DAI-EL High Performance

advertisement
™
DaikinDAI-EL
HighPerformanceFluoroelastomers
DAI-EL™ Equals Quality Plus Performance
Fluoroelastomer Expertise
Daikin offers the most complete line of fluoroelastomer products in the world today. From
low Mooney materials to high-performance peroxide-curable products, Daikin’s FKM technologies are
designed to perform in a broad range of demanding service and processing environments.
When you choose DAI-EL, you choose the highest quality fluoroelastomer products. And you
join our growing family of satisfied customers who benefit from excellent support of new applications
development. Daikin is continuously striving to develop newer and better fluoroelastomer
technologies, and provide outstanding technical support for customers worldwide.
Technical Support
Daikin provides extensive technical support in all major markets: automotive, aerospace
and the chemical industries. Our customer support facilities in Orangeburg, New York; Hanover,
Massachusetts and Decatur, Alabama are designed to support the needs of our customers
in these dynamic markets.
Property Comparison of Fluoroelastomers with Other Rubbers
Fluoroelastomer
Silicone
Rubber
Acrylic
Rubber
Nitrile
Rubber
Ethylene
Propylene
Rubber
FKM
MQ, VMQ
ACM
NBR
EPDM
Specific Gravity
1.8~2.0
1.0
1.0
1.0
0.9
Heat Resistance
★★★★★
★★★★★
★★★★
★★★
★★★★
★★★
★★★★★
★★★★
★★★★★
★★★★★
Electrical Properties
★★★★
★★★★
★★★
★★★
★★★★★
Solvent Resistance
★★★★★
★★★★★
★★★★
★★★
★★★★
Flame Resistance
★★★★★
★★★★
★★
★★
★★
Ozone Resistance
★★★★★
★★★★★
★★★★★
★
★★★★★
Steam Resistance
★★★★★
★★★★
★
★★★
★★★★
Acid Resistance
★★★★★
★★★★
★★★
★★★★
★★★★★
Oil Resistance
★★★★★
★★★
★★★★
★★★★
★
Permeability Resistance
★★★★★
★★
★★★★
★★★★
★★★
Low Temperature Resistance
★★★★★ Excellent
★★★★
Good
★★★
Fair
★★
Marginal
★
Poor
The Flexibility to Provide Customized Solutions
Daikin can provide DAI-EL fluoroelastomer in exactly the form that you need: As a base
polymer (gum), a cure incorporated precompound or a full compound. So whether you mix your own
compound or have someone else do it, consider the benefits of using our custom compound facility.
Perfect Chemistry
All of our manufacturing, research and development, sales and marketing teams are
linked by a common pursuit: To better serve our customers so our customers can better serve theirs.
At Daikin, we strive to be proactive instead of reactive. We try to learn all we can about our
clients’ businesses, their needs, their goals–to help our customers maintain their
competitive edge.
DAI-EL Copolymers
DAI-EL
Polymer Grade
Fluorine %
ML1+10
@ 121°C
Shore A
Hardness
Tensile
Strength
(Mpa)
Elongation
(%)
100%
Modulus
(Mpa)
Compression
Set 70 hrs
@ 200°C
Temp of
Retraction
TR10 (°C)
Bisphenol Cured Copolymers
G701
66
41
76
13.7
191
6.3
22
-18
G702
66
41
71
13.8
236
4.7
28
-18
G704
66
30
74
14.1
236
5.4
26
-18
G755 c
66
25
72
14.7
253
4.4
24
-18
G7251
66
20
75
12.4
200
5.8
16
-18
G7261
66
22
75
12.7
218
5.6
14
-18
G7262(GN20)
66
23
74
12.2
287
3.9
20
-18
G7329(GN34)
66
34
75
13.9
208
6.1
21
-18
G7371(GN32)
66
32
74
13.8
196
6.0
13
-18
G7451
66
40
77
13.9
215
6.2
13
-18
G7452(GN21)
66
42
73
15.3
252
4.7
15
-18
G7801
66
66
77
13.5
227
6.2
12
-18
Base polymers (gums) corresponding to the bisphenol containing polymers above are also available.
Please ask your sales or customer service representative for information.
Peroxide Cured Copolymers
G801
66
37
66
22.0
450
2.0
38
-19
G802
66
20
66
18.7
390
2.0
27
-19
G8002
66
25
66
21.0
330
2.8
22
-19
a
N/A
N/A
N/A
N/A
N/A
N/A
Non-Curing Liquid Copolymer
G101
66
a. 3000 cp @ 150°C
b. For test compound cure system, consult technical data sheet
c. Test compound contains 13 phr N770 black in place of N990 black
d. Gehman Torsion
DAI-EL Copolymers
Processing and Features
DAI-EL
Polymer Grade
Compression
Molding
Transfer
Molding
Injection
Molding
Extrusion &
Calendering
Features and Applications
Bisphenol Cured Copolymers
G701
●
General purpose grade; good metal adhesion
G702
●
Easier demolding of complex parts; dynamic seals
G704
●
G755c
●
General purpose grade; good metal adhesion
●
●
Smooth, fast extrusion & calendering
G7251
●
General purpose grade; best mold flow
G7261
●
●
Easier mill handling; low compression set
G7262(GN20)
●
●
Easier demolding of complex shapes; dynamic seals
G7329(GN34)
●
●
Enhanced metal adhesion
G7371(GN32)
●
●
Easier roll handling; low compression set
G7451
●
●
Low compression set with good mold flow
G7452(GN21)
●
●
Easier demolding of complex parts; dynamic seals
G7801
●
Fast curing; best compression set
Base polymers (gums) corresponding to the bisphenol containing polymers above are also available.
Please ask your sales or customer service representative for information.
Peroxide Cured Copoloymers
G801
●
Water & acid resistance; FDA 177.2600
●
G802
●
Water & acid resistance; FDA 177.2600
G8002
●
Excellent mold flow & flex fatigue resistance
Non-Curing Liquid Copolymer
G101
a. 3000 cp @ 150°C
b. For test compound cure system, consult technical data sheet
c. Test compound contains 13 phr N770 black in place of N990 black
d. Gehman Torsion
Non curing viscosity modifier; improves extrusion
DAI-EL Terpolymers and Low Temperature Polymers
DAI-EL
Polymer Grade
Fluorine %
ML1+10
@ 121°C
Shore A
Hardness
Tensile
Strength
(Mpa)
Elongation
(%)
100%
Modulus
(Mpa)
Compression
Set 70 hrs
@ 200°C
Temp of
Retraction
TR10 (°C)
Bisphenol Cured Terpolymers
G551
69
48
74
15.9
210
4.4
25
-14
G558 c
69
34
68
12.5
200
2.7
28
-14
G603
71
31
77
14.0
280
3.7
60
-8
G621
71
50
76
16.2
280
3.3
29
-8
G671
66
35
71
16.0
210
5.1
19
-20
Base polymers (gums) corresponding to the bisphenol containing polymers above are also available.
Please ask your sales or customer service representative for information.
Peroxide Cured Terpolymers
G901
71
48
70
22.0
320
2.8
32
-8
G902
71
19
70
22.0
330
3.1
28
-8
G912
71
56
73
20.0
170
8.5
16
-8
G952
69
40
67
24.0
320
2.3
28
-14
G9062
71
23
68
20.6
220
4.6
12
-8
G9074
71
42
66
18.5
262
3.6
11
-8
68
74
75
17.4
280
4.1
65
-16
LT252
67
35
74
18.5
300
3.6
26
-25
LT302
64
44
65
18.1
250
3.5
17
-31
LT303L
65
14
62
16.9
290
2.2
28
-30
LT304
65
26
63
14.3
210
3.4
16
-30
TBD
N/A
67
11.0
650
TBD
N/A
-9d
Diamine Cured Terpolymer
G501NK
Low Temperature Polymers
Thermoplastic
T-530
Notes:
DAI-EL Terpolymers and Low Temperature Polymers
Processing and Features
DAI-EL
Polymer Grade
Compression
Molding
Transfer
Molding
Injection
Molding
Extrusion &
Calendering
Special Characteristics and applications
Bisphenol Cured Terpolymers
G551
Superior oil & fuel resistance vs copolymer
●
G558c
●
G603
●
G621
●
G671
●
Smooth, fast extrusion for fuel hose
Excellent fuel & chemical resistance
●
Excellent fuel resistance & sealing ability
Balance of low temperature & fluid resistance
●
Base polymers (gums) corresponding to the bisphenol containing polymers above are also available.
Please ask your sales or customer service representative for information.
Peroxide Cured Terpolymers
G901
●
Excellent fuel, water & chemical resistance
●
G902
Excellent fuel, water & chemical resistance
●
G912
●
G952
●
Chemical resistance & low compression set
Good balance of fluid resistance & low temperature flexibility
●
G9062
G9074
●
●
Excellent mold flow; low compression set
●
Very good mold flow; low compression set
Diamine Cured Terpolymer
G501NK
Good mechanical properties & metal adhesion
●
Low Temperature Polymers
LT252
●
LT302
●
Good balance of low temperature sealing & fluid resistance
●
Excellent low temperature sealing; part demolding
●
LT303L
LT304
●
●
Fast mold flow; viscosity modifier in blends
●
Superior heat and compression set resistance
Test Compound Formulas
Polymer
N990 Black
MgO
Ca(OH)2
Peroxide
TAIC
Diamine Curing Agent
Bisphenol Cured
Copolymers
Bisphenol Cured
Terpolymers
Peroxide Cured
Copolymers
Peroxide Cured
Terpolymers
Low Temperature
Polymers
Diamine Cured
Terpolymer
100
30
3
6
-
100
20*
3
6
-
100
20
1.5
3*
-
100
20
1.5
4*
100
20*
1.5
3**
-
100
20
15 (low activity)
3
*G-558:
15 phr N-762
*G-8002=4
*G-9074=3
*LT-252=30
**LT-302=4
Safe Handling
1. Compounding agent and facility: The common fillers and facilities for commodity rubber can be
used for DAI-EL. The mixing mill needs to be cooled. Finely divided metallic powder or filler,
such as aluminum and magnesium, or amine compounds of more than 10% should not be used as compounding agents for DAI-EL because such materials are known to decompose vigorously at
moderately elevated temperature.
2. Storage and remixing: Store the compound in a tightly closed package in a cool and dry place.
Another milling before use is recommended when the compound is left for more than three days. Too
tight a nip between the rolls in the mixing mill may cause scorching. Be sure to cool the rolls well
whenever the compound is milled with tight nip.
3. Molding/Curing: The work area should be adequately ventilated at all times because a
small amount of toxic gases (e.g. HF, acetone, methanol, acetaldehyde, methyl iodine and carbon
monoxide) may be evolved during curing.
4. Material handling: A slight amount of hydrogen fluoride vapor may be produced during the use
at high temperatures(above 200ºC). The room should be well ventilated. Do not smoke in the work
area as harmful vapors may be inhaled when cigarettes are exposed to the powder of DAI-EL. After
handling the powder of DAI-EL, knock off any dust from your hair or clothing and wash your face and
hands thoroughly before smoking.
5. Disposal: Do not incinerate DAI-EL as this can produce harmful vapors. Disposal should be
done in accordance with local laws and regulations.
• Read the “Material Safety Data Sheet” before use.
ISO Certification: Daikin Industries, Ltd. and Daikin America, Inc. have obtained ISO 14001 environmental
management system registration and ISO 9001-2000 quality system registration.
ISO 14001 is a standard established by the International Organization for Standardization which applies to
environmental preservation activities. Activities, products and services of our fluorochemicals plant have been
certified as being environmentally sound by an internationally recognized body.
ISO 9001-2000 is a certification system for quality control established by the International Organization for
Standardization which certifies our quality control system, including all activities related to the design, manufacture and delivery of our products.
Important Notice: The information contained herein is based on technical data and tests we believe to be reliable
and is intended for use by persons having technical knowledge and skill, solely at their own discretion and risk.
Since conditions of use are outside our control, we assume no responsibility for results obtained or damages incurred through application of the data given; and the publication of the information herein shall not be understood as permission or recommendation for the use of our fluorocarbon compounds in violation of any patent or
otherwise. We only warrant that the product conforms to description and specification, and our only obligation
shall be to replace goods shown to be defective or refund the original purchase price thereof.
Medical Use: This product is not specifically designed or manufactured for use in implantable medical and/or
dental devices. We have not tested it for such application and will only sell it for such use pursuant to contract
containing specific terms and conditions required by us.
Trademarks: DAI-EL is a registered trademark of Daikin Industries, Ltd.
DAIKIN AMERICA, INC.
20 Olympic Drive
Orangeburg, NY 10962, U.S.A.
Phone: (845) 365-9500
Toll-Free: (800) 365-9570
Fax: (845) 365-9515
www.daikin-america.com
DAIKIN INDUSTRIES, LTD.
Umeda Center Building
2-4-12 Nakasaki-Nishi, Kita-Ku
Osaka 530-8323, Japan
Phone: +81-6-6373-4312
Fax: +81-6-6373-4380
www.daikin.com
DAIKIN CHEMICAL
EUROPE GmbH
Immermannstr, 65D
40210 Düsseldorf, Germany
Phone: +49-211-1792250
Fax: +49-211-1640732
www.daikinchem.de
2013-1M
Download