™ DaikinDAI-EL HighPerformanceFluoroelastomers DAI-EL™ Equals Quality Plus Performance Fluoroelastomer Expertise Daikin offers the most complete line of fluoroelastomer products in the world today. From low Mooney materials to high-performance peroxide-curable products, Daikin’s FKM technologies are designed to perform in a broad range of demanding service and processing environments. When you choose DAI-EL, you choose the highest quality fluoroelastomer products. And you join our growing family of satisfied customers who benefit from excellent support of new applications development. Daikin is continuously striving to develop newer and better fluoroelastomer technologies, and provide outstanding technical support for customers worldwide. Technical Support Daikin provides extensive technical support in all major markets: automotive, aerospace and the chemical industries. Our customer support facilities in Orangeburg, New York; Hanover, Massachusetts and Decatur, Alabama are designed to support the needs of our customers in these dynamic markets. Property Comparison of Fluoroelastomers with Other Rubbers Fluoroelastomer Silicone Rubber Acrylic Rubber Nitrile Rubber Ethylene Propylene Rubber FKM MQ, VMQ ACM NBR EPDM Specific Gravity 1.8~2.0 1.0 1.0 1.0 0.9 Heat Resistance ★★★★★ ★★★★★ ★★★★ ★★★ ★★★★ ★★★ ★★★★★ ★★★★ ★★★★★ ★★★★★ Electrical Properties ★★★★ ★★★★ ★★★ ★★★ ★★★★★ Solvent Resistance ★★★★★ ★★★★★ ★★★★ ★★★ ★★★★ Flame Resistance ★★★★★ ★★★★ ★★ ★★ ★★ Ozone Resistance ★★★★★ ★★★★★ ★★★★★ ★ ★★★★★ Steam Resistance ★★★★★ ★★★★ ★ ★★★ ★★★★ Acid Resistance ★★★★★ ★★★★ ★★★ ★★★★ ★★★★★ Oil Resistance ★★★★★ ★★★ ★★★★ ★★★★ ★ Permeability Resistance ★★★★★ ★★ ★★★★ ★★★★ ★★★ Low Temperature Resistance ★★★★★ Excellent ★★★★ Good ★★★ Fair ★★ Marginal ★ Poor The Flexibility to Provide Customized Solutions Daikin can provide DAI-EL fluoroelastomer in exactly the form that you need: As a base polymer (gum), a cure incorporated precompound or a full compound. So whether you mix your own compound or have someone else do it, consider the benefits of using our custom compound facility. Perfect Chemistry All of our manufacturing, research and development, sales and marketing teams are linked by a common pursuit: To better serve our customers so our customers can better serve theirs. At Daikin, we strive to be proactive instead of reactive. We try to learn all we can about our clients’ businesses, their needs, their goals–to help our customers maintain their competitive edge. DAI-EL Copolymers DAI-EL Polymer Grade Fluorine % ML1+10 @ 121°C Shore A Hardness Tensile Strength (Mpa) Elongation (%) 100% Modulus (Mpa) Compression Set 70 hrs @ 200°C Temp of Retraction TR10 (°C) Bisphenol Cured Copolymers G701 66 41 76 13.7 191 6.3 22 -18 G702 66 41 71 13.8 236 4.7 28 -18 G704 66 30 74 14.1 236 5.4 26 -18 G755 c 66 25 72 14.7 253 4.4 24 -18 G7251 66 20 75 12.4 200 5.8 16 -18 G7261 66 22 75 12.7 218 5.6 14 -18 G7262(GN20) 66 23 74 12.2 287 3.9 20 -18 G7329(GN34) 66 34 75 13.9 208 6.1 21 -18 G7371(GN32) 66 32 74 13.8 196 6.0 13 -18 G7451 66 40 77 13.9 215 6.2 13 -18 G7452(GN21) 66 42 73 15.3 252 4.7 15 -18 G7801 66 66 77 13.5 227 6.2 12 -18 Base polymers (gums) corresponding to the bisphenol containing polymers above are also available. Please ask your sales or customer service representative for information. Peroxide Cured Copolymers G801 66 37 66 22.0 450 2.0 38 -19 G802 66 20 66 18.7 390 2.0 27 -19 G8002 66 25 66 21.0 330 2.8 22 -19 a N/A N/A N/A N/A N/A N/A Non-Curing Liquid Copolymer G101 66 a. 3000 cp @ 150°C b. For test compound cure system, consult technical data sheet c. Test compound contains 13 phr N770 black in place of N990 black d. Gehman Torsion DAI-EL Copolymers Processing and Features DAI-EL Polymer Grade Compression Molding Transfer Molding Injection Molding Extrusion & Calendering Features and Applications Bisphenol Cured Copolymers G701 ● General purpose grade; good metal adhesion G702 ● Easier demolding of complex parts; dynamic seals G704 ● G755c ● General purpose grade; good metal adhesion ● ● Smooth, fast extrusion & calendering G7251 ● General purpose grade; best mold flow G7261 ● ● Easier mill handling; low compression set G7262(GN20) ● ● Easier demolding of complex shapes; dynamic seals G7329(GN34) ● ● Enhanced metal adhesion G7371(GN32) ● ● Easier roll handling; low compression set G7451 ● ● Low compression set with good mold flow G7452(GN21) ● ● Easier demolding of complex parts; dynamic seals G7801 ● Fast curing; best compression set Base polymers (gums) corresponding to the bisphenol containing polymers above are also available. Please ask your sales or customer service representative for information. Peroxide Cured Copoloymers G801 ● Water & acid resistance; FDA 177.2600 ● G802 ● Water & acid resistance; FDA 177.2600 G8002 ● Excellent mold flow & flex fatigue resistance Non-Curing Liquid Copolymer G101 a. 3000 cp @ 150°C b. For test compound cure system, consult technical data sheet c. Test compound contains 13 phr N770 black in place of N990 black d. Gehman Torsion Non curing viscosity modifier; improves extrusion DAI-EL Terpolymers and Low Temperature Polymers DAI-EL Polymer Grade Fluorine % ML1+10 @ 121°C Shore A Hardness Tensile Strength (Mpa) Elongation (%) 100% Modulus (Mpa) Compression Set 70 hrs @ 200°C Temp of Retraction TR10 (°C) Bisphenol Cured Terpolymers G551 69 48 74 15.9 210 4.4 25 -14 G558 c 69 34 68 12.5 200 2.7 28 -14 G603 71 31 77 14.0 280 3.7 60 -8 G621 71 50 76 16.2 280 3.3 29 -8 G671 66 35 71 16.0 210 5.1 19 -20 Base polymers (gums) corresponding to the bisphenol containing polymers above are also available. Please ask your sales or customer service representative for information. Peroxide Cured Terpolymers G901 71 48 70 22.0 320 2.8 32 -8 G902 71 19 70 22.0 330 3.1 28 -8 G912 71 56 73 20.0 170 8.5 16 -8 G952 69 40 67 24.0 320 2.3 28 -14 G9062 71 23 68 20.6 220 4.6 12 -8 G9074 71 42 66 18.5 262 3.6 11 -8 68 74 75 17.4 280 4.1 65 -16 LT252 67 35 74 18.5 300 3.6 26 -25 LT302 64 44 65 18.1 250 3.5 17 -31 LT303L 65 14 62 16.9 290 2.2 28 -30 LT304 65 26 63 14.3 210 3.4 16 -30 TBD N/A 67 11.0 650 TBD N/A -9d Diamine Cured Terpolymer G501NK Low Temperature Polymers Thermoplastic T-530 Notes: DAI-EL Terpolymers and Low Temperature Polymers Processing and Features DAI-EL Polymer Grade Compression Molding Transfer Molding Injection Molding Extrusion & Calendering Special Characteristics and applications Bisphenol Cured Terpolymers G551 Superior oil & fuel resistance vs copolymer ● G558c ● G603 ● G621 ● G671 ● Smooth, fast extrusion for fuel hose Excellent fuel & chemical resistance ● Excellent fuel resistance & sealing ability Balance of low temperature & fluid resistance ● Base polymers (gums) corresponding to the bisphenol containing polymers above are also available. Please ask your sales or customer service representative for information. Peroxide Cured Terpolymers G901 ● Excellent fuel, water & chemical resistance ● G902 Excellent fuel, water & chemical resistance ● G912 ● G952 ● Chemical resistance & low compression set Good balance of fluid resistance & low temperature flexibility ● G9062 G9074 ● ● Excellent mold flow; low compression set ● Very good mold flow; low compression set Diamine Cured Terpolymer G501NK Good mechanical properties & metal adhesion ● Low Temperature Polymers LT252 ● LT302 ● Good balance of low temperature sealing & fluid resistance ● Excellent low temperature sealing; part demolding ● LT303L LT304 ● ● Fast mold flow; viscosity modifier in blends ● Superior heat and compression set resistance Test Compound Formulas Polymer N990 Black MgO Ca(OH)2 Peroxide TAIC Diamine Curing Agent Bisphenol Cured Copolymers Bisphenol Cured Terpolymers Peroxide Cured Copolymers Peroxide Cured Terpolymers Low Temperature Polymers Diamine Cured Terpolymer 100 30 3 6 - 100 20* 3 6 - 100 20 1.5 3* - 100 20 1.5 4* 100 20* 1.5 3** - 100 20 15 (low activity) 3 *G-558: 15 phr N-762 *G-8002=4 *G-9074=3 *LT-252=30 **LT-302=4 Safe Handling 1. Compounding agent and facility: The common fillers and facilities for commodity rubber can be used for DAI-EL. The mixing mill needs to be cooled. Finely divided metallic powder or filler, such as aluminum and magnesium, or amine compounds of more than 10% should not be used as compounding agents for DAI-EL because such materials are known to decompose vigorously at moderately elevated temperature. 2. Storage and remixing: Store the compound in a tightly closed package in a cool and dry place. Another milling before use is recommended when the compound is left for more than three days. Too tight a nip between the rolls in the mixing mill may cause scorching. Be sure to cool the rolls well whenever the compound is milled with tight nip. 3. Molding/Curing: The work area should be adequately ventilated at all times because a small amount of toxic gases (e.g. HF, acetone, methanol, acetaldehyde, methyl iodine and carbon monoxide) may be evolved during curing. 4. Material handling: A slight amount of hydrogen fluoride vapor may be produced during the use at high temperatures(above 200ºC). The room should be well ventilated. Do not smoke in the work area as harmful vapors may be inhaled when cigarettes are exposed to the powder of DAI-EL. After handling the powder of DAI-EL, knock off any dust from your hair or clothing and wash your face and hands thoroughly before smoking. 5. Disposal: Do not incinerate DAI-EL as this can produce harmful vapors. Disposal should be done in accordance with local laws and regulations. • Read the “Material Safety Data Sheet” before use. ISO Certification: Daikin Industries, Ltd. and Daikin America, Inc. have obtained ISO 14001 environmental management system registration and ISO 9001-2000 quality system registration. ISO 14001 is a standard established by the International Organization for Standardization which applies to environmental preservation activities. Activities, products and services of our fluorochemicals plant have been certified as being environmentally sound by an internationally recognized body. ISO 9001-2000 is a certification system for quality control established by the International Organization for Standardization which certifies our quality control system, including all activities related to the design, manufacture and delivery of our products. Important Notice: The information contained herein is based on technical data and tests we believe to be reliable and is intended for use by persons having technical knowledge and skill, solely at their own discretion and risk. Since conditions of use are outside our control, we assume no responsibility for results obtained or damages incurred through application of the data given; and the publication of the information herein shall not be understood as permission or recommendation for the use of our fluorocarbon compounds in violation of any patent or otherwise. We only warrant that the product conforms to description and specification, and our only obligation shall be to replace goods shown to be defective or refund the original purchase price thereof. Medical Use: This product is not specifically designed or manufactured for use in implantable medical and/or dental devices. We have not tested it for such application and will only sell it for such use pursuant to contract containing specific terms and conditions required by us. Trademarks: DAI-EL is a registered trademark of Daikin Industries, Ltd. DAIKIN AMERICA, INC. 20 Olympic Drive Orangeburg, NY 10962, U.S.A. Phone: (845) 365-9500 Toll-Free: (800) 365-9570 Fax: (845) 365-9515 www.daikin-america.com DAIKIN INDUSTRIES, LTD. Umeda Center Building 2-4-12 Nakasaki-Nishi, Kita-Ku Osaka 530-8323, Japan Phone: +81-6-6373-4312 Fax: +81-6-6373-4380 www.daikin.com DAIKIN CHEMICAL EUROPE GmbH Immermannstr, 65D 40210 Düsseldorf, Germany Phone: +49-211-1792250 Fax: +49-211-1640732 www.daikinchem.de 2013-1M