Electrical conductivity measurement of the atmosphere using the Gerdien voltage decay method in high altitude flight Katherine O. Blackburn and Joseph T. D. Tran Abstract Atmospheric electrical conductivity research of the atmosphere has not had many scientific findings since the 1980’s when Gerdien first used the voltage decay mode to determine electrical conductivity. This paper explores the use of Gerdien’s 1980 concept of using two cylindrical electrodes to measure electrical conductance. The condensers were created from dimensions specified by the equations derived by K.L. Aplin et. al. cited. A unique feature of these condensers is the specially designed caps, which promote laminar flow through the condensers, while acting to secure the condensers in a fixed position. Previous attempts at measuring conductivity have been limited to around 30,000 ft but because high altitude flight is now possible through the LaACES program, the electrical conductivity measurements can be made for altitudes up to 100,000 ft. I. Background Introduction to the Program The Louisiana Aerospace Catalyst Experiences for Students (LaACES) is an intensive, one-year program that allows students to design, implement, construct, and test a payload that can be used to extract scientific data corresponding to increasing altitude, pressure, and/or temperature. The student payloads are attached to a 3 kilogram sounding balloon by use of two flight strings that will carry the payloads to about 100,000 feet. Data is recovered and analyses follows. The goal of this project was to successfully design, build, launch and recover a payload to investigate the levels of atmospheric electrical conductivity as a function of altitude while surviving the challenges of extreme high altitude flight. Though a parachute failure caused an impact condition greater than originally tested, the launch, which took place in Lubbock, TX on May 26, 2010, was successful. Applications of Atmospheric Conductivity Atmospheric conductivity is a complex variable part of the atmosphere with many contributing factors. It plays a significant role in many fields including Meteorology, Environmental Science, and Radiology. Measurement of air conductivity near ground levels is used to determine the pollution level of air (1). Variations in the conductivity of the atmosphere can also be used to detect unnatural or increased radiation in an area due to the effects of ionic radiation in the atmosphere. The formation of thunderstorms and the coalescence process of precipitation are also affected by conductivity. Increased knowledge of this intriguing property of atmosphere will lead to greater predictive abilities in meteorology (3). Generally, in any atmospheric conductivity measurement, only the smallest, fastest particles contribute greatly to the ionization in the atmosphere as they have the greatest concentration and average mobility. These ion clusters have radii on the order of 0.5 nm (nanometers). Many factors can increase or decrease the rate of production of these small ions, affecting conductivity, including wind speed, pressure, and humidity, which all affect the concentrations of these ions as well as their mobility (2). While the specifics of atmospheric conductivity are debated, certain variables are classically recognized as major contributors such as the factors above, cosmic ray and solar activity, and atmospheric levels of aerosols. Cosmic rays entering the upper atmosphere cause the majority of electrical conductivity in the atmosphere. At lower altitudes, the cosmic rays have spent their energy in ionizing the atmosphere and less ionization occurs. At higher altitudes, cosmic rays have not yet lost their energy and greatly ionize the atmosphere. As the energy of cosmic rays is spent in the upper atmosphere, less conductivity is seen. Finally, radiation from the earth is also a major influence near surface level, though not as potent as cosmic radiation, and it releases as many as 105 ions per 4 MeV (mega electron volt) alpha particles (5). Conductivity ions in the atmosphere, generally of a mobility of about 10-4 m2v-1s-1, are formed from cosmic rays when these rays energize a particle and strip electrons from it. These positive and negative ions now combine with others and eventually form numerous positive and negative ions. humidity levels are close to 60% or higher. In Palestine, TX (the original launch site) and in Lubbock, TX (final launch site) relative humidity was expected to be less. Passing through a cloud layer that is fully saturated with water vapors would potentially have much higher levels, causing the Gerdien condenser to temporarily malfunction. II. Methods Equation 1 gives the current (i) achieved in the Gerdien condenser where V is voltage difference between the outer and inner cylinder, l is the length of the condenser, σ is the conductivity, b the inner radius, and a the outer radius. General Background A Gerdien capacitor consists of two coaxial cylinders. A constant positive voltage is applied to the outermost cylinder, repelling positive ions toward the center and increasing the voltage on the innermost cylinder. This voltage curve determines positive conductivity. Measuring negativity conductivity involves applying a negative voltage to the outermost cylinder. This measurement mode, which our team will utilize, is termed voltage decay mode. It is also possible to directly measure the current. In order to effectively measure conductivity, the ion stream must be parallel to the axis of the cylinders. In addition, the Gerdien capacitor can only measure ions with a mobility greater than the critical mobility of the capacitor. Ions encountered in the atmosphere are expected to be in the range of 2.5 – 3 fS/m. Effects of Humidity Scientists have observed that humidity affects the conductivity—in one case, Moore and Vonnegut observed that the conductivity of dry air as twice that of air over boiling water. Harrison, another scientist, used mass spectrometry data to compute the relative concentrations of different hydrations of the atmospheric ion H+ (2). He concluded that at 300K, the mean mobility is expected to decrease from 2.05(10 -4) at a relative humidity of 20% to 1.74(10-4) at 100% (17% drop). In the lower atmosphere from 0 to 30,000 ft, relative humidity is a global average of 10-20%. However these values can vary greatly per location; in Baton Rouge, Equation 1 This equation is derived under the assumption of uniform mobility, laminar flow and Gerdien capacitor of infinite length. The same applies for Equation 2 in which the critical mobility, μc, or the minimum ion mobility that can be measured, can be calculated given µ (wind speed). The wind speed will be calculated using the global positioning system coordinates and known values of altitude. Equation 2 Measuring wind flow is thus important to determine the accuracy of a measurement and the minimum critical mobility (2). Voltage Decay Mode In voltage decay mode, voltage is sampled about 1-2 Hz for 5-20 s. After, the inner cylinder is reset to its initial voltage (13). At this time charge injection can occur from the atmosphere to produce a non-fixed inner cylinder voltage. In order to get the value of dV c/dt, the voltage decay is fit with an exponential curve. The natural log is then taken of this curve for a better linear fit and the derivative of this result is the value dVc/dt. This is used in the following equation to calculate conductivity with the constant 0 = 8.85x10-12 F/m and the bias voltage between the inner electrodes (the voltage on the outer electrode minus the voltage on the inner). Equation 3 This method does not require the Gerdien capacitance. Alternatively, Equation 5 below in conjunction with Equation 6 is used to determine air conductivity where Cg is the Gerdien capacitance, Cm is the measurement system capacitance (usually assumed to be 0), Vb is the voltage across the outer electrode of the Gerdien capacitor and Vc is the voltage across the inner electrode. Equation 5 The usage of actual Gerdien capacitance instead of the theoretical value reduces somewhat the error associated with the infinite length assumption. Both methods mentioned assume a uniform ion mobility spectrum, which is unlikely at lower altitudes due to large particles and other contaminants. As such, observed voltage decays curves are not exponential at lower altitudes; however at higher altitudes, an ideal decay curve has been observed. It is possible to derive an ion mobility spectrum from the observed voltage decay given the assumption that ion mobilities are similar in concentration and that the wind speed is known. System Interface Equation 4 All electrical components will be contained inside the payload box. The BalloonSat board containing the Basic Stamp Microprocessor, the Real Time Clock, the Figure 1 - Figure showing major functional groups and interfaces EEPROM Memory Storage, and the Analog to Digital Converter is the main component and the control subsystem. Figure 1 shows the system design of the components. The Analog to Digital Converter is interfaced to the Gerdien condenser circuit through two analog data lines (one for each condenser) on the BalloonSat. The control and sensor systems are supported by two separate power supplies, the first is a set of 1.5 V batteries in a 15 V configuration, which supplies 15 V of power to the BalloonSat and 12 V through a voltage regulator to the Gerdien circuit. The second power supply consists of 2 sets of 3 V batteries in a 30 V configuration. These provide the positive and negative 30 V bias required for the outer electrode of the Gerdien condensers. Gerdien Condenser The circuit used to control the Gerdien condenser, shown in Figure 2, consists of three parts: the input circuitry, the signal conditioning, and the switch, which will reset the voltage across the capacitor. The purpose of the input circuitry is to act as a low leakage op-amp buffer. It consists of a low leakage opamp, the LMC6042, along with two jFETs which allow the switch to reset the capacitor’s voltage. The op-amp, with an offset voltage of 2 mV, will cause a leakage current of less than 5 fA for 40 % and greater than 20 fA for 50 % percent of a random assortment of jFETs. A current gate leakage of less than 8 fA will result in less than 10 % error contribution (7). Signal conditioning is achieved via a voltage divider, which reduces the voltage output of the input circuitry from 0-12 V. The voltage is then fed through a high pass filter, another op-amp buffer, and then to the ADC. The switch (4053BE MOSFET) has two modes: measure and reset. In reset mode, it applies approximately 10 V to the inner cylinder for measuring negative conductivity and 3 V for measuring positive conductivity. This is possible via the use of 2 jFETs, which act as diodes and also as protection against high voltage. In measure mode, the voltage on the inner electrode is allowed to decay as ions collect in the Figure 2 – Flight Schematic Gerdien condenser. The outermost cylinder for measuring positive and negative conductivity will always be charged to ±30 V. As the voltage on the inner cylinders decays, the cylinder for measuring negative conductivity will change from 10 V to nearly 0 V while the cylinder measuring positive conductivity will change from 3V to nearly 12 V (it will jump from around 10 V to 12 V when the common mode range of the LMC6042 opamp is exceeded, however the op-amp will recover). The outermost cylinder’s voltage will never be transferred through the LMC 6042 op amp, thus this voltage does not otherwise exceed its common mode range In order to minimize interference, the connection between pin 5 of the op-amp input buffer and the inner electrode was made as short as possible. Therefore, the op-amp is located as close to the inner electrode as possible. This particular portion of the circuit is highly sensitive to stray voltages and currents, so the resistors connected between the inner electrode and pin 3 and 5 of the op amp are air wired (connected directly to each other and not to the circuit board) to each. Pins 4 and 15 of the 4053BE MOSFET are also air wired to the jFETs and these are wired to the resistor mentioned previously. The variable resistor in the circuit for each condenser controls how much of the 12 V supply voltage shows up on the inner electrode and will be set (a) to supply +11V to one electrode and +3V to the other. Two 0.1 µF capacitors are soldered from the input voltage to ground as a filter near pin 8 of the LMC6042 op-amp and pin 16 of the 4053BE MOSFET switch to minimize signal noise. The Gerdien condenser does not need to be calibrated, the equations presented above in the Technical Background are used, along with the measured capacitance of each cylinder, to calculate the ions encountered based on the wind-speed of the air flowing through it and the voltage decay seen on the inner electrode (2). Figure 3 shows the schematic for the Gerdien condenser interface. In this interface the output voltage to the opamp will be a minimum of 0 V and a maximum of 3 V because of the resistor networks made up by resistors 2, 3, 6, and 7. Thus, the output matches the base and span of the ADC, which is 0 V – 3V and needs no further signal conditioning. Mechanical Specification During the flight, there are many extreme variable conditions that can potentially destroy the payload or render any data collected unusable if the mechanical design and specifications are not correctly identified. Temperatures can reach well down to-70°C while pressures can reach almost vacuum conditions. In addition to the physical environment, the payload (b) Figure 3- (a) External structure (b )Gerdien condenser with caps. should be as light as possible, be structurally sound, and be within the mechanical specifications such as having two holes spaced 17 cm apart. The payload should also be able to withstand an impact of about 20 feet per second. Taking all of these considerations into account, a semi-hexagonal box with weight-reducing grooves was designed to fit all the external and physical requirements as shown in the Figure 5a. An important structure that is considered to be an external component is the Gerdien condenser shown in Figure 5b. The condenser’s unique features are its two snap-on cap designed and made using the Dimension Elite 3D Printer. There are two of these condenser assemblies that are placed in the open compartment of the payload box. The condensers were glued to the divider and were protected using pieces of mesh fabric to cover the top and bottom openings of the box; this acts as a prevention method incase the condensers come loose. The internal structure, which is in the enclosed compartment seen in Figure 5a, consists of the BalloonSat board, the Gerdien circuit board, the battery packs and supporting circuitry. System Testing A series of three tests were required in order to ensure the payload was flight ready. The first test was an impact test, which mimics the harsh flight landing condition. This test was also done first because it was most likely to have problems and will allow time to make design changes. The second test was the thermal test; the flight was mimicked using a combination of a refrigerated compartment, a freezer, and dry ice. The third test performed was the pressure test with the use of a pressure chamber. The flight profile was mimicked using a graph of the expected pressure drop from a previous flight. III. Results The payload box was connected to a high-altitude balloon, which carries the payload to 100,000 feet in the atmosphere at an ascent rate of roughly 1000 ft/min. This target ascent rate was used to calculate the dimensions of the two Gerdien condensers according to the critical mobility of the ions measured. From Launch altitude until around 40,000 ft, the payload ascended at a rate of approximately 1333.33 ft/min and then from 40,000 until 100,000 ft, the ascent rate was approximately 800 ft/min. These rates are close to the target rate of 1000 ft/min and thus impacted data Positive conductivity 3403 4807 7606 10532 13395 16285 19393 23006 26884 31034 35103 39357 42470 44284 46062 48436 50729 53147 55265 57558 59792 62384 64584 66757 69297 71496 73787 76116 78619 80785 83129 85270 87677 89563 91992 94202 96437 98538 68803 43954 27734 14909 5848 Conductivity (S/m) Conductivity vs. Altitude -5E-15 Altitude (ft) Figure 4 – Graph of Conductivity vs. Altitude collection only marginally. At 100,000 ft, the payload string connecting the payloads to the balloon was cut, allowing the payload to fall back to earth, with a parachute attached. This occurred during flight at about 9:30 and the payload fell with a descent rate of about 5,249 ft/min due to incorrect parachute operation. Several important observations must be made to interpret Figure 5 below. First, as noted previously, the ascent rate of the payload was roughly 1333.33 ft/min until 40,000 ft. After this point, the data returns extremely low values, orders of magnitude lower than the expected value in fS/m. From this, it is assumed that a wind speed lower than that intended (1000 ft/min as designed) is insufficient for good data. When the balloon burst at around 98000 ft, conductivity is again measured, indicating the sensor is too sensitive for a slow wind speed. However, it can also be noted that as the descent rate increased (reaching 11000 ft/min at times) data was again skewed. Further investigation into the effects of wind speed on the Gerdien condenser is absolutely vital for continuation of this project and will be pursued. In this graph, only positive conductivity measurements have been graphed. This is because the condenser measuring negative conductivity did not function properly during flight. The reset value of the negative Gerdien condenser was intended to be 10V and the condenser should have decayed to 0V, however the average reset during flight was only 2.89V though it did decay to 1.35V on average. Therefore, this data is considered invalidated. The average reset voltage on the other condenser was intended to be 3V and it should have increased to 12V as positive ions were attracted to the inner electrode. This condenser’s reset value was an average of 3.67V, a perfectly acceptable number. The decay value however is imperfect on this condenser, giving an average value of 4.55V. It was observed to properly decay at some points, from 3V to 12V, however for the period in flight from 40,000 feet until descent the condensers both worked incorrectly. IV. Discussion Extremely low conductivity values were expected to some extent, because of the nature of the device. As the altitude increases, the atmosphere thins and no decays were observed on the devices. This also corresponded with the slower descent rate of 800 ft/min and further studies should be done to investigate this problem. Interestingly, the condensers did not behave this way during system tests, during which no wind passed through the condensers, again bringing up questions about the true effect of wind speed. In system testing, during the cold test both condensers ran properly, decaying and resetting consistently. In the pressure test, only one condenser worked correctly (decaying and resetting as intended), however the one that did not function has worked intermittently throughout the entire development process. Due to the sensitivity of this circuitry, a first attempt at this project was exceedingly difficult. As mentioned previously, precaution had to be taken to keep the condensers clean (stray fingerprints can affect the circuit electrically) and keep connections between the condensers and the circuit board as short as possible. The connection to the condensers even had to be switched at one point, effectively changing which condenser measured positive and negative conductivity. After this swap, the condensers worked properly even though one had not before. For this and other reasons, this project should be attempted again and better data can certainly be achieved with several minor improvements. Ultimately however, this sensor may not be ideal for measuring conductivity in a high-altitude situation. Few previous studies have conducted balloon flights and even fewer have reached the heights this flight did. The limitation on the Gerdien condensers comes from the effect of wind speed on the accuracy of the measurements, which is not completely understood. Eventually an entire new sensor may need to be designed that has no dependency on wind speed, which can quite possibly be done, in order to measure regardless of a slow flight or low atmosphere at high altitudes. However, several minor changes can certainly be made to this payload in order to get better data and more clear conclusions on the accuracy of this measuring device. One change, which should have been incorporated into this payload, is two voltage regulators on the 30V supplies to the condensers. All batteries experience a decrease in voltage as temperature decreases, changing the bias voltage between the condensers. Since this payload had no method of measuring the voltage on the condensers, they were assumed to be 30V and -30V because little de-rating should have occurred due to very small current draw on the batteries. Another minor issue is the batteries; due to weight concerns AAA batteries should provide adequate mAh for this flight. Again, the dependence of wind speed must be determined in order to achieve good results. They should be tested for results in different configurations relative to wind flow, i.e. parallel to wind flow or perpendicular, etc. as well as tested in different areas for different conductivities. Wind flow should also be incorporated into system testing if necessary. Finally, the issue of the reset voltage must be addressed. Both condensers consistently reset in all system tests, however during flight they did not. One of the condensers also intermittently and should be addressed. Procedures for working with the condensers are advisable in order to prevent stray electric charges or residue from affecting them and the sensitive circuitry near them. V. References 1. Bering, E.A., Few, A.A., & Benbrook, J.R. (1998). The Global electric circuit. Journal of Physics Today, 51(10), 24-30. 2. Aplin, K.L. (2000). Instrumentation for atmospheric ion measurements. University of Reading Department of Meteorology, 1-274. 3. Scott, J.P., & Evans, W.H. (1969). 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