JOURNAL OF APPLIED PHYSICS VOLUME 92, NUMBER 5 1 SEPTEMBER 2002 Improvement in light-output efficiency of InGaNÕGaN multiple-quantum well light-emitting diodes by current blocking layer Chul Huh, Ji-Myon Lee,a) Dong-Joon Kim,b) and Seong-Ju Parkc) Nanophotonic Semiconductor Laboratory, Department of Materials Science and Engineering, Kwangju Institute of Science and Technology, Kwangju 500-712, Korea 共Received 17 January 2002; accepted for publication 5 June 2002兲 The fabrication and characterization of an InGaN/GaN multiple-quantum well 共MQW兲 light-emitting diode 共LED兲 with a SiO2 current blocking layer inserted beneath the p-pad electrode is described. The light-output power and external quantum efficiency for the InGaN/GaN MQW LED chip with a current blocking layer were significantly increased compared to those for the conventional InGaN/GaN MQW LED chip. The increase in the light-output power can be attributed to the injection of additional current into the light-emitting quantum well layer of the LED by the SiO2 current blocking layer and a reduction in parasitic optical absorption in the p-pad electrode. © 2002 American Institute of Physics. 关DOI: 10.1063/1.1497467兴 I. INTRODUCTION eration and degradation in the reliability of LEDs due to the high-electrical carrier density in a localized area of the device. Therefore, to increase the light output from GaN-based LEDs, a more efficient light extraction through the chip, packaging, and device design will be required. In this article, we report on an investigation of the fabrication and characterization of InGaN/GaN multiple-quantum well 共MQW兲 LEDs with a current blocking layer 共CBL兲 inserted beneath the p-pad electrode by means of an insulating SiO2 layer. The results show that the light-output power of an InGaN/ GaN MQW LED chip with a CBL is considerably enhanced compared to that of an InGaN/GaN MQW LED chip with a conventional structure. GaN-based wide band-gap semiconductors have recently attracted considerable interest, in terms of applications for optoelectronic devices, which operate in the blue, green, and ultraviolet 共UV兲 wavelength regions, as well as for electronic devices operating at high-temperature/high-power conditions.1,2 As the result of the recent developments of GaN-based light emitting diodes 共LEDs兲 with increased brightness, applications including displays, traffic signals, exterior automotive lighting, and backlights for cell phones have become possible. In particular, an interest has developed concerning the use of white LEDs for general illumination using high-brightness LEDs. However, even though the brightness of visible/UV LEDs based on GaN-based materials continues to increase, the light output is still low compared to conventional light sources in high-flux lighting systems and it is necessary to further improve the light-output efficiency from LEDs.3 A general requirement of GaN-based LEDs is that both n- and p-type electrodes are formed on the same side of the epitaxial layer due to the insulating properties of the sapphire substrates. The p-type electrode, which is fabricated on the top surface of a mesa structure, is composed of a thin transparent layer of metal and a thick metal layer for wire bonding. In such a structure, the p electrode is situated in the middle of the light path, which extends from the active region of the LED structure to the top side. Hence, some loss of light is inevitable as a result of photon absorption near the p-pad electrode. Another problem arising from the lateral structure of GaN-based LEDs involves current crowding around the p-pad electrode, depending on the electrical properties of the n-GaN layer and the light-transmitting layer.4 This current crowding adversely affects the uniformity and stability of the far-field emission. In addition, current crowding may also cause a decrease in the efficiency of light gen- II. EXPERIMENTAL DETAILS The device samples were grown on c-plane sapphire substrates using a metal-organic vapor deposition system 共Emcore D125™兲 with a rotating-disk reactor. The multilayer structures consisted of a GaN nucleation layer, a Si-doped n-GaN layer (2⫻1018 cm⫺3 ), five periods of InGaN/GaN MQW active layers, and a Mg-doped p-GaN capping layer. The samples were then thermally annealed at 950 °C for 60 s in a nitrogen atmosphere using a rapid thermal annealing process in order to activate the Mg acceptors. This process produced a room-temperature p-layer concentration of 2⫻1017 cm⫺3 . As shown in Fig. 1共a兲, an InGaN/GaN MQW LED with an insulating SiO2 CBL inserted beneath the p-pad electrode was fabricated using standard photolithographic patterning and inductively coupled plasma dry etching. To insert the CBL, the surface region of the p-GaN layer beneath the p-pad electrode was partially etched by means of an inductively coupled CH4 /Cl2 /H2 /Ar plasma until the n-GaN layer was exposed. An insulating SiO2 layer was then grown using a plasma-enhanced chemical-vapor deposition system. A Ti/Al layer 共30/80 nm兲 was deposited on the n-GaN layer by e-beam evaporation, to serve as the n electrode, and a Pt film 共8 nm兲 as a light-transmitting layer was then deposited onto the p–GaN layer. Finally, a Ni/Au 共30/80 nm兲 film was de- a兲 Present address: Basic Research Laboratory, Electronics and Telecommunications Research Institute, Daejeon 305-350, Korea. b兲 Present address: Samsung Electro-Mechanics, Suwon 442-743, Korea. c兲 Electronic mail: sjpark@kjist.ac.kr 0021-8979/2002/92(5)/2248/3/$19.00 2248 © 2002 American Institute of Physics Downloaded 18 Nov 2002 to 203.237.47.107. Redistribution subject to AIP license or copyright, see http://ojps.aip.org/japo/japcr.jsp J. Appl. Phys., Vol. 92, No. 5, 1 September 2002 Huh et al. 2249 FIG. 3. Room-temperature EL spectra of the InGaN/GaN MQW LED chip with a current blocking layer as a function of the forward current. FIG. 1. 共a兲 Schematic diagram showing the structure of the InGaN/GaN MQW LED chip and the position of the CBL in the LED structure. 共b兲 Possible lateral current paths in the LED structure. posited on the light-transmitting layer, to serve as the p-pad electrode. All metal contacts were annealed at 500 °C for 30 s under an N2 ambient to obtain low-resistance ohmic contacts. Except for the additional fabrication process for the CBL, the process for the fabrication of a LED chip with a CBL is almost identical to that used for a conventional LED chip. Conventional InGaN/GaN MQW LED chips with the same device area (300⫻300 m2 ) were also fabricated using the same wafer for comparison studies. Figure 1共b兲 shows the possible current paths in the conventional MQW LEDs. III. RESULTS AND DISCUSSION Figure 2 shows the power efficiencies 共output power/ input power兲 for the InGaN/GaN MQW LED chip with a CBL and a conventional InGaN/GaN MQW LED chip. The power efficiency was calculated from the measured light output power and I – V curve. The power efficiency for LEDs with a CBL is higher than that for LEDs without a CBL and FIG. 2. Power efficiencies 共output power/input power兲 for the InGaN/GaN MQW LED chip with a CBL and a conventional LED chip. increases with increasing input power, as shown in Fig. 2. From I – V curves of two LEDs 共not shown兲, the forward voltage at 20 mA for the InGaN/GaN MQW LED chip with a CBL was slightly increased by 0.1 V compared to that of a conventional InGaN/GaN MQW LED chip. Acceptable electrical properties are also exemplified by the low-reverse current which is less than 10 A at ⫺10 V for both cases. The slight increase in forward voltage can be attributed to the reduction in the total area of the p-type metal contact between the transparent Pt layer and the p-GaN as the result of the presence of an insulating SiO2 layer, which is used as a CBL. The area of the CBL which is inserted beneath the p-pad electrode is about 30% of the total p-type GaN area of the InGaN/GaN MQW LED fabricated in this study. Jin et al.5 also reported that a slight increase in the forward voltage at 20 mA can be attributed to the reduction in the total contact area between the p-type GaN and the metal in the case of microdisk LEDs. Figure 3 shows the room-temperature electroluminescence spectra of the InGaN/GaN MQW LED chip with a CBL as a function of the forward current. The peak wavelength and the full width at half maximum of the emission spectra are 470 and 20 nm at 20 mA, respectively. When the forward current is increased from 20 to 80 mA, the peak wavelength of the LED chip with a CBL slightly shifts to 466 nm. It is generally known that the shift of wavelength can be attributed to the In composition fluctuation in the InGaN well layer due to the natural phase separation of InGaN during growth or the band-filling effect with the increment in the current injection. Here, the slight shift toward the short wavelength in emission spectra is caused by the bandfilling effect in InGaN/GaN MQW due to the increase in the injection current. This is also in good agreement with our previous result.6 Figure 4 shows the light-output power 共P兲 and external quantum efficiency ( ext) calculated from the measured light-output power of bare LED chips with and without a CBL as a function of forward current. The light-output power was measured from the topside of the bare LED wafer chips with an area of 300 m⫻300 m using a calibrated Si photodiode 共Model 818-UV兲 connected to an optical power meter 共Model 1835-C兲. As shown in Fig. 4, the light-output power of the InGaN/GaN MQW LED chip with a CBL at 20 Downloaded 18 Nov 2002 to 203.237.47.107. Redistribution subject to AIP license or copyright, see http://ojps.aip.org/japo/japcr.jsp 2250 Huh et al. J. Appl. Phys., Vol. 92, No. 5, 1 September 2002 FIG. 4. Light-output power 共P兲 and external quantum efficiency ( ext) for an InGaN/GaN MQW LED chip with a CBL and a conventional LED chip measured through the light-transmitting layer on an unpackaged chip as a function of forward current. mA was increased by 62% compared to that of the conventional InGaN/GaN MQW LED chip, although the lightemitting active area was reduced due to the CBL region inserted into the LED structure, as shown in Fig. 1共a兲. These results show that the current blocking layer inserted into the LED structure can significantly improve the light-output efficiency of a conventional LED chip. GaN-based LEDs grown on an insulating sapphire substrate should have a lateral current path because two electrodes are formed on the same side of the substrate,7 as shown in Fig. 1共b兲. Perfectly uniform current spreading across the active area of the LED can be achieved only when the total voltage drop across path A is same as the voltage drop across path B. However, the current will flow efficiently in only one of the two current paths, depending on the electrical properties of current paths A and B. If the lighttransmitting metal layer is relatively thick and thus becomes a perfect current spreader, the resistivity of the n-type GaN layer would be expected to significantly affect the current spreading. Otherwise, the resistivity of the light-transmitting layer would be expected to play a crucial role in the current flow. It has been reported that when the electron concentration in an n-type GaN layer is below 1018 cm⫺3 and the conductivity of the n-type GaN layer is, therefore, insufficient to meet the current uniformity conditions, the current will flow via the shortest path B through the lighttransmitting metal layer, resulting in current crowding near the n-pad electrode.4 The electron concentration of the n-type GaN layer in our InGaN/GaN MQW LED was about 2 ⫻1018 cm⫺3 and the resistivity, as determined by Hall measurement was about 10 m⍀ cm. The thickness of the lightemitting Pt layer used in this study was 8 nm. It is generally accepted that the resistivity of a metal film is inversely proportional to the thickness of the metal and the resistivity of a thin metal film with a thickness below 10 nm is about 1000 times higher than that of a bulk film.8 Because the resistivity of a Pt bulk film is about 10.8 ⍀ cm,9 the resistivity of a Pt thin film with a thickness of 8 nm will therefore be above 20 m⍀ cm. Under these conditions, the current from the p-pad electrode will flow more easily through path A than path B as shown in Fig. 1共b兲 due to less resistance to the current flow. Therefore, the current would be crowded near the p-pad electrode in this case. This current crowding near the p-pad electrode can result in low light-output efficiency due to both inefficient current injection into the active area in the LED structure and limited recombination near the p-pad electrode. It has been reported that the increase in the current injection into the active area of the LED structure through a lighttransmitting metal layer plays an important role in improving LED performance.10,11 Hence, the increase in the light-output power of the InGaN/GaN MQW LED chip with a CBL can be attributed to the increase in current injection into the entire active area of the LED through path B 共light-transmitting layer兲 as shown in Fig. 1共b兲. In addition, for the case of the InGaN/GaN MQW LED chip with a CBL, because the current was dominantly injected into the middle area of LED through the light-transmitting layer 共through path B兲 as discussed above, the parasitic optical absorption12 can be reduced due to the reduction in light absorption at the thick p-pad electrode. This results in a further improvement in the light output of the LED chip with a CBL compared to that of a conventional LED chip. IV. CONCLUSION We report here on the fabrication of an InGaN/GaN MQW LED chip having a CBL inserted beneath the p-pad electrode and its characterization. The light-output power of the InGaN/GaN MQW LED chip with a CBL was found to be greatly increased compared to that of a conventional LED chip structure due to the increase in current injection into the active layer of the LED structure via the light-transmitting Pt layer and a reduced parasitic optical absorption at the p-pad electrode. ACKNOWLEDGMENT This work was partially supported by a grant from the National Research Laboratory Program on Nanophotonic Semiconductors in Korea. S. Nakamura and G. Fasol, The Blue Laser Diode 共Springer, New York, 1997兲. M. A. Khan, J. N. Kuznia, A. R. Bhattarai, and D. T. Olson, Appl. Phys. Lett. 62, 1786 共1993兲. 3 J. J. Wierer, D. A. Steigerwald, M. R. Krames, J. J. O’Shea, M. J. Ludowise, G. Christenson, Y.-C. Shen, C. Lowery, P. S. Martin, S. Subramanya, W. Götz, N. F. Garder, R. S. Kern, and S. A. 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