pV pV pV pV θ

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Thermal Expansion, Temperature
temperature (n)
A property of an object that indicates in which direction heat energy will flow if the object is placed in
thermal contact with another object. Heat energy flows from places of higher temperature to places of
lower temperature.
Zeroth law of
thermodynamics
If two bodies X and Y are each separately in thermal equilibrium with another body Z, then they are in
thermal equilibrium with one another. In the most common case the body Z is a thermometer.
temperature scale
A sequence of values which represent temperature. Such a sequence is usually obtained by choosing
two fixed points (identified by specified properties of stated substances) between which there are
subdivisions made on a chosen basis. The Celsius scale has 99 divisions between the melting point of
pure water and the boiling point of pure water.
Celsius scale
A temperature scale for which the ice point is at 0° and the steam point is at 100°. One Celsius degree
is defined as 1/100 of the temperature interval between the ice point and the steam point.
Centigrade scale
The name formerly used for the Celsius scale. The name is not now used in International System of
Units (SI) but is often used by meteorologists.
Fahrenheit scale
A temperature scale for which the ice point is at 32°F and the steam point at 212°F. Originally the
zero was obtained in a freezing mixture and another point was fixed at 96° for blood temperature.
Réaumur scale
A temperature scale in which the ice point is at 0° and the steam point at 80°.
ideal gas scale
A scale in which changes of temperature are measured either by changes of pressure, or changes of
volume, for gases operating at pressure low enough for the gases to behave as ideal gases. The Celsius
temperature is defined on the scale by:
 
 pV 0   pV 0
 100
 pV 100   pV 0
thermodynamic scale
A temperature scale which does not depend upon the working properties of any substance. The ideal
gas scale is identical with this scale.
absolute scale
A thermodynamic temperature scale in which the lower fixed point is absolute zero of temperature and
the interval is identic with that on the Celsius scale. The temperature on the absolute scale is obtained
by adding to u, the Celsius temperature, 1/a where a is the coefficient of expansion of a gas at constant
pressure. This gives a scale on which the ice point is 273.15°; i.e.
°A = °C + 273.15.
The absolute scale was often called the Kelvin scale and temperatures measured in °A or °K. In SI
units temperature is measured in kelvins (K) by defining the triple point of water as 273.16 K. The ice
point is then 273.15 K. The kelvin has the same size as the degree absolute.
fixed points
Those points on a temperature scale which are fixed and which can be referred to a given property of a
substance. The two main fixed points are the ice point and the steam point.
ice point
That fixed point on a temperature scale at which pure solid water (ice) and pure liquid water are in
equilibrium at 101 325 N m-2 (760 mm Hg). It may be more simply described as the melting point of
pure ice at standard pressure (101 325 N m-2 or 760 mm Hg).
steam point
That fixed point on a temperature scale at which pure water boils at standard pressure (101 325 N m2; 760 mm Hg). This is 100° on the Celsius scale.
zinc point
A fixed point on an international temperature scale, fixed at the temperature at which zinc changes
from liquid to solid (the freezing point of zinc) at standard pressure (101 325 N m-2). This corresponds
to 419.58 °C.
international
temperature scale
A practical scale which is as near as possible to the thermodynamic scale but easily referable to a
series of fixed points.
Triple point of hydrogen
Boiling point of neon
Triple point of oxygen
-259.34 °C
-246.048 °C
-218.789 °C
Boiling point of oxygen
-182.962 °
Triple point of water
0.01°C
Boiling point of water
100.0 °C
Freezing point of zinc oil
419.58 °C
Freezing point of silver
961.93 °C
Freezing point of gold
1064.43°C
Below 630°C platinum resistance thermometer; up to 1064°C a thermocouple or special platinum
resistance thermometer, above 1064 °C a radiation pyrometer.
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