Phys Educ. 20 1985. Prlnted In Northern Ireland. Electromotive force A C Rose-lnnes Students, when dealing with electric circuits, often have difficulty in understanding the distinction betweenpotential difference (PD) andelectromotive force (EMF). Yet it is important to understand this distinction, which occurs in several situations: the potential difference at the terminals of a battery may be less than its EMF-Kirchhoff‘s second law tells us that around any closed circuit the sum of the EMFS (a) equals the sum of the PDS ( V ) : but if we cannot distinguish between PDS and EMFS, how do we know on which side of the equation to put any particularvoltage?Forexample, is the voltage across an inductor a PD or an EMF? In my experience, any difficulty usually arises from misunderstanding a of the nature of electromotive force rather than a failure to understand the nature of potential difference. EMF and the ‘electropump’ The potential difference between two points is defined as the work which must be done to transfer unit charge from one point to the other. Potential difference is the result of the electrostatic attraction and repulsion which charges exert on each other. Alistair Christopher Rose-Innes is Professor of Physics andElectrical Engineering, University of Manchester Institute of Science and Technology. His M A (Physics) and D Phil were obtained at Oxford and his DSc from Manchester University. He was previously a Principle Scientific Officer in the Royal Naval Scientific Service and his researchinterests include low-temperature techniques and solid-state physics, especially superconductivity and contact electrification. He has written three books and numerous articles in scientifc journals on these subjects. 0031-9120/85/060272+035’2.25 0 1985 The Institute of Physlcs a A B c D b A’ B’ C’ D’ Figure 1 Analogy between a fluid-flow and b electric current The distinction between PD and EMF in a circuit is probably best explained by looking at an analogous fluid circuit. Consider the sequence of water-filled pipes shown in figure la: if the pressureat A is greaterthan the pressure at D, water willflow through from A to D. Conversely, a flowof water forced through from A to D will create pressure drops across each pipe, the pressure on the right hand side of each pipe becoming less than that on the left handside. The electrical equivalent is shown in figure lb: potential is analogous t o pressure and electric current to fluid flow. So, if the potential at A’ is greater than the potential at D’, current flows from A’ to D’ and potential a difference will be set up across each resistor. How do we, however, keep the current flowing through the resistors? To keep the current flowing we must maintain a potential difference V , - VD across the resistor chain. Let us return to the fluid analogue. To keepthe fluidflowingwe needa pump (figure 2a). What does a pump do? A pump is a device which uses some form of energy to create apressure difference between its inletand outlet. For example, a pump may use the energy from an electric motor or the kinetic energy of the wind. The analogouselectric circuit is shown in figure 2b; current through the resistors is maintained by a battery which maintains a potential difference between its positive and negative terminals. We see that a battery is an ‘electropump’ which uses the energy of a chemical reaction to maintain the potential difference between its terminals. Thereare, of course, many kinds of electropump: the dynamo which uses the rotational kinetic energy of a motor to maintain the potential difference between its terminals, the photovoltaic cell (solar battery) which uses the energy of light etc, etc (Kip 1962, Harnwell 1949). Electromotive force is a potential difference which is produced by the conversion of other f o r m ofenergy (kinetic energy, light energy etc). Of course, virtually all electropumps have an internal resistance, r say, so when they are delivering current, I , the PD, V , betweentheir output terminals will be less than the EMF 8 by the potential drop produced across the internal resistance by the current I, V = 8 - Ir. Note that in a circuit a potential difference only appears across a component if a current is flowing through it. Thus in figure 2b there will only be a voltage drop across the resistors if the switch S is closed, but an electropump produces an EMF whether or not current is passing through it. Note also that where there is a potential difference, the direction of the current isalways from the higher potential to the lower potential, butcurrent may flow either way with respect to an EMF. In figure 3 thecurrent flows through the two batteries in opposite directions relative to their EMFS. g* Figure 3 Direction of current [with respect to EMFS g R L l An example In Kirchhoff's equation (1) we put all the EMFS on one side and the PDS on the other. It is usually easy to see which are EMFS and which are PDS but there are cases where it is not completely obvious. A careful application of the concepts of EMF and PD as given above will always resolve the problem. Consider,for example, a circuit containing an inductor, as shown in figure 4. If we want to know what current flows round this circuit at time t after the switch has closed we can apply Kirchhoff's law. 8 is clearly the EMF of the battery and goes on one side of the equation and the voltage drop IR across R is clearly a PD and goes on the other. But what about the voltage across the inductor? Figure 2 Electric battery b as an analogue of a fluid Pump a L 1 Pump Pump I % S Figure 4 Circuit containing inductance The voltage across an inductor is generated by the changing magnetic flux threading the coils; in other words, an inductance can be considered as an electropump using the energy of a magnetic field to create apotentialdifference. We may, therefore, regard the voltage across it as an EMF and put it on the left side of equation (1). On the other hand, the voltage across an inductor is duetothe current through it,t so this looks like a PD and should go on the right handside of equation (1). Is there a paradox?No; we can treatthe voltage across an inductor as either an EMF or a PD. If, first, we consider the inductor as an electropump, theEMF it generates is - L dlldt, so we would write Kirchhoff's equation for the circuit in figure 4 as: 8 + (-L dlldt) = RI. (2) On the other hand, we can consider the inductor as a passive circuit element across which a current produces a PD equal to LdIldt.Kirchhoff's equation for the circuit of figure 4 can therefore be written: 8 = R I -k L dIldt. It can be seen that this equation is exactly equivalent toequation(2).In practice, in circuit problems it is usually more convenient to treat the voltage across an inductance as a PD equal to i The magnitude of the voltage is proportional to the rate of change of the current. 273 Phys Educ. 20 1985Printed In Northern Ireland LdIldt, though it can be seen that treating it as an EMF equal to -LdI/dt is equally valid. No problem arises, of course, if the nature of both PD and EMF are fully understood. T o summarise; EMF is produced by an electropump, a device which uses non-electrical energy to maintain a potential difference between its terminals. The EMF is produced whether or not the ‘pump‘ is delivering current. If this concept of an electropump is firmly understood, there should be no difficulty in understanding the natureof EMF and its relationship to PD. References Kip A F 1962 Electricity and Magnetism (New York: McGraw-Hill) Harnwell G P 1949 Principles of Electricity and Electromagnetism (New York: McGraw-Hill) The refractive index of thin solid films S K J AI-Ani and J Beynon A fundamentalopticsexperiment in theschool/ undergraduate physics laboratory is theinvestigation of the dispersion of visible light using a prism spectrometer. The refractive index, n, of the prism material can be calculated for various wavelengths with the help of the familiar relation n = sin [ ( A Computers in physics teaching The Computational Physics and Education Groups of The Institute of Physics are planning a series of joint meetings on topics of common interest to both Groups. Thefirst meeting, on ‘The use of computers in mainstream physics teaching’, will be held at the Universityof Essex on Thursday 9 January 1986 and will be a full day meeting (10.30-17.00) organised jointly by Dr D Tilley (Education Group) and DrH Liddell (Computational Physics Group). The meetingwill consist of a mixture of invited and contributed talks, poster presentations and demonstrations by manufacturers, publishers and individuals who have developed interesting software in this area. The provisional programme includes the following speakers and topics: ‘The Computer Board initiativeon facilities for teaching’ by R J Elliott (Oxford) or J Forty (Warwick); ‘Computer assisted texts’by R A Harding (Cambridge); ‘Physics students and computers’ by G Toombs (Nottingham); ‘Microcomputer perturbation theory’by J Killingbeck (Hull); and ‘Software for undergraduatephysics’ by A D Boardman (Salford). Further details can be obtained from the Meetings Officer, The Instituteof Physics, 47 Belgrave Square, London SWlX 8QX (tel.01-235 6111). 0031-9120/85/060274~04$2.250 1985 The lnstltute of Physlcs + Dmi,)/2]/sin( A / 2 ) , (1) where A is therefractingangle of theprismand Dminis theangle of minimum deviation. Figure 1 shows the variation of n with wavelength obtained with an ordinary ‘student’ optical spectrometer and a sodium discharge lamp as source. With reasonable care it is possible to verify that n and A satisfy a simplifiedCauchy relationof the form n=L + MA-2, (2) where L and M are constants characteristic of the prism material.Equation ( 2 ) is alsoplotted in Salwan Al-Ani, a graduate of Baghdad Universim, gainedan MPhil from the University of Surreyin 1981and a doctorate from Brunel University in 1984. His research interests are in theoretical physics-the kinetic theory of gases and amorphous thin film properties-and he is the author of various articles in this field.He now lectures at Baghdad University. John Beynon is a lecturer in physics and co-director of the physics and electronics joint honours course at Brunel University. He gained a doctorate from the University of Wales, was a CEGB Research Fellow at University College, Swansea and has worked with The Signals Research and Development Establishment. His main research interests are thin films and vacuum technology andhis publications include Conduction of Electricity in Gases (1971 London: Harrap) and Physics andChance (1974 London: Hutchinson Educational).