Heterogeneous Integration of Enhancement Mode In0.7Ga0.3As Quantum Well Transistor on Silicon Substrate using Thin (≤ 2 µm) Composite Buffer Architecture for High-Speed and Low-voltage ( 0.5V) Logic Applications M. K. Hudait, G. Dewey, S. Datta, J. M. Fastenau*, J. Kavalieros, W. K. Liu*, D. Lubyshev*, R. Pillarisetty, W. Rachmady, M. Radosavljevic, T. Rakshit and Robert Chau Technology and Manufacturing Group, Intel Corporation, Hillsboro, OR-97124, USA *IQE Inc, Bethlehem, USA Contact: robert.s.chau@intel.com Abstract This paper describes for the first time, the heterogeneous integration of In0.7Ga0.3As quantum well device structure on Si substrate through a novel, thin composite metamorphic buffer architecture with the total composite buffer thickness successfully scaled down to 1.3µm, resulting in highperformance short-channel enhancement-mode In0.7Ga0.3As QWFETs on Si substrate for future high-speed digital logic applications at low supply voltage such as 0.5V. Introduction The InGaAs quantum well field effect transistor (QWFET) is one of the most promising device candidates for future high-speed and low-power digital logic applications due to high electron mobility, large Γ to L valley separation and good short-channel performance [1-3]. A seamless, robust heterogeneous integration of high-performance InGaAs QWFET on Si substrate will allow low-voltage, high-speed III-V based logic circuit blocks to couple with the main stream Si CMOS platform for future microprocessor applications, while avoiding the need for developing large diameter (≥300mm) III-V substrates. This paper describes in detail for the first time, the integration of In0.7Ga0.3As quantum well (QW) structure on Si through a novel, thin composite metamorphic buffer architecture consisting of GaAs and graded InxAl1-xAs layers, resulting in short-channel enhancement-mode In0.7Ga0.3As QWFETs on silicon with high performance at low supply voltage of 0.5V. Materials Growth and Characterization In0.7Ga0.3As quantum well (QW) device layers shown in Fig. 1 were heterogeneously grown on 4o off-cut (100) p-type Si substrates with lattice mismatch of >8% using a composite metamorphic buffer consisting of GaAs and graded InxAl1-xAs layers by solid source MBE. The thickness of the composite buffer is successfully scaled down to 1.3µm for the first time without degrading the properties of In0.7Ga0.3As QW. Figs. 2a-2b show cross-sectional TEM images of the entire structure grown on Si with 1.5µm and 1.3µm composite buffer, respectively. In both cases, the misfit and threading dislocations are predominantly contained in the composite buffer, and the active device layers are virtually defect-free, which is also shown in Fig. 2c using highresolution TEM. The relaxation state and the grading scheme 1-4244-0439-X/07/$25.00 © 2007 IEEE were evaluated using high-resolution x-ray rocking curve, as shown in Fig. 3. The angular separation between the diffraction peaks of GaAs with respect to Si confirms full relaxation of the GaAs layer. The indium composition of the InxAl1-xAs buffer layer is graded from 0 to 52%, with an overshoot of indium concentration (0.52<x<0.7) in-between, as evidenced by the two peaks existing in the InxAl1-xAs buffer region of Fig. 3. This overshoot was employed to ensure full relaxation of this buffer layer while minimizing its total thickness. The relaxation of the entire composite buffer layer allows the growth of a defect-free In0.7Ga0.3As QW on Si (Figs.2a-2c). Figs. 2c and 3 suggest the In0.7Ga0.3As QW layer is compressively strained with respect to the In0.52Al0.48As barrier. AFM surface morphology of the In0.7Ga0.3As QW layers grown on Si with 2µm and 1.3µm composite buffers exhibit a cross-hatch pattern, as shown in Figs. 4a and 4b respectively, demonstrating excellent metamorphic growth of the buffer layers. The surface rms roughness of In0.7Ga0.3As QW grown on Si was measured over an area of 5x5µm2 to be less than 4nm, which is similar to that of In0.7Ga0.3As QW grown on GaAs [4]. Figure 5a shows the In0.7Ga0.3As QW mobility at 300K and 77K as a function of total buffer thickness ranging from 3.2µm to 1.3µm of the composite buffer grown on Si. No mobility degradation is observed for all the buffer thicknesses, demonstrating that the thin composite metamorphic buffer architecture is effective in filtering dislocations. Fig. 5b compares the Hall mobility versus sheet carrier density (Ns) measured in the In0.7Ga0.3As QW layers grown on Si, GaAs and InP substrates at 300K and 77K. For a given Ns, the mobility in the In0.7Ga0.3As QW layer grown on silicon via the composite buffer is equivalent to those in the In0.7Ga0.3As QW layers grown on III-V substrates such as GaAs and InP. No degradation in QW mobility on Si is observed despite the >8% lattice mismatch, demonstrating effective dislocation filtering using the composite buffer on Si. Fig. 6a shows the quantitative mobility spectrum analysis (QMSA) for In0.7Ga0.3As QW on Si at different temperatures. The large conductivity ratio between the majority carrier (electrons) and the minority carrier (holes) at all temperatures and also the increase in electron mobility with decreasing temperature suggest no parallel, parasitic conduction in Si or through the composite buffer layer. In addition, both Ns and mobility exhibit no dependence on magnetic field at different 625 Device Characteristics Figure 7 shows the SEM micrograph of an In0.7Ga0.3As QWFET on Si with the composite buffer described above. The use of a combination of wet and RIE etch to recess the gate towards the channel, as well as Pt/Au Schottky gates, enable enhancement-mode (e-mode) operation and improve short channel performance of the device. The ID-VDS characteristics of the e-mode LG=80nm In0.7Ga0.3As QWFET on Si with 1.3µm composite buffer layer is shown in Fig. 8. Figs. 9a and 9b show the ID-VG characteristics of the e-mode LG=80nm In0.7Ga0.3As QWFETs on Si with 2µm and 1.3µm buffer, respectively. The Schottky gate leakage is also included for reference. Both devices exhibit good transistor characteristics and high performance at VDS=0.5V. The LG=80nm In0.7Ga0.3As QWFET on Si with 1.3µm composite buffer achieves threshold voltage (VT) = + 0.11V, IDsat = 0.32mA/µm and ION/IOFF = 2150 at VDS=0.5V with 0.5V VG swing. Fig. 10 shows VT as a function of LG for the e-mode and depletion-mode (d-mode) In0.7Ga0.3As QWFETs on Si. A positive VT shift of ~600mV from d-mode to e-mode operation was accomplished through gate recess etch. Figs. 11 and 12 show the sub-threshold slope (SS) and drain induced barrier lowering (DIBL), respectively as a function of LG for In0.7Ga0.3As QWFETs on Si, demonstrating improved SS and DIBL of e-mode over d-mode devices. Fig.13 shows the transconductance (Gm) characteristics of emode and d-mode LG =80nm In0.7Ga0.3As QWFETs on Si with different composite buffer thicknesses at VDS = 0.5V. The improved Gm’s of the e-mode devices with 1.3µm and 1.5µm buffer layers over that of the e-mode device with 2µm buffer are due to the improved transistor fabrication process. Fig. 14 shows the current gain (h21) versus frequency of the emode LG=80nm In0.7Ga0.3As QWFET on Si with 1.3µm composite buffer at VDS = 0.5V. Fig. 15 shows the cut-off frequency as a function of DC power dissipation comparing the e-mode LG=80nm In0.7Ga0.3As QWFET on Si with 1.5µm composite buffer at VDS=0.5V versus the standard LG=60nm Si n-MOSFET transistor at both VDS=0.5V and 1.1V. Comparing to the Si n-MOSFET, the e-mode In0.7Ga0.3As QWFET on Si exhibits >10X reduction in DC power dissipation for the same speed performance or >2X gain in speed performance for the same power. Conclusions In0.7Ga0.3As quantum well structure has been successfully integrated onto Si substrate using a novel, thin composite metamorphic buffer architecture with total buffer thickness scaled down to 1.3µm, resulting in high-performance shortchannel enhancement-mode In0.7Ga0.3As QWFETs on Si substrate with good device characteristics for future highspeed, ultra-low power digital logic applications. References [1]S. Datta et al, IEEE Electron Dev. Lett., vol. 28 (8), p. 685 (2007). [2]D. Kim and J. A. del Alamo, IEDM Tech. Dig., p. 837 (2006). [3]Y. Yamashita et al, IEEE Electron Dev. Lett., vol. 23 (10), p. 573 (2002). [4]D. Lubyshev et al, J. Vac. Sci. Technol. B, vol. 22 (3), p. 1565 (2004). n++-In0.53Ga0.47As contact InP etch stop : 20 nm : 6 nm In0.52Al0.48As top barrier : 8 nm Si delta-doped layer In0.52Al0.48As spacer layer : 5 nm In0.7Ga0.3As channel : 13 nm In0.52Al0.48As bottom barrier : 100 nm InxAl1-xAs graded buffer (x=0-0.52): 0.7-1.1 µm GaAs nucleation and buffer layer: 0.5-2.0 µm 4o(100) Offcut p-type Si substrate Metamorphic buffer temperatures, as shown in Fig. 6b, further indicating no parallel, parasitic conduction in the buffer layer or in Si. Fig.1: Heterogeneous integration of In0.7Ga0.3As QWFETs on Si using metamorphic composite buffer architecture consisting of GaAs and InxAl1-xAs graded buffer layers. The composite buffer in this work has total thickness in the range of 1.3µm to 3.2µm. In0.7Ga0.3 As QW 0.8 µm InxAl1-xAs 0.7 µm GaAs Si Fig. 2a: Cross-sectional TEM image of In0.7Ga0.3As QWFET on Si using 1.5µm composite buffer. The misfit and threading dislocations are predominantly contained in the composite buffer, with the In0.7Ga0.3As QW virtually defect-free. In 0.7Ga 0.3As QW 0.8µm InxAl1-xAs 0.5µm GaAs Si Fig. 2b: Cross-sectional TEM image of In0.7Ga0.3As QWFET on Si using composite buffer with total thickness of 1.3µm. The active In0.7Ga0.3As QW is virtually defect-free. 626 Si substrate InxAl1-xAs graded buffer GaAs buffer In0.53Ga0.47As cap layer 3.2µm X- ray Intensity [a.u] InP etch stop In0.52Al0.48As top barrier In0.7Ga0.3As QW 2µm 1.6µm 1.5µm 1.3µm In0.7Ga0.3As Quantum well -15000 In0.52Al0.48As bottom barrier Fig. 2c: High-resolution TEM of In0.7Ga0.3As QW, In0.52Al0.48As barriers, InP etch stop and In0.53Ga0.47As cap layer. The device layers are defect-free. 2µm buffer -10000 -5000 Omega/2theta [arcsec] 0 40000 10000 300K 77K 1000 1.2 13 Electron Hole -5 12 -2 Sheet Carrier Density [cm ] -1 Conductivity [Ω ] 200K -3 -5 10 -7 10 75K -3 10 77K 77K 77K 77K 20000 10000 300K 12 2x10 12 4x10 12 2DEG sheet carrier density [cm-2] 4 11 3 10 13 10 10 5 10 200K 4 10 11 Source 3 1013 10 105 10 75K 4 10 10 Gate Active device region Source Mesa isolation (Stop on InAlAs bottom layer) Gate air-bridge -7 11 2 10 3 4 10 10 Mobility [cm2/Vs] 5 10 Fig. 6a: QMSA mobility spectra for In0.7Ga0.3As QW on Si at different temperature demonstrating no parallel, parasitic conduction to the active In0.7Ga0.3As channel. 10 3 3 10 4 10 Field [Gauss] 10 5 10 Fig. 6b: Sheet carrier density (Ns) and electron mobility show no dependence on magnetic field at different temp, indicating no parallel, parasitic conduction in the composite buffer layer on Si. Fig.7: SEM micrograph of a two-finger In0.7Ga0.3As QWFET on Si with Pt/Au gate airbridge at the mesa edge and Ti/Pt/Au source/drain metals. 627 12 6x10 Fig. 5b: Electron mobility versus sheet carrier density (Ns) in In0.7Ga0.3As QW grown on Si (via novel composite buffer), GaAs and InP substrates at 300K and 77K. No degradation in QW mobility on Si despite >8% lattice mismatch, demonstrating effective dislocation filtering with the composite metamorphic buffer architecture on Si. 10 -5 10 300K; 300K; 300K; Drain -7 On Si On GaAs On InP 30000 10 3.2 10 300K 10 10 10 2.8 5 10 300K 10 2.4 Mobility [cm2/Vs] -3 2.0 Composite buffer layer thickness [µm] Fig. 5a: In0.7Ga0.3As QW electron mobility versus composite buffer layer thickness on Si at 300K and 77K. No mobility degradation is observed, demonstrating that the metamorphic buffer architecture is effective in filtering dislocations. Fig. 4b: AFM image from the surface of In0.7Ga0.3As QW layer on Si with 1.3µm composite buffer shows cross-hatch pattern with surface rms roughness of 39Å. 10 1.6 2D Hall electron mobility [cm2/Vs] Quantum well mobility [cm2/Vs] 40000 1.3µm buffer Fig. 4a: AFM image from the surface of In0.7Ga0.3As QW layer on Si with 2µm composite buffer shows cross-hatch pattern with surface rms roughness of 30Å. Fig. 3: High-resolution x-ray rocking curves from the (004) Bragg lines of In0.7Ga0.3As QWFET structures on Si substrates with different composite buffer thicknesses ranging from 1.3-3.2µm. 10 VGS = 0.5V 1.3 µm buffer -1 0.30 0.3V 0.10 0.2V 0.05 -3 10 -4 10 -5 10 0.00 0.0 0.1 0.2 0.3 0.4 -7 10 -0.4 0.5 Drain voltage, VDS [V] 200 0.2 -0.2 600mV -0.4 -0.6 e-mode on Si with 1.3µm buffer e-mode on Si with 2µm buffer d-mode on Si with 2µm buffer 50 75 100 125 150 175 200 180 120 100 80 60 50 225 Gm [ µS / µm ] 1400 1200 1000 150 175 200 Embedded fT = 302 GHz 600 400 200 VDS = 0.5V 0 -1.0 -0.8 -0.6 -0.4 -0.2 0.0 0.2 0.4 0.6 0.8 Fig.13: Transconductance, Gm characteristics of e-mode and d-mode LG =80nm In0.7Ga0.3As QWFETs on Si with different composite buffer thicknesses at VDS = 0.5V. 400 Fig. 14: Current gain (h21) versus frequency for the 80nm LG enhancement-mode In0.7Ga0.3As QWFET on Si with 1.3µm composite buffer, showing the embedded and de-embedded data at VDS = 0.5V. e-mode In0.7Ga0.3As QWFET on Si with 1.5µm buffer 350 300 250 VDS = 0.5V 1.1V 200 VDS = 0.5V 150 100 50 Frequency [Hz] 225 Fig.12: DIBL as a function of LG for emode and d-mode In0.7Ga0.3As QWFETs on Si, showing improved DIBL of e-mode devices over d-mode due to shorter gate to channel separation in e-mode. 450 -20 dB/dec 0.6 Gate length, LG [nm] De-embedded 800 Gate voltage, VG [V] 225 Model IG @VDS=0.5V -0.2 0.0 0.2 0.4 Gate voltage, VG [V] 220 e-mode on Si with 1.3µm buffer 200 e-mode on Si with 2µm buffer 180 d-mode on Si with 2µm buffer 160 140 120 100 80 60 40 20 VDS = 0.5V 0 50 75 100 125 150 175 200 Fig. 11: Sub-threshold slope (SS) as a function of LG for e-mode and d-mode In0.7Ga0.3As QWFETs on Si, showing improved SS of e-mode over dmode devices due to shorter gate to channel separation in e-mode. |h21| [dB] 1600 125 -0.4 Gate length, LG [nm] Fig. 10: Threshold voltage (VT) as a function of LG for enhancement-mode (e-mode) and depletionmode (d-mode) In0.7Ga0.3As QWFETs on Si. Positive VT shift of about 600mV from d-mode operation to e-mode operation was accomplished through gate recess etch. e-mode on Si: 1.3µm buffer e-mode on Si: 1.5µm buffer e-mode on Si: 2µm buffer d-mode on Si: 2µm buffer 100 IG @VDS=0.05V 1.3 µm buffer Fig. 9b: Drain current (ID) and gate leakage (IG) versus VG of enhancement-mode LG=80nm In0.7Ga0.3As QWFET on Si with 1.3µm composite buffer at room temperature. VT = +0.11V, IDsat = 0.32mA/µm, ION/IOFF = 2150 at VDS=0.5V with 0.5V VG swing. VDS = 0.5V 75 -5 10 -7 e-mode on Si with 1.3µm buffer e-mode on Si with 2µm buffer d-mode on Si with 2µm buffer 140 -4 10 10 0.6 160 Gate length, LG [nm] 1800 -0.2 0.0 0.2 0.4 Gate voltage, VG [V] -3 10 10 Fig. 9a: Drain current (ID) and gate leakage (IG) versus VG of enhancement-mode LG=80nm In0.7Ga0.3As QWFET on Si with 2µm composite buffer at room temperature. VT = + 0.07V, IDsat = 0.25mA/µm, ION/IOFF = 2500 at VDS=0.5V with 0.5V VG swing. Sub-threshold slope [mV/dec] Threshold voltage, VT @VDS=0.05V Fig.8: ID-VDS characteristics of enhancementmode LG=80nm In0.7Ga0.3As QWFET on Si with 1.3µm composite buffer at room temperature. 0.0 2 µm buffer 10 -6 IG @VDS=0.05V IG @VDS=0.5V -6 10 0.1V DIBL [mV/V] 0.15 10 ID & IG [mA/µm] 0.20 ID @ VDS =0.5V -2 Cut-off frequency, fT [GHz] 0.4V ID @ VDS =0.05V -1 10 -2 0.25 -0.8 10 ID @ VDS =0.05V ID @ VDS =0.5V 10 ID & IG [mA/µm] Drain current, ID [mA/µm] 0.35 0 0 0.40 Si n-MOSFET Si n-MOSFET 10 1 2 3 10 DC power dissipation [µW/µm] 10 Fig. 15: Cut-off frequency as a function of DC power dissipation for the enhancement-mode LG=80nm In0.7Ga0.3As QWFET on Si with 1.5µm composite buffer at VDS=0.5V, versus standard Si n-MOSFET transistor with LG = 60nm at VDS=0.5V and 1.1V. 628