Computational Materials Science 45 (2009) 327–335 Contents lists available at ScienceDirect Computational Materials Science journal homepage: www.elsevier.com/locate/commatsci Numerical study and comparisons of gas tungsten arc properties between argon and nitrogen Shanping Lu *, Wenchao Dong, Dianzhong Li, Yiyi Li Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China a r t i c l e i n f o Article history: Received 7 April 2008 Received in revised form 25 September 2008 Accepted 2 October 2008 Available online 26 November 2008 PACS: 51.50.+V Keywords: Numerical simulation Arc plasma Nitrogen Argon a b s t r a c t In this paper, nitrogen was used as an alternative gas for its fine protection to weld pool and relatively low cost, in contrast to widely used argon and helium shielding gases in gas tungsten arc welding (GTAW). A two-dimensional axisymmetric numerical model from McKelliget et al. was adopted to describe the heat transfer and fluid flow in the gas tungsten arc (GTA) to predict the basic energy source properties of nitrogen GTA. Simulation results showed that the arc temperature contours, the distribution of heat flux and current density at the anode agree well with experimental results in literature for both argon-shielded arc and nitrogen-shielded arc. To solve the model, the nitrogen arc plasma properties, i.e. temperature, voltage drop and flow fields have been derived. And the distribution of the heat flux, current density and gas shear stress at the anode with the different arc lengths and welding currents has been studied. Moreover, by comparing with the properties between the argon and nitrogen arc, the results indicate that the nitrogen arc is more contraction than that of argon arc under the same arc length and welding current. Especially, the increasing of the maximum of heat flux and current density at the anode shows that the nitrogen GTA possessed excellent energy source properties for GTAW in contrast to the argon arc. Ó 2008 Elsevier B.V. All rights reserved. 1. Introduction As a thermal plasma, the gas tungsten arc (GTA) has been extensively utilized in material processing, such as welding, cutting and spraying [1]. Therefore, it is necessary to understand accurately the basic phenomena of the arc plasma. However, the arc processing needs relatively higher cost compared with the convectional treatment by combustion, since the arc can be produced only by large electric power. For this reason, the optimization of the operating conditions for the improvement of cost performance has been expected eagerly in the industrial world. Nevertheless, it is experimentally difficult to clarify the physical phenomenon in detail and to optimize the operating conditions of an arc-electrodes system, since the thermofluid field of an arc is very complex in the extreme conditions. The numerical modeling is expected to be one of the effective approaches to solve this problem. In the last two decades, the axisymmetric arc model has been widely studied [2–9]. A very fundamental work concerned with the study of the plasma arc configurations is the one of Hsu et al. [2]. McKelliget and Szekely [3] published a mathematical model considering all the important physics. Their main contribution was to propose a better representation of heat flux and current density at the anode surface. Choo et al. [4], Wu et al. [5] and Ramirez et al. [6] provided similar numerical * Corresponding author. Tel./fax: +86 24 23971429. E-mail address: shplu@imr.ac.cn (S. Lu). 0927-0256/$ - see front matter Ó 2008 Elsevier B.V. All rights reserved. doi:10.1016/j.commatsci.2008.10.010 models, to investigate the behaviors of the TIG welding arc plasma in argon. Lago et al. [7] included the solid anode domain in the computation, as well as the effects of anode vaporization. Lowke and Tanaka et al. [8,9] developed a unified model considering simultaneously both the electrodes and arc regions. In general, the difference between those models is the critical boundary condition at the cathode tip. Nevertheless, those models are all proven to give satisfactory results in regard of the plasma stream variables. Majority of the researches are strengthened on the argon shielding gas. Energy source properties of GTA strongly depend on the physical properties of the shielding gas. For instance, Tanaka et al. [9,10] compared the differences between the argon arc and the helium arc. In contrast to the argon arc, the current channel of helium arc is constricted due to its low electrical conductivity. Consequently, the constriction increases the heat input intensity to the target materials and, thus, leads to high productivity. However, the high cost of helium and the poor arc ignitability limit its applications in industry. Therefore, an alternative shielding gas with lower cost and better energy source properties is required. Nitrogen is another prospective gas with good protection, cheep cost and easy available in industry. Generally, the nitrogenshielded gas GTA welding is applied to the high nitrogen stainless steel. Addition of nitrogen to stainless steels improves the strength, the corrosion and the fracture toughness of the steels [11]. The effect of the nitrogen in GTA welding on the melting and penetration of AZ80 magnesium alloy is investigated by Marya [12], and the 328 S. Lu et al. / Computational Materials Science 45 (2009) 327–335 Nomenclature Az, Ar Bh Cp e I jz, jr JC K kb kg P QA Qc Qe Qr QC RC SR T axial, radial electrical vector potential azimuthal magnetic field (Wb m2) heat capacity (J kg1 K1) electronic charge (C) arc current (A) axial, radial current density (A m2) cathode current density (A m2) thermal conductivity (W m1 K1) Boltzman’s constant (J K1) thermal conductivity taken at an average temperature of the gas (W m1 K1) pressure (Pa) anode heat flux (W m2) conversion contribution to the anode heat flux (W m2) electron contribution to the anode heat flux (W m2) radiation contribution to the anode heat flux (W m2) cathode heat flux (W m2) cathode spot radius (m) radiate source (W m3) temperature (K) Ta,g Tanode Tc,g Tcat Telec u; v Va VC z; r l l0 q r / UW a d temperature at 0.1 mm from the anode (K) temperature at the anode surface (K) temperature of the gas in the cell closest to the cathode (K) temperature in the cathode (K) temperature of the electrons (K) axial, radial velocities (m s1) anode voltage fall (V) cathode voltage fall (V) axial, radial coordinate (m) viscosity (kg m1 s1) magnetic permeability of free space (H m1) density (kg m3) electric conductivity (S m1) potential (V) material work function (V) ratio of electrons to plasma temperature at the anode fall (1.2 [6]) maximum experimentally observed thickness of the anode fall region (0.1 mm [7]) results show that with diatomic gases such as nitrogen and hydrogen, voltage and weld dimensions were even further increased. Yan et al. [13] simulated the welding temperature patterns of gas tungsten arc welding for copper thick plates during Ar, He or N2 shielded arc welding. By comparing the size of the heat-affected zones, it is the narrowest during N2 arc welding. In addition, Haidar et al. [14] and Murphy [15] used the spectroscopic and laser-scattering technique to measure the free-burning nitrogen arc, respectively. In this paper, by adopting nitrogen, the basic energy source properties of nitrogen GTA are investigated systematically. Calculations are carried out using the commercial software FLUENT version 6.2.16, adapted for thermal plasmas. First, the arc plasma 2D configuration is presented and compared with experimental in order to validate the model. Not only the nitrogen arc properties are predicted, but also the effects of the welding current, arc length on the heat flux, current density and shear stress at the anode are analyzed. Finally, the results are compared with those of conventional argon gas tungsten arc. 2. Mathematical modeling Fig. 1. Computational domain for the welding arc. The computational domain for the welding arc is shown in Fig. 1. The welding arc consists of an electric arc struck between a tungsten electrode and a steel workpiece. In GTAW, the process is usually direct current straight polarity, where the electrode is negative (cathode) and the workpiece is positive (anode). As the arc plasma can be approximated to a fluid, the Navier–Stokes equations are used to describe the arc plasma column, to which the electromagnetic equations are added to take into account the electromagnetic properties of the arc. The arc plasma is supposed to be in local thermal equilibrium (LTE), which implies that the electron and heavy particle temperatures are not significantly different. The plasma is optically thin, i.e. no absorption is taking place inside the arc. Gravity and heat dissipation due to viscosity effects are neglected. 2.1. Assumptions 2.2. Governing equations The following assumptions are made in the mathematical model: Using the above assumptions, the conservation equations can be written as follows. Mass continuity equation is The arc is steady, radially symmetrical. So the arc can be modeled in a two-dimensional cylindrical coordinate. And the flow is assumed to be laminar. o 1 o ðqvz Þ þ ðqrvr Þ ¼ 0 oz r or Radial momentum conservation equation is ð1Þ 329 S. Lu et al. / Computational Materials Science 45 (2009) 327–335 o 1 o oP o ov ov l rþl z ðqvz vr Þ þ ðqrvr vr Þ ¼ þ oz r or or oz oz or 1 o ovr þ 2r l jz Bh r or or Table 1 Boundary conditions for the welding arc models ð2Þ Axial momentum conservation equation is o 1 o oP o ovz ðqvz vz Þ þ ðqrvr vz Þ ¼ þ 2l oz r or oz oz oz 1 o ovz ovr þ jr Bh þ rl þ rl r or or oz ð3Þ o 1 o o k oh 1 o k oh þ ðqvz hÞ þ ðqrvr hÞ ¼ r oz r or oz C p oz r or C p or 2 2 jz þ jr 5 kb jz oh jr oh þ SR þ þ 2 e C p oz C p or r ð4Þ The last three terms in Eq. (4) represent the Joule heating, the radiation losses and the diffusive transport of enthalpy due to the electron flux, respectively. Current continuity equation is ð5Þ According to Ohm’s law, the current density components are as follows jz ¼ r o/ oz vz vr T / Az oAz oz oAz oz oAz or oAz oz oAz or oAz oz oAz or ¼0 1000 ¼0 1000 o/ oz o/ oz o/ or o/ oz o/ or 1000 0 oT or o/ or ab – 0 0 3000, Q = Eq. (16) bc – 0 0 3000 cd – 0 0 3000 de 1 ef 1 ovz oz ovz or fg – 0 ga – ovz or ¼0 ¼0 ovr oz ovr or 0 ¼0 ovr or ¼0 ¼ 0, Q = Eq. (21) ¼ JC ¼0 ¼0 ¼0 ¼0 ¼0 Ar ¼0 ¼0 ¼0 ¼0 ¼0 ¼0 ¼0 oAr oz oAr oz oAr or oAr oz oAr or oAr oz oAr or ¼0 ¼0 ¼0 ¼0 ¼0 ¼0 ¼0 The unit for pressure P, velocity vz ; vr , temperature T and potential / is atm, m/s, K and V, respectively. Energy conservation equation is o o/ 1 o o/ r þ rr ¼0 oz oz r or or P ð6Þ jz ¼ J C r < RC ð13Þ jz ¼ 0 r > RC ð14Þ where the radius of the cathode spot is defined as sffiffiffiffiffiffiffi I RC ¼ pJC ð15Þ McKelliget and Szekely [3] found that a single value of the cathode current density gave good results, compare with experimental measurements, for different values of welding current and arc length. In this paper, JC is assumed to be 6.5 107 A/m2. The electric potential is assumed to be iso-potential (zero) at the anode (regions f–g). This is based on the assumption that the conductivity in the metal is much higher than that in the plasma, implying that the variation of the electric potential in the metal is much less than that in the arc. 2.4. Source terms used at the cathode and anode regions o/ jr ¼ r or ð7Þ In order to obtain the magnetic field, the potential vector method is adopted [7]. ! ! ! r 2 A ¼ l0 j ð8Þ so o2 Az 1 o oAz þ r þ l0 jz ¼ 0 2 r or oz or o2 Ar 1 o oAr Ar þ r 2 þ l0 jr ¼ 0 r or oz2 or r ð9Þ Q C ¼ jJ C jV C ð10Þ ð11Þ Bh ¼ oAr oAz oz or 5 kB T elec 2 e ð12Þ 2.3. Boundary conditions In order to solve the transport equations for the calculation domain, boundary conditions need to be specified. A complete listing of boundary conditions for the welding arc is presented in Table 1. Domain boundaries are lines linked by points expressed by capital letters according to the notation used in Fig. 1. The most critical boundary condition is the electrical potential / at the cathode. Here, the boundary condition is approximated by assuming that the cathode current density, J C emitted from the cathode normal to the surface is constant inside the cathode spot radius, RC (regions a–b), and is zero outside, i.e. ð17Þ where T elec is approximated by the following relationship [17] T elec ¼ T c;g T cat Therefore ð16Þ and the cathode voltage fall V C , can be described as VC ¼ From them we can deduce the azimuthal magnetic induction ! ! ! B ¼r A 2.4.1. Cathode region It was shown by Hsu and Pfender [16] that in the cathode boundary layer the plasma is not in LTE condition due to a difference in temperature between electrons and heavy particles. For thermionic cathodes, McKelliget and Szekely [3] suggested that a positive source term could be used to account for the energy used in the cathode boundary layer to ionize the plasma and thereby cause a drop in the electric potential. This heat source for the arc column can be expressed as ð18Þ 2.4.2. Anode region In this investigation, the following four different mechanisms for the heat transfer from the arc to the anode are considered: (1) heat flux due to the electron flow, (2) conduction from the plasma, (3) radiation from the plasma. Heat loss due to vaporization in the anode boundary is neglected. The heat flux to the anode due to the flow of electrons may be expressed as Q e ¼ jz 5 kB aT a;g T anode þ jz ðUW þ V a Þ 2 e ð19Þ For steel, the work function plus the anode fall UW þ V a is equal to 6.76 V [6]. The heat transferred by conduction from the arc is calculated as follows 330 Q c ¼ kg S. Lu et al. / Computational Materials Science 45 (2009) 327–335 T a;g T anode d ð20Þ Ushio [18] found that the contribution of plasma radiation Qr to the anode is less than 5% of the total heat input. So Qr is taken as 3% here. In conclusion, the total energy from the arc to the anode is represented as follows QA ¼ Qe þ Qc þ Qr ð21Þ 2.5. Physical properties Physical properties, namely density, viscosity, thermal conductivity, specific heat and electrical conductivity of argon and nitrogen are treated as functions of temperature. All these properties are taken from the tabulated data of Boulos et al. [19], as shown in Fig. 2a–e. The radiation loss term SR for argon in the energy conservation equation is taken from experimental data of Evans and Tankin [20], as shown in Fig. 2f. In this study, the radiation loss term for argon is used in the nitrogen calculations, due to a lack of sufficient data for nitrogen. It is important to note the highly nonlinear properties of the argon and nitrogen arc with respect to temperature. To solve the above equations, the commercial fluid dynamics software FLUENT V6.2.16 is used. FLUENT is a computer program based on the finite volume method that models fluid flow, heat transfer and so on. User-defined subroutines are written to handle some special boundary conditions, special source terms appearing in each equation, as well as the extra scalar equations needed for the electromagnetic variables [21]. These subroutines are added to the program to solve the welding arc problem. The face values of scalar variables are also required for the convection terms and their values are gained from interpolation. First order upwind scheme was adopted to calculate the face values of the scalar variables, since the problem was convection-dominated flow. For pressure and velocity coupling, the SIMPLE algorithm was employed [22]. For the solution algorithm, the segregated solver was selected. This means that the segregated approach solves a single variable field by taking all control volumes at the same time into consideration. It then solves for the next field variable by again considering all control volumes at the same time and so on [21]. 3. Results and discussion 2.6. Numerical method 3.1. Validation The whole calculation domain as shown Fig. 1 is discretized with a quadrilateral, nonstructured grid. The nodes are clustered near the electrodes surfaces and the arc axis. The smallest grids are the thickness of the anode fall region (0.1 mm 0.1 mm). As was stated in the aforementioned introduction, the extensive experimental welding arc studies are available in the literature and can be used to validate the predictions of the current arc model. Fig. 2. Physical properties of argon and nitrogen as a function of temperature: (a) density [19], (b) specific heat [19], (c) viscosity [19], (d) thermal conductivity [19], (e) electrical conductivity [19], and (f) radiation loss [20]. S. Lu et al. / Computational Materials Science 45 (2009) 327–335 331 Figs. 3 and 4 show the comparison of the temperature contours between the calculated and experimental results [2,14] for the argon arc at 200 A welding current, 10 mm arc length and the nitrogen arc at 200 A welding current, 5 mm arc length, respectively. The typical bell shape of the arc periphery expressed Fig. 4. Comparison between experimental and calculated temperature contours in the welding arc for nitrogen arc. The experimental results (200 A at 5 mm arc length) are from Haidar et al. [14]. Fig. 2 (continued) Among the various arc properties, the temperature distribution, the heat flux to the workpiece and the anode current density are mostly concerned due to its affects on the heat transfer and fluid flow in the weld pool. For the purpose to verify the validity of the model, the result of the calculations is compared with available experimental data. Fig. 3. Comparison between experimental and calculated temperature contours in the welding arc for argon arc. The experimental results (200 A at 10 mm arc length) are from Hsu et al. [2]. Fig. 5. Comparison between experimental and calculated radial profiles of the plasma temperature of a 200 A nitrogen arc at two axial distances from the cathode (a) 1 mm and (b) 3 mm. The experimental results are from Murphy [15]. 332 S. Lu et al. / Computational Materials Science 45 (2009) 327–335 by the isotherm of 11000 K and 8000 K is clearly observed for both the argon arc and the nitrogen arc. The comparisons between calculated and measured temperature contours show a fairly good agreement when the temperature is above 12000 K. The difference between the experimental and the calculated data for the 12000 K temperature distributions could be due to several reasons. The most probable one is due to the LTE assumption used in the present study. It is known that the outer fringes of the arc are not in LTE, which cause the experimental and calculated results to be a little off in the arc fringes. Figs. 5a and b show that the calculated radial profiles of the plasma temperature of a welding current 200 A, arc length 5 mm nitrogen arc at two axial distance, 1 mm and 3 mm, from the cathode, and compared with the experimental results [15]. It can be seen that the experimental measurements and the calculated results agree well. Fig. 5b shows the difference between experimental and calculated data when the radial distance is over 4 mm. The reason could be the LTE assumption as previously mentioned. Additional comparisons between the present calculated results and corresponding experimental data from Nestor [23] at 200 A welding current and 6.3 mm arc length are presented in Fig. 6 including the anode heat flux and current density for argon arc. It can also be seen that a reasonable agreement is obtained between the present predicted results and the experimental data. In summery, these figures provide confidence in the arc model and which can be utilized to investigate other the properties of the argon and nitrogen arc. 3.2. Nitrogen arc properties Nitrogen is an easily obtained gas with good protection to weld pool. Also it is cheap compared with argon or helium shielding gas. It is a prospective shielding gas for arc welding especially for copper and high nitrogen steel. Systematically simulation works on the nitrogen arc are studied here, and compared with the argon arc. Six major properties of the arc, i.e. maximum temperature ðT max Þ, maximum axial velocity ðvmax Þ, electric potential difference (V), anode pressure difference (P), maximum anode current density ðJ a; max Þ and the maximum anode heat flux ðQ a; max Þ for nitrogen arc are summarized as shown in Table 2. The welding current and electrode tip work distance (arc length) are two main welding parameters strongly affecting the weld pool shape, volume and welding productivity to which paid attention by the welding researchers and engineers. However, the real reason working the weld pool variable is from the arc properties affected by the shielding gas and welding parameters. For gas tungsten arc welding (GTAW), the welding current is often below 400 A, and the arc length is generally between 2.0 and 6.0 mm. In this study, the effects of welding current and arc length on the nitrogen gas tungsten arc are systematically studied. Figs. 7 and 8 show the radial variation of the anode heat flux and current density for nitrogen arc at 200 A for three different arc lengths of 2.0 mm, 3.0 mm and 5.0 mm, respectively. As the arc length increases, the maximum of heat flux and current density at the anode decreases, and its distribution radius increases. The increase of arc length can lead to the extension of the arc distribution on the anode surface. As the conductive cross-sectional radius Table 2 Calculated arc parameters at 2.0 mm and 5.0 mm arc lengths. Fig. 6. Comparison between experimental and calculated anode heat flux (a) and current density (b) distributions for argon arc. The experimental results are from Nestor [23]. Arc length 2.0 mm Arc current 100 A 160 A 200 A 100 A 5.0 mm 160 A 200 A Q a; max (w/mm2) Ja; max (A/mm2) umax (m/s) T max (K) P (Pa) V arc (V) 91.5 9.1 154.2 17,161 355.7 16.2 172.5 16.7 266.9 20,541 692.9 16.7 202.5 19.5 310.6 22,118 917.0 17.1 29 2.8 193.0 18,024 416.3 18.8 89.5 8.3 396 22,338 824.2 20.4 128 11.7 505.5 24,316 1085.8 21.2 Fig. 7. Effect of arc length on the anodic heat flux with welding current I = 200 A for nitrogen arc. S. Lu et al. / Computational Materials Science 45 (2009) 327–335 333 Fig. 8. Effect of arc length on the anodic current density with welding current I = 200 A for nitrogen arc. Fig. 11. Effect of arc length on the shear stress with welding current I = 200 A for nitrogen arc. Fig. 9. Effect of welding current on the anodic heat flux at arc length L = 5.0 mm for nitrogen arc. Fig. 12. Comparison of axial velocity between argon and nitrogen arc under different welding current. Fig. 10. Effect of welding current on the anodic current density at arc length L = 5.0 mm for nitrogen arc. Fig. 13. Comparison of the anodic heat flux between argon and nitrogen arc at arc length L = 5.0 mm and welding current I = 200 A. 334 S. Lu et al. / Computational Materials Science 45 (2009) 327–335 increases and the welding current maintains unchanged, the maximum of heat flux and current density at the anode decreases. The effect of different levels of welding current (100, 160 and 200 A) on the anode heat flux and current density distribution for a 5.0 mm long nitrogen arc is shown in Figs. 9 and 10, respectively. The maximum and the distribution radius of the heat flux and current density at the anode increase with the increasing welding current. The main reason is that the arc power increases with increasing welding current, so that the arc plasma temperature, the gas electric conductivity in the arc column and the conductive cross-sectional radius increase too. The increase of the arc power and the arc cross-sectional radius results in the increase of the distribution radius and the maximum of the heat flux and current density at the anode. The shear stress generated by the motion of the plasma past the anode surface results in a transfer of momentum from the plasma to the anode. For solid surfaces this is unimportant but for a weld pool the shear stress is one of the main driving forces affecting the fluid flow, heat transfer and hence, the weld shape. Fig. 11 shows the radial variation of the anode shear stress for nitrogen arc at 200 A for three different arc lengths. As the radial distance increases, the shear stress increases firstly and then decreases. In addition, at shorter arc length of 2.0 mm, the maximum shear stress becomes smaller. When the arc length is shorter, the gas could not be accelerated by the electromagnetic force to high velocity. Accordingly, the gas velocity on the anode surface is small and it results in smaller shear stress. The higher the shear stress on pool surface is, the stronger the outward convection on liquid pool occurs. And the heat flux is easily transferred from the pool center to the edge making the weld pool wide and shadow. Therefore, arc length is one of the important parameters controlling the weld pool shape. Fig. 14. Comparison of the anodic current density between the argon and nitrogen arc at arc length L = 5.0 mm and welding current I = 200 A. 3.3. Comparisons of nitrogen and argon arc The axial distribution of plasma velocity of argon and nitrogen arc at 200 A is shown in Fig. 12. The predicted maximum velocities of the axial flow of plasma range, for pure argon, from 106.4 m/s at 100 A to 243.9 m/s at 200 A. For the pure nitrogen arc, these values increase due to the higher magnetic pinch pressure of the more constricted arc to be 193.0 m/s at 100 A and 505.5 m/s at 200 A. It is clearly shown that the axial velocity of the nitrogen arc plasma is much larger than that of the argon arc plasma. For the predicted electric potential difference, the analogous calculated results can be obtained. The electric potential difference is from 13.2 V at 100 A to 15.8 V at 200 A for pure argon arc, and 15.8 V at 100 A and 21.2 V at 200 A for pure nitrogen arc. Figs. 13 and 14 show the radial distributions of heat flux and current density at the anode surface for 200 A arcs in argon and nitrogen, respectively. The results show important information about pure and initial properties of arcs in argon and nitrogen as a heat source for the welding, and a tendency for type of shielding gas to change the current density and heat flux distribution. The on-axis current density and heat flux for the nitrogen arc is much higher than that of the argon arc. In addition, the distribution radius of the current density on the anode surface for nitrogen arc is smaller than that for argon arc. That means the nitrogen arc constricts more compared with the argon arc. Fig. 15 shows the comparison of calculated temperature contours of argon and nitrogen arc at 200 A with a gap between the cathode and the workpiece of 5.0 mm. The dashed line and the solid line represent the arc temperature contours for argon and nitrogen, respectively. It is shown that the nitrogen arc constricts obviously, in contrast to the argon arc. The maximum temperature near the cathode tip increases more than 24000 K and high-temperature region elongates toward the anode due to the active Joule heating. Fig. 15. Comparison of temperature contours between argon and nitrogen arc at arc length L = 5.0 mm and welding current I = 200 A. Physical properties of argon and nitrogen have been investigated by Boulos et al. [19] including the specific heat, thermal conductivity and electrical conductivity. The most important characteristic of nitrogen is its high specific heat and its high thermal conductivity at lower temperatures as shown in Figs. 2b and d. For nitrogen GTA, as shown in Fig. 13, the peak heat flux on the anode surface reaches 1.3 108 W/m2, which is approximately two times higher than that of argon GTA, mainly due to the current constriction. The higher specific heat of nitrogen than that of argon will suppress the expansion of the high-temperature region in the arc plasma, and hence, constriction lifts the on-axis plasma temperature, reduces the diameter of the current channel and leads to the current constriction. The resulting increase in arc current density (for constant arc current) will increase the electromagnetic force that is the driving force of the fluid flow of the arc plasma. Also the increasing electromagnetic force should result in the increase of the arc plasma velocity. On the other hand, the increased flow velocity prompts the energy loss in the fringe of the arc plasma, and hence, the constriction of the plasma raises the arc voltage. As a results, the peak heat flux onto the anode surface increases. High heat fluxes by constrict nitrogen arc will directly increase the weld pool volume S. Lu et al. / Computational Materials Science 45 (2009) 327–335 and contribute to higher productivity in the GTAW applications. Nitrogen is another prospective shielding gas for arc welding. 4. Conclusions The following conclusions could be summarized: (1) A two-dimensional axisymmetric numerical model from McKelliget et al. [3] was adopted by the commercial model FLUENT to study the nitrogen arc plasma’s characteristics, especially, the effects of the heat flux, current density and gas shear stress on the anode surface under different welding current and arc length. (2) The calculated temperature distribution in the arc plasma, the calculated distribution of current density and heat flux at the anode agree well with existing experimental data in literature [2,14,15,23] for both argon-shielded arc and nitrogen-shielded arc. (3) A gas with high specific heat such as nitrogen has the ability to constrict arc plasma. The constriction lifts the on-axis plasma temperature, thereby localizing the arc current path to the arc axis area. The resulting increase in arc current density (for constant arc current) will increase the electromagnetic force and the arc plasma velocity. On the other hand, the increased flow velocity prompts the energy loss in the fringe of the arc plasma, and hence, the constriction of the plasma raises the arc voltage. As a results, the peak heat flux and current density onto the anode surface increase. (4) In contrast to the argon arc, the nitrogen arc is more constrict due to the high specific heat and thermal conductivity. The high heat fluxes by constrict nitrogen arc will directly enlarge the weld pool volume and the weld productivity for GTAW process. 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