Material Safety Data Sheet - Glitters Date: 17-06-2010 Updated 10-02-2016 Section1 – Identification of the Substance/Preparation and of the Company Undertaking Product Name: Lecenté Cosmetic Holographic, Cosmetic Pastel, Cosmetic Mica, Premier Polyester, Premier Holographic, Premier Pearl, Premier Iridescent Saw tooth Fibres, Angelina Fibres, glitters for cosmetics and toiletries. Manufacturer: Lecenté, Unit 15 Canal Industrial Park, Canal Road, Gravesend, Kent. DA12 2PA Emergency Phone Numbers: +44 1474 327770 Product : Purple Holographic, Green Holographic, Red Holographic, Black Holographic, Gold Holographic, White Holographic, Silver Holographic, Blue Holographic, Lavender Holographic, Darkest Pink Holographic, Deep Red Holographic, Iron Holographic, Raspberry Holographic, Turquoise Holographic. Blue Ultra Fine, Green Ultra Fine, Light Gold Ultra Fine, Bright Red Ultra Fine, Pink Ultra Fine, Gold Ultra Fine, Lime Ultra Fine, Navy Blue Ultra Fine, Magenta Ultra Fine, Light Pink Ultra Fine, Bronze Ultra Fine, Silver Ultra Fine, Black Ultra Fine, Purple Ultra Fine, Gunmetal Ultra Fine, Chocolate Ultra Fine, Emerald Ultra Fine, Garnet Ultra Fine, Bordeaux Ultra Fine, Cardinal Ultra Fine, Sea Green Ultra Fine, Blueberry Ultra Fine, Hunter Ultra Fine, Apricot Ultra Fine, Blue Gunmetal Ultra Fine, Lilac Ultra Fine, Sahara, Golden orange, New York Pink, Sand, Scarlet Ultra Fine, Periwinkle Ultra Fine, Cinnamon Ultra Fine, Ocean Spray Ultra Fine, Light Copper Ultra Fine, Violet Ultra Fine, Tiffany Ultra Fine, Rose Gold Ultra Fine. Rhubarb Iridescent, Coral Iridescent, Banana Iridescent, Bubblegum Iridescent, Tickle Me Pink Iridescent, Petunia Iridescent, Turquoise Iridescent , Rhubarb Iridescent, Mint Iridescent, Salmon Iridescent, Candy Pink Iridescent, Apple Iridescent, Azure Iridescent, Blackcurrant Iridescent, Capri Iridescent, Chameleon Iridescent, Confetti Pink Iridescent, Golden White Iridescent, Midnight Blue Iridescent, Petrol Green Iridescent, Pink Champagne Iridescent, Rainbow Blue Iridescent, Tangerine Iridescent, Indigo Blue Iridescent, Baby Pink Iridescent, Baby Blue Iridescent, Thistle Iridescent, Peru Iridescent, Liberty Iridescent, Carnation Iridescent, Pumpkin Iridescent, Crushed Ice, Banana Strands, Aqua Strands, Blackcurrant Strands. Pink Irregular, Silver Cloud Irregular, Green Irregular, Purple Irregular. Purple 1.5mm Squares, Rose 1.5mm Squares, Bright Pink 1.5mm Squares, Pink 1.5mm Squares Hot Pink Dazzling Diamonds, Pink Dazzling Diamonds, Rose Dazzling Diamonds, Lime Dazzling Diamonds Variants include: Vixen, Winter Wonderland, Sleigh Bells, Showgirl, Trixie, Femme, Foxy, Mistress, She Devil, Hot Lips, Sugar Lips, Goddess, Treacle, Starlet, Diva. Fireworks include: Flame, Crackle, Spark, Burst, Firefly, Pop, Cherry Bomb, Ember, Carnival, Rocket, Mortar, Waterfall. 1.2. Relevant Identified uses of the substance or mixture and uses advised against Decorative material. 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] - Not classified Classification according to EU Directives 67/548/EEC or 1999/45/EC - Not classified 2.2. Label elements Labelling according to Regulation (EC) No 1272/2008 [CLP] Pictogram: na Signal word: na Hazard statement(s) None Precautionary statement(s) None Supplemental Hazard Statements None According to European Directive 67/548/EEC as amended. Hazard symbol(s) na R-phrase(s) None. S-phrase(s) None 2.3. Other hazards None 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Description of Material: Solids made from coated polyester foils. EINECS N° 231-072-3 CAS N° INDEX N° Chemical name Conc. (% w/w) 25038-59-9 n.a. Polyethylene Terephthalate Aluminium 90 - 95% Binder Polyurethane 33 4 - 5% 7429-90-5 125826-44-0 0 - 0.5% Hazard class and category code None Hazard statement Danger symbol/R phrases None None Flam. Sol. 1 Water react 2 None H228 H261 «N», R43, R52/53 None None Hazard statement Danger symbol/R phrases None None None None Pigments Used EINECS N° CAS N° INDEX N° Chemical name Conc. (% w/w) 226-109-5 229-142-3 5281-04-9 6417-83-0 CI 15850 CI 15880 1 - 3% 1 - 3% 217-699-5 1934-21-0 CI 19140 1 - 3% None None None 247-304-1 25869-00-5 CI 77510 1 - 3% None None None 205-685-1 215-609-9 147-14-8 1333-86-4 CI 74160 CI 77266 1 - 3% 1 - 3% None None None None None None 226-939-8 213-561-3 228-767-9 236-675-5 5567-15-7 980-26-7 6358-30-1 13463-67-7 CI 21108 CI 73915 CI 51319 CI 77891 1 - 3% 1 - 3% 1 - 3% 1 - 3% None None None None None None None None None None None None 223-339-8 241-409-6 242-355-6 208-253-0 3844-45-9 17372-87-1 18472-87-2 518-47-8 CI 42090 CI 45380 CI 45410 CI 45350:1 1 - 3% 1 - 3% 1 - 3% 1 - 3% None None None None None None None None None None None None 201-353-5 81-48-1 CI 60725 1 - 3% None None None 213-879-2 247-368-0 1047-16-1 25956-17-6 CI 73900 CI 16035 1 - 3% 1 - 3% None None None None None None 229-355-1 215-168-2 310-127-6 6486-23-3 1309-37-1 12001-26-2 CI 11710 CI77491 CI77019 D&C Red 7 FD&C Red 34 FD&C Yellow 5 FD&C Blue 27 Blue 15:3 Black 7 D&C Black 2 Yellow 83 Red 122 Violet 23 Titanium Dioxide FD&C Blue 1 D&C Red 21 D&C Red 28 D&C Yellow 7 Solvent Violet 13 Violet 19 FD&C Red 40 Yellow 3 Iron Oxide Mica Hazard class and category code None None 1 - 3% 1-4% 1-4% None None None None None None None None None 4. FIRST AID MEASURES 4.1 Description of First Aid Measures General Advice: First aid followed by medical attention. Inhalation: Move exposed person to fresh air. Keep warm and at rest. Seek medical attention as soon as possible. Skin contact: Wash with mild soap and water. Generally the product does not irritate the skin. Seek medical advice if irritation occurs/persists. Eye Contact: Rinse opened eye for several minutes under running water. Seek medical attention if irritation persists. Ingestion: Wash mouth out with water, seek medical attention if symptoms occur. 4.2 Most Important Symptoms and effects, both acute and delayed No data available 4.3 Indication of any immediate medical attention and special treatment needed No data available 5. FIRE FIGHTING MEASURES 5.1 Suitable Extinguishing Media: Water spray, extinguishing foam, dry powder extinguisher, carbon dioxide. 5.2 Special hazards arising from the substance or mixture: If these products are either ignited or exposed to elevated temperatures causing decomposition toxic vapours may be emitted. 5.3 Advice for fire-fighters: Wear self contained breathing apparatus for fire fighting. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions: Wear protective equipment. Keep unprotected persons away. Avoid formation of dust 6.2 Environmental precautions: Do not allow product to reach ground water, water bodies or sewerage system. 6.3 Methods for cleaning up: Pick up manually or vacuum. 7. HANDLING AND STORAGE 7.1 Precautions for Safe Handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection. 7.2 Conditions for safe storage including any incompatibilities: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from sources of ignition. 7.3 Specific end uses: None 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control Parameters: These products do not contain any relevant quantities of materials with critical values that have to be monitored in the workplace. (ref: EH40/2005 as consolidated with amendments Oct 2007) National exposure control limits must be considered where appropriate. 8.2 Exposure Controls: Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal Protective equipment Ventilation: Preferably Local exhaust ventilation (LEV) must be sufficient to keep concentration below occupational exposure limit Respiratory protection: Particulate cartridge filter type when LEV cannot be supplied. Hand Protection: Gloves: consult manufacturer for suitable specification. A suitable barrier cream is recommended. Eye Protection: Safety glasses with side shields. Body Protection: Protective work clothing General Safety and Hygiene measures: Do not eat or drink while working with the product. Wash hands before breaks and at the end of work. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES 9.2 Information on basic physical and chemical properties a) Appearance: Solid flakes b) Odour: Mild, characteristic c) Odour Threshold: No data Available d) pH: No data available e) Melting point/freezing point: 260°C f) Initial boiling Point and boiling range: No data available g) Flash point: No data Available h) Evaporation rate: No data Available i) Flammability (solid, gas): No data Available j) Upper/lower flammability of explosive limits: No data Available k) Vapour pressure: No data Available l) Vapour density: No data Available m) Relative Density: 1.4g/cm 3 at 20°C n) Water solubility: Insoluble o) Partition Coefficient: n octanol/water: No data Available p) Auto ignition temperature: Not self igniting q) Decomposition temperature: No data Available r) Viscosity: No data Available s) Explosive properties: Does not present explosive hazard t) Oxidising Properties No data Available 9.3 Other Safety Information No data available 10. STABILITY AND REACTIVITY 10.1 Reactivity no data available 10.2 Chemical stability no data available 10.3 Possibility of hazardous reactions no data available 10.4 Conditions to avoid Avoid contact with acids, alkalis and strong oxidizing agents. 10.5 Incompatible materials no data available 10.6 Hazardous decomposition products no data available 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell Mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects no data available Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Additional Information When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. The substance is not subject to classification according to the latest version of the EU lists. 12. ECOLOGICAL INFORMATION 12.1 Toxicity no data available 12.2 Persistence and degradability no data available 12.3 Bio accumulative potential no data available 12.4 Mobility in soil no data available 12.5 Results of PBT and vPvB assessment no data available 12.6 Other adverse effects no data available 13. DISPOSAL CONSIDERATIONS Product: Remove in accordance with local official regulations. Used packaging material: Containers may be recycled or re-used. Observe local/state/federal regulations. 14. TRANSPORT INFORMATION: Not restricted for transport. 15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available 15.2 Chemical Safety Assessment no data available 16. OTHER INFORMATION Cosmetic Polyester Cosmetic Holographic Cosmetic Pastel Cosmetic Mica Premier Polyester Premier Holographic Premier Pearl Premier Iridescent Sawtooth Fibres Angelina Fibres Ref:MCSNPL/01