WE KNOW HOW Product and Service Offering Our Complete ¢ Contact Materials, Semi-finished Products and Contact Parts ¢ Contact Rivets ¢ Stamping Technology ¢ Electro-mechanical Components ¢ Surface and Coating Technology ¢ Precious Metal recycling and Silver Powders RANGE OF PRODUCTS AND SERVICES Your Partner for Premium Contact Technology DODUCO is a global leader when it comes to electrical contacts. Since over 90 years we have been active in precious metal processing. Our broad experience and know-how enables us to be a reliable partner to our customers as a supplier of products and services – in all stages of product development and planning, all the way to manufacturing and recycling. DODUCO serves the electrical, electronics, automotive and many other industries through its business units for precious metal contact materials, stamping technology, contact parts, for high and medium voltage, electromechanical components, surface coatings and precious metal recycling. By combining these different technologies we can create optimal technical and economical solutions. Our in-house application and testing laboratories with state-of-the-art equipment allows us to conduct fundamental research, optimize products and processes and find innovative solutions. With production facilities in Germany (Pforzheim, Sinsheim), Spain (Madrid) and in China (Tianjin) we are close to development and manufacturing centers of leading customer companies. Our global sales organization is ready to serve as a contact partner in most countries around the world. Market driven dynamics and customer oriented services the business principles we live by. The basis of this philosophy was established by the company founder Dr. Eugen Dürrwächter. In 1922 he started DODUCO as a precious metal refining company for gold, silver and platinum materials for the reclamation and re-use in jewelry making in Pforzheim, the jewelry center of Germany. The development of improved processing allowed the jewelry industry to introduce many new products to their market. Soon after Dr. Dürrwächter realized that the growing electrical industry provided a new market opportunity for related materials. DODUCO engaged very early in the manufacturing of precious metal electrical contacts and their alloys and in 1932 established a dedicated factory for contact manufacturing. By investing in new technologies and based on the innovation driven spirit of its employees DODUCO developed over the years into a technology company and a world leader in electrical contact manufacturing. Today DODUCO is an internationally operating company with approximately 1.300 employees worldwide. Optimizing existing and developing new, innovative and environmentally friendly products, processes and technologies ensures the long term growth objectives of the company – always with advantages to our customers in mind and supported by the exceptional knowledge and motivation of our employees. To our customers the name DODUCO is a trademark for quality and at the same time synonymous for technological leadership and customer service in all areas of contact manufacturing and sales – with a unique depth of processing and product technologies. New products offer new opportunities for our customers. To quickly respond to the many market challenges you should from the start take advantage of the technological competence of DODUCO. As a true cooperation partner we actively incorporate our knowledge and experience into the improvement and new development of customer products. We can apply our unique and comprehensive depth of manufacturing: from contact materials manufacturing by powder and melt metallurgy all the way to electromechanical components, from precision stamping through contact parts and surface coatings to the complete range of precious metal recycling. Every single step of production can be employed in the manufacturing of simple contact parts up to seamless solutions to customer project requirements. DODUCO employees can assume the role of project managers or can pragmatically cooperate with the customer's experts. Our application and process engineers and development staff are available in the early design stage with concept developments for meeting the requirements of the new product regarding resource utilization and cost-benefit profiles. Many years of experience are employed to evaluate design principles, the electrical and mechanical requirements and to select the most suitable contact materials. We also consider the influences of applied manufacturing technologies and the environmental effects on the design and materials. Our project management serves as the link between the customer and manufacturing, product development, suppliers, the laboratory services involved and quality assurance. It coordinates technical alternatives and transparently monitors and controls time tables, costs and additional measures as required. Focal points are always the customer's product, optimal quality and the shortest possible time-to-market. At DODUCO development cooperation always means responsible, open and target oriented cooperation with our partners. Early on technical, economical and logistics aspects are considered. D ev e l o p Partners m t enip h ustome r C Product Development E co no C cs mi ct tomer Produ us Product Delivery RANGE OF PRODUCTS AND SERVICES Results-oriented Development Cooperation DODUCO is your expert in electrical contacts For over 80 years our world has centered on precious metals and the conduction of electrical energy. We conduct basic research, development in the areas of new materials manufacturing and processing technologies involved in the production of electrical contacts. We disseminate our expertise through publications, presentations at technical seminars and conferences and through application engineering. We also participate in cooperative development partnerships with various institutions. DODUCO develops new electrical contacts The requirements on electrical contacts are very versatile. Current, voltage, load characteristics, geometry, kinetics and kinematics are different for every application. They pose a new challenge with every new project. DODUCO has a very broad spectrum of contact materials and processing technologies. These are constantly improved upon in an application based and project oriented way. DODUCO offers comprehensive technical application engineering The most suitable selection of contact materials requires expert knowledge. Our application engineers are specialists in their respective fields. They contribute to the project and give successful advice during all project phases. They are supported in their efforts by our modern equipped application and test laboratories. DODUCO has the full depth of manufacturing technologies We exemplify a unique and comprehensive depth of manufacturing: from precious metal refining through semifinished materials manufacturing by powder and melt metallurgy all the way to precious metal contacts. Stamping technology, plastic molding, electroplating and the whole range of welding and rivet staking techniques – our knowhow is at your disposal. Every level of manufacturing depth, from a simple contact part up to seamless solutions for complex components is available. Contact Materials, Semi-Finished Products, Contact Parts for Power Engineering and Information Technology Competency in Electrical Contacts The properties of the contact material are the deciding factors for the reliable function of the contact spots in any electromechanical device. From a broad range of contact materials we develop and manufacture semi-finished products and contact parts, which are optimized towards the application in electromechanical switching devices and electronic components. Using the most environmentally friendly composite materials and alloys, such as for example Silver-Tin Oxide, is of increasing importance. Contact Materials for Information Technology Silver and Silver Alloys (Ag, AgCu): Favorable electrical properties for a broad application range. Silver-Palladium (AgPd): Sulfur resistant contacts. Fine Silver (Ag): Combines the best electrical and thermal conductivity with very good chemical stability. Gold-Cobalt (AuCo) and PalladiumCopper (PdCu): With special microstructure, resistant against material transfer in DC circuits. ARGODUR Spezial (Fine Grain Silver AgNi 0.15): Better arc erosion resistance than Fine Silver. Gold-Nickel (AuNi) and Gold-SilverNickel (AuAgNi): Significantly improved mechanical strength compared to Gold. For high reliability contacts for switching low loads. ARGODUR 27 (AgCuNi) and Hard Silver (AgCu): Strongly increased mechanical properties with decreased chemical stability, compared to ARGODUR Spezial. Contact parts for low voltage power engineering ARGODUR 32 (AgMgNi): In precipitation hardened condition suitable as temperature stable spring and contact material for higher power relays. RANGE OF PRODUCTS AND SERVICES Gold-, Platinum- and Palladium-Alloys: For highest requirements on corrosion resistance. Semi-finished Materials Wire, strip and profiles from precious metals, their alloys and composite materials. Wire Solid, also electroplated with Silver or Gold Strip Electroplated with Silver or Gold. Totally clad on one or both sides (Overlay). Clad as stripe on strip or at edge with precious metal or Aluminum (Inlay, Edgelay) – also known as ContactBimetals. Selectively electroplated with Silver, Gold, Palladium, Tin Tinned by hot-dipping in stripe form or at edges Profiles Solid, two- or multiple layers as miniature profile. Brazed onto substrate strip material as Toplay profile. Seamwelded onto thin spring-hard carrier strips as FDR profile. Silver Bronze With high electrical conductivity CONDUFLEX High Conductivity Spring Materials Multi-layer composite materials with good spring properties and high electrical conductivity DODURIT ZnO, Silver-Zinc Oxide (Ag/ZnO): For current limiting powder switches, motor protectors and for electrical wiring applications. DODURIT CdO, Silver-Cadmium Oxide (Ag/CdO): Internally oxidized or made by powder metallurgy. High load contacts in low voltage switching devices. GRAPHOR, Silver-Graphite (Ag/C): For switching contacts with extremely high resistance to contact welding in circuit breakers and for sliding contacts. SIWODUR, Silver-Tungsten and SilverTungsten Carbide (Ag/W and Ag/WC): For circuit breakers and protective power switches. SILMODUR, Silver-Molybdenum (Ag/Mo): As highly arc erosion resistant contacts in circuit breakers. Composite Bi- or Tri-metal Rivets With contact layers of Silver, Silver alloys, Silver-Metal Oxide or Silver-Nickel on a copper base. Contact Tips With bottom layer suitable for brazing or welding, also with brazing alloy coated underside. Weld Buttons With contact material surface layer and weldable material on bottom. Rivet-staked, Brazed, Welded or Clad Contact Parts FULMIDUR Welded contact assemblies. Contact Pins and Arc Tip Assemblies With Tungsten-Copper tips. CUWODUR, Tungsten-Copper (W/Cu): Extremely arc erosion resistant for load switches and circuit breakers in medium and high voltage switchgear. VAKURIT, Low gas content materials based on Copper-Chromium and Tungsten-Copper (Cu/Cr and W/Cu): For vacuum switches and circuit breakers. Contact Materials for Power Engineering SINIDUR, Silver-Nickel (Ag/Ni): For auxiliary current switches, relays and circuit breakers (with Silver-Graphite as mating contact) SISTADOX, Silver-Tin Oxide (Ag/SnO2): Manufactured by powder metallurgy (AgSnO2 with and without additives) or internally oxidized (with In2O3). Environmentally friendly and arc erosion resistant contacts for relays, contactors and circuit breakers. Contact Parts for Power Engineering Contact Rivets Solid from Silver, Silver alloys and composite materials. Refractory contacts for high voltage power enginieering Contact Tulips and Tubes With Tungsten-Copper layers on Copper or Copper-Chromium-Zirconium carriers. Spring-loaded Contact Tulips From Copper-Chromium-Zirconium for current carrying main contacts. SISTADOX 12 WPD CUWODUR with braze alloy backing microstructure Contact Discs, Rings and Formed Parts From low gas content materials based on Tungsten-Copper or CopperChromium for vacuum switches. Equipment for blister packaging of small contact parts RANGE OF PRODUCTS AND SERVICES Production Competency in Stamping Technology The Full DODUCO manufactures precision stamped parts incorporating electrical contact functions. These can be welded, brazed, riveted, coated by electroplating, clad or mechanically mounted and assembled. Depending on our customer's requirements we supply these products as individual parts, prestamped strips, in comb segments or blister packaged. Welded Stamped Parts The contacts are attached by resistance welding from wire, profiles or by feeding of single contacts. Depending on the application, Gold, Silver or Palladium based contact materials are used. Riveted Stamped Parts Utilizing composite Bi- or Tri-metal rivets manufactured at our facility in Spain Progressive die with assembling of springs allows to keep the usage of precious metal at the absolute minimum required for reliable switching functions. During wire-staking – the forming of rivet shaped contacts in a progressive die – the contact rivet is produced without additional costs and allows significantly higher production speeds. Stamped Parts from Semi-finished Contact Materials Stamped contact parts made from semifinished strip material are economically manufactured endlessly and at high production rates. The contact materials made in our mill operations are based on Gold, Palladium and Silver. Aluminum is used as a bondable surface layer. Subassembled Stamped Parts In a progressive die the attachment of stamping frames to each other is performed by forming and riveting or by welding. This way the different properties of the individual components can be combined in the assembled stamped part. Such as, for example, high electrical conductivity with exceptional spring properties. Added Value for Our Customers By linking the above technologies and adding multiple form tapping devices into a progressive die, we can offer to our customers the most economical solutions on the highest level. Comprehensive tool building for all important production steps RANGE OF PRODUCTS AND SERVICES Electro-mechanical Components Synergy of Material and Function In Europe DODUCO develops and manufactures electromechanical components of varying complexity; if requested, even electronic components can be incorporated, greatly expanding their functionality range. Combining plastics, metal parts and contact surface coatings leads to a complete solution which reduces for our customers the need for additional interfaces and produces significant cost savings. In order to accomplish these goals we get involved in the early stages of development and design. Assembly Technology Stamped, plastic molded and discrete electronic components are assembled to components with new extended functionality. Hybrid Housings Metal – Plastic composite components with single or multiple stamped and/or electronic insert parts for the application in electronic circuits. Hybrid frames for application in power electronics and automotive contact systems and management of control functions Over-molded components Reel-to-Reel Technology Contact systems combined in metalplastic composites as a solution to customer-specific application requirements. Assembled components for hybrid applications and automotive mirror memory setting Products, Processes and Coatings for the Surface Technology The Unique Service Combination The combination of related products and services allows elaborate solutions from one source. DODUCO supplies precious and non precious metal electrolytes for technical and decorative applications and offers job-shop surface coating using all important processes. Electroplating Solutions for Technical and Decorative Applications Gold Electrolytes Acidic, neutral and cyanide gold electrolytes for the deposition of Pure Gold, Hard Gold, Colored Gold and Gold Alloy layers. Electroless Gold baths and galvano-forming solutions. High speed processes for reel-to-reel plating. Platinum Metal Electrolytes Electrolytes for the deposition of Ruthenium, Rhodium, Palladium, Palladium-Nickel and Platinum. DODUSTAN Immersen Tin process for the electroless tinning of printed circuit board and other technical applications. Silver Electrolytes Electrolytes for the deposition of Hard and Pure Silver. DODUBOND Electr.-Ni/Pd/Au ENIPIG and ENEPIG, Pd/Au EPIG process for surfaces for gold wire bonding. Non-precious Metal Electrolytes Copper and Nickel electrolytes for technical and decorative applications. Tin and Tin-Lead baths for electrical and electronic surface coatings. White and Yellow Bronze processes for technical and decorative applications. CONTAMET Electroless Nickel baths for different technical applications. RANGE OF PRODUCTS AND SERVICES DOFLUX Flux for hot air leveling with lead-free and lead containing Tin. Products for the Metal Surface Treatment Cleaning and polishing agents, Etching solutions, Metal strippers, Anti Tarnishings. Precious Metal Salts and Concentrates Gold salts and Gold complexes, Silver salts, Concentrates for Platinum, Rhodium, Ruthenium- and Palladium electrolytes. Precious Metal Preparations ARGONOR Silver for furnace firing For the manufacture of conducting coatings and circuit paths on glass, quartz and ceramics. AUROMAL Silver Conductive Paints, Pastes And Conductive Adhesives For the coating, contacting and bonding of plastics, metals, ceramics and glass. Electrically Conductive Single- and TwoComponent Adhesives GRAPHAROL Conductive Adhesives For electrostatic and high-resistance applications. Services Technical Consulting, assistance in Coating technology for decorative and technical applications manufacturing, analytical analysis testing customer specific application and process development. Braze Alloy Powders For brazing of automatically produced jewelry chains. Job-shop Parts Electroplating Plating with Gold, hard Gold, Silver, hard Silver, Rhodium, Palladium, PalladiumNickel and Platinum for electrical engineering and electronics, automotive components, aerospace industry, HF technology, chemical industry, mechanics, laser optics, measurement and control and medical technology. Selective and spot plating of Gold and Silver on combs and single parts. Internal plating of hollow parts. Custom electroplating with controlled thicknesses: Silver up to 300 µm, hard Gold up to 30 µm, Fine Gold up to 100 µm. Non-precious Metal Surface Coatings With Copper, Nickel, Tin, Tin-Lead, Bronze-DODUBRONCE. Chemical Electroless Nickel Rack- and barrel-plating. Electrolytes and processes for technical surfaces Printed Circuit Board Plating Plating of rigid, rigid-flexible and flexible PCBs up to 610 x 605 mm with Nickel, Tin, Tin-Lead, Silver, Fine Gold, Hard Gold and Electroless Nickel/Gold – DODUCHEM and DODUBOND. Rhodium and Palladium coatings up to 500 x 400 mm and 300 x 400 mm resp. Ceramic Substrates Coating of conductive circuit paths on ceramic substrates with solderable and bondable (Al, Au wires) surfaces. Printed Circuit Board Express Service At our customer's request we can provide a turn-around time of 24 hours. Aluminum coatings Coating of Al, Al alloys and Al composite materials with electroless Ni and electroplated solderable layer. Silver Powder Chemical precipitation fine, agglomerated / wide range of specific surface areas Electrolytic deposition dendritic / crystalline, densely agglomerated, medium to low specific surface areas Atomization spherical / high tap density, low specific surface areas Flakes Reel-to-Reel Strip Electroplating Coating of strip, wire or stamped parts reel-to-reel With Gold, Silver, Palladium-Nickel, Copper, Nickel, Tin and Tin-Lead. In addition strips can also be tin coated by hot-tin-dipping. Full or selective coverage in stripes On one or both sides of the strip material. PVD (Physical Vapor Deposition) Coatings With precious metals, precious metal alloys, non-precious metals and alloys. Specialty coatings such as Titanium/ Titanium Nitride, Chromium, Molybdenum, Tungsten and Aluminum. Process Combinations Combined coatings of electroplated and PVD layers for high performance applications. Engineering Services Technical consulting, development of customer specific coating properties, specialty coatings to agreed customer specifications. Vacuum PVD coated parts RANGE OF PRODUCTS AND SERVICES Materials and Coatings for Electronics We Offer More for Power Electronics Based on our broad spectrum of materials and material combinations we offer comprehensive solutions for the electronic packaging and connection industry. They include selected materials structures and the deposition of defined coating. Aluminum-clad Strip And Stamped Parts for Housings in Controls And Power Electronics AlSi1-clad copper and copper alloy strips with and without electroplated surfaces, and stamped parts. The connection between the connector and the electronic circuit is achieved by Aluminum wire bonding on AlSi1. Coating of AlSiC heat sinks Molybdenum substrate discs Coating of Substrate Materials for Power Electronics Molybdenum substrate discs electroplated with precious and non-precious metals within close mechanical tolerances. Coatings are applied on both sides or selectively as required by the appli- cation. Electroplated and chemical deposition of Nickel on composite Aluminum/Silicon Carbide (AlSiC) material for soldering applications. AlSiC is increasingly used as heat sink material in power electronics. Aluminum clad strip and stamped parts Precious metal melting RANGE OF PRODUCTS AND SERVICES Recycling equipment X-Ray-Analytical equipment Metal Recycling Precious for the World of Tomorrow New Materials from Scrap Our precious metal refining facility uses efficient and environmentally safe processes to reclaim the precious metals Gold, Silver, Platinum, Palladium and Rhodium from different manufacturing residues. Precious metals are recovered from the following materials: Contact Materials n Clad strip and stamping scrap n Alloying scrap n Silver-Tungsten scrap n Brazed and assembled contact parts Electronics n Processors and integrated circuits n Ceramic substrates n Paste coated foil scrap n Connectors and switches n Printed circuit boards Electroplating n Surface coated metal scrap n Precious metal containing spent electrolytes and rinse water n Saturated resins and filters, electrolytically deposited precious metal powders and sludge Catalysts n Automotive exhaust catalysts n Catalysts from the chemical industry n Silver catalysts Others n Jewelry alloys, jewelry making and dental alloy scrap RANGE OF PRODUCTS AND SERVICES Comprehensive Quality and Environmental Management Benefitting Our Customers DODUCO is the Right Partner for You For the development of a new product it is important to select the right partner who has the experience and resources to help in accomplishing your project objectives. DODUCO employs all key technologies, including contact material manufacturing, precision stamping, electromechanical component assembly, surface coating and precious metal recycling. The necessary stamping and plastic molding dies are also produced in-house. This allows us to offer complete seamless solutions from a single source. For each of the manufacturing phases critical quality requirements can be established. This leads to the high quality standard of DODUCO. Highest Quality Standards DODUCO's quality management system is certified globally according to the DIN EN ISO 9001 standard. Depending on specific market requirements we are also certified for ISO TS 16949. Highest Environmental Standards One of the key aims of our corporate philosophy is to develop technologies that benefit and do not endanger mankind and the environment. Accordingly, all our activities follow the dictates of ecological responsibility in the handling of natural resources and demonstrate environmental awareness. Our environmental management system is certified according to DIN EN ISO 14001. Our Competencies Technical Consulting Comprehensive application engineering assistance Testing of Switching Devices We conduct electrical power performance and life testing according to DIN VDE 57660/Part 101-104, DIN VDE 57664,DIN VDE 57641. Power limits: 400V/6kA n Bounce characteristics n Electrical life of contact parts n Temperature rise n Make and break capacity n Arc movement behavior n Chopping current characteristics for vacuum switch contacts Material Testing and Surface Analysis Contact resistance measurement Metallography: Microstructure analysis Failure analysis Chemical Analysis: X-ray fluorescence (RFA) Atomic absorption spectroscopy (AAS) Gas content analysis Surface Analysis: Scanning electron microscopy (SEM) Energy and wavelength dispersive X-ray analysis (EDX, WDX) Research and Development Activities Concentrating on materials, surface technology, analytical methods, powder metallurgy, wear reducing surface layers (PVD), decorative and functional surface treatments (Electroplating, PVD) WE KNOW HOW DODUCO GmbH Breite Seite 1 74889 Sinsheim Germany Phone +49 7261 409-0 Fax +49 7261 409-288 ~ DODUCO ESPANA, S.L. Manises 1 28224 Pozuelo de Alarcón Spain Phone +34 91 799-4620 Fax +34 91 799-4655 Printed in Germany by WA,SCHN . 6/2014 . 0,3 e DODUCO GmbH Im Altgefäll 12 75181 Pforzheim Germany Phone +49 7231 602-0 Fax +49 7231 602-398 DODUCO CHINA Co. Ltd. 11 Xinxing Road, Wuqing development Area Tianjin 301700 PRC Phone +86 22 82939 166 Fax +86 22 82939 169 http://www.doduco.net Mail: info@doduco.net