ARTICLE IN PRESS Progress in Retinal and Eye Research 26 (2007) 263–301 www.elsevier.com/locate/prer Ion channels in the RPE Sönke Wimmers, Mike O. Karl, Olaf Strauss Experimentelle Ophthalmologie, Klinik und Poliklinik für Augenheilkunde, Universitätsklinikum Hamburg-Eppendorf, MartinistraX e 52, 20246, Hamburg, Germany Abstract In close interaction with photoreceptors, the retinal pigment epithelium (RPE) plays an essential role for visual function. The analysis of RPE functions, specifically ion channel functions, provides a basis to understand many degenerative diseases of the retina. The invention of the patch-clamp technique significantly improved the knowledge of ion channel structure and function, which enabled a new understanding of cell physiology and patho-physiology of many diseases. In this review, ion channels identified in the RPE will be described in terms of their specific functional role in RPE physiology. The RPE expresses voltage- and ligand-gated K+, Cl, and Ca2+-conducting channels. K+ and Cl channels are involved in transepithelial ion transport and volume regulation. Voltage-dependent Ca2+ channels act as regulators of secretory activity, and ligand-gated cation channels contribute to RPE function by providing driving forces for ion transport or by influencing intracellular Ca2+ homoeostasis. Collectively, activity of these ion channels determines the physiology of the RPE and its interaction with photoreceptors. Furthermore, changes in ion channel function, such as mutations in ion channel genes or a changed regulation of ion channel activity, have been shown to lead to degenerative diseases of the retina. Increasing knowledge about the properties of RPE ion channels has not only provided a new understanding of RPE function but has also provided greater understanding of RPE function in health and disease. r 2007 Elsevier Ltd. All rights reserved. Contents 1. 2. 3. 4. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . The function of the RPE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . K+ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.1. K+ channels and cell function . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.2. K+ ions in RPE function . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.3. K+ channels of the RPE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.3.1. Inward rectifier K+ channels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.3.2. Voltage-gated K+ channels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.3.3. Ca2+-activated K+ channels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.3.4. Two-pore K+ channels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.4. Summary of K+ channel function . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.1. The role of Cl and Cl channels in cell function . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.2. Cl ions in RPE function . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.2.1. Fluid transport . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.2.2. Volume control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.2.3. pH regulation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.2.4. Intracellular organelles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Corresponding author. Tel.: +49 40 42803 9469; fax: +49 40 42803 5017. E-mail address: o.strauss@uke.uni-hamburg.de (O. Strauss). 1350-9462/$ - see front matter r 2007 Elsevier Ltd. All rights reserved. doi:10.1016/j.preteyeres.2006.12.002 264 264 266 266 266 267 267 269 270 271 272 273 273 273 273 274 274 275 ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 264 Identification and properties of Cl channels in the RPE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.3.1. ClC Cl channels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.3.2. CFTR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.3.3. Ca2+-activated Cl channels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.3.4. Volume regulated anion channels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.3.5. Other Cl channels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2+ Ca .................................................................................... 5.1. Ca2+ and cell function in general . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.2. Ca2+ homeostasis in the RPE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.3. Ca2+ and RPE function . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.4. Ca2+ channels of the RPE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.4.1. Voltage-dependent Ca2+ channels . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.4.2. TRP channels. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.4.3. ATP receptors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.4.4. Glutamate receptors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Na+ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.1. Na+ ions in RPE cell function . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.2. Na+ channels of the RPE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Ion channels and RPE disease . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.1. Change or loss of ion channel function leading to RPE diseases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7.2. Involvement of ion channels in signalling cascades leading to degenerative processes in the retina . . . . . . . . . . . . . . Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Acknowledgements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.3. 5. 6. 7. 8. 275 275 277 277 278 279 279 279 280 281 281 282 284 285 286 286 286 287 287 287 288 289 289 289 1. Introduction 2. The function of the RPE With the invention of the patch-clamp technique, understanding of the structure and function of ion channels substantially improved and changed (Ackerman and Clapham, 1997; Colquhoun, 1991; Hamill et al., 1981; Jurkat-Rott and Lehmann-Horn, 2004; Neher and Sakmann, 1976, 1992; Sakmann and Neher, 1984; Sigworth, 1986). General ion channel characteristics were described in detail and the understanding of their cellspecific behaviour in different tissues improved. This knowledge shed new light on many different cell functions and also opened new doors toward an understanding of patho-physiologic changes in cell behaviour. The latter studies coined the term ‘‘channelopathies’’ for ion channelrelated diseases (Ackerman and Clapham, 1997; LehmannHorn and Jurkat-Rott, 1999). The retinal pigment epithelium (RPE) fulfills many tasks, which are essential for visual function (Bok, 1993; Steinberg, 1985; Strauss, 2005). The characterization of ion channels in the RPE is, therefore, a necessity to understand these important functions in retinal health and disease. The first patch-clamp study using cells of RPE was published in 1988 by Fox et al. (1988). Since then, the investigation of RPE ion channels has been undertaken by several different research groups who have now described a large number of different ion channels in the RPE. In this review we have endeavoured to summarize existing knowledge about ion channels of the RPE in relation to RPE function and its pathophysiology. The RPE is a monolayer of pigmented cells covering the inner wall of the eye bulb (Bok, 1993). The apical membrane of the RPE faces the light-sensitive outersegments of photoreceptors and the basolateral membrane of the RPE is enface with the fenestrated capillaries of the choroid (Bok, 1993; Boulton and Dayhaw-Barker, 2001; Marmorstein, 2001; Marmorstein et al., 1998). The interaction with the adjacent tissues relies on extracellular matrices on both sides of the RPE. For a close interaction with photoreceptors, the RPE has long apical microvilli that surround the outer-segments of photoreceptors (Boulton, 1991). The space in-between the RPE and photoreceptors is filled with the interphotoreceptor matrix (IPM). The IPM is essential for the interaction between RPE and photoreceptors (Acharya et al., 1998; GonzalesFernandez, 2003; Hageman and Johnson, 1991; Hollyfield, 1999; Pepperberg et al., 1993; Uehara et al., 1990). In the differentiated eye, the IPM facilitates the interaction between RPE and photoreceptors enabling the exchange of nutrients, signalling molecules, and metabolic end products (Acharya et al., 1998; Gonzales-Fernandez, 2003; Hageman and Johnson, 1991; Hollyfield, 1999; Pepperberg et al., 1993; Uehara et al., 1990). At the basolateral side, the RPE is separated from the choriocapillaris by Bruch’s membrane, a multilayered extracellular matrix structure (Garron, 1963; Guymer et al., 1999; Lerche, 1963; Marshall et al., 1998; Sumita, 1961). Bruch’s membrane represents an interface for exchange of nutrients and signalling molecules, in this case between RPE and the ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 265 Fig. 1. Summary of RPE function to support vision. The figure is from Strauss (2005). MV ¼ apical microvilli; OS ¼ photoreceptor outer segments; PEDF ¼ pigment epithelium-derived factor; VEGF ¼ vascular endothelial growth factor. blood stream and between the RPE and the choroidal endothelial cells (Fig. 1). Electrophysiological studies have characterized the RPE as a tight epithelium with a paracellular resistance 10 times higher than the transcellular resistance (Miller and Steinberg, 1977a, b). This is achieved by a specific subset of tight-junction proteins and defines the RPE as a part of the blood/retina barrier (Ban and Rizzolo, 2000a, b; Kniesel and Wolburg, 1993; Kojima et al., 2002; Konari et al., 1995; Nishiyama et al., 2002; Williams and Rizzolo, 1997). With its location and characteristics, the RPE is able to fulfil a multitude of functions that are essential for visual function (Bok, 1993; Steinberg, 1985; Strauss, 2005). With its pigmentation, the RPE absorbs light energy, which is focussed onto the macula by the lens (Boulton, 1991, 1998; Boulton and Dayhaw-Barker, 2001). As part of the blood/retina barrier, it transports nutrients such as glucose or vitamin A from the blood to the photoreceptors (Baehr et al., 2003; Ban and Rizzolo, 2000b; Marmorstein, 2001; Sugasawa et al., 1994). On the other hand, the RPE eliminates water from the subretinal space. Water accumulates in the subretinal space from metabolic activity of photoreceptors and from the vitreous humour driven by intraocular pressure (Hamann, 2002; Marmor, 1990; Moseley et al., 1984). The transport of water is mainly driven by a transepithelial transport of Cl from the subretinal space to the blood (Bialek et al., 1996; Blaug et al., 2003; Edelman et al., 1994a, b; Edelman and Miller, 1991; Hamann, 2002; Hughes et al., 1984; Maminishkis et al., 2002; Miller et al., 1982; Peterson et al., 1997; Rymer et al., 2001; Stamer et al., 2003; Steinberg, 1985). Furthermore, the RPE is essential for establishing and maintaining the immune privilege of the eye. This is not only established by its barrier function, but also by interfering with the signalling pathways which coordinate the immune system and has immune suppressive function in the healthy eye (Ishida et al., 2003; Streilein et al., 2002; Wenkel and Streilein, 2000). The RPE not only controls the amount of fluid in the subretinal space, it helps to establish a constant ion composition in the subretinal space by compensating for light-induced changes (Dornonville de la Cour, 1993; Gallemore et al., 1997; Hughes et al., 1998; Steinberg, 1985; Steinberg et al., 1983; Steinberg and Miller, 1973). For example, illumination of photoreceptors results in a decrease of the K+ concentration in the subretinal space from 5 to 2 mM (Dornonville de la Cour, 1993; Gallemore et al., 1997; Miller and Steinberg, 1977b; Steinberg et al., 1983). To maintain constant excitability of photoreceptors this change in the K+ concentration is compensated for by the RPE, which releases K+ into the subretinal space (Dornonville de la Cour, 1993; Gallemore et al., 1997; Miller and Steinberg, 1977b; Steinberg et al., 1983). The transport and metabolism of vitamin A is coupled to another function essential for visual function, a metabolic pathway named the visual cycle of retinal (Baehr et al., 2003). The process of vision starts with absorption of light energy by 11-cis retinal in the pigment of rhodopsin (Baehr et al., 2003; Baylor, 1996; Bok, 1993). The light absorption leads to the isomeric change of retinal from the 11-cis to the all-trans isomer. Photoreceptors are unable to re-isomerise all-trans retinal into 11-cis retinal. For re-isomerisation, retinal is transported to the RPE where it is re-isomerised into the 11-cis isomer (Arshavsky, 2002; Mata et al., 2002; Thompson and Gal, 2003). After re-delivery to the photoreceptors it serves to regenerate rhodopsin. Light exposure of photoreceptors is accompanied by photo-oxidative damage of proteins and phospholipids of the outer segments (Beatty et al., 2000). To maintain the excitability of photoreceptors, the outer segments have to be regenerated (Bok, 1993; Bok and Hall, 1971; Finnemann, 2003; LaVail, 1976; Steinberg, 1985). In this regeneration process, new photoreceptor outer-segments are constantly assembled from the connecting cilium. The ARTICLE IN PRESS 266 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 tips of the outer segments are constantly shed from the photoreceptors and phagocytized by the RPE. Proper function of photoreceptors depends on the maintenance of the right size of outer segments. This is achieved by the coordinated shedding and phagocytosis of the tips and requires a tight regulation in communication between RPE and photoreceptors. The regulation takes place in a circadian manner with a peak after onset of light (LaVail, 1976). In humans, the photoreceptor outer segments are completely renewed every 11 days. Transport, phagocytosis, and immune suppression require communication with adjacent tissues. For this purpose, the RPE expresses a large variety of receptors and is also able to secrete a variety of factors (Campochiaro, 1993; Strauss, 2005). The secretory function of the RPE tissue enables not only a functional coordination with photoreceptors and endothelium, but also immune suppression and stabilization of the functional integrity of photoreceptors and endothelial cells. For the latter purpose, the RPE secretes growth factors, such as the pigment epithelium derived factor (PEDF) to the apical or the photoreceptor side (Becerra et al., 2004; King and Suzuma, 2000; Steele et al., 1992) and the vascular endothelial growth factor (VEGF) to the basolateral or endothelial side (Blaauwgeers et al., 1999; Slomiany and Rosenzweig, 2004a; Witmer et al., 2003). These collective functions of the RPE are tightly linked to alterations in ion channel activity and underscore the importance of the study of ion channels in the RPE in order to shed new light on the cellular mechanisms by which the RPE supports visual function. 3. K+ 3.1. K+ channels and cell function The largest group of ion channels in the human genome represents the family of K+ channels consisting of at least 78 pore-forming a subunits (Yu et al., 2005). These include the 15 members of the inwardly rectifying K+ channel subfamily with two transmembrane domains, 40 mainly outwardly rectifying voltage-gated K+ channels with six transmembrane domains, 9 Ca2+-activated K+ channels with six or seven transmembrane domains, and 15 twopore or leak K+ channels with four transmembrane domains and two pores. The term rectification refers to the characteristic conductance changes of ion channels upon membrane potential changes. The inwardly rectifying ion channels have larger ion conductivity in response to hyperpolarizing membrane potential changes than in response to depolarization. Nevertheless, the current mediated by inwardly rectifying K+ channels is predominantly a K+ efflux since the direction of K+ flux is controlled by the reversal potential or equilibrium potential for this ion, which is typically around 80 mV. Accordingly, at potentials positive to 80 mV, K+ ions flow out of the cell and at potentials negative to 80 mV, K+ flows into the cell. The outwardly rectifying channels have a larger ion conductance in response to depolarization of the membrane potential. The subsequent outflow of K+ ions repolarizes the membrane potential back towards the K+ equilibrium potential. All K+ channels are highly selective for K+ ions. Why this diversity in K+ channels? K+ as a charge carrier and an osmotically active molecule is involved in many cell functions. One task of K+ channels in excitable cells is to control the resting membrane potential of the cells shifting it towards the reversal potential of K+. Additionally, K+ channels are involved in the shaping/ duration of action potentials and in adaptive mechanisms by repetitive excitation of neurons (Hille, 2001). In non-excitable cells, K+ channels are responsible for the maintenance of the hyperpolarized resting membrane potential. In addition to this, these channels play essential roles in (1) transepithelial transport processes, (2) the control of cell volume and intracellular pH, (3) the recycling and secretion of K+, (4) the cell cycle and apoptosis, and (5) in the regulation of hormone and growth factor secretion (Ashcroft and Gribble, 1999; Bauer et al., 1999; MacDonald and Wheeler, 2003; Masi et al., 2005; Warth, 2003). 3.2. K+ ions in RPE function As stated above, (Section 2) one function of the RPE is to control the ion composition in the subretinal space. The K+ concentration of the subretinal space in the absence of light is approximately 5 mM. Under these conditions K+ enters the RPE cells through the apically located Na+/K+ ATPase and leaves the cells via the basolateral membrane, leading to a net absorption of K+ (la Cour et al., 1986; Miller and Steinberg, 1982). When exposed to light, photoreceptors hyperpolarize due to the closure of cyclic nucleotide-gated Na+-conducting cation channels, which are located in the membrane of the light sensitive outer segments (Liebman et al., 1987). In the darkness, the K+ ions entering the photoreceptors and the RPE cells through their Na+/K+-ATPases and the K+ ions leaving the photoreceptors as counterion to Na+ are in equilibrium (Baylor, 1996; Strauss, 2005). Due to the hyperpolarization induced by light exposure, less K+ ions leave the photoreceptors. Consequently, the K+ concentration in the subretinal space decreases in the light from 5 to 2 mM (Oakley and Steinberg, 1982; Steinberg et al., 1980). Because of the large K+ conductivity of the apical membrane, the decrease of the extracellular K+ concentration leads to a hyperpolarization of the apical membrane of the RPE (Griff and Steinberg, 1984; Miller and Steinberg, 1977b; Steinberg et al., 1970). Additionally, the low extracellular K+ concentration inhibits the Na+/K+/ 2Cl co-transporter in the apical membrane of the RPE cells (Bialek et al., 1995; Joseph and Miller, 1991) resulting in a decrease of the intracellular Cl concentration (Joseph and Miller, 1991), and as a consequence to an extrusion of ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 cytosolic water and shrinkage of the RPE cells and acidification of the cytosol (Adorante, 1995; Adorante and Miller, 1990; Bialek and Miller, 1994; Huang and Karwoski, 1992; Kennedy, 1994; Li et al., 1994a; Lin and Miller, 1991). The extrusion of water together with cell shrinkage leads to an increase of the subretinal space and to a further decrease of the subretinal K+ concentration. The large apical K+ conductance helps to restore the normal subretinal K+ concentration. Another function of K+ channels is to counteract Ca2+ influx. As Ca2+ influx leads to an increase of intracellular free Ca2+ and to depolarization of the cell, and Ca2+ ions are involved in many RPE functions (see Section 5) there must be a counterbalance for Ca2+ flux in RPE cells. K+ channels are good candidates because they are activated by depolarization (voltage-gated K+ channels) and by Ca2+ itself (Ca2+-activated K+ channels). Additionally, they may support functions as described in other epithelial cell types such as wound healing, regulation of nutrient transport, and cell proliferation/differentiation (Warth, 2003). 3.3. K+ channels of the RPE In Fig. 2, patch-clamp data from two representative RPE cells are shown. Both cells have an inwardly rectifying current but with very different kinetics. Cell 2 has an additional outwardly rectifying current showing the heterogeneity of K+ conductances in these cells. In the next chapters, the different K+ conductances identified in RPE cells will be introduced in relation to their particular K+ channel classes and discussed in their possible roles for RPE function. 3.3.1. Inward rectifier K+ channels 3.3.1.1. Inward rectifier K+ (Kir) channels in general. Kir channels are activated upon hyperpolarization. Though K+ RPE Cell 1 30 mV K+ Cell 2 -60 mV -150 mV 100 pA 10 ms 100 pA 10 ms Fig. 2. Patch-clamp measurements of two mouse RPE cells exemplifying the heterogeneity of membrane K+ currents in these cells. The cells were held at 60 mV and stimulated with voltage-steps of 10 mV, first 10 depolarizing steps then 10 hyperpolarizing steps. 267 their name suggests that they maintain K+ inward current, their main function in most cells is to bring the membrane potential towards the K+ equilibrium potential. As in most cells, in RPE cells the equilibrium potential is negative to the resting membrane potential; thus Kir channels mainly conduct outward K+ currents. Kir channels are composed of four pore-forming subunits with two transmembrane domains, a pore loop and cytoplasmic N- and C-termini (Bichet et al., 2003). Their inward rectification is caused by a block of the channel pore by internal Mg2+ and by cytoplasmic polyamines such as spermine or spermidine at positive voltages (Lu, 2004; Nichols and Lopatin, 1997). Based on their biophysical properties and their sensitivity to intracellular signals the Kir channels are subdivided into seven subfamilies (Kubo et al., 2005). The Kir1 subfamily consists of only one member with weak inwardly rectifying properties (Ho et al., 1993). The four Kir2 subfamily members are strong inward rectifiers (Kubo et al., 1993a; Morishige et al., 1994; Takahashi et al., 1994; Topert et al., 1998). The members of the Kir3 or GIRK subfamily are G-protein-coupled inward rectifiers being activated by the Gbg subunits of G proteins (Dissmann et al., 1996; Kofuji et al., 1995; Kubo et al., 1993b; Spauschus et al., 1996). Members of the Kir4 and 5 subfamilies are able to form heteromultimers with each other (Pearson et al., 1999; Pessia et al., 1996). While Kir4 members are able to form functional channels alone (Pessia et al., 1996), the Kir5 subunit must be co-expressed with Kir4 subunits (Bond et al., 1994). Both homomeric Kir4 channels and heteromeric Kir4/5 channels are weakly inwardly rectifying (Pessia et al., 1996). The Kir6 subfamily members co-assemble with sulfonylurea receptor SUR1 and 2 to form K+ channels that are sensitive to the intracellular ATP/ADP ratio (Aguilar-Bryan et al., 1995; Inagaki et al., 1995a, b, 1996; Sakura et al., 1995). Finally, the Kir7.1 subunit forms a weak inward rectifier that has higher conductance with decreasing extracellular K+ concentrations (Doring et al., 1998; Krapivinsky et al., 1998). Though, most Kir channels are blocked by extracellular Ba2+, the subfamilies can be further characterized by their different sensitivity to Ba2+. Kir7.1 has, for example, a very low Ba2+ sensitivity with an IC50 of 1 mM (Doring et al., 1998; Krapivinsky et al., 1998) while Kir4.1 is much more sensitive with an IC50 in the micromolar range (Bond et al., 1994). 3.3.1.2. Inward rectifier K+ (Kir) channels in the RPE. Different subtypes of inwardly rectifying K+ channel subunits have been identified in the RPE (Ettaiche et al., 2001; Ishii et al., 1997; Kusaka et al., 1999, 2001; Shimura et al., 2001; Yang et al., 2003). In the libraries of the National Eye Institute only KCNJ13 (or Kir7.1) is listed in both the human and the mouse library of expressed sequence tags (EST; http://neibank.nei.nih.gov/). RT-PCR and immunohistological investigations have identified the additional expression of Kir4.1 (Kusaka et al., 1999) and Kir6.2 together with its auxiliary subunit SUR1 in the RPE of rats (Ettaiche et al., 2001). Further, several ARTICLE IN PRESS 268 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 electrophysiological investigations using Ussing chambers as well as the patch-clamp technique, have shown that RPE cells contain K+ currents with inwardly rectifying properties (Gallemore et al., 1993; Hernandez et al., 1995; Hughes et al., 1995a; Hughes and Steinberg, 1990; Hughes and Takahira, 1996, 1998; Immel and Steinberg, 1986; Kusaka et al., 1999, 2001; Poyer et al., 1996; Segawa and Hughes, 1994; Shimura et al., 2001; Strauss et al., 1993, 1994; Takahira and Hughes, 1997; Tao et al., 1994; Wen et al., 1993; Wollmann et al., 2006; Yuan et al., 2003). The Ussing chamber investigations allowed only their indirect identification by the application of the unspecific blockers Ba2+ and Cs+, which also block other ion channels including voltage-gated, Ca2+-activated, and two-pore K+ channels (Goldstein et al., 2005; Grissmer et al., 1993; Ho et al., 1999; Hurst et al., 1996). Nevertheless, it has been shown by these studies that there is a large Ba2+-sensitive K+ conductance in both the apical and the basolateral membrane (Gallemore et al., 1993; Hughes et al., 1995a). Using the patch-clamp technique, single freshly isolated as well as cultivated RPE cells of different species have been studied. In most of these studies, inwardly rectifying K+ currents were identified. The inwardly rectifying K+ currents appeared in all species investigated: frog, monkey, human, rat, toad, rabbit, bovine, and mouse. In rat and bovine RPE cells, combined patch-clamp and molecular biological studies revealed that these inwardly rectifying currents are carried either by Kir7.1 channels alone or by Kir7.1 and Kir4.1 channels (Kusaka et al., 1999, 2001; Shimura et al., 2001; Yang et al., 2003). Both of these channels were shown to be located in the apical membrane of the RPE cells by immunohistochemistry (Kusaka et al., 1999, 2001; Yang et al., 2003). The currents measured in these studies showed some features typical for Kir7.1 channels: (i) weak inward rectification, (ii) an increase in the conductance with reduced K+ concentration in the bath (all other inward rectifiers show a reverse K+ dependence) and (iii) a relative low Ba2+ sensitivity. While some of the observations seem to fit very well with the presence of Kir7.1 channels, some data suggest that there might be different types of inward rectifiers expressed in the RPE, even in the same species (Strauss et al., 1993; Wen et al., 1993). In bovine RPE cells an inward rectifier has been described that exhibits a pronounced rundown of current when measured without intracellular ATP (Hughes and Takahira, 1998). Although it has not been investigated in detail, the Kir7.1 channels seem to be ATP-independent while Kir4.2 is known to be enhanced by ATP (Yang et al., 2000). This finding supports the study of Kusaka et al. (1999) who showed by single channel recordings from the apical side of RPE cells and by immunohistochemistry that Kir4.1 channels are also localized in the apical membrane. Additionally, in cultured RPE cells, currents have been measured with a much more pronounced inward rectification than that of Kir7.1 and Kir4.1 channels which both are weak inward rectifiers (Hughes and Takahira, 1996). Thus, there might also be channels of the Kir2 or the Kir3 subfamilies expressed. Since comparison of inwardly rectifying currents between freshly isolated and cultured human or monkey RPE cells revealed some noticeable differences in respect to inactivation, Ba2+-sensitivity, and dependence on extracellular K+, the expression of inward rectifiers with strong inward rectification may be an expression of the potential of RPE cells to de- and transdifferentiate in culture (Zhao et al., 1997). Accordingly, for the investigation of the in vivo situation, the use of freshly isolated RPE cells should be favoured. 3.3.1.3. Role of inwardly rectifying K+ (Kir) channels for RPE function. The RPE is responsible for the homoeostasis of K+ in the subretinal space (Dornonville de la Cour, 1993; Strauss, 2005). Since K+ continuously enters the RPE cells through the apical membrane via the electrogenic Na+/K+-ATPase and a Na+-K+-2Cl cotransporter and since very little K+ is transcellularly transported at least with low subretinal K+ concentrations of 2 mM as occurs in the light (Dornonville de la Cour, 1993), the RPE needs a way to recycle the K+ at the apical membrane, e.g. for the activity of the apical Na+/K+ ATPase (la Cour et al., 1986). Kir7.1 channels, perhaps together with Kir4.1 channels, are expressed in the apical membrane. Due to their weak inwardly rectifying properties, these channels are well suited for K+ recycling through the apical membrane. In the dark, this K+ recycling through the inward rectifier and the Na+ recycling through the Na+/K+-ATPase on the apical membrane supports Cl transport through the cell (Bialek and Miller, 1994; La Cour, 1992). This Cl transport across the cell supports fluid transport through the RPE in the retina to choroid direction (DiMattio et al., 1983; Frambach and Misfeldt, 1983; Miller and Edelman, 1990; Tsuboi et al., 1986). Thus, the inward rectifier in the apical membrane supports the absorption of water across the RPE. The consequent reduction of the subretinal space holds the retina in the proximity of the RPE, which is necessary for the maintenance of retinal function and helps to prevent retinal detachment. Upon illumination, the K+ concentration in the subretinal space decreases from 5 to 2 mM (Huang and Karwoski, 1992; Li et al., 1994a, b; Oakley and Steinberg, 1982; Steinberg et al., 1980) and the volume of the subretinal space increases. This volume increase seems to be caused by an increased water efflux from the RPE (Huang and Karwoski, 1992). The driving force for this water efflux is believed to be a decreased intracellular K+ concentration in RPE cells. Part of this K+ decrease is likely driven by K+ efflux through inwardly rectifying K+ channels. The atypical behaviour of Kir7.1 channels in their dependence to the extracellular K+ concentration, whereby at lower K+ concentrations they possess a higher conductivity (Doring et al., 1998; Krapivinsky et al., 1998), makes them good candidates to generate the underlying increased K+ efflux. Besides this volume regulation of the subretinal space, there are some reports that a Ba2+-sensitive K+ channel is ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 involved in the regulation of the RPE cell volume itself (Adorante, 1995; Kennedy, 1994). Since inwardly rectifying K+ channels are blocked by the Ba2+ concentrations used in these studies, the participation of inward rectifiers in the regulatory volume decrease (RVD) induced by hypoosmotic stress seems very likely. Nevertheless, Ba2+ is a nonspecific blocker of voltage-gated and Ca2+-activated K+ channels (Bello and Magleby, 1998; Grissmer et al., 1993; Park et al., 2003). As the direct activation of Ca2+-activated K+ channels has been demonstrated (Sheu et al., 2004), the participation of inward rectifiers in volume regulation remains to be proven. In other cell types a participation of inwardly rectifying channels on hormone secretion has been reported (e.g. in pancreatic b cells the intracellular ATP/ADP ratio is coupled to the activity of inwardly rectifying K+ channels). The increase of this ratio leads to the closure of ATPsensitive inward rectifiers composed of the same subunits found in the RPE, Kir6.2 and SUR1 (Ashcroft and Gribble, 1999; Ettaiche et al., 2001). This closure leads to depolarization of the cells, to Ca2+ entry through voltagegated Ca2+ channels, and to increased insulin secretion. As the secretion of a variety of cytokines is controlled by intracellular Ca2+, which enters the cell via voltage-gated Ca2+ channels (see Section 5), a participation of these ATP-sensitive inward rectifiers on the regulation of secretion in RPE cells may not be excluded. Nevertheless, functional data showing the physiological relevance of these channels in the RPE are still missing. 3.3.2. Voltage-gated K+ channels 3.3.2.1. Voltage-gated K+ channels in general. Like inwardly rectifying K+ channels, voltage-gated K+ channels are composed of four pore-forming a subunits (Yellen, 2002). The channels can be formed of four of the same subunits forming homomeric channels or of different subunits forming heteromeric channels (Jan and Jan, 1997). As the channels open upon membrane depolarization, most channels are outwardly rectifying (Gutman et al., 2005). Homology sequence analysis was used to subdivide the voltage-gated K+ channels into 11 subgroups with up to eight subfamily members. Though, the members of the Kv5, 6, 8 and 9 subfamilies do not form functional K+ channels when expressed alone in heterologous expression systems, they form part of the channel pore when expressed together with members of different subfamilies (Gutman et al., 2005). The different a subunits are further characterized by different biophysical and pharmacological properties. While some channels inactivate very fast at depolarizing voltages (so-called A currents), others show only slow or no inactivation at all. Additionally, the channels differ in their voltage-sensitivity, and for most channels highly selective blockers have been described. In non-excitable cells the role of voltage-gated K+ channels is difficult to define because most of these cells show only small membrane potential changes and some of 269 them stay in hyperpolarized states in which the expressed channels should not be active. Nevertheless, voltage-gated K+ channels in non-excitable cells have been shown to be involved in the following functions: (i) transport of nutrients and electrolytes, (ii) recycling and secretion of K+, (iii) regulation of cell volume and pH, (iv) control of cell cycle progression, and (v) regulation of growth factor secretion (O’Grady and Lee, 2005; Warth, 2003). 3.3.2.2. Voltage-gated K+ channels in the RPE. According to the databases of EST of the National Eye Institute, six different pore-forming subunits of voltage-gated K+ channels are expressed in the RPE/choroid (Kv1.2, 2.1, 7.1-3 and 8.2). Additionally, two ESTs of auxiliary subunits have been identified in these preparations (Kvb2, KCNE4 ¼ MiRP3). By RT-PCR the expression of Kv1.2 and 2.1 has been confirmed (Pinto and Klumpp, 1998). Further, transcripts of Kv1.3, 1.4 and 4.2 have been identified by RT-PCR. Western blot and immunohistochemcical data show that Kv1.3 and 1.4 subunits are located in the apical membrane of RPE cells (Pinto and Klumpp, 1998; Strauss et al., 2002; Wollmann et al., 2006). As voltage-gated K+ channels are composed of four pore-forming subunits and the different members of one subfamily are able to form functional channels together, the Kv1.2, 1.3 and 1.4 subunits may form heteromeric channels. The Kv4.2 subunits were localized to the basolateral membrane (Pinto and Klumpp, 1998). The expression of Kv7 subunits has recently been confirmed in human and monkey RPE cells (Hughes et al., 2006) in a combined molecular biological and electrophysiological study. The data confirmed the expression of Kv7.1 but instead of Kv7.2 and 7.3 they found transcripts of Kv7.4 and 7.5. Patch-clamp experiments with different blockers suggest that these currents are mainly mediated by Kv7.5 channels. Additionally, in preparations from bovine RPE, K+ currents have been measured that resemble the M current, which is known to be carried by Kv7 channels (Takahira and Hughes, 1997). In all species investigated, in addition to these M currents, other voltage-gated outwardly rectifying K+ currents have been characterized electrophysiologically (Fox and Steinberg, 1992; Hughes and Steinberg, 1990; Hughes and Takahira, 1996; Hughes et al., 1995b; Poyer et al., 1996; Strauss et al., 1993, 1994, 2002; Takahira and Hughes, 1997; Tao et al., 1994; Wen et al., 1993; Wollmann et al., 2006). But the currents display very heterogeneous biophysical properties. Even in the same species outwardly rectifying K+ currents with different properties were described (Hughes and Takahira, 1996; Hughes et al., 1995b; Strauss et al., 1993; Wen et al., 1993). For example, in freshly isolated human RPE cells a non-inactivating current with an activation threshold of 30 mV was observed (Wen et al., 1993) while in another preparation non-inactivating currents with a threshold of 60 mV were found (Hughes et al., 1995b). Despite these differences all identified currents have a relatively low sensitivity to tetraethylammonium (TEA) in common—an unspecific ARTICLE IN PRESS 270 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 blocker of voltage-gated K+ channels. Additionally, with one exception, all currents exhibit slow or no inactivation. These findings suggest that members of the Kv4.x subfamily are not functionally expressed—though Pinto and Klumpp found Kv4.2 in the basolateral membrane of rat RPE cells (Pinto and Klumpp, 1998)—since these channels display a very fast inactivation (Gutman et al., 2005). Such a fast inactivation was only found in one preparation of foetal human RPE cells (Wen et al., 1993) and not in the rat cells which were studied by Pinto and Klumpp. So far, only one attempt has been made to identify the molecular basis of outwardly rectifying K+ currents in RPE cells (Strauss et al., 2002). The current investigated in that study was inhibited by the K+ channel blocker agitoxin-2, which is highly specific for Kv1.1, 1.3 and 1.6 channels (Garcia et al., 1994) while blockers specific for other K+ channels had no effect on the current. Furthermore, the expression of Kv1.3 was confirmed by western blots. However, it cannot be excluded that these Kv1.3 subunits form heteromeric channels with other subunits of the same subfamily. 3.3.2.3. Role of voltage-gated K+ channels for RPE function. Most voltage-gated K+ currents described in RPE cells activate at potentials positive to 40 to 30 mV (Fox and Steinberg, 1992; Hughes and Steinberg, 1990; Strauss et al., 1993, 1994, 2002; Takahira and Hughes, 1997; Tao et al., 1994; Wen et al., 1993), some of them at even more positive potentials (Hughes and Takahira, 1996; Wollmann et al., 2006). As RPE cells have resting membrane potentials between 50 and 40 mV with only small changes to more positive potentials (Dornonville de la Cour, 1993; Fujii et al., 1992; Gallemore et al., 1997; Hughes and Steinberg, 1990; Joseph and Miller, 1991; Miller and Steinberg, 1977b; Quinn and Miller, 1992; Steinberg et al., 1978; Wen et al., 1993), it remains unclear how these channels might contribute to RPE cell function. One possible mechanism that may lead to their opening has been shown by Strauss et al. (2002). This study demonstrated that the outwardly rectifying K+ channel investigated in rat RPE cells is completely abolished by the inhibition of a tyrosine kinase and increased by the addition of an activated pp60csrc tyrosine kinase. As this activation might be attributed to a shift in the activation threshold, this provides a way to activate voltage-gated channels without changing the membrane potential. These channels are probably composed of Kv1.3 subunits. Kv1.3 channels are widely expressed in cells of the immune system (Cahalan et al., 2001; George Chandy et al., 2004). In microglia Kv1.3 channels are necessary for their immune reaction (Fordyce et al., 2005). As RPE cells are part of the immune system in the posterior part of the eye (Streilein, 2003; Streilein et al., 2002), the delayed rectifier in the RPE cells may be part of their immune response. The M current identified in freshly isolated bovine RPE cells activated at potentials positive to 80 mV. Accordingly, these channels may contribute to the maintenance of the resting membrane potential. M currents, carried by Kv7 channels, are inhibited by Gq/11 coupled membrane receptors (Delmas and Brown, 2005). Gq proteins activate phospholipase Cb which hydrolyze phosphatidylinositol4,5-bisphosphate (PIP2) into inositol-1,4,5-trisphosphate (InsP3) and diacylglycerol (DAG). The breakdown of PIP2 leads to the closure of M channels. RPE cells have been shown to express different Gq/11 protein coupled receptors: epinephrine receptors a1B and a1D (Moroi-Fetters et al., 1995), serotonin receptor 5HT2 (Nash et al., 1999; Osborne et al., 1993) and purinergic receptors P2Y1 and P2Y2 (Maminishkis et al., 2002; Reigada et al., 2005; Sullivan et al., 1997). Stimulation of purinergic and epinephrine receptors leads to elevated intracellular free Ca2+ in RPE cells (Maminishkis et al., 2002; Quinn et al., 2001). Further, these stimulations lead to the depolarization of apical and basolateral membranes. While depolarization of the basolateral membrane may be attributed to the activation of a Ca2+-activated Cl conductance, the apical depolarization may be due to the decrease of a K+ conductance. As M currents are inhibited by the activation of these receptors, they are good candidates for this purpose presuming that they are expressed in the apical membrane of RPE cells. Furthermore, stimulation of both purinergic and epinephrine receptors is involved in reattachment of the retina to the RPE by elevated fluid transport from the subretinal space to the choroid (Maminishkis et al., 2002; Rymer et al., 2001). When these M channels are expressed in the apical membrane and Ca2+-activated K+ channels in the basolateral membrane this would provide a possibility for the regulation of directed K+ transport through the RPE, as both channels are reciprocally regulated by Gq/11-coupled receptors. One member of this subfamily (Kv7.1) is involved in ion transport in various tissues. This includes Cl secretion in airway (Leroy et al., 2004) and gastrointestinal epithelia (Kunzelmann et al., 2001a, b), K+ secretion in the stria vascularis (Marcus et al., 1997, 1998; Shen and Marcus, 1998; Sunose et al., 1997) and K+ recycling in gastric parietal cells (Warth and Barhanin, 2003). Thus, in RPE, M channels may participate in the ion homoeostasis of the subretinal space. 3.3.3. Ca2+-activated K+ channels 3.3.3.1. Ca2+-activated K+ channels in general. Many processes in the RPE are coupled to changes in the intracellular free Ca2+ concentration (see Section 5). As Ca2+-activated K+ channels are gated by changes in intracellular free Ca2+, they are capable of fulfilling a variety of cellular functions (Vergara et al., 1998; Weiger et al., 2002). Based on single channel conductance, sequence homologies and pharmacology, Ca2+-activated K+ channels are subdivided into three subgroups (Wei et al., 2005): (i) SK channels with a small K+ conductance (4–14 pS), (ii) IK channels with an intermediate K+ conductance (20–80 pS), and (iii) BK or maxi K channels with a large conductance (200–300 pS). While SK and IK channels are gated solely by intracellular Ca2+, BK ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 channels are gated by both intracellular Ca2+ and voltage. Like voltage-gated K+ channels they are formed of four subunits with six transmembrane domains. The BK channel has an additional N-terminal transmembrane domain (S0) (Bond et al., 1999; Ghatta et al., 2006). Ca2+-activated K+ channels are found in close vicinity to voltage-gated Ca2+ channels in neurons (Gola and Crest, 1993; Grunnet and Kaufmann, 2004; Marrion and Tavalin, 1998) and in cochlear hair cells (Issa and Hudspeth, 1994; Roberts et al., 1990) proposing a role as feedback modulators for voltage-gated Ca2+ channels that provide the Ca2+ needed for the activation of Ca2+-activated K+ channels. In non-neuronal tissues Ca2+-activated K+ channels were found to be involved in volume regulation, and in transepithelial ion secretion or absorption, and cell cycle regulation (Begenisich et al., 2004; Feranchak et al., 2004; Huang et al., 2002; Joiner et al., 2003; Liu et al., 2002; Turnheim et al., 2002). 3.3.3.2. Ca2+-activated K+ channels in the RPE. So far, Ca2+-activated K+ channel subunits have not been identified in the RPE, either by molecular biological or by protein biochemical methods. However, patch-clamp measurements with RPE cells from different species have provided evidence that an outwardly rectifying K+ channel is activated by elevated intracellular Ca2+ concentrations (Ryan et al., 1999; Sheu and Wu, 2003; Sheu et al., 2004, 2005; Tao and Kelly, 1996). These currents were completely blocked by the specific BK channel inhibitor iberiotoxin and had a unitary conductance of 150 pS (Sheu and Wu, 2003; Tao and Kelly, 1996). As charybdotoxin, a blocker of BK and IK channels, and apamin, a blocker of SK channels, had no additional blocking effect on these currents, it seems likely that the K+ channels activated by raising intracellular Ca2+ are of the BK subtype (Sheu and Wu, 2003). Since BK channels have not yet been studied by either immunohistochemistry or electrophysiological measurements using intact RPE tissue, it is not known whether these channels are in the apical or basolateral membrane. 3.3.3.3. Role of Ca2+-activated K+ channels for RPE function. Different physiological stimuli have been used to activate Ca2+-activated K+ channels in the RPE. Application of ATP has been shown to increase intracellular Ca2+ concentrations in RPE cells through the activation of different purinergic receptors (see Section 5). This increase in intracellular free Ca2+ in turn stimulates the apical to basolateral fluid transport through the RPE (Peterson et al., 1997). The fluid transport is driven by Ca2+-dependent Cl currents in the basolateral membrane (see Section 4) and may be supported by Ca2+-activated K+ channels. Ca2+-activated K+ channels were shown to be involved in volume regulation in RPE cells in response to hypotonic stress (Sheu et al., 2004). In that study, BK currents were increased by hypoosmotic stress. The induced K+ efflux together with a yet unidentified anion efflux is thought to be responsible for the RVD (Kennedy, 271 1994). Furthermore, intracellular Ca2+ signalling regulates a variety of RPE cell functions (e.g. photoreceptor phagocytosis, growth factor secretion, immune responses, differentiation). To control these processes the cells need mechanisms to terminate the Ca2+ signals. One possibility is simply to extrude the Ca2+ from the cytosol via different membrane transporters and pumps (Kennedy and Mangini, 1996; Loeffler and Mangini, 1998; Mangini et al., 1997). The second possibility is to terminate the signal by stopping the Ca2+ influx. As in other cell types, the participation of Ca2+-activated K+ channels in the latter process has been proven (Ghatta et al., 2006) and it is tempting to speculate that these channels may serve the same purpose in the RPE. Furthermore, BK channels in the RPE are inhibited by oxidizing agents (Sheu and Wu, 2003). Mutational analysis has revealed a protective mechanism against oxidative stress that involves the participation of heterologously expressed BK channels (Santarelli et al., 2006). As RPE cells are exposed to high oxidative stress (Mainster, 1987; Tanito et al., 2002; van Best et al., 1997), the BK channels may provide part of the oxidant protective mechanisms in these cells. 3.3.4. Two-pore K+ channels The last group of K+ channels to mention is the family of two-pore K+ channels. In contrast to other K+ channels, which are all formed by four subunits with one pore domain each, two-pore K+ channels are formed by two subunits with two pore domains each (Goldstein et al., 2005; Lesage and Lazdunski, 2000). In vertebrates, 15 members of this K+ channel subclass have been identified which are further divided into six subfamilies: the weakly inwardly rectifying TWIK channels, the arachidonic acid and mechanosensitive TREK channels, the acid-sensitive TASK channels, the alkaline-sensitive TALK channels, the halothane-inhibited THIK channels, and the TRESK channel (Goldstein et al., 2001, 2005). Two-pore K+ channels have a widespread tissue distribution being expressed in neuronal and non-neuronal tissues (Lesage and Lazdunski, 2000). They are also called leak channels because they are constitutively open. The activity of these channels is influenced by a plethora of chemical and physical stimuli—oxygen tension, pH, lipids, mechanical stretch, neurotransmitters, and G-protein-coupled receptors (Plant et al., 2005)—and thus, may be involved in many physiological functions relevant for RPE cells including maintenance of the resting membrane potential, pH regulation, and K+ homoeostasis. As some of these channels are blocked by low concentrations of Ba2+ (Decher et al., 2001; Meadows et al., 2000; Patel et al., 2000) it cannot be excluded that some of the Ba2+-sensitive effects measured in Ussing chamber experiments must be attributed to two-pore channels and not exclusively to inwardly rectifying K+ channels as concluded in most reports. However, as there is no direct evidence for the expression of two-pore channels in the RPE, their possible role in the RPE will not be further discussed. ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 272 3.4. Summary of K+ channel function extracellular K+ concentrations in that they have an increased K+ conductance when extracellular K+ is reduced. Thus, they are activated when light falls on the retina as illumination is accompanied by a decrease in subretinal K+ concentration. By this mechanism, Kir7.1 channels are involved in the K+ homoeostasis in the light. The Kv7 channels on the other hand are regulated by Gq/11-protein-coupled receptors. These receptors activate phospholipase C, which hydrolyzes PIP2 into InsP3 and DAG, leading to an inhibition of Kv7 channels and an increase in intracellular free Ca2+, which in turn activates Ca2+-activated K+ channels. If these two K+ channels are expressed in opposing membranes of the RPE cells, e.g. the M channels in the apical membrane and the BK channels in the basolateral membrane, this would lead to a regulated K+ transport through the RPE. Under normal conditions, K+ recycling across the apical membrane would be favored whereas upon activation of Gq/11 proteins, the absorption of K+ ions through the basolateral membrane would be favored. This regulation of K+ transport direction could support water transport through the RPE, which is elevated upon ATP stimulation, although this water flux is mainly thought to be coupled to Cl absorption. This Cl absorption is also increased by the activation of purinergic receptors, mediated by Ca2+-activated Cl channels. An additional role of the BK channels is probably to counteract the voltage-gated Ca2+ channels In Fig. 3, a scheme is presented that summarizes the possible roles of K+ channels in RPE cells. Although it has not been resolved which K+ channels are expressed in the RPE and what their specific functions are, some conclusions can be drawn from the electrophysiological data. It is well accepted that the Na+/K+-ATPase, the Na+-K+-2Cl cotransporter, and an inwardly rectifying K+ channel are expressed in the apical membrane of RPE cells. They are functionally coupled via Na+ ions, which leave the cells through the Na+/K+-ATPase and are used by the Na+-K+-2Cl cotransporter to uptake K+ and Cl into the cell. K+ is recycled into the subretinal space through an inwardly rectifying K+ channel and Cl ions leave the cells across the basolateral membrane through a not yet identified Cl channel. This Cl absorption drives apical to basolateral water transport. Kv7 channels and Ca+-activated K+ channels may also play a role in K+ homoeostasis of the subretinal space. Due to the negative activation threshold of Kv7 channels they may also be involved in the K+ recycling at the apical membrane. As they do not inactivate at the negative membrane potentials in RPE cells, they are capable of conducting a sustained outward current. The participation of two different K+ conductances allows the cells to fine-tune the K+ efflux. The inwardly rectifying Kir7.1 channels are regulated by K+ Epinephrine ATP M channel (Kv7) apical K+ Kv1.3 AQ1 ? PLC H 2O 3 Na+ Kir7.1 Kir4.1 Gαq/11 ati sm p la m o d E n icu l u t Re K+ K+ Na+ 2 K+ 2 Cl- IP3 Ca2+ c H2O IP3R Ca2+ ? L-type channel basolateral BK channel K+ AQ1 Cl channel CaCl channel Kv1.3 Cl- K+ Cl- H 2O Fig. 3. Schematic diagram summarizing how different K+ currents may be involved in RPE cell function. All ion channels as well as the water channels are drawn in blue, second-messenger pathways are in yellow with red arrows, ion transporters are drawn in light blue. The Na+/ K+-ATPase and the Na+-K+-2Cl cotransporter are drawn in grey, G-protein-coupled receptors and their ligand in pale blue. Black arrows show the ion through the cell and through the cell membrane, green arrows mean activating influence, red arrows inhibiting influence. Abbreviations are: AQ1 ¼ aquaporine 1; ATP ¼ adenosine triphosphate; BK channel ¼ large conductance Ca2+-activated K+ channel; CaCl channel ¼ Ca2+-activated Cl channel; Gaq/11 ¼ G protein a-subunit q/11; IP3 ¼ inositol-1,4,5-trisphosphate; PLC ¼ phospholipase C. ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 in the RPE as the entering Ca2+ activates BK channels. Their activation in turn leads to the hyperpolarization of the cell and consequently to the closure of the voltagegated Ca2+ channels. The role of the other voltage-gated K+ channels including Kv1.3 in RPE cells remains obscure as these channels should be inactive at the RPE cell’s resting membrane potentials. Possibly, they are involved in cell proliferation/differentiation and wound-healing processes. 4. Chloride 4.1. The role of Cl and Cl channels in cell function Chloride is the most abundant permeable anion under physiologic conditions; therefore, anion channels (hereafter only referred to as chloride channels) mostly conduct chloride. In contrast to most other ions, the Cl resting concentration significantly differs among various mammalian cell types and during cell development (Cherubini et al., 1991; Chipperfield and Harper, 2000). Like other ions, Cl transport is regulated across plasma membranes as well as membranes of intracellular organelles. Chloride can be actively released out of cells, accumulated within cells, or passively distributed or co-transported to maintain electroneutrality. Depending on Cl ion channel localization, in the plasma membrane or intracellular organelles, Cl channels are involved in modulating the excitability of cells, transepithelial salt transport, cell volume regulation and homoeostasis or regulation of organelle volume, the acidification of intra- and extracellular compartments, calcium or proton gradients, the cell cycle, and apoptosis (Jentsch et al., 2005c; Nilius and Droogmans, 2003). In many epithelia Cl channels are involved in the vectorial, transepithelial transport of salt and water (Begenisich and Melvin, 1998; Spring, 1998). Cl channels also help protect epithelial cells against excessive osmotic cell swelling (Sarkadi and Parker, 1991; Spring and Ericson, 1982; Strange, 2004; Strange et al., 1996). The existence of Cl conductance is important for endosomal, lysosomal, and phagolysosomal vesicles and turnover along the endocytic apparatus (Faundez and Hartzell, 2004; Jentsch et al., 2005a). Three major Cl ion channel families (A–C) have been well characterized using molecular means. Other Cl conductances/channels (D) are described either by expression studies or by functional characterization, but their molecular counterpart and /or their role in health and disease remains unknown. (A) Voltage-gated Cl channels (CLC1–7, CLC-K1,2, CLC-0), (B) Cystic fibrosis transmembrane conductance regulator (CFTR) channel, and (C) extracellular ligandgated ion channels such as g-aminobutyric acid (GABA) or glycine receptors have been distinguished. Some of these Cl channels are located primarily, or exclusively, in membranes of intracellular organelles, but their localisation is still controversial (ClC3–7). (D) Two different 273 classes of Cl channels primarily defined from their mechanism of activation and biophysical properties are: (I) calcium-activated Cl channels (CaCC) (Evans and Marty, 1986) and (II) swelling-activated/volume-regulated anion channels (VRAC). However, this classification is an oversimplification as many Cl channels are regulated by more than one mechanism and might consist of molecularly diverse classes. It should be mentioned that most Cl channel blockers are unselective, have a low potency, and have various side effects; therefore, pharmacological studies have to be interpreted with caution (d’Anglemont de Tassigny et al., 2003; Jentsch et al., 1999; Kidd and Thorn, 2000). Finally, the discrepancy of functional Cl channels and actual cloned proteins may stem from the fact that there are no conserved gene sequences characterizing Cl channels among the known channel families. Consequently, entire families of Cl channels may not have been determined. 4.2. Cl ions in RPE function 4.2.1. Fluid transport The RPE mediates water transport from the subretinal space to the choroid. Together with Müller glial cells, which transport water from the subretinal space to the vitreous, the RPE controls the volume of the subretinal space (Bringmann et al., 2005; Hughes et al., 1998; Marmor, 1983; Newman and Reichenbach, 1996; Steinberg et al., 1983; Strauss, 2005). In fact, the primary function of Cl channels in secretory cells is transepithelial ion transport (Begenisich and Melvin, 1998; Do and Civan, 2004). The retina produces a large amount of water due to its enormous metabolic turnover and intraocular pressure drives water movement from the vitreous body through the retina. This water is eliminated from the subretinal space into the choroid plexus by the RPE and into the vitreous by Müller cells. Therefore, fluid transport from choroid to retina (secretion) and vice versa (absorption) by the RPE are essential pathways for fluid regulation in the eye. Fluid absorption must occur without interruption for retinal adherence and interaction with the RPE to be maintained (Hamann, 2002; Marmor, 1990, 1993; Verkman, 2003). In pathologic states like retinal detachment or macular oedema, increased fluid absorption by the RPE may lead to a recovery (Bringmann et al., 2004; Marmor, 1999). RPE transport of Cl and K+ is thought to drive transepithelial water transport. Under control conditions it was estimated that the Cl conductance is up to 70% of the total basolateral conductance. The transport rate of water was estimated between 1.4 and 11 ml cm2 h1 (Gallemore et al., 1997; Hamann, 2002; Strauss, 2005). Fluid absorption involves different mechanisms operating in the apical and basolateral membranes of the RPE cells (Fig. 5). Several Cl transporters use the energy stored in transmembrane gradients of other ions to move Cl across the RPE cell membranes against an electrochemical gradient. The electrogenic Na+/K+-ATPase generates a Na+ ARTICLE IN PRESS 274 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 gradient from the extracellular (subretinal) to the intracellular space, which also can be measured as the steady-state retina-positive potential of about 10 mV (Gallemore et al., 1997). This so-called standing potential depends on the separation of apical and basolateral properties. In the dark, photoreceptors maintain K+ recycling leading to a higher subretinal K+ concentration than during illumination of the retina (Bialek and Miller, 1994). The increase in [K+]o stimulates the apical Na+-K+-2Cl cotransporter, thereby increasing the cellular uptake of K+ and Cl (Adorante and Miller, 1990; Hamann, 2002; Hughes et al., 1989; Joseph and Miller, 1991; Keller et al., 1988; Kennedy, 1990, 1994; la Cour, 1991a, b; Lin and Miller, 1991). Thus, a high intracellular Cl activity of up to 60 mM is established providing a driving force for Cl out of the cell (Bialek and Miller, 1994; Fujii et al., 1992; Quinn et al., 2001; Rymer et al., 2001). Retinal adhesion as an indicator of functional fluid transport is lost by inhibition of the apical Na+/K+-ATPase by ouabain (Endo et al., 1988; Marmor, 1983; Marmor and Yao, 1989). Thus, Cl absorption in tight epithelia like the RPE is accompanied by the transport of water to balance osmotic pressure through aquaporins (Bialek and Miller, 1994; Tsuboi and Pederson, 1988a, b; Verkman, 2003). Evidence strongly suggests that Cl exits across Ca2+-activated, volumeactivated, and/or cAMP-activated ion channels in the basolateral membrane of the RPE, but its differential contributions are not understood and its molecular counterparts are still controversial (Gallemore et al., 1997; Hartzell et al., 2005b; Hughes et al., 1998; Strauss, 2005). 4.2.2. Volume control Many transporting epithelia regulate their volume after osmotic perturbations that shrink or swell the cells (Sarkadi and Parker, 1991; Spring and Ericson, 1982; Strange et al., 1996). The acute component after cell swelling is frequently mediated by conductive losses of Cl and K+, and related water efflux to control cell volume (RVD). Contrary, cell shrinkage results in regulatory volume increase (RVI) by mechanisms that decrease K+ and Cl conductance. The specific features of cell-volume regulation vary considerably among cell types and the physiological significance is not always proven (la Cour, 1985; Lang et al., 1993, 1998a, b), and we don’t know the exact extent of physiological osmotic changes on subretinal and choroidal sites of the RPE cell layer. RPE cells have effective volume regulating mechanisms, as shown by volume manipulation. Cultured RPE cells possess hypertonically-activated Na+-K+-2Cl cotransporter, hypotonically-activated K+-Cl cotransporter, and a Ba2+—inhibitable hypotonically activated K+ efflux pathway (Civan et al., 1994; Tsuboi and Pederson, 1988a, b). Remarkably, Cl channel inhibition with the broad Cl channel blocker NPPB reduced cell shrinkage. Thus, the RVD of RPE cells likely reflects efflux of K+ and Cl through parallel channels. The transport situation seems to differ in the light- and dark-adapted eye. In the dark, lactate increases subretinally whereas it decreases in the RPE. Therefore, a gradient from retina to choroid is established which imposes an osmotic load for the RPE (Adler and Southwick, 1992; Hamann, 2002; Hsu and Molday, 1994; Winkler, 1995). During illumination, subretinal K+ decreases, subretinal space volume increases and RPE cell volume decreases (Gallemore et al., 1997). Some studies suggest that changes in subretinal hydration and ion composition, RPE cell volume regulation and fluid transport mechanisms are interrelated (Adorante and Miller, 1990; Bialek and Miller, 1994; Botchkin and Matthews, 1993; Civan et al., 1994; Hartzell and Qu, 2003; Kennedy, 1994). Moreover, phagocytosis is regulated by illumination and hypoosmotic cell swelling or application of the Cl channel blocker tamoxifen decreases RPE phagocytosis (Irschick et al., 2006; Mannerstrom et al., 2001). Therefore, it is not yet clear whether cell volume alterations due to photoreceptor phagocytic uptake, nutrient and lactate transport, or pathophysiologic disturbances in subretinal osmolarity (hydration and ion composition) require RPE cell volume control capability and fluid transport across the RPE. 4.2.3. pH regulation Controlling the ionic composition of the cytoplasm is inevitable. Most cells are more alkaline intracellularly than calculated from electrochemical equilibrium (Chipperfield and Harper, 2000). Light-induced changes in ion transport maintain ion homoeostasis in the subretinal space and evoke changes in pH (Gallemore et al., 1997; Strauss, 2005). The mechanism by which pH homeostasis is maintained in RPE cells is not completely understood. RPE cells support photoreceptor function by eliminating lactic acid thereby regulating the extracellular pH (Hamann, 2002). Transcellular fluid transport requires an efficient regulation of intracellular pH as well, since some Cl channels are modulated by pH changes. The subretinal pH and intracellular pH are regulated by transepithelial transport of HCO 3 , which needs pathways for Cl recycling (Edelman et al., 1994a; Lin and Miller, 1991). Apically, RPE cells have a Na+/H+ exchanger and a Na+/ 2HCO3-cotransporter, and basolaterally a HCO 3 /Cl exchanger, and they are acid-loaded due to transepithelial lactate transport (Hamann, 2002; Keller et al., 1986, 1988; Strauss, 2005). Increased cytosolic HCO 3 alkalinizes the cytosol which stimulates the basolateral Cl–HCO 3 exchanger (Edelman et al., 1994a; Kenyon et al., 1997; Lin and Miller, 1991). The increased Cl–HCO 3 exchanger activity results in acidification of the cytosol by HCO 3 extrusion and to Cl uptake. This CI recycled to the choroidal site by basolateral CI channels and facilitates acidification by HCO 3 extrusion. Furthermore, the enhanced CI uptake by the Cl–HCO 3 exchanger results in reduced Cl and water secretion. A favoured hypothesis is that this recycling determines the balance of fluid absorption and secretion so that the net Cl movement is toward ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 275 the subretinal space. Therefore the RPE behaves as a net secretory epithelium. 4.2.4. Intracellular organelles Intracellular Cl channels have received much less attention, but genetic evidence has revealed some of their physiological significance. Cl channels in vesicles might be involved in endosomal, lysosomal, phagosomal, and synaptic vesicle pathways (Jentsch et al., 2005c). b 4.3. Identification and properties of Cl channels in the RPE Molecular counterparts of most Cl channels in the RPE are still not known. CFTR, ClC-2, -3, -5, and -7, Ca2+ activated, and volume activated Cl channels have been claimed to be expressed in RPE cells to date (Blaug et al., 2003; Bosl et al., 2001; Botchkin and Matthews, 1993; Hartzell and Qu, 2003; Hughes and Segawa, 1993; Loewen et al., 2003; Reigada and Mitchell, 2005; Strauss et al., 1996, 1998a, 1999; Ueda and Steinberg, 1994; Weng et al., 2002; Wills et al., 2000; Wollmann et al., 2006; Wu et al., 2006). Fig. 4 shows an example of CI currents in RPE cells. 4.3.1. ClC Cl channels 4.3.1.1. ClC Cl channels in general. Mammalian genome contain nine different genes that encode for the ClC channels. Some comprise plasma membrane channels (ClC-1,-2, -ka, kb) and others are predominately in intracellular membranes (ClC-3, -4, -5, -6, -7). All ClC channels examined to date are dimers. Most of these channels are characterized by voltage-dependent gating, all display a specific permeability sequence (Cl4Br4I) and are mostly regulated by extracellular anions and pH (Jentsch et al., 2005a–c, 2002; Nilius and Droogmans, 2003). ClC-1 has been described as a double-barrel model represented by two identical parallel pores (Middleton et al., 1996; Pusch and Jentsch, 2005). Each pore independently opens a fast gate (10 ms range) upon depolarization which displays inward rectification, and a common slow inactivating gate (10–100 s) closes both pores at the same time. The slow gate opens upon hyperpolarization. Gating mechanisms and selectivity of ClC channels are still unknown. The functional role of ClC-1 is stabilizing the membrane potential; ClC-2 channels are inwardly rectifying after activation by hyperpolarization, cell swelling, or extracellular acidosis; and ClC-3, -4 and -5 are constitutively active and outwardly rectifying as well as are ClC-Ka and -Kb in the presence of the b-subunit Barttin. In a recent study, vesicular ClC-4, -5 and -7 (and possibly ClC-3 and -6) have been demonstrated to function as electrogenic chloridehydrogen exchangers (also called antiporters) which extrude protons against their electrochemical gradient, demonstrating secondary active transport (Accardi and Miller, 2004; Kasper et al., 2005; Kornak et al., 2001; Picollo and Pusch, 2005; Pusch et al., 2006; Scheel et al., 2005). c d Fig. 4. Example of voltage-dependent Cl channel currents in freshly isolated mouse RPE cells. (a) Schematic diagram showing the recording configuration. Membrane currents were measured in K+-free solutions in the whole-cell configuration. (b) Pattern of electrical stimulation: from a holding potential of 40 mV the cells were stepwise depolarized up to a potential +50 mV and then stepwise hyperpolarized to a potential 130 mV. The step duration is 50 ms and the increment 10 mV. (c) Example of currents activated by electrical stimulation. (d) Effect of the Cl channel blocker DIDS on the voltage-dependent currents. Application of 1 mM DIDS (right panel) reduced the outwardly directed currents observed under control conditions (left panel). 4.3.1.2. ClC Cl of the RPE. So far ClC channels -2, -3, -5, and -7 have been reported to be expressed in human RPE cell (Fig. 5) by RT-PCR, Western blotting and immunohistochemistry, but biophysical characterization has not been completed (Hartzell and Qu, 2003; Weng et al., 2002; Wills et al., 2000). ClC-2 has been implicated as a potential Cl exit pathway in epithelia. Strikingly, disruption of ClC-2 leads to degeneration of the retina (Bosl et al., 2001). Retinal degeneration might be secondary due to RPE dysfunction, which likely would result in abnormal composition of subretinal fluid and secondarily impairs photoreceptor viability. RPE short-circuit currents are reduced in ClC-2 / mice ARTICLE IN PRESS 276 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 Fig. 5. Schematic diagram summarizing the Cl channel function in RPE cells. All ion channels as well as the water channels are drawn in blue, secondmessenger pathways are in yellow with red arrows, ion transporters are drawn in light blue, intracellular ion channels are drawn in light yellow. The abbreviations are: AQ1 ¼ aquaporine 1; ATP ¼ adenosine triphosphate, cAMP ¼ cyclic adenosine monophosphate; CaCl ¼ Ca2+-dependent Cl channel; ClC 2,3,5,7 ¼ ClC chloride channels 2,3,5,7; CFTR ¼ cycstic fibrosis transmembrane regulator; ER ¼ endoplasmic reticulum; Gaq/11 ¼ G protein a-subunit q/11; IP3 ¼ inositol-1,4,5 trisphosphate; IP3R ¼ inositol-1,4,5 trisphosphate receptor; PLC ¼ phospholipase C; VMD2 ¼ product of the vitelliform macular dystrophy 2 gene. supporting the role in transepithelial fluid transport. But the physiological role of ClC-2 and the pathomechanism of the RPE phenotype in ClC-2 knockout mice remain unknown. Currents resembling ClC-2 (hyperpolarization-activated, slowly activating, inwardly rectifying, acid-activated, Zn2+ -inhibited) have been described for the RPE, but definite characterization including a description of the anion permeability sequence (Cl4I) is missing (Hartzell and Qu, 2003). In order to understand the contribution of various Cl ion channels to transepithelial transport the identification of the apical and basolateral channels is required and is, to date, unknown. Cellular pH might be regulated by basolateral Cl/ HCO 3 exchangers and linked Cl cycling through ClC-2. In support of this, ClC-2 is activated by an increased intracellular Cl concentration (Catalan et al., 2004; Niemeyer et al., 2003; Pusch et al., 1999) as well as by extracellular acidification (Edelman et al., 1994a; Jordt and Jentsch, 1997). ClC-3, -5 and -7 transcripts have been found in RPE cells, but neither has been investigated functionally (Kasper et al., 2005; Kornak et al., 2001; Stobrawa et al., 2001). In general, these channels are located on intracellular vesicles, endosomes, and lysosomes. Their disruption might impair the acidification of intracellular compartments. Whether or not ClC-3 channels may get to the cell membrane is controversial (Coca-Prados et al., 1996; Do et al., 2005; Duan et al., 1999; Hara-Chikuma et al., 2005; Jentsch et al., 2005b, c). ClC-3, -5 and -7 channels may provide an electric shunt for the H+-ATPase in acidic intracellular compartments like endosomes, and ClC-7 to a large degree to lysosomes, and therefore are likely involved in processes like endocytosis (Hartzell et al., 2005b; Kasper et al., 2005; Kornak et al., 2001; Piwon et al., 2000; Stobrawa et al., 2001). An important RPE cell function, phagocytosis, depends on vesicular membrane trafficking, lysosomal fusion, phagolysosomal maturation, and digestion (Besharse and Defoe, 1998; Hartzell et al., 2005b). Lipofuscin granules which originate from phagocytosis accumulate with age in the RPE, the largest increase occurring after the first decade of life in humans (Delori et al., 2001). Intracellular Cl ion channels are involved in regulating pH and ionic composition of functionally different organellar compartments. Perturbation of the ionic composition of cell organelles by inhibition of the V type ATPase or by addition of a Na+ ionophor impairs RPE functions like secretion of interphotoreceptor retinoid-binding protein, leading to lysosomal dysfunction and inhibition of phagocytosis of photoreceptor outer segments (Deguchi et al., 1994; Edwards et al., 1987; Mahon et al., 2004; Peters et al., 2006; Sundelin et al., 1998; Sundelin and Terman, 2002; Toimela et al., 1998). Therefore, regulation of vesicular [Cl] is important in RPE cells in daily processes. Some interference might not be obvious immediately, but might still bear some age-related pathophysiological implications. ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 4.3.2. CFTR 4.3.2.1. CFTR in general. CFTR resides at the membrane surfaces and in endosomes in various epithelia, is involved in transepithelial fluid transport. In some epithelia (e.g. colon) CFTR represents the major apical Cl conductance (Begenisich and Melvin, 1998; Greger, 2000; Jentsch et al., 2002). A genetic defect in CFTR causes cystic fibrosis, a life threatening disease characterized by the clogged ducts or tubes of various organs by mucus or other secretions (Fuller and Benos, 1992; Thiagarajah and Verkman, 2003). CFTR belongs to the traffic ATPases or so called ABC transporters, but represents the only protein in that family which was identified as ion channel (Anderson et al., 1991). Intracellularely, CFTR contains two nucleotide binding domains (NBD1 and NBD2) separated by a large polar regulatory domain with nine sites for phosphorylation by PKA and seven sites for phosphorylation by PKC (Riordan et al., 1989). ATP-driven conformational changes by binding of ATP, which in other ABC proteins fuels uphill substrate transport across cellular membranes, in CFTR, opens and closes a gate to allow transmembrane flow of anions down their electrochemical gradient (Gadsby et al., 2006; Vergani et al., 2005). Furthermore, cAMP-dependent activation of PKA activates CFTR channels, which are voltage independent and display a permeability sequence of Br 4Cl4I4F (Dawson et al., 1999; Li et al., 1988; McCarty, 2000). Besides its Cl channel function, CFTR might be involved in the regulation of other ion channels, transporters, or cellular functions like: electrolyte and osmolyte transport, cell volume regulation, efflux of ATP through CFTR channels or CFTR regulated ATP release by vesicles, inhibition of epithelial sodium channel (ENaC), CaCC and VRAC. 4.3.2.2. CFTR of the RPE. Human RPE cells display CFTR mRNA expression and CFTR protein has been immunolocalized to the apical and basolateral membranes. A cAMP-dependent increase in transepithelial Cl transport or conductance indicates a functional role of CFTR in the RPE (Fig. 5) (Blaug et al., 2003; Hartzell et al., 2005b; Hughes and Segawa, 1993; Loewen et al., 2003; Quinn et al., 2001; Reigada and Mitchell, 2005; Weng et al., 2002; Wills et al., 2000). A main lead for CFTR in RPE function stems from the fact that part of the transepithelial Cl transport and net fluid absorption is dependent on cAMP-activated Cl conductance (Gallemore et al., 1997). An increase of [cAMP]i in foetal human RPE induces a decrease in basolateral membrane resistance and the activation of a Cl conductance (Weng et al., 2002). Thereby intracellular Cl decreases and generates a depolarization. Moreover, cAMP increases short circuit current, increases transepithelial potential, and decreases the ratio of basolateral to apical resistance (Hughes et al., 1987, 1988; Miller and Farber, 1984). Although these data suggest an increase in basolateral conductance, the effects are complex, possibly 277 reflecting different transport pathways. ClC-2 is another possible cAMP-activated candidate. ClC-2 is also a cAMP activated Cl channel with a NO 3 ¼ I 4Br 4Cl b HCO3 permeability sequence (Hughes and Segawa, 1993). From studies of CFTR /ClC-2 double knockout mice it was concluded that ClC-2 does not compensate for CFTR (Zdebik et al., 2004), suggesting that CFTR and ClC-2 have differential roles for Cl ion efflux regulation. Another line of observations supports a different or additional role for CFTR in RPE cells. RPE cells release ATP and its release mechanism has been linked to CFTR Cl channels in various epithelial cells, including RPE. cAMP-activating RPE cell manipulation led to increased apical ATP release whereas glibenclamide and the more specific inhibitor CFTR-172 (Ma et al., 2002) prevented hypotonically triggered ATP release. A precise pathway for the release of Cl and ATP in RPE cells and the relationship to CFTR remains controversial (Braunstein et al., 2001; Prat et al., 1996; Reigada and Mitchell, 2005). 4.3.3. Ca2+-activated Cl channels 4.3.3.1. Ca2+-activated Cl channels in general. Chloride channels activated by intracellular calcium (CaCC) are widely expressed. Voltage-dependence and Cl concentration gradients allow Cl influx or efflux that produces hyperpolarization or depolarization, respectively. CaCC conductances are implicated in diverse functions like transepithelial fluid transport, excitability modulation, and regulation of smooth muscle cell tonus. Endogenous calcium activated Cl currents are voltage-dependent (outwardly rectifying), and display a SCN4NO 3 4I 4 Br 4Cl 4F permeability sequence. The voltage-dependence disappears with high [Ca2+]i (Begenisich and Melvin, 1998; Eggermont, 2004; Hartzell et al., 2005a; Jentsch et al., 2002; Kidd and Thorn, 2000; Melvin, 1999; Morris, 1999; Nilius and Droogmans, 2003; Scott et al., 1995; Suzuki et al., 2006). So far at least three potential classes of CaCC have been suggested: (i) activated by increased [Ca2+]i, (ii) regulated by calmodulin-dependent protein kinase II, and (iii) cGMP-dependent channel types (Jentsch et al., 2002; Matchkov et al., 2004). Putative candidate proteins (e.g. CLCA, bestrophin) have been cloned from various species (Bakall et al., 1999; Gandhi et al., 1998; Marquardt et al., 1998; Stohr et al., 2005; White et al., 2000), but the correlation of biophysical properties of heterologously expressed channels to native calcium dependent Cl currents are still unsolved or controversial (Fuller et al., 2001; Jentsch et al., 2002; Loewen et al., 2002a; Nilius and Droogmans, 2003; Pauli et al., 2000). Bestrophins have been shown to be anion-selective channels and are activated by physiological [Ca2+]i in heterologous expression systems (Fischmeister and Hartzell, 2005; Hartzell et al., 2005b; Hartzell and Qu, 2003; Qu et al., 2003, 2004, 2006b; Qu and Hartzell, 2004; Sun et al., 2002; Tsunenari et al., 2006). Four bestrophin isoforms have been discovered, all of which generate membrane currents in ARTICLE IN PRESS 278 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 transfected HEK293 cells and two of them with a I4 Br4Cl permeability sequence matching endogenous CaCC (Qu et al., 2004, 2006b; Qu and Hartzell, 2004; Sun et al., 2002; Tsunenari et al., 2006). But heterologously expressed CLCAs and bestrophins showed instantaneous but not time dependent, outwardly rectifying currents as characteristic for endogenous CaCC. Other studies suggest that CLCAs and bestrophins might not only constitute a Cl channel itself, but also modulate other ion channels (Loewen et al., 2002a, b, 2003; Marmorstein et al., 2004, 2006; Pusch, 2004; Rosenthal et al., 2006). 4.3.3.2. Ca2+-activated Cl channels in the RPE. Indirect evidence from choroid-RPE preparations suggests that CaCC might be the light-induced basolateral Cl conductance important for fluid, and possibly volume regulation, in the RPE (Fig. 5). Extracellular epinephrine and ATP activate calcium signalling, basolateral Cl conductance, and fluid absorption in RPE cells (Edelman and Miller, 1991; Joseph and Miller, 1991; Leipziger, 2003; Lin and Miller, 1991; Peterson et al., 1997). ATP is currently still discussed as a factor activating fluid transport across RPE cells due to illumination (light-peak substance) and triggering this fluid absorption by stimulating apical P2Y2 receptors with a specific agonist can reduce the size of fluid blebs in the subretinal space in vivo (Maminishkis et al., 2002; Meyer et al., 2002). External application of DIDS (an unspecific Cl channel blocker) reduced basolateral Cl conductance and fluid absorption and therefore CaCC are suggested to be important for fluid and ion transport regulation across the RPE (Bultmann and Starke, 1994; Edelman et al., 1994a; Gallemore et al., 1997; Peterson et al., 1997; Quinn et al., 2001; Soltoff et al., 1993; Ziganshin et al., 1996). CaCC have been shown to be present in Xenopus, rat, and mice RPE cells by patchclamp measurements (Botchkin and Matthews, 1993; Hartzell and Qu, 2003; Marmorstein et al., 2006; Strauss et al., 1996, 1998a, 1999; Ueda and Steinberg, 1994; Wollmann et al., 2006). InsP3 induced calcium influx into the cell activates a Cl conductance, which was inhibitable by DIDS, but not flufenamic acid or Zn+. The currents showed outward rectification, a fast voltage-dependent activation, and transient activation depending on [Ca2+]i. Direct application of a high intracellular Ca2+ concentration activates these currents as well. VMD2 (hBest1), was originally positionally cloned from families with Best’s vitelliform macular dystrophy (Marquardt et al., 2000; Petrukhin et al., 1998; Stanton et al., 2006; Stohr et al., 2002; White et al., 2000) and its gene product was recently suggested as a novel prospective Cl channel candidate expressed by the RPE (Fischmeister and Hartzell, 2005; Hagen et al., 2005; Qu et al., 2004, 2006b; Qu and Hartzell, 2004; Stanton et al., 2006; Sun et al., 2002; Tsunenari et al., 2003, 2006). hBest1 and hBest2, are highly expressed in the RPE (Bakall et al., 2003; Kramer et al., 2004; Marmorstein et al., 2000; Stohr et al., 2002). Best patients have a reduced light-peak propably caused by a reduced basolateral Cl conductance. Heterologeous expression of the VMD2 gene product bestrophin-1 in the human kidney cell line HEK293 results in an increase in the membrane conductance for Cl, which was dependent on increased intracellular free Ca2+ (Sun et al., 2002). Sidedirected mutagenesis of the putative pore region of the channel protein resulted in a change of the permeability for SCN ions of the channel (Qu et al., 2004, 2006a; Qu and Hartzell, 2004). 4.3.4. Volume regulated anion channels 4.3.4.1. Volume regulated anion channels in general. Volume regulated anion channels (VRAC) are ubiquitously expressed in mammalian cells and play an important role in cell volume homoeostasis (Clapham, 1998; d’Anglemont de Tassigny et al., 2003; Hoffman et al., 1998; Hoffmann, 1992; Lang et al., 1998a, b, 2005; Nilius and Droogmans, 2003; Nilius et al., 1997; Okada, 2004; Okada and Maeno, 2001; Okada et al., 2001; Sardini et al., 2003). Small cell volume changes might even be linked to vectorial transport of solutes and water across epithelia (Foskett, 1990). The activation of VRAC is believed to provide one of the initial triggers linking cell swelling to the subsequent loss of KCl through Cl and K+ channels—osmolyte and water efflux resulting in a RVD. The associated current is referred to as ICl,swell. In experimental setups, exposure to hypotonic solutions is the common technique to swell cells. In most cells this manoeuvre activates outwardly rectifying anion channels (anion influx), which are voltage-dependent (inactivate at positive membrane potentials in many, but not all cell types), depend on intracellular ATP, and exhibit an anion selectivity of SCN 4I 4NO 3 4Br 4Cl 4 F 4glutamate . This conductance is also regulated by cell shrinkage (exposure to hypertonic solution is the common experimental manoeuvre) and in some cells a similar conductance initiated by the hypotonic solution appears to develop spontaneously under isotonic conditions, which can be suppressed by exposure to hypertonic solutions. Moreover, ICl,swell may be activated by a reduction in intracellular ion strength, shear stress, and application of GTPgS. Some lines of evidence suggest that VRAC is also permeable to lactate and bicarbonate pointing to a role in pH regulation. This putative channel was named volumestimulated osmolyte and anion channel (VSOAC) and depends like VRAC on intracellular ATP (Jackson et al., 1994). Besides ICl,swell, other ion channels (e.g. ClC-2, bestrophin, maxi-Cl channel) appeared to be volumeactivated as well, but display discernable biophysical characteristics. Besides these mentioned candidates others have been proposed, but none of these has yet received acceptance (Clapham, 1998; Jentsch et al., 2002; Pusch, 2004). ICl,swell may also be important for other processes including regulation of membrane excitability, transcellular Cl transport, cell proliferation, release of nucleotides (e.g. ATP), and apoptosis. VRAC may not be a single entity, but may instead stand for several different ion channels (Lang et al., 1993, 1998b; Nilius et al., 1996). ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 4.3.4.2. Volume regulated anion channels in the RPE. Epithelial cells involved in transepithelial transport need to balance their ion transport rates to maintain their volume within certain limits. Furthermore, RPE cells phagocytose photoreceptor outer segments at a high rate likely challenging cell volume and maybe leading to successive osmolarity changes, which must be compensated (Hartzell et al., 2005b; Nguyen-Legros and Hicks, 2000; Strauss, 2005; Wettstein et al., 2000). Hypoosmotic swelling inhibits RPE phagocytosis and suggests that cell volume regulation and phagocytic functions are linked (Irschick et al., 2006). The RPE is likely exposed to lightdependent osmotic challenge, as photoreceptor activity alters the solute composition in the restrictive volume of the subretinal space (Bialek and Miller, 1994; Borgula et al., 1989; Dmitriev et al., 1999; Huang and Karwoski, 1992; Li et al., 1994b; Oakley and Steinberg, 1982; Shirao et al., 1987). And it has been demonstrated that iso-osmotic changes in RPE cell volume affect the level of RPE-retina adhesivity (Marmor, 2005) and also alter the volume of the subretinal space (Adorante, 1995; Adorante and Edelman, 1997; Adorante and Miller, 1990; Bialek and Miller, 1994). Moreover, transepithelial salt and water transport could place an additional osmotic load on the RPE cell. Hypotonic swelling of RPE cells in vitro leads to a RVD (Fig. 5) due to parallel efflux of Cl and K+ through respective ion channels (Adorante, 1995; Civan et al., 1994). Inhibition of RVD by both basal Ba2+ (blocking K+ channels) and elevated basal K+ strongly suggests the RVD is mediated by K+ efflux across the basolateral membrane (Adorante, 1995; Hughes et al., 1988; Immel and Steinberg, 1986; Kennedy, 1994). The K+-induced depolarization also reduced the driving force for conductive Cl efflux across the basolateral membrane. Therefore, cell swelling is most likely due to a decrease in the driving force for K+ and Cl efflux across the basolateral membrane during continued solute uptake by the electroneutral Na+-K+-2Cl and electrogenic Na+/HCO 3 cotransporters located at the apical membrane of the RPE (Hughes et al., 1988, 1989; la Cour, 1991a, b). RPE cell shrinkage in vitro produces RVI likely reflecting the work of ion antiporter under baseline conditions. Na+ -K+-2Cl cotransporter activation likely increases [Cl]i as has been discussed for fluid transport and, therefore, might again be coupled to a Cl efflux through ion channels. In RPE cells, application of intracellular pressure or decrease in extracellular osmolarity induced cell swelling and activation of outwardly rectifying currents. These currents showed time-dependent inactivation and were inhibited by DIDS, SIDS. In addition, the currents were sensitive to the potential VRAC blockers niflumic acid and anthracene-9-carboxylic acid (Botchkin and Matthews, 1993; Fischmeister and Hartzell, 2005; Ueda and Steinberg, 1994). Cell swelling increased Cl conductance by as much as 5- to 13-fold. The mechanism of activation of the swelling activated Cl conductance is not identified yet, and could consist of, or be modulated by, Ca2+-activated 279 channels. The latter hypothesis stems from the observation that hyperosmotic shrinkage of RPE cells suppressed part of the Cl current and that heterologous expression of hBest1 induced Cl currents are likewise profoundly inhibited by that manoeuvre (Fischmeister and Hartzell, 2005). Among other candidate volume sensitive channels ClC-3 (CLCN3), ICln (CLNS1A) and bestrophin (VMD2) is located in RPE (NEI EST search; http://neibank.nei. nih.gov/). 4.3.5. Other Cl channels There are further well-characterized putative anion channels not mentioned in this review. Searching NCBI Geo database profiles (http://www.ncbi.nlm.nih.gov/geo/) (Barrett et al., 2005) of the genes expressed in the human RPE determined through serial analysis of gene expression (SAGE) and both in the human and in the mouse RPE/ choroid library of EST (http://neibank.nei.nih.gov/) yielded nonconfirmed data on expression of CLICs, GABAA receptors, MCLC and Tweety. GABA (g-aminobutyric acid) A and C receptors are ligand-gated Cl channels, whereas GABA B receptors are metabotropic receptors (Chebib and Johnston, 1999; Hevers and Luddens, 1998; Jentsch et al., 2002). GABAA and GABAC receptors are biochemically, pharmacologically, and physiologically different. Currently, there are 16 human GABAA receptor subunits (a1–6, b1–4, g1–4, d, e) and two human GABAC receptor subunits (r1 and r2) that have been cloned. GABAA receptor subunits GABRa2, GABRa6, GABRb1, GABRg2, GABRd, GABRe and GABRp appeared in NCBI Geo database for native or cultured RPE cells. Using antibodies recognizing GABAA receptor subunit b2 and b3 showed positive immunoreactivity for human and rat RPE in cultured cells, and distinctive bands at two different molecular masses in Western blot data (Wood and Osborne, 1996). And, benzodiazepine binding sites on rat, monkey, and human RPE cells support the notion of functional GABAA receptors on RPE cells (Robbins and Ikeda, 1989; Zarbin and Anholt, 1991), but the details still need to be elucidated. The Cl intracellular channel (CLIC1, 4, 5, 6), MID-1related Cl channel (MCLC) and TTYH1–3, human homologues of the Drosophila melanogaster Tweety (tty) genes suggested to represent novel maxi-Cl channel proteins (Suzuki et al., 2006) have not been investigated in RPE cells. 5. Ca2+ 5.1. Ca2+ and cell function in general Ca2+ ions have a high affinity to proteins (Carafoli, 2005a, b; Williams, 1974, 1994). The binding of Ca2+ to proteins results in changes of their conformation and subsequent alteration of the protein function (Carafoli, 2005a, b; Williams, 1974, 1994). With these characteristics, ARTICLE IN PRESS 280 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 the functional role of Ca2+ differs from that of many other ions. It can directly act as a modifier of protein function and, thus, regulate cell function. In many different tissues, Ca2+ was found to act in the initiation or modulation of contraction, secretion, gene expression, migration, apoptosis, necrosis, cell division, endocytosis, coagulation, excitation, energy metabolism, and signal transduction (Berridge, 2005; Carafoli, 2005a; Shuttleworth, 1997; Williams, 1974). Ca2+ controls these functions either by directly triggering protein interaction such as in excitation–contraction coupling or by acting as a secondmessenger, activated in response to extracellular stimuli (Berridge et al., 2003; Berridge et al., 2000). Small changes in Ca2+ concentration can have profound changes in cell function. Normally, cells keep the concentration of intracellular free Ca2+ very low (at a proximal 100 nM) and maintain a concentration gradient of 1:10,000 between intracellular space and extracellular environment, although their total intracellular Ca2+ content can be quite high (Berridge et al., 2000, 2003; Carafoli, 2005a; Saris and Carafoli, 2005). To keep the concentration of intracellular free Ca2+ low, cells use energy to store Ca2+ in intracellular compartments such as mitochondria or intracellular Ca2+ stores of the endoplasmic or sarcoplasmic reticulum (Berridge et al., 2000, 2003; Carafoli, 2005a; Saris and Carafoli, 2005). Ca2+-induced changes in cell function are triggered by an increase in intracellular free Ca2+. The specificity of this signal is encoded by the complex pattern of each Ca2+ signal which follows a specific stimulus (Berridge, 2005; Berridge et al., 2000, 2003). These patterns differ in the amplitude, and the spatial- and time-dependent distribution inside the cell. The need for a tight control of a low intracellular Ca2+ concentration at rest and the generation of complex patterns of Ca2+ increases during stimulation requires the presence of many different Ca2+ transporting proteins, such as Ca2+ conducting ion channels, Ca2+ cotransporters, and Ca2+pumps—as well as the presence of Ca2+ binding proteins (Berridge, 2005; Berridge et al., 2000, 2003). Thus the specificity of Ca2+ signals arises from recruitment of specific sets of Ca2+ transporting or Ca2+ binding proteins (Berridge, 2005; Berridge et al., 2000, 2003; Carafoli, 2005a; Saris and Carafoli, 2005; Williams, 1994). 5.2. Ca2+ homeostasis in the RPE RPE cells contain with 15 mmol/l higher amounts of Ca2+ than other cells (Bellhorn and Lewis, 1976; Fishman et al., 1977; Hess, 1975; Salceda and Riesgo-Escovar, 1990; Ulshafer et al., 1990). Large amounts of this Ca2+ are stored in melanosomes (Boulton, 1991; Boulton and Dayhaw-Barker, 2001; Drager, 1985; Hess, 1975; Ulshafer et al., 1990). To handle large amounts of Ca2+ the RPE possesses several Ca2+ transporting proteins. A Na+/Ca2+ exchanger eliminates Ca2+ from the intracellular space in exchange with 3 Na+ ions (Fijisawa et al., 1993; Loeffler and Mangini, 1998; Mangini et al., 1997; Salceda, 1989). In immunohistochemical studies, the transporter could be identified as the cardiac subtype of Na+/Ca2+ exchanger (Loeffler and Mangini, 1998), which is also found in cardiac myocytes and eliminates Ca2+ from the intracellular space to initiate the rhythmic relaxation of the myocardium. This Na+/Ca2+ exchanger represents a very efficient Ca2+ transport system to extrude Ca2+ from the intracellular space. Thus, the changes in intracellular free Ca2+ in RPE cells can have the same efficient dynamics as in cardiac myocytes. Due to its stoichiometry of 1 Ca2+ exchanged with 3 Na+, the Na+/Ca2+ exchanger is an electrogenic transporter. Accordingly, elimination of Ca2+ from the intracellular space should lead to moderate cell depolarization. On the other hand, strong depolarization of the cell can change the transport direction in the way that the Na+/Ca2+ exchanger now transports Ca2+from the extracellular space into the cell. The extrusion of Ca2+ from the cytosol by the Na+/Ca2+ exchanger is supported by the activity of the plasma membrane Ca2+-ATPase which hydrolyzes ATP for an active transport of Ca2+ out of the cell against its concentration gradient into the extracellular space (Kennedy and Mangini, 1996). Furthermore, like many epithelia, RPE cells are connected to each other via gap junctions, forming a functional syncytium (Gomes et al., 2003; Himpens et al., 1999; Himpens and Vereecke, 2000; Pearson et al., 2004; Stalmans and Himpens, 1997). The cell-to-cell connection via gap junction channels enables Ca2+ signals to spread between the cells within the epithelial monolayer. Thus, increases in intracellular free Ca2+ can influence the function of the entire RPE. In the past, a large number of receptors, which stimulate an increase in intracellular free Ca2+ as a second messenger have been identified in the RPE. Most of these receptors act via stimulation of G proteins or tyrosine kinase activity to initiate a formation and release of InsP3 into the cytosol. InsP3 activates a release of Ca2+ from InsP3 sensitive cytosolic Ca2+ stores (Ammar et al., 1998; Berridge, 2005; Berridge et al., 2000, 2003; Crook and Polansky, 1992; Feldman et al., 1991; Fragoso and Lopez-Colome, 1999; Karihaloo et al., 1997; Kuriyama et al., 1992; Mergler and Strauss, 2002; Nakashima et al., 1989; Strauss et al., 1996). This in turn can stimulate an increase in the membrane permeability for Ca2+ and an influx of extracellular Ca2+ into the cell. The latter event results in a sustained Ca2+ increase and a long-lasting change in cell function (Berridge, 2005; Berridge et al., 2000, 2003). However, some receptors, ionotropic glutamate receptors or purinergic P2X receptors, function as ligand-gated ion channels and directly increase intracellular free Ca2+ (Ryan et al., 1999). Other receptors such as purinergic P2Y receptors increase intracellular free Ca2+ by release of Ca2+ only from cytosolic Ca2+ stores without generating an influx of Ca2+ into the cell (Collison et al., 2005; Mitchell, 2001; Peterson et al., 1997; Poyer et al., 1996; Ryan et al., 1999; Sullivan et al., 1997). In general, a sustained increase in ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 intracellular free Ca2+ requires an influx of extracellular Ca2+ into the cell and, thus, the presence of Ca2+-conducting ion channels. Thus the understanding of the Ca2+-dependent regulation of RPE cell function was substantially improved with patch-clamp studies on RPE cells uncovering the expression of different Ca2+ channels. 5.3. Ca2+ and RPE function As stated above, the RPE has many functions which are essential to maintain structural integrity and excitability of photoreceptors (Bok, 1993; Steinberg, 1985; Strauss, 2005). Many of these functions are regulated by changes in intracellular free Ca2+. These are: Dark adaptation of photoreceptor activity: This occurs by Ca2+-dependent mechanisms inside the photoreceptor outer segments (Korenbrot, 1995; Korenbrot and Rebrik, 2002). The required Ca2+ enters the photoreceptor outer segments through cGMP-gated cation channels, which are open in the dark and conduct Ca2+. The subretinal Ca2+ concentration in the dark is larger than in the light (Gallemore et al., 1994). A Ca2+ source for this increase in subretinal Ca2+ might be melanosomes of the RPE (Drager, 1985; Hess, 1975; Lavallee et al., 2003; Moriya et al., 1996; Salceda and SanchezChavez, 2000) which is suggested by the finding that albino rats show slower dark adaptation than normal pigmented rats (Behn et al., 2003). Transepithelial transport of ions and water: Increases in intracellular free Ca2+ achieved either using a Ca2+ ionophore (Joseph and Miller, 1992) or by the stimulation of a-adrenergic (Edelman and Miller, 1991; Joseph and Miller, 1992; Nash and Osborne, 1995; Quinn and Miller, 1992; Quinn et al., 2001; Rymer et al., 2001) or purinergic receptors (Maminishkis et al., 2002; Mitchell, 2001; Peterson et al., 1997; Ryan et al., 1999; Sullivan et al., 1997) were found to stimulate Cl and water transport by RPE cells. The Ca2+-dependent stimulation of transepithelial Cl transport occurs by three mechanisms. One is by modulation of the electrical driving forces for ions to move across the cell membrane (Edelman et al., 1994b). This is achieved by Ca2+-dependent opening of non-specific cation channels, K+ or Cl channels and subsequent changes in the resting potential (Bialek et al., 1996; Fischmeister and Hartzell, 2005; Hu et al., 1996; Joseph and Miller, 1992; Miller and Edelman, 1990; Quinn and Miller, 1992; Ryan et al., 1999; Ryan and Kelly, 1998; Sheu and Wu, 2003; Sheu et al., 2004; Strauss et al., 1996; Sun et al., 2002; Tao and Kelly, 1996). The second mechanism is opening of Ca2+-dependent Cl channels in the basolateral membrane (Hartzell and Qu, 2003; Qu et al., 2004; Quinn et al., 2001; Strauss et al., 1996, 1999; Ueda and Steinberg, 1994). The third mechanism occurs via the activation of apically located K+ channels (see Section 3). 281 Phagocytosis: Studies on the regulation of phagocytosis imply that the stimulation of increases in intracellular free Ca2+ has a regulatory function (Greenberger and Besharse, 1985; Hall et al., 1991; Heth and Marescalchi, 1994; Nakashima et al., 1989; Nguyen-Legros and Hicks, 2000; Strauss et al., 1998b). However, the role of the rise in intracellular free Ca2+ is not clear. Since a participation of the InsP3 second messenger system was found to play a role in the initiation of phagocytosis (Heth and Marescalchi, 1994) an increase in intracellular free Ca2+ should represent a starting signal for phagocytosis (Berridge et al., 2003). However, in another study an increase in intracellular free Ca2+ and subsequent activation of protein kinase C (PKC) was described as a shut-off signal for phagocytosis (Hall et al., 1991). These contradictory observations may be explained by different patterns of Ca2+ increases underlying these two different regulatory effects. Secretion: Since in many tissues exocytosis and secretion are known to be triggered by an increase in intracellularfree Ca2+, it is likely that these processes are triggered by Ca2+ in the RPE (Barg, 2003; Berridge et al., 2000; Mears, 2004; Satin, 2000; Shuttleworth, 1997). Stimulation by ATP or various growth factors is known to induce secretion of growth factor by the RPE (Guillonneau et al., 1997; Mitchell, 2001; Reigada and Mitchell, 2005; Rosenthal et al., 2004, 2005; Slomiany and Rosenzweig, 2004a, b). Since stimulation of the RPE by growth factors (Rosenthal et al., 2004, 2005) as well as by ATP (Mitchell, 2001; Peterson et al., 1997; Ryan et al., 1999) have been described to result in an increase in intracellular free Ca2+ it is very likely that these increases in cytosolic Ca2+ not only represent a signal to change gene expression (Rosenthal et al., 2005) but also to trigger the release of other growth factors (Rosenthal et al., 2004, 2005). Differentiation: In general, growth factor-dependent changes in gene expression were described to arise from increases in intracellular free Ca2+. The underlying changes in the gene expression are achieved by Ca2+activated phosphorylation of transcription factors (Fields et al., 2005). Stimulation of the RPE by basic fibroblast growth factor (bFGF) leads to an increase in intracellular free Ca2+ as well as to changes in the expression of the immediate early gene c-fos (Rosenthal et al., 2005). In summary, a lot of RPE functions to maintain visual function are controlled by increases in intracellular-free Ca2+. Thus, Ca2+ channels, which provide major routes for an influx of extracellular Ca2+ into the cell to increase intracellular-free Ca2+ must play an important role in the control of these functions. 5.4. Ca2+ channels of the RPE So far three types of Ca2+-conducting ion channels have been described in the RPE: voltage-dependent Ca2+ ARTICLE IN PRESS 282 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 channels, members of transient receptor potential (TRP) channel family and ligand-gated Ca2+-conducting, nonselective cation channels. 5.4.1. Voltage-dependent Ca2+ channels 5.4.1.1. Voltage-dependent Ca2+ channels in general. Voltage-gated Ca2+ channels are highly specific Ca2+conducting channels which are mainly activated by changes of the membrane potential toward more positive values (i.e., by depolarization) (Catterall, 1998, 2000; Catterall et al., 2005; Striessnig, 1999; Striessnig et al., 2004). Ten voltage-dependent Ca2+ channels have been described differing in their voltage-dependence, kinetic behaviour, and pharmacology. The 10 different channels share a common molecular architecture. They are composed of an a1-subunit, a b-subunit, an a2d subunit, and in some cases a g subunit. The a1-subunit forms the ion-conducting pore and defines the pharmacological, electrophysiological, and kinetic characteristics of the channel. The 10 different channel types can be subdivided into the following subfamilies: L-type channels (CaV1.1–1.4 or a1S, C, D and F), N, P/Q and R-type channels (CaV2.1–2.3 or a1A, B and E) and the T-type channels (CaV3.1–3.3 or a1G–I). The known four b-subunits modify channel activity, blocker sensitivity, and targeting of the a1-subunits to the plasma membrane. In addition, nine different g subunits and 4 different a2d subunits have been identified. Members of both subunit types may be involved in intracellular targeting of the a1 subunits and influence the electrophysiological properties of the Ca2+ channels. 2+ 5.4.1.2. The voltage-dependent Ca channels of the RPE. So far only one subtype of voltage-dependent Ca2+ channel has been characterized in detail in RPE cells (Fig. 6). Ca2+ channels in cultured or in freshly isolated RPE cells from various species including man were characterized by patch-clamp recordings of whole-cell Ba2+ or Ca2+ currents (Rosenthal and Strauss, 2002; Sakai and Saito, 1997; Strauss et al., 1997, 2000; StrauX and Wienrich, 1994; Ueda and Steinberg, 1993, 1995; Wollmann et al., 2006). The usage of Ba2+ as a charge carrier is a commonly used tool to study L-type Ca2+ channels because these channels display larger Ba2+ than Ca2+ currents. RPE cells responded to depolarization to potentials more positive than 30 mV with fast activating and much more slowly inactivating inward currents (Fig. 6) (Mergler and Strauss, 2002; Rosenthal et al., 2006; Sakai and Saito, 1997; Ueda and Steinberg, 1993, 1995; Wollmann et al., 2006). These currents are modulated by dihydropyridine derivatives. Dihydropyridines specifically modulate the activity of L-type channels. For example BayK8644 stimulates L-type channel activity whereas nifedipine or nimodipine inhibit L-type channels. In the RPE, application of the Ca2+ channel activator BayK8644 resulted in larger currents whereas the Ca2+ channel blocker nifedipine decreased the inward currents (Rosenthal et al., 2001, 2006; Rosenthal and Strauss, a Nystatin 10 mM Ba2+ RPE Whole-cell currents b + 20 mV -70 mV c 0.5 nA 20 ms d -80 Pipette potential (mV) -60 -40 -20 20 -800 control BayK 8644 (5 µM) -1600 Membrane current (pA) Fig. 6. Example of voltage-dependent Ba2+ currents in cultured human RPE cells indicating the presence L-type Ca2+ channels. (a) Schematic diagram illustrating the recording technique: the patch-pipette which is attached to the RPE cell enables a voltage-clamp of the cell membrane potential as well as measurements of membrane currents at different potentials. The pipette contains a solution which mimicks the ion composition of the intracellular space. Furthermore, the pipette solution contains an ionophore (nystatin), which perforates the membrane patch inside the inner diameter of the pipette. With this configuration, membrane currents could be measured without disturbance of the intracellular milieu, which is essential to measure stable L-type channel currents. Pipette and bath solution are K+-free to prevent the measurement of K+ currents superimposed to the Ca2+ channel currents. In addition, the bath solution contains Ba2+ as a charge carrier for Ca2+ channel currents because with Ba2+ as a charge carrier Ca2+ channels display larger currents. (b) Electrical stimulation to activate currents through Ca2+ channels: from the holding potential of 70 mV the cells were depolarized with nine voltage steps of 50 ms duration and +10 mV increment. (c) Ba2+ currents activated by the stimulation protocol shown in 6B in a cultured human RPE cell. (d) Current/voltage plot of the currents shown in Fig. 6C: the maximal current amplitudes were plotted against the potentials of the stimulation protocol. Furthermore, the effect of the L-type channel opener BayK8644 is shown in this diagram. 2002; Sakai and Saito, 1997; Ueda and Steinberg, 1993; Wollmann et al., 2006). These properties are characteristic for L-type channels and were observed in RPE cells in primary culture, RPE cell lines, and in freshly isolated RPE cells. Despite the fact that between the different studies L-type currents showed some differences in inactivation, ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 voltage-dependence, and dihydropyridine sensitivity, all studies concluded that L-type channels represent the major type of voltage-dependent Ca2+ channel in the RPE (Rosenthal et al., 2006; Ueda and Steinberg, 1993; Wollmann et al., 2006). Recently, it could be shown that systemic application of the L-type channel blocker nimodipine led to a reduction of the light-peak amplitude in the rat direct-current electro-retinogram (DC-ERG) (Rosenthal et al., 2006). Thus, these data indicate the functional presence of L-type channels in the RPE of an intact eye. Using Western blot techniques, the L-type a1 subunit was identified as the a1D or CaV1.3 subunit or the neuroendocrine subtype of L-type channels (Rosenthal et al., 2001, 2006; Strauss et al., 2000; Wollmann et al., 2006). In the rat RPE cell line RPE-J, and in cultured mouse RPE cells, this L-type channel appeared to be the major subtype. The conclusion that CaV1.3 subunits mainly form the L-type Ca2+ channel pore is supported by the fact that rather high concentrations of dihydropyridine derivatives were required to decrease Ba2+ currents in RPE cells (Rosenthal et al., 2006; Strauss et al., 1997). A low sensitivity to dihydropyridines has been reported to be characteristic for CaV1.3 when heterologousely expressed (Koschak et al., 2001, 2003; Scholze et al., 2001). Finally, RPE cells mainly express a splicing variant of CaV1.3 which has not been described thus far (Rosenthal et al., 2006). It might be that properties of this splicing variant could explain the differences between L-type currents in RPE cells and those in other tissues or heterologeous expression systems. 5.4.1.3. Role of voltage-dependent Ca2+ channels for RPE function. The expression of CaV1.3 Ca2+ channel subunits, which are also termed as the neuroendocrine subtype 283 of L-type channels imply that these voltage-dependent Ca2+ channels play a role in the regulation of secretion. However, some questions have to be answered to conclude that this might also be their function in RPE cells (Fig. 7). The first question is whether high voltage-activated Ca2+ channels can play a functional role in retinal epithelial cells with a resting membrane potential of 40 to 45 mV. Investigation of CaV1.3-mediated currents in other cell systems showed that they have the most negative activation threshold and potential for half maximal activation among all L-type channel subtypes (Koschak et al., 2001; Michna et al., 2003; Scholze et al., 2001). Furthermore, in a study using patch-clamp techniques in combination with measurements of intracellular free Ca2+ it could be shown that L-type channels contribute to an increase in intracellular free Ca2+at membrane potentials fixed to the resting potential of RPE cells of about 40 mV (Mergler and Strauss, 2002). This effect is achieved by activation of the Ca2+/InsP3 second-messenger system. Intracellular application of InsP3 led to a phosphorylation-dependent shift in the voltage-dependence of L-type channels to more negative values, more close to the resting potential of RPE cells (Mergler and Strauss, 2002). This increased the number of open channels mediating a larger membrane conductance for Ca2+ at the resting membrane potential. The resulting influx of extracellular Ca2+ into the cell leads to an increase in cytosolic free Ca2+. A comparable mechanism was found for the bFGF-dependent stimulation of RPE cells (Rosenthal et al., 2001). Application of bFGF leads to an increase in intracellular free Ca2+ by a nifedipine-sensitive influx of Ca2+ into the cell through L-type Ca2+ channels (Mergler et al., 1998). This effect was not mediated by activation of the Ca2+/InsP3 secondmessenger system. Instead, the bFGF-dependent rise in RPE 2+ Ca st s ore Melanosomes Mit och on dri a TRPC1 NMDA receptor Glutamate Ca2+ IP3 -Adrenaline Ca2+ Ca2+ Gαq/11 -Growth factors PLC - ATP TK - AtCh Ca2+ - Secretion ATP - Phagocytosis Ca2+ - Transepithelial transport P2X receptor - Dark adaptation CaV1.3 bFGF FGFR2 Na+ Ca2+ Ca2+ PMCA NCX1 Fig. 7. Schematic diagram summarizing different Ca2+-conducting ion channels and their impact on Ca2+ homoeostasis in RPE cells. The ion channels are drawn in blue. The factors, which activate these ion channels are drawn in red. Connected second-messenger pathways are drawn in yellow (the box summarises agonists stimulating these pathways). In light blue are membrane proteins, which are not ion channels but contribute to changes in the Ca2+ homoeostasis as well. Abbreviations are: ATP ¼ adenosine triphosphate; AtCh ¼ acetyl choline; bFGF ¼ basic fibroblast growth factor; CaV1.3 ¼ a1 Ca2+ channel subunit 1.3; Gaq/11 ¼ G protein a-subunit q/11; FGFR2 ¼ fibroblast growth factor receptor 2; IP3 ¼ inositol-1,4,5-trisphosphate; NMDA ¼ N-methyl-D-aspartate; NCX-1 ¼ cardiac Na+/Ca2+ exchanger; PLC ¼ phospholipase; PMCA ¼ plasma membrane Ca2+-ATPase; P2X receptor ¼ purinergic ionotropic receptor; TK ¼ tyrosine kinase; TRPC1 ¼ transient receptor potential channel C1. ARTICLE IN PRESS 284 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 intracellular free Ca2+ results from the physical interaction (Fig. 7) between the bFGF receptor FGFR2 and the CaV1.3 subunits (Rosenthal et al., 2001). This interaction leads to tyrosine phosphorylation of the Ca2+ channel and a subsequent shift in the voltage-dependent activation towards more negative potentials, again closer to the resting potential of RPE cells. Also the resting activity of L-type channels in the RPE is dependent on interaction with a tyrosine kinase. L-type channels are constantly activated by the cytosolic tyrosine kinase pp60csrc (Strauss et al., 1997, 2000). This regulatory effect is based on a physical interaction of the CaV1.3 subunits and pp60csrc (Strauss et al., 2000). Among the serine/threonine kinases, regulation of PKC seems to have the most important impact on L-type channel activity in RPE cells. Based on the application of various blockers it was concluded that it is unlikely that protein kinase A or G have any effects on L-type channel activity (Strauss et al., 1997). PKC has two effects on L-type channel activity (Strauss et al., 1997). One is the direct activation of this channel. With basic PKC activity, pp60csrc and PKC have additive effects on the L-type channel activity. However, a second function of PKC emerges when PKC is further activated. With stimulated PKC, not only the L-type channel activity increases but also the effect of pp60csrc changes. Under these conditions pp60csrc becomes an inhibitor of L-type channel activity (Strauss et al., 1997). The underlying mechanism is not clear. It is possible that different isoforms of PKC are responsible for these two different effects of L-type Ca2+ channel regulation in RPE cells. In summary, L-type channels in the RPE contribute to changes in intracellular free Ca2+ not by changes in the membrane potential but by shifts of their voltagedependence which increases the number of open channels at the resting potential of RPE cells. The next question is, in which signalling pathways are L-type channels involved? A major regulation by tyrosine kinase implies that L-type channels in the RPE are involved in growth factordependent Ca2+ signalling because many growth factors act via stimulation of tyrosine kinase-dependent pathways. As mentioned above, this hypothesis has been proven for bFGF (Rosenthal et al., 2001). Other growth factors such as insuline-like growth factor-1 (IGF-1) are also very likely candidates as an IGF-1-dependent regulation of L-type channel activity has been shown in smooth muscle cells and the RPE is known to express IGF-1 receptors (BenceHanulec et al., 2000; Rosenthal et al., 2004; Slomiany and Rosenzweig, 2004a, b). Another question is, what changes in cell function might be achieved by increases in intracellular-free Ca2+mediated by activated L-type channels? One effect of many growth factors is their influence on cell differentiation or cell function by changes in the gene expression profile. These changes are regulated by increased expression of transcription factors (Fig. 7). In RPE cells the direct opening of L-type channels by the dihydropyridine compound BayK8644 resulted in an increased transcrip- tion rate c-fos too (Rosenthal et al., 2005). Increased c-fos expression is also induced by bFGF. However, the bFGFdependent expression of c-fos was independent from L-type channel activity. Thus stimulation of L-type channels in the RPE can change the expression of immediate early genes which is a mechanism playing a role in the growth factordependent modulation of gene expression by other growth factors than bFGF (Rosenthal et al., 2005). As stated above, the subtype of L-type channels in the RPE is the neuroendocrine subtype. This implies a role of L-type channels in the regulation of secretion. The RPE is known to secrete a variety of growth factors. Furthermore, the secretion of growth factors by the RPE is regulated by other growth factors (Campochiaro et al., 1994; Guillonneau et al., 1997; Hackett et al., 1997; Nagineni et al., 2003; Ohno-Matsui et al., 2003; Rosenthal et al., 2004; Slomiany and Rosenzweig, 2004a, b) which in some cases have been shown to stimulate L-type channels via tyrosine kinasedependent phosphorylation. Thus the prominent role of L-type channels in RPE cells is most likely the regulation of growth factor secretion. Indeed, bFGF-induced secretion of VEGF was reduced to the basic secretion rate observed in the absence of bFGF after inhibition of L-type channels (Rosenthal et al., 2005). As stated above, L-type channels seem to participate in the generation of the light-peak in the DC-ERG (Rosenthal et al., 2006). The light-peak is a signal in the human electro-oculogram (EOG, equivalent to the DC-ERG) which is thought to derive from activation of Cl channels in the basolateral membrane of the RPE (Gallemore et al., 1988; Gallemore and Steinberg, 1989a, 1993). In a recent study, it was shown that bestrophin-1, proposed to act as a Ca2+-dependent Cl channel (Qu et al., 2004; Qu and Hartzell, 2004; Sun et al., 2002), additionally regulates L-type Ca2+ channels in the RPE (Rosenthal et al., 2006). Furthermore, mutant bestrophins showed different effects on L-type channel properties. The possible interaction of the L-type channel with bestrophin-1, in other words interaction of a Ca2+ channel and a Ca2+-dependent Cl channel, would put the activation of the Ca2+-dependent Cl channel into a close feedback mechanism thereby influencing transepithelial Cl and fluid transport. In summary, L-type channels can contribute to changes in intracellular free Ca2+ at the resting potential of RPE cells. The L-type channel-dependent changes in cytosolic free Ca2+ participate in the regulation of growth factor secretion and likely in the regulation of epithelial transport of Cl and water. An influence on gene expression enables an adaptation of transcriptional activity to the underlying functional changes. To achieve this regulatory function L-type channels mainly underlie the control by PKC and tyrosine kinase activity. 5.4.2. TRP channels 5.4.2.1. TRP channels in general. TRP channels represent a large family of Ca2+-conducting cation channels (Clapham et al., 2003; Inoue, 2005; Ramsey et al., 2005). The ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 name TRP derived from the Drosophila homologue TRP. TRP channels are represented by six families with individual members who can contribute to a large variety of signalling pathways or sensory function. The family of TRPC (classic) and of the TRPM (metastatin like) channels are involved in intracellular signalling cascades due to their activation by G protein subunits, metabolites of second-messenger cascades, or by depletion of cytosolic Ca2+ stores. TRPV (vanilloid receptor) and TRPA (with ankryn repeats) channels play a role in sensory mechanisms because they can be activated by a variety of physical stimuli such as temperature or pH. One family represents channels in intracellular organelles (TRPML) and the function of the channels in other families is still unknown. 5.4.2.2. TRP channels in the RPE and their role in RPE function. Early patch-clamp studies on rat RPE cells indicated a possible presence of TRP channels (Poyer et al., 1996). Poyer et al. (1996) described G protein-activated cation channels, which were selective for many different monovalent cations. Thus, it could be that the authors described currents mediated by TRPC channels. However, the cation currents described in the study by Poyer et al. seemed not to be carried by Ca2+ and it seemed that Gaisubunits or at least pertussis toxin-sensitive G-proteins and not Gaq/11 subunits were responsible for their activation. These are not characteristic properties for TRPC channels. Nevertheless, in a recent publication, the expression of TRPC1 channels was detected in the human RPE cell line ARPE-19 (Bollimuntha et al., 2005). As mentioned above, TRPC channels are integrated into the InsP3/Ca2+ second messenger pathway (Fig. 7) either by their function as store-operated Ca2+ channels (SOCs) or by their activation by Gaq/11 subunits (Clapham et al., 2003; Inoue, 2005; Ramsey et al., 2005). In a study with combined measurements of membrane currents and changes in intracellular free Ca2+ it could be shown that together with L-type Ca2+ channels another type of Ca2+-conducting ion channel contributes to InsP3-induced increases in intracellular free Ca2+ (Mergler and Strauss, 2002). This study used a standard protocol for induction of capacitative Ca2+ influx as a standard system to explore activation of store-operated Ca2+ influx. Thereby, a component of Ca2+ conductance insensitive to blockers for L-type channels was detected. It might be that TRPC channels underlie this additional InsP3-induced membrane conductance for Ca2+. In the RPE, TRPC channels could play a role in a couple of different agonist-controlled Ca2+dependent signalling pathways. The RPE expresses P2Y (Peterson et al., 1997; Reigada et al., 2005; Reigada and Mitchell, 2005; Ryan et al., 1999; Sullivan et al., 1997), muscarinic (Feldman et al., 1991; Friedman et al., 1988; Gonzalez et al., 2004) and adrenergic receptors (Edelman and Miller, 1991; Feldman et al., 1991; Joseph and Miller, 1992; Quinn and Miller, 1992; Quinn et al., 2001; Rymer et al., 2001). These receptors are known to act via stimulation of Gaq/11 proteins (Wettschureck and Offer- 285 manns, 2005) and to stimulate an increase in intracellular free Ca2+ as second messenger. Since TRPC channels can be activated by Gaq/11 proteins these ion channels might play a role in the regulation of RPE function which are modulated by these receptors: adrenergic or purinergic regulation of transepithelial ion transport and muscarinergic or purinergic regulation of phagocytosis. Although the involvement of TRPC channels in these regulatory pathways is not proven, the presence of these channels might further help to identify so far unknown membrane conductances for Ca2+ which contribute to the underlying Ca2+ signalling. Another feature of TRPC1 channels in RPE cells is that they are interacting with beta-tubulin filaments of the cytoskeleton (Bollimuntha et al., 2005). This interaction enables a regulation of temporal and spatial distribution of TRPC1 channels in the cell membrane. The differentially regulated presence in the cell membrane modulates the effectiveness of an agonist to influence RPE cell function. 5.4.3. ATP receptors 5.4.3.1. ATP receptors in general. ATP can be released by different cell types and can act as an autocrine or paracrine extracellular messenger (Burnstock, 2004; Burnstock and Knight, 2004). ATP can bind to two different receptor types. These are the P2Y and P2X receptor families. Whereas the P2Y receptors are coupled to activation of G proteins (mainly Gaq/11 or Gai/O subunits) (Burnstock, 2004; Burnstock and Knight, 2004) and initiate an intracellular second messenger cascade, the P2X receptors are ligand-activated ion channels (North, 2002). ATP binding to P2X receptors results in the activation of a cation channel, which can conduct Na+ as well as Ca2+. With this mechanism, ATP can directly contribute to increases in intracellular free Ca2+ via stimulation of an influx of extracellular Ca2+ into the cell. The P2X receptors represent a gene family of 7 members which can form homomeric or heteromeric ATP-activated ion channels (North, 2002). Currents through P2X receptor channels show fast inactivation and desensitization to ATP. P2X receptors are expressed in a variety of tissues and have been described to modulate synaptic currents, contractility, and secretion. 5.4.3.2. P2X receptors in the RPE and their role for RPE function. So far the expression of P2X receptors in the RPE has not been shown by molecular biological or protein biochemical methods. However, a study with rat RPE cells on ATP-dependent signalling revealed changes in the membrane conductance which indicate the functional presence of P2X receptors (Ryan et al., 1999). Extracellular application of ATP resulted in the depolarization of RPE cells due to activation of cation channels (Fig. 7). This cation conductance shared some properties known of P2X receptors in heterologeous expression studies (North and Surprenant, 2000). ARTICLE IN PRESS 286 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 In the RPE, ATP-dependent signalling was found to play a role in the regulation of transepithelial ion and water transport, and phagocytosis (Collison et al., 2005; Peterson et al., 1997; Quinn and Miller, 1992; Reigada et al., 2005; Reigada and Mitchell, 2005; Ryan et al., 1999; Sullivan et al., 1997). The main source for ATP seems to be the RPE itself which can release ATP in response to a variety of stimuli such as bFGF or hypotonic challenge (Mitchell, 2001; Reigada et al., 2005; Reigada and Mitchell, 2005). ATP that functions as an autocrine messenger can do so by binding to different purinergic receptors such as P2Y, P2X, or adenosine receptors after degradation by ectonucleases (Mitchell, 2001; Reigada et al., 2005; Reigada and Mitchell, 2005). P2Y receptor stimulation leads to an increased transepithelial transport of Cl and water (Peterson et al., 1997). The responsible receptor-mediated signalling promotes these effects in two ways. One is an increase in intracellular free Ca2+ and the subsequent activation of ion channels such as Ca2+-dependent Cl channels which directly provide a transportation pathway for ions (Peterson et al., 1997). So far, the ATP-induced increases in intracellular-free Ca2+ were found to arise mainly from release of Ca2+ from cytosolic Ca2+ stores indicating that these are mediated by activation of P2Y receptors (Peterson et al., 1997; Ryan et al., 1999). In addition, it was found that ATP-dependent increases in intracellular free Ca2+ activate Ca2+-dependent K+ channels leading to hyperpolarization of the RPE cell (Ryan et al., 1999). This could be another mechanism by which ATP modulates transepithelial ion transport: modulation of the driving forces for ions to move across membranes. In this case, the activation of K+ channels would increase the driving force for Cl to leave the cell. For the modulation of these driving forces the P2Y and P2X receptors can interact. This was found in a study in which the effects of ATP on the membrane conductance were investigated (Ryan et al., 1999). Here, application of ATP first resulted in a cell depolarization, which was followed by cell hyperpolarization. The first event was found to be dependent on the stimulation of P2X receptors whereas the later event resulted from activation of Ca2+dependent BK Ca2+ channels (see Section 3). 5.4.4. Glutamate receptors 5.4.4.1. Glutamate receptors in general. Like ATP, the neurotransmitter glutamate can bind to either ligand-gated ion channels, the so called ionotropic glutamate receptors (Kew and Kemp, 2005; Mayer, 2005), or to receptors which activate G-protein-coupled intracellular second-messenger cascades, the metabotropic glutamate receptors (Conn, 2003; Kew and Kemp, 2005). 5.4.4.2. Glutamate receptors in the RPE. In independent studies, the functional expression of glutamate receptors has been described in the RPE (Fig. 7). The RPE expresses both metabotropic as well ionotropic glutamate receptors (Feldman et al., 1991; Fragoso and Lopez-Colome, 1999; Lopez-Colome et al., 1993, 1994; Uchida et al., 1998). Stimulation of either metabotropic or ionotropic glutamate receptors in the RPE result in an increase in the cytosolicfree Ca2+ (Feldman et al., 1991; Fragoso and LopezColome, 1999). The stimulation of metabotropic receptors leads to an increase in intracellular free Ca2+ via stimulation of a phospholipase C-dependent intracellular second messenger cascade. Interestingly, this increase was reduced after application of the L-type channel blocker nifedipine (Fragoso and Lopez-Colome, 1999). This might be enabled by the InsP3-dependent stimulation of L-type Ca2+ channels, which has been described above. However, glutamate-dependent increases in intracellular-free Ca2+ were also reduced in the presence of the ionotropic NMDA receptor (N-methyl-D-aspartate receptor) antagonists. Thus glutamate also activates NMDA receptors in RPE cells. Because of the expression of two different receptor subtypes of glutamate receptors, glutamate initiates a complex pattern of intracellular Ca2+ signalling in RPE cells. However, the effects of this Ca2+ signalling for RPE function are not entirely clear. Recently, it could be shown that stimulation of NMDA receptors in the RPE activates the release of ATP from RPE cells (Reigada et al., 2006). In the dark, photoreceptors release glutamate at their synaptic terminals. It is likely that part of this glutamate reaches RPE cells and leads to an adaptation of the RPE function to the requirements of photoreceptor function in the dark. One of these functions might be the regulation of the phagocytic activity of RPE cells which is controlled by changes in the illumination of the retina (Greenberger and Besharse, 1985; Lopez-Colome et al., 1994). 6. Na+ In addition to its role as charge carrier in excitable cells where a Na+ influx is responsible for the depolarization of the plasma membrane, Na+ plays a central role in many transport processes of diverse organic molecules like amino acids, sugars, and neurotransmitters where the steep Na+ gradient is used for secondary active transport of these molecules. Therefore, the Na+ homeostasis of a cell is of great importance for its normal function. Two main families of Na+ channels exist: the voltagegated Na+ channels (Nav1.1–Nav1.9) and the epithelial Na+ channels (ENaCa, b, g and d). These two families have very different functions. While voltage-gated channels are found almost exclusively in excitable cells where they are responsible for cell depolarization, ENaC are involved in Na+ homeostasis in epithelial cells. 6.1. Na+ ions in RPE cell function Over the apical membrane of the RPE cells a Na+ gradient is established by the Na+/K+-ATPase. Besides the contribution to the negative membrane potential, this gradient is used for the transport of various molecules from the subretinal space into the cells. These molecules include ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 + K+ and Cl, HCO 3 , H , lactate, GABA and taurine. These transport mechanisms are involved in volume regulation of the subretinal space, pH regulation, and the removal of metabolic products and neurotransmitters. For these tasks, Na+ is permanently secreted by the RPE into the subretinal space. While it is well known that Na+ leaves the cells through the apical membrane by the Na+/ K+ ATPase activity, it is still a subject of speculation how the Na+ enters the cells through the basolateral membrane. The steep chemical gradient between the extracellular space and the cytosol provides ideal conditions for Na+-conducting ion channels to perform Na+ influx through the basolateral membrane of the RPE. 6.2. Na+ channels of the RPE In cultured RPE cells from rat, newt, and humans, voltage-gated Na+ channels have been observe in patchclamp investigations (Botchkin and Matthews, 1994; Sakai and Saito, 1997; Wen et al., 1994). Nevertheless, it has also been shown that these Na+ channels appear only in RPE cells when they are cultured for at least 24 h. Thus, there should be other Na+-conducting proteins in the basolateral membrane. By immunohistochemistry and molecular biological methods, different members of the other family of Na+ channels (ENaC) have been detected in the RPE (Dyka et al., 2005; Golestaneh et al., 2002; Mirshahi et al., 1999). Though, the physiological data providing evidence for their expression in RPE cells are still missing, their contribution to the transepithelial transport seems very likely since such a coordinated transport activity between the Na+/K+ ATPase and ENaC localized in opposite membranes in Na+ transport is well known from other epithelial cell types e.g. in the collecting duct in the kidney. Because of the missing electrophysiological data we will not go further into detail regarding the Na+ channels in the RPE. 7. Ion channels and RPE disease Ion channel research improved the understanding of many diseases in two ways. On the one hand, analysis of ion channel function resulted in a better understanding of the physiology of cell function in general (Jurkat-Rott and Lehmann-Horn, 2004). This led also to new insights into the pathophysiology of diseases and, thus, into the development of new treatments. Together with genetic analyses of genes coding for ion channels the term of channelopathies emerged (Celesia, 2001; Hubner and Jentsch, 2002; Jentsch et al., 2004; Lehmann-Horn and Jurkat-Rott, 1999; Striessnig et al., 2004). Channelopathies are disorders, which result from malfunction of ion channels. These can be due to gain of function, loss of function, or by dominant-negative effects leading, for example, to a decreased number of channels in the cell membrane. 287 7.1. Change or loss of ion channel function leading to RPE diseases Mainly changes in Cl channel function were found to lead to degeneration of the retina. Although not a channelopathy, the inactivation of the ClC-2 channel gene in mouse results in a phenotype very similar to the clinical picture of retinitis pigmentosa in man (Bosl et al., 2001). A comparable cause for retinitis pigmentosa was not found in the human disease, important aspects of RPE function can be discussed from this mouse model. Analysis of transepithelial transport properties of the ClC-2 knock-out mouse revealed that the RPE in these mice show no transepithelial potential (Bosl et al., 2001) indicating the absence of transepithelial transport of Cl and water. The first conclusion, which can be drawn from this is that ClC-2 channels might provide the most important efflux pathway for Cl across the basolateral membrane according to the model of transepithelial transport which has been described in the chapters above. The second conclusion, which can be drawn from the observations in the ClC-2 / mouse is the importance of the transepithelial transport of water and Cl from the subretinal space to the blood side for the maintenance of photoreceptor function and survival. The absence of the transport leads to the degeneration of photoreceptors. More important for a human disease are the effects of mutations in the gene coding for bestrophin-1, the VMD2 gene (Marquardt et al., 1998; Petrukhin et al., 1998). Mutations in the VMD2 gene cause an inherited form of macular degeneration with juvenile onset, Best’s vitelliform macular dystrophy (Best, 1905; Cross and Bard, 1974; Godel et al., 1986; Weingeist et al., 1982). It is discussed that the mutations in the VMD2 gene lead to a changed basolateral membrane conductance for Cl to explain an important symptom for the diagnosis of Best’s disease. Thus Best’s macular dystrophy might be understood as a channelopathy. This diagnostic symptom is the reduction of the light-rise or light-peak in the patient’s electrooculogram of the Best patients (Cross and Bard, 1974). An analysis of the chick DC-ERG revealed that an increase in the basolateral membrane conductance for Cl with subsequent depolarization of the basolateral membrane represents the underlying mechanism contributing to the light-rise (Gallemore et al., 1988, 2004; Gallemore and Steinberg, 1989b). It is believed that a light-peak substance is released from the retina after illumination (Gallemore et al., 1988, 2004; Gallemore and Steinberg, 1989b). This substance diffuses to the RPE, binds to a receptor at the apical membrane, and initiates an intracellular second messenger cascade, which in turn most likely results in the activation of a Ca2+-dependent Cl channel in the basolateral membrane of the RPE. Thus, mutations in the VMD2 gene lead to a decrease in the basolateral membrane conductance for Cl in the RPE. Following this line of reasoning it became a very attractive hypothesis that the VMD2 gene product itself might function as ARTICLE IN PRESS 288 S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 a Ca2+-dependent Cl channel and that the mutations lead to a loss in the Cl channel function. Indeed, the VMD2 gene product bestrophin-1 appears to function as Ca2+-dependent Cl channel (see Section 4) (Sun et al., 2002). Furthermore, 15 different mutant bestrophins were investigated so far and it seems that all mutations lead to a loss in Cl channel function with a dominant negative effect on the wild-type allele. However, the hypothesis that a loss of the Cl channel function of bestrophin causes the leading symptom and the retinal degeneration in Best’s disease is not supported by recent studies of the clinical picture of patients with VMD2 mutations and by a study investigating light-peak increases in bestrophin-1 / mice. Patients carrying mutations in the VMD2 gene can have a macular degeneration but normal electro-oculograms (Kramer et al., 2000; Pollack et al., 2005; Renner et al., 2005; Wabbels et al., 2004, 2006). Or in other cases the changes in the patient’s light-peak appeared secondary to the onset of the macular degeneration (Wabbels et al., 2004). Thus not all mutations, which lead to macular degeneration seem to result in a loss of Cl channel function. This impression is supported by an investigation of a bestrophin-1 knockout mouse model. In these mice, the absence of bestrophin-1 did not reduce the light-peak amplitude in the DC-ERG (Marmorstein et al., 2006). Furthermore, at low light-intensities, the bestrophin-1 / mice showed increased light-peak amplitudes compared to the wild-type mice. Thus, either the lack of the Cl channel function in the RPE could be compensated for by another Cl channel, which could also be the case in the human RPE and would have comparable changes in the human electro-oculogram. Or bestrophin-1 might have additional functions to the Cl channel function involved in generation of the light peak and in the aetiology of the human macular degeneration, if mutations have changed this function. This additional function might be an influence of bestrophin-1 on the Ca2+ homeostasis of the RPE as it has been discussed in the chapter about Ca2+ channels of the RPE (Rosenthal et al., 2006). Another disease which might have an impact on RPE function is cystic fibrosis (Blaug et al., 2003). The gene product of the disease-causing gene, CFTR, is also expressed in the RPE (Blaug et al., 2003; Reigada and Mitchell, 2005; Weng et al., 2002; Wills et al., 2000). CFTR is known to function as Cl channel (Jentsch et al., 2002). Although cystic fibrosis patients show a decreased signal in the electro-oculogram which is also discussed to be associated with an activation of Cl channels in the RPE (Blaug et al., 2003), the loss of CFTR Cl channel function in patients with cystic fibrosis seems not to have any degenerative effects on the macula (Blaug et al., 2003). In summary, loss of ion channel function in the RPE can have severe effects on the retina and lead to retinal degeneration. Such a mechanism is discussed to be the cause for an inherited form of macular degeneration, Best vitelliform macular dystrophy. However, such a mechanism has not to been proven to be the case in Best disease. 7.2. Involvement of ion channels in signalling cascades leading to degenerative processes in the retina Normal ion channel function in the RPE can play a role in the aetiology of degenerative diseases of the retina. If an ion channel has an important contribution to a signal pathway leading to the initiation of processes which mark important steps in a chain of events leading to pathologic changes in cell function then this ion channel may play a key role in the aetiology of a disease. This may be the case for L-type Ca2+ channels. As mentioned above, the RPE is able to secrete a variety of growth factors in health and in disease. Several lines of evidence indicate that growth factors secreted by the RPE promote the development of choroidal neovascularization in age-related macular degeneration (Amin et al., 1994; Frank, 1997; Holz et al., 2004; Lambooij et al., 2003; Oh et al., 1999; Rosenthal et al., 2004), the most common cause for blindness in industrialized countries. In this disease the complication of choroidal neovascularization accounts for the major component of vision loss (Ambati et al., 2003). In the chain of events which lead to choroidal neovascularization the RPE seem to play a central role by its secretion of the major angiogenic factor, VEGF (Amin et al., 1994; Frank, 1997; Krzystolik et al., 2002; Lambooij et al., 2003; Lopez et al., 1996; Rosenthal et al., 2004). The secretion of VEGF by the RPE is under control of other growth factors which might be secreted by photoreceptors or by the RPE itself (Frank, 1997; Kondo et al., 2003; Mousa et al., 1999; Nagineni et al., 2003; Rosenthal et al., 2004, 2005; Slomiany and Rosenzweig, 2004a, b; Witmer et al., 2003). Thus, the secretion of growth factors by the RPE has several effects in the initiation of choroidal neovascularization. These are autocrine and paracrine stimulation. As mentioned above, the L-type Ca2+ channels in the RPE regulate secretion of VEGF. Due to regulation of L-type channels by other growth factors or cytosolic tyrosine kinase, which are stimulated by other growth factors, L-type Ca2+ channels are also able to fulfil the autocrine stimulation pathway of VEGF secretion. Thus, with this important function, L-type channels might play a key role in the initiation of choroidal neovascularization in agerelated macular degeneration and could be a target for the development of strategies to prevent this severe complication (Strauss et al., 2003). This hypothesis is supported by the observation that freshly isolated RPE cells from patients with age-related macular degeneration and choroidal neovascularization still show Ba2+ currents with properties of L-type Ca2+ channels (Strauss et al., 2003). A sensitive reaction of L-type channels to degenerative processes in the retina was detected in studies of L-type channel function in RPE cells of an animal model for human retinitis pigmentosa, the Royal College of Surgeons (RCS) rat. Here, the L-type Ca2+ channels showed an increased activity due to a changed regulation (Mergler et al., 1998). Although the consequences of these effects have not been further explored these observations show ARTICLE IN PRESS S. Wimmers et al. / Progress in Retinal and Eye Research 26 (2007) 263–301 that L-type channel dependent Ca2+-signalling is sensitively adapted to the changed patho-physiologic situation in the degenerative process of the retina. 8. Summary The patch-clamp technique provides a strong tool in the identification and characterization of ion fluxes across membranes. In the RPE it has been used to support the data previously obtained by other techniques like molecular biological, protein biochemical, and other electrophysiological studies with Ussing chambers. The patch-clamp studies not only confirmed these data but also extended our knowledge on ionic currents across the RPE membranes. This in turn led us to the development of new ideas of how ion channels may be involved in RPE cell functions. So, it could be confirmed that a K+ conductance through inwardly rectifying K+ channels contributes to the K+ homoeostasis in the subretinal space. Considering the additional expression of voltage-gated and Ca2+activated K+ channels, the picture of K+ transport by the RPE could be extended. Comparably, the proposed Cl conductance in the basolateral membrane of RPE cells was confirmed by patch-clamp studies. This technique proves to be important for the identification of the function of a macular disease associated protein, bestrophin. Based on patch-clamp data, bestrophin is now thought to be a Cl channel and/or a modulator of voltage-gated Ca2+ channels. These Ca2+ channels have been shown by the patch-clamp technique to be involved in RPE cell functions like the secretion of growth factors and in transcellular transport. However, the investigation of ion channels in the RPE is not finished and a closer investigation of bestrophin function, glutamate receptors, P2X receptors, and TRPC channels will further understanding and open new aspects to the role of the RPE in visual function. 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