NOVO-GLOSS IQ GONIOPHOTOMETER Application Notes- Powder Coating Smoothness Scale RHOPOINT INSTRUMENTS LTD Novo-Gloss IQ Application Notes Rhopoint Instruments Beeching Road • Bexhill-on-Sea East Sussex, UK, TN39 3LG Phone +44 (0) 1424214291 • Fax +44 (0) 1424 730600 Table of Contents Powder Coating Quality............................................................ 1 Assessing Coating Reflective Qualities .................................... 1 Instrumental Assessment of Coatings ...................................... 2 Glossmeter ............................................................................... 2 Distinctness of Image ............................................................... 3 Novo-Gloss IQ Goniophotometer ............................................. 4 Haze ........................................................................................ 5 RSPEC..................................................................................... 6 BYK Micro-Wave-Scan............................................................. 6 Powder Coating Quality A high quality finish is becoming increasingly important for powder coated products. In the past it was best known for its durability and low environmental impact, but with improvements in formulation and application techniques, a powder coating finish can now match or exceed the appearance quality of liquid paints. Achieving the highest quality finish requires skilled operators, well formulated coatings and optimum application equipment and conditions. This is particularly true in for powder coatings as the process can be prone to orange peel, surface texture and haze effects. These imperfections can dramatically reduce the visual impact of finished products and are historically difficult to measure. Assessing Coating Reflective Qualities To aid designers, coating manufacturers and applicators the Powder Coating Institute has developed a comparison tool to simulate all possible finishes that are achievable using this technology. This visual scale comprises ten powder coated panels, which have been graded from 1- high roughness & orange peel to 10- a very smooth glossy finish. The set is often used to grade the quality of powder coated surfaces; the operator simply judges which the panel is closest visually to the sample. Unsurprisingly the results achieved by this method are highly subjective and prone to errors due to sample area, lighting conditions and coating colour. Panels 1,5 and 10 showing the reflection of a fluorescent desk lamp. Note the decreasing amounts of orange peel. 1 Instrumental Assessment of Coatings To avoid the errors associated with operator judgment, sample type and measurement conditions, it is preferable to use an instrument to measure such a crucial parameter. Three instruments were compared to determine their suitability for measuring textured surfaces and in particular the powder coating smoothness scale, a set of these panels were used in the assessment. Glossmeter The most commonly used instrument to measure coating reflective appearance quality is a glossmeter. Glossmeters shine light at a surface and measure the amount of reflection at the specular angle. The standard for gloss measurement specifies three geometries for measuring high, medium and low gloss levels. The most commonly used geometries used in powder coatings are 20⁰ and 60⁰. A Rhopoint Novo-Gloss Trio was used to assess the 10 panels, the average of 10 readings for each panel is shown below. 20⁰ 60⁰ 85⁰ 1 53.1 95.3 79.8 2 3 86.4 92.2 101.9 101.5 94.8 92 4 98.8 99.1 92 5 93.6 98.6 95.2 6 96 .8 98.3 94.3 7 94.9 96.6 93.7 8 90 95.9 90.2 9 94.5 95.8 98.8 10 93.1 98.5 99.4 Despite large differences in appearance, the gloss readings for the panels are almost identical. This is because the glossmeter can only measure the amount of reflected light and is not sensitive to distortions which affect appearance quality. Differences in gloss values are only apparent on panels 1 and 2 on where the orange peel is reflecting light outside the detection range of the instrument resulting in a lower 20⁰ gloss value. Applications such as powder coatings which are highly likely to be affected by orange peel and similar effects logically require a measurement method which more successfully quantifies texture. 2 Distinctness of Image D.O.I is a parameter which describes the visual distortion seen in a reflection of an object viewed in a textured surface. To understand this concept, the reflection of a specially designed test chart has been viewed and photographed in each of the 10 powder coating smoothness panels. Panel 1 Panel 2 Panel 3 Panel 4 Panel 5 Panel 6 Panel 7 Panel 8 Panel 9 Panel 10 The photographs illustrate how the very high orange peel in panel one produces an image with poor clarity, as the orange peel reduces; the distinctness of the image improves. Distinctness of image is quantified instrumentally by measuring the spread of a beam of light after it has been reflected from a surface. Surfaces which reflect an image perfectly without any distortion have a DOI value of 100, surfaces with no image clarity have a DOI of 0. 3 Novo-Gloss IQ Goniophotometer The new Novo-Gloss IQ instrument from Rhopoint Instruments was used to measure the reflective qualities of the panels at 20⁰. Unlike a glossmeter which quantifies the amount of reflected light by using a single sensor, the IQ uses an array of 256 micro-sensors that allow it to fingerprint how the light is reflected, producing a goniphotometric profile around the specular angle. Connecting the instrument to a PC the user can view Goniophotometric profiles, comparing how the light is distributed for different surfaces. The goniophotometric profiles for panels 1,5 and 10, manipulated in MS excel to show +/- 1⁰ from specular. The instrument calculates GLOSS, HAZE, RSPEC and DISTINCTNESS OF IMAGE using the angular tolerances specified in relevant international standards for these measurements. The values shown are the average of 10 readings. The instrument is operated with a single button push, all values are displayed on a single screen. 4 Gloss20⁰ Log Hze RSpec DOI 1 46.0 488.2 9.6 31.3 2 3 91.4 102.6 104.0 2.2 20.6 32.8 44.4 60.2 4 98.8 0.0 41.4 74.2 5 96.5 0.0 54.3 89.1 6 99.2 0.0 61.5 92.8 7 97.0 0.0 70.3 96.9 8 93.5 0.0 71.9 98.1 9 94.7 0.0 79.0 98.9 10 92.4 0.0 79.9 99.5 The DOI perfectly shows the reduction in orange peel from panels 1 to 10, whilst gloss values can be seen to equate to those measured using a conventional instrument. The DOI of the panels increases as the amount of texture reduces (orange peel). Haze Haze is a phenomenon where micro structures on the surface of the coating cause reflected light to be slightly diffused around the specular angle. Surfaces with haze exhibit a milky finish or a halo effect around the reflection of a strong light source. The effect of surface haze can be viewed on the reflected test panel pictures 1 and 2, the edges of these charts are blurred and slightly enlarged compared to the panels without measured haze. Powder coating is especially prone to haze effects; this can be due to stoving problems, raw material incompatibilities or additive migration. 5 RSPEC RSPEC is the peak gloss value at the specular angle; surfaces with high DOI have a sharper goniophotometric curve and hence have a higher RSPEC value. BYK Micro-Wave-Scan The BYK wave scan is used extensively to measure surface texture on automotive finishes. A smaller version of this instrument the micro-wave-scan is used to assess curved surfaces and small parts. Its mode of operation is different to that of glossmeters and the Novo-Gloss IQ, the instrument is rolled across the surface to be tested and a laser is employed to measure the topography. The information obtained is mathematically manipulated to provide a number of indices that are used to assess quality and diagnose faults in paint application. The instrument also produces DOI values, and these were used to assess the finish of the PCI powder coat smoothness panels. 1 Du Wa Wb Wc Wd LW SW OP DOI BOI out of range 2 25.5 38.1 69.6 96.2 75 104 84.9 25 71.9 49.8 3 12.5 32.3 60.8 81.8 67.8 86.9 76.9 25 79.1 64.1 4 13.6 27.6 43.3 56.8 53.3 54 44 25 84.1 74.1 5 7.2 14.3 24.4 43.2 45.3 38.6 22.3 25 90.5 87.1 6 5.2 9.7 16.9 30.8 41.4 28.2 14.5 25.7 93 91.9 7 3.1 11.8 22.4 16.4 30.9 14.6 18.8 43 92.4 90.9 8 7.1 12.6 19.9 14.8 32.5 13.6 15.5 40.1 91.6 89.4 9 6.1 14.5 19.7 12.3 16.1 6 14.4 62.3 91.8 89.6 10 5.8 16.1 27.3 8.5 11 3.2 21.9 71.2 90.8 87.6 Data obtained for the PCI set using a BYK micro gloss (average of 5 readings). The instrument could not measure panel one. 6 A chart showing two DOI indices calculated for the PCI set using the BYK micro-wave scan. BOI is BYK DOI. The data provided by the instrument is more detailed than that provided by the Novo-Gloss IQ and may contain information on the size and frequency of the structures that are the causing orange peel effects. The DOI indices used in the Micro-Wave-Scan do not show the improvement in surface finish after panel 6 in the PCI scale. Samples with a high degree of orange peel such as panel one cannot be measured with this instrument. Conclusions Many coating technologies can be affected by surface texturing caused by poor formulation, application technique, and substrate quality or application conditions. Visual assessment of these defects is subjective and prone to error introduced by lighting conditions and the size, colour and orientation of the surface being measured. The tradition glossmeter is not able to measure orange peel and other types of surface texture. The DOI values obtained by the BYK micro-wave-scan do not alone describe the orange peel affects seen on a PCI powder coating scale and it cannot measure the most textured surfaces. 7 More detailed data about the size and frequency of textures is available from the wavescan but the complexity of interpreting such information and costs of ownership may limit the instruments use to research and the automotive industry. The Rhopoint IQ is backwards compatible with measurements taken using a traditional glossmeter. It also measures DOI which perfectly described the orange peel effects viewed on the PCI powder coating smoothness panels. The instrument can measure samples of any size and the measurements are independent of colour. The Haze information detailed by the instrument is extremely useful in the powder coating industry as well as most other coating applications. The instrument is simple to use and the data easy to understand and set specifications around. The cost of this instrument makes it suitable as QA or Research tool. Tony Burrows Rhopoint Instruments Ltd Oct 2009 8