INTERCONNECTION RELIABILITY OF INTERPOSER AND REBALLING OPTIONS FOR BALL GRID ARRAY BACKWARD COMPATIBILITY Richard Coyle1, Michael Meilunas 2, Richard Popowich1, Martin Anselm2, Peter Read1, Mike Oswald3, and Debra Fleming1 1 Alcatel-Lucent Murray Hill, NJ, USA 2 Universal Instruments, Inc. Conklin, NY, USA 3 Interconnect Systems, Inc. Camarillo, CA, USA richard.coyle@alcatel-lucent.com; anselm@uic.com; mike.oswald@isipkg.com ABSTRACT High reliability electronic equipment producers that continue to manufacture and support tin-lead (SnPb) electronic products are faced with an increasing number of availability issues with SnPb ball grid array (BGA) components. These supply chain constraints are driving development of backward compatible assembly solutions, which requires integrating a Pb-free BGA component into a printed circuit board assembly (PCBA) being manufactured with SnPb solder processing. This paper addresses two backward compatible assembly solutions: 1) SnPb assembly using an interposer card to mount the Pb-free BGA and 2) SnPb assembly using a SnPb component created by reballing the original Pb-free component. The primary objective of the study was to determine if the interposer or reballing assembly processes degraded the board level attachment reliability of a 676 I/O plastic ball grid array. The intermetallic solder attachments and microstructures were characterized before and after board level assembly using optical metallography and scanning electron microscopy. The reliability was characterized using a 0 to 100 C accelerated temperature cycle with 10 minute ramp and 10 minute dwell times. The reliability of the backward compatible assembly solutions is discussed relative to that of the basic SnPb and Pb-free assembly processes. supply chain that is rapidly converting to Pb-free offerings and thus has a decreasing motivation to continue producing SnPb product for these low-volume end users [2]. Until recently these supply chain constraints were limited to high volume, small ball grid array (BGA) packages components such as memory devices. Now there is a growing concern surrounding availability of larger SnPb BGA components. There are product and performance constraints that can preclude complete Pb-free conversion and consequently, these component availability issues can force companies to use Pb-free BGAs with the SnPb solder assembly process. The requirement to integrate a Pb-free BGA into product that is assembled with a typical SnPb surface mount process is referred to as backward compatibility or back ward compatible manufacturing. The ability to address backward compatibility effectively enables a viable alternative manufacturing path when complete product conversion to Pb-free manufacturing is not possible. There are three common options for addressing Pb-free BGA backward compatibility: 1) assembly with mixed alloy processing which requires soldering the Pb-free BGA directly with a SnPb soldering process, 2) assembly using an interposer card, and 3) basic SnPb assembly using a SnPb component created by reballing the original Pb-free component. Mixed alloy processing is the most prevalent BGA backward compatibility production option despite the fact that it is discouraged almost universally by equipment producers, contract manufacturers, and component suppliers. The technical issues associated with mixed alloy processing have been addressed in a significant number of studies [3-52] and those results have been reviewed and discussed in detail in previous publications [3, 48, 49, 50, 51]. Mixed alloy assembly is not drop-in replacement process and requires custom process development. Further, there has been on ongoing debate over the solder joint thermal fatigue reliability of BGA packages assembled with mixed processing. As the need for backward compatible assembly has grown, the interposer and reballing options Key words: Pb-free solder, backward compatibility, interposer assembly, reballing, thermal fatigue, accelerated temperature cycling INTRODUCTION Most high reliability electronic equipment producers continue to manufacture and support tin-lead (SnPb) electronic products despite the increasing trend for design and conversion to Pb-free manufacturing. These equipment suppliers can continue to use SnPb solder assembly and remain in compliance with the RoHS Directive (restriction on certain hazardous substances) by invoking the European Union Pb-in-solder exemption [1]. At the same time, companies are facing increased pressure from a component 894 have emerged as potential alternatives for BGA backward compatible assembly. finish is high temperature organic solderability preservative (OSP). Interposer assembly allows the manufacturer to maintain the continuity of SnPb assembly without altering the assembly profile established for the product board. From the assembly perspective, the BGA interposer subassembly is treated as a distinct SnPb component. Although there are logistical issues with interposer implementation, they can be overcome with adequate planning. However, the interposer subassembly introduces mechanical complexity and an additional level of solder attachments, which creates a concern for overall solder joint reliability. There appears to be no solder joint reliability data in the literature for interposers but there is at least one BGA connector study that showed that increased mechanical complexity could reduce the inherent fatigue life of a BGA [53]. There is one daisy chain net for each land pattern. Daisy chain nets from each of the components patterns are brought out to a card edge connector and soldered connections are used to monitor the resistances of the daisy chain nets during temperature cycling. BGA reballing processes have been used by the defense and aerospace industries in order to avoid Pb-free conversion [54]. However, commercial equipment suppliers generally have shunned BGA reballing due to the process uncertainties related to the overall reliability of the device, package, or solder interfaces and attachments. As a whole, component suppliers are concerned about the impact on IC device and package reliability caused by the additional number of thermal excursions required to remove the Pbfree balls and attach new SnPb balls. There is a minimal amount of data in the literature evaluating reballing [55-58] and the most complete study did not include completed results for attachment reliability of reballed BGA components [55]. The shortage of characterization and test data is indicative of the limited exposure of this process in practice. Figure 1: Top view of a populated printed circuit board. The primary test vehicle contains SnPb, reballed SnPb, and interposer components soldered with a SnPb reflow profile. The components for the SAC305 test cell were assembled on dedicated test boards using a Pb-free reflow profile. Table 1: The package attributes for the 676 I/O PBGA. Package Attribute Value Package Type PBGA I/O 676 Body Size 27 x 27 mm (1.06 x 1.06 in) Die Size 16.5 x 16.5 mm (0.650 x 0.65 in) Die Thickness 0.34 (13 mils) Ball Pitch 1.0 mm (40 mils) Ball Diameter 0.5 mm (20 mils) Solder Ball Alloy 63Sn37Pb Sn3.0Ag0.5Cu Substrate Pad Design Circular – Solder Mask Defined (SMD) Substrate Pad Solder Mask 0.45 mm (18 mils) Opening Diameter Substrate Pad Surface Finish Electrolytic Ni/Au Substrate Type BT, 2 metal layer Substrate Thickness 0.61 mm (24 mils) Package Thickness 1.73 mm (69 mils) This paper presents results from attachment quality and reliability evaluations of a 676 I/O PBGA assembled with interposers and reballed components. Test boards were assembled containing Pb-free components mounted on SnPb interposer cards, Pb-free components reballed with SnPb attachments, and virgin SnPb and Pb-free components as the baseline control samples. The basic objectives were to determine if the SnPb board level attachments were degraded by the interposer or by the reballing assembly processes or if Pb-free solder attachments were degraded by using an interposer card assembly. EXPERIMENTAL BGA Test Vehicle The top view of the populated printed circuit board test vehicle is shown in Figure 1 and the attributes of the ball grid array package are listed in Table 1. Interposer and Reballed BGA Test Vehicles A schematic representation of the interposer sub-assembly is shown in Figure 2 and the interposer attributes are provided in Table 2. The 2nd level attachments of the interposer card are eutectic SnPb balls with 0.4 mm diameter (16 mils) nonsolder mask defined (NSMD) pads on the underside of the card to enhance board level reliability. The Pb-free (SAC305) BGA was assembled onto the top side of the interposer card using a Pb-free solder paste and a Pb-free The test board has 8 layers with dimensions 222 mm x 140 mm x 2.36 mm (8.75 in. x 5.5 in. x 0.093 in.) and contains six identical BGA component footprints. The component sites have non-solder mask defined (NSMD) land patterns that are 0.35 mm (14 mils) in diameter and the board surface 895 reflow profile. In this study, the interposers were provided in JEDEC trays to enable surface mount assembly. The components and the test circuit boards were daisy chained to allow electrical continuity testing after surface mount assembly and in situ, continuous monitoring during thermal cycling. The resistance of each loop was independently monitored during the temperature cycle test. All assembled circuit boards were thermally cycled from 0 C to 100 C with a 10 minute ramp between temperature extremes. The dwell times were 10 minutes in accordance with the IPC-9701A industry test guidance [59]. The solder joints were monitored continuously during thermal cycling using an event detector set at a resistance limit of 1000 ohms. A spike of 1000 ohms for 0.2 microseconds followed by 9 additional events within 10% of the cycles to the initial event was flagged as a failure. The failure data are reported as characteristic life (typically the number of cycles to achieve 63.2% failure) and slope from a two-parameter Weibull analysis. The Pb-free BGA ball removal (“deballing”) was accomplished using a proprietary wave solder-type process. The process was engineered specifically for the 676 I/O BGA used in this study to minimize thermal exposure and avoid damage to the solder ball pads on the package. The SnPb balls were attached with a flux-only process in a nitrogen environment using a SnPb soldering profile in compliance with typical component manufacturer specifications. Following the reballing, all packages were subjected to 100% automated optical inspection (AOI) to document and confirm coplanarity and flatness. Microstructural Characterization and Failure Analysis The intermetallic solder attachments and bulk solder microstructures were characterized before and after board level assembly. Failure analysis was performed after temperature cycling to document the location of the failures and the failure mode. Microstructural characterization and failure analysis was done with optical microscopy and scanning electron microscopy (SEM). Phase identification and elemental analysis was accomplished using energy dispersive spectroscopy (EDS) and backscattered electron imaging (BEI). Optical metallography was the primary tool used to verify the failure mode. The SEM operating in the backscattered electron imaging (BEI) mode was used to differentiate phases. Figure 2: A schematic representation of the interposer subassembly. The interposer solution addresses backward compatibility by incorporating the Pb-free BAG into a subassembly that subsequently can be attached to main board with a SnPb soldering process. Table 2: 676 I/O PBGA interposer attributes. Interposer Attribute Value I/O 676 Ball Pitch 1.0 mm (40 mils) Ball Diameter 0.63 mm (25 mils) Solder Ball Alloy 63Sn37Pb Substrate Pad Design Circular – Non-Solder Mask Defined (NSMD) Substrate Pad Diameter 0.4 mm (16 mils) Substrate Pad Surface Finish Electrolytic Ni/Au Substrate Type High temperature FR-4 Substrate Thickness 0.4 mm (16 mils) RESULTS AND DISCUSSION Baseline Characterization – Interposer Card Assembly Low magnification metallographic cross sections of an interposer subassembly are shown in Figure 3 (compare to the drawing in Figure 2). Higher magnification images of the soldered interfaces and bulk solder of the PBGA and interposer are shown in Figures 4 and 5. These microstructures are typical of Pb-free and SnPb solder joints respectively. Surface Mount Assembly and Test Matrix The build matrix for the accelerated temperature cycling tests is shown in Table 3. An initial sample size of 18 component sites was used for all test cells except for the SAC305 baseline, which had a sample size of 24. Additional boards were populated to provide samples for baseline microstructural analysis. Table 3: The build matrix for the temperature cycling tests. 676 I/O PBGA Build Matrix Component Variation Sample Size SnPb as-received 18 SnPb reballed from SAC305 18 SAC305 as-received 24 SAC305 on SnPb interposer 18 Accelerated Temperature Cycling 896 Figure 3: An interposer subassembly in cross section with SAC305 BGA balls on the package and SnPb balls on the interposer. The interposer uses non-solder mask defined pads to enhance solder joint reliability. are attached. In both cases, the BGA pads are exposed directly to molten solder, which has the potential to create more severe damage than a simple thermal excursion. The Figure 6 shows a series of high magnification backscattered electron micrographs of the intermetallic compound (IMC) layers and the bulk solder microstructures for as-received and reballed SnPb (reballed from SAC305) ball grid arrays. The intermetallic layer is similar in both samples and nominally is 1µm thick, which is typical for the Ni3Sn4 intermetallic layer that forms on an electrolytic Ni/Au BGA pad. The highest magnification images (lower) reveal a slightly more uniform IMC layer in the reballed BGA, which is consistent with the additional reflow cycles during reballing. Note that this is evident only when viewed at the highest magnification, which originally was 10,000X. The bulk solder microstructure of the reballed BGA is slightly coarser (larger Sn-rich and Pb-rich regions) than the as-received BGA but this is a minor difference and is not considered a detriment to reliability. The reballing process does not appear to induce any substantial changes or anomalies in the soldered structure. Figure 4: Backscattered electron images of the solder interfaces and bulk solder microstructure of the SAC305 BGA assembled onto the interposer card. Figure 5: Backscattered electron images of the solder interfaces and bulk solder microstructure of the SnPb interposer card. Figure 6: A comparison of IMC layers and bulk solder microstructures for as-received and reballed SnPb BGA packages before surface mount assembly. Baseline Characterization – BGA and BGA Reballing A significant concern regarding reballed BGA package reliability is the effect of thermal cycles on the integrity of the solder ball attachment interface and BGA pad resulting from final ball attachment. Reballing involves two major additional thermal cycles above the melting point of the solder. The first cycle occurs above the melting point of the Pb-free solder to enable solder ball removal. The second occurs above the SnPb melting point as the new solder balls Accelerated Temperature Cycling Test Results The thermal cycling test results are summarized in Table 4 in the Weibull plots in Figure 7. The results show that the difference in characteristic lifetime for the as-received SnPb and the reballed SnPb is less than 5%, which is considered to be within experimental error. There also is no statistical 897 difference between two data sets at the 90% confidence level. Based on these results, it is reasonable to conclude that reballing causes no significant degradation of the thermal fatigue performance of the 676 I/O PBGA package. A comparison of the data for the as-received SAC305 and SAC305 assembled onto the interposer card shows that the SAC305 BGA fatigue life is degraded by approximately 10% with use of the interposer. A slight degradation associated with additional mechanical complexity is consistent qualitatively with the data published previously for BGA socket attachments [53]. Regardless, it should be noted that even with interposer assembly, the SAC305 reliability remains significantly better than the SnPb reliability. edge of the BGA package. Thermal fatigue failures were detected in the first full row of solder balls under the die of the SAC305 BGA, which is a common location for fatigue failures in full array BGA packages. There are two significant findings here: 1) the fatigue failures occur exclusively in the SAC305 BGA, and 2) there is no detectable fatigue damage in the SnPb interposer balls. The former result might seem surprising considering that SAC305 typically outperforms SnPb in short-dwell time BGA tests [60]. However, the SnPb interposer is designed with NSMD pads on both sides of the solder joint specifically to improve attachment reliability. The better thermal fatigue performance of the SnPb interposer joints demonstrates the ability of the NSMD pad features to delay fatigue crack initiation. Additionally, the coefficient of thermal expansion (CTE) mismatch is expected to be minimal between the interposer and the PCB. Therefore, the SnPb solder joint stress is dominated by this minimal CTE mismatch plus some effect due to the SAC305 component soldered onto the interposer. Table 4: Summary of 0 to 100 °C thermal cycling statistics for the 676 I/O PBGA. 676 I/O PBGA Thermal Cycling Data Characteristic Component Variation Lifetime (cycles) SnPb as-received 2049 SnPb reballed from 1969 SAC305 SAC305 as-received 4863 SAC305 on SnPb 4402 interposer Slope β 9.36 8.99 7.87 7.69 Figure 7: Weibull plot comparing the performance of the SnPb and SAC305 packages to the interposer and reballed backward compatible assembly options. Figure 8: Failure map and optical photomicrographs for an interposer subassembly that failed by thermal fatigue in the SAC305 BGA solder balls (upper images). There is no evidence of fatigue crack initiation in the eutectic SnPb interposer balls (lower images). FAILURE ANALYSIS Failure analysis was performed on temperature cycled samples to document the failure mode and specific location of the failures in the components and interposer subassemblies. Figure 8 shows the failure map and solder joint failures for an interposer subassembly. The photomicrographs in Figure 9 compare the failure mode of the as-received SnPb BGA to the reballed SnPb BGA. The critical characteristics of the two failures are identical, which indicates that the reballing process has no appreciable Cross sectioning was initiated in the outer row of the subassembly and proceeded incrementally towards the die 898 CONCLUSIONS The accelerated temperature cycling test results demonstrate acceptable thermal fatigue reliability for the interposer subassembly and the reballed BGA. Based on thermal fatigue requirements, interposer assembly and reballing are alternative solutions for backward compatible assembly of the 676 I/O PBGA. affect on the failure. The crack paths are at the package side of the solder ball near the IMC layer but contained in the bulk solder. The higher magnification SEM images of additional failed joints in Figure 10 show that the crack path clearly is between the Sn-rich and Pb-rich phases in the bulk solder. In the case of SnPb solder, failure is preceded by grain coarsening in the microstructure [61]. For the case of the Pb-free (SAC305) BGA assembled onto a SnPb interposer card, the solder joint failures occur in the SAC305 BGA solder joints. The test data indicate that using the interposer results in a slight degradation in attachment reliability (measured by characteristic lifetime) compared to the case of the same SAC305 BGA soldered directly onto a circuit board. Despite this minor degradation, the resultant solder joint attachment reliability of the interposer subassembly is substantially better than the reliability of the SnPb version of the identical BGA. The failure analysis also indicates that the SnPb interposer solder interconnections are inherently robust from a thermal fatigue perspective, presumably a result of using non-solder mask defined (NSMD) pads in the substrate design and the minimal CTE mismatch between the interposer and the PCB. Figure 9: Comparison of the fatigue fractures in as-received SnPb and SnPb reballed from SAC305. For the case of the reballed SnPb BGA, there is no statistically significant difference in thermal fatigue reliability of the solder joints between an as-received version of the 676 I/O SnPb BGA and the SnPb version created by reballing a SAC305 BGA. Although there is a slight difference in time-zero microstructure between the asreceived and reballed packages, it would be highly speculative to attribute the small differences in thermal fatigue reliability to the microstructural differences. Figure 10: Secondary electron images (SEI) showing solder fatigue failures in the SnPb and reballed SnPb samples. ACKNOWLEDGEMENTS The authors thank Sherwin Kahn and Marc Benowitz from Alcatel-Lucent, and Prashant Joshi, Karen Hille, and Glen Griswold from Interconnect Systems for supporting this work. SUGGESTIONS FOR ADDITIONAL WORK This work focused specifically on assessing thermal fatigue performance of the solder attachments of a 676 I/O BGA interposer subassembly and a reballed 676 I/O BGA. While thermal fatigue resistance is considered critical for telecommunication applications, resistance to drop, shock, and vibration are important in other applications. It would be beneficial to expand the interposer and reballing evaluation to include mechanical testing to address other application requirements. Mechanical integrity might be particularly critical for the interposer subassembly. There also would be value in performing similar studies on larger BGA packages. REFERENCES [1] “Annex to Directive 2002/95/EC, Restriction on the use of hazardous substances (RoHS) in electrical and electronic equipment,” Official Journal of the European Union, 14.10.2006, L283/48-49, October 12, 2006. [2] iNEMI Availability of SnPb-Compatible BGAs Workshop, Cupertino, CA, March 1, 2007. http://www.inemi.org/cms/projects/ese/SnPb_BGAs.ht ml [3] Richard Coyle, Peter Read, Steven Kummerl, Debra Fleming, Richard Popowich, and Indraneel Chatterji, “A Comprehensive Analysis of the Thermal Fatigue Reliability of SnPb and Pb Free Plastic Ball Grid Arrays (PBGA) Using Backward and Forward Compatible Assembly Processes,” SMT Journal, Volume 21, Issue 4, 33-47, October-December, 2008. [4] B. Smith, P. Snugovsky, M. Brioux, and A. Grivon, “Industrial Backward Solution for Lead Free There are other important factors related to reballing technology that have not been addressed in this paper. These include the risk that reballing will cause package warpage, delamination, or solder pad damage. Meschter began to address and evaluate these effects [55] but given the evolution of package materials and package construction needed to enable Pb-free technologies, additional work may be needed. 899 [5] [6] [7] [8] [9] [10] [11] [12] [13] [14] [15] [16] Exempted AHP Electronic Products, Part 2: Process Technology Fundamentals ands Failure Analysis,” Proceedings of APEX 2008, S15-01, Las Vegas, NV, 2008. P. Snugovsky, H. McCormick, S. Bagheri, Z. Bagheri, C. Hamilton, and M. Romansky, “Microstructure, Defects, and Reliability of Mixed Pb free/SnPb Assemblies,” Supplemental Proceedings: Volume I: Materials Processing and Properties TMS (The Minerals, Metals, and Materials Society, 631-642, New Orleans, LA, 2008. Robert Kinyanjui, Quyen Chu, Polina Snugovsky, Richard Coyle, “Solder Joint Reliability of Pb-free SnAgCu Ball Grid Array (BGA) Components in SnPb Assembly Process,” Proceedings of APEX 2008, S1502, Las Vegas, NV, 2008. Robert Kinyanjui and Quyen Chu, “The Pb-free SnAgCu Ball Grid Array (BGA) Components in SnPb Assembly Process: Process Characterization and Solder Joint Reliability,” Proceedings of SMTAI, 760769, Orlando, FL, 2007. H. McCormick, P. Snugovsky, C. Hamilton, Z. Bagheri, and S. Bagheri, “The Great SAC Debate: The Reliability of SAC305 and SAC405 Solders in a Variety of Applications,” Proceedings of PanPac Symposium, 333-341, January 31, 2007. J. Nguyen, D. Geiger, D, Rooney, and D. Shangguan, "Backward Compatibility Study of Lead-Free Area Array packages with Tin-Lead Soldering Processes," Proceedings of APEX, S09-03, Anaheim, CA, 2006. J. Nguyen, D. Geiger, D, Rooney, and D. Shangguan, "Reliability Study of Lead-Free Area Array Packages with Tin-Lead Soldering Processes," Proceedings of SMTAI, 433-438, Chicago, IL, 2006. H. McCormick, P. Snugovsky, Z. Bagheri, S. Bagheri, C. Hamilton, G. Riccitelli, and R. Mohabir, “Mixing Metallurgy: Reliability of SAC Balled Area Array Packages Assembled Using SnPb Solder,” Proceedings of SMTAI, 425-432, Chicago, IL, 2006. A. Zbrzezny, P. Snugovsky, T. Lindsay, R. Lau, “Reliability Investigation of Mixed BGA Assemblies”; IEEE Transactions on Electronic Package Manufacturing, vol. 29, no.3, 211-216, July, 2006. O. Maire, C. Munier, S. Bousquet, C. Chastenet, and M. Jeremias, “Backward Compatibility of Lead-Free BGA: Microstructural Characterization and Reliability,” Proceedings IPC Soldertec, Malmo, Sweden 2006. C. Hunt and M. Wickham, “Impact of Lead Contamination on Reliability of Lead Free Alloys,” Proceedings IPC Printed Circuits Expo 2006, S39-01, 2006. I. Chatterji, “Backward Compatibility, Are We ReadyA Case Study”; Proceedings of SMTAI, 416-424, Chicago, IL, 2006. M. Abtew, R. Kinyanjui, N. Nuchsupap, T. Chavasiri, N. Yingyod, P. Saetang, J. Krapun, and K. Jikratoke, “Effect of Inert Atmosphere Reflow and Solder Paste Volume on the Microstructure and Mechanical [17] [18] [19] [20] [21] [22] [23] [24] [25] [26] 900 Strength of Mixed Sn-Ag-Cu and Sn-Pb Solder Joints,” Proceedings of SMTAI, 74-78, Chicago, IL, 2006. H. McCormick, P. Snugovsky, Z. Bagheri, and S. Bagheri, “Pb-free Test Vehicle, Microstructure and ATC Behavior of SAC305 and SAC405 BGAs Assembled with SnPb Solder,” Proceedings of International Conference on Lead-free Soldering, Toronto, ON, Canada, no. 11, 1-9, May 16-18, 2006. A. Giamis, G. Wenger, and P. Solan, “Mixed Alloy Solder Joint Reliability Sanity Check,” Proceedings of International Conference on Lead-free Soldering, Toronto, ON, Canada, no. 12, 1-5, May 16-18, 2006. Woodrow, T.A., “JCAA/JG-PP Lead-Free Solder Project: -20 to +80 °C Thermal Cycling Test”, Proceedings SMTA International, 825-835, Rosemont, IL, September 24-28, 2006. A. Zbrzezny, P. Snugovsky, T. Lindsay, R. Lau, “Reliability Investigation of Mixed Solder Interconnects – Case Studies,” Proceedings of SMTAI, 397-402, Chicago, IL, 2005. H. McCormick, P. Snugovsky, Z. Bagheri, S. Bagheri, C. Hamilton, G. Riccitelli, and R. Mohabir, “Mixing Metallurgy: Reliability of SAC Balled Area Array Packages Assembled Using SnPb Solder,” SMTA Journal, Vol. 20, no. 2, 11-18, 2007. P. Snugovsky, A. R. Zbrzezny, M. Kelly, M. Romansky, “Theory and Practice of Lead-Free BGA Assembly Using Sn-Pb Solder,” Proceedings CMAP (Centre for Microelectronics Assembly and Packaging in Canada) International Conference on Lead-free Soldering, University of Toronto, Toronto, ON Canada, May 2005. J. Bath, S. Sethuraman, X. Zhou, D. Willie, K. Hyland, K. Newman, L. Hu, D. Love, H. Reynolds, K. Kochi, D. Chiang, V. Chin, S. Teng, M. Ahmed, G. Henshall, V. Schroeder, Q. Nguyen, A. Maheswari, M. Lee, J-P Clech, J. Cannis, J. Lau, C. Gibson, “Reliability Evaluations of Lead-Free SnAgCu PBGA676 Components Using Tin-Lead and Lead-Free SnAgCu Solder Paste,” Proceedings of SMTAI, 891-901, Chicago, IL, September 25-29, 2005. D. Hillman, M. Wells, and K. Cho, “The Impact of Reflowing a Pb-free Solder Alloy using a Tin/Lead Solder Alloy Reflow Profile on Solder joint Integrity,” Proceedings CMAP (Centre for Microelectronics Assembly and Packaging in Canada) International Conference on Lead-free Soldering, University of Toronto, Toronto, ON Canada, May 2005. J. L. Evans, C. Mitchell, M. Bozak, L. N. Payton, M. R. McQuenney, and J. R. Thompson, “Reliability of SAC BGA Using SnPb Paste for Harsh Environment Electronics,” Proceedings of SMTAI, 365-370, Chicago, IL, September 25-29, 2005. B. Nandagopal, Z. Mei, and S. Teng, “Microstructure and Thermal fatigue Life of BGAs with Eutectic SnAg-Cu Balls Assembled at 210 °C with Eutectic Sn-Pb Paste,” Proceedings of Electronic Component and [27] [28] [29] [30] [31] [32] [33] [34] [35] [36] [37] [38] [39] Technology Conference, 875-883, San Diego, CA, 2006. B. Nandagopal, D. Chiang, S. Teng, P. Thune, L. Anderson, R. Jay, and J. Bath, “Study on Assembly, Rework Process, Microstructures and Mechanical Strength of Backward Compatible Assembly,” Proceedings of SMTAI, 861-870, Chicago, IL, September 25-29, 2005. Gunter Grossmann, Joy Tharian, Pascal Jud, and Urs Sennhauser, "Microstructural investigation of lead-free BGAs soldered with tin-lead solder," Soldering & Surface Mount Technology, vol. 17 no. 2, pp. 10-21, 2005. C. Handwerker, "Transitioning to Pb-free Assemblies,” Circuits Assembly; March, 2005. M. Wickham, L. Zou, M. Dusek, C. Hunt, “Measuring the Reliability of Electronics Assemblies During the Transition Period to Lead-Free Soldering”, NPL Report DEPC MPR 030, National Physical Laboratory, UK August 2005. Peter Borgesen, 2005 Year End Report Unovis Area Array Consortium (formerly Universal Instruments Consortium). Jean-Paul Clech, Lead-Free and Mixed Assembly Solder Joint Reliability Trends, Proceedings of APEX 2004, S28-3, Anaheim, CA, February 24-26, 2004. C. Handwerker and J. Bath, et al.; “NEMI Lead-Free Assembly Project: Comparison between PbSn and SnAgCu Reliability and Microstructures,” Proceedings of SMTA International, 2003. P. Snugovsky, M. Kelly, Z. Bagheri, and M. Romansky, “Lead Free and Lead Bearing Solder Intermetallic Formation on Electroless Ni/Immersion Au Interconnects Affected by Black Pad,” Proceedings of APEX, S02-1, January 20-24, 2002. F. Hua, R. Aspandiar, T. Rothman, C. Anderson, G. Clemons, and M. Klier, “Solder Joint Reliability of SnAg-Cu BGA Components attached with Eutectic PbSn Solder Paste” Journal of Surface Mount Technology, Volume 16, Issue 1, 34-42, 2003. F. Hua, R. Aspandiar, T. Rothman, C. Anderson, G. Clemons, C-K. Chung, M. Faizul, “Solder Joint Reliability Assessment of Sn-Ag-Cu BGA Components Attached with Eutectic Pb-Sn Solder,” Proceedings of SMTA International Conference, 246252, Chicago, IL, 2003. C. K. Chung, R. Aspandiar, K. F. Leong, C.S. Tay, “The Interactions of Lead (Pb) in Lead-Free Solder (Sn/Ag/Cu) System,” Proceedings of Electronic Components and Technology Conference, 166-173, San Diego, CA, May 28-31, 2002. P. Snugovsky, Z. Baghjeri, M. Kelly, M. Romansky, “Solder Joint Formation with Sn-Ag-Cu and Sn-Pb Solder balls and Pastes,” Proceedings of SMTA International Conference, SOL3-1, Chicago, IL, Sep 22-26, 2002. J. Oliver, O. Rod, M. Nylén, C. Markou, “Fatigue Properties of Sn/3.5ag/0.7cu Solder Joints and Effects [40] [41] [42] [43] [44] [45] [46] [47] [48] 901 of Pb-Contamination,” Journal of SMT, Volume 15, Issue 4, 23-28, 2002. Karl Seelig and David Suraski, “A Study of LeadContamination in Lead-free Electronics Assembly and its Impact on Reliability,” Proceedings of SMTA, SOL4-3, Chicago, IL, 2002. J. Bartelo, S. Cain, D. Caletka, K. Darbha, T. Gosselin, D. Henderson, D. King, K. Knadle, A. Sarkhel, G. Thiel, C. Woychik, D. Shih, S. Kang, K. Puttlitz and J. Woods, “Thermomechanical Fatigue Behavior of Selected Pb-Free Solders, IPC APEX 2001, LF2-2, January 14-18, 2001. S. Choi, T. R. Bieler, K. N. Subramanian, J. P. Lucas, “Effects of Pb contamination on the eutectic Sn-Ag solder joint”; Soldering & Surface Mount Technology, 13/2, 26-29, 2001. Q. Zhu, M. Sheng, and L. Luo, “The effect of Pb contamination on the microstructure and mechanical properties of SnAg/Cu and SnSb/ Cu solder joints in SMT,” Soldering & Surface Mount Technology, 12/3,19-23, 2000. Paul Vianco, Jerry Rejent, Iris Artaki, Urmi Ray, Donald Finley, and Anna Jackson, “Compatibility of Lead-Free Solders with Lead Containing Surface Finishes as a Reliability Issue in Electronic Assemblies,” Proceedings of Electronic Component and Technology Conference, 1172-1183, Orlando, FL, May 28-31, 1996. R. Coyle, M. Reid, C. Ryan, R. Popowich, P. Read, D. Fleming, M. Collins, J. Punch, I. Chatterji, “The Influence of the Pb free Solder Alloy Composition and Processing Parameters on Thermal Fatigue Performance of a Ceramic Chip Resistor,” Proceedings of Electronic Components Technology Conference, 423-430, San Diego, CA, May 26-29, 2009. Mark Logterman and Lavanya Gopalakrishnan, “A Product Feasibility Study of Assembling Pb-free BGAs in a Eutectic Sn/Pb Process, Proceedings of 59th Electronic Component and Technology Conference, 742-751, San Diego, CA, May 26-29, 2009. Quyen Chu, Girish Wable, Anthony Babasa, Evan Doxtad, Michael Lapitan, Michael Santos, Josh Solon, Ken Hubbard, Gnyaneshwar Ramakrishna, Greg Henshall, Ahmer Syed, Ranjit Pandher, Chrys Shea, “Low-Silver BGA Assembly Phase I – Reflow Considerations and Joint Homogeneity Third Report: Comparison of Four Low-Silver Sphere Alloys and Assembly Process Sensitivities,” Proceedings IPC APEX 2009, S05-03, Las Vegas, NV, April 2009. Robert Kinyanjui, Raiyo Aspandiar, Richard Coyle, Vasu Vasudevan Stephen Tisdale, Jorge Arellano, and Satish Parupalli, “Challenges in Reflow Profiling Large and High Density Ball Grid Array (BGA) Packages Using Backward Compatible Assembly Processes,” Proceedings of IPC APEX 2010, Las Vegas, NV, xxx, April , 2010. [49] Richard Coyle, Heather McCormick, Peter Read, Richard Popowich, Debra Fleming, and John Osenbach, “A Reliability Comparison of SAC305 AND SAC105 Plastic Ball Grid Arrays Assembled with Backward Compatible Soldering Processes,” Proceedings of SMTAI 2010, 68-75, Orlando, FL, October 2010. [50] Vasu Vasudevan, Richard Coyle, Raiyo Aspandiar, Steve Tisdale, Robert Kinyanjui and Gary Long, “Thermal Cycling Reliability, Microstructural Characterization, and Assembly Challenges Encountered with Backward Compatible Soldering of a Large, High Density Ball Grid Array,” Proceedings of Electronic Components Technology Conference, IEEE, Piscataway, NJ 2011. [51] Richard Coyle, Richard Popowich, Peter Read, Debra Fleming, Raiyo Aspandiar, Alan Donaldson, Vasu Vasudevan, Iulia Muntele, Stephen Tisdale, and Robert Kinyanjui, “The Relationship between Backward Compatible Assembly and Microstructure on the Thermal Fatigue Reliability of an Extremely Large Ball Grid Array,” Proceedings of APEX 2012, S32-02, Las Vegas, NV, March 2012. [52] M. Meilunas and P. Borgeson, “Effects of Cycling Parameters on the Thermal Fatigue Life of Mixed SnAgCu/SnPb Solder Joints,” Journal of Electronic Packaging, ASME, Vol. 133, Issue 2, 2011. [53] Richard J. Coyle, Albert Holliday, Patrick P. Solan, Charlene Yao, Howard A. Cyker, John C. Manock, Ronald Bond, Ralph E. Stenerson, Robert G. Furrow, Michael V. Occhipinti, and Steven A. Gahr “Solder Joint Attachment Reliability and Assembly Quality of a Molded Ball Grid Array Socket,” Proceedings of the Electronic Components & Technology 51st Conference, 1219-1226, Orlando, FL, May 30 - June 1, 2001. [54] S. J. Meschter and J. Arnold, “BGA Reballing from Pb-Free to Sn-Pb Metallurgy,” Advanced Technology Workshop on High Reliability Microelectronics for Military Applications, International Microelectronics and Packaging Society (IMAPS), August 31September 2, 2010., Bethesda, MD. [55] S. J. Meschter, S.A. McKeown, R. Feathers and E. Arseneau, “BGA Reballing from Pb-Free to Sn-Pb Metallurgy,” Proceedings of SMTAI 2010, Orlando, FL, October 2010. [56] Raymond Cirimele, “BGA Reballing Reliability,” Circuits Assembly, June 2009. [57] Lei Nie, Michael Osterman and Michael Pecht, Fubin Song, Jeffrey Lo and S.W. Ricky Lee, “Solder Ball Attachment Assessment of Reballed Plastic Ball Grid Array Packages,” Proceedings APEX 2009, P07-03, Las Vegas, NV, 2009. [58] L. Nie, M. Osterman, and M. Pecht, “Microstructural Analysis of Reworked Ball Grid Array Assemblies Under Thermomechanical Loading Conditions,” IEEE Trans. on Device and Materials Reliability, Vol. 10, No. 2, 276-286, June 2010. [59] IPC-9701A, “Performance Test Methods and Qualification Requirements for Surface Mount Solder Attachments,” IPC, Bannockburn, IL, 2006. [60] Richard Coyle, John Osenbach, Maurice Collins, Heather McCormick, Peter Read, Debra Fleming, Richard Popowich, Jeff Punch, Michael Reid, and Steven Kummerl, “Phenomenological Study of the Effect of Microstructural Evolution on the Thermal Fatigue Resistance of Pb-Free Solder Joints,” IEEE Trans. CPMT, vol. 1, no. 10, 1583-1593, October 2011. [61] Paul G. Harris, M. A. Whitemore, and William B. Hampshire, “An Introduction to the Metallurgy of Soldered Joints,” Proc. Surface Mount International 1992, San Jose, Ca., 445-452, September 1-3, 1992. 902