8 0 25 83 92 0 100 Lake Yarrunga - dam wall DTA1 11 55 27 0 64 91 91 0 45 Lake Yarrunga - Shoalhaven River arm DTA5 11 64 0 0 45 100 91 0 45 Lake Yarrunga - Kangaroo River Arm DTA8 12 58 8 0 33 100 92 0 71 0 17 92 100 0 97 Wingecarribee Reservoir 12 13 7 DWI1 Water Filtration Plants (compliance with raw water supply agreement site specific standards - refer Table 4.2) Wingecarribee HWI1 13 0 0 0 0 0 0 Kangaroo Valley HKV1 13 0 0 0 0 0 17 Where there is no applicable benchmark cells are greyed out. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 45 5.6.1 Catchments As in previous reporting periods, nutrients were regularly above the ANZECC benchmark while chlorophyll-a rarely exceeded the 5 ug/L benchmark. Located directly downstream of the Braidwood township and sewage treatment plant, the Gillamatong Creek site recorded the highest nutrient and chlorophyll-a concentrations. Further downstream concentrations are significantly reduced by dilution and in-stream processes. 5.6.2 Storages All storages with the Shoalhaven system continued to record high non-compliance with nutrient and chlorophyll-a benchmarks, particularly the transfer storages Bendeela Pondage, Fitzroy Falls Reservoir and Wingecarribee Reservoir. Speciation identified mostly non-toxin producing species thus ADWG and NHMRC recreational guidelines were never exceeded. 5.6.3 Water Filtration Plants Two samples at Kangaroo Valley water filtration plant exceeded the RWSA standard for algal cross sectional area (ASU), leading to shortened filter run times in the plant. Management of this issue is described in section 8.2.1. No health related algal guidelines were exceeded. All other water quality parameters were maintained within the raw water supply agreement standards for Kangaroo Valley and Wingecarribee Shire Council water filtration plants. All samples were below ADWG for health related characteristics. 5.7 Algal monitoring The SCA samples for algae and cyanobacteria concurrently with routine catchment and storage monitoring (Section 3.2). At locations with a history of algal activity, seasonal monitoring is conducted more frequently in the warmer months between October and May to facilitate early detection of emerging algal events. Routine algal monitoring at WFPs is also undertaken. Reported results consider both routine and seasonal monitoring. Statistical summaries are provided in Appendix A. Refer to Section 4.8 for relevant benchmarks. 5.7.1 Warragamba system All Warragamba catchment sites complied with the recreational guidelines for potentially toxin producing cyanobacteria count, toxicity and cyanobacteria biovolume. Waterways in the Wollondilly River catchment frequently exceeded the chlorophyll-a criterion, particularly Wingecarribee River at Berrima Weir, which exceeded the threshold most of the year Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 46 (maximum of 43 µg/L). The highest chlorophyll-a concentration in the Wollondilly sub-catchment was 55 µg/L near Goulburn. Sites in the Coxs River subcatchment exceeded the chlorophyll-a threshold less often. One site in the Nattai River exceeded the chlorophyll-a thresholds for half of the year (maximum of 7.5 µg/L), while the other site only had a single exceedance. All Lake Burragorang sites complied with the NHMRC recreational benchmarks. Chlorophyll-a concentration exceeded 5 μg/L at all locations on occasion, with the highest result of 13.5 μg/L recorded in the upper reaches of the Coxs River arm. Populations of potential toxin producing algal species remained low, similar to concentrations observed in 2013-14 and where analysed, no algal toxins were detected. Chlorophyll-a concentrations in Prospect Reservoir exceeded 5 μg/L in less than 30% of the routine samples collected. Concentrations of potential toxin producing algal species remained below threshold levels of concern and no algal toxins were detected. Raw water supplied to Orchard Hills, Warragamba and Prospect WFPs continued to meet ADWG criteria with respect to algae, with no detections of potential toxin producing cyanobacteria such as Anabaena circinalis or Microcystis aeruginosa. 5.7.2 Upper Nepean system Catchment sites in the Upper Nepean system showed very little sign of algae in 2013-14, only exceeding the chlorophyll-a trigger (5 μg/L) for additional analysis in two samples from the Cordeaux catchment, with a maximum of 6.8 μg/L (compared to a maximum of 80.5 μg/L in Goondarin Creek in 2012-13). Potentially toxin-producing cyanobacteria was not reported at any of these sites. Similarly, storage sites in the Upper Nepean rarely exceeded the 5 μg/L Chlorophyll-a criterion for additional algal analysis. Potentially toxin producing species were rarely detected and toxin analysis was not required. Raw water supplied to Macarthur, Nepean and Illawarra WFPs complied with the cyanobacteria guidelines during 2013-14, with only very low levels of potential toxin producing species observed in Nepean and Macarthur raw water. 5.7.3 Woronora system As in previous years, chlorophyll-a remained below the threshold for additional analysis in catchment and lake sites and no potentially toxin producing species were detected in raw water supplied for treatment. 5.7.4 Blue Mountains system Chlorophyll-a concentrations exceeded 5 µg/L in over 40% of routine samples in Upper Cascades and Greaves Creek storages (maximum of 14.9 µg/L) but no potentially toxin producing species were detected. Elevated chlorophyll-a was associated with non-toxic diatoms which temporarily caused Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 47 elevated algal ASU (an indicator of filter clogging potential) in raw water supplied to Cascades WFP (refer to minor incident in Appendix B). The plant had no issues treating the raw water supplied. 5.7.5 Shoalhaven system Algal blooms are historically common in the Shoalhaven system and chlorophyll-a exceeded the 5 μg/L threshold in most catchment sites at least once during the year, with a maximum of 99 μg/L in Gillamatong Creek, near Braidwood. However, as in 2012-13, potential toxin producing species were not detected. Chlorophyll-a exceeded the 5 μg/L threshold in almost all lake samples from Bendeela Pondage and Fitzroy Falls Reservoir and almost half of the samples from Lake Yarrunga, including 70% of samples from the Kangaroo Valley arm. However, all lake sites complied with the guidelines for potentially toxin-producing cyanobacteria cell counts, toxicity and cyanobacteria biovolume. An unknown species of Microcystis was reported in ten out of 35 samples in the Kangaroo Valley site with a maximum of 6,150 cells/mL, but microcystin toxin was below detectable levels. Raw water supplied to Kangaroo Valley and Wingecarribee WFPs complied with ADWG cyanobacteria guidelines and did not require toxicity analysis due to very low algal cell counts. 5.8 Cryptosporidium and Giardia monitoring Routine monitoring is undertaken in catchments, storages and delivery networks at varying frequencies as agreed between the SCA, Sydney Water and NSW Health. Statistical summaries are provided in Appendix A. 5.8.1 Catchments Monitoring for Cryptosporidium and Giardia is undertaken at eight selected streams in the Warragamba catchment as part of an ongoing pathogens program. The sampling schedule is monthly, except for Werriberri Creek (E531) which is weekly. Cryptosporidium oocysts were detected at low concentrations (up to 5 oocysts IFA/10L) at five sites: Kowmung River (E130), Kedumba River (E157), Werriberri Creek (E531), Wollondilly River (E488) and Little River (E243). Overall, oocysts were detected in 7% of samples from all sites (excluding Gibbergunyah Creek E203). In contrast, as in previous years, Gibbergunyah Creek (E203) registered the greatest Cryptosporidium content (75% of samples with up to 62 oocysts IFA/10L). Over the last three years there has been no notable change in the frequency of Cryptosporidium and Giardia detected in catchment sites. Giardia was once again most common at Gibbergunyah Creek (E203), being detected in all samples. The median concentration of Giardia observed at this site was 44 cysts IFA/10L with a maximum of 253 cysts IFA/10L. Giardia cysts were detected infrequently at the other sites and when cysts were Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 48 detected in the Kowmung, Kedumba and Wollondilly rivers and Werriberri Creek they were at low concentrations (up to 5 cysts IFA/10L). Special testing has previously found that 100% of Cryptosporidium oocysts present at Gibbergunyah Creek (E203) are non-infectious. Consequently, the occurrence of elevated (oo)cyst counts at this site, which is located downstream of the point where UV-disinfected STP effluent is discharged, does not pose a Giardia/Cryptosporidium risk. The evidence of this investigation as well as the research into sewage treatment efficacy for Cryptosporidium inactivation (see 7.3.2.8) have demonstrated that monitoring Cryptosporidium and Giardia at E203 should cease as it is not a high risk catchment site. With the endorsement of the catchment auditor and NSW Health, Cryptosporidium and Giardia analysis for E203 has been removed from the Water Monitoring Program as of July 2014. 5.8.2 Storages Routine monitoring was conducted six days per week at one lake site (DWA2) in Lake Burragorang, twice weekly at two sites (RPR1 and RPR6) in Prospect Reservoir, and weekly at one site (DWI1) in Wingecarribee Reservoir. (Oo)cysts did not exceed the alert level at any of the lake sites during 201314. Both Cryptosporidium and Giardia were detected infrequently and at low concentrations in these samples. Cryptosporidium was detected in 1.9% of samples from DWA2 (up to 4 oocysts IFA/10L) and one percent and four percent of samples from RPR1 and RPR6, respectively (up to 3 oocysts IFA/10L). Giardia was detected in 1.3% of samples from DWA2 (up to 3 cysts IFA/10L) and two to six percent of samples from the other three sites (up to 5 cysts IFA/10L). The results are detailed in Appendix A. Over the last three years there has been no notable change in the frequency of Cryptosporidium and Giardia detected in storages. 5.8.3 Water Filtration Plants A joint monitoring program in raw water at the water filtration plants is undertaken by Sydney Water and results are provided to the SCA and NSW Health for: Macarthur WFP (MACSP1A) Prospect WFP (composite sample) Nepean, Illawarra, Woronora and Cascade WFP composite (COMP16). The Prospect WFP sample is a composite of the sources supplying raw water. Approximately 92% and 95% of samples were below the level of detection for Cryptosporidium and Giardia respectively. All of the (oo)cysts were at very low concentrations (maximum of 3 oocysts/10L and 2 cysts/10L). Pathogen concentrations were below the limit of detection for the vast majority of Macarthur WFP supply samples. Cryptosporidium was detected in two of 52 samples at concentrations ranging from approximately 1–2 oocyst IFA/10L. Giardia was detected in one of 52 samples at a concentration of approximately 1 cyst IFA/10L. Similarly, Cryptosporidium and Giardia were rarely detected from COMP16 samples. Cryptosporidium was not detected from the 52 samples collected during the year and Giardia was detected in a single sample at a concentration of 1 cyst IFA/10L. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 49 Over the last three years there has been no notable change in the frequency of Cryptosporidium and Giardia detected in WFP supply. 5.9 Picnic area monitoring Routine monitoring is undertaken in Avon, Cataract, Cordeaux and Fitzroy Falls picnic area taps where disinfected water is supplied directly from storages after chlorination (excluding Fitzroy Falls Reservoir). The results from picnic area monitoring are compared to applicable guidelines (section 4.7) and are presented in Table 5.6. Refer to Appendices A2.4 (Upper Nepean) and A5.4 (Fitzroy Falls) for the statistical summaries of the data. Table 5.6: Picnic areas - percentage of samples exceeding benchmarks. Manganese total Chlorophyll-a Toxic Cyanobacterial Count Microcystin 92 0 0 0 0 2 0 0 NA NA 51 69 0 2 10 10 98 14 0 NA NA Lake Cordeaux HCO6 51 94 2 0 2 2 47 6 0 NA NA Fitzroy Falls Reservoir HFFR 52 96 0 0 2 0 0 0 4 0 NA Iron total 49 HCA1 Aluminium total HAV3 Lake Cataract Turbidity pH Lake Avon Site E. coli Cyanobacteria Chlorine Residual Metals Number of samples Physical Station code Pathogenic Results were generally consistent with last year. Chlorine residual was frequently outside of the NHMRC guidelines at all four picnic areas (0.2-0.5 mg/L residual chlorine). In the case of Cataract and Fitzroy Falls picnic areas, this was often due to chlorine residuals being above the guideline range, whereas at Avon and Cordeaux picnic areas this was more likely due to chlorine levels being below the guideline range. Testing for E.Coli was used to confirm effectiveness of disinfection. Public use of water from picnic taps can be low and variable, which leads to long water age and chlorine decay in the reticulation system. This is why at Avon and Cordeaux picnic areas residuals are often below guidelines. Cataract picnic area has a recirculation system to re-dose chlorine to maintain residual and Fitzroy Falls picnic area is supplied by water tanker from a nearby potable water supply and rechlorinated on site. This is why these locations often have elevated chlorine residual. There were only infrequent excedeences of the NHMRC Health guideline of 5 µg/L (3 times at Avon, twice at Fitzroy Falls and once at Cataract picnic area). Cataract and Cordeaux picnic areas often had iron and occasionally manganese and aluminium above the aesthetic guidelines. Cataract picnic area in particular frequently had iron above the 0.3 mg/L NHMRC aesthetic guideline (98% samples). This is similar to last year and reflects the nature of the Upper Nepean catchments which are naturally high in iron and other metals. There were also 10% of samples from Cataract picnic area that had turbidity above the 5 NTU aesthetic guideline. These elevated levels occurred after significant rainfall in March that increased the turbidity in Lake Cataract and affected turbidity in the picnic area supply for a period of 3 weeks. Chlorine concentrations was adjusted to ensure effective disinfection. The inflows were also the cause of some of the higher iron, manganese and aluminium levels in the picnic area supply. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 50 Fitzroy Falls picnic area was the only site that had chlorophyll-a above the 5 µg/L trigger value for algal analysis (two samples in January 2014). Further analysis revealed no algae was present in the sample and an investigation was carried out into the cause of the elevated chlorophyll-a levels. Investigative monitoring did not detect chlorophyll-a at any stage of the supply chain and the cause of the elevated levels was not able to be determined. The supply and monitoring process was audited to ensure conformance to operational guidelines. SCA has developed a Drinking Water Management Plan and has adopted the NSW Private Water Supply Guidelines (NSW Health, 2014) as part of our actions to conform with the amendments to the NSW Public Health Act (2010). As such in future, chlorine residual targets will change from 0.2-0.5 mg/L to >0.5 mg/L which affect our management and reporting of chlorine residuals at picnic areas. As part of the drinking water management plan critical control points have been set for chlorine dosing and selective abstraction (depth of water in lake where supply is sourced from). 5.10 Dam seepage monitoring Chemical monitoring of seepage waters is conducted at the SCA dams to: Determine the origin and/or path of leakage Assess concrete degradation Assess dispersive behaviour and erodability of embankment and foundation materials. The dams sampled for chemical analysis of seepage waters this year were Avon, Cataract, Cordeaux, Nepean, Prospect, Tallowa, Warragamba, Wingecarribee and Woronora. All of these dams are tested annually. Prospect and Wingecarribee dams are of earth embankment construction and are tested for a variety of metals, particularly their sodium absorption ratio. Metals testing is also conducted at concrete and masonry construction dams (Avon, Cataract, Cordeaux, Nepean, Tallowa, Warragamba and Woronora), with net calcium levels measured as the key indicator of concrete degradation. A site upstream in the storage is tested at all dams to provide a control point. A variety of sites downstream at these dams are also tested. For example, net levels of calcium (i.e. calcium levels at the test site minus calcium levels in the storage water) are included in an equation to determine concrete degradation rates. No safety concerns (relating to chemical monitoring or concrete degradation) were identified for any dams during 2013-14. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 51 6 Monitoring for the Water Licences 6.1 Water quality The SCA undertakes sampling of waters downstream of storages in accordance with the requirements of the Water Licences. The results of downstream sampling are reported against ANZECC guidelines in Table 6.1. Number of samples Turbidity pH Dissolved Oxygen (%Sat) Phosphorus Total Nitrogen Total Chlorophyll-a E303 34 0 0 0 0 0 94 E851 12 0 17 25 0 8 42 G0515 12 0 75 100 0 0 0 Webbs Creek N14 12 0 0 33 0 17 92 Sackville Ferry N21 12 0 0 17 0 8 100 Windsor N35 12 0 0 17 8 58 100 North Richmond N42 13 0 0 38 0 38 100 Yarramundi Nepean River N44 13 0 0 23 0 54 92 Penrith Weir N57 12 0 0 25 0 17 92 Warragamba River junction N64 12 0 0 8 0 42 67 Megarritys Ck N641 12 0 0 33 0 50 25 Wallacia N67 12 0 0 42 0 50 67 Sharpes Weir N75 12 0 0 17 0 42 58 Menangle Bridge N85 12 0 0 58 0 0 25 Pheasants Nest Weir N86 12 0 0 25 0 0 0 Broughtons Pass Weir N881 12 0 0 0 0 0 0 Maldon Weir N92 12 0 0 42 0 33 0 Site Station Code Table 6.1: Downstream of storages - percentage of samples exceeding benchmarks Wingecarribee River Sheepwash Bridge Shoalhaven River d/s Lake Yarrunga Woronora River The Needles Hawkesbury River Water quality in the Hawkesbury-Nepean system typically declines in a downstream direction. This trend is particularly evident in chlorophyll-a concentration, which increases rapidly downstream of SCA control structures (Pheasants Nest, Broughtons Pass). Dissolved oxygen and pH at The Needles (Woronora River) were outside of ANZECC benchmarks for a majority of samples. Much like pH in Lake Woronora and Woronora River (upstream of Lake Woronora), pH was below the ANZECC benchmark and is the result of natural conditions. Dissolved oxygen was below ANZECC benchmarks yet above 50% saturation. At this level, ecological communities are not considered to be impacted. 6.2 Water quantity Inflows for the 2013-2014 reporting period were slightly under the historical average (based on the 1996-2014 period). All storages operated at high capacities throughout the period, with very little water transferred between systems. Figure 6.1 presents the annual inflows and transfers to key SCA storages for the period 1996-2014. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 52 Figure 6.1: Annual inflows into Lake Nepean, Lake Yarrunga (Tallowa) and Lake Burragorang (Warragamba) since 1996-97 Environmental release requirements for Woronora, Cataract, Cordeaux, Avon, Nepean, Broughtons Pass, Pheasants Nest and Tallowa are calculated as a function of inflows on a daily basis. There is a fixed environmental flow requirement for Wingecarribee Reservoir. Below is a summary of the releases for these dams and weirs. 6.2.1 Upper Nepean system 6.2.1.1 Cataract Dam Figure 6.2 shows the environmental flow releases and spills from Cataract Dam over the 2013-14 reporting period. Figure 6.2: Environmental releases and spills – Cataract Dam Approximately 14,700 ML was discharged as environmental flows from Cataract Dam in 2013‐14. The releases ranged from a minimum of 1 ML/d up to 519 ML/d in July, 2013. The average release over the 12 months was 40 ML/d. Following the storm event in late March 2014 (refer to section 8.1 for details), releases from Cataract Dam were reduced to 50 ML/d to reduce turbidity in raw water supplied to Macarthur WFP. Environmental releases were also limited to 350 ML/d while the release valve was repaired. NSW Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 53 Office of Water was notified of these issues and agreed to the SCA’s proposal for making up release shortfalls as per the agreed protocol. The valve was repaired and shortfalls made up by 9 April 2014. 6.2.1.2 Cordeaux Dam Figure 6.3 shows the environmental flow releases and spills from Cordeaux Dam over the 2013-14 reporting period. Figure 6.3: Environmental releases and spills – Cordeaux Dam Approximately 8,900 ML was discharged as environmental flows from Cordeaux Dam in 2013‐14. The releases ranged from a minimum of 1 ML/d up to 485 ML/d in July, 2013. The average release over the 12 months was 25 ML/d. 6.2.1.3 Avon Dam Figure 6.4 shows the environmental flow releases and spills from Avon Dam over the 2013-2014 reporting period. Figure 6.4: Environmental releases and spills – Avon Dam Approximately 11,400 ML was discharged as environmental flows from Avon Dam in 2013‐14. The releases ranged from a minimum of 1 ML/d up to 742 ML/d in July, 2013. The average release over the 12 months was 31 ML/d. There was a short period in March, 2014 when required release exceeded output capacity. The shortfall was made up in the following week in consultation with NSW Office of Water. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 54 6.2.1.4 Nepean Dam Figure 6.5 shows the environmental flow releases and spills from Nepean Dam over the 2013-2014 reporting period. Figure 6.5: Environmental releases and spills – Nepean Dam Approximately 11,150 ML was discharged as environmental flows from Nepean Dam in 2013‐14. The releases ranged from a minimum of 1 ML/d up to 460 ML/d in September, 2013. The average release over the 12 months was 31 ML/d. Nepean Dam spilled throughout July and August, 2013 followed by another spill event in late September, 2013. A maximum spill of 2400ML/d occurred in September, 2013 with a total of 27,700ML spilling over the 12 month period. 6.2.1.5 Broughtons Pass Weir Figure 6.6 shows the environmental flow releases and spills from Broughtons Pass Weir over the 2013-2014 reporting period. Figure 6.6: Environmental releases – Broughtons Pass Weir Approximately 19,200 ML was discharged as environmental flows from Broughtons Pass Weir in 2013‐14. The releases ranged from a minimum of 1 ML/d up to 798 ML/d in July, 2013. The average release over the 12 months was 52 ML/d. 6.2.1.6 Pheasants Nest Weir Figure 6.7 shows the environmental flow releases and spills from Pheasants Nest Weir over the 20132014 reporting period. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 55 Figure 6.7: Environmental releases – Pheasants Nest Weir Approximately 38,400 ML was discharged as environmental flows from Pheasants Nest Weir in 2013‐ 14. The releases ranged from a minimum of 1 ML/d up to 1969 ML/d in July, 2013. The average release over the 12 months was 105 ML/d. 6.2.2 Woronora system 6.2.2.1 Woronora Dam Figure 6.8 shows the environmental flow releases and spills from Woronora Dam over the 2013-2014 reporting period. Figure 6.8: Environmental releases and spills – Woronora Dam Approximately 4,900 ML was discharged as environmental flows from Woronora Dam in 2013‐14. The releases ranged from a minimum of 1 ML/d up to 248 ML/d in July, 2013. The average release over the 12 months was 13 ML/d. 6.2.3 Shoalhaven system 6.2.3.1 Tallowa Dam Figure 6.9 shows the environmental flow releases and spills from Tallowa Dam over the 2013-2014 reporting period. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 56 Figure 6.9: Environmental releases and spills – Tallowa Dam Approximately 204,000 ML was discharged as environmental flows from Tallowa Dam in 2013‐14. The releases ranged from a minimum of 46 ML/d up to 11,700 ML/d in March, 2014. The average release over the 12 months was 560 ML/d. Occasional shortfalls in daily release requirements occurred sporadically during the year due to failure of the automatic daily release setting on the overshot gate. The fault was compounded by fluctuating storage levels in Tallowa Dam due to hydroelectric generation by Origin Energy. Each instance was reported to NSW Office of Water who agreed with the SCA’s strategy for manually setting daily releases and making up for shortfalls as per agreed protocols. Spills were recorded throughout the year, with a maximum spill of 23,000 ML/d occurring in September, 2013. A total of 240,00ML spilled from Tallowa Dam over the 12 month period. 6.3 Thermal impacts of environmental releases Water released from storages can often be significantly warmer or cooler than downstream systems due to depth of offtake, thermal stratification and greater thermal mass. Large releases of thermally disparate waters into downstream systems can significantly impact on downstream riverine systems though disruption of fish migration and alteration of macroinvertebrate assemblages. To investigate the effect of environmental releases, water temperature is measured at a number of locations downstream of SCA storages. To determine potential thermal impacts, the temperature of storage inflows and environmental releases for the reporting period are compared. In this instance, storage inflows provide a measure of expected water temperatures in the natural conditions. Downstream temperatures are taken from the closest downstream hydrometric station. Only systems with Environmental Flow conditions are presented, namely the Upper Nepean, Woronora and Shoalhaven systems. 6.3.1 Upper Nepean system The Upper Nepean System comprises of the Avon, Cataract, Cordeaux and Nepean catchments, all of which are subject to environmental releases. While the SCA endeavours to provide the highest Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 57 quality water for environmental release, system configuration precludes diversion specifically for environmental releases from the Upper Nepean storages. As such, all Upper Nepean environmental releases are sourced from offtake depths determined to provide the highest quality water for human consumption. As such, the SCA is particularly interested in detecting suppressed downstream water temperatures as a result of deep water offtakes. Daily temperature data was recorded at the following SCA hydrometrics stations and represent reference catchment conditions: Avon catchment - Avon River at Summit Tank Cataract catchment – Cataract River at Corrimal Cordeaux catchment – Sandy creek at Fire Road 15 Nepean catchment – Nepean River at Nepean Dam inflow Downstream water temperature was recorded at Menangle Weir on the Nepean River which represents the first hydrometric station after the confluence of all Upper Nepean Storage releases. The station is approximately 20km downstream of the furthest Upper Nepean storage, Lake Cordeaux. As shown in Figure 6.10, downstream temperatures at Menangle Weir are consistently higher than the inflow reference temperatures, indicating no persistent downstream cold water pollution as a result of environmental releases. Furthermore, downstream temperatures and reference temperature profiles exhibit small scale changes and seasonal trends. Reference temperatures display greater small scale variability resulting from their smaller flow. Figure 6.10: Upper Nepean system temperature profile 6.3.2 Woronora system As with the Upper Nepean storages, the system configuration at Lake Woronora does not support offtakes specifically for environmental releases. As a result, environmental releases may be significantly cooler than surface waters due to thermal stratification. Downstream water Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 58 temperatures in the Woronora River are analysed to detect any evidence of persistent cold water pollution. Reference temperatures for the Woronora catchment are recorded daily at the major inflow locations to Lake Woronora: Woronora River at Fire Rd 9F Waratah Rivulet at Fire Rd 95 Downstream temperatures were recorded daily at The Needles on the Woronora River, approximately 10km downstream from the environmental release point. As seen in Figure 6.11, the downstream temperature at The Needles closely matches that of the reference temperatures. Both show a strong seasonal trend and show very similar small scale variations resulting from local weather conditions. Figure 6.11: Woronora system temperature profile 6.3.3 Shoalhaven system Since 2008, environmental releases from Lake Yarrunga have been predominantly supplied via an overshot gate on the dam which allows for the preferential release of surface waters. There is also a high level outlet which contributes to the environmental release via the fishway. As surface waters aren’t subject to thermal stratification, they should more closely match downstream temperatures. Reference temperatures for Lake Yarrunga are recorded daily on the major tributaries: Shoalhaven River at Fossickers Flat Kangaroo River at Hampden Bridge Downstream temperatures were recorded daily at: Shoalhaven River downstream of Tallowa Dam Shoalhaven River at Grassy Gully Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 59 The downstream site at Tallowa Dam is immediately downstream of the environmental releases and provides a good measure of the release temperature. Grassy Gully is approximately 20km further downstream. Figure 6.12 clearly shows that temperatures at both downstream sites closely match those of the upstream Shoalhaven reference site. The similarity between the two downstream sites suggests the environmental releases are very near ambient condition. The Kangaroo River catchment is small, so temperatures fluctuate more in response to local rain events. Considering the Shoalhaven River contributed 5-6 times more water during the reporting period, the site at Fossickers Flat is a more relevant reference for comparing upstream and downstream temperatures. Figure 6.12: Shoalhaven system temperature profile Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 60 7 Targeted and investigative monitoring The SCA undertakes targeted and investigative monitoring to understand and assess impacts that are not addressed by the routine monitoring program. The results of the monitoring are discussed in greater detail in the sections below. A summary of water quality incidents during 2013-14 is included in Section 8. 7.1 Wet weather inflow monitoring To assist in evaluating impacts on water quality from runoff during significant rainfall events, the SCA undertakes wet weather sampling. A key component of the wet weather monitoring program is the use of autosampler stations at strategic catchment sites which are programmed to automatically take samples once a river height trigger has been reached. Wet weather monitoring is used to quantify the water quality risks for incoming waters to storages. During high rainfall events, catchments are often closed to operational traffic and storages closed to boat traffic to protect the health and safety of staff and members of the public. Using auto-samplers helps to acquire valuable water quality information on the water quality effects of rainfall events. The SCA maintains two types of autosamplers, measuring the following analytes: Type 1 – total organic carbon, suspended solids, total phosphorus, total nitrogen, total aluminium, total iron and total manganese. Type 2 – total nitrogen, total phosphorus, Cryptosporidium and Giardia. Where specific water quality issues have been identified, additional characteristics are analysed on request. At high priority reservoir inflow locations, both auto-sampler types have been installed. Given the differing sampling mechanisms, trigger values may differ between the two autosampler types. Type 2 samples are reserved for locations identified as potentially significant pathogen sources, requiring a much larger sample volume (hence the lower number of samples). Table 7.1 shows number of samples collected for each site during the year. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 61 Table 7.1: Number of wet-weather samples from SCA autosamplers 2013–14 Station Code* Autosampler Type I System Autosampler Type II Number of samples Number of days Number of samples Number of days E083 Warragamba 3 1 0 0 E130 Warragamba 1 1 0 0 E157 Warragamba 14 6 2 2 E203 Warragamba 0 0 17 11 E206 Warragamba 46 11 0 0 E332 Warragamba 11 3 0 0 E409 Warragamba 15 5 0 0 E450 Warragamba 12 2 0 0 E457 Warragamba 12 3 0 0 E531 Warragamba 3 1 0 0 E6006 Upper Nepean 15 4 0 0 E604 Upper Nepean 13 4 0 0 E608 Upper Nepean 10 4 0 0 E609 Upper Nepean 16 4 0 0 E610 Upper Nepean 6 2 0 0 G0515 Woronora 18 5 0 0 E6131 Woronora 30 7 0 0 E677 Woronora 11 4 0 0 E680 Shoalhaven 26 9 0 0 E706 Shoalhaven 77 11 2 2 E822 Shoalhaven 26 5 0 0 E847 Shoalhaven 22 6 0 0 E860 Shoalhaven 20 4 0 0 E861 Shoalhaven 14 5 0 0 E891 Shoalhaven TOTAL 27 448 5 112 0 21 0 15 * Refer to catchment maps in Section 5 for location of autosampler sites 7.2 Macroinvertebrate monitoring The Macroinvertebrate Monitoring Program (MMP) is an annual assessment of the ecological health of river sites in the SCA’s drinking water supply catchment. Macroinvertebrate sampling was conducted at 61 sites in 27 sub-catchments, collecting 121 individual samples, a slight increase compared with the 2012 MMP. Sampling sites and assessments are presented in Figure 7.1. Results were generally similar to 2012 program. No sites were in above reference condition (compared to one site in 2012) but there was only one site well below reference condition (compared to three sites in 2012). Macroinvertebrate sampling was conducted at 26 sites from 12 sub‐catchments in the Warragamba catchment in 2013. Sixty five percent of sites were rated to be in a reference or above reference condition, an improvement on the 2012 results. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 62 Twelve sub‐catchments were sampled in the Shoalhaven catchment, with macroinvertebrate monitoring conducted at 26 sites in 2013. Nearly 40% of sites had AUSRIVAS ratings in a reference condition, but none above reference condition. Catchment wide, this is an improvement when compared to the previous year’s findings. Four sites in the Metropolitan catchment were sampled for macroinvertebrates in 2013. Only one of the four sites sampled in the Metropolitan catchment was rated in 2013 to be in reference condition, with the remaining sites rated to be below reference condition. This result is the same as the 2012 assessment. Health in the Woronora sub-catchment improved compared to last year, with one site in reference condition and one site below reference. AUSRIVAS ratings for the three Blue Mountains sub-catchment sites were similar to 2012 and ranged from reference to below reference condition. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 63 Figure 7.1: AUSRIVAS ratings for each of the sites sampled in 2013 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 64 7.3 Investigative monitoring The SCA’s investigative monitoring program is designed to target known risks, emerging issues and to enhance modelling and management options. Investigative monitoring can be used for identifying pollution sources, understanding pollutant fate and transport in a variety of flow conditions, and investigating the risk of pollutants reaching inflows and raw water off-take points. Investigative monitoring is also one method used in evaluating the effectiveness of actions in the catchments and storages to address pollutants. 7.3.1 Investigative monitoring for operational decision making 7.3.1.1 Prospect Reservoir draw down for dam safety works In agreement with Sydney Water, a monitoring program to assess key water quality parameters is always implemented prior to and during the planned use of Prospect Reservoir. From 1 July to 28 September 2013 Prospect Water Filtration Plant (WFP) was supplied with water from Prospect Reservoir. This was done to draw down the Prospect Reservoir to greater than 3.4 m below full supply to allow for critical dam safety works. This monitoring aims to assess whether the water quality is acceptable for supply, as Prospect Reservoir is a small reservoir that can experience rapid changes in water quality. The outcome of this monitoring was the successful draw down of Prospect Reservoir for the dam works without compromising water quality supplied to Prospect WFP. 7.3.1.2 Wet weather event June-July 2013 Extended wet weather in late June and early July 2013 caused significant inflows into multiple storages. Inflow intrusions were present in Lake Burragorang, Lake Nepean, Lake Cataract, Lake Cordeaux, Lake Avon and Lake Woronora. Additional water quality monitoring was undertaken to assess the impact of the inflows on supply. This included sampling of the lakes to assess what depth of water in the lakes were impacted by the inflow, what the magnitude of impacts were and where the best quality water for supply was located. Extensive post-wet weather event monitoring was undertaken in Lake Burragorang due to the major changes in water quality caused by this event. Particularly, elevated colour was causing treatment difficulties at Orchard Hills and Prospect WFPs. The outcome of this monitoring was the optimisation of offtakes and supply sources under highly variable conditions. This monitoring also highlighted a gap in our knowledge around the release of colour causing organics from the catchments during large wet weather events. A research project has commenced to address this knowledge gap (refer to section 7.3.2). Monitoring during this event revealed some useful observations regarding protozoan pathogens: Sewage overflows contained much more Giardia than Cryptosporidium but Cryptosporidium dominated in the water at the inflows to Lake Burragorang and within the lake itself. This suggested that diffuse sources within the catchment were a much greater source of oocysts than STPs. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 65 A large proportion of oocysts in samples of sewage and receiving water immediately downstream of the bypassing STPs were infective. No infective oocysts were detected in water samples well downstream of the STPs or in Lake Burragorang. This means that the Cryptosporidium risk from this event was low. Cryptosporidium oocysts were detected at low-moderate concentrations in the intrusion as the underflow moved along the lake. It is not known whether the observations made during this event can be generalised to other events. A Cryptosporidium and Giardia campaign monitoring program has been developed to inform risk assessment for future wet weather events. 7.3.1.3 Post-bushfire water quality in the Upper Nepean system Bushfires in the Southern Highlands in October 2013 affected more than 15,600 hectares of bushland, including 7,000 hectares of Special Areas surrounding Lake Nepean and the two weirs that are used to supply Macarthur and Prospect water filtration plants with water from the Upper Nepean lakes. In March 2014, intense storms occurred over the bushfire-affected areas (with a total 230mm rainfall received in a very short period), increasing the risk of iron and nutrients being transported into the storages and rivers during storm events. Additional monitoring was undertaken after both of these events to identify risks to water quality, provide early warning and optimise quality of water supplied to the water filtration plant. Outcomes of this monitoring are also included in section 8.1. 7.3.2 Scientific research Eleven science investigations were completed in 2013/14, including three that were contracted to external providers. 7.3.2.1 Effect of chlorination on Giardia in the Upper Canal The Upper Canal delivers water in the Upper Nepean storages (Nepean, Avon, Cordeaux and Cataract reservoirs) from Broughtons Pass to Prospect WFP. The water is chlorinated at the tunnel entrance at Broughtons Pass. The main purpose of chlorination is to provide Giardia initial kill in the raw water prior to reaching the Prospect WFP. The investigation showed that while chlorination of the Upper Canal will reduce the overall Giardia risk, the filtration and post-filtration chlorination conducted at Prospect WFP is sufficient to reduce the Giardia risk to an acceptable level without Upper Canal chlorination under the range of flow/rain conditions represented in the historical data set. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 66 7.3.2.2 Sources of taste and odour producing compounds Prospect Reservoir is an integral part of Sydney’s water supply system and it is strategically placed as a potential back up supply. Customer complaints about taste and odour have been attributed to water quality from Prospect Reservoir in the past with above average complaints coinciding with time of supply from Prospect Reservoir but there is no direct evidence of correlation. While Prospect Reservoir has had occasional detections of known taste and odour producing compounds the definitive sources of these compounds were not well established. An investigation of the sources of specific taste and odour compounds (MIB and geosmin) in Prospect Reservoir was initiated to inform mitigation strategies. The study identified ten species of cyanobacteria in Prospect Reservoir that are known to produce taste and odour compounds, and confirmed that MIB is the predominant cause of taste and odour. A collaborative project with the University of Adelaide has commenced to further improve our understanding of the sources of MIB and geosmin in Prospect Reservoir. 7.3.2.3 Cryptosporidium in kangaroos This project was designed to resolve uncertainty over whether eastern grey kangaroos in the Sydney catchment areas are carriers of human-infective strains of Cryptosporidium. Over a two year period approximately 600 faecal samples were collected from eastern grey kangaroos. Only 1.7% of the samples contained Cryptosporidium and these were genotypes that are not considered human infective. The risk to human health from kangaroo faeces is therefore considered to be very low. Field sampling for this project ceased in June 2014. The work will be incorporated into a collaborative Australian Research Council (ARC) Linkage Project between the SCA, Murdoch University and other Australian and international organisations on the health risks of Cryptosporidium and Giardia in native and introduced animals and the potential for cross infection. The findings should reduce the need to genotype oocysts from water from catchments with no human or livestock contamination and assist justify a reduction in baseline pathogen monitoring in these catchments. 7.3.2.4 Review of pesticides and synthetic organic compounds The Australian Drinking Water Guidelines (ADWG) released in 2011 nominated guideline values for 147 organic chemicals to consider in health risk assessment. Many of these organics have not been monitored in SCA reservoirs or catchments. A risk assessment was conducted in consultation with stakeholders to review pesticide usage within SCA catchments from 2000-2012 leading to a short list from the ADWG organic chemicals for further risk assessment. The SCA collaborated with EPA and NSW Department of Primary Industries pesticide experts to collate information on contemporary pesticide usage in NSW/SCA catchments and emerging products. The risk assessment has led to a revision of the pesticides and synthetic organic contaminants (SOCs) monitored at inlet to water filtration plants. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 67 7.3.2.5 Characterising pathogen risk in catchments A method was developed to assess catchments for microbiological risk and piloted on two SCA catchments. The catchment assessment method is based on the WSAA two-tier assessment method that has been modified to incorporate the more detailed catchment information. For the SCA, this is through the Pollutant Source Assessment Tool and includes a component that utilised quantitative microbial risk assessment (QMRA) based on long-term Cryptosporidium monitoring data. The catchment assessments provide scientifically-defensible evidence of microbiological risk in SCA catchments and forms an integral part of the discussions with NSW Health regarding the health response required following future WFP turbidity exceedance and will reduce the monitoring requirement. The following SCA-sponsored scientific investigations conducted by external providers were reported in 2013/14: 7.3.2.6 Physico-chemical controls on cyanobacteria in Sydney reservoirs The aim of this project was to improve understanding of the factors controlling the toxic cyanobacterial blooms in water reservoirs, with a focus on Microcystis sp. Insight into the forms of nutrients that are most readily assimilated by toxin-producing species of cyanobacteria prevalent in water supply reservoirs and an understanding of the spatial and temporal distribution of the forms of nutrients, and light and temperature will assist in determining the key drivers to occurrence of blooms of these organisms. The study shows that nutrient uptake rate increases with greater iron limitation in high-nutrient conditions, and decreases with greater iron limitation in low-nutrient conditions. Greater iron limitation increases the production of microcystin toxins in low-nutrient conditions, and does not have strong influence in high-nutrient conditions. Greater knowledge of toxin genesis should inform the monitoring required in conditions likely to indicate a possible toxic event. 7.3.2.7 Physical, chemical and microbiological degradation of cyanobacterial compounds Once cyanobacterial toxins or taste and odour compounds are present in water, it is critical to know the fate of these compounds. Understanding of the natural removal of the compounds by physical, chemical and biological mechanisms will be useful for the SCA to determine the potential down time of the reservoirs after a toxic bloom. The study found that biodegradation and photolysis are the key processes governing the fate of the cyanobacteria metabolites in Lake Burragorang, and are influenced by seasonal variations. Cyanobacteria metabolites are biodegradable, with half-lives from 3 to 36 days. Half-lives for photodegradation range from 2 to 39 days. Cyanotoxins are more easily biodegradable than the taste and odour causing compounds. The fugacity model developed in this project specifically assesses the fate Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 68 of cyanobacteria exudates, but is suitable for the analysis of any other organic chemical in Lake Burragorang. These findings will inform post-bloom monitoring. 7.3.2.8 Sewage Treatment Plant Evaluation Study This study monitors the effectiveness of sewerage projects in reducing pathogenic loads by determining the loading, infectivity and persistence of pathogens discharged from STPs within the catchment. Preliminary results show that while Cryptosporidium was consistently present in STP effluent discharged to catchment streams, none were infectious under normal conditions. 7.3.2.9 Validation of the Grazing Evaluation Model A preliminary grazing runoff pollutant model is being developed from field trials to more confidently assess the pollutant exports from grazed hill slopes and the effectiveness of grazing interventions. The study will inform the selection of future interventions and best management practices for SCA catchments. 7.3.2.10 Benthic cyanobacteria and taste and odour compounds This project will provide a robust understanding of the presence, development, measurement and control of benthic (reservoir bed) cyanobacteria in Prospect Reservoir and their role in generating taste and odour producing compounds. This study builds on findings from an earlier project to investigate the sources of MIB and geosmin in Prospect Reservoir. 7.3.2.11 Environmental E. coli Escherichia coli is an indicator bacterium commonly used to indicate the presence of faecal contamination in waters. However, some strains of E.coli can grow in water, which can result in a false warning of faecal contamination. This study aims to identify and ultimately develop a method to differentiate E.coli strains from faecal and environmental sources and reduce false alarms. 7.3.2.12 Sources and causes of true colour in raw water A project has been initiated to investigate the sources and causes of true colour in raw water, initially focussing on Lakes Nepean and Woronora. The project will determine the relationship between spectra at various wavelengths and other water quality characteristics (e.g. iron, organic carbon). A sampling campaign has been developed to better understand the spatial and temporal dynamics of catchment sources of true colour. 8 Incidents and events Water quality incidents are managed in accordance with the SCA’s Raw Water Quality Incident Response Plan. The plan sets out agreed water quality trigger levels for various actions and Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 69 notifications. Any issue that poses a potential risk to public health is reported to NSW Health immediately and incident responses are developed in consultation with relevant stakeholders. The SCA’s Water Monitoring Program also specifies monitoring required in anticipation of events which pose potential threats to raw water quality, such as large inflow events and seasonal turnover in Lake Burragorang. The pre-planned monitoring during periods leading to and during such events allows operational changes to be made proactively and prevents such events manifesting into incidents. During 2013–14 there were no emergency incidents, four major incidents and nine minor water quality incidents recorded in the SCA’s area of operations (see Appendix B). 8.1 Macarthur storm event Intense storms over the Upper Nepean catchment areas on Saturday 22 March and Monday 24 March (about 230 mm of rain in total) resulted in highly variable water quality at Broughtons Pass Weir pool (where water is supplied to Macarthur Water Filtration Plant). These catchments were affected by bushfire in October 2013, increasing the risk of metals and nutrients being transported into the rivers and storages during subsequent storm events. The dry summer did not allow ground cover to re-establish sufficiently to reduce the risk of runoff. Following the initial storm event, turbidity in Broughtons Pass weir pool rapidly increased, exceeding 100 NTU (major incident threshold for Macarthur water filtration plant raw water is 50 NTU under typical demand conditions) and variable water quality impacted operation of the water filtration plant intermittently over the next few days. The plant reported elevated levels of true colour, while total iron peaked at 1.72 mg/L and moderate levels of E. coli (up to 1,300 orgs/mL) were recorded in samples taken during the incident. Significant additional monitoring, including surveillance of online information, was undertaken throughout the event to inform configuration changes. The SCA worked with Sydney Water to optimise raw water quality, undertaking additional monitoring and changing the source of supply to reduce the colour and turbidity in the raw water. While the plant was off line, the SCA closed off supply from Pheasants Nest weir and allowed the more turbid water to spill over Broughtons Pass weir. The Upper Canal was also temporarily diverted to Prospect Reservoir. Following the event a formal debrief was held and Sydney Water and NSW Health were satisfied with the SCA’s response to the incident. 8.2 Major water quality incidents Other than the Macarthur storm event, the only other major incident level events related to algal filter clogging potential (ASU), with samples exceeding the respective major incident triggers on three occasions. Prompt notifications and effective incident response ensured no adverse effects were experienced in water quality delivered to the WFPs. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 70 8.2.1 Elevated Algae Areal Standard Units in Kangaroo Valley raw water On 28 January 2014 a raw water sample at the inlet to Kangaroo Valley WFP (HKV1) recorded total algal areal standard units (ASU) of 7,016 ASU/mL. The major incident trigger for raw water supplied to Kangaroo Valley WFP is 5,000 ASU/mL. There is no health guideline for algae ASU. It is primarily used as an indicator for the potential for water filtration plant filters to become blocked, slowing flow through the plant and requiring more frequent filter cleaning. Diatoms, some of which have filter clogging potential, were the main source of the high ASU in January, but by February the algal population was dominated by the blue-green algae Cyanonephron. This type of algae is not known to produce any toxins and is generally not problematic. Algal blooms are common in Bendeela Pondage in late summer to autumn and blooms of Cyanonephron were recorded here between March and May in 2012 and 2013. Algal levels declined below the incident trigger in the monthly raw water sample collected in March, but again exceeded the major incident threshold in April 2014 (the sample taken on 22 April recorded 7,862 ASU/mL). In this sample the concentration of Cyanonephron peaked at over 3 million cells per millilitre before the algal population in Bendeela Pondage gradually declined. Shoalhaven City Council, which manages the Kangaroo Valley WFP, was notified of these results. Council reported no issues with treating the water. Operators checked the plant daily to assess the need for increased chemical cleaning of the membranes. Follow-up seasonal sampling on 28 April in Bendeela Pondage indicated a significant decrease in the algae ASU to 3,466 ASU/mL. The incident was downgraded and subsequently closed with further decreases in ASU recorded. 8.2.2 Elevated Algae Areal Standard Units in Prospect raw water From October 2013 to June 2014, during stage 1 of the Prospect Dam Safety upgrade, Prospect Reservoir was required to be maintained within a storage level range from 3.7 to 4 metres below full storage level. Rain events in March and associated diversions of the Upper Canal to the reservoir caused the storage level to increase above that range, so the SCA prepared to pump from the reservoir to supply to Prospect WFP. Preparations included implementation of event monitoring as agreed with Sydney Water to ensure that water quality was within acceptance criteria. This event monitoring program continued throughout the period of pumping from 29 March to 7 April 2014. A sample collected on 31 March 2013 recorded 2,002 ASU/mL in the raw water supplied to Prospect Water Filtration Plant. The major incident trigger level for Prospect WFP is 2,000 ASU/mL. The high ASU was related to high counts of diatoms present in the sample. Some species of diatoms have potential to clog filters but are not toxic and do not pose any risk to water quality. The results of this and other samples collected during the pumping event monitoring program were provided to Sydney Water. Previous and later raw water samples and samples from Prospect Reservoir showed comparatively low ASU (in the order of 30 to 150 ASU/mL) with no potentially toxic species of bluegreen algae. The plant reported no issues with treating the water and there was no increase in customer complaints relating to taste and odour. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 71 9 References ANZECC (2000). Australian and New Zealand Guidelines for Fresh and Marine Water Quality. Australian and New Zealand Environment and Conservation Council and Agriculture and Resource Management Council of Australia and New Zealand, Australia. Governor of NSW (2012). Operating Licence for the Sydney Catchment Authority 2012-2017. Issued under the Sydney Water Catchment Management Act 1998, New South Wales Government, Sydney. IPART (2013). Reporting manual for the Sydney Catchment Authority, 2013. Independent Pricing and Regulatory Tribunal, Sydney. NHMRC (2008). Guidelines for Managing Risks in Recreational Water. National Health and Medical Research Council, Canberra. NHMRC (2011). Australian Drinking Water Guidelines. National Health and Medical Research Council and the Natural Resource Management Ministerial Council, Commonwealth of Australia, Canberra. NSW Health (2014). NSW Private Water Supply Guidelines. NSW Health, Sydney. NSW Office of Water (2012). Sydney Catchment Authority Water Licences and Approvals Package. Water Administration Ministerial Corporation, Penrith. Sydney Catchment Authority and Sydney Water Corporation (2013). Sydney Catchment Authority and Sydney Water Corporation Raw Water Supply Agreement. Sydney Catchment Authority and Sydney Water Corporation, Sydney. Sydney Catchment Authority (2012). Healthy Catchments Strategy 2012 – 2016. Sydney Catchment Authority, Penrith. Sydney Catchment Authority (2010). Sydney Catchment Authority Water Monitoring Program 2010 – 2015. Sydney Catchment Authority, Penrith. Sydney Catchment Authority (2010). Raw Water Quality Incident Response Plan. Sydney Catchment Authority, Penrith. Sydney Catchment Authority (2010). Science Strategic Plan 2010 – 2015. Sydney Catchment Authority, Penrith. Sydney Catchment Authority (2012). Pollution Source Assessment Tool Implementation Plan 2012 – 2016. Sydney Catchment Authority, Penrith. Sydney Catchment Authority and NSW Health (2011). Memorandum of Understanding. Sydney Catchment Authority and NSW Health, Sydney. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 72 Sydney Catchment Authority and Shoalhaven City Council (2010). Sydney Catchment Authority and Shoalhaven City Council Raw Water Supply Agreement. Sydney Catchment Authority and Shoalhaven City Council, Nowra. Sydney Catchment Authority and Wingecarribee Shire Council (2010). Sydney Catchment Authority and Wingecarribee Shire Council Raw Water Supply Agreement. Sydney Catchment Authority and Wingecarribee Shire Council, Bowral. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 73 10 Glossary Aesthetic Considered pleasant to the senses. Algae Simple chlorophyll-bearing plants, mostly aquatic and microscopic in size. Algal bloom Rapid growth of algae in surface waters due to an increase in nutrients such as nitrogen and phosphorus and ideal conditions for proliferation. Alkalinity The capacity to neutralise acid. Analytes Physical, chemical and biological properties analysed. Catchment Area where water is collected by the natural landscape. In a catchment, all rain and run-off water eventually flows to a creek, river, lake or ocean, or into the groundwater system. Chlorophyll-a Green pigments in plants. Colour Colour is a measure of the absorption of light in certain frequencies by water. Colour in water may result from the presence of natural metallic ions (iron and manganese), humus and peat materials, algae and industrial wastes. True colour is the colour of water with no suspended material present. Composite sample A sample made up of component samples or collected at more than one location. Contaminant Biological (e.g. bacterial and viral pathogens) and chemical introductions capable of producing an adverse effect in biota. Cyanobacteria A division of photosynthetic bacteria that can produce toxins, formerly known as blue–green algae. Cyanotoxin Toxin produced by some cyanobacteria. Cyst A resting spore of many algae and protozoa. Detection limit The smallest concentration or amount of a substance that can be reported as present with a specified degree of certainty by definite complete analytical procedure. Diurnal Daily. Dissolved oxygen The amount of oxygen dissolved in water. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 74 Environmental flow Water released from reservoirs aimed at improving and maintaining the ecological health of the river downstream. Epilimnion The warmer upper layer of water in a stratified lake. Eutrophic Water bodies rich in mineral and organic nutrients that promote a proliferation of plant life. Field Blank For QA/QC purposes, a blank sample measures the magnitude of contaminant concentration that may have been introduced as a result of sampling-related activities. Blank water is specially prepared distilled, deionised or sterilised water that is laboratory produced, qualitycontrolled, and carries a certificate of analyte concentrations for each lot of water produced. Field blank samples are collected and processed in the field site in the same manner, and using the same equipment, as the primary sample. These samples are analysed along with routine samples and collected on the same trip. This helps to identify sources of contamination. Field duplicate The primary purpose of duplicate samples is to identify and/or quantify the variability in all, or part, of the sampling and analysis system. Duplicate, triplicate, or greater multiples are considered ‘identical’ or ‘almost identical’ in composition and are analysed for the same properties. Variations between the primary sample and the duplicate should be within the laboratories prescribed limits of the analytical methodology for each parameter analysed Hardness A measure of the concentration of calcium and magnesium ions in water, frequently expressed as mg/L calcium carbonate equivalent (CaCO3). Hypolimnion The colder lower layer of water in a stratified lake. IFA A presumptive test to detect Giardia cysts and Cryptosporidium oocysts by microscopy after staining with immuno-fluorescent antibodies Indicator A parameter that can be used to provide a measure of the quality of water or the condition of an ecosystem. Median The value of the middle item when the data are arranged in an increasing or decreasing order of magnitude. Metal Certain opaque, fusible, ductile, and typically lustrous substances that yield basic oxides and hydroxides that generally occur in trace amounts in living organisms. Can become toxic at higher concentrations. Nutrients Compounds required for growth by plants and other organisms. Major Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 75 plant nutrients are phosphorus and nitrogen. Oligotrophic Water bodies with low primary productivity, the result of low nutrient content. Oocyst Dormant but resistant phase of the life cycle of some protozoa. Parameter A measurable or quantifiable characteristic or feature. Pathogens Disease-causing organisms, such as bacteria and viruses. Pesticide A chemical that is toxic to pests. pH A measure of the degree of acidity or alkalinity, expressed on a logarithmic scale of one to 14 (one is most acid, seven neutral and 14 most alkaline). Physicochemical Refers to the physical (e.g. temperature, electrical conductivity) and chemical (e.g. concentrations of nitrate, mercury) characteristics of water. Reservoir An artificial body of water, often behind a dam. Runoff The portion of precipitation that flows towards streams, either above or below ground, often carrying dissolved or suspended material. Sediment Soil or other particles that settle to the bottom of lakes, rivers, and other waters. Special Area Areas of unspoilt bushland close to reservoirs that act as a buffer zones to help stop pollutants from entering reservoirs. Stratification Arrangement of layers, especially of water having different physicochemical properties in lakes. Thermal stratification The formation of distinct layers in lakes based on temperature, usually most pronounced during the summer months. Thermocline A region of rapidly changing temperature in a lake, found between the epilimnion and hypolimnion. Thermotolerant coliforms Bacteria used as a primary indicator of sewage pollution. Thermotolerant coliforms may in some instances include bacteria of environmental rather than faecal origin. Toxin A poisonous substance of biological origin. Turbidity A measure of the amount of suspended material (usually fine clay or silt particles) in water and thus the degree of scattering or absorption of Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 76 light in the water. Trip blank For QA/QC purposes, trip blank sample bottles are filled with clean water at the service providers’ depots prior to a sampling run. This helps to identify contamination that may occur during transportation, or from the containers themselves Trophic status Categorisation based on the level of nutrient enrichment in a lake which could lead to algal growth e.g. oligotrophic (low mineral and nutrient concentrations), eutrophic (high mineral and nutrient concentrations). Water column The region of water between the surface and bottom of a lake or river. Water filtration plant A treatment plant that improves water quality by removing impurities through filtration. Water quality benchmark The recommended quality of water for various uses based on evaluation of scientific data. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 77 11 Acronyms ADWG Australian Drinking Water Guidelines ASU Areal standard unit (a measure of algae) ANZECC Australian and New Zealand Environment and Conservation Council ARMCANZ Agriculture and Resource Management Council of Australia and New Zealand AUSRIVAS Australian Rivers Assessment System CFU Colony forming units (a measure of microorganisms) DPI Department of Primary Industries EPA Environment Protection Authority GIS Geographical Information System IFA Immuno-fluorescent antibody IPART Independent Pricing and Regulatory Tribunal LOR Limit of Reporting mg/L Milligrams per litre mm Millimetres ML Megalitre (one million litres) ML/d Megalitres per day MMP Macroinvertebrate monitoring program NATA National Association of Testing Authorities NHMRC National Health and Medical Research Council NOW New South Wales Office of Water NTU Nephelometric turbidity units QA/QC Quality assurance and quality control RWQIRP Raw Water Quality Incident Response Plan RWSA Raw Water Supply Agreement μg/L Micrograms per litre SCA Sydney Catchment Authority SCARMS SCA Reservoir Management System Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 78 SOC Synthetic Organic Compounds STP Sewage treatment plant SWC Sydney Water Corporation WFP Water filtration plant WMP Water monitoring program WSAA Water Services Association of Australia Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 79 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 Appendices Contents Appendix A A1 Statistical summaries ...................................................................................................... 7 Warragamba system ............................................................................................................... 7 A1.1 Catchments ......................................................................................................................... 7 A1.2 Storages............................................................................................................................. 18 A1.3 Water filtration plants....................................................................................................... 29 A2 Upper Nepean system .......................................................................................................... 33 A2.1 Catchments ....................................................................................................................... 33 A2.2 Storages............................................................................................................................. 38 A2.3 Water filtration plants....................................................................................................... 44 A2.4 Picnic areas........................................................................................................................ 48 A3 Woronora system.................................................................................................................. 49 A3.1 Catchments ....................................................................................................................... 49 A3.2 Storages............................................................................................................................. 51 A3.3 Water filtration plants....................................................................................................... 53 A4 Blue Mountains system......................................................................................................... 55 A4.1 Storages............................................................................................................................. 55 A4.2 Water filtration plants....................................................................................................... 58 A5 Shoalhaven system ............................................................................................................... 60 A5.1 Catchments ....................................................................................................................... 60 A5.2 Storages............................................................................................................................. 65 A5.3 Water filtration plants....................................................................................................... 71 A5.4 Picnic areas........................................................................................................................ 75 A6 Downstream rivers ................................................................................................................ 76 Appendix B Incidents ........................................................................................................................ 86 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 2 List of tables Table A1 Warragamba system – catchments - physico-chemical .......................................................... 7 Table A2 Warragamba system – catchments – nutrients ....................................................................... 9 Table A3 Warragamba system – catchments – metals ......................................................................... 11 Table A4 Warragamba system – catchments – cyanobacteria ............................................................. 13 Table A5 Warragamba system – catchments – pathogens................................................................... 15 Table A6 Warragamba system – catchments – Cryptosporidium and Giardia ..................................... 17 Table A7 Warragamba system – storages – physico-chemical ............................................................. 18 Table A8 Warragamba system – storages – nutrients .......................................................................... 20 Table A9 Warragamba system – storages – metals .............................................................................. 22 Table A10 Warragamba system – storages – cyanobacteria ................................................................ 24 Table A11 Warragamba system – storages – pathogens ...................................................................... 26 Table A12 Warragamba system – storages – heavy metals ................................................................. 28 Table A13 Warragamba system – storages – Cryptosporidium and Giardia ........................................ 28 Table A14 Warragamba system – water filtration plants - physico-chemical ...................................... 29 Table A15 Warragamba system – water filtration plants - metals ....................................................... 29 Table A16 Warragamba system – water filtration plants - cyanobacteria ........................................... 30 Table A17 Warragamba system – water filtration plants – pathogens ................................................ 30 Table A18 Warragamba system – water filtration plants – heavy metals ............................................ 31 Table A19 Warragamba system – water filtration plants - pesticides .................................................. 31 Table A20 Warragamba system – water filtration plants – synthetic organic compounds and radionucleids ......................................................................................................................................... 32 Table A21 Warragamba system – water filtration plants – Cryptosporidium and Giardia................... 32 Table A22 Upper Nepean system – catchments – physico-chemical ................................................... 33 Table A23 Upper Nepean system – catchments - nutrients ................................................................. 34 Table A24 Upper Nepean system – catchments - metals ..................................................................... 35 Table A25 Upper Nepean system – catchments - cyanobacteria ......................................................... 36 Table A26 Upper Nepean system – catchments - pathogens ............................................................... 37 Table A27 Upper Nepean system – storages – physico-chemical ........................................................ 38 Table A28 Upper Nepean system – storages – nutrients ..................................................................... 39 Table A29 Upper Nepean system – storages – metals ......................................................................... 40 Table A30 Upper Nepean system – storages – cyanobacteria ............................................................. 41 Table A31 Upper Nepean system – storages – pathogens ................................................................... 42 Table A32 Upper Nepean system – storages – heavy metals ............................................................... 43 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 3 Table A33 Upper Nepean system – water filtration plants – physico-chemical ................................... 44 Table A34 Upper Nepean system – water filtration plants - metals .................................................... 44 Table A35 Upper Nepean system – water filtration plants – cyanobacteria ........................................ 45 Table A37 Upper Nepean system – water filtration plants – heavy metals ......................................... 46 Table A38 Upper Nepean system – water filtration plants – pesticides .............................................. 46 Table A39 Upper Nepean system – water filtration plants – Synthetic organic compounds and radionucleids ......................................................................................................................................... 47 Table A40 Upper Nepean system – water filtration plants – Cryptosporidium and Giardia ................ 47 Table A41 Upper Nepean system – picnic areas................................................................................... 48 Table A42 Upper Nepean system – picnic areas - cyanobacteria ......................................................... 48 Table A43 Woronora system – catchments – physico-chemical .......................................................... 49 Table A44 Woronora system – catchments – nutrients ....................................................................... 49 Table A45 Woronora system – catchments - metals ............................................................................ 50 Table A46 Woronora system – catchments - cyanobacteria ................................................................ 50 Table A47 Woronora system – catchments – pathogens ..................................................................... 50 Table A48 Woronora system – storage – physico-chemical ................................................................. 51 Table A49 Woronora system – storage – nutrients .............................................................................. 51 Table A50 Woronora system – storage – metals .................................................................................. 51 Table A51 Woronora system – storage – cyanobacteria ...................................................................... 52 Table A52 Woronora system – storage – pathogens ............................................................................ 52 Table A53 Woronora system – storage – heavy metals ....................................................................... 52 Table A54 Woronora system – water filtration plant – physico-chemical ........................................... 53 Table A55 Woronora system – water filtration plant - metals ............................................................. 53 Table A56 Woronora system – water filtration plant - cyanobacteria ................................................. 53 Table A57 Woronora system – water filtration plant - pathogens ....................................................... 54 Table A59 Woronora system – water filtration plant - pesticides ........................................................ 54 Table A60 Woronora system – water filtration plant – synthetic organic compounds and radionucleids ......................................................................................................................................... 54 Table A61 Blue Mountains system – storages – physico-chemical ...................................................... 55 Table A62 Blue Mountains system – storages – nutrients ................................................................... 55 Table A63 Blue Mountains system – storages – metals ....................................................................... 56 Table A64 Blue Mountains system – storages – cyanobacteria ........................................................... 56 Table A65 Blue Mountains system – storages – pathogens ................................................................. 57 Table A66 Blue Mountains system – storages –heavy metals .............................................................. 57 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 4 Table A67 Blue Mountains system – water filtration plant – physico-chemical .................................. 58 Table A68 Blue Mountains system – water filtration plant – metals ................................................... 58 Table A69 Blue Mountains system – water filtration plant - cyanobacteria ........................................ 58 Table A70 Blue Mountains system – water filtration plant - pathogens .............................................. 58 Table A71 Blue Mountains system – water filtration plant – heavy metals ......................................... 59 Table A72 Blue Mountains system – water filtration plant - pesticides ............................................... 59 Table A73 Blue Mountains system – water filtration plant – synthetic organic compounds and radionucleids ......................................................................................................................................... 59 Table A74 Shoalhaven system – catchments – physico-chemical ........................................................ 60 Table A75 Shoalhaven system – catchments – nutrients ..................................................................... 61 Table A76 Shoalhaven system – catchments – metals ......................................................................... 62 Table A77 Shoalhaven system – catchments – cyanobacteria ............................................................. 63 Table A78 Shoalhaven system – catchments – pathogens ................................................................... 64 Table A79 Shoalhaven system – storages – physico-chemical ............................................................. 65 Table A80 Shoalhaven system – storages – nutrients .......................................................................... 66 Table A81 Shoalhaven system – storages – metals .............................................................................. 67 Table A82 Shoalhaven system – storages – cyanobacteria .................................................................. 68 Table A83 Shoalhaven system – storages – pathogens ........................................................................ 69 Table A84 Shoalhaven system – storages – heavy metals .................................................................... 70 Table A85 Shoalhaven system – storages – Cryptosporidium and Giardia........................................... 70 Table A86 Shoalhaven system – water filtration plants – physico-chemical ........................................ 71 Table A87 Shoalhaven system – water filtration plants - metals ......................................................... 71 Table A88 Shoalhaven system – water filtration plants - cyanobacteria ............................................. 72 Table A89 Shoalhaven system – water filtration plants - pathogens ................................................... 72 Table A90 Shoalhaven system – water filtration plants – heavy metals .............................................. 73 Table A91 Shoalhaven system – water filtration plants - pesticides .................................................... 73 Table A92 Shoalhaven system – water filtration plants – synthetic organic compounds and radionucleids ......................................................................................................................................... 74 Table A93 Shoalhaven system – picnic areas........................................................................................ 75 Table A94 Shoalhaven system – picnic areas - cyanobacteria .............................................................. 75 Table A95 Downstream of storages – physico-chemical ...................................................................... 76 Table A96 Downstream of storages – nutrients ................................................................................... 78 Table A97 Downstream of storages – metals ....................................................................................... 80 Table A98 Downstream of storages – cyanobacteria ........................................................................... 82 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 5 Table A99 Downstream of storages – pathogens ................................................................................. 84 Appendix B1: Water quality incidents that occurred during the 2013-2014 reporting period. ........... 86 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 6 Appendix A Statistical summaries A1 Warragamba system A1.1 Catchments True Colour at 400nm True Colour at 420nm Turbidity (NTU) 12 12 10 10 12 10 10 10 8 12 10 86.7 7.9 7.0 13 0.5 7.6 23.0 1.8 6 13 1 0.06 Median 37 11 23 0.24 3.5 100.4 9.2 7.8 35 2.5 14.7 36.5 3.6 9 24 3 0.10 Max 80 14 43 0.49 6.2 122.0 12.8 8.9 77 19 21.8 51.0 6.4 21 48 46 0.34 Above Max Guideline - - - - - 17 - 17 - - - - - - - 8 - Below Min Guideline - - - - - 8 - 0 - - - - - - - 0 - n 10 10 10 12 10 12 12 12 10 10 12 10 10 10 8 12 10 Min 31 8 9 0.15 1.7 82.2 6.7 7.0 15 0.5 8.6 36.0 1.9 6 16 2 0.06 Median 64 14 11 0.24 3.0 97.6 9.2 7.6 27 4 18.8 58.5 3.3 9 19 3 E083 0.10 Max 91 21 12 0.31 4.0 107.0 12.2 7.9 39 7 27.6 85.0 4.4 14 31 7 0.14 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 17 - 0 - - - - - - - 0 - n 10 10 10 12 10 12 12 12 10 10 12 10 10 10 8 12 10 Min 17 5 4 0.06 1.1 71.2 5.9 7.0 4 0.5 7.8 21.0 1.0 5 12 1 0.05 Median 41 8 6 0.11 2.1 98.7 9.4 7.5 6 2 18.5 33.5 2.5 7 17 2 E130 0.07 Max 60 14 26 0.18 3.3 104.0 12.3 7.6 7 4 27.7 56.0 3.3 11 26 5 0.11 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 33 - 0 - - - - - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 12 12 12 8 12 12 Min 11 3 7 0.07 1.5 78.6 7.1 6.8 6 0.5 8.8 12.0 1.4 6 17 1 0.06 Median 14 4 8 0.08 3.0 93.8 9.0 7.0 8 2 16.0 13.0 2.9 9 27 2 E157 0.08 Max 17 4 9 0.09 5.4 102.0 11.6 7.6 9 9 21.7 18.0 5.2 16 39 7 0.14 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 25 - 0 - - - - - - - 0 - n 11 11 11 12 11 12 12 12 11 11 12 11 11 11 8 12 11 Min 40 12 36 0.20 4.0 72.5 6.5 7.0 24 1 9.0 55.0 4.4 8 26 2 0.12 Median 51 21 50 0.42 6.1 93.8 9.0 7.3 54 4 15.1 73.0 6.2 16 38 5 E203 0.17 Max 68 43 64 0.58 12.3 99.0 10.7 7.7 76 12 21.0 132.0 12.0 30 65 46 0.33 Above Max Guideline - - - - - 0 - 0 - - - - - - - 8 - Below Min Guideline - - - - - 25 - 0 - - - - - - - 0 - n 11 11 11 12 11 12 12 12 11 11 12 11 11 11 8 12 11 E206 Min 17 8 33 0.19 3.5 70.7 6.1 7.1 21 0.5 8.6 36.0 3.3 10 23 0 0.10 Median 36 16 47 0.33 4.7 96.8 9.6 7.4 37 1 14.9 65.0 4.9 13 33 1 0.13 Max 52 25 57 0.48 8.8 104.0 11.7 8.1 52 18 21.7 87.0 8.6 34 76 33 0.46 Above Max Guideline - - - - - 0 - 17 - - - - - - - 8 - Below Min Guideline - - - - - 17 - 0 - - - - - - - 0 - n 11 11 11 12 11 12 12 12 11 11 12 11 11 11 7 12 11 E210 Min 33 7 36 0.24 2.8 60.0 5.2 6.7 26 1 9.4 42.0 2.8 12 27 3 0.14 Median 41 9 50 0.29 5.1 92.1 8.8 7.1 33 5 18.2 51.0 5.3 19 42 4 0.16 Max 62 14 59 0.38 6.3 101.0 11.2 7.5 43 10 23.9 80.0 6.8 32 69 6 0.26 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 42 - 0 - - - - - - - 0 - n 11 11 11 12 11 12 12 12 11 11 12 11 11 11 7 12 11 Min 2 1 29 0.12 1.2 80.0 6.8 6.4 16 0.5 10.4 8.0 1.3 2 7 1 0.03 Median 4 1 35 0.13 2.0 95.2 8.9 6.9 19 2 17.6 12.0 1.9 5 18 1 E243 0.06 Max 8 2 40 0.15 4.4 102.0 11.4 7.3 21 4 23.9 21.0 4.3 11 30 2 0.12 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 25 - 8 - - - - - - - 0 - Statistic Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices UV Absorbing constituents (organic) Total Organic Carbon (mg/L) 12 2.1 Temperature (Deg C) Sodium Filtered (mg/L) 10 0.14 Suspended Solids (mg/L) pH 12 10 Dissolved Oxygen (mg/L) 10 6 Dissolved Oxygen (%Sat) Chloride (mg/L) 10 21 Dissolved Organic Carbon (mg/L) Calcium Filtered (mg/L) 10 Min Conductivity (mS/cm) Alkalinity (mgCaCO3/L) n Station Code E046 Total Hardness (mgCaCO3/L) Table A1 Warragamba system – catchments - physico-chemical 7 Total Organic Carbon (mg/L) True Colour at 400nm True Colour at 420nm Turbidity (NTU) 12 12 11 11 12 11 11 11 8 12 11 29.2 2.5 6.9 13 3 8.4 29.0 4.7 10 23 3 0.16 Median 46 13 37 0.26 6.0 77.4 7.6 7.2 29 8 16.9 59.0 6.4 15 32 9 0.20 Max 60 15 48 0.34 7.3 111.0 10.5 7.9 40 12 25.6 66.0 7.1 24 36 22 0.29 Above Max Guideline - - - - - 8 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 75 - 0 - - - - - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 12 12 12 9 12 12 Min 56 21 98 0.55 5.8 60.9 5.1 7.1 50 2 8.4 127.0 5.4 13 29 2 0.20 Median 135 38 177 0.86 7.8 88.7 8.4 7.7 89 5 16.8 231.5 7.9 18 35 4 0.25 Max 175 44 260 1.17 14.0 123.0 11.9 8.2 134 20 23.4 287.0 13.9 41 48 15 0.53 Above Max Guideline - - - - - 25 - 33 - - - - - - - 0 - Below Min Guideline - - - - - 50 - 0 - - - - - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 12 12 12 9 12 12 Min 36 10 72 0.34 5.2 82.5 6.8 7.2 29 0.5 8.6 73.0 5.1 10 23 1 0.14 Median 75 24 144 0.64 7.6 97.7 8.7 7.8 63 3.5 17.7 154.5 7.6 16 34 2 0.22 Max 111 37 224 0.96 11.3 112.0 11.2 8.3 96 8 24.1 232.0 11.4 37 44 12 0.43 Above Max Guideline - - - - - 17 - 42 - - - - - - - 0 - Below Min Guideline - - - - - 17 - 0 - - - - - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 12 12 12 9 12 12 Min 44 20 125 0.56 10.8 78.1 6.8 7.4 51 2 8.2 120.0 10.5 19 42 2 0.34 Median 98 43 214 0.96 12.7 93.2 8.7 8.4 91 8 17.2 244.0 13.0 29 51 4 0.43 Max 131 46 245 1.03 14.7 167.0 16.0 8.9 97 22 22.4 259.0 14.8 58 98 17 0.65 Above Max Guideline - - - - - 17 - 67 - - - - - - - 0 - Below Min Guideline - - - - - 33 - 0 - - - - - - - 0 - 10 10 10 12 10 12 12 12 10 10 12 10 10 10 8 12 10 Min 39 14 41 0.26 3.9 63.5 5.1 7.4 24 0.5 8.2 72.0 4.1 9 20 2 0.12 Median 109 28 104 0.56 6.3 99.2 9.7 8.0 49 4.5 20.0 164.5 6.6 12 26 4 0.18 Max 134 33 174 0.82 9.2 128.0 11.9 8.6 84 8 28.7 212.0 10.1 34 29 16 0.39 Above Max Guideline - - - - - 17 - 42 - - - - - - - 0 - Below Min Guideline - - - - - 17 - 0 - - - - - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 12 12 12 8 12 12 Min 7 4 74 0.29 1.5 42.1 3.6 6.4 33 2 8.2 39.0 1.8 4 11 3 0.10 Median 14 5 89 0.34 3.5 71.1 7.4 6.8 45 3.5 14.8 48.5 3.7 17 43 4 0.19 Max 20 6 109 0.40 5.6 96.0 10.5 7.5 51 6 21.5 58.0 5.4 31 76 11 0.27 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 83 - 8 - - - - - - - 0 - n 9 9 9 11 9 11 11 11 9 9 11 9 9 9 7 11 9 Min 11 10 22 0.19 1.7 46.6 4.1 6.4 11 0.5 8.6 58.0 1.7 2 4 0 0.03 Median 24 42 32 0.55 2.7 66.3 6.4 7.1 19 1 15.7 216.0 3.1 4 8 1 0.07 Max 43 70 38 0.76 6.6 103.0 11.4 7.7 27 4 21.3 344.0 7.7 12 27 12 0.28 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 73 - 18 - - - - - - - 0 - Statistic n E409 E450 E457 n E488 n E531 E551 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices UV Absorbing constituents (organic) Suspended Solids (mg/L) E332 Total Hardness (mgCaCO3/L) Sodium Filtered (mg/L) 12 4.8 Temperature (Deg C) pH 11 0.13 Dissolved Oxygen (mg/L) 12 24 Dissolved Oxygen (%Sat) Chloride (mg/L) 11 5 Dissolved Organic Carbon (mg/L) Calcium Filtered (mg/L) 11 32 Conductivity (mS/cm) Alkalinity (mgCaCO3/L) 11 Min Station Code n 8 Potassium Filtered (mg/L) E130 E157 E203 E206 E210 E243 12 10 10 10 10 0.4 0.1 0.02 0.03 3 2.7 Median 1.5 0.01 0.9 0.2 1.1 0.5 0.02 0.06 5 6.6 Max 17.3 0.22 1.7 0.9 1.9 1.2 0.06 0.09 9 10.0 Above Max Guideline - - - - 100 - - 100 - - Below Min Guideline - - - - 0 - - 0 - - n 12 10 10 10 10 12 10 10 10 10 Min 0.5 0.00 0.0 0.1 0.2 0.1 0.00 0.01 2 5.1 Median 2.0 0.00 0.0 0.2 0.2 0.5 0.01 0.02 3 5.8 Max 6.0 0.04 0.2 0.3 0.4 1.5 0.02 0.03 4 9.7 Above Max Guideline - - - - 20 - - 20 - - Below Min Guideline - - - - 0 - - 0 - - n 12 10 10 10 10 12 10 10 10 10 Min 0.4 0.00 0.0 0.0 0.1 0.1 0.00 0.01 1 6.3 Median 0.7 0.00 0.0 0.1 0.1 0.2 0.01 0.01 1 7.0 Max 4.1 0.01 0.1 0.2 0.2 0.7 0.01 0.04 1 9.4 Above Max Guideline - - - - 0 - - 20 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.1 0.00 0.1 0.0 0.2 0.1 0.00 0.01 1 3.0 Median 0.7 0.00 0.2 0.1 0.3 0.1 0.01 0.01 1 3.9 Max 1.4 0.01 0.3 0.1 0.4 0.5 0.01 0.01 2 5.9 Above Max Guideline - - - - 67 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 12 11 11 11 11 12 11 11 11 11 Min 1.0 0.00 0.4 0.1 0.6 0.1 0.01 0.02 3 3.7 Median 3.6 0.02 1.8 0.4 2.6 1.8 0.01 0.08 15 5.1 Max 32.7 0.29 5.1 1.8 6.8 4.0 0.02 0.16 22 7.6 Above Max Guideline - - - - 100 - - 91 - - Below Min Guideline - - - - 0 - - 0 - - n 12 11 11 11 11 12 11 11 11 11 Min 1.1 0.00 0.3 0.1 0.6 0.1 0.00 0.01 4 0.6 Median 2.0 0.01 0.9 0.2 1.0 0.4 0.01 0.02 7 2.1 Max 7.9 0.02 2.2 0.4 2.6 1.0 0.01 0.05 15 6.0 Above Max Guideline - - - - 100 - - 36 - - Below Min Guideline - - - - 0 - - 0 - - n 12 11 11 11 11 12 11 11 11 11 Min 0.7 0.00 0.0 0.1 0.1 0.1 0.00 0.00 3 1.4 Median 4.4 0.01 0.1 0.2 0.3 0.3 0.00 0.01 4 3.2 Max 6.8 0.02 0.3 0.3 0.5 1.7 0.01 0.02 6 6.4 Above Max Guideline - - - - 55 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 12 11 11 11 11 12 11 11 11 11 Min 0.1 0.00 0.0 0.0 0.0 0.1 0.00 0.00 1 3.7 Median 0.6 0.00 0.0 0.1 0.1 0.1 0.00 0.01 1 4.5 Max 6.2 0.01 0.0 0.2 0.2 1.1 0.01 0.01 2 4.9 Above Max Guideline - - - - 0 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - 12 11 11 11 11 12 11 11 11 11 Min 3.4 0.00 0.0 0.4 0.4 0.2 0.00 0.02 2 0.0 Median 18.4 0.05 0.1 0.5 0.7 1.8 0.00 0.04 5 0.6 Max 40.7 0.30 0.4 0.7 1.0 4.1 0.01 0.05 9 2.8 Above Max Guideline - - - - 100 - - 91 - - Below Min Guideline - - - - 0 - - 0 - - Statistic n E332 Silicate Reactive (SiO2 mg/L) Phosphorus Total (mg/L) E083 Phosphorus Filterable (mg/L) 10 0.1 Phaeophytin (ug/L) 10 0.3 Nitrogen Total (mg/L) 10 0.00 Nitrogen TKN (mg/L) 10 0.5 Nitrogen Oxidised (mg/L) 12 Min Lorenzen (ug/L) n Station Code E046 Nitrogen Ammoniacal (mg/L) Table A2 Warragamba system – catchments – nutrients Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 9 E457 E488 E531 E551 Silicate Reactive (SiO2 mg/L) Potassium Filtered (mg/L) E450 Phosphorus Filterable (mg/L) 12 12 12 12 12 0.4 0.1 0.00 0.01 3 0.3 Median 10.7 0.00 0.0 0.6 0.7 0.5 0.01 0.04 5 3.3 Max 28.6 0.24 0.5 0.7 1.0 2.3 0.08 0.12 6 9.2 Above Max Guideline - - - - 100 - - 92 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 1.4 0.00 0.0 0.2 0.3 0.1 0.00 0.00 2 0.5 Median 3.4 0.01 0.0 0.4 0.5 0.3 0.01 0.02 4 3.5 Max 15.4 0.05 0.5 0.9 1.0 3.3 0.02 0.03 6 8.0 Above Max Guideline - - - - 100 - - 42 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.7 0.00 0.0 0.6 0.6 0.1 0.01 0.03 4 0.2 Median 8.5 0.06 0.0 1.1 1.1 1.0 0.03 0.08 7 5.5 Max 48.4 0.59 0.5 3.6 3.6 8.3 0.12 0.25 9 9.2 Above Max Guideline - - - - 100 - - 100 - - Below Min Guideline - - - - 0 - - 0 - - n 12 10 10 10 10 12 10 10 10 10 Min 0.9 0.00 0.0 0.2 0.3 0.1 0.00 0.01 3 1.5 Median 4.1 0.00 0.0 0.4 0.5 0.1 0.00 0.02 4 2.9 Max 7.0 0.02 0.3 0.7 0.7 0.9 0.01 0.05 6 8.3 Above Max Guideline - - - - 100 - - 50 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 1.0 0.00 0.0 0.1 0.1 0.1 0.00 0.00 2 2.5 Median 2.3 0.01 0.0 0.1 0.2 0.3 0.00 0.01 3 4.3 Max 5.7 0.01 0.3 0.4 0.5 1.1 0.01 0.04 4 5.7 Above Max Guideline - - - - 33 - - 25 - - Below Min Guideline - - - - 0 - - 0 - - n 11 9 9 9 9 11 9 9 9 9 Min 0.3 0.00 0.0 0.0 0.0 0.1 0.00 0.01 2 5.4 Median 1.0 0.00 0.0 0.1 0.1 0.1 0.00 0.02 3 6.7 Max 7.2 0.39 0.1 0.6 0.6 0.5 0.01 0.05 5 8.7 Above Max Guideline - - - - 11 - - 56 - - Below Min Guideline - - - - 0 - - 0 - - Statistic Phaeophytin (ug/L) 12 0.4 Nitrogen Total (mg/L) 12 0.0 Nitrogen TKN (mg/L) 12 0.00 Nitrogen Oxidised (mg/L) Phosphorus Total (mg/L) E409 Nitrogen Ammoniacal (mg/L) 12 3.2 Lorenzen (ug/L) 12 Min Station Code n Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 10 10 10 2 0.01 0.01 E046 Median 0.03 0.10 0.08 0.24 3 0.02 0.02 Max 0.06 0.56 0.20 0.95 4 0.04 0.04 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 10 10 10 10 10 10 10 Min 0.01 0.02 0.03 0.07 4 0.00 0.01 Median 0.01 0.05 0.03 0.14 6 0.01 0.03 Max 0.02 0.13 0.06 0.24 8 0.02 0.05 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 10 10 10 10 10 10 10 Min 0.01 0.01 0.03 0.06 2 0.00 0.00 Median 0.01 0.03 0.04 0.10 3 0.00 0.01 Max 0.03 0.18 0.08 0.17 5 0.02 0.03 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.02 0.07 0.13 1 0.01 0.01 Median 0.01 0.05 0.12 0.29 1 0.01 0.01 Max 0.04 0.10 0.31 0.60 2 0.02 0.04 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 11 11 11 11 11 11 11 Min 0.01 0.12 0.03 0.05 5 0.01 0.04 Median 0.05 0.30 0.16 0.31 6 0.05 0.05 Max 0.08 0.89 0.35 0.82 7 0.06 0.07 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 11 11 11 11 11 11 11 Min 0.01 0.02 0.03 0.09 4 0.00 0.01 Median 0.01 0.02 0.08 0.15 6 0.01 0.01 Max 0.09 0.84 0.36 0.88 7 0.02 0.03 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 11 11 11 11 11 11 11 Min 0.01 0.02 0.07 0.21 6 0.00 0.02 Median 0.01 0.05 0.44 0.91 7 0.03 0.05 Max 0.03 0.12 0.80 1.27 11 0.06 0.08 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 11 11 11 11 11 11 11 Min 0.01 0.02 0.05 0.16 2 0.01 0.01 Median 0.01 0.03 0.09 0.30 3 0.02 0.02 Max 0.03 0.07 0.21 0.54 4 0.04 0.05 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 11 11 11 11 11 11 11 Min 0.01 0.07 0.03 0.16 4 0.01 0.04 Median 0.02 0.18 0.09 0.45 6 0.05 0.07 Max 0.11 0.58 0.67 0.78 7 0.35 0.37 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - Statistic n E083 n E130 n E157 n E203 n E206 n E210 n E243 n E332 Manganese Total (mg/L) 10 0.14 Manganese Filtered (mg/L) Magnesium Filtered (mg/L) 10 0.06 Iron Filtered (mg/L) 10 0.03 Aluminium Total (mg/L) 10 0.01 n Aluminium Filtered (mg/L) 10 Min Station Code Iron Total (mg/L) Table A3 Warragamba system – catchments – metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 11 12 0.01 0.03 E409 Median 0.01 0.06 0.04 0.25 33 0.05 0.09 Max 0.04 0.65 0.28 1.50 44 0.14 0.17 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.01 0.03 0.08 11 0.00 0.01 Median 0.01 0.05 0.08 0.23 23 0.01 0.03 Max 0.06 0.51 0.32 1.06 34 0.24 0.26 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.01 0.03 0.14 17 0.04 0.07 Median 0.01 0.09 0.11 0.28 34 0.16 0.20 Max 0.06 0.79 0.30 0.98 36 0.27 0.36 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 10 10 10 10 10 10 10 Min 0.01 0.02 0.03 0.12 9 0.00 0.01 Median 0.01 0.06 0.04 0.17 22 0.01 0.04 Max 0.08 0.52 0.24 0.65 33 0.06 0.10 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.02 0.03 0.66 7 0.03 0.03 Median 0.01 0.07 0.36 1.12 9 0.07 0.08 Max 0.06 0.19 0.73 1.91 11 0.39 0.42 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - n 9 9 9 9 9 9 9 Min 0.01 0.01 0.03 0.06 8 0.01 0.01 Median 0.01 0.01 0.03 0.26 27 0.13 0.15 Max 0.02 0.10 0.30 1.58 41 2.06 2.06 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - Statistic n E450 n E457 n E488 n E531 E551 Manganese Total (mg/L) Magnesium Filtered (mg/L) 12 17 Manganese Filtered (mg/L) Iron Total (mg/L) 12 0.11 Iron Filtered (mg/L) 12 0.03 Aluminium Total (mg/L) 12 0.01 Aluminium Filtered (mg/L) 12 0.01 Station Code 12 Min n Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 12 n E046 E083 E130 E157 E203 E206 E210 E243 E332 Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Cyanobacterial biovolume (mm3/L) Cyanobacteria Total Count (cells/mL) Chlorophyll-a (ug/L) Areal Standard Unit (algae) Algal Total Count (cells/mL) Algal biovolume (mm3/L) Statistic Station Code Table A4 Warragamba system – catchments – cyanobacteria 2 2 2 12 2 2 0 2 2 Min 0.5 2330 577 0.5 <LOR <LOR NA <LOR <LOR Median 1.8 3680 1408 1.8 <LOR <LOR NA <LOR <LOR Max 3.1 5030 2239 18.2 <LOR <LOR NA <LOR <LOR Above Max Guideline - - - 17 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 1 1 1 12 1 1 0 1 1 Min 0.4 697 243 0.4 <LOR <LOR NA <LOR <LOR Median 0.4 697 243 2.4 <LOR <LOR NA <LOR <LOR Max 0.4 697 243 7.1 <LOR <LOR NA <LOR <LOR Above Max Guideline - - - 8 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.3 NA NA NA NA NA Median NA NA NA 0.8 NA NA NA NA NA Max NA NA NA 4.5 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.2 NA NA NA NA NA Median NA NA NA 0.5 NA NA NA NA NA Max NA NA NA 1.3 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 7 7 7 12 7 7 0 7 7 Min 0.0 256 37 1.3 <LOR <LOR NA <LOR <LOR Median 0.5 1130 521 5.5 569 0.04 NA <LOR <LOR Max 1.5 22650 1435 35.7 19180 0.80 NA 0.005 219 Above Max Guideline - - - 58 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 1 1 1 12 1 1 0 1 1 Min 0.7 4550 781 1.1 <LOR <LOR NA <LOR <LOR Median 0.7 4550 781 2.5 <LOR <LOR NA <LOR <LOR Max 0.7 4550 781 8.7 <LOR <LOR NA <LOR <LOR Above Max Guideline - - - 8 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 6 6 6 12 6 6 0 6 6 Min 0.5 2150 517 0.6 <LOR <LOR NA <LOR <LOR Median 0.8 3850 885 4.9 151 <LOR NA <LOR <LOR Max 1.4 11120 2477 7.5 427 0.00 NA <LOR <LOR Above Max Guideline - - - 50 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 1 1 1 12 1 1 0 1 1 Min 1.9 5260 1591 0.1 <LOR <LOR NA <LOR <LOR Median 1.9 5260 1591 0.5 <LOR <LOR NA <LOR <LOR Max 1.9 5260 1591 7.0 <LOR <LOR NA <LOR <LOR Above Max Guideline - - - 8 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 10 10 10 12 10 10 3 10 10 Min 0.7 5650 715 4.1 <LOR <LOR 0.15 <LOR <LOR Median 4.1 29360 2951 20.7 12820 0.09 0.35 0.008 236 Max 14.8 82170 8864 43.3 39560 0.88 1.4 0.842 28250 Above Max Guideline - - - 92 - 0 0 - 0 Below Min Guideline - - - 0 - 0 0 - 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 13 E457 E488 E531 E551 Toxic Cyanobacterial Count (cells/mL) Microcystin LR equiv (ug/L) 12 10 10 0 10 10 668 3.1 48 <LOR NA <LOR <LOR Median 1.8 11810 1442 11.2 885.5 0.01 NA <LOR <LOR Max 3.7 33760 6685 30.4 13590 0.20 NA 0.166 1110 Above Max Guideline - - - 83 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 5 5 5 12 5 5 0 5 5 Min 0.0 1250 52 1.6 <LOR <LOR NA <LOR <LOR Median 2.0 1540 744 3.9 436 0.00 NA <LOR <LOR Max 2.5 17470 3792 17.8 1340 0.03 NA <LOR 14 Above Max Guideline - - - 42 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 9 9 9 12 9 9 3 9 9 Min 0.3 1450 264 0.4 492 0.00 0.33 <LOR <LOR Median 3.9 9780 2022 9.0 1450 0.05 0.34 0.042 618 Max 7.2 28080 16650 55.2 19420 0.53 3.98 0.518 16270 Above Max Guideline - - - 75 - 0 0 - 0 Below Min Guideline - - - 0 - 0 0 - 0 n 5 5 5 12 5 5 0 5 5 Min 1.8 5290 1171 0.9 633 <LOR NA <LOR <LOR Median 3.2 25280 1914 4.5 15930 0.03 NA <LOR <LOR Max 7.6 37200 2366 7.4 30560 0.09 NA <LOR <LOR Above Max Guideline - - - 42 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 2 2 2 12 2 2 0 2 2 Min 0.5 1730 383 0.9 534 <LOR NA <LOR <LOR Median 0.8 1750 400 2.4 548 <LOR NA <LOR <LOR Max 1.1 1770 416 6.3 562 <LOR NA <LOR <LOR Above Max Guideline - - - 17 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 1 1 1 11 1 1 0 1 1 Min 1.3 1380 456 0.1 223 0.00 NA <LOR <LOR Median 1.3 1380 456 0.7 223 0.00 NA <LOR <LOR Max 1.3 1380 456 7.2 223 0.00 NA <LOR <LOR Above Max Guideline - - - 9 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 Statistic Toxic Cyanobacterial biovolume (mm3/L) 10 2720 Cyanobacterial biovolume (mm3/L) Cyanobacteria Total Count (cells/mL) E450 Areal Standard Unit (algae) Chlorophyll-a (ug/L) E409 Algal Total Count (cells/mL) 10 0.8 Algal biovolume (mm3/L) 10 Min Station Code n Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 14 Coliforms Thermotolerant (cfu/100mL) Coliforms Total (cfu/100mL) E. coli (orgs/100mL) Enterococci (orgs/100ml) n 12 12 0 12 12 Min 7 27 NA 17 7 Median 38 56 NA 122 55 Max E046 E083 E130 E157 E203 E206 E210 E243 E332 Statistic Station Code Clostridium Perfringens Lamp Method Table A5 Warragamba system – catchments – pathogens 600 3100 NA 2400 660 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 2 NA 1 2 Median 4 16 NA 12 22 Max 13 88 NA 130 79 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 1 NA 3 4 Median 1 20 NA 20 13 Max 14 36 NA 50 88 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 7 NA 6 12 Median 6 30 NA 37 73 110 420 NA 220 520 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 31 38 NA 37 11 Median 76 220 NA 310 55 2100 49000 NA 23000 4300 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 5 NA 1 6 Median 7 46 NA 53 24 Max Max Max 70 1800 NA 2400 2300 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 3 NA 3 1 Median 3 17 NA 15 15 Max 8 170 NA 100 110 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 1 NA 1 1 Median 1 5 NA 7 14 Max 20 62 NA 81 71 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 2 3 NA 2 1 Median 9 15 NA 12 7 Max 24 110 NA 120 58 Above Max Guideline - - - - - Below Min Guideline - - - - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 15 Clostridium Perfringens Lamp Method Coliforms Thermotolerant (cfu/100mL) Coliforms Total (cfu/100mL) E. coli (orgs/100mL) Enterococci (orgs/100ml) 11 12 0 12 12 Min 1 13 NA 8 2 Median 4 37 NA 51 24 Max E409 E450 E457 E488 E531 E551 Statistic Station Code n 27 94 NA 130 67 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 3 NA 2 2 Median 4 20 NA 35 20 Max 13 660 NA 1200 100 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 1 NA 11 3 Median 4 39 NA 51 14 Max 23 260 NA 520 280 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 1 NA 1 1 Median 1 16 NA 9 27 Max 7 78 NA 140 58 Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 12 Min 1 12 NA 11 17 Median 4 51 NA 39 59 Max 16 130 NA 120 340 Above Max Guideline - - - - - Below Min Guideline - - - - - n 11 11 0 11 11 Min 1 1 NA 1 1 Median 1 15 NA 13 3 Max 1 80 NA 93 76 Above Max Guideline - - - - - Below Min Guideline - - - - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 16 E083 E130 E157 E203 E210 E243 E488 E531 Giardia IFA /10L Adj for Recovery Crypto IFA /10L Adj for Recovery Statistic Station Code Table A6 Warragamba system – catchments – Cryptosporidium and Giardia n 12 12 % <LOR 100 100 Min* NA NA Median* NA NA Max* NA NA N 12 12 % <LOR 92 83 Min* 1 2 Median* 1 3 Max* 1 3 N 12 12 % <LOR 83 92 Min* 2 5 Median* 2 5 Max* 2 5 N 12 12 % <LOR 25 0 Min* 2 19 Median* 4 44 Max* 62 253 N 12 12 % <LOR 100 100 Min* NA NA Median* NA NA Max* NA NA N 12 12 % <LOR 92 100 Min* 3 NA Median* 3 NA Max* 3 NA N 12 12 % <LOR 83 92 Min* 2 2 Median* 3 2 Max* 3 2 N 50 50 % <LOR 98 96 Min* 5 2 Median* 5 2 Max* 5 2 * detection samples only Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 17 A1.2 Storages Total Organic Carbon (mg/L) True Colour at 400nm True Colour at 420nm 29 25 25 25 25 29 25 <LOR 13.1 31 5.1 10 21 <LOR 0.14 DWA12 Median 34.0 8 23.5 0.18 6.4 90.5 7.7 7.7 15.5 2 19.2 43 6.6 13 28 1.6 0.17 Max 42.0 10 35.5 0.20 10.7 106.0 9.9 8.2 19.0 5 25.6 50 10.8 23 49 3.2 0.21 Above Max Guideline - - - - - 0 - 17 - - - - - - - 0 - Below Min Guideline - - - - - 46 - 0 - - - - - - - 0 - n 6 6 6 7 6 7 7 7 6 6 7 6 6 6 6 7 6 Min 32.3 8 16.0 0.16 5.0 69.2 7.0 7.3 14.5 1 13.5 40 4.8 10 24 0.4 0.14 Median 36.3 9 25.3 0.17 6.8 95.2 7.8 7.7 16.0 3 19.0 43 6.7 12 27 1.8 DWA15 0.18 Max 37.5 10 26.5 0.19 7.2 105.7 9.5 8.5 18.0 3 26.9 50 7.0 18 40 2.7 0.20 Above Max Guideline - - - - - 0 - 14 - - - - - - - 0 - Below Min Guideline - - - - - 43 - 0 - - - - - - - 0 - n 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 DWA19 Min 30.0 8 14.0 0.15 4.9 75.4 7.3 7.4 13.5 2 14.0 40 5.0 10 21 1.9 0.14 Median 36.5 8 24.5 0.17 5.8 86.6 7.8 7.6 15.8 3 20.6 41 5.9 14 30 3.1 0.17 Max 38.0 10 30.0 0.19 6.7 101.7 8.0 8.4 18.5 4 27.5 48 6.8 19 42 3.4 0.20 Above Max Guideline - - - - - 0 - 17 - - - - - - - 0 - Below Min Guideline - - - - - 50 - 0 - - - - - - - 0 - 25 25 25 40 25 40 40 39 25 25 40 25 25 25 25 40 25 Min 30.0 5 15.0 0.16 5.2 70.8 7.1 7.0 13.0 <LOR 13.3 29 5.2 9 22 <LOR 0.14 Median 34.0 8 23.5 0.17 6.5 88.8 7.9 7.6 15.0 1 16.5 40 6.5 14 30 1.5 0.17 Max 40.0 10 31.5 0.20 11.1 105.0 10.0 8.3 20.0 3 24.2 50 11.2 20 46 4.9 0.23 Above Max Guideline - - - - - 0 - 5 - - - - - - - 0 - Below Min Guideline - - - - - 53 - 0 - - - - - - - 0 - n 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 Min 31.0 8 14.0 0.15 5.7 75.1 7.3 7.4 12.5 2 14.2 40 5.8 10 24 1.4 0.14 Median 37.0 9 24.3 0.17 6.0 90.3 7.8 7.6 15.8 3 20.8 43 6.0 12 26 2.5 0.17 Max 40.0 10 29.0 0.19 6.8 105.0 8.7 8.5 19.0 4 27.7 50 6.8 18 40 3.5 0.19 Above Max Guideline - - - - - 0 - 33 - - - - - - - 0 - Below Min Guideline - - - - - 50 - 0 - - - - - - - 0 - 25 25 25 29 25 28 28 29 25 25 29 25 25 25 25 29 25 Min 32.7 7 19.0 0.17 5.4 72.1 6.9 7.3 14.0 <LOR 13.1 38 5.4 10 21 <LOR 0.14 Median 36.0 9 25.0 0.19 6.9 89.7 7.8 7.7 16.0 1 19.2 45 6.9 13 28 1.8 0.18 Max 43.0 11 32.5 0.20 11.4 113.7 9.4 8.4 20.0 4 25.7 51 11.3 21 46 3.9 0.23 Above Max Guideline - - - - - 4 - 21 - - - - - - - 0 - Below Min Guideline - - - - - 50 - 0 - - - - - - - 0 - n 6 6 6 8 6 8 8 8 6 6 8 6 6 6 6 8 6 Min 34.0 8 20.0 0.18 6.1 72.3 7.2 7.4 14.0 2 13.4 42 6.3 10 21 1.4 0.15 Median 36.3 9 28.0 0.19 6.8 84.8 8.0 7.6 16.3 2 17.4 46 7.0 14 30 2.0 0.18 Max 44.5 12 32.5 0.21 8.4 103.7 8.7 8.3 18.5 5 25.7 58 8.3 22 48 2.8 0.23 Above Max Guideline - - - - - 0 - 13 - - - - - - - 0 - Below Min Guideline - - - - - 63 - 0 - - - - - - - 0 - n 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 Statistic n DWA2 DWA21 n DWA27 DWA311 DWA39 Min 34.0 8 22.0 0.18 6.1 80.1 7.5 7.6 15.5 2 14.1 40 6.0 10 22 2.4 0.17 Median 38.0 10 29.5 0.20 7.1 90.4 8.1 7.7 16.8 3 19.5 49 7.2 14 30 3.4 0.19 Max 47.0 11 31.0 0.22 9.6 105.5 9.3 8.3 18.0 4 26.8 56 9.5 23 51 3.7 0.24 Above Max Guideline - - - - - 0 - 17 - - - - - - - 0 - Below Min Guideline - - - - - 50 - 0 - - - - - - - 0 - 25 25 25 29 25 29 29 29 25 25 29 25 25 25 25 29 25 Min 28.5 7 16.5 0.16 5.3 64.7 6.8 7.3 13.0 <LOR 13.2 33 5.2 10 21 <LOR 0.15 Median 33.5 8 25.0 0.18 6.8 90.2 8.0 7.7 15.0 2 18.0 40 6.9 13 29 1.3 0.17 Max 41.0 10 34.0 0.20 10.3 100.9 9.5 8.0 19.5 5 24.5 50 10.6 25 56 13.5 0.22 Above Max Guideline - - - - - 0 - 3 - - - - - - - 0 - Below Min Guideline - - - - - 48 - 0 - - - - - - - 0 - n DWA9 UV Absorbing constituents (organic) Total Hardness (mgCaCO3/L) 25 13.0 Turbidity (NTU) Temperature (Deg C) 25 7.3 Suspended Solids (mg/L) 29 6.9 Sodium Filtered (mg/L) 28 66.5 pH 28 5.3 Dissolved Oxygen (mg/L) 25 0.16 Dissolved Oxygen (%Sat) 29 19.0 Dissolved Organic Carbon (mg/L) 25 6 Conductivity Field (mS/cm) 25 30.3 n Chloride (mg/L) Calcium Filtered (mg/L) 25 Min Station Code Alkalinity (mgCaCO3/L) Table A7 Warragamba system – storages – physico-chemical Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 18 Temperature (Deg C) Total Hardness (mgCaCO3/L) Total Organic Carbon (mg/L) True Colour at 400nm True Colour at 420nm 12 103 12 12 12 12 12 12 24.5 1 12.8 36 3.2 2 4 <LOR 0.05 RPR1 Median 28.3 7 41.8 0.22 3.7 98.1 8.9 7.8 27.0 3 19.8 40 3.8 2 5 1.2 0.06 Max 30.5 8 44.0 0.23 5.3 105.1 10.3 8.3 32.0 4 26.5 45 5.3 4 8 1.7 0.07 Above Max Guideline - - - - - 0 - 8 - - - - - - - 0 - Below Min Guideline - - - - - 0 - 0 - - - - - - - 0 - n 6 6 6 7 6 7 7 7 6 6 103 6 6 6 6 7 6 Min 28.0 6 39.5 0.20 3.3 95.4 8.3 7.7 26.5 2 12.0 38 3.3 2 4 1.3 0.05 Median 28.5 8 41.8 0.22 3.8 99.9 8.7 7.8 28.8 5 20.1 44 3.6 2 6 2.7 RPR6 0.07 Max 30.0 10 44.0 0.23 5.8 100.9 10.2 7.9 32.5 29 26.8 47 6.4 4 7 4.9 0.08 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 0 - 0 - - - - - - - 0 - Statistic Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 19 UV Absorbing constituents (organic) Suspended Solids (mg/L) 12 7.6 Turbidity (NTU) Sodium Filtered (mg/L) 12 8.1 pH 12 91.7 Dissolved Oxygen (mg/L) 12 3.1 Dissolved Oxygen (%Sat) 12 0.20 Dissolved Organic Carbon (mg/L) 12 38.5 Conductivity Field (mS/cm) Calcium Filtered (mg/L) 12 6 Chloride (mg/L) Alkalinity (mgCaCO3/L) 12 25.0 Station Code 12 Min n Potassium Filtered (mg/L) DWA19 DWA2 DWA21 DWA27 DWA311 DWA39 DWA9 Silicate Reactive (SiO2 mg/L) Phosphorus Total (mg/L) DWA15 Phosphorus Filterable (mg/L) 25 25 25 25 25 25 0.21 0.27 <LOR <LOR <LOR 2 0.8 Median 3.2 <LOR 0.12 0.27 0.40 <LOR 0.00 0.01 3 1.9 Max 6.0 0.02 0.24 0.31 0.51 0.7 0.01 0.02 4 4.4 Above Max Guideline - - - - 80 - - 40 - - Below Min Guideline - - - - 0 - - 0 - - n 6 6 6 6 6 6 6 6 6 6 Min 3.5 <LOR 0.03 0.24 0.29 <LOR 0.00 0.01 3 0.7 Median 4.4 0.01 0.10 0.28 0.37 0.1 0.01 0.01 3 2.2 Max 11.7 0.01 0.20 0.32 0.52 0.5 0.01 0.01 3 3.9 Above Max Guideline - - - - 50 - - 17 - - Below Min Guideline - - - - 0 - - 0 - - n 6 6 6 6 6 6 6 6 6 6 Min 4.8 <LOR <LOR 0.27 0.30 <LOR <LOR 0.01 2 0.5 Median 8.4 0.00 0.06 0.29 0.34 0.2 0.00 0.01 3 1.7 Max 9.3 0.02 0.18 0.32 0.48 0.8 0.00 0.01 3 3.7 Above Max Guideline - - - - 50 - - 67 - - Below Min Guideline - - - - 0 - - 0 - - n 25 25 25 25 25 25 25 25 25 25 Min 2.0 <LOR 0.02 0.21 0.32 <LOR 0.00 <LOR 2 0.9 Median 3.5 0.00 0.17 0.27 0.42 0.1 0.00 0.01 3 2.3 Max 6.3 0.03 0.30 0.39 0.53 0.8 0.01 0.02 4 3.8 Above Max Guideline - - - - 92 - - 32 - - Below Min Guideline - - - - 0 - - 0 - - n 6 6 6 6 6 6 6 6 6 6 Min 4.1 <LOR 0.01 0.24 0.29 <LOR <LOR 0.01 2 0.5 Median 7.9 0.00 0.05 0.30 0.34 0.3 0.00 0.01 3 1.7 Max 13.1 0.02 0.18 0.51 0.69 1.2 0.01 0.01 3 3.7 Above Max Guideline - - - - 33 - - 50 - - Below Min Guideline - - - - 0 - - 0 - - n 25 25 25 25 25 25 25 25 25 25 Min 1.7 <LOR 0.03 0.21 0.28 <LOR <LOR <LOR 2 0.7 Median 3.0 <LOR 0.13 0.28 0.40 <LOR 0.00 0.01 3 1.7 Max 7.0 0.02 0.29 0.33 0.55 0.4 0.01 0.01 4 4.2 Above Max Guideline - - - - 80 - - 32 - - Below Min Guideline - - - - 0 - - 0 - - n 6 6 6 6 6 6 6 6 6 6 Min 2.0 <LOR 0.03 0.29 0.32 <LOR 0.00 <LOR 2 0.4 Median 5.3 <LOR 0.10 0.31 0.41 0.1 0.00 0.01 3 1.3 Max 6.5 0.01 0.22 0.34 0.55 0.6 0.01 0.01 3 3.6 Above Max Guideline - - - - 67 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 6 6 6 6 6 6 6 6 6 6 Min 7.1 <LOR 0.01 0.30 0.32 <LOR 0.00 0.01 2 0.2 Median 8.1 <LOR 0.08 0.34 0.41 0.2 0.00 0.01 3 1.1 Max 8.6 0.03 0.20 0.37 0.57 0.5 0.01 0.02 3 3.2 Above Max Guideline - - - - 83 - - 50 - - Below Min Guideline - - - - 0 - - 0 - - n 25 25 25 25 25 25 25 25 25 25 Min 2.0 <LOR 0.05 0.23 0.31 <LOR <LOR <LOR 2 0.9 Median 2.9 <LOR 0.15 0.28 0.43 <LOR 0.00 0.01 3 2.1 Max 6.8 0.02 0.25 0.33 0.50 0.5 0.01 0.02 4 4.2 Above Max Guideline - - - - 84 - - 32 - - Below Min Guideline - - - - 0 - - 0 - - Statistic Phaeophytin (ug/L) 25 0.05 Nitrogen Total (mg/L) 25 <LOR Nitrogen TKN (mg/L) 25 1.8 Nitrogen Oxidised (mg/L) 25 Min Lorenzen (ug/L) n Station Code DWA12 Nitrogen Ammoniacal (mg/L) Table A8 Warragamba system – storages – nutrients Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 20 Silicate Reactive (SiO2 mg/L) Potassium Filtered (mg/L) RPR6 Phosphorus Filterable (mg/L) 12 12 12 12 12 0.19 <LOR 0.00 <LOR 2 0.1 Median 3.8 0.00 0.02 0.21 0.23 0.1 0.00 0.01 2 0.4 Max 5.6 0.02 0.04 0.27 0.28 0.4 0.01 0.03 2 0.7 Above Max Guideline - - - - 0 - - 25 - - Below Min Guideline - - - - 0 - - 0 - - n 6 6 6 6 6 6 6 6 6 6 Min 2.3 <LOR 0.00 0.20 0.20 <LOR <LOR 0.00 2 0.1 Median 4.4 <LOR 0.01 0.22 0.24 <LOR 0.00 0.01 2 0.4 Max 6.1 0.01 0.04 0.28 0.29 0.2 0.00 0.01 2 0.7 Above Max Guideline - - - - 0 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - Statistic Phaeophytin (ug/L) 12 0.16 Nitrogen Total (mg/L) 12 <LOR Nitrogen TKN (mg/L) 12 <LOR Nitrogen Oxidised (mg/L) Phosphorus Total (mg/L) RPR1 Nitrogen Ammoniacal (mg/L) 12 2.0 Lorenzen (ug/L) 12 Min Station Code n Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 21 n DWA12 DWA15 DWA19 DWA21 DWA311 DWA39 Manganese Total (mg/L) Manganese Filtered (mg/L) Magnesium Filtered (mg/L) Iron Total (mg/L) 25 25 25 25 25 0.01 <LOR <LOR 4.0 <LOR 0.00 Median 0.01 0.03 0.08 0.13 5.0 0.00 0.00 Max 0.02 0.14 0.13 0.25 6.0 0.00 0.02 Above Max Guideline - 28 - - - - 0 Below Min Guideline - 0 - - - - 0 n 6 6 6 6 6 6 6 Min <LOR 0.01 <LOR 0.03 5.0 <LOR 0.00 Median 0.00 0.04 0.07 0.14 5.3 0.00 0.01 Max 0.02 0.10 0.15 0.21 6.0 0.00 0.02 Above Max Guideline - 33 - - - - 0 Below Min Guideline - 0 - - - - 0 n 6 6 6 6 6 6 6 Min <LOR 0.03 <LOR 0.10 5.0 <LOR 0.01 Median <LOR 0.04 0.09 0.20 5.0 0.00 0.01 Max 0.02 0.08 0.14 0.28 5.5 0.01 0.02 Above Max Guideline - 33 - - - - 0 Below Min Guideline - 0 - - - - 0 25 25 25 25 25 25 25 Min <LOR <LOR <LOR <LOR 4.0 <LOR 0.00 Median 0.01 0.03 0.08 0.11 5.0 <LOR 0.00 Max 0.02 0.10 0.12 0.20 6.0 0.00 0.01 Above Max Guideline - 32 - - - - 0 Below Min Guideline - 0 - - - - 0 n 6 6 6 6 6 6 6 Min <LOR 0.01 <LOR 0.09 5.0 <LOR 0.01 Median 0.01 0.03 0.09 0.16 5.0 0.00 0.01 Max 0.02 0.09 0.14 0.24 6.0 0.01 0.02 Above Max Guideline - 17 - - - - 0 Below Min Guideline - 0 - - - - 0 25 25 25 25 25 25 25 Min <LOR 0.01 <LOR <LOR 5.0 <LOR 0.00 Median <LOR 0.03 0.07 0.09 6.0 0.00 0.00 Max 0.03 0.13 0.15 0.25 6.0 0.01 0.01 Above Max Guideline - 36 - - - - 0 Below Min Guideline - 0 - - - - 0 n 6 6 6 6 6 6 6 Min <LOR 0.01 <LOR <LOR 5.3 <LOR 0.00 Median 0.01 0.04 0.07 0.11 5.8 <LOR 0.01 Max 0.03 0.10 0.17 0.31 7.0 0.00 0.02 Above Max Guideline - 33 - - - - 0 Below Min Guideline - 0 - - - - 0 n 6 6 6 6 6 6 6 Min <LOR 0.02 <LOR 0.07 5.0 <LOR 0.01 Median 0.01 0.05 0.11 0.22 6.0 0.00 0.01 Max 0.02 0.10 0.15 0.28 7.0 0.00 0.03 Above Max Guideline - 33 - - - - 0 Below Min Guideline - 0 - - - - 0 25 25 25 25 25 25 25 Min <LOR 0.01 <LOR <LOR 4.0 <LOR 0.00 Median 0.01 0.03 0.07 0.10 5.0 0.00 0.00 Max 0.03 0.11 0.16 0.21 6.0 0.00 0.01 Above Max Guideline - 32 - - - - 0 Below Min Guideline - 0 - - - - 0 n DWA9 Iron Filtered (mg/L) 25 <LOR n DWA27 Aluminium Total (mg/L) 25 Min n DWA2 Aluminium Filtered (mg/L) Statistic Station Code Table A9 Warragamba system – storages – metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 22 RPR1 RPR6 Manganese Total (mg/L) Manganese Filtered (mg/L) Magnesium Filtered (mg/L) Iron Total (mg/L) Iron Filtered (mg/L) Aluminium Total (mg/L) Aluminium Filtered (mg/L) Statistic Station Code n 12 12 12 12 12 12 12 Min <LOR 0.02 <LOR <LOR 5.0 <LOR 0.01 Median 0.01 0.05 <LOR 0.04 6.0 <LOR 0.01 Max 0.02 0.09 0.19 0.10 6.0 0.00 0.03 Above Max Guideline - 42 - - - - 0 Below Min Guideline - 0 - - - - 0 n 6 6 6 6 6 6 6 Min <LOR 0.03 <LOR <LOR 5.0 <LOR 0.01 Median 0.01 0.10 <LOR 0.12 6.0 0.00 0.01 Max 0.02 0.27 <LOR 0.28 6.0 0.00 0.03 Above Max Guideline - 83 - - - - 0 Below Min Guideline - 0 - - - - 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 23 n DWA12 DWA15 DWA19 DWA21 DWA27 DWA311 DWA39 DWA9 Toxic Total Algal Count Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Cyanobacterial biovolume (mm3/L) Chlorophyll-a (ug/L) Areal Standard Unit (algae) Algal Total Count (cells/mL) 2 2 2 25 2 2 2 2 2 Min 2.16 4130 738 1.9 0.005 <LOR 0.01 114 544 Median 2.59 9060 907 3.3 0.023 <LOR 0.02 1202 1562 Max 3.02 13990 1076 6.1 0.040 <LOR 0.04 2290 2580 Above Max Guideline - - - 8 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - n 3 3 3 6 3 0 3 3 3 104 Min 1.02 8700 786 3.4 0.001 NA <LOR <LOR Median 1.69 38300 1230 4.7 0.026 NA <LOR <LOR 579 Max 7.95 185500 2031 11.7 0.133 NA 0.01 429 2820 Above Max Guideline - - - 50 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - n 6 6 6 6 6 1 6 6 6 Min 0.81 3610 559 5.1 0.001 <LOR <LOR <LOR 34 Median 2.97 47585 1623 9.2 0.029 <LOR <LOR <LOR 179 Max 10.51 79210 2497 10.1 0.089 <LOR 0.07 3930 5530 Above Max Guideline - - - 100 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - 24 24 24 25 24 0 24 24 24 Min 0.31 1510 201 2.5 <LOR NA <LOR <LOR <LOR Median 1.10 7390 501 3.6 0.012 NA 0.00 121 311 Max 6.06 125000 3656 6.6 0.086 NA 0.02 1240 1290 Above Max Guideline - - - 16 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - n 5 5 5 6 5 1 5 5 5 Min 0.91 41810 574 4.4 0.018 <LOR <LOR <LOR 29 Median 3.89 43570 1865 8.6 0.032 <LOR <LOR <LOR 684 Max n DWA2 Algal biovolume (mm3/L) Statistic Station Code Table A10 Warragamba system – storages – cyanobacteria 20.43 107100 5072 13.5 0.148 <LOR 0.13 6230 6230 Above Max Guideline - - - 83 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - n 4 4 4 25 4 1 4 4 4 Min 0.24 6250 209 1.9 0.001 <LOR <LOR 20 29 Median 1.60 25915 728 2.9 0.012 <LOR 0.00 35 267 Max 2.73 66430 826 6.9 0.096 <LOR 0.01 385 1430 Above Max Guideline - - - 12 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - n 4 4 4 6 4 1 4 4 4 Min 0.87 14960 358 1.9 0.014 <LOR <LOR <LOR 163 Median 1.20 29245 739 5.6 0.028 <LOR 0.01 82 242 Max 2.52 129500 1008 6.7 0.144 <LOR 0.02 207 1370 Above Max Guideline - - - 67 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - n 6 6 6 6 6 2 6 6 6 236 Min 1.37 5550 767 7.6 0.011 <LOR <LOR 56 Median 2.34 53605 1289 8.7 0.081 <LOR 0.02 656 992 Max 6.32 137300 2485 9.2 0.154 <LOR 0.15 4820 5110 Above Max Guideline - - - 100 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - n 6 6 6 25 6 1 6 6 6 Min 0.29 2870 255 2.0 <LOR <LOR <LOR <LOR 29 Median 1.52 5875 602 3.0 0.010 <LOR <LOR 29 801 Max 3.60 37240 1182 6.6 0.036 <LOR 0.03 2250 2250 Above Max Guideline - - - 12 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 24 35 <LOR <LOR RPR1 Median 0.95 86010 620 3.8 0.035 <LOR <LOR <LOR <LOR Max 2.83 470200 1864 6.4 0.196 <LOR 0.02 858 858 Above Max Guideline - - - 18 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - 36 36 36 36 36 35 36 36 36 Statistic n RPR6 Toxic Total Algal Count 35 <LOR Toxic Cyanobacterial Count (cells/mL) 35 <LOR Toxic Cyanobacterial biovolume (mm3/L) 35 <LOR Microcystin LR equiv (ug/L) 35 <LOR Cyanobacterial biovolume (mm3/L) Areal Standard Unit (algae) 38 92 Chlorophyll-a (ug/L) Algal Total Count (cells/mL) 35 3580 Algal biovolume (mm3/L) 35 0.22 Station Code 35 Min n Min 0.19 1060 159 <LOR <LOR <LOR <LOR <LOR <LOR Median 0.93 86660 593 4.5 0.046 <LOR <LOR <LOR <LOR Max 4.76 501300 2116 10.0 0.226 <LOR 0.08 1320 1320 Above Max Guideline - - - 39 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 25 n DWA12 DWA19 1 <LOR <LOR Median <LOR <LOR NA <LOR <LOR Max 1 1 NA 1 <LOR Above Max Guideline - - - - - Below Min Guideline - - - - - n 6 6 0 6 0 <LOR <LOR NA <LOR NA Median 0 0 NA 1 NA Max 2 2 NA 1 NA Above Max Guideline - - - - - Below Min Guideline - - - - - n 6 6 0 6 0 Min 1 <LOR NA 1 NA Median 3 2 NA 1 NA Max 6 4 NA 5 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 25 25 0 25 0 <LOR <LOR NA <LOR NA Median 1 <LOR NA 1 NA Max 3 3 NA 4 NA Above Max Guideline - - - - - Below Min Guideline - - - - - n 6 6 0 6 0 <LOR <LOR NA <LOR NA Median 0 1 NA 1 NA Max 2 2 NA 2 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 25 25 0 25 1 Min <LOR <LOR NA <LOR <LOR Median <LOR <LOR NA <LOR <LOR Max 1 20 NA 2 <LOR Above Max Guideline - - - - - Below Min Guideline - - - - - n 6 6 0 6 0 Min <LOR <LOR NA <LOR NA Median <LOR <LOR NA 1 NA Max <LOR <LOR NA 2 NA Above Max Guideline - - - - - Below Min Guideline - - - - - n 6 6 0 6 0 Min <LOR <LOR NA <LOR NA Median <LOR <LOR NA <LOR NA Max 2 1 NA 1 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 25 25 0 25 1 Min <LOR <LOR NA <LOR <LOR Median <LOR <LOR NA <LOR <LOR Max 2 1 NA 1 <LOR Above Max Guideline - - - - - Below Min Guideline - - - - - n DWA311 DWA39 n DWA9 Enterococci (cfu/100ml) 25 NA Min DWA27 E. coli (orgs/100mL) 0 <LOR Min DWA21 Coliforms Total (cfu/100mL) 25 <LOR n DWA2 Coliforms Thermotolerant (cfu/100mL) 25 Min Min DWA15 Clostridium Perfringens Lamp Method Statistic Station Code Table A11 Warragamba system – storages – pathogens Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 26 Coliforms Thermotolerant (cfu/100mL) Coliforms Total (cfu/100mL) E. coli (orgs/100mL) 12 0 12 1 1 1 NA 1 5.5 RPR1 RPR6 Statistic Enterococci (cfu/100ml) Clostridium Perfringens Lamp Method 12 Min Station Code n Median 7 4 NA 3 5.5 Max 17 132 NA 107 5.5 Above Max Guideline - - - - - Below Min Guideline - - - - - n 6 6 0 6 0 Min 31 37 NA 27 NA Median 54 85 NA 92 NA Max 245 300 NA 445 NA Above Max Guideline - - - - - Below Min Guideline - - - - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 27 Table A12 Warragamba system – storages – heavy metals Giardia IFA /10L Adj for Recovery n 310 310 % <LOR 98 99 Min* 1 2 Median* 3 2 Max* 4 3 N 103 103 % <LOR 99 98 Min* 2 1 Median* 2 2 Max* 2 3 N 103 103 % <LOR 96 97 Min* 1 1 Median* 2 1 Max* 3 3 DWA2 RPR1 RPR6 Statistic Station Code Crypto IFA /10L Adj for Recovery Table A13 Warragamba system – storages – Cryptosporidium and Giardia * detection samples only Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 28 A1.3 Water filtration plants True Colour at 400nm True Colour at 420nm 13 13 13 13 13 13 13.5 31 5 11 25 2.2 0.145 HWA2 Median 32 0.173 6.5 59.8 5.9 7.09 14.6 40 6.1 18 40 3.2 0.207 Max 52 0.234 10 97.2 9.7 9.8 16.7 50 9.2 23 47 9.7 0.227 Above Max Guideline 0 - - - - - - 0 - 0 - 0 - Below Min Guideline 0 - - - - - - 0 - 0 - 0 - n 12 13 12 12 12 13 13 12 12 11 11 13 12 Min 28 0.128 5.6 37.5 3.8 5.81 12.4 36 5.5 11 21 1.8 0.16 Median 30 0.173 6.2 52.75 5.3 6.9 13.4 40 5.95 13 30 3.5 0.181 HBR1 Max 37 0.177 7.2 109 10.7 7.29 14.8 50 7 16 35 4.3 0.201 Above Max Guideline 0 - - - - - - 0 - 0 - 0 - Below Min Guideline 0 - - - - - - 0 - 0 - 0 - n 13 13 13 13 13 13 13 13 13 13 13 13 13 Min 17 0.016 5.3 90.3 8.73 6.9 13.5 31 5.2 8 16 <LOR 0.118 Median 26 0.161 5.8 106.3 10.74 7.2 15 38 5.6 12 27 1.3 PWFP10 0.169 Max 32 0.18 7.6 118.4 11.43 7.4 17.8 50 7.3 17 50 2.4 0.206 Above Max Guideline 0 - - - - - - 0 - 0 - 0 - Below Min Guideline 0 - - - - - - 0 - 0 - 0 - Statistic UV Absorbing constituents (organic) Total Organic Carbon (mg/L) 13 6.34 Turbidity (NTU) Total Hardness (mgCaCO3/L) 13 3.8 pH 13 38.2 Dissolved Oxygen (mg/L) 13 4.8 Dissolved Oxygen (%Sat) 13 0.165 Dissolved Organic Carbon (mg/L) 13 31 Conductivity (mS/cm) 13 Min Alkalinity (mgCaCO3/L) n Station Code Temperature (Deg C) Table A14 Warragamba system – water filtration plants - physico-chemical n HWA2 Manganese Total (mg/L) Manganese Filtered (mg/L) Iron Total (mg/L) Iron Filtered (mg/L) 13 13 13 13 13 <LOR 0.04 <LOR 0.1 <LOR 0.006 Median 0.02 0.14 0.11 0.24 0.002 0.009 Max 0.03 0.43 0.13 0.65 0.015 0.061 Above Max Guideline - 0 - 0 - 0 Below Min Guideline - 0 - 0 - 0 12 12 12 12 12 12 Min 0.01 0.08 0.09 0.18 <LOR 0.006 Median 0.02 0.125 0.115 0.22 0.004 0.009 Max 0.03 0.21 0.15 0.34 0.022 0.036 Above Max Guideline - 0 - 0 - 0 Below Min Guideline - 0 - 0 - 0 13 13 13 13 13 13 Min 0.01 0.04 0.05 0.08 0.001 0.006 Median 0.02 0.13 0.12 0.25 0.004 0.009 Max 0.2 0.19 0.22 0.3 0.015 0.021 Above Max Guideline - 0 - 0 - 0 Below Min Guideline - 0 - 0 - 0 n PWFP10 Aluminium Total (mg/L) 13 Min n HBR1 Aluminium Filtered (mg/L) Statistic Station Code Table A15 Warragamba system – water filtration plants - metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 29 13 13 13 NA <LOR <LOR <LOR HWA2 Median 0.103 1320 64 NA NA <LOR <LOR <LOR Max 0.567 2760 267 NA NA 0.002 170 177 Above Max Guideline - - - - NA - 0 - Below Min Guideline - - - - NA - 0 - 12 12 12 0 0 12 12 12 Statistic n HBR1 Min 0.011 93 13 NA NA <LOR <LOR <LOR Median 0.09 455.5 51 NA NA <LOR <LOR <LOR Max 0.483 1530 270 NA NA 0.004 196 196 Above Max Guideline - - - - NA - 0 - Below Min Guideline - - - - NA - 0 - 13 13 13 0 0 13 13 13 Min 0.066 120 29 NA NA <LOR <LOR <LOR Median 0.13 494 94 NA NA <LOR <LOR <LOR Max 0.453 1630 241 NA NA 0.001 113 113 Above Max Guideline - - - - NA - 0 - Below Min Guideline - - - - NA - 0 - n PWFP10 Toxic Total Algal Count 0 NA Toxic Cyanobacterial Count (cells/mL) 0 12 Toxic Cyanobacterial biovolume (mm3/L) 13 94 Microcystin LR equiv (ug/L) Areal Standard Unit (algae) 13 0.014 n Chlorophyll-a (ug/L) Algal Total Count (cells/mL) 13 Min Station Code Algal biovolume (mm3/L) Table A16 Warragamba system – water filtration plants - cyanobacteria Enterococci (orgs/100ml) 12 12 <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR Above Max Guideline - - - - Below Min Guideline - - - - 13 13 13 13 Min <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR Max 2 <LOR 1 1 Above Max Guideline - - - - Below Min Guideline - - - - 13 13 13 13 Min <LOR <LOR <LOR <LOR Median <LOR 3 2 2 Max 8 10 4 10 Above Max Guideline - - - - Below Min Guideline - - - - n PWFP10 E. coli (orgs/100mL) 12 <LOR n HWA2 Coliforms Thermotolerant (cfu/100mL) 12 Min n HBR1 Clostridium Perfringens - Lamp Method Statistic Station Code Table A17 Warragamba system – water filtration plants – pathogens Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 30 n HWA2 HBR1 PWFP10 Tin Total (mg/L) Silver Total (mg/L) Selenium Total (mg/L) Molybdenum Total (mg/L) Mercury Total (mg/L) Iodide (mg/L) Boron Total (mg/L) Beryllium-Total (mg/L) Barium Total (mg/L) Arsenic Total (mg/L) Statistic Station Code Table A18 Warragamba system – water filtration plants – heavy metals 4 4 4 4 1 4 4 4 1 4 Min <LOR 0.018 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR 0.02 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR 0.021 <LOR 0.01 <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 0 0 - Below Min Guideline 0 0 0 0 0 0 0 0 0 - n 4 4 4 4 1 4 4 4 1 4 Min <LOR 0.02 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR 0.02 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR 0.022 <LOR 0.02 <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 0 0 - Below Min Guideline 0 0 0 0 0 0 0 0 0 - n 4 4 4 4 1 4 4 4 1 4 Min <LOR 0.018 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR 0.02 <LOR 0.01 <LOR <LOR <LOR <LOR <LOR <LOR Max 0.001 0.024 <LOR 0.02 <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 0 0 - Below Min Guideline 0 0 0 0 0 0 0 0 0 - n HBR1 HWA2 PWFP10 Triclopyr (ug/L) Hexazinone (ug/L) Heptachlor (ug/L) Glyphosate (ug/L) Diuron (ug/L) Diquat (ug/L) Diazinon (ug/L) Chlorpyrifos (ug/L) Atrazine (ug/L) Amitrole (ug/L) 2,4-D (ug/L) 2,4,5-T (ug/L) Statistic Station Code Table A19 Warragamba system – water filtration plants - pesticides 1 12 1 1 12 12 1 1 12 1 1 12 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR 0.01 Above Max Guideline 0 0 0 0 0 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 0 0 0 0 0 n 1 13 1 1 13 13 1 1 13 1 1 13 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR 0.01 Above Max Guideline 0 0 0 0 0 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 0 0 0 0 0 n 1 13 1 1 13 13 1 1 13 1 1 13 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR 0.01 Above Max Guideline 0 0 0 0 0 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 0 0 0 0 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 31 n HWA2 HBR1 PWFP10 Vinyl chloride (ug/L) Hexachlorobutadiene (ug/L) Gross Beta Gross Alpha Benzene (ug/L) trans-1,2-Dichloroethene (ug/L) 1,2-Dichloroethane (ug/L) Statistic Station Code Table A20 Warragamba system – water filtration plants – synthetic organic compounds and radionucleids 13 13 13 1 1 13 13 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 n 12 12 12 1 1 12 12 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 n 13 13 13 1 1 13 13 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 Giardia IFA /10L Adj for Recovery n 311 311 % <LOR 92 95 Min* 1 1 Median* 1 1 Max* 3 2 Prospect - COMP Statistic Station Code Crypto IFA /10L Adj for Recovery Table A21 Warragamba system – water filtration plants – Cryptosporidium and Giardia * detection samples only Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 32 A2 Upper Nepean system A2.1 Catchments True Colour at 400nm True Colour at 420nm Turbidity (NTU) 12 12 12 12 12 12 12 12 9 12 12 74.5 6.5 5.2 9 0.5 9.5 0.5 1.7 3 10 1 0.05 Median 2 1 24 0.09 2.7 96.8 9.4 5.8 13 1 15.8 4.0 2.8 9 21 2 0.11 Max 8 1 33 0.10 4.8 101.5 11.3 7.0 14 3 22.3 8.0 4.6 15 36 6 0.22 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 42 - 92 - - - - - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 12 12 12 8 12 12 Min 9 2 13 0.08 1.6 95.1 8.2 6.9 8 0.5 8.6 13.0 1.5 9 34 2 0.08 Median 16 3 19 0.11 3.3 102.5 10.2 7.2 10 2 16.0 18.5 3.4 19 61 3 0.16 Max 27 4 26 0.13 8.3 106.0 12.3 7.4 12 6 22.6 26.0 8.1 37 86 8 0.27 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 0 - 0 - - - - - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 12 12 12 8 12 12 Min 1 1 11 0.06 2.3 94.3 8.2 5.7 8 0.5 8.3 0.5 2.1 14 45 1 0.10 Median 5 1 17 0.08 3.8 104.1 10.4 6.5 10 0.75 15.7 4.0 3.5 23 57 2 0.17 Max 8 1 26 0.10 7.4 105.3 12.0 7.0 14 8 23.1 15.0 7.2 29 70 6 0.27 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 0 - 50 - - - - - - - 0 - 13 13 13 13 13 13 13 13 13 13 13 13 13 13 9 13 13 Min 4 1 13 0.08 1.2 91.3 8.8 6.3 10 0.5 8.0 7.0 1.0 2 7 1 0.03 Median 15 3 29 0.13 1.9 98.2 10.4 6.8 15 0.5 13.8 24.0 1.9 4 10 1 0.04 Max 20 4 32 0.15 5.6 105.2 11.9 7.1 17 5 18.1 26.0 5.5 20 44 6 0.20 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 0 - 15 - - - - - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 12 12 12 8 12 12 Min 13 3 16 0.13 1.0 85.5 9.1 6.5 13 0.5 9.0 22.0 0.9 3 12 1 0.04 Median 33 5 25 0.15 2.0 96.9 10.2 7.0 16 2 11.9 31.5 1.9 7 19 2 0.08 Max 44 8 32 0.19 5.9 101.6 11.4 7.5 18 8 16.9 49.0 6.2 12 26 4 0.13 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 8 - 0 - - - - - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 12 12 12 8 12 12 Min 5 2 16 0.07 1.8 78.5 8.1 5.6 12 0.5 9.0 13.0 1.9 6 16 2 0.08 Median 12 4 25 0.11 3.5 91.0 9.2 6.2 15 2.5 13.0 17.0 3.4 11 30 4 0.14 Max 16 5 31 0.13 6.8 94.3 10.7 6.7 17 4 17.0 25.0 6.8 19 43 7 0.19 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 42 - 83 - - - - - - - 0 - 11 11 11 11 11 11 11 11 11 11 11 11 11 11 8 11 11 Min 4 1 10 0.06 0.8 89.4 8.7 6.7 8 0.5 8.7 7.0 0.9 2 11 1 0.02 Median 20 4 13 0.11 2.4 97.5 10.5 7.0 9 1 13.1 22.0 2.5 7 20 1 0.07 Max 32 6 21 0.14 5.4 104.6 11.9 7.4 11 13 17.3 40.0 5.3 20 44 2 0.18 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 18 - 0 - - - - - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 12 12 12 9 12 12 Min 4 1 11 0.06 2.4 87.8 8.1 6.0 8 0.5 9.6 0.5 2.4 6 26 1 0.07 Median 13 3 17 0.10 3.9 100.2 9.7 6.9 10 2 15.6 20.0 4.0 15 36 3 0.14 Max 16 3 27 0.11 7.2 102.9 11.4 7.2 12 3 21.8 24.0 7.4 36 82 9 0.30 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 8 - 17 - - - - - - - 0 - 11 11 11 11 11 11 11 11 11 11 11 11 11 11 8 11 11 Min 9 2 10 0.07 1.5 91.1 8.6 6.6 7 0.5 6.6 13.0 1.5 5 20 3 0.08 Median 16 3 12 0.09 2.7 102.2 10.6 7.3 9 2 13.4 20.0 2.9 14 30 5 0.14 Max 23 5 26 0.11 8.9 105.4 12.1 7.6 12 8 18.8 29.0 9.0 44 100 13 0.39 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 0 - 0 - - - - - - - 0 - Statistic n E601 E602 n E604 E608 n E609 n E610 n E680 n E697 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 33 UV Absorbing constituents (organic) Total Organic Carbon (mg/L) 12 1.7 Temperature (Deg C) Sodium Filtered (mg/L) 12 0.07 Suspended Solids (mg/L) pH 12 14 Dissolved Oxygen (mg/L) 12 1 Dissolved Oxygen (%Sat) Chloride (mg/L) 12 1 Dissolved Organic Carbon (mg/L) Calcium Filtered (mg/L) 12 Min Conductivity (mS/cm) Alkalinity (mgCaCO3/L) n Station Code E6006 Total Hardness (mgCaCO3/L) Table A22 Upper Nepean system – catchments – physico-chemical Potassium Filtered (mg/L) E602 E604 E608 E609 E610 E680 E697 Silicate Reactive (SiO2 mg/L) Phosphorus Total (mg/L) E601 Phosphorus Filterable (mg/L) 12 12 12 12 12 12 0.0 0.0 0.1 0.00 0.01 1 2.5 Median 0.3 0.00 0.0 0.0 0.0 0.1 0.00 0.01 1 3.3 Max 1.7 0.01 0.0 0.1 0.1 0.4 0.01 0.02 1 3.7 Above Max Guideline - - - - 0 - - 8 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.3 0.00 0.0 0.0 0.2 0.1 0.00 0.01 1 0.2 Median 0.6 0.00 0.3 0.1 0.4 0.1 0.01 0.01 1 5.1 Max 2.3 0.05 0.7 0.3 0.7 0.5 0.01 0.03 1 7.6 Above Max Guideline - - - - 58 - - 25 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.2 0.00 0.0 0.0 0.0 0.1 0.00 0.00 1 2.5 Median 0.5 0.00 0.0 0.1 0.1 0.1 0.00 0.01 1 3.6 Max 1.7 0.00 0.0 0.2 0.2 0.1 0.01 0.02 1 5.0 Above Max Guideline - - - - 0 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 12 13 13 13 13 12 13 13 13 13 Min 0.1 0.00 0.0 0.0 0.1 0.1 0.00 0.00 1 3.4 Median 0.6 0.00 0.1 0.1 0.2 0.1 0.00 0.01 1 3.8 Max 1.1 0.01 0.2 0.3 0.3 0.4 0.01 0.01 1 4.9 Above Max Guideline - - - - 15 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.1 0.00 0.1 0.0 0.1 0.1 0.00 0.01 1 4.8 Median 0.5 0.00 0.1 0.0 0.1 0.1 0.01 0.01 1 5.7 Max 0.8 0.01 0.1 0.1 0.2 0.5 0.01 0.02 1 6.9 Above Max Guideline - - - - 0 - - 17 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.1 0.00 0.0 0.0 0.0 0.1 0.00 0.01 1 3.8 Median 0.5 0.01 0.0 0.0 0.1 0.1 0.00 0.01 1 4.7 Max 1.6 0.02 0.1 0.1 0.2 0.5 0.01 0.02 1 5.3 Above Max Guideline - - - - 0 - - 8 - - Below Min Guideline - - - - 0 - - 0 - - n 11 11 11 11 11 11 11 11 11 11 Min 0.1 0.00 0.0 0.0 0.0 0.1 0.00 0.00 1 2.8 Median 0.3 0.00 0.0 0.1 0.1 0.1 0.00 0.01 1 4.3 Max 1.0 0.00 0.0 0.3 0.3 2.0 0.01 0.02 1 5.2 Above Max Guideline - - - - 9 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.7 0.00 0.0 0.0 0.1 0.1 0.00 0.00 1 2.6 Median 2.0 0.01 0.0 0.1 0.1 0.2 0.00 0.01 1 3.4 Max 6.6 0.06 0.2 0.3 0.3 2.0 0.01 0.02 1 5.0 Above Max Guideline - - - - 8 - - 8 - - Below Min Guideline - - - - 0 - - 0 - - n 11 11 11 11 11 11 11 11 11 11 Min 0.8 0.00 0.0 0.0 0.2 0.1 0.00 0.01 1 3.1 Median 1.7 0.01 0.4 0.1 0.5 0.1 0.00 0.02 1 5.0 Max 3.1 0.02 0.8 0.3 0.9 3.6 0.01 0.04 1 6.8 Above Max Guideline - - - - 82 - - 27 - - Below Min Guideline - - - - 0 - - 0 - - Statistic Phaeophytin (ug/L) 12 0.0 Nitrogen Total (mg/L) 12 0.00 Nitrogen TKN (mg/L) 12 0.2 Nitrogen Oxidised (mg/L) 12 Min Lorenzen (ug/L) n Station Code E6006 Nitrogen Ammoniacal (mg/L) Table A23 Upper Nepean system – catchments - nutrients Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 34 12 12 1 0.03 0.03 E6006 Median 0.04 0.13 0.16 0.49 1 0.04 0.04 Max 0.16 0.20 0.44 1.22 2 0.19 0.20 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.04 0.22 0.47 2 0.00 0.01 Median 0.02 0.09 0.45 0.80 3 0.01 0.01 Max 0.06 0.28 0.89 1.22 4 0.04 0.09 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.02 0.04 0.16 0.30 1 0.01 0.01 Median 0.04 0.10 0.50 0.86 1 0.02 0.02 Max 0.13 0.26 0.82 1.67 3 0.03 0.05 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 13 13 13 13 13 13 13 Min 0.01 0.01 0.03 0.03 1 0.00 0.00 Median 0.01 0.03 0.03 0.03 4 0.01 0.01 Max 0.16 0.29 0.10 0.22 4 0.01 0.02 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.06 0.07 0.21 3 0.01 0.01 Median 0.02 0.10 0.09 0.32 5 0.01 0.02 Max 0.05 0.17 0.19 0.77 7 0.02 0.04 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.02 0.06 0.19 0.36 2 0.05 0.05 Median 0.04 0.11 0.29 0.81 2 0.07 0.08 Max 0.12 0.24 0.45 1.44 3 0.12 0.12 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 11 11 11 11 11 11 11 Min 0.01 0.01 0.03 0.16 1 0.01 0.01 Median 0.02 0.03 0.10 0.28 3 0.01 0.02 Max 0.13 0.28 0.16 0.64 6 0.03 0.04 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.04 0.12 0.26 1 0.01 0.02 Median 0.03 0.06 0.31 0.61 3 0.03 0.04 Max 0.15 0.32 1.01 1.65 4 0.08 0.09 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 11 11 11 11 11 11 11 Min 0.01 0.08 0.15 0.60 2 0.01 0.01 Median 0.02 0.16 0.30 0.75 3 0.01 0.02 Max 0.12 0.44 0.56 1.07 4 0.04 0.05 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - Statistic n E601 n E602 n E604 n E608 n E609 n E610 n E680 n E697 Manganese Total (mg/L) 12 0.21 Manganese Filtered (mg/L) Magnesium Filtered (mg/L) 12 0.10 Iron Filtered (mg/L) 12 0.05 Aluminium Total (mg/L) 12 0.03 n Aluminium Filtered (mg/L) 12 Min Station Code Iron Total (mg/L) Table A24 Upper Nepean system – catchments - metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 35 n E6006 E601 E602 E604 E608 E609 E610 E680 E697 Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Cyanobacterial biovolume (mm3/L) Cyanobacteria Total Count (cells/mL) Chlorophyll-a (ug/L) Areal Standard Unit (algae) Algal Total Count (cells/mL) Algal biovolume (mm3/L) Statistic Station Code Table A25 Upper Nepean system – catchments - cyanobacteria 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.1 NA NA NA NA NA Median NA NA NA 0.2 NA NA NA NA NA Max NA NA NA 1.0 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.3 NA NA NA NA NA Median NA NA NA 0.6 NA NA NA NA NA Max NA NA NA 2.7 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.1 NA NA NA NA NA Median NA NA NA 0.2 NA NA NA NA NA Max NA NA NA 1.6 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 13 0 0 0 0 0 Min NA NA NA 0.1 NA NA NA NA NA Median NA NA NA 0.3 NA NA NA NA NA Max NA NA NA 1.0 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.1 NA NA NA NA NA Median NA NA NA 0.4 NA NA NA NA NA Max NA NA NA 1.0 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.1 NA NA NA NA NA Median NA NA NA 0.5 NA NA NA NA NA Max NA NA NA 1.4 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 11 0 0 0 0 0 Min NA NA NA 0.1 NA NA NA NA NA Median NA NA NA 0.4 NA NA NA NA NA Max NA NA NA 2.2 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 2 2 2 12 2 2 0 2 2 Min 0.7 6030 552 0.7 4830 0.01 NA <LOR <LOR Median 0.7 8555 564 2.4 7155 0.01 NA <LOR <LOR Max 0.8 11080 576 6.8 9480 0.02 NA <LOR <LOR Above Max Guideline - - - 17 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 0 0 0 11 0 0 0 0 0 Min NA NA NA 0.7 NA NA NA NA NA Median NA NA NA 1.8 NA NA NA NA NA Max NA NA NA 3.7 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 36 Coliforms Thermotolerant (cfu/100mL) Coliforms Total (cfu/100mL) E. coli (orgs/100mL) Enterococci (orgs/100ml) n 4 12 0 12 12 Min* 1 2 NA 2 1 Median* 1 10 NA 16 18 Max* 1 90 NA 690 84 Above Max Guideline - - - - - Below Min Guideline - - - - - n 4 12 0 12 12 Min* 1 1 NA 2 1 Median* 2 14 NA 10 30 Max* E6006 E601 E602 E604 E608 E609 E610 E680 E697 Statistic Station Code Clostridium Perfringens Lamp Method Table A26 Upper Nepean system – catchments - pathogens 10 51 NA 70 360 Above Max Guideline - - - - - Below Min Guideline - - - - - n 3 12 0 12 12 Min* 1 1 NA 2 1 Median* 1 7 NA 8 12 Max* 2 30 NA 20 65 Above Max Guideline - - - - - Below Min Guideline - - - - - n 2 13 0 13 13 Min 1 1 NA 1 1 Median 1 5 NA 4 25 Max 2 65 NA 76 160 Above Max Guideline - - - - - Below Min Guideline - - - - - n 6 12 0 12 12 Min* 1 1 NA 1 1 Median* 1 7 NA 6 18 Max* 3 41 NA 44 92 Above Max Guideline - - - - - Below Min Guideline - - - - - n 6 12 0 12 12 Min* 1 8 NA 6 4 Median* 1 27 NA 40 28 Max* 7 94 NA 150 220 Above Max Guideline - - - - - Below Min Guideline - - - - - n 5 11 0 11 11 Min* 1 2 NA 5 1 Median* 1 23 NA 18 11 Max* 4 140 NA 250 150 Above Max Guideline - - - - - Below Min Guideline - - - - - n 3 12 0 12 12 Min* 1 3 NA 1 1 Median* 3 41 NA 38 40 Max* 7 190 NA 460 1000 Above Max Guideline - - - - - Below Min Guideline - - - - - n 3 11 0 11 11 Min* 1 10 NA 10 6 Median* 5 29 NA 23 19 Max* 6 120 NA 260 140 Above Max Guideline - - - - - Below Min Guideline - - - - - * detection samples only Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 37 A2.2 Storages True Colour at 400nm True Colour at 420nm 12 12 12 12 12 12 12.4 2 3.8 2 5 <LOR 0.06 DAV1 Median 4.5 1 13.3 0.07 4.3 105.9 9.3 7.0 9.3 1 18.5 10 4.0 4 10 <LOR 0.07 Max 5.5 1 21.5 0.09 5.4 110.4 10.7 7.5 10.5 2 25.3 11 4.7 8 18 2.4 0.11 Above Max Guideline - - - - - 8 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 25 - 8 - - - - - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 Min 4.0 <LOR 10.7 0.07 3.6 79.6 8.0 6.1 8.0 0 12.0 <LOR 3.6 2 7 <LOR 0.04 Median 5.0 1 13.2 0.07 4.2 98.7 9.0 7.0 9.5 2 19.1 6 4.1 5 11 0.1 DAV7 0.08 Max 5.7 2 23.0 0.08 7.3 108.2 10.8 7.5 10.7 4 24.2 13 7.3 9 21 3.1 0.11 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 17 - 8 - - - - - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 DCA1 Min 1.5 <LOR 12.0 0.07 4.2 87.5 7.8 5.7 9.0 1 11.6 <LOR 4.0 6 13 <LOR 0.09 Median 2.0 <LOR 14.3 0.07 5.1 101.1 9.1 6.6 10.0 2 19.6 4 5.0 11 24 0.1 0.12 Max 2.5 1 26.0 0.09 6.8 107.2 10.5 7.8 12.0 3 25.1 7 6.8 22 47 2.7 0.21 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 17 - 42 - - - - - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 Min 7.0 1 13.5 0.09 4.7 77.4 7.7 6.5 10.5 <LOR 11.3 11 4.2 5 11 <LOR 0.09 Median 9.8 2 16.0 0.09 5.1 98.2 8.7 6.9 11.8 2 19.7 13 4.9 9 20 0.8 DCO1 0.12 Max 12.0 2 23.5 0.10 9.4 104.0 10.4 7.6 14.0 5 25.5 13 9.2 16 36 5.5 0.16 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 25 - 0 - - - - - - - 0 - n 12 12 12 13 12 13 13 13 12 12 13 12 12 12 12 13 12 Min 6.0 <LOR 11.0 0.07 4.3 82.7 7.8 6.2 8.0 <LOR 11.0 4 4.3 13 27 <LOR 0.14 Median 8.5 2 12.3 0.08 5.7 100.2 9.6 6.6 9.8 2 18.7 13 5.7 19 43 2.1 DNE2 0.18 Max 9.0 2 14.5 0.08 8.3 117.5 11.8 7.4 10.5 4 21.4 13 8.0 30 64 7.8 0.24 Above Max Guideline - - - - - 15 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 38 - 31 - - - - - - - 0 - Statistic Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 38 UV Absorbing constituents (organic) Total Organic Carbon (mg/L) 12 <LOR Turbidity (NTU) Total Hardness (mgCaCO3/L) 12 8.0 Suspended Solids (mg/L) 12 6.3 Sodium Filtered (mg/L) 12 8.7 pH 12 89.4 Dissolved Oxygen (mg/L) 12 3.7 Dissolved Oxygen (%Sat) 12 0.07 Dissolved Organic Carbon (mg/L) 12 12.0 Conductivity Field (mS/cm) 12 <LOR Chloride (mg/L) 12 4.0 Calcium Filtered (mg/L) 12 Min Alkalinity (mgCaCO3/L) n Station Code Temperature (Deg C) Table A27 Upper Nepean system – storages – physico-chemical DAV1 DAV7 DCA1 DCO1 DNE2 Silicate Reactive (SiO2 mg/L) Potassium Filtered (mg/L) Phosphorus Total (mg/L) Phosphorus Filterable (mg/L) Phaeophytin (ug/L) Nitrogen Total (mg/L) Nitrogen TKN (mg/L) Nitrogen Oxidised (mg/L) Nitrogen Ammoniacal (mg/L) Lorenzen (ug/L) Statistic Station Code Table A28 Upper Nepean system – storages – nutrients n 12 12 12 12 12 12 12 12 12 12 Min 1.0 <LOR <LOR 0.12 0.12 <LOR <LOR <LOR <LOR 1.2 Median 2.4 <LOR 0.00 0.14 0.15 <LOR 0.00 <LOR <LOR 1.5 Max 5.0 0.02 0.04 0.16 0.18 0.6 0.01 0.01 1 2.0 Above Max Guideline - - - - 0 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 1.6 <LOR <LOR 0.07 0.08 <LOR 0.00 <LOR <LOR 1.0 Median 3.8 <LOR 0.00 0.14 0.16 0.2 0.00 0.00 <LOR 1.5 Max 6.6 0.02 0.03 0.17 0.18 0.5 0.01 0.01 <LOR 2.0 Above Max Guideline - - - - 0 - - 17 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 1.8 <LOR <LOR 0.10 0.11 <LOR <LOR <LOR <LOR 0.7 Median 2.4 0.00 0.01 0.15 0.16 0.1 0.00 0.00 <LOR 0.8 Max 3.9 0.04 0.02 0.19 0.21 0.3 0.00 0.02 <LOR 1.3 Above Max Guideline - - - - 0 - - 8 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 1.7 <LOR <LOR 0.14 0.14 <LOR 0.00 <LOR <LOR 1.0 Median 3.0 0.01 0.01 0.20 0.21 <LOR 0.00 0.01 <LOR 1.4 Max 8.1 0.06 0.03 0.22 0.24 1.3 0.01 0.02 1 2.3 Above Max Guideline - - - - 0 - - 17 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 1.2 <LOR 0.13 0.08 0.27 <LOR 0.00 0.01 <LOR 1.7 Median 1.8 0.02 0.18 0.18 0.38 <LOR 0.00 0.01 1 3.2 Max 5.9 0.05 0.23 0.29 0.50 0.8 0.01 0.02 1 3.8 Above Max Guideline - - - - 67 - - 92 - - Below Min Guideline - - - - 0 - - 0 - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 39 n DAV1 Manganese Total (mg/L) Manganese Filtered (mg/L) Magnesium Filtered (mg/L) 12 12 12 12 <LOR <LOR 0.5 <LOR 0.01 Median 0.01 0.02 <LOR 0.02 1.8 0.00 0.01 Max 0.05 0.09 0.05 0.07 2.0 0.01 0.03 Above Max Guideline - 17 - - - - 0 Below Min Guideline - 0 - - - - 0 12 12 12 12 12 12 12 Min <LOR 0.01 <LOR 0.02 <LOR <LOR 0.01 Median 0.01 0.03 0.03 0.15 1.0 0.00 0.02 Max 0.04 0.07 0.08 0.23 2.0 0.03 0.04 Above Max Guideline - 8 - - - - 0 Below Min Guideline - 0 - - - - 0 12 12 12 12 12 12 12 Min 0.02 0.03 0.11 0.18 <LOR 0.00 0.01 Median 0.06 0.09 0.14 0.24 1.0 0.01 0.02 Max 0.12 0.24 0.22 0.32 1.0 0.02 0.04 Above Max Guideline - 75 - - - - 0 Below Min Guideline - 0 - - - - 0 12 12 12 12 12 12 12 Min <LOR 0.01 <LOR 0.03 2.0 <LOR 0.01 Median 0.02 0.04 0.08 0.14 2.0 0.00 0.02 Max 0.06 0.13 0.13 0.24 2.0 0.04 0.12 Above Max Guideline - 33 - - - - 0 Below Min Guideline - 0 - - - - 0 12 12 12 12 12 12 12 Min 0.05 0.09 0.18 0.32 1.0 0.01 0.01 Median 0.07 0.15 0.31 0.51 2.0 0.05 0.06 Max 0.14 0.39 0.42 0.63 2.0 0.07 0.09 Above Max Guideline - 100 - - - - 0 Below Min Guideline - 0 - - - - 0 n DNE2 Iron Total (mg/L) 12 0.01 n DCO1 Iron Filtered (mg/L) 12 <LOR n DCA1 Aluminium Total (mg/L) 12 Min n DAV7 Aluminium Filtered (mg/L) Statistic Station Code Table A29 Upper Nepean system – storages – metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 40 DCA1 DCO1 Toxic Total Algal Count Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Cyanobacterial biovolume (mm3/L) Chlorophyll-a (ug/L) 2 12 2 0 2 2 2 4910 125 0.9 0.001 NA <LOR <LOR <LOR Median 0.70 4995 426 2.5 0.003 NA <LOR <LOR <LOR Max 1.09 5080 727 5.0 0.004 NA <LOR <LOR <LOR Above Max Guideline - - - 0 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - 12 12 12 12 12 0 12 12 12 Min 0.23 1480 108 1.8 <LOR NA <LOR <LOR <LOR Median 0.72 10670 450 4.2 0.004 NA <LOR <LOR <LOR Max 1.86 85400 1064 6.5 0.050 NA 0.01 98 112 Above Max Guideline - - - 8 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - n 0 0 0 12 0 0 0 0 0 Min NA NA NA 1.8 NA NA NA NA NA Median NA NA NA 2.5 NA NA NA NA NA Max NA NA NA 4.4 NA NA NA NA NA Above Max Guideline - - - 0 NA NA - NA - Below Min Guideline - - - 0 NA NA - NA - n 1 1 1 12 1 0 1 1 1 Min 1.29 128400 600 1.8 0.061 NA 0.00 147 147 Median 1.29 128400 600 3.4 0.061 NA 0.00 147 147 Max 1.29 128400 600 9.1 0.061 NA 0.00 147 147 Above Max Guideline - - - 8 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - 12 12 12 12 12 0 12 12 12 Min 0.06 272 44 1.3 <LOR NA <LOR <LOR <LOR Median 0.27 863 87 1.8 <LOR NA <LOR <LOR <LOR Max 1.78 8440 581 6.8 0.003 NA <LOR 15 15 Above Max Guideline - - - 8 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - n DNE2 Areal Standard Unit (algae) 2 0.32 n DAV7 Algal Total Count (cells/mL) 2 Min n DAV1 Algal biovolume (mm3/L) Statistic Station Code Table A30 Upper Nepean system – storages – cyanobacteria Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 41 n DAV1 Enterococci (cfu/100ml) 12 0 NA <LOR NA Median <LOR <LOR NA 1 NA Max 1 8 NA 4 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 12 12 0 12 0 Min <LOR <LOR NA <LOR NA Median <LOR 2 NA 1 NA Max 1 104 NA 143 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 12 12 0 12 0 Min <LOR <LOR NA <LOR NA Median <LOR <LOR NA <LOR NA Max 1 15 NA 10 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 12 12 0 12 0 Min <LOR <LOR NA <LOR NA Median <LOR 1 NA 1 NA Max 5 15 NA 18 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 12 12 0 12 0 Min <LOR <LOR NA <LOR NA Median <LOR 0 NA 1 NA Max 5 2 NA 6 NA Above Max Guideline - - - - - Below Min Guideline - - - - - n DNE2 E. coli (orgs/100mL) 0 <LOR n DCO1 Coliforms Total (cfu/100mL) 12 <LOR n DCA1 Coliforms Thermotolerant (cfu/100mL) 12 Min n DAV7 Clostridium Perfringens Lamp Method Statistic Station Code Table A31 Upper Nepean system – storages – pathogens Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 42 Table A32 Upper Nepean system – storages – heavy metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 43 A2.3 Water filtration plants Dissolved Organic Carbon (mg/L) Dissolved Oxygen (%Sat) Dissolved Oxygen (mg/L) pH Temperature (Deg C) Total Hardness (mgCaCO3/L) Total Organic Carbon (mg/L) True Colour at 400nm True Colour at 420nm Turbidity (NTU) UV Absorbing constituents (organic) IWFP-R Conductivity (mS/cm) HNED n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline Alkalinity (mgCaCO3/L) HMAC1 Statistic Station Code Table A33 Upper Nepean system – water filtration plants – physico-chemical 12 2 5.5 9 0 0 12 4 7.5 9 0 0 12 4 5 8 0 0 12 0.078 0.082 0.09 12 0.072 0.076 0.084 12 0.071 0.076 0.081 - 12 4 4.7 5.8 12 4.6 5.55 9 12 3.6 3.95 12.7 - 12 103.4 106.3 108.6 12 89.6 98.85 105.5 12 105 107.4 108.9 - 12 9.16 10.27 11.91 12 8.95 9.635 10.78 12 9.28 10.13 11.35 - 12 6.3 7 7.7 0 0 12 6.3 6.8 7 0 0 12 6.3 7.05 7.4 17 0 12 10.8 16.9 22.8 12 11.2 15.35 21.7 12 12.6 18.7 22.5 - 12 4 12 21 0 17 12 7 12 13 0 0 12 <LOR 9 11 0 0 12 3.8 4.65 5.9 12 4.3 5.3 9.1 12 3.6 3.95 13.2 - 12 12 14 22 0 0 12 17 20.5 30 0 0 12 3 6.5 10 0 0 12 27 33 51 12 39 47 68 12 8 16 23 - 12 <LOR 1.2 3.1 0 0 12 <LOR 2.6 9.9 0 0 12 <LOR 0.65 3.1 0 0 12 0.128 0.139 0.199 12 0.152 0.193 0.315 12 0.063 0.09 0.118 - Iron Filtered (mg/L) Iron Total (mg/L) Manganese Filtered (mg/L) Manganese Total (mg/L) IWFP-R Aluminium Total (mg/L) HNED n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline Aluminium Filtered (mg/L) HMAC1 Statistic Station Code Table A34 Upper Nepean system – water filtration plants - metals 12 0.02 0.05 0.08 12 0.04 0.08 0.13 12 <LOR 0.01 0.03 - 12 0.05 0.105 0.28 0 0 12 0.07 0.18 0.53 0 0 12 0.01 0.04 0.11 0 0 12 0.16 0.225 0.38 12 0.22 0.32 0.4 12 <LOR 0.08 0.11 - 12 0.3 0.38 0.64 0 0 12 0.37 0.49 0.76 0 0 12 0.08 0.31 0.51 0 0 12 0.009 0.017 0.029 12 0.012 0.046 0.07 12 <LOR 0.004 0.016 - 12 0.017 0.024 0.037 0 0 12 0.021 0.054 0.087 0 0 12 0.013 0.045 0.133 0 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 44 Areal Standard Unit (algae) Microcystin LR equiv (ug/L) Toxic Cyanobacterial biovolume (mm3/L) Toxic Cyanobacterial Count (cells/mL) Toxic Total Algal Count IWFP-R Algal Total Count (cells/mL) HNED n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline Algal biovolume (mm3/L) HMAC1 Statistic Station Code Table A35 Upper Nepean system – water filtration plants – cyanobacteria 12 0.036 0.067 0.175 12 0.025 0.107 0.236 12 0.301 0.761 2.811 - 12 210 865.5 3240 12 107 430.5 5430 12 1380 11430 53180 - 12 25 63 131 0 0 12 17 63.5 142 0 0 12 143 327.5 1329 0 0 0 NA NA NA NA NA 0 NA NA NA NA NA 0 NA NA NA NA NA 12 <LOR <LOR <LOR 12 <LOR <LOR 0.004 12 <LOR <LOR 0.018 - 12 <LOR <LOR 28 0 0 12 <LOR 3.5 87 0 0 12 <LOR <LOR 393 0 0 12 <LOR <LOR 28 12 <LOR 3.5 87 12 <LOR <LOR 393 - E. coli (orgs/100mL) Enterococci (orgs/100ml) IWFP-R Coliforms Thermotolerant (cfu/100mL) HNED n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline Clostridium Perfringens - Lamp Method HMAC1 Statistic Station Code Table A36 Upper Nepean system – water filtration plants - pathogens 12 <LOR <LOR 10 12 <LOR <LOR 7 12 <LOR <LOR 2 - 12 <LOR 13 150 12 <LOR <LOR 7 12 <LOR <LOR 37 - 12 2 11 180 12 <LOR <LOR 4 12 <LOR <LOR 45 - 12 7 20 120 12 <LOR <LOR 1 12 <LOR 1.5 20 - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 45 Beryllium-Total (mg/L) Boron Total (mg/L) Iodide (mg/L) Mercury Total (mg/L) Molybdenum Total (mg/L) Selenium Total (mg/L) Silver Total (mg/L) Tin Total (mg/L) IWFP-R Barium Total (mg/L) HNED n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline Arsenic Total (mg/L) HMAC1 Statistic Station Code Table A37 Upper Nepean system – water filtration plants – heavy metals 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 0.009 0.012 0.014 0 0 4 0.01 0.01 0.01 0 0 4 0.009 0.011 0.014 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR 0.005 0.01 0 0 4 <LOR <LOR 0.01 0 0 4 <LOR 0.005 0.04 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 4 <LOR <LOR <LOR 4 <LOR <LOR <LOR - Amitrole (ug/L) Atrazine (ug/L) Chlorpyrifos (ug/L) Diazinon (ug/L) Diquat (ug/L) Diuron (ug/L) Glyphosate (ug/L) Heptachlor (ug/L) Hexazinone (ug/L) Triclopyr (ug/L) IWFP-R 2,4-D (ug/L) HNED n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline 2,4,5-T (ug/L) HMAC1 Statistic Station Code Table A38 Upper Nepean system – water filtration plants – pesticides 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 12 <LOR <LOR <LOR 0 0 12 <LOR <LOR 0.02 0 0 12 <LOR <LOR <LOR 0 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 46 Benzene (ug/L) Gross Alpha Gross Beta Hexachlorobutadiene (ug/L) Vinyl chloride (ug/L) IWFP-R trans-1,2-Dichloroethene (ug/L) HNED n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline n Min Median Max Above Max Guideline Below Min Guideline 1,2-Dichloroethane (ug/L) HMAC1 Statistic Station Code Table A39 Upper Nepean system – water filtration plants – Synthetic organic compounds and radionucleids 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 0.009 0.012 0.014 0 0 4 0.01 0.01 0.01 0 0 4 0.009 0.011 0.014 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR 0.005 0.01 0 0 4 <LOR <LOR 0.01 0 0 4 <LOR 0.005 0.04 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 1 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 4 <LOR <LOR <LOR 0 0 Crypto IFA /10L Adj for Recovery Giardia IFA /10L Adj for Recovery Statistic Station Code Table A40 Upper Nepean system – water filtration plants – Cryptosporidium and Giardia 52 52 100 94 n % <LOR COMP16 MACSP1A Min* NA 1 Median* NA 1 Max* NA 1 n 52 52 % <LOR 96 98 Min* 1 1 Median* 2 1 Max* 2 1 * detection samples only Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 47 A2.4 Picnic areas n HAV3 Turbidity Field (NTU) Temperature (Deg C) pH (Field) Manganese Total (mg/L) Manganese Filtered (mg/L) Iron Total (mg/L) Iron Filtered (mg/L) E. coli (orgs/100mL) Dissolved Oxygen (mg/L) Dissolved Oxygen (%Sat) Conductivity Field (mS/cm) Chlorine Residual (mg/L) 49 49 49 49 49 49 49 49 49 49 49 49 49 <LOR <LOR <LOR 0.085 79.2 6.8 <LOR <LOR <LOR <LOR 0.002 6.8 11.8 <LOR Median 0.02 0.03 0.08 0.103 101.8 9.41 <LOR <LOR 0.09 0.002 0.005 7.5 18.9 <LOR Max 0.04 0.13 8.8 0.138 106.3 11.09 <LOR 0.18 0.38 0.016 0.016 8.1 25.6 3 Above Max Guideline - 0 16 - - - 0 - 2 - 0 0 - 0 Below Min Guideline - 0 76 - - - 0 - 0 - 0 0 - 0 51 51 51 51 51 51 51 51 51 51 51 51 51 51 Min <LOR 0.02 0.01 0.081 89.8 8.71 <LOR 0.06 0.14 0.002 0.007 6.2 10.9 <LOR Median 0.06 0.12 0.56 0.095 103 9.76 <LOR 0.27 0.51 0.009 0.03 7 18.2 1.2 Max 0.1 1.04 6.4 0.127 109.4 11.71 <LOR 0.55 2.42 0.213 2.15 7.9 22.5 36.5 Above Max Guideline - 10 55 - - - 0 - 98 - 14 0 - 10 Below Min Guideline - 0 14 - - - 0 - 0 - 0 2 - 0 51 51 51 51 51 51 51 51 51 51 51 51 51 51 Min <LOR <LOR 0.01 0.098 78.4 7.09 <LOR <LOR 0.06 0.002 0.002 6.8 9.8 <LOR Median 0.01 0.03 0.06 0.125 88.7 8.6 <LOR 0.13 0.3 0.007 0.025 7.5 17.1 <LOR Max 0.16 0.97 1.5 0.183 104.4 11.21 1 0.83 2.4 0.12 0.155 7.9 23.3 5.9 Above Max Guideline - 2 10 - - - 2 - 47 - 6 0 - 2 Below Min Guideline - 0 84 - - - 0 - 0 - 0 0 - 0 n HCO6 Aluminium Total (mg/L) 49 Min n HCA1 Aluminium Filtered (mg/L) Statistic Station Code Table A41 Upper Nepean system – picnic areas n HAV3 HCA1 HCO6 Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Chlorophyll-a (ug/L) Areal Standard Unit (algae) Algal Total Count (cells/mL) Algal biovolume (mm3/L) Statistic Station Code Table A42 Upper Nepean system – picnic areas - cyanobacteria 0 0 0 49 0 0 0 Min NA NA NA <LOR NA NA NA Median NA NA NA <LOR NA NA NA Max NA NA NA 0.3 NA NA NA Above Max Guideline - - - 0 NA - NA Below Min Guideline - - - 0 NA - NA n 0 0 0 51 0 0 0 Min NA NA NA <LOR NA NA NA Median NA NA NA <LOR NA NA NA Max NA NA NA 1.5 NA NA NA Above Max Guideline - - - 0 NA - NA Below Min Guideline - - - 0 NA - NA n 0 0 0 51 0 0 0 Min NA NA NA <LOR NA NA NA Median NA NA NA <LOR NA NA NA Max NA NA NA 1 NA NA NA Above Max Guideline - - - 0 NA - NA Below Min Guideline - - - 0 NA - NA Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 48 A3 Woronora system A3.1 Catchments Total Organic Carbon (mg/L) True Colour at 400nm True Colour at 420nm Turbidity (NTU) 12 12 12 12 12 12 12 12 12 12 8 12 12 0.11 0.8 88.7 7.8 6.8 14 0.5 10.4 16.0 0.9 2 8 1 0.03 Median 35 11 31 0.21 2.0 93.4 9.4 7.1 21 1 17.1 44.0 2.0 4 10 2 0.07 Max 62 18 39 0.36 5.0 103.6 11.6 7.4 27 3 21.8 66.0 5.0 19 38 4 0.18 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 17 - 0 - - - - - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 12 12 12 8 12 12 E677 Min 1 1 24 0.11 1.7 74.5 6.8 5.5 16 0.5 9.2 11.0 1.7 2 6 1 0.04 Median 2 1 45 0.18 2.9 90.2 8.6 6.0 26 1 16.1 19.0 3.1 5 16 1 0.08 Max 4 2 55 0.20 5.7 102.5 11.8 6.5 32 4 23.7 21.0 5.7 21 45 8 0.25 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 42 - 92 - - - - - - - 0 - Dissolved Oxygen (%Sat) Conductivity (mS/cm) Statistic Potassium Filtered (mg/L) Silicate Reactive (SiO2 mg/L) Phosphorus Total (mg/L) E677 Phosphorus Filterable (mg/L) 12 12 12 12 12 12 0.0 0.0 0.1 0.00 0.00 1 3.0 Median 0.5 0.00 0.0 0.0 0.0 0.1 0.00 0.01 1 4.3 Max 0.9 0.01 0.4 0.1 0.4 0.3 0.01 0.01 1 5.1 Above Max Guideline - - - - 8 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.1 0.00 0.0 0.0 0.0 0.1 0.00 0.00 1 2.9 Median 0.7 0.00 0.0 0.1 0.1 0.1 0.00 0.01 1 3.9 Max 1.7 0.01 0.0 0.2 0.2 0.2 0.00 0.02 1 4.5 Above Max Guideline - - - - 0 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - Statistic Phaeophytin (ug/L) 12 0.0 Nitrogen Total (mg/L) 12 0.00 Nitrogen TKN (mg/L) 12 0.1 Nitrogen Oxidised (mg/L) 12 Min Lorenzen (ug/L) n Station Code E6131 Nitrogen Ammoniacal (mg/L) Table A44 Woronora system – catchments – nutrients Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 49 UV Absorbing constituents (organic) Sodium Filtered (mg/L) 12 18 Temperature (Deg C) pH 12 3 Suspended Solids (mg/L) Chloride (mg/L) 12 8 Dissolved Oxygen (mg/L) Calcium Filtered (mg/L) 12 Min Dissolved Organic Carbon (mg/L) Alkalinity (mgCaCO3/L) n Station Code E6131 Total Hardness (mgCaCO3/L) Table A43 Woronora system – catchments – physico-chemical 12 12 2 0.04 0.05 E6131 Median 0.01 0.03 0.14 0.58 4 0.05 0.06 Max 0.10 0.18 0.35 0.76 5 0.07 0.08 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.03 0.03 0.13 2 0.01 0.01 Median 0.03 0.08 0.10 0.27 4 0.02 0.03 Max 0.15 0.24 0.60 1.69 4 0.06 0.06 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - Statistic n E677 Manganese Total (mg/L) 12 0.37 Manganese Filtered (mg/L) Magnesium Filtered (mg/L) 12 0.03 Iron Filtered (mg/L) 12 0.02 Aluminium Total (mg/L) 12 0.01 n Aluminium Filtered (mg/L) 12 Min Station Code Iron Total (mg/L) Table A45 Woronora system – catchments - metals n E6131 E677 Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Cyanobacterial biovolume (mm3/L) Cyanobacteria Total Count (cells/mL) Chlorophyll-a (ug/L) Areal Standard Unit (algae) Algal Total Count (cells/mL) Algal biovolume (mm3/L) Statistic Station Code Table A46 Woronora system – catchments - cyanobacteria 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.1 NA NA NA NA NA Median NA NA NA 0.3 NA NA NA NA NA Max NA NA NA 0.7 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.1 NA NA NA NA NA Median NA NA NA 0.4 NA NA NA NA NA Max NA NA NA 1.2 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA Coliforms Thermotolerant (cfu/100mL) Coliforms Total (cfu/100mL) E. coli (orgs/100mL) Enterococci (orgs/100ml) n 4 12 0 12 12 Min 1 3 NA 1 4 Median 1 23 NA 22 12 Max 3 94 NA 120 79 Above Max Guideline - - - - - Below Min Guideline - - - - - n 4 12 0 12 12 Min 1 1 NA 1 1 Median 1 4 NA 4 9 Max 2 150 NA 210 69 Above Max Guideline - - - - - Below Min Guideline - - - - - E6131 E677 Statistic Station Code Clostridium Perfringens Lamp Method Table A47 Woronora system – catchments – pathogens Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 50 A3.2 Storages Total Organic Carbon (mg/L) True Colour at 400nm True Colour at 420nm 12 12 12 12 12 12 12 12 12 12 12 12 4.2 93.3 8.5 6.2 13.0 <LOR 13.4 8 4.0 10 23 <LOR 0.11 DWO1 Median 3.8 2 24.3 0.11 4.9 101.8 9.6 6.6 14.0 1 19.2 13 4.7 12 28 <LOR 0.13 Max 4.5 2 32.0 0.11 6.4 111.8 10.1 7.4 18.0 2 23.3 13 6.3 18 40 3.1 0.16 Above Max Guideline - - - - - 25 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 0 - 42 - - - - - - - 0 - DWO1 pH Dissolved Oxygen (%Sat) Dissolved Organic Carbon (mg/L) Chloride (mg/L) Statistic Silicate Reactive (SiO2 mg/L) Potassium Filtered (mg/L) Phosphorus Total (mg/L) Phosphorus Filterable (mg/L) Phaeophytin (ug/L) Nitrogen Total (mg/L) Nitrogen TKN (mg/L) Nitrogen Oxidised (mg/L) Nitrogen Ammoniacal (mg/L) Lorenzen (ug/L) Statistic Station Code Table A49 Woronora system – storage – nutrients n 12 12 12 12 12 12 12 12 12 12 Min 0.5 0.00 0.06 0.09 0.15 <LOR <LOR <LOR <LOR 2.2 Median 1.2 0.01 0.07 0.11 0.19 <LOR 0.00 0.00 <LOR 2.5 Max 2.0 0.03 0.70 0.29 0.99 0.3 0.01 0.02 1 2.8 Above Max Guideline - - - - 8 - - 8 - - Below Min Guideline - - - - 0 - - 0 - - n DWO1 Manganese Total (mg/L) Manganese Filtered (mg/L) Magnesium Filtered (mg/L) Iron Total (mg/L) Iron Filtered (mg/L) Aluminium Total (mg/L) Aluminium Filtered (mg/L) Statistic Station Code Table A50 Woronora system – storage – metals 12 12 12 12 12 12 12 Min 0.03 0.07 0.17 0.30 1.5 0.01 0.01 Median 0.07 0.14 0.22 0.33 2.0 0.01 0.02 Max 0.10 0.19 0.25 0.50 2.0 0.02 0.03 Above Max Guideline - 100 - - - - 0 Below Min Guideline - 0 - - - - 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 51 UV Absorbing constituents (organic) Total Hardness (mgCaCO3/L) 12 0.10 Turbidity (NTU) Temperature (Deg C) 12 17.0 Suspended Solids (mg/L) 12 1 Sodium Filtered (mg/L) 12 3.0 Dissolved Oxygen (mg/L) 12 Min Conductivity Field (mS/cm) Calcium Filtered (mg/L) n Station Code Alkalinity (mgCaCO3/L) Table A48 Woronora system – storage – physico-chemical 12 12 <LOR <LOR <LOR DWO1 Median 0.11 1435 75 1.3 <LOR NA <LOR <LOR <LOR Max 0.27 2330 175 2.0 <LOR NA <LOR <LOR 15 Above Max Guideline - - - 0 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - Statistic Toxic Total Algal Count 12 NA Toxic Cyanobacterial Count (cells/mL) 0 <LOR Toxic Cyanobacterial biovolume (mm3/L) 12 0.5 Microcystin LR equiv (ug/L) 12 40 Cyanobacterial biovolume (mm3/L) 12 650 Chlorophyll-a (ug/L) Areal Standard Unit (algae) 12 0.07 n Algal biovolume (mm3/L) 12 Min Station Code Algal Total Count (cells/mL) Table A51 Woronora system – storage – cyanobacteria n DWO1 Enterococci (cfu/100ml) E. coli (orgs/100mL) Coliforms Total (cfu/100mL) Coliforms Thermotolerant (cfu/100mL) Clostridium Perfringens Lamp Method Statistic Station Code Table A52 Woronora system – storage – pathogens 12 12 0 12 0 Min <LOR <LOR NA <LOR NA Median <LOR 0 NA 1 NA Max 3 6 NA 6 NA Above Max Guideline - - - - - Below Min Guideline - - - - - Table A53 Woronora system – storage – heavy metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 52 A3.3 Water filtration plants Total Organic Carbon (mg/L) True Colour at 400nm True Colour at 420nm 14 14 13 13 13 13 14 13 8.98 6.2 13.3 11 3.9 8 24 <LOR 0.108 HWO1-A Median 4 0.106 4.8 104.2 9.77 6.6 18.7 13 4.7 13 29 1 0.134 Max 5 0.113 6.4 108.1 10.83 7.5 23.3 13 6.1 19 42 2.9 0.174 Above Max Guideline 0 - - - - - - 0 - 0 - 0 - Below Min Guideline 0 - - - - - - 0 - 0 - 0 - Statistic UV Absorbing constituents (organic) Total Hardness (mgCaCO3/L) 14 98 Turbidity (NTU) Temperature (Deg C) 14 4.1 pH 13 0.1 Dissolved Oxygen (mg/L) Dissolved Oxygen (%Sat) 14 3 Conductivity (mS/cm) 13 Min Alkalinity (mgCaCO3/L) n Station Code Dissolved Organic Carbon (mg/L) Table A54 Woronora system – water filtration plant – physico-chemical Manganese Total (mg/L) Manganese Filtered (mg/L) Iron Total (mg/L) Iron Filtered (mg/L) Aluminium Total (mg/L) 13 13 13 13 13 13 Min 0.04 0.07 0.16 0.28 0.008 0.012 Median 0.06 0.15 0.22 0.33 0.014 0.019 Max 0.09 0.21 0.28 0.39 0.019 0.023 Above Max Guideline - 0 - 0 - 0 Below Min Guideline - 0 - 0 - 0 n HWO1-A Aluminium Filtered (mg/L) Statistic Station Code Table A55 Woronora system – water filtration plant - metals 13 13 <LOR <LOR <LOR HWO1-A Median 0.06 1100 42 NA NA <LOR <LOR <LOR Max 0.093 1800 66 NA NA <LOR 35 35 Above Max Guideline - - - - NA - 0 - Below Min Guideline - - - - NA - 0 - Statistic Toxic Total Algal Count 13 NA Toxic Cyanobacterial Count (cells/mL) 0 NA Toxic Cyanobacterial biovolume (mm3/L) 0 10 Microcystin LR equiv (ug/L) 13 Min Chlorophyll-a (ug/L) Areal Standard Unit (algae) 13 205 n Algal biovolume (mm3/L) 13 0.011 Station Code Algal Total Count (cells/mL) Table A56 Woronora system – water filtration plant - cyanobacteria Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 53 Enterococci (orgs/100ml) E. coli (orgs/100mL) Coliforms Thermotolerant (cfu/100mL) 13 13 13 13 Min <LOR <LOR <LOR <LOR Median n HWO1-A Clostridium Perfringens Lamp Method Statistic Station Code Table A57 Woronora system – water filtration plant - pathogens <LOR <LOR <LOR <LOR Max 2 6 3 5 Above Max Guideline - - - - Below Min Guideline - - - - Tin Total (mg/L) Silver Total (mg/L) Selenium Total (mg/L) Molybdenum Total (mg/L) Mercury Total (mg/L) Iodide (mg/L) Boron Total (mg/L) Beryllium-Total (mg/L) Barium Total (mg/L) 4 4 4 4 1 4 4 4 1 4 Min <LOR 0.012 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR 0.013 <LOR 0.005 <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR 0.014 <LOR 0.04 <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 0 0 - Below Min Guideline 0 0 0 0 0 0 0 0 0 - n HWO1-A Arsenic Total (mg/L) Statistic Station Code Table A58 Woronora system – water filtration plant – heavy metals Triclopyr (ug/L) Hexazinone (ug/L) Heptachlor (ug/L) Glyphosate (ug/L) Diuron (ug/L) Diquat (ug/L) Diazinon (ug/L) Chlorpyrifos (ug/L) Atrazine (ug/L) Amitrole (ug/L) 2,4-D (ug/L) 1 13 1 1 13 13 1 1 13 1 1 13 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 0 0 0 0 0 n HWO1-A 2,4,5-T (ug/L) Statistic Station Code Table A59 Woronora system – water filtration plant - pesticides Vinyl chloride (ug/L) Hexachlorobutadiene (ug/L) Gross Beta Gross Alpha Benzene (ug/L) trans-1,2-Dichloroethene (ug/L) 13 13 13 1 1 13 13 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 n HWO1-A 1,2-Dichloroethane (ug/L) Statistic Station Code Table A60 Woronora system – water filtration plant – synthetic organic compounds and radionucleids Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 54 A4 Blue Mountains system A4.1 Storages True Colour at 400nm True Colour at 420nm 12 12 17 12 12 12 12 17 12 3.5 2 7.2 <LOR 2.9 9 21 1.8 0.08 Median 1.0 <LOR 6.0 0.03 3.9 75.4 6.7 5.9 4.0 3 16.7 <LOR 4.2 17 38 2.6 0.17 Max 3.0 <LOR 8.0 0.04 8.0 95.3 9.9 7.0 5.0 11 17.9 <LOR 8.1 84 193 9.1 0.51 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 82 - 88 - - - - - - - 0 - n 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 DLC1 pH Dissolved Oxygen (%Sat) Dissolved Organic Carbon (mg/L) Chloride (mg/L) Statistic Min 18.0 9 8.0 0.07 2.2 79.4 6.3 7.4 4.0 <LOR 8.4 22 2.3 2 4 1.3 0.03 Median 25.8 11 9.5 0.09 3.2 87.9 8.1 7.5 4.0 2 16.0 29 3.1 4 8 1.4 0.05 Max 28.5 13 11.5 0.11 3.5 94.6 9.2 7.8 5.0 3 21.3 35 3.6 5 12 6.4 0.06 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 67 - 0 - - - - - - - 0 - 12 12 12 18 13 18 18 18 12 12 18 12 13 12 12 18 12 Min 5.5 3 6.0 0.03 3.6 73.3 6.0 6.8 4.0 <LOR 8.0 6 3.6 6 13 <LOR 0.07 Median 14.3 4 7.3 0.07 4.3 85.8 7.3 7.2 4.5 2 18.6 16 4.7 6 14 0.2 0.10 Max 22.5 5 9.5 0.08 8.0 92.1 9.6 7.8 6.0 3 22.1 21 8.1 10 22 5.1 0.11 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 78 - 0 - - - - - - - 0 - n DTC1 DLC1 DTC1 Silicate Reactive (SiO2 mg/L) Potassium Filtered (mg/L) Phosphorus Total (mg/L) Phosphorus Filterable (mg/L) Phaeophytin (ug/L) Nitrogen Total (mg/L) Nitrogen TKN (mg/L) Nitrogen Oxidised (mg/L) Nitrogen Ammoniacal (mg/L) Lorenzen (ug/L) Statistic Station Code Table A62 Blue Mountains system – storages – nutrients DGC1 UV Absorbing constituents (organic) Total Organic Carbon (mg/L) 17 5.5 Turbidity (NTU) Suspended Solids (mg/L) 17 3.5 Temperature (Deg C) Sodium Filtered (mg/L) 17 42.7 Dissolved Oxygen (mg/L) 12 2.7 Conductivity Field (mS/cm) 17 0.02 Calcium Filtered (mg/L) 12 6.0 Min Alkalinity (mgCaCO3/L) 12 <LOR Station Code 12 <LOR n DGC1 Total Hardness (mgCaCO3/L) Table A61 Blue Mountains system – storages – physico-chemical n 12 12 12 12 12 12 12 12 12 12 Min 1.5 0.01 0.01 0.10 0.12 <LOR 0.00 0.00 <LOR 3.2 Median 3.3 0.03 0.03 0.12 0.16 0.2 0.00 0.01 <LOR 3.6 Max 6.3 0.23 0.06 0.30 0.34 1.2 0.01 0.02 <LOR 4.1 Above Max Guideline - - - - 0 - - 50 - - Below Min Guideline - - - - 0 - - 0 - - n 6 6 6 6 6 6 6 6 6 6 Min 1.5 0.01 0.05 0.08 0.16 <LOR <LOR <LOR <LOR 2.9 Median 2.2 0.02 0.07 0.10 0.18 <LOR 0.00 0.00 <LOR 3.3 Max 2.7 0.02 0.10 0.17 0.23 0.5 0.00 0.02 <LOR 4.4 Above Max Guideline - - - - 0 - - 17 - - Below Min Guideline - - - - 0 - - 0 - - n 12 13 13 13 13 12 13 13 12 12 Min 2.5 <LOR 0.00 0.12 0.18 <LOR 0.00 <LOR <LOR 2.1 Median 4.0 0.00 0.04 0.24 0.27 0.3 0.00 0.01 0.5 2.7 Max 9.2 0.02 0.14 0.35 0.39 0.7 0.00 0.01 2 3.3 Above Max Guideline - - - - 15 - - 23 - - Below Min Guideline - - - - 0 - - 0 - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 55 n DGC1 DLC1 Manganese Total (mg/L) Manganese Filtered (mg/L) Magnesium Filtered (mg/L) Iron Total (mg/L) Iron Filtered (mg/L) Aluminium Total (mg/L) 12 12 12 12 12 12 12 Min 0.08 0.15 0.19 0.45 <LOR 0.02 0.02 Median 0.10 0.17 0.30 0.80 <LOR 0.03 0.03 Max 0.18 0.24 6.00 6.45 <LOR 0.07 0.07 Above Max Guideline - 100 - - - - 0 Below Min Guideline - 0 - - - - 0 n 6 6 6 6 6 6 6 Min <LOR 0.01 <LOR 0.09 <LOR 0.00 0.03 Median 0.01 0.02 0.04 0.17 <LOR 0.01 0.04 Max 0.02 0.04 0.10 0.26 1.0 0.03 0.10 Above Max Guideline - 0 - - - - 0 Below Min Guideline - 0 - - - - 0 12 12 12 12 12 12 12 Min <LOR <LOR <LOR <LOR <LOR <LOR 0.01 Median 0.02 0.04 0.06 0.12 1.5 0.00 0.01 Max 0.05 0.06 0.10 0.19 2.0 0.01 0.02 Above Max Guideline - 8 - - - - 0 Below Min Guideline - 0 - - - - 0 n DTC1 Aluminium Filtered (mg/L) Statistic Station Code Table A63 Blue Mountains system – storages – metals 34 34 <LOR <LOR <LOR DGC1 Median 0.71 3490 395 4.3 0.003 <LOR <LOR <LOR <LOR Max 3.90 20210 2525 14.9 0.058 <LOR 0.01 498 498 Above Max Guideline - - - 41 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - n 0 0 0 6 0 0 0 0 0 Min NA NA NA 1.5 NA NA NA NA NA Median NA NA NA 2.2 NA NA NA NA DLC1 NA Max NA NA NA 3.0 NA NA NA NA NA Above Max Guideline - - - 0 NA NA - NA - Below Min Guideline - - - 0 NA NA - NA - 35 35 35 35 35 34 35 35 35 Min 0.15 2940 119 2.1 <LOR <LOR <LOR <LOR <LOR Median 0.72 9120 461 4.5 0.009 <LOR <LOR <LOR <LOR Max 4800 34410 3445 12.8 0.027 <LOR <LOR 28 216 Above Max Guideline - - - 46 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - Statistic n DTC1 Toxic Total Algal Count 34 <LOR Toxic Cyanobacterial Count (cells/mL) 33 <LOR Toxic Cyanobacterial biovolume (mm3/L) 34 1.6 Microcystin LR equiv (ug/L) 34 32 Cyanobacterial biovolume (mm3/L) 34 370 Chlorophyll-a (ug/L) Areal Standard Unit (algae) 34 0.05 n Algal biovolume (mm3/L) 34 Min Station Code Algal Total Count (cells/mL) Table A64 Blue Mountains system – storages – cyanobacteria Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 56 E. coli (orgs/100mL) Enterococci (cfu/100ml) 12 1 NA <LOR 1 Median <LOR 2 NA 1 1 12 17 NA 11 1 Above Max Guideline - - - - - Below Min Guideline - - - - - n 6 6 0 6 0 Statistic Max <LOR <LOR NA <LOR NA Median 1 5 NA 3 NA Max 4 14 NA 10 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 12 12 0 12 1 n Min DTC1 Coliforms Total (cfu/100mL) 0 <LOR Min DLC1 Coliforms Thermotolerant (cfu/100mL) 12 <LOR Station Code 12 Min n DGC1 Clostridium Perfringens Lamp Method Table A65 Blue Mountains system – storages – pathogens <LOR <LOR NA <LOR <LOR Median 1 2 NA 2 <LOR Max 4 35 NA 57 <LOR Above Max Guideline - - - - - Below Min Guideline - - - - - Table A66 Blue Mountains system – storages –heavy metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 57 A4.2 Water filtration plants True Colour at 400nm True Colour at 420nm 12 12 12 12 12 12 12 12 7.1 6.18 8.3 7 3.6 5 12 0.8 0.09 Median Dissolved Oxygen (%Sat) Conductivity (mS/cm) Statistic HCSR UV Absorbing constituents (organic) Total Organic Carbon (mg/L) 12 91.1 Turbidity (NTU) Total Hardness (mgCaCO3/L) 12 3.5 pH 12 0.046 Dissolved Oxygen (mg/L) 12 6 Dissolved Organic Carbon (mg/L) 12 Min Alkalinity (mgCaCO3/L) n Station Code Temperature (Deg C) Table A67 Blue Mountains system – water filtration plant – physico-chemical 14.5 0.067 4.25 98.25 8.6 7.065 16.5 15 4.2 6 14.5 1.05 0.097 Max 23 0.081 9.1 109 11.1 7.77 22.3 21 9 10 23 1.6 0.116 Above Max Guideline 0 - - - - - - 0 - 0 - 0 - Below Min Guideline 0 - - - - - - 0 - 0 - 0 - n HCSR Manganese Total (mg/L) Manganese Filtered (mg/L) Iron Total (mg/L) Iron Filtered (mg/L) Aluminium Total (mg/L) Aluminium Filtered (mg/L) Statistic Station Code Table A68 Blue Mountains system – water filtration plant – metals 12 12 12 12 12 12 Min <LOR <LOR <LOR <LOR <LOR 0.004 Median 0.015 0.02 0.055 0.12 0.001 0.009 0.04 0.09 0.1 0.21 0.003 0.013 Max Above Max Guideline - 0 - 0 - 0 Below Min Guideline - 0 - 0 - 0 12 12 <LOR <LOR <LOR Median 0.475 5980 413 NA NA <LOR <LOR <LOR Max 2.56 16880 1777 NA NA 0.004 56 56 Above Max Guideline - - - - NA - 0 - Below Min Guideline - - - - NA - 0 - Statistic HCSR Toxic Total Algal Count 12 NA Toxic Cyanobacterial Count (cells/mL) 0 NA Toxic Cyanobacterial biovolume (mm3/L) 0 66 Microcystin LR equiv (ug/L) 12 777 n Chlorophyll-a (ug/L) Areal Standard Unit (algae) 12 0.115 Algal biovolume (mm3/L) 12 Min Station Code Algal Total Count (cells/mL) Table A69 Blue Mountains system – water filtration plant - cyanobacteria Enterococci (orgs/100ml) E. coli (orgs/100mL) Coliforms Thermotolerant (cfu/100mL) 12 12 12 12 <LOR <LOR <LOR <LOR Median 0.5 2.5 3.5 4 Max 22 66 34 120 Above Max Guideline - - - - Below Min Guideline - - - - n Min HCSR Clostridium Perfringens Lamp Method Statistic Station Code Table A70 Blue Mountains system – water filtration plant - pathogens Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 58 n HCSR Tin Total (mg/L) Silver Total (mg/L) Selenium Total (mg/L) Molybdenum Total (mg/L) Mercury Total (mg/L) Iodide (mg/L) Boron Total (mg/L) Beryllium-Total (mg/L) Barium Total (mg/L) Arsenic Total (mg/L) Statistic Station Code Table A71 Blue Mountains system – water filtration plant – heavy metals 4 4 4 4 1 4 4 4 1 4 Min <LOR 0.008 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR 0.009 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR 0.01 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 0 0 - Below Min Guideline 0 0 0 0 0 0 0 0 0 - n HCSR Triclopyr (ug/L) Hexazinone (ug/L) Heptachlor (ug/L) Glyphosate (ug/L) Diuron (ug/L) Diquat (ug/L) Diazinon (ug/L) Chlorpyrifos (ug/L) Atrazine (ug/L) Amitrole (ug/L) 2,4-D (ug/L) 2,4,5-T (ug/L) Statistic Station Code Table A72 Blue Mountains system – water filtration plant - pesticides 12 12 1 12 12 12 1 1 12 1 12 12 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 0 0 0 0 0 n HCSR Vinyl chloride (ug/L) Hexachlorobutadiene (ug/L) Gross Beta Gross Alpha Benzene (ug/L) trans-1,2-Dichloroethene (ug/L) 1,2-Dichloroethane (ug/L) Statistic Station Code Table A73 Blue Mountains system – water filtration plant – synthetic organic compounds and radionucleids 12 12 12 1 1 12 12 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 59 A5 Shoalhaven system A5.1 Catchments 7 7 7 7 8 7 10.8 16 2.5 7 16 2.1 0.10 Median 15.0 4 13.0 0.10 4.2 86.7 8.1 7.2 10.0 6 18.4 18 4.1 15 36 4.3 0.14 Max 17.0 5 22.0 0.12 4.7 101.5 11.1 7.6 12.0 9 23.9 25 4.9 21 47 9.2 0.21 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 63 - 0 - - - - - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 Min 9.5 1 9.5 0.07 3.6 94.1 8.8 6.9 6.0 5 8.3 2 3.5 4 10 1.7 0.07 Median 10.8 2 11.0 0.07 4.2 99.3 10.1 7.5 7.5 7 16.0 13 4.5 6 12 4.3 0.09 Max 12.3 3 19.5 0.08 8.3 105.8 11.5 8.2 9.0 12 20.4 16 8.6 10 19 8.6 0.13 Above Max Guideline - - - - - 0 - 8 - - - - - - - 0 - Below Min Guideline - - - - - 0 - 0 - - - - - - - 0 - 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 Min 11.0 3 10.0 0.08 5.5 62.4 5.6 6.4 8.0 2 10.2 16 5.3 13 30 1.8 0.16 Median 15.0 4 12.0 0.10 6.9 88.8 8.0 6.8 10.0 3 19.3 20 6.9 35 82 3.3 0.31 Max 22.5 7 21.0 0.11 13.3 96.3 10.0 7.3 12.5 6 24.9 34 13.0 52 123 19.1 0.67 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 55 - 27 - - - - - - - 0 - 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 Min 13.5 3 9.5 0.09 5.1 69.4 6.6 6.6 8.0 2 9.8 16 4.9 9 23 2.8 0.09 Median 23.0 4 12.0 0.11 6.7 87.1 7.3 7.0 10.0 4 19.1 20 6.4 22 50 4.8 0.27 Max 30.0 8 21.0 0.15 13.1 98.8 10.3 7.4 13.0 7 24.5 36 12.2 61 160 19.5 0.63 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 64 - 0 - - - - - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 Min 9.0 2 12.3 0.08 2.2 36.9 3.1 6.5 9.0 2 11.4 10 2.2 9 22 0.2 0.09 Median 16.7 4 16.3 0.11 4.8 82.4 7.8 6.8 11.5 5 16.5 18 4.7 22 50 3.9 0.20 Max 24.0 6 22.3 0.13 8.7 100.8 10.7 7.3 13.0 9 23.6 31 8.2 47 115 6.1 0.34 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 58 - 8 - - - - - - - 0 - 12 12 12 15 12 15 15 15 12 12 53 12 12 12 12 15 12 Min 10.5 1 9.5 0.07 3.7 78.7 7.1 6.8 6.0 4 8.0 7 3.7 7 16 <LOR 0.11 Median 11.3 2 10.3 0.07 4.4 95.6 9.8 7.4 7.0 10 16.2 13 4.2 11 23 9.3 0.14 Max 13.0 3 20.0 0.08 5.7 107.9 11.5 8.1 8.0 22 24.6 16 5.9 19 45 16.9 0.22 Above Max Guideline - - - - - 0 - 7 - - - - - - - 0 - Below Min Guideline - - - - - 13 - 0 - - - - - - - 0 - Statistic n DFF6 n DTA1 n DTA5 n DTA8 n DWI1 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 60 UV Absorbing constituents (organic) True Colour at 400nm 8 2 Turbidity (NTU) Total Organic Carbon (mg/L) 7 8.0 True Colour at 420nm Suspended Solids (mg/L) 7 6.8 Temperature (Deg C) Sodium Filtered (mg/L) 8 6.5 pH 8 73.1 Dissolved Oxygen (mg/L) 8 2.3 Dissolved Oxygen (%Sat) 7 0.09 Dissolved Organic Carbon (mg/L) 8 10.0 Conductivity Field (mS/cm) Calcium Filtered (mg/L) 7 3 Chloride (mg/L) Alkalinity (mgCaCO3/L) 7 10.0 Station Code 7 Min n DBP1 Total Hardness (mgCaCO3/L) Table A74 Shoalhaven system – catchments – physico-chemical Potassium Filtered (mg/L) E847 E860 E861 12 12 12 12 12 0.2 0.1 0.00 0.02 1 4.3 Median 0.9 0.01 0.1 0.2 0.3 0.7 0.01 0.03 1 6.8 Max 13.9 0.03 0.3 0.2 0.4 3.5 0.02 0.04 1 10.1 Above Max Guideline - - - - 58 - - 92 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.4 0.00 0.0 0.1 0.1 0.1 0.00 0.01 1 0.3 Median 1.1 0.00 0.0 0.1 0.1 0.4 0.01 0.01 1 7.6 Max 2.4 0.02 0.1 0.4 0.5 1.6 0.01 0.04 1 10.0 Above Max Guideline - - - - 8 - - 8 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 0.7 0.00 0.0 0.1 0.1 0.1 0.00 0.00 1 2.0 Median 1.7 0.00 0.0 0.2 0.2 0.1 0.01 0.01 1 6.3 Max 4.8 0.02 0.1 0.6 0.7 0.7 0.01 0.05 2 9.9 Above Max Guideline - - - - 33 - - 25 - - Below Min Guideline - - - - 0 - - 0 - - n 11 11 11 11 11 11 11 11 11 11 Min 0.8 0.00 0.0 0.1 0.1 0.1 0.01 0.02 1 9.2 Median 1.4 0.00 0.0 0.2 0.2 0.3 0.01 0.02 1 10.8 Max Statistic 3.4 0.01 0.1 0.3 0.3 0.9 0.02 0.04 1 12.9 Above Max Guideline - - - - 36 - - 64 - - Below Min Guideline - - - - 0 - - 0 - - n 10 10 10 10 10 10 10 10 10 10 Min 1.2 0.00 0.0 0.1 0.1 0.1 0.00 0.01 1 6.4 Median 3.1 0.00 0.0 0.2 0.2 0.5 0.01 0.01 1 8.2 Max 7.3 0.00 0.0 0.3 0.3 2.5 0.01 0.03 2 10.1 Above Max Guideline - - - - 30 - - 30 - - Below Min Guideline - - - - 0 - - 0 - - 10 10 10 10 10 10 10 10 10 10 Min 0.8 0.00 0.0 0.3 0.3 0.1 0.01 0.02 2 9.7 Median 11.8 0.00 0.0 0.3 0.4 0.9 0.01 0.04 4 14.7 Max n E891 Silicate Reactive (SiO2 mg/L) Phosphorus Total (mg/L) E822 Phosphorus Filterable (mg/L) 12 0.1 Phaeophytin (ug/L) 12 0.0 Nitrogen Total (mg/L) 12 0.00 Nitrogen TKN (mg/L) 12 0.1 Nitrogen Oxidised (mg/L) 12 Min Lorenzen (ug/L) n Station Code E706 Nitrogen Ammoniacal (mg/L) Table A75 Shoalhaven system – catchments – nutrients 87.6 0.13 0.4 0.6 0.8 13.7 0.03 0.22 5 22.1 Above Max Guideline - - - - 100 - - 100 - - Below Min Guideline - - - - 0 - - 0 - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 61 12 12 2 0.01 0.01 E706 Median 0.02 0.12 0.31 0.51 2 0.02 0.02 Max 0.15 0.33 0.52 0.91 4 0.06 0.08 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.05 0.11 0.25 1 0.00 0.01 Median 0.03 0.10 0.21 0.42 1 0.01 0.01 Max 0.26 0.64 0.61 0.88 2 0.03 0.04 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 12 12 12 12 12 12 12 Min 0.01 0.02 0.07 0.14 3 0.00 0.01 Median 0.03 0.09 0.21 0.34 4 0.01 0.02 Max 0.26 1.16 0.46 1.00 5 0.10 0.12 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 11 11 11 11 11 11 11 Min 0.01 0.04 0.23 0.34 2 0.01 0.01 Median 0.02 0.10 0.29 0.64 2 0.01 0.02 Max 0.12 0.52 0.45 1.10 3 0.02 0.04 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 10 10 10 10 10 10 10 Min 0.01 0.04 0.09 0.21 2 0.00 0.01 Median 0.01 0.09 0.28 0.48 3 0.01 0.02 Max 0.10 0.53 0.33 0.74 5 0.01 0.05 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - 10 10 10 10 10 10 10 Min 0.01 0.01 0.03 0.11 15 0.00 0.02 Median 0.01 0.04 0.20 1.08 18 0.12 0.13 Max 0.01 0.73 4.74 15.30 24 4.56 4.51 Above Max Guideline - - - - - - - Below Min Guideline - - - - - - - Statistic n E822 n E847 n E860 n E861 n E891 Manganese Total (mg/L) 12 0.39 Manganese Filtered (mg/L) Magnesium Filtered (mg/L) 12 0.19 Iron Filtered (mg/L) 12 0.06 Aluminium Total (mg/L) 12 0.01 n Aluminium Filtered (mg/L) 12 Min Station Code Iron Total (mg/L) Table A76 Shoalhaven system – catchments – metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 62 n E706 E822 E847 E860 E861 Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Cyanobacterial biovolume (mm3/L) Cyanobacteria Total Count (cells/mL) Chlorophyll-a (ug/L) Areal Standard Unit (algae) Algal Total Count (cells/mL) 1 1 1 12 1 1 0 1 1 Min 2.0 4330 1376 0.1 <LOR <LOR NA <LOR <LOR Median 2.0 4330 1376 1.4 <LOR <LOR NA <LOR <LOR Max 2.0 4330 1376 16.4 <LOR <LOR NA <LOR <LOR Above Max Guideline - - - 8 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.5 NA NA NA NA NA Median NA NA NA 1.2 NA NA NA NA NA Max NA NA NA 2.8 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 12 0 0 0 0 0 Min NA NA NA 0.9 NA NA NA NA NA Median NA NA NA 1.7 NA NA NA NA NA Max NA NA NA 5.0 NA NA NA NA NA Above Max Guideline - - - 8 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 0 0 0 11 0 0 0 0 0 Min NA NA NA 0.9 NA NA NA NA NA Median NA NA NA 1.5 NA NA NA NA NA Max NA NA NA 4.1 NA NA NA NA NA Above Max Guideline - - - 0 - NA NA - NA Below Min Guideline - - - 0 - NA NA - NA n 2 2 2 10 2 2 0 2 2 Min 0.9 4160 864 0.7 197 <LOR NA <LOR <LOR Median 1.7 6155 1800 3.5 356.5 0.01 NA 0.007 174 Max 2.4 8150 2736 8.5 516 0.01 NA 0.013 348 Above Max Guideline - - - 30 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 n 8 8 8 10 8 8 0 8 8 0.2 368 166 0.9 <LOR <LOR NA <LOR <LOR Min E891 Algal biovolume (mm3/L) Statistic Station Code Table A77 Shoalhaven system – catchments – cyanobacteria Median 1.1 3735 856 12.6 578 0.02 NA 0.005 268 141.6 11170 18150 99.0 7950 0.86 NA 0.225 1490 Above Max Guideline - - - 80 - 0 NA - 0 Below Min Guideline - - - 0 - 0 NA - 0 Max Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 63 Coliforms Thermotolerant (cfu/100mL) Coliforms Total (cfu/100mL) E. coli (orgs/100mL) Enterococci (orgs/100ml) n 6 12 0 12 12 Min 1 25 NA 70 25 Median 10 160 NA 280 59 Max 25 1200 NA 1300 410 Above Max Guideline - - - - - Below Min Guideline - - - - - n 2 12 0 12 12 Min 3 3 NA 5 6 Median 3 27 NA 26 33 Max 3 380 NA 1400 260 Above Max Guideline - - - - - Below Min Guideline - - - - - n 5 12 0 12 12 Min 1 2 NA 2 6 Median 4 8 NA 4 15 Max E706 E822 E847 E860 E861 E891 Statistic Station Code Clostridium Perfringens Lamp Method Table A78 Shoalhaven system – catchments – pathogens 14 62 NA 88 96 Above Max Guideline - - - - - Below Min Guideline - - - - - n 2 11 0 11 11 Min 4 4 NA 1 6 Median 5 23 NA 16 15 Max 6 240 NA 133 110 Above Max Guideline - - - - - Below Min Guideline - - - - - n 3 10 0 10 10 Min 2 1 NA 2 2 Median 3 12 NA 9 14 Max 7 110 NA 120 32 Above Max Guideline - - - - - Below Min Guideline - - - - - n 2 10 0 10 10 Min 4 8 NA 8 5 Median 4 27 NA 31 27 Max 4 850 NA 390 320 Above Max Guideline - - - - - Below Min Guideline - - - - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 64 A5.2 Storages 7 7 7 7 8 7 10.8 16 2.5 7 16 2.1 0.10 Median 15.0 4 13.0 0.10 4.2 86.7 8.1 7.2 10.0 6 18.4 18 4.1 15 36 4.3 0.14 Max 17.0 5 22.0 0.12 4.7 101.5 11.1 7.6 12.0 9 23.9 25 4.9 21 47 9.2 0.21 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 63 - 0 - - - - - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 Min 9.5 1 9.5 0.07 3.6 94.1 8.8 6.9 6.0 5 8.3 2 3.5 4 10 1.7 0.07 Median 10.8 2 11.0 0.07 4.2 99.3 10.1 7.5 7.5 7 16.0 13 4.5 6 12 4.3 0.09 Max 12.3 3 19.5 0.08 8.3 105.8 11.5 8.2 9.0 12 20.4 16 8.6 10 19 8.6 0.13 Above Max Guideline - - - - - 0 - 8 - - - - - - - 0 - Below Min Guideline - - - - - 0 - 0 - - - - - - - 0 - 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 Min 11.0 3 10.0 0.08 5.5 62.4 5.6 6.4 8.0 2 10.2 16 5.3 13 30 1.8 0.16 Median 15.0 4 12.0 0.10 6.9 88.8 8.0 6.8 10.0 3 19.3 20 6.9 35 82 3.3 0.31 Max 22.5 7 21.0 0.11 13.3 96.3 10.0 7.3 12.5 6 24.9 34 13.0 52 123 19.1 0.67 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 55 - 27 - - - - - - - 0 - 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 Min 13.5 3 9.5 0.09 5.1 69.4 6.6 6.6 8.0 2 9.8 16 4.9 9 23 2.8 0.09 Median 23.0 4 12.0 0.11 6.7 87.1 7.3 7.0 10.0 4 19.1 20 6.4 22 50 4.8 0.27 Max 30.0 8 21.0 0.15 13.1 98.8 10.3 7.4 13.0 7 24.5 36 12.2 61 160 19.5 0.63 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 64 - 0 - - - - - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 Min 9.0 2 12.3 0.08 2.2 36.9 3.1 6.5 9.0 2 11.4 10 2.2 9 22 0.2 0.09 Median 16.7 4 16.3 0.11 4.8 82.4 7.8 6.8 11.5 5 16.5 18 4.7 22 50 3.9 0.20 Max 24.0 6 22.3 0.13 8.7 100.8 10.7 7.3 13.0 9 23.6 31 8.2 47 115 6.1 0.34 Above Max Guideline - - - - - 0 - 0 - - - - - - - 0 - Below Min Guideline - - - - - 58 - 8 - - - - - - - 0 - 12 12 12 15 12 15 15 15 12 12 53 12 12 12 12 15 12 Min 10.5 1 9.5 0.07 3.7 78.7 7.1 6.8 6.0 4 8.0 7 3.7 7 16 <LOR 0.11 Median 11.3 2 10.3 0.07 4.4 95.6 9.8 7.4 7.0 10 16.2 13 4.2 11 23 9.3 0.14 Max 13.0 3 20.0 0.08 5.7 107.9 11.5 8.1 8.0 22 24.6 16 5.9 19 45 16.9 0.22 Above Max Guideline - - - - - 0 - 7 - - - - - - - 0 - Below Min Guideline - - - - - 13 - 0 - - - - - - - 0 - Statistic n DFF6 n DTA1 n DTA5 n DTA8 n DWI1 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 65 UV Absorbing constituents (organic) True Colour at 400nm 8 2 Turbidity (NTU) Total Organic Carbon (mg/L) 7 8.0 True Colour at 420nm Suspended Solids (mg/L) 7 6.8 Temperature (Deg C) Sodium Filtered (mg/L) 8 6.5 pH 8 73.1 Dissolved Oxygen (mg/L) 8 2.3 Dissolved Oxygen (%Sat) 7 0.09 Dissolved Organic Carbon (mg/L) 8 10.0 Conductivity Field (mS/cm) Calcium Filtered (mg/L) 7 3 Chloride (mg/L) Alkalinity (mgCaCO3/L) 7 10.0 Station Code 7 Min n DBP1 Total Hardness (mgCaCO3/L) Table A79 Shoalhaven system – storages – physico-chemical n DFF6 DTA1 DTA5 DTA8 Silicate Reactive (SiO2 mg/L) Potassium Filtered (mg/L) Phosphorus Total (mg/L) Phosphorus Filterable (mg/L) Phaeophytin (ug/L) Nitrogen Total (mg/L) Nitrogen TKN (mg/L) Nitrogen Oxidised (mg/L) 7 7 7 7 6 7 7 7 7 <LOR <LOR 0.15 0.24 0.5 0.00 0.02 <LOR 0.2 Median 7.2 0.02 0.06 0.26 0.32 1.6 0.00 0.02 1 4.2 Max 32.1 0.03 0.34 0.32 0.59 7.5 0.01 0.03 1 9.9 Above Max Guideline - - - - 43 - - 100 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 6.7 <LOR <LOR 0.22 0.22 <LOR <LOR 0.00 <LOR 0.0 Median 9.0 <LOR 0.00 0.29 0.30 1.1 0.00 0.01 <LOR 0.2 Max 15.4 <LOR 0.13 0.37 0.43 2.1 0.00 0.02 1 0.5 Above Max Guideline - - - - 25 - - 83 - - Below Min Guideline - - - - 0 - - 0 - - n 11 11 11 11 11 11 11 11 11 11 Min 1.0 <LOR <LOR 0.21 0.21 <LOR 0.00 0.01 <LOR 2.9 Median 4.0 0.02 0.10 0.27 0.39 0.7 0.01 0.02 1 4.9 Max 8.3 0.05 0.18 0.59 0.69 4.1 0.01 0.04 2 6.4 Above Max Guideline - - - - 64 - - 91 - - Below Min Guideline - - - - 0 - - 0 - - n 11 11 11 11 11 11 11 11 11 11 Min 0.9 <LOR <LOR 0.19 0.21 <LOR 0.00 0.01 1 3.2 Median 3.3 0.02 0.07 0.29 0.30 0.8 0.00 0.02 1 5.9 Max 10.8 0.08 0.14 0.55 0.66 2.5 0.01 0.04 2 8.4 Above Max Guideline - - - - 45 - - 100 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 12 12 Min 2.1 0.00 <LOR 0.12 0.18 0.2 0.00 0.01 <LOR 0.8 Median 7.2 0.02 0.05 0.25 0.30 2.1 0.00 0.02 0.625 5.0 Max 42.7 0.09 0.33 0.31 0.44 6.4 0.01 0.03 1 9.8 Above Max Guideline - - - - 33 - - 100 - - Below Min Guideline - - - - 0 - - 0 - - 12 12 12 12 12 12 12 12 12 12 Min 4.6 <LOR <LOR 0.23 0.23 0.1 <LOR 0.01 <LOR <LOR Median 11.6 <LOR <LOR 0.29 0.30 1.6 0.00 0.02 0.5 0.3 Max 17.4 0.02 0.13 0.33 0.41 5.5 0.01 0.03 1 1.3 Above Max Guideline - - - - 17 - - 92 - - Below Min Guideline - - - - 0 - - 0 - - n DWI1 Nitrogen Ammoniacal (mg/L) 6 5.7 Min DBP1 Lorenzen (ug/L) Statistic Station Code Table A80 Shoalhaven system – storages – nutrients Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 66 n DBP1 Manganese Total (mg/L) Manganese Filtered (mg/L) 7 7 7 0.14 2.0 <LOR 0.01 Median 0.02 0.13 0.21 0.52 2.0 0.00 0.02 Max 0.07 0.41 0.29 0.79 3.0 0.02 0.06 Above Max Guideline - 86 - - - - 0 Below Min Guideline - 0 - - - - 0 12 12 12 12 12 12 12 Min <LOR 0.06 <LOR 0.12 <LOR <LOR 0.01 Median 0.02 0.14 <LOR 0.20 2.0 <LOR 0.01 Max 0.07 0.29 0.11 0.44 2.0 0.00 0.02 Above Max Guideline - 92 - - - - 0 Below Min Guideline - 0 - - - - 0 11 11 11 11 11 11 11 Min 0.01 0.04 0.07 0.13 2.0 <LOR 0.02 Median 0.08 0.23 0.31 0.56 2.5 0.02 0.03 Max 0.27 0.87 0.43 0.86 4.0 0.12 0.14 Above Max Guideline - 91 - - - - 0 Below Min Guideline - 0 - - - - 0 11 11 11 11 11 11 11 Min <LOR 0.05 0.08 0.28 2.0 0.01 0.02 Median 0.07 0.22 0.36 0.66 2.5 0.03 0.06 Max 0.33 0.96 0.49 0.92 4.0 0.10 0.14 Above Max Guideline - 91 - - - - 0 Below Min Guideline - 0 - - - - 0 12 12 12 12 12 12 12 Min 0.00 0.04 0.21 0.52 1.3 0.01 0.02 Median 0.02 0.11 0.31 0.63 2.0 0.02 0.03 Max 0.12 0.25 0.48 1.07 4.0 0.09 0.15 Above Max Guideline - 92 - - - - 0 Below Min Guideline - 0 - - - - 0 12 12 12 12 12 12 12 Min 0.01 0.10 0.03 0.17 1.0 <LOR 0.01 Median 0.05 0.25 0.18 0.52 2.0 0.00 0.03 Max 0.12 0.52 0.34 0.80 2.0 0.01 0.08 Above Max Guideline - 100 - - - - 0 Below Min Guideline - 0 - - - - 0 n DWI1 Magnesium Filtered (mg/L) 7 <LOR n DTA8 Iron Total (mg/L) 7 0.03 n DTA5 Iron Filtered (mg/L) 7 <LOR n DTA1 Aluminium Total (mg/L) 7 Min n DFF6 Aluminium Filtered (mg/L) Statistic Station Code Table A81 Shoalhaven system – storages – metals Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 67 DTA1 DTA5 Toxic Total Algal Count Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Cyanobacterial biovolume (mm3/L) 34 34 34 34 34 34 103 4.4 <LOR <LOR <LOR <LOR <LOR Median 1.87 73515 1596 10.6 0.040 <LOR <LOR <LOR 159 Max 8.82 1967000 5579 33.6 0.851 <LOR 0.17 3930 3930 Above Max Guideline - - - 97 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - 12 12 12 12 12 0 12 12 12 Min 0.64 2700 343 7.1 <LOR NA <LOR <LOR <LOR Median 1.44 78900 1532 9.8 0.100 NA <LOR <LOR <LOR Max 5.92 763500 2478 15.8 0.322 NA 0.02 1490 1490 Above Max Guideline - - - 100 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - n 5 5 5 11 5 0 5 5 5 Min 1.28 11720 867 1.0 0.003 NA <LOR <LOR <LOR Median 1.83 31640 1511 4.1 0.033 NA <LOR <LOR <LOR Max 5.10 467900 2669 9.8 0.194 NA 0.02 161 161 Above Max Guideline - - - 45 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - n 5 5 5 11 5 0 5 5 5 Min 0.05 910 59 0.9 <LOR NA <LOR <LOR <LOR Median 1.36 15170 857 3.9 0.009 NA <LOR <LOR 15 Max 1.91 84900 1329 7.8 0.033 NA <LOR 15 90 Above Max Guideline - - - 45 0 NA - 0 - Below Min Guideline - - - 0 0 NA - 0 - 35 35 35 35 35 33 35 35 35 <LOR Min 0.01 18 6 0.7 <LOR <LOR <LOR <LOR Median 0.79 18590 643 7.8 0.008 <LOR <LOR <LOR 7 Max 17.65 99625 6324 156.1 0.108 <LOR 0.05 3075 3110 Above Max Guideline - - - 71 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - 35 35 35 35 35 34 35 35 35 Min 0.70 13185 530 4.4 0.005 <LOR <LOR <LOR <LOR Median 1.45 43970 1252 13.9 0.032 <LOR 0.00 272 340 Max 7.42 177600 2912 26.6 0.218 <LOR 0.05 3260 3260 Above Max Guideline - - - 97 0 0 - 0 - Below Min Guideline - - - 0 0 0 - 0 - n DWI1 Chlorophyll-a (ug/L) 34 609 n DTA8 Areal Standard Unit (algae) 34 0.18 n DFF6 Algal Total Count (cells/mL) 34 Min n DBP1 Algal biovolume (mm3/L) Statistic Station Code Table A82 Shoalhaven system – storages – cyanobacteria Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 68 Coliforms Total (cfu/100mL) E. coli (orgs/100mL) 7 0 7 0 <LOR 4 NA 5 NA Median Statistic n DBP1 <LOR 19 NA 15 NA Max 2 39 NA 47 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 12 12 0 12 0 n Min DFF6 <LOR <LOR NA <LOR NA Median 0 1 NA 0 NA Max 4 2 NA 2 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 11 11 0 11 0 n Min DTA1 <LOR <LOR NA <LOR NA Median 1 2 NA 2 NA Max 19 37 NA 34 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 11 11 0 11 0 n Min DTA5 DTA8 <LOR <LOR NA <LOR NA Median 1 2 NA 2 NA Max 15 36 NA 74 NA Above Max Guideline - - - - - Below Min Guideline - - - - - n 12 12 0 12 0 Min 1 5 NA 4 NA Median 3 40 NA 44 NA Max 20 263 NA 417 NA Above Max Guideline - - - - - Below Min Guideline - - - - - 12 12 0 12 0 n Min DWI1 Enterococci (cfu/100ml) Coliforms Thermotolerant (cfu/100mL) 7 Min Station Code Clostridium Perfringens Lamp Method Table A83 Shoalhaven system – storages – pathogens <LOR <LOR NA <LOR NA Median 1 1 NA 1 NA Max 7 14 NA 15 NA Above Max Guideline - - - - - Below Min Guideline - - - - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 69 Table A84 Shoalhaven system – storages – heavy metals Giardia IFA /10L Adj for Recovery n 52 52 % <LOR 98 94 Min* 1 2 Median* 1 2 Max* 1 5 DWI1 Statistic Station Code Crypto IFA /10L Adj for Recovery Table A85 Shoalhaven system – storages – Cryptosporidium and Giardia * detection samples only Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 70 A5.3 Water filtration plants True Colour at 420nm 13 13 12 12 12 12 13 12 8.33 6.8 8.5 <LOR 3.5 6 15 2.3 0.106 HKV1 pH Dissolved Oxygen (%Sat) Conductivity (mS/cm) Statistic Median UV Absorbing constituents (organic) True Colour at 400nm 13 91.8 Turbidity (NTU) Total Organic Carbon (mg/L) 13 3.6 Temperature (Deg C) 12 0.071 Dissolved Oxygen (mg/L) 13 10 Dissolved Organic Carbon (mg/L) 12 Min Alkalinity (mgCaCO3/L) n Station Code HWI1 Total Hardness (mgCaCO3/L) Table A86 Shoalhaven system – water filtration plants – physico-chemical 11.5 0.074 4.2 96.4 9.75 7.2 16.4 13 3.95 11.5 25 6.7 0.145 Max 14 0.08 6.4 104.2 11.59 7.7 20.2 16 6.3 15 34 12.6 0.217 Above Max Guideline 0 - - - - - - 0 - 0 - 0 - Below Min Guideline 0 - - - - - - 0 - 0 - 0 - n 12 13 12 13 13 13 13 12 12 12 12 13 12 Min 9 0.06 2.3 74.3 6.54 6.7 10.9 <LOR 2.5 7 16 1.6 0.061 Median 15 0.092 4.65 97.1 8.58 7.3 19.2 16 4.6 14 33 4 0.153 Max 22 0.122 6.9 120.8 11.6 8.3 24.1 25 6.8 30 65 14.3 0.28 Above Max Guideline 0 - - - - - - 0 - 0 - 0 - Below Min Guideline 0 - - - - - - 0 - 0 - 0 - n Manganese Total (mg/L) Manganese Filtered (mg/L) Iron Total (mg/L) 12 12 12 12 12 0.03 <LOR 0.11 <LOR 0.017 Median 0.02 0.145 0.18 0.44 0.006 0.03 Max 0.07 0.4 0.37 0.84 0.027 0.121 - Above Max Guideline - - - 0 - Below Min Guideline - - - 0 - n - 12 12 12 12 12 12 <LOR 0.02 <LOR 0.09 <LOR 0.01 Median 0.05 0.22 0.2 0.475 0.002 0.025 Max 0.12 0.54 0.34 0.85 0.011 0.076 Min HWI1 Iron Filtered (mg/L) 12 <LOR Min HKV1 Aluminium Total (mg/L) Aluminium Filtered (mg/L) Statistic Station Code Table A87 Shoalhaven system – water filtration plants - metals Above Max Guideline - - - 0 - - Below Min Guideline - - - 0 - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 71 n HKV1 Toxic Total Algal Count Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Chlorophyll-a (ug/L) Areal Standard Unit (algae) 12 12 12 0 0 12 12 12 Min 0.821 2200 429 NA NA <LOR <LOR <LOR Median 2.3335 41580 1701 NA NA <LOR <LOR <LOR 13.4 3249000 7862 NA NA 0.041 769 838 Above Max Guideline - - - - NA - 0 - Below Min Guideline - - - - NA - 0 - 12 12 12 0 0 12 12 12 Max n HWI1 Algal Total Count (cells/mL) Algal biovolume (mm3/L) Statistic Station Code Table A88 Shoalhaven system – water filtration plants - cyanobacteria Min 0.415 8990 395 NA NA 0.001 71 71 Median 1.1645 32440 943 NA NA 0.0085 456.5 458.5 Max 2.575 142100 1956 NA NA 0.027 1860 2080 Above Max Guideline - - - - NA - 0 - Below Min Guideline - - - - NA - 0 - HKV1 12 12 12 <LOR 1 <LOR Enterococci (orgs/100ml) 12 <LOR 0.5 8.5 5.5 4.5 Max 6 49 45 47 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 <LOR Median n <LOR <LOR <LOR Median 2 1 1 2 Max 4 16 16 19 Above Max Guideline - - - - Below Min Guideline - - - - Min HWI1 E. coli (orgs/100mL) Min Coliforms Thermotolerant (cfu/100mL) n Clostridium Perfringens Lamp Method Statistic Station Code Table A89 Shoalhaven system – water filtration plants - pathogens Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 72 n HKV1 HWI1 Tin Total (mg/L) Silver Total (mg/L) Selenium Total (mg/L) Molybdenum Total (mg/L) Mercury Total (mg/L) Iodide (mg/L) Boron Total (mg/L) Beryllium-Total (mg/L) Barium Total (mg/L) Arsenic Total (mg/L) Statistic Station Code Table A90 Shoalhaven system – water filtration plants – heavy metals 4 4 4 4 1 4 4 4 1 4 Min <LOR 0.01 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR 0.012 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR 0.014 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 0 0 - Below Min Guideline 0 0 0 0 0 0 0 0 0 - n 4 4 4 4 1 4 4 4 1 4 Min <LOR 0.008 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR 0.01 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR 0.01 <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 0 0 - Below Min Guideline 0 0 0 0 0 0 0 0 0 - n HKV1 HWI1 Triclopyr (ug/L) Hexazinone (ug/L) Heptachlor (ug/L) Glyphosate (ug/L) Diuron (ug/L) Diquat (ug/L) Diazinon (ug/L) Chlorpyrifos (ug/L) Atrazine (ug/L) Amitrole (ug/L) 2,4-D (ug/L) 2,4,5-T (ug/L) Statistic Station Code Table A91 Shoalhaven system – water filtration plants - pesticides 1 12 1 1 12 12 1 1 12 1 1 12 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR 0.02 Above Max Guideline 0 0 0 0 0 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 0 0 0 0 0 n 1 12 1 1 12 12 1 1 12 1 1 12 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR 0.04 Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR <LOR 0.14 Above Max Guideline 0 0 0 0 0 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 0 0 0 0 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 73 n HKV1 HWI1 Vinyl chloride (ug/L) Hexachlorobutadiene (ug/L) Gross Beta Gross Alpha Benzene (ug/L) trans-1,2-Dichloroethene (ug/L) 1,2-Dichloroethane (ug/L) Statistic Station Code Table A92 Shoalhaven system – water filtration plants – synthetic organic compounds and radionucleids 12 12 12 1 1 12 12 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 n 12 12 12 1 1 12 12 Min <LOR <LOR <LOR <LOR <LOR <LOR <LOR Median <LOR <LOR <LOR <LOR <LOR <LOR <LOR Max <LOR <LOR <LOR <LOR <LOR <LOR <LOR Above Max Guideline 0 0 0 0 0 0 0 Below Min Guideline 0 0 0 0 0 0 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 74 A5.4 Picnic areas Turbidity Field (NTU) Temperature (Deg C) pH (Field) Manganese Total (mg/L) Manganese Filtered (mg/L) Iron Total (mg/L) Iron Filtered (mg/L) E. coli (orgs/100mL) Dissolved Oxygen (mg/L) Dissolved Oxygen (%Sat) Conductivity Field (mS/cm) Chlorine Residual (mg/L) Aluminium Total (mg/L) 52 52 52 52 52 51 52 52 52 52 52 52 52 0.03 0.03 0.4 0.116 91.4 8.4 <LOR <LOR <LOR <LOR 0.002 7.3 9.1 <LOR Median 0.065 0.09 0.88 0.219 99.45 9.695 <LOR <LOR <LOR <LOR 0.01 8 15.8 <LOR 0.1 0.15 8.8 0.233 109.3 11.81 <LOR 0.05 0.15 0.004 0.036 8.3 23.7 5.3 Above Max Guideline - 0 96 - - - 0 - 0 - 0 0 - 2 Below Min Guideline - 0 0 - - - 0 - 0 - 0 0 - 0 Toxic Cyanobacterial Count (cells/mL) HFFR 52 Min Toxic Cyanobacterial biovolume (mm3/L) n Aluminium Filtered (mg/L) Statistic Station Code Table A93 Shoalhaven system – picnic areas Max n HFFR Microcystin LR equiv (ug/L) Chlorophyll-a (ug/L) Areal Standard Unit (algae) Algal Total Count (cells/mL) Algal biovolume (mm3/L) Statistic Station Code Table A94 Shoalhaven system – picnic areas - cyanobacteria 2 2 2 51 0 2 2 Min <LOR <LOR <LOR <LOR NA <LOR <LOR Median <LOR 14 1 <LOR NA <LOR <LOR Max <LOR 28 2 24.1 NA <LOR <LOR Above Max Guideline - - - 4 NA - 0 Below Min Guideline - - - 0 NA - 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 75 A6 Downstream rivers n E303 N35 N42 N44 N57 UV Absorbing constituents (organic) Turbidity Field (NTU) True Colour at 400nm Temperature (Deg C) Suspended Solids (mg/L) pH (Field) Dissolved Oxygen (mg/L) 0 0 0 0 0 0 0 0 NA NA NA NA NA NA NA NA NA Median NA NA NA NA NA NA NA NA NA NA NA Max NA NA NA NA NA NA NA NA NA NA NA Above Max Guideline - - - NA - NA - - - NA - Below Min Guideline - - - NA - NA - - - NA - 12 12 12 12 12 12 12 12 12 12 12 7 0.076 2.3 78.1 7.61 6.2 1 11.5 15 1 0.162 16.5 0.099 5.65 104.9 8.925 7 2 18.25 29.5 2.8 0.256 24 0.112 10.3 112.6 12.26 7.6 17 25.5 58 17.9 0.49 Above Max Guideline - - - 17 - 0 - - - 0 - Below Min Guideline - - - 8 - 17 - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 Median Max Min N21 Dissolved Oxygen (%Sat) 0 NA n N14 Dissolved Organic Carbon (mg/L) 0 NA Min G0515 Conductivity Field (mS/cm) 0 Min n E851 Alkalinity (mgCaCO3/L) Statistic Station Code Table A95 Downstream of storages – physico-chemical 4 0.119 3.2 51.3 4.61 6.1 <LOR 10.2 8 <LOR 0.085 Median 7.5 0.149 4.75 63.35 6 6.35 0.5 18.2 11 1.25 0.121 Max 10 0.164 6.7 83.9 9.76 6.6 4 22.7 19 3.4 0.17 Above Max Guideline - - - 0 - 0 - - - 0 - Below Min Guideline - - - 100 - 75 - - - 0 - n 11 8 11 12 12 12 11 12 11 12 11 Min 26 0.23 1.4 66.8 5.1 6.89 5 13 6 5.4 0.1 Median 49 7.657 2 91.75 7.8 7.365 13 21.05 8 9.05 0.112 Max 63 21.6 16.6 102 10.1 7.6 18 27.3 23 28 0.31 Above Max Guideline - - - 0 - 0 - - - 0 - Below Min Guideline - - - 33 - 0 - - - 0 - n 11 11 10 12 12 12 11 12 11 12 11 Min 26 0.191 3.4 74.7 6 7.08 <LOR 13.4 6 3.7 0.077 Median 34 0.269 4.4 95.95 8.65 7.56 8 20.8 10 7 0.145 Max 38 0.757 5.2 111 10.7 8.01 16 27 19 12 0.194 Above Max Guideline - - - 8 - 0 - - - 0 - Below Min Guideline - - - 8 - 0 - - - 0 - n 11 11 10 12 12 12 11 12 11 12 11 Min 25 0.192 3.4 69.3 5.6 6.84 3 12.5 8 7.7 0.122 Median 37 0.295 4.7 91.2 8.15 7.415 13 20.85 11 14 0.163 Max 59 0.403 6.3 104.5 10 7.68 24 27.4 19 27 0.221 Above Max Guideline - - - 0 - 0 - - - 0 - Below Min Guideline - - - 17 - 0 - - - 0 - n 12 13 12 13 13 13 12 13 10 13 12 Min 12 0.135 3.3 78.4 6.1 6.92 3 13 8 4.3 0.095 Median 31 0.236 4.25 97.5 9.1 7.32 6.5 21.9 10 6.5 0.129 Max 50 0.308 6.5 118.8 11 7.53 11 28.6 19 19 0.21 Above Max Guideline - - - 15 - 0 - - - 0 - Below Min Guideline - - - 23 - 0 - - - 0 - n 12 13 12 13 13 13 12 13 10 13 12 Min 20 0.158 4 70.4 5.8 7.12 2 13.6 8 3.6 0.099 Median 36 0.258 4.75 95.6 8.7 7.53 4.5 21.8 9.5 5.2 0.131 Max 56 0.338 6.6 116.8 11.3 7.94 21 26.7 20 7.2 0.211 Above Max Guideline - - - 15 - 0 - - - 0 - Below Min Guideline - - - 8 - 0 - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 Min 18 0.153 3.8 77.1 6.2 6.89 3 12.9 7 3.1 0.113 Median 33 0.261 4.7 96.15 8.65 7.355 5 19.95 10 5.05 0.131 Max 54 0.303 10.8 110.3 11.3 7.83 6 25.7 20 6.8 0.224 Above Max Guideline - - - 8 - 0 - - - 0 - Below Min Guideline - - - 17 - 0 - - - 0 - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 76 Temperature (Deg C) True Colour at 400nm 12 12 12 12 12 12 7.7 7.23 1 11.9 8 2.2 0.114 N64 33.5 0.26 4.75 101.9 9.2 7.515 3.5 19.4 12.5 4.3 0.13 53 0.371 30 112.5 11.5 7.96 6 26.4 20 15 0.204 Above Max Guideline - - - 8 - 0 - - - 0 - Below Min Guideline - - - 0 - 0 - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 Statistic Median Max n Min N641 N67 31 0.165 4.5 90.2 7.7 7.04 2 11.7 11 1.8 0.129 36.5 0.198 5.55 101.3 10.2 7.42 2 18.25 14 3.5 0.172 47 0.27 12.8 133.3 11.7 7.68 4 22.8 20 9 0.218 Above Max Guideline - - - 33 - 0 - - - 0 - Below Min Guideline - - - 0 - 0 - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 Min 15 0.174 3.9 81.4 6.6 7.04 <LOR 10.7 7 3.3 0.121 Median 35 0.297 4.55 105.6 9.6 7.555 4 21.5 11.5 5.55 0.147 Max 59 0.342 5.4 123.9 10.8 7.92 7 27.4 23 8.2 0.217 Above Max Guideline - - - 33 - 0 - - - 0 - Below Min Guideline - - - 8 - 0 - - - 0 - 12 12 12 12 12 12 12 12 12 12 12 Median Max n Min N75 N85 N86 N881 N92 UV Absorbing constituents (organic) Suspended Solids (mg/L) 12 90.7 Turbidity Field (NTU) pH (Field) 12 4 Dissolved Oxygen (mg/L) Dissolved Organic Carbon (mg/L) 12 0.181 Dissolved Oxygen (%Sat) Conductivity Field (mS/cm) 12 26 Alkalinity (mgCaCO3/L) 12 Min Station Code n 17 0.157 3.9 90.9 7.5 7.01 <LOR 11.2 10 3 0.125 29.5 0.221 4.6 102.9 9.6 7.515 2.5 20.75 14.5 3.9 0.141 52 0.306 5.4 114.3 10.8 7.87 4 26.8 21 5.9 0.199 Above Max Guideline - - - 17 - 0 - - - 0 - Below Min Guideline - - - 0 - 0 - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 Min 13 0.114 3.1 75.8 6.3 6.97 2 11.2 10 1.9 0.123 Median 23 0.14 4.65 87 8 7.58 2 19.55 14 2.8 0.138 Max 64 0.239 15.9 115.6 10.3 8.25 4 25.4 21 5.6 0.191 Above Max Guideline - - - 8 - 0 - - - 0 - Below Min Guideline - - - 50 - 0 - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 Min 5 0.078 3.8 96.7 9.1 6.7 <LOR 9.3 6 <LOR 0.064 Median 8 0.088 4.65 108.3 10.71 7.3 0.5 17.55 14 1.15 0.131 Max 11 0.094 5.5 117.3 12.02 7.6 2 25 23 5 0.179 Above Max Guideline - - - 25 - 0 - - - 0 - Below Min Guideline - - - 0 - 0 - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 Min 2 0.077 4.1 105.2 9.21 6.7 <LOR 10.7 13 <LOR 0.113 Median 6 0.083 4.7 107.2 10.41 7.05 <LOR 16.3 15 <LOR 0.136 Max 10 0.089 5.8 109.8 12.18 7.8 2 23.2 22 27.5 0.201 Above Max Guideline - - - 0 - 0 - - - 0 - Below Min Guideline - - - 0 - 0 - - - 0 - n 12 12 12 12 12 12 12 12 12 12 12 Min 24 0.114 1.2 80 6.78 7.1 <LOR 11.2 8 <LOR 0.079 Median 58 0.211 4.65 105.6 9.47 7.55 1.5 19.8 13.5 1.55 0.136 Max 140 0.369 7.6 116.9 11.5 8.5 3 25.4 26 3.7 0.24 Above Max Guideline - - - 33 - 0 - - - 0 - Below Min Guideline - - - 8 - 0 - - - 0 - Median Max Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 77 n E303 E851 G0515 Silicate Reactive (SiO2 mg/L) Potassium Filtered (mg/L) Phosphorus Total (mg/L) Phosphorus Filterable (mg/L) 0 0 0 0 0 NA NA NA NA NA NA Median NA NA NA NA NA NA NA NA NA NA Max NA NA NA NA NA NA NA NA NA NA Above Max Guideline - - - - NA - - NA - - Below Min Guideline - - - - NA - - NA - - n 12 12 12 12 12 12 12 12 0 12 Min 0.4 <LOR 0.018 0.15 0.22 <LOR <LOR 0.013 NA 2.86 Median 4.2 0.016 0.127 0.26 0.38 0.8 0.006 0.022 NA 5.49 Max 8.7 0.035 0.191 0.44 0.57 1.8 0.013 0.044 NA 7.15 Above Max Guideline - - - - 8 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 0 12 Min 0.5 <LOR <LOR 0.07 0.07 <LOR 0.001 <LOR NA 0.94 Median 1.1 <LOR 0.007 0.12 0.135 <LOR 0.002 0.005 NA 2 Max 1.8 0.006 0.047 0.2 0.2 0.6 0.007 0.018 NA 3.26 Above Max Guideline - - - - 0 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - 12 11 11 11 11 12 11 11 0 11 Min 3.8 <LOR 0.002 0.22 0.24 <LOR <LOR <LOR NA 0.15 Median 8.95 <LOR 0.138 0.28 0.41 1.05 0.004 0.011 NA 0.91 Max 16.7 0.013 0.296 0.36 0.63 2.8 0.008 0.038 NA 3.18 Above Max Guideline - - - - 18 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - 12 11 11 11 11 12 11 11 0 11 6.3 <LOR <LOR 0.21 0.24 0.3 0.001 0.007 NA 0.09 Median 17.35 <LOR 0.036 0.25 0.37 1.25 0.003 0.015 NA 0.34 Max 65.2 0.011 0.303 0.4 0.51 3.1 0.01 0.035 NA 3.24 Above Max Guideline - - - - 9 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - 12 11 11 11 11 12 11 11 0 11 6.9 <LOR 0.008 0.2 0.36 0.6 <LOR 0.014 NA 0.16 Median 25.15 0.012 0.29 0.32 0.55 2.45 0.004 0.027 NA 1.96 Max 33.6 0.028 0.627 0.4 0.83 5.6 0.006 0.053 NA 3.38 Above Max Guideline - - - - 64 - - 9 - - Below Min Guideline - - - - 0 - - 0 - - 13 12 12 12 12 13 12 12 0 12 0.07 n Min 4.4 <LOR 0.038 0.08 0.35 1 <LOR 0.008 NA Median 10.3 0.004 0.175 0.28 0.475 2.5 0.003 0.026 NA 1.7 40 0.079 0.408 0.46 0.68 6.8 0.006 0.038 NA 3.72 Above Max Guideline - - - - 42 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 13 12 12 12 12 13 12 12 0 12 Min 3.6 <LOR 0.03 0.13 0.39 0.5 <LOR 0.015 NA <LOR Median 10 0.016 0.205 0.345 0.545 2.6 0.006 0.032 NA 1.01 27.5 0.057 0.464 0.42 0.69 5.6 0.01 0.046 NA 3.42 Above Max Guideline - - - - 58 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - 12 12 12 12 12 12 12 12 0 12 Max Max n Min N57 Phaeophytin (ug/L) 0 NA Min N44 Nitrogen Total (mg/L) 0 NA n N42 Nitrogen TKN (mg/L) 0 NA Min N35 Nitrogen Oxidised (mg/L) 0 NA n N21 Nitrogen Ammoniacal (mg/L) 0 Min n N14 Lorenzen (ug/L) Statistic Station Code Table A96 Downstream of storages – nutrients 4 <LOR <LOR 0.16 0.16 <LOR 0.003 0.009 NA <LOR Median 7.6 <LOR 0.207 0.235 0.435 0.75 0.004 0.015 NA 1.675 Max 18.9 0.008 0.322 0.29 0.52 2.4 0.01 0.028 NA 3.8 Above Max Guideline - - - - 17 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 78 N881 N92 Silicate Reactive (SiO2 mg/L) Potassium Filtered (mg/L) Phosphorus Total (mg/L) Phosphorus Filterable (mg/L) Phaeophytin (ug/L) 12 12 12 12 0 12 0.05 0.18 0.4 0.003 0.01 NA 1.31 Median 5.55 0.003 0.296 0.185 0.485 1.05 0.007 0.017 NA 2.06 Max 10.9 0.028 0.638 0.24 0.81 2.3 0.012 0.029 NA 3.71 Above Max Guideline - - - - 42 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - 12 12 12 12 12 12 12 12 0 12 Min 2.2 <LOR 0.134 0.16 0.31 <LOR 0.003 0.009 NA 2.13 Median 3.65 0.004 0.26 0.235 0.5 0.35 0.004 0.013 NA 2.885 Max 7.9 0.019 0.462 0.27 0.63 0.9 0.008 0.019 NA 4.19 Above Max Guideline - - - - 50 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - 12 12 12 12 12 12 12 12 0 12 Min 2.8 <LOR 0.129 0.09 0.35 <LOR 0.002 0.011 NA 0.51 Median 6.55 0.009 0.297 0.205 0.515 0.85 0.004 0.018 NA 1.73 Max 20.3 0.031 0.638 0.33 0.97 1.7 0.014 0.024 NA 3.6 Above Max Guideline - - - - 50 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - 12 12 12 12 12 12 12 12 0 12 <LOR 2 <LOR <LOR 0.15 0.3 <LOR <LOR 0.011 NA Median 5.2 <LOR 0.261 0.185 0.455 0.75 0.003 0.015 NA 1.9 Max 10.6 0.027 0.463 0.3 0.64 1.5 0.007 0.021 NA 3.08 Above Max Guideline - - - - 42 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - 12 12 12 12 12 12 12 12 0 12 n N86 Nitrogen Total (mg/L) 12 0.056 Min N85 Nitrogen TKN (mg/L) 12 <LOR n N75 Nitrogen Oxidised (mg/L) 12 2.7 n N67 Nitrogen Ammoniacal (mg/L) 12 Min n N641 Lorenzen (ug/L) Statistic Station Code N64 n Min 0.5 <LOR <LOR 0.13 0.18 <LOR <LOR 0.01 NA <LOR Median 3.05 0.009 0.107 0.155 0.255 0.5 0.003 0.012 NA 1.78 Max 6 0.036 0.228 0.19 0.36 1.7 0.004 0.017 NA 2.83 Above Max Guideline - - - - 0 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 12 12 12 12 12 12 12 12 0 12 Min 0.5 <LOR 0.041 0.1 0.18 <LOR 0.001 <LOR NA 0.14 Median 0.8 <LOR 0.097 0.13 0.24 <LOR 0.004 0.008 NA 2.35 Max 1 0.021 0.159 0.28 0.44 0.6 0.006 0.02 NA 3.15 Above Max Guideline - - - - 0 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 11 12 12 12 12 11 12 12 0 12 Min 0.5 <LOR <LOR 0.11 0.16 <LOR <LOR <LOR NA <LOR Median 0.8 0.008 0.072 0.13 0.21 <LOR 0.002 0.003 NA 1.75 Max 1.3 0.018 0.126 0.43 0.46 0.5 0.002 0.013 NA 2.5 Above Max Guideline - - - - 0 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - n 11 12 12 12 12 11 12 12 0 12 Min 0.6 <LOR 0.074 0.1 0.24 <LOR 0.001 0.005 NA 1.44 Median 1.4 0.005 0.19 0.165 0.355 <LOR 0.004 0.01 NA 2.19 Max 2.4 0.019 0.524 0.28 0.69 0.9 0.007 0.018 NA 3.43 Above Max Guideline - - - - 33 - - 0 - - Below Min Guideline - - - - 0 - - 0 - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 79 n E303 0 NA NA Median NA NA NA NA NA NA Max NA NA NA NA NA NA Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 Min 0.01 0.05 0.12 0.24 0.005 0.016 Median 0.065 0.175 0.275 0.56 0.014 0.033 Max 0.22 0.97 0.33 1.08 0.101 0.166 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 Min <LOR 0.02 0.14 0.29 0.003 0.006 Median 0.025 0.06 0.23 0.405 0.008 0.011 Max 0.09 0.19 0.32 0.63 0.014 0.025 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 11 11 11 11 11 11 Min <LOR 0.1 <LOR 0.16 0.002 0.011 Median <LOR 0.16 <LOR 0.29 0.004 0.032 Max 0.02 0.48 0.18 0.86 0.015 0.048 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 11 11 11 11 11 11 Min <LOR 0.04 <LOR 0.16 <LOR 0.019 Median 0.01 0.11 <LOR 0.29 0.002 0.029 Max 0.02 0.26 0.21 0.59 0.006 0.067 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 11 11 11 11 11 11 Min <LOR 0.05 <LOR 0.12 0.004 0.035 Median <LOR 0.21 0.05 0.49 0.014 0.061 Max 0.02 0.33 0.19 0.88 0.038 0.095 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 n N42 Min <LOR 0.06 <LOR 0.24 <LOR 0.027 Median 0.01 0.085 0.125 0.365 0.005 0.049 Max 0.02 0.4 0.24 0.74 0.026 0.099 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 Min <LOR 0.06 <LOR 0.16 <LOR 0.024 Median 0.01 0.1 0.07 0.25 0.012 0.039 Max 0.03 0.22 0.22 0.52 0.029 0.064 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 n N44 n N57 Manganese Total (mg/L) 0 NA n N35 Manganese Filtered (mg/L) 0 NA n N21 Iron Total (mg/L) 0 NA n N14 Iron Filtered (mg/L) 0 NA n G0515 Aluminium Total (mg/L) 0 Min n E851 Aluminium Filtered (mg/L) Statistic Station Code Table A97 Downstream of storages – metals Min <LOR 0.03 <LOR 0.12 <LOR 0.018 Median <LOR 0.095 0.08 0.295 0.002 0.027 Max 0.03 0.29 0.26 0.56 0.009 0.054 Above Max Guideline - - - - - - Below Min Guideline - - - - - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 80 N64 12 <LOR 0.021 Median 0.005 0.105 0.145 0.36 0.002 0.039 Max 0.02 0.34 0.26 0.57 0.044 0.067 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 Min <LOR 0.05 <LOR 0.22 0.001 0.014 Median 0.01 0.08 0.155 0.385 0.007 0.03 Max 0.06 0.32 0.23 0.65 0.036 0.049 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 Min <LOR 0.06 <LOR 0.2 0.005 0.038 Median 0.01 0.12 0.17 0.42 0.022 0.064 Max 0.05 0.29 0.45 0.98 0.115 0.127 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 Min <LOR 0.05 0.09 0.26 0.001 0.03 Median 0.02 0.09 0.23 0.395 0.013 0.04 Max 0.06 0.29 0.35 0.74 0.064 0.077 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 Min <LOR 0.05 0.13 0.26 0.004 0.02 Median 0.02 0.08 0.23 0.415 0.009 0.037 Max 0.06 0.28 0.36 0.6 0.04 0.065 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 Min 0.02 0.04 0.12 0.2 0.007 0.012 Median 0.035 0.09 0.19 0.285 0.01 0.017 Max 0.08 0.2 0.31 0.5 0.017 0.024 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 n N881 Min 0.02 0.03 0.17 0.28 0.009 0.018 Median 0.055 0.095 0.235 0.375 0.014 0.022 Max 0.08 0.28 0.36 0.59 0.022 0.036 Above Max Guideline - - - - - - Below Min Guideline - - - - - - 12 12 12 12 12 12 Min 0.01 0.02 0.1 0.14 0.001 0.01 Median 0.035 0.08 0.205 0.32 0.011 0.02 Max 0.08 0.32 0.36 0.62 0.045 0.059 Above Max Guideline - - - - - - Below Min Guideline - - - - - - n N92 Manganese Total (mg/L) 12 0.15 n N86 Manganese Filtered (mg/L) 12 <LOR n N85 Iron Total (mg/L) 12 0.03 n N75 Iron Filtered (mg/L) 12 <LOR n N67 Aluminium Total (mg/L) 12 Min n N641 Aluminium Filtered (mg/L) Statistic Station Code n Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 81 n G0515 N14 34 <LOR Median 51030 1923 33255 0.0465 <LOR 0.0055 361 Max 184300 5347 167900 0.37 <LOR 0.363 17340 Above Max Guideline - - - - 0 0 0 Below Min Guideline - - - - 0 0 0 n 5 5 5 5 0 5 5 1610 378 125 <LOR NA <LOR <LOR Median 9470 1665 4280 0.029 NA <LOR <LOR 347300 4468 343200 1.812 NA 0.045 1690 Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 n 0 0 0 0 0 0 0 Min NA NA NA NA NA NA NA Median NA NA NA NA NA NA NA Max NA NA NA NA NA NA NA Above Max Guideline - - - - NA NA NA Below Min Guideline - - - - NA NA NA n 10 11 11 11 0 11 11 Min 468 197 <LOR <LOR NA <LOR <LOR Median 2380 410 553 <LOR NA <LOR <LOR Max 5890 1038 1450 0.007 NA <LOR 28 Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 11 12 12 12 0 12 12 <LOR Max Min 6160 839 555 0.001 NA <LOR Median 33610 2249.5 31845 0.549 NA 0.3635 2645 Max 190900 20010 172000 2.044 NA 1.751 49370 Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 11 12 12 12 0 12 12 Min 9200 851 2230 0.007 NA <LOR <LOR Median 53710 3944 26050 0.0655 NA <LOR <LOR Max 372900 10640 319900 1.038 NA 0.152 1190 Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 13 13 13 13 0 13 13 Min 2150 513 <LOR <LOR NA <LOR <LOR Median 56560 3557 26070 0.12 NA <LOR <LOR Max 159900 9706 91340 0.31 NA 0.003 142 Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 12 12 12 12 0 12 12 Min 5960 933 143 <LOR NA <LOR <LOR Median 37680 2721 14270 0.051 NA <LOR <LOR Max 170000 7304 147900 0.58 NA 0.005 216 Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 10 11 11 11 0 11 11 n N57 Toxic Cyanobacterial Count (cells/mL) 34 <LOR n N44 Toxic Cyanobacterial biovolume (mm3/L) 34 <LOR n N42 Microcystin LR equiv (ug/L) 34 0.002 n N35 Cyanobacterial biovolume (mm3/L) 34 1600 n N21 Cyanobacteria Total Count (cells/mL) 34 496 Min E851 Areal Standard Unit (algae) 34 9380 Min E303 Algal Total Count (cells/mL) Statistic Station Code Table A98 Downstream of storages – cyanobacteria Min 6430 791 <LOR <LOR NA <LOR <LOR Median 22260 2348 5550 0.015 NA <LOR <LOR Max 60610 6074 54460 0.205 NA 0.001 71 Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 82 N64 N641 N67 N75 N85 N86 N881 N92 Toxic Cyanobacterial Count (cells/mL) Toxic Cyanobacterial biovolume (mm3/L) Microcystin LR equiv (ug/L) Cyanobacterial biovolume (mm3/L) Cyanobacteria Total Count (cells/mL) Areal Standard Unit (algae) Algal Total Count (cells/mL) Statistic Station Code n 8 8 8 8 0 8 8 Min 1980 408 399 <LOR NA <LOR <LOR Median 10895 1248.5 4995 0.0185 NA <LOR <LOR Max 76610 5561 64000 0.335 NA <LOR <LOR Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 n 3 3 3 3 0 3 3 Min 8620 1146 2390 0.009 NA <LOR <LOR Median 8940 1228 3020 0.018 NA <LOR <LOR Max 9400 1586 3800 0.069 NA 0.002 100 Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 n 8 8 8 8 0 8 8 Min 4980 547 143 <LOR NA <LOR <LOR Median 18560 1306.5 8480 0.0145 NA <LOR <LOR Max 44410 4055 29200 0.088 NA <LOR <LOR Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 n 7 7 7 7 0 7 7 Min 3690 466 2200 0.003 NA <LOR <LOR Median 17330 975 3050 0.012 NA <LOR <LOR Max 40120 2704 37010 0.112 NA <LOR <LOR Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 n 3 3 3 3 0 3 3 Min 5990 764 288 0.001 NA <LOR <LOR Median 27590 960 22880 0.068 NA <LOR <LOR Max 37870 1023 35230 0.124 NA <LOR <LOR Above Max Guideline - - - - NA 0 0 Below Min Guideline - - - - NA 0 0 n 0 0 0 0 0 0 0 Min NA NA NA NA NA NA NA Median NA NA NA NA NA NA NA Max NA NA NA NA NA NA NA Above Max Guideline - - - - NA NA NA Below Min Guideline - - - - NA NA NA n 0 0 0 0 0 0 0 Min NA NA NA NA NA NA NA Median NA NA NA NA NA NA NA Max NA NA NA NA NA NA NA Above Max Guideline - - - - NA NA NA Below Min Guideline - - - - NA NA NA n 0 0 0 0 0 0 0 Min NA NA NA NA NA NA NA Median NA NA NA NA NA NA NA Max NA NA NA NA NA NA NA Above Max Guideline - - - - NA NA NA Below Min Guideline - - - - NA NA NA Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 83 0 NA NA Median NA NA NA NA Max NA NA NA NA Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 <LOR 1 <LOR 3 Median 0.5 5 5 13.5 Max 29 52 100 56 Above Max Guideline - - - - Below Min Guideline - - - - 10 12 12 12 n <LOR 5 2 5 Median 4 22 21.5 8.5 Max Min 65 420 730 66 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 <LOR n <LOR 2 1 Median 3 8.5 20 3 Max 15 41 460 41 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 <LOR 2 <LOR 1 1.5 7 5.5 5 Max 9 49 35 28 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 Min N14 n Min N21 Median n Min N35 Median 3 6 15 13.5 64 79 53 - - - - Below Min Guideline - - - - 13 13 13 13 Min 5 1 3 <LOR Median 10 43 37 29 Max 41 150 96 87 Above Max Guideline - - - - Below Min Guideline - - - - 13 13 13 13 n <LOR 26 20 8 Median 9 77 62 32 Max Min 21 110 140 73 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 n <LOR 9 4 8 2.5 83.5 114.5 36.5 Max 6 510 650 70 Above Max Guideline - - - - Below Min Guideline - - - - Min N57 4 17.5 20 n N44 5 10.5 Above Max Guideline Max N42 Enterococci (orgs/100ml) 0 NA Min G0515 E. coli (orgs/100mL) 0 NA n E851 Coliforms Thermotolerant (cfu/100mL) 0 Min n E303 Clostridium Perfringens Statistic Station Code Table A99 Downstream of storages – pathogens Median Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 84 Clostridium Perfringens Coliforms Thermotolerant (cfu/100mL) E. coli (orgs/100mL) Enterococci (orgs/100ml) 12 12 12 1 <LOR 5 Median 1.5 5 8 12 Max Statistic Station Code 12 <LOR n Min N64 18 44 73 82 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 n N641 Min <LOR 2 <LOR <LOR Median <LOR 7.5 5.5 26 42 55 56 56 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 24 Max n <LOR 14 11 Median 3 24 25.5 30 Max 11 250 220 180 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 Min N67 n <LOR 9 12 2 Median 3 40.5 31.5 28.5 Max Min N75 20 390 490 49 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 n <LOR 9 9 8 Median 3 18.5 16 23 Max Min N85 10 58 60 64 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 n N86 Min <LOR 2 2 <LOR Median <LOR 6.5 5 22 Max 1 84 99 94 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 n N881 Min <LOR 3 <LOR 5 Median <LOR 13 11 28 Max 6 40 36 90 Above Max Guideline - - - - Below Min Guideline - - - - 12 12 12 12 n N92 Min <LOR 8 2 2 Median <LOR 10.5 8.5 10 Max 9 310 68 69 Above Max Guideline - - - - Below Min Guideline - - - - Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 85 Appendix B Incidents Appendix B1: Water quality incidents that occurred during the 2013-2014 reporting period. Date Subtype Location Details Assess Consequences Root Cause Analysis Actions Taken 04 Feb 14 Algae Kangaroo Valley WFP A sample of raw water supplied to Kangaroo Valley WFP on 28/01/2014 recorded 7,016 ASU/mL (an indicator of filter clogging potential). Major incident trigger for Kangaroo Valley WFP is 5,000 ASU/mL. Potential for blockage of membranes at Kangaroo Valley WFP Unknown, algal growth is common in this storage during warmer weather. Kangaroo Valley WFP advised and confirmed that plant was operating OK with no apparent problems. Operators checked plant daily to assess need for increased chemical cleaning of membranes. RMContinued monitoring and liaison with WFP Operators. 22-Mar-14 Turbidity Macarthur WFP Following a significant rain event on 22 March 2014; the turbidity of the inflows from Pheasants Nest to Broughton Pass Weir increased rapidly to above 100 NTU. Major incident trigger for Macarthur WFP is 50 NTU (60 NTU when demand is lower than 80 ML/d) The variable water quality in Broughton Pass Weir caused significant treatment issues for the Macarthur WFP. Production was suspended intermittently on 22 and 23 March. Significant rain event in the catchment areas upstream of Broughton Pass Weir on Saturday 22 March 2014. Catchment was affected by bushfire in October 2013 so there was insufficient regrowth to prevent runoff transporting nutrients and metals into waterways SCA and Sydney Water continuously monitored water quality at the Broughton Pass & Pheasants Nest Weirs and Upper Canal on real-time systems with regular consultation & communication with the Macarthur and Prospect WFPs. Appropriate adjustments were made to the configuration of the raw water supply to Broughton Pass Weir and the Upper Canal as required to maintain the best available raw water supply for the Macarthur & Prospect WFPs throughout this period. 02 Apr 14 Algae Prospect WFP A sample of raw water supplied to Prospect WFP on 31/03/2014 recorded 2,002 ASU/mL. This was part of an event monitoring program prior to supplying from Prospect Reservoir. Major Incident trigger for Prospect WFP is 2,000 ASU/mL. Sydney Water advised that the plant did not express any concern and were not aware of any impact on filter run times Presence of diatoms which contributed to 75% of the ASU. Reviewed other related samples collected on the same day and other samples from this site on previous and following days and advised Sydney Water. Other samples in March and April 2014 showed ASU around 30 – 150 ASU/mL. Prospect Reservoir was used for supply from 29 March to 7 April with no treatment issues and no customer complaints. 25 Apr 14 Algae Kangaroo Valley WFP A sample of raw water supplied to Kangaroo Valley WFP on 22/04/2014 recorded 7,862 ASU/mL. Major incident trigger is 5,000 ASU/mL The dominant type of algae found was Cyanonephron which is very small, not toxic, does not produce taste and odour or clog filters Cyanonephron has been found in large numbers at this time of year in 2013 and 2012. The WFP was contacted to ensure there was no impact on plant processes. Monitoring of Bendeela Pondage continued and the plant was contacted regularly to ensure no impact on its ability to adequately treat water. MAJOR MINOR Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 86 Date Subtype Location Details Assess Consequences Root Cause Analysis Actions Taken 05-Jul-13 Turbidity Nepean WFP A sample of raw water supplied to Nepean WFP on 03/7/2013 recorded turbidity at 14.7 NTU. Minor incident trigger is 10 NTU Plant confirmed no issues treating the raw water Rain event Nepean WFP notified. Routine monitoring to continue 05-Jul-13 Metals Nepean WFP A sample of raw water supplied to Nepean WFP on 01/7/2013 recorded total iron concentration of 1.1 mg/L. Minor incident trigger is 1 mg/L. Plant confirmed no issues treating raw water Rain event. Nepean WFP notified. Routine monitoring to continue. 17-Sep-13 Turbidity Wingecarribee WFP A sample of raw water supplied to Wingecarribee WFP on 16/9/2013 recorded turbidity of 11.2 NTU. Minor incident trigger is 10 NTU Plant confirmed no issues treating raw water Typical result for Wingecarrribee Reservoir at this time of year. Wingecarribee WFP notified. No additional action required 25 Oct-13 Turbidity Wingecarribee WFP A sample of raw water supplied to Wingecarribee WFP on 24/10/2013 recorded turbidity of 11.0 NTU. Minor incident trigger is 10 NTU Plant confirmed no issues treating raw water Typical result for Wingecarrribee Reservoir at this time of year. Wingecarribee WFP notified. No additional action required 21-Nov-13 Turbidity Wingecarribee WFP A sample of raw water supplied to Wingecarribee WFP on 20/11/2013 recorded turbidity of 10.6 NTU. Minor incident trigger is 10 NTU Plant confirmed no issues for treatment process. Typical result for Wingecarribee Reservoir at this time of year. Wingecarribee WFP notified. No additional action required 05-Feb-14 Catchment Wingecarribee catchment Wingecarribee Council ranger reported a pollution incident in Iron Mines creek believed to be white paint, quantity unknown. Localised water quality incident with minimal or no impact on water supply. May have immediate environmental impacts Likely due to painters cleaning equipment resulting in runoff to stormwater system Wingecarribee Shire Council informed EPA hotline and were advised that Council are the appropriate regulatory authority under POEO. Fire and Rescue Services attended site and contained the spillage. Council are investigated the source through the market place storm water system. SCA provided verbal advice on clean up and offered the assistance of Compliance & Investigation staff if required. 24-Feb-14 Algae Cascades Dam A sample of raw water supplied to Cascade WFP on 12/02/2014 recorded 1,777 ASU/mL. Minor incident trigger for Cascades WFP is 1,000 ASU/mL. Plant confirmed no issues for treatment process. Increased seasonal algal activity Cascade WFP was notified. Continued to monitor algal activity in the Top Cascades as per water monitoring program and liaise regularly with Cascades WFP. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 87 Date Subtype Location Details Assess Consequences Root Cause Analysis Actions Taken 17 Mar 14 Algae Cascades Dam A sample of raw water supplied to Cascade WFP on 12/03/2014 recorded 1,545 ASU/mL. Minor incident trigger for Cascades WFP is 1,000 ASU/mL. Not Applicable Increased seasonal algal activity. Cascade WFP was notified and continues to successfully treat raw water supplied. Continued to monitor algal activity in the Upper Cascades reservoir as per water monitoring program and liaise regularly with Cascades WFP. 30 Apr 14 Livestock Upper Canal Dead cow found on trash rack Potential for canal overflow due to blocked trash rack (minor risk due to low flow conditions). Potential for water quality impact. Poor condition of fences in that area resulting in cows entering canal corridor. All gates were confirmed as secure upon inspection by security. Prospect WFP was notified and possible diversion of the Upper Canal to Prospect Reservoir was discussed. Contractors and Catchment officers attended site and removed cow by 08:45 the next morning. Improvements to boundary fencing undertaken at this location of the Upper Canal. Sydney Catchment Authority Annual Water Quality Monitoring Report 2013-14 - Appendices 88