Silver-Coated Textiles Establish New Markets By Samuel Etris, Senior Technical Consultant to The Silver Institute I L V E R I N S T I T U T E EL I N S T I T U T O DE LA PLATA First Quarter 2008 H E AT E D S G E R B I N G ’ S THE abrics that generate warmth, control bacteria, reduce odor, and stimulate muscle tone may seem a bit futuristic, but clothing made of silver-coated textiles has created a new class of consumer wear with more applications ahead. Thirty years ago, silver-coated fibers were introduced for use in antistatic rugs which proved essential to prevent sparking in hospital operating rooms. Electrical sparks present a danger amid oxygen-rich areas. The antibacterial characteristics of these fibers were soon put to use in stockings. Sauquoit Industries, Inc., for example, began marketing X-Static socks and underwear which now reach a $50 million a year market. Silverlon fabrics have revolutionized the clinical dressing market. They provide effective antibacterial control for wounded soldiers in the Iraq and Afghanistan wars. The fabrics also are made into antibacterial blankets for the wounded as they are transported in military aircraft on long These heated jackets rely flights to veterans hospitals in the US. on silver wires embedded The electrical conductivity of silver-coated in textiles to keep ProtexAg textiles manufactured by Carolina Silver wearers warm in Technologies, LLC in Valdese, North Carolina, cold weather. provides the clothing industry with a further advantage: electrically heated outerwear. Gerbings Heated Clothing, Inc., manufactures motorcycle jackets of these textiles which, when heated by the 12-volt motorcycle system, keep riders comfortable on the road in winter. Scuba divers, hunters, and spelunkers also are recognizing the merits of batteryheated clothing to extend their time in cold environments. Military pilots flying at high altitude during long missions can fly in warm comfort and at the same time reduce muscle fatigue using these heated clothes. During field trials of Silverlon, researchers noted relief of muscle fatigue. The skin is the largest organ of the body, and nerve endings interact with the environment to convert light, touch, and sound into electrical impulses that are transmitted to the central nervous system for action. A prompt response often can mean the difference between life and death. The electrical potential generated on the surface of the skin is known as its transepithelial potential (TEP). Damage to the skin or bone alters this potential, and pain is the body’s natural response. Silver-coated fabric blanketing the skin provides an additional electrical circuit to the skin that enhances the restoration of normal electrical impulses over areas where the TEP has been altered by stress and thus provides effective pain relief. Silverlon fabrics engineered to reduce pain are being marketed as ‘BioEnhancement Orthotics’ and provide direct interaction with the skin to rebalance altered TEP. Silver fabrics also may prove useful for those with carpal tunnel syndrome. In a study of 20 people suffering from carpal tunnel syndrome conducted by Argentum Medical LLC of Chicago, Illinois, patients wore a Silverlon Carpal Tunnel Sleeve 24 hours a day for three weeks. The sleeve was removed every three to five days for washing. Patients were then asked to complete a questionnaire. Nineteen of 20 patients reported a 70 percent pain reduction within 96 hours and 95 percent pain reduction within two weeks. Eighteen of 20 patients reported resolution of finger numbness within four weeks. The two patients who did not report any change in sensation were insulin-dependent diabetics. As researchers learn more about the power of silver textiles, many more applications are expected. C L O T H I N G F Silver Keeps Humidifiers Germ Free any people use humidifiers in their homes during winter months because moist, warm air is healthier to breath than dry, heated air. This is especially true for infants and those with respiratory problems. Unfortunately, humidifiers need to be cleaned and disinfected regularly because mold and mildew can build up in the water tank and other parts and disperse microscopic fungi and bacteria into the air. One humidifier, the Air-O-Swiss 7142 uses two silver-based parts to reduce these problems. First, a replaceable demineralization cartridge reduces so-called ‘white dust,’ composed of lime scale and other mineral deposits from the mist output. The plastic housing of the demineralization cartridge is silver treated to inhibit microbial growth on the surface of the cartridge. Second, a patented Ionic Silver Stick uses aqueous silver ions to control microbial growth for up to one year of continuous use. This optional accessory uses the antimicrobial action of silver to keep the unit safe and free of microbial growth. It is self-regulating and maintenance-free and should be replaced once a year, company officials say. A lifecycle replacement indicator lets users know when to change the Stick. The humidifier retails for $US199. A I R - O - S W I S S M Humidifiers are prone to germ and mildew buildup but silver ions keep this unit free of microbes. Hunters Wear Silver Clothes to Outfox Prey S tarting this fall, textile and chemical manufacturer Milliken & Company and outdoor products company Browning will team up to offer a retail line of scent-control hunting apparel powered by Milliken’s VisaEndurance Shield, which uses silver ions to control odors. Scent control is vital for hunters because many animals, such as deer, can pick up human odors from far away. The new line, branded under Browning's new ScentSmart line, was introduced at The Shooting, Hunting, Outdoor Trade Show and Conference (SHOT Show) in Las Vegas in February. VisaEndurance Shield is a technology that adsorbs and suppresses most body odor molecules in fabrics, then releases the odors during traditional home-machine laundering with unscented detergents. According to Milliken officials, VisaEndurance Shield fabrics are more breathable, flexible, and less bulky than activated carbon-containing fabrics. The technology works wet or dry, garments can be drip-dried or tumble-dried, and the scent-control technology is effective for the life of the garment. The first products will be a shirt, pants (both US$100) and a T-shirt (US$64). Browning currently sells base layer shirts and pants that use VisaEndurance Ion, Milliken's silver-ion based technology that prevents the growth of odor-causing bacteria. "We recognize that scent control is one of the most important success factors for hunters, and it's one of the most difficult to manage," said Tom Leopard, general manager for Milliken's Performance Fabrics. "At Milliken we're committed to developing fabric technologies that provide hunters with the best scent control and we're pleased to have Browning be the first partner to bring both VisaEndurance Ion and VisaEndurance Shield to market." New Vacuum Cleaners Go Silver hree vacuum cleaner makers are using silver ions to prevent bacteria buildup in their dust holders. The LG Kompressor is aimed at allergy and asthma sufferers and uses a dustcompressing technology that compacts dirt, dust, and other particles sucked up by the vacuum into hygienic solid ‘bricks’ that are easy to dispose. The tank that holds these bricks employ silver ions to prevent the growth of bacteria in the container and stop dust fungus and viruses from spreading back into the room air. The new vacuum cleaner also has a washable HEPA air filter that retains most of the dirt particles. The LG Kompressor will be available in two models at a cost of $US599 and $US799. Another vacuum cleaner comes from Samsung, whose Silencio SC9540 ($US200) uses silver ions in the dust bin, pre-motor filter and post motor filter of the vacuum cleaner. According to company officials, this not only prevents the build-up of bacteria and odors but ensures that the air emitted by the exhaust is odor and bacteria free. Finally, the Germ Guardian Clean2 Hand Vac portable vacuum cleaner ($US100) also employs silver embedded into the dirt cup to fight the growth of odor-causing bacteria and mold. L G T The LG Kompressor vacuum cleaner compresses dust into ‘bricks’ which are kept in a bin until disposal. Silver in the bin prevents the growth of bacteria. Silver of Peru Exhibit Opens in Finland EverBank Offers Silver Certificates of Deposit F or investors looking for a lower-risk way to invest in silver, EverBank offers Five-Year Certificates of Deposit that are pegged to the price of silver. If the price of silver increases in value over the term of the ‘MarketSafe CD,’ investors receive their principal plus additional payment. If the price of silver drops, investors receive 100 percent of their principal upon maturity. Every six months, EverBank records the spot price of silver, and at the end of the five-year period an average of these spot prices is returned to the investor. CDs are issued on a particular date during the month. For deposits made before the deadline, money is held in the company’s high-yield MarketSafe Cash Account. There is a penalty for early withdrawals and the minimum deposit is $1,500. All accounts are FDIC insured. A gold CD is also available. For more information: www.everbank.com D E L P L ATA PAT R O N AT O n exhibition titled Silver of Peru: 2,000 Years of Art opened January at the Sinebrychoff Art Museum in Helsinki and will move to Turku later this year. Consisting of 184 silver pieces from Pre-Columbian, Viceroyalty, Republican and Contemporary Peruvian time periods, the exhibit -- mounted by the Patronato Plata del Peru in cooperation with the Peruvian Embassy in Finland and The Finnish Art Gallery –illustrates the diverse uses and functions of silver objects through time. Pre-Columbian pieces include masks, nose ornaments, bracelets, beakers, crowns and musical instruments. Even though gold was very important in pre-Columbian These objects from the Siver of Peru: 2,000 Years of Art exhibit are cultures, silver also was used for on display this year in Finland. objects with mystical-religious and symbolic meanings. The Viceroyalty and Republican periods are represented by incense pots, crowns, chalices and alms bowls, as well as utilitarian pieces and dance ornaments. During the Viceroyalty period, silver played an important role in the economy; public buildings displayed silver works and many households had silver objects. Silver also was used as currency. In the Republican era, emancipation wars set back the craft of silversmithing. However, this time period also saw the emergence of silver liturgical pieces. The Modern Peruvian era is marked by three main uses: industrial silver, often machine-made products; handcrafted silver, made in small individual and family workshops using manual tools; and silver pieces designed by college-trained artists. Thirteen prize-winning silver pieces from the Peruvian Silver Contest organized annually by Patronato Plata del Peru are offered as examples of modern Peruvian silver art. The exhibit will be in Helsinki until May 18 and then moved to Turku’s Aboa Vetus & Ars Nova for display from June 7 to August 31. P E R U A Silver Ions for Smelly Locker Rooms I f any place needs germ protection, it’s locker rooms. To help inhibit bacterial, mold, and odor build-up on locker surfaces, as well as stop the touch transfer of microbes on locker handles and doors, Lyon Workspace Products of Montgomery, Illinois, has introduced silver-based antimicrobial lockers. The lockers are finished in a silver-ion coating technology from DuPont and Agion that has been approved for medical devices and food contact applications. The silver-ion technology is well suited for locker rooms because of the high moisture content in the air and on clothing. Moisture triggers the controlled release of the silver ions. Silver in Silk Would Allow Longer Storage Periods in Humid Climates cientists at the Indian Institute of Technology in New Delhi have developed a method to create anti-microbial silk by infusing the delicate material with silver ions, according to the April 2008 Journal of Applied Polymer Science. This marks the first time that silver ions have been embedded into woven silk, although it has been successfully applied to cotton and synthetic textiles. The researchers produced silver particles through a chemical method that reduced silver nitrate with agents such as hydrazine and glucose. The particles were applied to silk and showed 100 percent effectiveness against bacteria including Staphylococcus aureus. “Silver nanoparticles have been known for anti-microbial activity, but silk treated with this material is not a commercial product yet,” Manisha Mathur, a senior scientist with the Synthetic and Art Silk Mills Research Association, told The (Calcutta) Times. “It might add value to the silk, but it will raise the cost, too.” The higher cost may be mitigated by allowing silk stored in high humid environments to resist microbe growth which ruins the fabric. Silk fabrics have a tendency to attract germs when stored for long periods of time. Indian scientists are not the only ones attempting to use silver as an antibacterial agent in silk. In November, scientists at Inha University in South Korea said they had introduced silver particles into non-woven silk for possible use as medical dressings. One aesthetic challenge facing researchers is a slight creamy color that silver brings to silk, which would make the treated silk better suited to colored fabrics rather than white. W W W. S A R I . O R G S Silk stored in humid climates can harbor germs and bacteria which ruin the fabric. Researchers are studying how to imbed silver in woven silk to increase the material storage life. US Food and Drug Administration Okays First Silver-Coated Breathing Tube Officials Say Silver Tube Prevents Pneumonia and Other Diseases T he US Food and Drug Administration in November cleared for marketing a breathing tube coated with a thin layer of silver designed to reduce the risk that patients on ventilators will acquire pneumonia while in the hospital. The Agento endotracheal tube, manufactured by C.R. Bard Inc. in Murray Hill, New Jersey, is intended for patients who must rely on a ventilator to breathe for 24 hours or more. According to FDA officials, patients requiring such a breathing support system are at risk of exposure to hospital-acquired bacteria that can build up on the breathing tube or pass through the tube to their lungs, eventually causing a lung infection known as ventilator-associated pneumonia (VAP). Fifteen percent of patients on ventilators develop VAP every year and 26,000 die from the infection, according to the Centers for Disease Control and Prevention. "Patients who require ventilator support are at increased risk for pneumonia, which poses a significant public health issue. This product can help to lower this risk," said Daniel Schultz, M.D., director of FDA's Center for Devices and Radiological Health. Although silver-coated catheters have been used for several years, this is the first endotracheal tube coated with silver, Schultz said. He noted that in a multicenter clinical trial comparing the Agento breathing tube to an uncoated tube, the percentage of patients who developed pneumonia was reduced from 7.5 percent to 4.8 percent. The Agento tube also delayed the onset of pneumonia. C.R. Bard is a developer, manufacturer and marketer of medical technologies in vascular medicine, urology, oncology and surgical specialty products. For Future Reference Silver Prices 1979-2007 2008 High Low Average Jan 16.95 15.17 16.05 2007 High Low Average Dec Nov Oct Sep Aug July June May Apr Mar Feb Jan 14.8 15.5 14.38 13.79 13.12 13.36 13.76 13.53 14.06 13.53 14.69 13.51 13.83 13.96 13.25 12.19 11.47 12.47 12.21 12.81 13.29 12.64 13.33 12.13 14.37 14.66 13.57 12.91 12.28 12.93 13.09 13.15 13.74 13.11 13.95 12.83 2006 High Low Average Dec Nov Oct Sep Aug July June May Apr Mar Feb Jan 14.06 14.06 12.21 13.07 12.90 11.51 12.25 14.85 14.50 11.62 9.84 9.85 12.36 13.72 10.71 10.76 11.85 10.46 9.60 12.28 11.67 9.71 9.10 8.82 13.23 13.83 11.59 11.56 12.22 11.16 10.69 13.44 12.63 10.40 9.52 9.18 Year High Low Average 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 1993 1992 1991 1990 1989 1988 1987 1986 1985 1984 1983 1982 1981 1980 1979 14.85 8.82 9.00 6.43 8.21 5.51 5.98 4.35 5.11 4.22 4.81 4.03 5.55 4.56 5.76 4.87 7.26 4.62 6.34 4.16 5.82 4.68 6.10 4.38 5.78 4.57 5.44 3.52 4.32 3.63 4.55 3.51 5.35 3.94 6.20 5.02 8.06 6.01 11.25 5.35 6.32 4.85 6.89 5.48 10.17 6.25 14.74 8.38 11.30 4.81 16.53 7.97 50.35 10.20 35.00 5.93 11.62 7.32 6.67 4.89 4.60 4.36 4.97 5.22 5.51 4.88 5.18 5.19 5.28 4.30 3.94 4.03 4.82 5.47 6.53 6.99 5.49 6.14 8.15 11.46 7.93 10.53 20.66 11.20 (COMEX settle) The Silver Institute El Instituto de la Plata INCORPORATED 1971 A WORLDWIDE ASSOCIATION OF SILVER MINERS, REFINERS, FABRICATORS AND MANUFACTURERS 1200 G Street, NW, Suite 800, Washington, DC 20005 Telephone (202) 835-0185; Fax (202) 835-0155 www.silverinstitute.org Editor, Larry Kahaner