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IGCSE SCIENCEBLAD.indd 2 To order see full details on the back page www.hoddereducation.com/igcse 08/05/2014 09:08 IGCSE SCIENCEBLAD.indd 3 08/05/2014 09:08 Contents Acknowledgementsviii Introductionx 1 Characteristics and classification of living organisms Characteristics of living organisms Concept and use of a classification system Features of organisms Dichotomous keys 2 Organisation of the organism Cell structure and organisation Levels of organisation Size of specimens 3 Movement in and out of cells 1 1 2 6 21 23 25 27 30 33 Diffusion36 Osmosis38 Active transport 42 4 Biological molecules Biological molecules 5Enzymes 45 47 52 Enzymes52 6 Plant nutrition 57 Photosynthesis60 Leaf structure 62 66 Mineral requirements 7 Human nutrition 70 Diet72 Alimentary canal 74 Mechanical and physical digestion 77 Chemical digestion 80 Absorption82 8 Transport in plants 85 Transport in plants 86 Water uptake 87 Transpiration90 Translocation92 v 9781444176469_IGCSE_Biology.indd 5 30/04/14 10:51 PM 9 Transport in animals 95 Circulatory system 95 Heart100 Blood and lymphatic vessels 101 Blood103 10 Diseases and immunity 105 Pathogens and transmission Defences against diseases 110 113 11 Gas exchange in humans Gas exchange in humans 12Respiration 118 118 130 Respiration132 Aerobic respiration 140 Anaerobic respiration 146 13 Excretion in humans 151 Excretion153 14 Co-ordination and response 162 Nervous system in humans 166 Sense organs 170 173 Hormones in humans Homeostasis176 180 Tropic responses 15Drugs 183 Drugs185 Medicinal drugs 190 194 Misused drugs 16Reproduction Asexual reproduction Sexual reproduction Sexual reproduction in plants Sexual reproduction in humans Sex hormones in humans Methods of birth control in humans Sexually transmitted infections (STIs) 17Inheritance 199 202 207 213 216 220 223 225 232 Inheritance240 Chromosomes, genes and proteins 243 Mitosis246 Meiosis250 Monohybrid inheritance 259 vi 9781444176469_IGCSE_Biology.indd 6 30/04/14 10:51 PM 18 Variation and selection 270 Variation275 Adaptive features 285 Selection290 19 Organisms and their environment Energy flow Food chains and food webs Nutrient cycles Population size 20 Biotechnology and genetic engineering 300 304 309 315 320 330 Biotechnology and genetic engineering 334 Biotechnology338 Genetic engineering 342 21 Human influences on ecosystems 351 Food supply 353 Habitat destruction 359 Pollution344 Conservation350 Index361 vii 9781444176469_IGCSE_Biology.indd 7 30/04/14 10:51 PM 1 Characteristics and classification of living organisms Characteristics of living organisms Listing and describing the characteristics of living organisms The basic features of plants and animals The main features of groups in the animal kingdom Concept and use of a classification system How organisms are classified, using common features Defining species Using the binomial system of naming species Dichotomous keys Use of keys based on easily identifiable features Construction of dichotomous keys Features of organisms Identifying the main features of cells ●● Characteristics of living organisms Key definitions Movement is an action by an organism causing a change of position or place (see Chapter 14). Respiration describes the chemical reactions in cells that break down nutrient molecules and release energy (see Chapter 12). Sensitivity is the ability to detect and respond to changes in the environment (see Chapter 14). Growth is a permanent increase in size (see Chapter 16). Reproduction is the processes that make more of the same kind of organism (see Chapter 16). Single-celled organisms and bacteria may simply keep dividing into two. Multicellular plants and animals may reproduce sexually or asexually. Excretion is the removal from organisms of toxic materials and substances in excess of requirements (see Chapter 13). Nutrition is the taking in of materials for energy, growth and development (see Chapters 6 and 7). All living organisms, whether they are singlecelled or multicellular, plants or animals, show the characteristics included in the definitions above: movement, respiration, sensitivity, growth, reproduction, excretion and nutrition. One way of remembering this list of the characteristics of living things is by using the mnemonic MRS GREN. The letters stand for the first letters of the characteristics. Mnemonics work by helping to make the material you are learning more meaningful. They give a structure which is easier to recall later. This structure may be a word, or a name (such as MRS GREN) or a phrase. For example, ‘Richard of York gave battle in vain’ is a popular way of remembering the colours of the rainbow in the correct sequence. The five-kingdom classification scheme The main features of groups in the plant kingdom The main features of viruses Key definitions If you are studying the extended syllabus you need to learn more detailed definitions of some of the characteristics of living things. Movement is an action by an organism or part of an organism causing a change of position or place. Most single-celled creatures and animals move about as a whole. Fungi and plants may make movements with parts of their bodies (see Chapter 14). Respiration describes the chemical reactions in cells that break down nutrient molecules and release energy for metabolism. Most organisms need oxygen for this (see Chapter 12). Sensitivity is the ability to detect or sense stimuli in the internal or external environment and to make appropriate responses (see Chapter 14). Growth is a permanent increase in size and dry mass by an increase in cell number or cell size or both (see Chapter 16). Even bacteria and single-celled creatures show an increase in size. Multicellular organisms increase the numbers of cells in their bodies, become more complicated and change their shape as well as increasing in size (see ‘Sexual reproduction in humans’ in Chapter 16). Excretion is the removal from organisms of the waste products of metabolism (chemical reactions in cells including respiration), toxic materials and substances in excess of requirements (see Chapter 13). Respiration and other chemical changes in the cells produce waste products such as carbon dioxide. Living organisms expel these substances from their bodies in various ways (see Chapter 13). Nutrition is the taking in of materials for energy, growth and development. Plants require light, carbon dioxide, water and ions. Animals need organic compounds and ions and usually need water (see Chapters 6 and 7). Organisms can take in the materials they need as solid food, as animals do, or they can digest them first and then absorb them, like fungi do, or they can build them up for themselves, like plants do. Animals, using readymade organic molecules as their food source, are called heterotrophs and form the consumer levels of food chains. Photosynthetic plants are called autotrophs and are usually the first organisms in food chains (see Chapters 6 and 19). 1 9781444176469_IGCSE_Biology.indd 1 30/04/14 10:51 PM Concept and use of a classification system The use of DNA has revolutionised the process of classification. Eukaryotic organisms contain chromosomes made up of strings of genes. The chemical which forms these genes is called DNA (which is short for deoxyribonucleic acid). The DNA is made up of a sequence of bases, coding for amino acids and, therefore, proteins (see Chapters 4 and 17). Each species has a distinct number of chromosomes and a unique sequence of bases in its DNA, making it identifiable and distinguishable from other species. This helps particularly when different species are very similar morphologically (in appearance) and anatomically (in internal structure). The process of biological classification called cladistics involves organisms being grouped together according to whether or not they have one or more shared unique characteristics derived from the group’s last common ancestor, which are not present in more distant ancestors. Organisms which share a more recent ancestor (and are, therefore, more closely Orang-utan 48 chromosomes Gorilla 48 chromosomes related) have DNA base sequences that are more similar than those that share only a distant ancestor. Human and primate evolution is a good example of how DNA has been used to clarify a process of evolution. Traditional classification of primates (into monkeys, apes and humans) was based on their anatomy, particularly their bones and teeth. This put humans on a separate branch, while grouping the other apes together into one family called Pongidae. However, genetic evidence using DNA provides a different insight – humans are more closely related to chimpanzees (1.2% difference in the genome – the complete set of genetic material of the organism) and gorillas (1.6% different) than to orang-utans (3.1% different). Also, chimpanzees are closer to humans than to gorillas (see Figure 1.6). Bonobos and chimps are found in Zaire and were only identified as different species in 1929. The two species share the same percentage difference in the genome from humans. Chimpanzee 48 chromosomes Bonobo 48 chromosomes Human 46 chromosomes 0 1 2 common ancestor, now extinct time/millions of years ago 3 4 5 6 common ancestor, now extinct 7 8 9 common ancestor, now extinct 10 11 12 13 common ancestor, now extinct 14 15 Figure 1.6 Classification of primates, based on DNA evidence 5 9781444176469_IGCSE_Biology.indd 5 30/04/14 10:51 PM Features of organisms The animal kingdom Animals are multicellular organisms whose cells have no cell walls or chloroplasts. Most animals ingest solid food and digest it internally. Animal kingdom (Only 8 groups out of 23 are listed here.) * Coelenterates (sea anemones, jellyfish) Flatworms Nematode worms Annelids (segmented worms) Arthropods CLASS Crustacea (crabs, shrimps, water fleas) Insects Arachnids (spiders and mites) Myriapods (centipedes and millipedes) Molluscs (snails, slugs, mussels, octopuses) Echinoderms (starfish, sea urchins) Vertebrates CLASS Fish Amphibia (frogs, toads, newts) Reptiles (lizards, snakes, turtles) Birds Mammals (Only 4 subgroups out of about 26 are listed.) Insectivores Carnivores Rodents Primates *All the organisms which do not have a vertebral column are often referred to as ­invertebrates. Invertebrates are not a natural group, but the term is convenient to use. Arthropods The arthropods include the crustacea, insects, centipedes and spiders (see Figure 1.8 on page 10). The name arthropod means ‘jointed limbs’, and this is a feature common to them all. They also have a hard, firm external skeleton, called a cuticle, which encloses their bodies. Their bodies are segmented and, between the segments, there are flexible joints which permit movement. In most arthropods, the segments are grouped together to form distinct regions, the head, thorax and abdomen. Table 1.1 outlines the key features of the four classes of arthropod. Crustacea Marine crustacea are crabs, prawns, lobsters, shrimps and barnacles. Freshwater crustacea are water fleas, Cyclops, the freshwater shrimp (Gammarus) and the water louse (Asellus). Woodlice are land-dwelling crustacea. Some of these crustacea are illustrated in Figure 1.8 on page 10. Like all arthropods, crustacea have an exoskeleton and jointed legs. They also have two pairs of antennae which are sensitive to touch and to chemicals, and they have compound eyes. Compound eyes are made up of tens or hundreds of separate lenses with light-sensitive cells beneath. They are able to form a crude image and are very sensitive to movement. Typically, crustacea have a pair of jointed limbs on each segment of the body, but those on the head segments are modified to form antennae or specialised mouth parts for feeding (see Figure 1.12). second antenna segmented abdomen thorax compound eye first antenna claw walking legs Figure 1.12 External features of a crustacean (lobster × 0.2) Insects The insects form a very large class of arthropods. Bees, butterflies, mosquitoes, houseflies, earwigs, greenfly and beetles are just a few of the subgroups in this class. Insects have segmented bodies with a firm exoskeleton, three pairs of jointed legs, compound eyes and, typically, two pairs of wings. The segments are grouped into distinct head, thorax and abdomen regions (see Figure 1.13). 11 9781444176469_IGCSE_Biology.indd 11 30/04/14 10:51 PM 1 Characteristics and classification of living organisms compound eye thorax are used in reproduction; the chelicerae are used to pierce their prey and paralyse it with a poison secreted by a gland at the base. There are usually several pairs of simple eyes. 1 pair antennae head pedipalp wing abdomen (segmented) 3 pairs of legs position of chelicerae cephalothorax poison sac chelicera (poison fang) held on underside of cephalothorax Figure 1.13 External features of an insect (greenbottle, × 5). Flies, midges and mosquitoes have only one pair of wings. Insects differ from crustacea in having wings, only one pair of antennae and only three pairs of legs. There are no limbs on the abdominal segments. The insects have very successfully colonised the land. One reason for their success is the relative impermeability of their cuticles, which prevents desiccation even in very hot, dry climates. Arachnids These are the spiders, scorpions, mites and ticks. Their bodies are divided into two regions, the cephalothorax and the abdomen (see Figure 1.14). They have four pairs of limbs on the cephalothorax, two pedipalps and two chelicerae. The pedipalps abdomen Figure 1.14 External features of an arachnid (× 2.5) Myriapods These are millipedes and centipedes. They have a head and a segmented body which is not obviously divided into thorax and abdomen. There is a pair of legs on each body segment but in the millipede the abdominal segments are fused in pairs and it looks as if it has two pairs of legs per segment (see Figure 1.15). As the myriapod grows, additional segments are formed. The myriapods have one pair of antennae and simple eyes. Centipedes are carnivorous; millipedes feed on vegetable matter. up to 70 abdominal segments fused in pairs } thorax (4 segments) 2 pairs of legs on each paired abdominal segment 1 pair of legs on each thoracic segment antenna simple eye head Figure 1.15 External features of a myriapod (× 2.5) Table 1.1 Key features of the four classes of arthropods Insects e.g. dragonfly, wasp • three pairs of legs Arachnids e.g. spider, mite • four pairs of legs • body divided into head, thorax • body divided into and abdomen cephalothorax and abdomen • one pair of antennae • one pair of compound eyes • several pairs of simple eyes • usually have two pairs of • chelicerae for biting and wings poisoning prey Crustacea e.g. crab, woodlouse • five or more pairs of legs • body divided into cephalothorax and abdomen • two pairs of antennae • one pair of compound eyes • exoskeleton often calcified to form a carapace (hard) Myriapods e.g. centipede, millipede • ten or more pairs of legs (usually one pair per segment) • body not obviously divided into thorax and abdomen • one pair of antennae • simple eyes 12 9781444176469_IGCSE_Biology.indd 12 30/04/14 10:51 PM IGCSE SCIENCEBLAD.indd 4 08/05/2014 09:08 Contents Acknowledgementsix Preface to the reader xi Chapter 1 The particulate nature of matter 1 Solids, liquids and gases 2 The kinetic theory of matter 2 Changes of state 4 6 Diffusion – evidence for moving particles Checklist8 Additional questions 9 Chapter 2 Elements, compounds and experimental techniques 10 Elements10 Compounds13 Mixtures16 Separating mixtures 17 25 Accuracy in experimental work in the laboratory Gels, sols, foams and emulsions 26 Mixtures for strength 28 Checklist29 Additional questions 31 Chapter 3 Atomic structure and bonding 33 Inside atoms 33 The arrangement of electrons in atoms 37 38 Ionic bonding Covalent bonding 45 54 Glasses and ceramics Metallic bonding 55 Checklist56 58 Additional questions Chapter 4 Stoichiometry – chemical calculations 59 Relative atomic mass 59 Reacting masses 59 Calculating moles 61 Calculating formulae 64 Moles and chemical equations 66 Checklist69 Additional questions 71 9781444176445.indb 5 15/03/14 5:05 PM Chapter 5 Electricity and chemistry 72 Electrolysis of lead(ii) bromide 73 Electrolysis of aluminium oxide 74 Electrolysis of aqueous solutions 77 80 Electrolysis of concentrated hydrochloric acid 80 Electrolysis of copper(ii) sulfate solution Electrolysis guidelines 83 Electroplating83 Checklist85 Additional questions 86 Chapter 6 Chemical energetics 88 Substances from oil 88 Fossil fuels 90 What is a fuel? 92 93 Alternative sources of energy Chemical energy 95 Changes of state 97 Cells and batteries 98 Checklist100 Additional questions 101 Chapter 7 Chemical reactions 104 Factors that affect the rate of a reaction 105 Enzymes111 Checklist114 Additional questions 115 Chapter 8 Acids, bases and salts 117 Acids and alkalis 117 Formation of salts 122 127 Crystal hydrates Solubility of salts in water 129 Titration129 Checklist132 Additional questions 133 Chapter 9 The Periodic Table 135 Development of the Periodic Table 135 Electronic structure and the Periodic Table 138 Group I – the alkali metals 138 Group II – the alkaline earth metals 140 Group VII – the halogens 141 Group 0 – the noble gases 143 Transition elements 144 The position of hydrogen 146 Checklist146 Additional questions 147 9781444176445.indb 6 15/03/14 5:05 PM Chapter 10Metals 149 Metal reactions 150 Decomposition of metal nitrates, carbonates, oxides and hydroxides 152 Reactivity of metals and their uses 153 155 Identifying metal ions Discovery of metals and their extraction 157 Metal waste 161 Rusting of iron 161 Alloys165 Checklist168 Additional questions 169 Chapter 11 Air and water 171 The air 171 How do we get the useful gases we need from the air? 174 Ammonia – an important nitrogen-containing chemical 176 180 Artificial fertilisers Atmospheric pollution 182 Water184 The water cycle 186 187 Hardness in water Water pollution and treatment 190 Checklist193 Additional questions 194 Chapter 12Sulfur 197 Sulfur – the element 197 Sulfur dioxide 198 199 Sulfuric acid Checklist203 204 Additional questions Chapter 13 Inorganic carbon chemistry 206 Limestone206 Carbonates211 Carbon dioxide 212 Checklist215 Additional questions 216 Chapter 14 Organic chemistry 1 218 Alkanes218 The chemical behaviour of alkanes 220 Alkenes222 The chemical behaviour of alkenes 224 226 A special addition reaction of alkene molecules Checklist230 Additional questions 231 9781444176445.indb 7 15/03/14 5:05 PM Chapter 15 Organic chemistry 2 233 Alcohols (R—OH) 233 Biotechnology236 Carboxylic acids 237 239 Soaps and detergents Condensation polymers 241 Some biopolymers 242 Pharmaceuticals246 Checklist247 Additional questions 249 Chapter 16 Experimental chemistry Objectives for experimental skills and investigations Suggestions for practical work and assessment Notes on qualitative analysis Revision and exam-style questions 251 251 251 261 264 Alternative to practical paper 264 Theory275 The Periodic Table of the elements 294 Index295 9781444176445.indb 8 15/03/14 5:05 PM Preface to the reader This textbook has been written to help you in your study of chemistry to Cambridge IGCSE. The different chapters in this book are split up into short topics. At the end of many of these topics are questions to test whether you have understood what you have read. At the end of each chapter there are larger study questions. Try to answer as many of the questions as you can as you come across them because asking and answering questions is at the heart of your study of chemistry. Some questions selected from the Cambridge IGCSE examination papers are included at the end of the book. In many cases they are designed to test your ability to apply your chemical knowledge. The questions may provide certain facts and ask you to make an interpretation of them. In such cases, the factual information may not be covered in the text. To help draw attention to the more important words, scientific terms are printed in bold the first time they are used. There are also checklists at the end of each chapter summarising the important points covered. As you read through the book, you will notice three sorts of shaded area in the text. You will see from the box at the foot of this page that the book is divided into four different areas of chemistry: Starter, Physical, Inorganic and organic chemistry. We feel, however, that some topics lead naturally on to other topics not in the same area. So you can, of course, read and study the chapters in your own preferred order and the colour coding will help you with this. The accompanying Revision CD-ROM provides invaluable exam preparation and practice. We want to test your knowledge with interactive multiple choice, mix and match, and true or false questions that cover both the Core and Extended curriculum. These are organised by syllabus topic. Together, the textbook and CD-ROM will provide you with the information you need for the Cambridge IGCSE syllabus. We hope you enjoy using them. Bryan Earl and Doug Wilford Material highlighted in green is for the Cambridge IGCSE Extended curriculum. Areas highlighted in yellow contain material that is not part of the Cambridge IGCSE syllabus. It is extension work and will not be examined. Questions are highlighted by a box like this. We use different colours to define different areas of chemistry: ‘starter’ chapters – basic principles physical chemistry inorganic chemistry organic chemistry and the living world. 9781444176445_FM.indd 11 30/04/14 10:49 PM 11 Air and water ●● Water pollution and treatment An adequate supply of water is essential to the health and well-being of the world’s population. Across the planet, biological and chemical pollutants are affecting the quality of our water. An adequate supply of fresh drinking water is needed for everyone on the planet. Lack of availability of fresh water leads to waterborne diseases, such as cholera and typhoid, and to diarrhoea, which is one of the biggest killers across the world. Agriculture needs a water supply in order to irrigate crops, especially in areas of the world with hot climates. The production of more and more crops for the ever-increasing population is essential. Water is very good at dissolving substances. Thus, it is very unusual to find really pure water on this planet. As water falls through the atmosphere, on to and then through the surface of the Earth, it dissolves a tremendous variety of substances. Chemical fertilisers washed off surrounding land will add nitrate ions (NO3−) and phosphate ions (PO43−) to the water, owing to the use of artificial fertilisers such as ammonium nitrate and ammonium phosphate. The nitrates encourage the growth of algae which eventually die and decay, removing oxygen from the water. It may also contain human waste as well as insoluble impurities such as grit and bacteria, and oil and lead ‘dust’ (to a decreasing extent) from the exhaust fumes of lorries and cars (Figure 11.37). Figure 11.37 A badly polluted river. All these artificial, as well as natural, impurities must be removed from the water before it can be used. Recent regulations in many countries have imposed strict guidelines on the amounts of various substances allowed in drinking water. Figure 11.38 This lake is used as a source of drinking water. A lot of drinking water is obtained from lakes and rivers where the pollution levels are low (Figure 11.38). Undesirable materials removed from water include: colloidal clay (clay particles in the water) ●● bacteria ●● chemicals which cause the water to be coloured and foul tasting ●● acids, which are neutralised. ●● Making water fit to drink The treatment needed to make water fit to drink depends on the source of the water. Some sources, for example mountain streams, may be almost pure and boiling may be enough to kill any microorganisms present. However, others, such as slowflowing rivers, may be contaminated. The object of treating contaminated water is to remove all microorganisms that may cause disease. The process of water treatment involves both filtration and chlorination and is summarised in Figure 11.39. 1Impure water is passed through screens to filter out floating debris. 2 Aluminium sulfate is added to coagulate small particles of clay so that they form larger clumps, which settle more rapidly. 3 Filtration through coarse sand traps larger, insoluble particles. The sand also contains specially grown microbes which remove some of the bacteria. 4 A sedimentation tank has chemicals known as flocculants, for example aluminium sulfate, added to it to make the smaller particles (which remain in the water as colloidal clay) stick together and sink to the bottom of the tank. 5These particles are removed by further filtration through fine sand. Sometimes a carbon slurry is used to remove unwanted tastes and odours, and a lime slurry is used to adjust the acidity. 190 9781444176445_Ch11.indd 190 30/04/14 10:47 PM Water pollution and treatment 1 water passed through screen covered storage tank 2 aluminium sulfate added water in pump sulfur dioxide added screen 3 coarse sand filter 4 sedimentation tank 5 fine sand filter 6 chlorine added pump sodium hydroxide added to homes and factories Figure 11.39 The processes involved in water treatment. 6 Finally, a little chlorine gas is added, which sterilises the water and kills any remaining bacteria. Excess chlorine can be removed by the addition of sulfur dioxide gas. The addition of chlorine gas makes the water more acidic and so appropriate amounts of sodium hydroxide solution are added. Fluoride is sometimes added to water if there is insufficient occurring naturally, as it helps to prevent tooth decay. Sewage treatment After we have used water, it must be treated again before it can be returned to rivers, lakes and seas. This multi-stage process known as sewage treatment is shown in Figure 11.41. sewage 1 screens 2 settlement tank The ‘iron problem’ If the acidity level of the treated water is not controlled, problems occur due to the precipitation of iron(iii) hydroxide. These include: vegetables turning brown tea having an inky appearance and a bitter taste ●● clothes showing rusty stains after washing (Figure 11.40). ●● ●● 5 sludge (for either dumping or conversion to fertiliser) and methane gas 3 trickling filter gravel 4 treated water is chlorinated and returned to the river Figure 11.41 The processes involved in sewage treatment. Used water, sewage, contains waste products such as human waste and washing-up debris as well as everything else that we put down a drain or sink. The processes that are involved in its treatment are as follows. Figure 11.40 The rusty stains on this pillowcase are due to iron (III) compounds in the water. 1 Large screens remove large pieces of rubbish. 2 Sand and grit are separated in large sedimentation tanks. The process is speeded up by adding aluminium sulfate, which helps the solids to 191 9781444176445_Ch11.indd 191 30/04/14 10:47 PM IGCSE SCIENCEBLAD.indd 5 08/05/2014 09:08 Contents Prefacevii Physics and technology viii Scientific enquiry x Section 1 General physics Measurements and motion 1Measurements 2 Speed, velocity and acceleration 3 Graphs of equations 4 Falling bodies 5Density Forces and momentum 6 Weight and stretching 7 Adding forces 8 Force and acceleration 9 Circular motion 10 Moments and levers 11 Centres of mass 12Momentum Energy, work, power and pressure 13 Energy transfer 14 Kinetic and potential energy 15 Energy sources 16 Pressure and liquid pressure 2 9 13 17 21 24 27 30 35 39 43 47 50 56 60 66 Section 2 Thermal physics Simple kinetic molecular model of matter 17Molecules 18 The gas laws Thermal properties and temperature 19 Expansion of solids, liquids and gases 20Thermometers 21 Specific heat capacity 22 Specific latent heat Thermal processes 23 Conduction and convection 24Radiation 72 76 81 85 88 91 97 102 v 9781444176421_FM_00.indd 5 30/04/14 11:02 PM Section 3 Properties of waves General wave properties 25 Mechanical waves Light 26 Light rays 27 Reflection of light 28 Plane mirrors 29 Refraction of light 30 Total internal reflection 31Lenses 32 Electromagnetic radiation Sound 33 Sound waves 106 113 116 119 122 126 129 135 140 Section 4 Electricity and magnetism Simple phenomena of magnetism 34 Magnetic fields Electrical quantities and circuits 35 Static electricity 36 Electric current 37 Potential difference 38Resistance 39Capacitors 40 Electric power 41 Electronic systems 42 Digital electronics Electromagnetic effects 43Generators 44Transformers 45Electromagnets 46 Electric motors 47 Electric meters 48Electrons 146 150 157 162 167 174 177 185 193 199 204 209 215 219 222 Section 5 Atomic physics 49Radioactivity 50 Atomic structure Revision questions Cambridge IGCSE exam questions Mathematics for physics Further experimental investigations Practical test questions Alternative to practical test questions 230 238 245 251 279 282 283 291 Answers299 Index307 Photo acknowledgements 312 vi 9781444176421_FM_00.indd 6 5/2/14 5:53 PM 12 ● ● ● ● Momentum Conservation of momentum Explosions Rockets and jets Force and momentum ● Momentum is a useful quantity to consider when bodies are involved in collisions and explosions. It is defined as the mass of the body multiplied by its velocity and is measured in kilogram metre per second (kg m/s) or newton second (N s). momentum = mass × velocity A 2 kg mass moving at 10 m/s has momentum 20 kg m/s, the same as the momentum of a 5 kg mass moving at 4 m/s. Repeat the experiment with another trolley stacked on top of the one to be pushed so that two are moving before the collision and three after. Copy and complete the tables of results. Before collision (m2 at rest) Mass m1 (no. of trolleys) Velocity v/m/s Momentum m1v 1 2 After collision (m1 and m2 together) Practical work Mass m1 + m2 (no. of trolleys) Collisions and momentum photogate 2 sloping runway Velocity v1/m/s Momentum (m1 + m2)v1 2 Figure 12.1 shows an arrangement which can be used to find the velocity of a trolley before and after a collision. If a trolley of length l takes time t to pass through a photogate, its velocity = distance/time = l/t. Two photogates are needed, placed each side of the collision point, to find the velocities before and after the collision. Set them up so that they will record the time taken for the passage of a trolley. trolley with ‘interrupt card’ photogate 1 Sport: impulse and collision time Practical work: Collisions and momentum ● to timer Figure 12.1 Do the results suggest any connection between the momentum before the collision and after it in each case? ● Conservation of momentum When two or more bodies act on one another, as in a collision, the total momentum of the bodies remains constant, provided no external forces act (e.g. friction). This statement is called the principle of conservation of momentum. Experiments like those in the Practical Work Section show that it is true for all types of collisions. As an example, suppose a truck of mass 60 kg moving with velocity 3 m/s collides and couples with a stationary truck of mass 30 kg (Figure 12.2a). The two move off together with the same velocity v which we can find as follows (Figure 12.2b). Total momentum before is (60 kg × 3 m/s) + (30 kg × 0 m/s) = 180 kg m/s ▲ ▲ A tickertape timer or motion sensor, placed at the top end of the runway, could be used instead of the photogates if preferred. Attach a strip of Velcro to each trolley so that they ‘stick’ to each other on collision and compensate the runway for friction (see Chapter 17). Place one trolley at rest halfway down the runway and another at the top; give the top trolley a push. It will move forwards with uniform velocity and should hit the second trolley so that they travel on as one. Using the times recorded by the photogate timer, calculate the velocity of the moving trolley before the collision and the common velocity of both trolleys after the collision. 3 47 9781444176421_Section_01.indd 47 5/2/14 4:17 PM 12 MOMENTUM Total momentum after is (60 kg + 30 kg) × v = 90 kg × v Since momentum is not lost 90 kg × v = 180 kg m/s or v = 2 m/s 3m /s 60 kg v at rest 30 kg a Before 60 kg air balloon 30 kg b After Figure 12.2 ● Explosions Momentum, like velocity, is a vector since it has both magnitude and direction. Vectors cannot be added by ordinary addition unless they act in the same direction. If they act in exactly opposite directions, such as east and west, the smaller subtracts from the greater, or if the same they cancel out. Momentum is conserved in an explosion such as occurs when a rifle is fired. Before firing, the total momentum is zero since both rifle and bullet are at rest. During the firing the rifle and bullet receive equal but opposite amounts of momentum so that the total momentum after firing is zero. For example, if a rifle fires a bullet of mass 0.01 kg with a velocity of 300 m/s, forward momentum of bullet = 0.01 kg × 300 m/s = 3 kg m/s ∴ by burning fuel and leaves the exhaust with large momentum. The rocket or jet engine itself acquires an equal forward momentum. Space rockets carry their own oxygen supply; jet engines use the surrounding air. backward momentum of rifle = 3 kg m/s If the rifle has mass m, it recoils (kicks back) with a velocity v such that mv = 3 kg m/s Taking m = 6 kg gives v = 3/6 m/s = 0.5 m/s. ● Rockets and jets If you release an inflated balloon with its neck open, it flies off in the opposite direction to that of the escaping air. In Figure 12.3 the air has momentum to the left and the balloon moves to the right with equal momentum. This is the principle of rockets and jet engines. In both, a high-velocity stream of hot gas is produced Figure 12.3 A deflating balloon demonstrates the principle of a rocket or a jet engine. ● Force and momentum If a steady force F acting on a body of mass m increases its velocity from u to v in time t, the acceleration a is given by a = (v − u)/t (from v = u + at) Substituting for a in F = ma, F = m (v − u ) mv − mu = t t Therefore force = change of momentum = rate of change of time momentum This is another version of Newton’s second law. For some problems it is more useful than F = ma. We also have Ft = mv − mu where mv is the final momentum, mu the initial momentum and Ft is called the impulse. ● Sport: impulse and collision time The good cricketer or tennis player ‘follows through’ with the bat or racket when striking the ball (Figure 12.4a). The force applied then acts for a longer time, the impulse is greater and so also is the gain of momentum (and velocity) of the ball. When we want to stop a moving ball such as a cricket ball, however, its momentum has to be 48 9781444176421_Section_01.indd 48 5/2/14 4:17 PM Sport: impulse and collision time reduced to zero. An impulse is then required in the form of an opposing force acting for a certain time. While any number of combinations of force and time will give a particular impulse, the ‘sting’ can be removed from the catch by drawing back the hands as the ball is caught (Figure 12.4b). A smaller average force is then applied for a longer time. Figure 12.5 Sand reduces the athlete’s momentum more gently. Questions Figure 12.4a Batsman ‘following through’ after hitting the ball Figure 12.4b Cricketer drawing back the hands to catch the ball The use of sand gives a softer landing for longjumpers (Figure 12.5), as a smaller stopping force is applied over a longer time. In a car crash the car’s momentum is reduced to zero in a very short time. If the time of impact can be extended by using crumple zones (see Figure 14.6, p. 58) and extensible seat belts, the average force needed to stop the car is reduced so the injury to passengers should also be less. 1 What is the momentum in kg m/s of a 10 kg truck travelling at a 5 m/s, b 20 cm/s, c 36 km/h? 2 A ball X of mass 1 kg travelling at 2 m/s has a head-on collision with an identical ball Y at rest. X stops and Y moves off. What is Y’s velocity? 3 A boy with mass 50 kg running at 5 m/s jumps on to a 20 kg trolley travelling in the same direction at 1.5 m/s. What is their common velocity? 4 A girl of mass 50 kg jumps out of a rowing boat of mass 300 kg on to the bank, with a horizontal velocity of 3 m/s. With what velocity does the boat begin to move backwards? 5 A truck of mass 500 kg moving at 4 m/s collides with another truck of mass 1500 kg moving in the same direction at 2 m/s. What is their common velocity just after the collision if they move off together? 6 The velocity of a body of mass 10 kg increases from 4 m/s to 8 m/s when a force acts on it for 2 s. a What is the momentum before the force acts? b What is the momentum after the force acts? c What is the momentum gain per second? d What is the value of the force? 7 A rocket of mass 10 000 kg uses 5.0 kg of fuel and oxygen to produce exhaust gases ejected at 5000 m/s. Calculate the increase in its velocity. Checklist After studying this chapter you should be able to • define momentum, • describe experiments to demonstrate the principle of conservation of momentum, • state and use the principle of conservation of momentum to solve problems, • understand the action of rocket and jet engines, • state the relationship between force and rate of change of momentum and use it to solve problems, • use the definition of impulse to explain how the time of impact affects the force acting in a collision. 49 9781444176421_Section_01.indd 49 5/2/14 4:17 PM Ultrasonics tuning fork (sine wave) piano transmitter receiver violin Figure 33.8 Notes of the same frequency (pitch) but different quality ultrasonic waves ●● Ultrasonics Sound waves with frequencies above 20 kHz are called ultrasonic waves; their frequency is too high to be detected by the human ear but they can be detected electronically and displayed on a CRO. a) Quartz crystal oscillators Ultrasonic waves are produced by a quartz crystal which is made to vibrate electrically at the required frequency; they are emitted in a narrow beam in the direction in which the crystal oscillates. An ultrasonic receiver also consists of a quartz crystal but it works in reverse, i.e. when it is set into vibration by ultrasonic waves it generates an electrical signal which is then amplified. The same quartz crystal can act as both a transmitter and a receiver. Figure 33.9 A ship using sonar In medical ultrasound imaging, used in antenatal clinics to monitor the health and sometimes to determine the sex of an unborn baby, an ultrasonic transmitter/receiver is scanned over the mother’s abdomen and a detailed image of the fetus is built up (Figure 33.10). Reflection of the ultrasonic pulses occurs from boundaries of soft tissue, in addition to bone, so images can be obtained of internal organs that cannot be seen by using X-rays. Less detail of bone structure is seen than with X-rays, as the wavelength of ultrasonic waves is larger, typically about 1 mm, but ultrasound has no harmful effects on human tissue. b) Ultrasonic echo techniques Ultrasonic waves are partially or totally reflected from surfaces at which the density of the medium changes; this property is exploited in techniques such as the non-destructive testing of materials, sonar and medical ultrasound imaging. A bat emitting ultrasonic waves can judge the distance of an object from the time taken by the reflected wave or ‘echo’ to return. Ships with sonar can determine the depth of a shoal of fish or the sea bed (Figure 33.9), in the same way; motion sensors (Chapter 2) also work on this principle. Figure 33.10 Checking the development of a fetus using ultrasound imaging ▲ ▲ 143 9781444176421_Section_03.indd 143 30/04/14 9:27 PM 33 sound Waves c) Other uses Ultrasound can also be used in ultrasonic drills to cut holes of any shape or size in hard materials such as glass and steel. Jewellery, or more mundane objects such as street lamp covers, can be cleaned by immersion in a tank of solvent which has an ultrasonic vibrator in the base. l● Seismic waves Earthquakes produce both longitudinal waves (P-waves) and transverse waves (S-waves) that are known as seismic waves. These travel through the Earth at speeds of up to 13 000 m/s. When seismic waves pass under buildings, severe structural damage may occur. If the earthquake occurs under the sea, the seismic energy can be transmitted to the water and produce tsunami waves that may travel for very large distances across the ocean. As a tsunami wave approaches shallow coastal waters, it slows down (see Chapter 25) and its amplitude increases, which can lead to massive coastal destruction. This happened in Sri Lanka (see Figure 33.11) and Thailand after the great 2004 Sumatra–Andaman earthquake. The time of arrival of a tsunami wave can be predicted if its speed of travel and the distance from the epicentre of the earthquake are known; it took about 2 hours for tsunami waves to cross the ocean to Sri Lanka from Indonesia. A similar time was needed for the tsunami waves to travel the shorter distance to Thailand. This was because the route was through shallower water and the waves travelled more slowly. If an early-warning system had been in place, many lives could have been saved. Questions 1 If 5 seconds elapse between a lightning flash and the clap of thunder, how far away is the storm? (Speed of sound = 330 m/s.) 2 a A girl stands 160 m away from a high wall and claps her hands at a steady rate so that each clap coincides with the echo of the one before. If her clapping rate is 60 per minute, what value does this give for the speed of sound? b If she moves 40 m closer to the wall she finds the clapping rate has to be 80 per minute. What value do these measurements give for the speed of sound? c If she moves again and finds the clapping rate becomes 30 per minute, how far is she from the wall if the speed of sound is the value you found in a? 3 a What properties of sound suggest it is a wave motion? b How does a progressive transverse wave differ from a longitudinal one? Which type of wave is a sound wave? 4 a Draw the waveform of (i) a loud, low-pitched note, and (ii) a soft, high-pitched note. b If the speed of sound is 340 m/s what is the wavelength of a note of frequency (i) 340 Hz, (ii) 170 Hz? Checklist After studying this chapter you should be able to • recall that sound is produced by vibrations, • describe an experiment to show that sound is not transmitted through a vacuum, • describe how sound travels in a medium as progressive longitudinal waves, • recall the limits of audibility (i.e. the range of frequencies) for the normal human ear, • explain echoes and reverberation, • describe an experiment to measure the speed of sound in air, • solve problems using the speed of sound, e.g. distance of thundercloud, • state the order of magnitude of the speed of sound in air, liquid and solids, • relate the loudness and pitch of sound waves to amplitude and frequency. Figure 33.11 This satellite image shows the tsunami that hit the southwestern coast of Sri Lanka on 26 December 2004 as it pulled back out to sea, having caused utter devastation in coastal areas. 144 9781444176421_Section_03.indd 144 30/04/14 9:27 PM Cambridge IGCSE exam questions 1 General physics block Measurements and motion 1a (i)The two diagrams show the dimensions of a rectangular block being measured using a ruler. They are not shown full size. Use the scales shown to find the length and the width of the block, giving your answers in cm. [1] 40 50 60 grams 70 Find the density of this block. [4] [Total: 8] 140 150 160 170 180 190 200 210 220 230 240 250 millimetres 40 50 60 70 80 90 250 90 100 110 120 130 140 150 160 30 80 20 70 10 60 140 50 140 210 220 230 240 250 260 270 280 290 300 250 millimetres (ii) When the block was made, it was cut from a piece of metal 2.0 cm thick. Calculate the volume of the block. [2] b Another block has a volume of 20 cm3. The diagram shows the reading when the block is placed on a balance. (Cambridge IGCSE Physics 0625 Paper 21 Q1 November 2010) 2 An engineering machine has a piston which is going up and down approximately 75 times per minute. Describe carefully how a stopwatch may be used to find accurately the time for one up-and-down cycle of the piston. [4] [Total: 4] (Cambridge IGCSE Physics 0625 Paper 31 Q1 June 2009) 3 Imagine that you live beside a busy road. One of your neighbours thinks that many of the vehicles are travelling faster than the speed limit for the road. You decide to check this by measuring the speeds of some of the vehicles. a Which two quantities will you need to measure in order to find the speed of a vehicle, and which instruments would you use to measure them? Quantity measured Instrument used [4] b State the equation you would use to calculate the speed of the vehicle. If you use symbols, state what your symbols mean. [1] 251 9781444176421_BM_06.indd 251 30/04/14 11:02 PM Title Author ISBN Publication Date Price Student’s Book 3rd edition plus CD-ROM D. G. Mackean and Dave Hayward 9781444176469 September 2014 £20.99 Laboratory Practical Book Mike Cole 9781444191615 November 2014 £6.99 Teacher’s CD-ROM D. G. Mackean and Dave Hayward 9781444196306 December 2014 £65.00 Workbook Dave Hayward 9781471807268 November 2014 £6.00 Student’s Book 3rd edition plus CD-ROM Bryan Earl and L. D. R. Wiford 9781444176445 July 2014 Laboratory Practical Book Tim Greenway 9781444192209 November 2014 £6.99 Teacher’s CD-ROM Bryan Earl and Doug Wilford 9781444196290 December 2014 £65.00 Workbook Bryan Earl and Doug Wilford 9781471807251 November 2014 £6.00 Student’s Book 3rd edition plus CD-ROM Heather Kennett and Tom Duncan 9781444176421 June 2014 Laboratory Practical Book Heather Kennett 9781444192193 November 2014 £6.99 Teacher’s CD-ROM Heather Kennett and Tom Duncan 9781444196283 December 2014 £65.00 Workbook Heather Kennett 9781471807244 November 2014 £6.00 BIOLOGY CHEMISTRY £20.99 PHYSICS £20.99 Also Revision Guides coming soon for first examination 2016. eBooks Student eTextbooks These time-limited downloadable eTextbooks give your students the freedom to study anytime, anywhere. Assigning eTextbooks to your students enables them to download and view titles on any device or browser. Visit www.hoddereducation.com/igcse to learn more. Single copy Standard single-copy eBooks are also available through a variety of third party retailers. Email anna.russo@hodder.co.uk for details of your local supplier. For details on how to order, plus more information www.hoddereducation.com/igcse 9781471837883 IGCSE SCIENCEBLAD.indd 6 08/05/2014 09:08