D018268-0019 D017414-8954 Removable lid This half of an unwelded diaphragm illustrates the aerodynamic flow path and liquid cooling passages. Main structural section (diffuser side) Controlling Greenhouse Gases SwRI researchers develop advanced centrifugal compressor technology for carbon capture and sequestration by J. Jeffrey Moore, Ph.D., Andrew Lerche, Hector Delgado and Tim Allison, Ph.D. C Engineers in SwRI’s Fluids and Machinery Engineering Department are working with both government and industry to advance technologies for reducing the release of greenhouse gas emissions from power plants. Pictured are (from left) Senior Research Engineer Dr. Tim Allison, Senior Research Engineer Andrew Lerche, Manager Dr. J. Jeffrey Moore and Research Engineer Hector Delgado. The team applies various analysis techniques to solve problems associated with rotating machinery and to advance new designs for industry. 6 Technology Today • Winter 2011 oal is used to generate about half of all electricity consumed in the United States. Unfortunately, coal has a high carbon content and produces twice the carbon dioxide (CO2) emissions when burned compared to natural gas. Because of growing concern over greenhouse gas emissions, the U.S. government and utilities are developing technologies to separate CO2 both preand post-combustion. To reduce the release of CO2 greenhouse gases to the atmosphere, industry is pursuing technologies for sequestering CO2 emitted from new power cycles, including integrated gasification combined cycle (IGCC) and oxy-fuel, as well as from traditional pulverized coal (PC) power plants. Significant progress has been made in sequestration of CO2 from power plants and other major producers of greenhouse gas emissions. Compressing the captured CO2 stream requires significant power, which affects plant availability, capital expenditures and operational costs. The power penalty for carbon capture can be as high as 27 to 37 percent for a traditional PC power plant and 13 to 17 percent for a typical IGCC plant. Compression represents a significant percentage of this total. Diffuser side of bulb Return channel side of bulb Main structural section (return channel side) Novel compression and pumping techniques SwRI researchers, under funding from the U.S. Department of Energy National Energy Technology Laboratory and industry partners, are working to reduce this penalty by developing novel combined compression and pumping processes. The research supports reducing the energy requirements for carbon capture and sequestration in electrical power production. These technologies are also applicable to other gases, including natural gas and air compression. The primary objective of this work is to boost the pressure of CO2 from near-atmospheric to pipeline pressures with the minimal amount of energy required. Previous thermodynamic analysis identified optimum processes for pressure rise in both liquid and gaseous states. Isothermal compression is well known to reduce the power requirements by minimizing the temperature of the gas entering downstream stages. Furthermore, because CO2 is a heavy gas, it may be liquefied at moderate temperature and pressures using industrial refrigeration systems that permit this use of a centrifugal pump for the highpressure stages. Combined compressionliquefaction-pumping schemes are being pursued in this study. Isothermal compression can be accomplished with an integrally geared machine, where multiple pinions are driven by a common gear. However, the reliability of integrally geared compressors cannot match the inline centrifugal machines widely used in the oil and gas industry. To address these issues, SwRI researchers designed an internally cooled, in-line centrifugal compressor diaphragm (patent pending) that removes the heat of compression without the need for external intercoolers using liquid cooling. The diaphragm removes heat of compression between each impeller by passing cooling water through the diaphragm. Temperature increases, due to the work input of the impeller, are reduced through the diaphragm flow path, thereby reducing the temperature into the downstream stage. To validate their predictions for both aerodynamic and heat transfer performance, SwRI researchers built and tested a single-stage prototype diaphragm. Significant challenges exist in cooling a high-velocity gas within the compressor due to the limited surface area and the need for minimum pressure drop of the gas stream. However, using three-dimensional computational fluid dynamics, researchers developed conjugate heat transfer models that combine the diaphragm structure, cooling fluid and the diaphragm process gas flow path. Using these models, researchers achieved an optimal design that provides good heat transfer with no additional pressure drop. The diaphragms were designed to permit fabrication by first machining the individual components, then welding D018305 D018307 SwRI researchers developed a conjugate heat transfer computational fluid dynamics (CFD) model to predict the aerodynamic flow field of the compressor and calculate the heat transfer to the cooling fluid through the aluminum diaphragm. This internally cooled compressor diaphragm removes the heat of compression inside a multi-stage centrifugal compressor used for CO2 compression applications. 308 D018 Technology Today • Winter 2011 7 D018268-0019 D017414-8954 Removable lid This half of an unwelded diaphragm illustrates the aerodynamic flow path and liquid cooling passages. Main structural section (diffuser side) Controlling Greenhouse Gases SwRI researchers develop advanced centrifugal compressor technology for carbon capture and sequestration by J. Jeffrey Moore, Ph.D., Andrew Lerche, Hector Delgado and Tim Allison, Ph.D. C Engineers in SwRI’s Fluids and Machinery Engineering Department are working with both government and industry to advance technologies for reducing the release of greenhouse gas emissions from power plants. Pictured are (from left) Senior Research Engineer Dr. Tim Allison, Senior Research Engineer Andrew Lerche, Manager Dr. J. Jeffrey Moore and Research Engineer Hector Delgado. The team applies various analysis techniques to solve problems associated with rotating machinery and to advance new designs for industry. 6 Technology Today • Winter 2011 oal is used to generate about half of all electricity consumed in the United States. Unfortunately, coal has a high carbon content and produces twice the carbon dioxide (CO2) emissions when burned compared to natural gas. Because of growing concern over greenhouse gas emissions, the U.S. government and utilities are developing technologies to separate CO2 both preand post-combustion. To reduce the release of CO2 greenhouse gases to the atmosphere, industry is pursuing technologies for sequestering CO2 emitted from new power cycles, including integrated gasification combined cycle (IGCC) and oxy-fuel, as well as from traditional pulverized coal (PC) power plants. Significant progress has been made in sequestration of CO2 from power plants and other major producers of greenhouse gas emissions. Compressing the captured CO2 stream requires significant power, which affects plant availability, capital expenditures and operational costs. The power penalty for carbon capture can be as high as 27 to 37 percent for a traditional PC power plant and 13 to 17 percent for a typical IGCC plant. Compression represents a significant percentage of this total. Diffuser side of bulb Return channel side of bulb Main structural section (return channel side) Novel compression and pumping techniques SwRI researchers, under funding from the U.S. Department of Energy National Energy Technology Laboratory and industry partners, are working to reduce this penalty by developing novel combined compression and pumping processes. The research supports reducing the energy requirements for carbon capture and sequestration in electrical power production. These technologies are also applicable to other gases, including natural gas and air compression. The primary objective of this work is to boost the pressure of CO2 from near-atmospheric to pipeline pressures with the minimal amount of energy required. Previous thermodynamic analysis identified optimum processes for pressure rise in both liquid and gaseous states. Isothermal compression is well known to reduce the power requirements by minimizing the temperature of the gas entering downstream stages. Furthermore, because CO2 is a heavy gas, it may be liquefied at moderate temperature and pressures using industrial refrigeration systems that permit this use of a centrifugal pump for the highpressure stages. Combined compressionliquefaction-pumping schemes are being pursued in this study. Isothermal compression can be accomplished with an integrally geared machine, where multiple pinions are driven by a common gear. However, the reliability of integrally geared compressors cannot match the inline centrifugal machines widely used in the oil and gas industry. To address these issues, SwRI researchers designed an internally cooled, in-line centrifugal compressor diaphragm (patent pending) that removes the heat of compression without the need for external intercoolers using liquid cooling. The diaphragm removes heat of compression between each impeller by passing cooling water through the diaphragm. Temperature increases, due to the work input of the impeller, are reduced through the diaphragm flow path, thereby reducing the temperature into the downstream stage. To validate their predictions for both aerodynamic and heat transfer performance, SwRI researchers built and tested a single-stage prototype diaphragm. Significant challenges exist in cooling a high-velocity gas within the compressor due to the limited surface area and the need for minimum pressure drop of the gas stream. However, using three-dimensional computational fluid dynamics, researchers developed conjugate heat transfer models that combine the diaphragm structure, cooling fluid and the diaphragm process gas flow path. Using these models, researchers achieved an optimal design that provides good heat transfer with no additional pressure drop. The diaphragms were designed to permit fabrication by first machining the individual components, then welding D018305 D018307 SwRI researchers developed a conjugate heat transfer computational fluid dynamics (CFD) model to predict the aerodynamic flow field of the compressor and calculate the heat transfer to the cooling fluid through the aluminum diaphragm. This internally cooled compressor diaphragm removes the heat of compression inside a multi-stage centrifugal compressor used for CO2 compression applications. 308 D018 Technology Today • Winter 2011 7 D018294 D018296 D018297 The SwRI-designed CO2 pump test loop, located at the Institute, will be used to characterize the performance and mechanical behavior of a multistage turbopump adapted for use with liquid CO2. Valve Knock-out Drum Motor CO2 Pump Tank D018306 Measured pump performance showing head (pressure rise) versus flow (in gallons per minute). the pieces together and heat-treating and machining the weldment. Compressor loop test rig Researchers retrofitted the compressor diaphragm into the SwRI closed-loop centrifugal compressor casing. Instrumentation was installed internally in the compressor diaphragm as well as externally throughout the test loop to measure aerodynamic and heat transfer performance. Multiple pressure and temperature sensors were installed at various stations throughout the flow path. An end-to-end calibration of all temperature probes was performed prior to installing the probes inside the loop and diaphragm. Cables for all of the internal instrumentation were passed through the compressor casing via sealing glands. Researchers developed the data acquisition and loop control software for the CO2 compressor loop using LabVIEW™ software. The program is capable of sending and receiving data to and from PSI NetScanner 9116 pressure scanners and National Instruments CompactDAQ™ systems to control and monitor the test rig. Temperature measurements at various locations inside the compressor were converted to total temperatures. The flow velocity at the suction and discharge measurement locations was used to calculate 8 the total temperature and pressure at these locations using procedures based on those in the ASME PTC10 specification. This conversion procedure was also performed for temperature measurements at the impeller exit, diffuser vane exit and return-channel bend. Stage performance was calculated at the bridgeover locations to eliminate the effect of the inlet and exit collector. This approach better represents a central stage in a multi-stage compressor. Performance tests were completed at three speeds (10,280, 11,565 and 12,850 rpm), three cooling flow rates (0, 12 and 20 gpm), three gas suction pressures (30, 60 and 90 psia) and two cooling water temperatures over a range of compressor flows. Adiabatic refers to no heat transfer (no cooling water flow) while diabatic is with cooling. Because this program tested only a single-stage compressor, the aerodynamic work input (and power) remained the same between the adiabatic and diabatic tests. Note that the benefit of the cooled diaphragm is realized on downstream stages in a multi-stage compressor. In some cases, the gas flow temperature decreased by Technology Today • Winter 2011 Schematic of the liquid CO2 pump loop constructed to perform qualification tests of a 12-stage centrifugal turbopump. Conclusions This plot shows the measured and predicted total temperature profiles throughout the compressor at different stations. Both adiabatic and diabatic conditions are given. The results show significant temperature reduction with the cooled diaphragm and good correlation with the CFD predictions. more than 20 degrees F, demonstrating the effectiveness of the cooled diaphragm concept. Using this measured amount of heat transfer, hypothetically a five-stage centrifugal compressor would require 20 percent less power using the internal cooling technology compared to a conventional compressor. Pump loop test rig Because a liquid CO2 pump of the size required for this service was not commercially available, SwRI engineers worked with a pump manufacturer to All of the goals set forth in the test program were accomplished. Early in 2011, SwRI was awarded a $9.9 million contract for Phase 3 to develop a multi-stage version of the cooled diaphragm and to construct a demonstration facility at SwRI consisting of an integrated compression-liquefactionpumping pilot plant. Tests will commence in 2013. This pilot-scale testing will increase to a technical readiness level, permitting implementation in a full-scale power plant. adapt an existing pump design for CO2 service. The pump test rig consists of a newly constructed liquid CO2 test loop and an industrial multi-stage turbopump adapted for service on liquid CO2. The pump is the smallest frame size for this product line, while still retaining the same configuration as large-scale pumps that would be used for power plant applications. The smaller size was selected to keep the cost of the facility to a minimum, yet still provide valid performance and mechanical data. The pump loop consists of a 12-stage centrifugal pump driven by a variablespeed electric motor and is fed from a 1,000-gallon pressurized vessel that maintains liquid CO2 at its boiling temperature of -12 degrees F at 250 psia. The discharge of the pump feeds an orifice flow meter followed by a control valve that drops the pressure from 2,215 psia to 250 psia. The control valve discharges into a knock-out drum for liquid-gas separation, since some flashing of the gas back to the vapor phase will occur. Finally, the liquid CO2 will be returned to the main vessel through a drain line, and the remaining gaseous CO2 will be vented to the atmosphere through a back-pressure control valve. The tests measured pump performance to quantify the power requirements. Also, mechanical performance was quantified, including vibration, temperatures and seal flows. Technology Today • Winter 2011 Questions about this article? Contact Moore at (210) 522-5812 or jeff.moore@swri.org. Acknowledgments The authors would like to thank the U.S. Department of Energy National Energy Technology Laboratory for providing the majority of the funding for this work, and Dresser-Rand and BP for additional co-funding. Machining of the compressor diaphragm components by Supervisor Robert Rendon and Staff Craft Technician Marc Johnson in SwRI’s Space Science and Engineering Division also is acknowledged. Thanks also to Principal Technicians Brian Moreland and Richard Skinner, both of the Mechanical Engineering Division, for the detail design of the cooled diaphragms and fabrication of the pump loop, respectively. 9 D018294 D018296 D018297 The SwRI-designed CO2 pump test loop, located at the Institute, will be used to characterize the performance and mechanical behavior of a multistage turbopump adapted for use with liquid CO2. Valve Knock-out Drum Motor CO2 Pump Tank D018306 Measured pump performance showing head (pressure rise) versus flow (in gallons per minute). the pieces together and heat-treating and machining the weldment. Compressor loop test rig Researchers retrofitted the compressor diaphragm into the SwRI closed-loop centrifugal compressor casing. Instrumentation was installed internally in the compressor diaphragm as well as externally throughout the test loop to measure aerodynamic and heat transfer performance. Multiple pressure and temperature sensors were installed at various stations throughout the flow path. An end-to-end calibration of all temperature probes was performed prior to installing the probes inside the loop and diaphragm. Cables for all of the internal instrumentation were passed through the compressor casing via sealing glands. Researchers developed the data acquisition and loop control software for the CO2 compressor loop using LabVIEW™ software. The program is capable of sending and receiving data to and from PSI NetScanner 9116 pressure scanners and National Instruments CompactDAQ™ systems to control and monitor the test rig. Temperature measurements at various locations inside the compressor were converted to total temperatures. The flow velocity at the suction and discharge measurement locations was used to calculate 8 the total temperature and pressure at these locations using procedures based on those in the ASME PTC10 specification. This conversion procedure was also performed for temperature measurements at the impeller exit, diffuser vane exit and return-channel bend. Stage performance was calculated at the bridgeover locations to eliminate the effect of the inlet and exit collector. This approach better represents a central stage in a multi-stage compressor. Performance tests were completed at three speeds (10,280, 11,565 and 12,850 rpm), three cooling flow rates (0, 12 and 20 gpm), three gas suction pressures (30, 60 and 90 psia) and two cooling water temperatures over a range of compressor flows. Adiabatic refers to no heat transfer (no cooling water flow) while diabatic is with cooling. Because this program tested only a single-stage compressor, the aerodynamic work input (and power) remained the same between the adiabatic and diabatic tests. Note that the benefit of the cooled diaphragm is realized on downstream stages in a multi-stage compressor. In some cases, the gas flow temperature decreased by Technology Today • Winter 2011 Schematic of the liquid CO2 pump loop constructed to perform qualification tests of a 12-stage centrifugal turbopump. Conclusions This plot shows the measured and predicted total temperature profiles throughout the compressor at different stations. Both adiabatic and diabatic conditions are given. The results show significant temperature reduction with the cooled diaphragm and good correlation with the CFD predictions. more than 20 degrees F, demonstrating the effectiveness of the cooled diaphragm concept. Using this measured amount of heat transfer, hypothetically a five-stage centrifugal compressor would require 20 percent less power using the internal cooling technology compared to a conventional compressor. Pump loop test rig Because a liquid CO2 pump of the size required for this service was not commercially available, SwRI engineers worked with a pump manufacturer to All of the goals set forth in the test program were accomplished. Early in 2011, SwRI was awarded a $9.9 million contract for Phase 3 to develop a multi-stage version of the cooled diaphragm and to construct a demonstration facility at SwRI consisting of an integrated compression-liquefactionpumping pilot plant. Tests will commence in 2013. This pilot-scale testing will increase to a technical readiness level, permitting implementation in a full-scale power plant. adapt an existing pump design for CO2 service. The pump test rig consists of a newly constructed liquid CO2 test loop and an industrial multi-stage turbopump adapted for service on liquid CO2. The pump is the smallest frame size for this product line, while still retaining the same configuration as large-scale pumps that would be used for power plant applications. The smaller size was selected to keep the cost of the facility to a minimum, yet still provide valid performance and mechanical data. The pump loop consists of a 12-stage centrifugal pump driven by a variablespeed electric motor and is fed from a 1,000-gallon pressurized vessel that maintains liquid CO2 at its boiling temperature of -12 degrees F at 250 psia. The discharge of the pump feeds an orifice flow meter followed by a control valve that drops the pressure from 2,215 psia to 250 psia. The control valve discharges into a knock-out drum for liquid-gas separation, since some flashing of the gas back to the vapor phase will occur. Finally, the liquid CO2 will be returned to the main vessel through a drain line, and the remaining gaseous CO2 will be vented to the atmosphere through a back-pressure control valve. The tests measured pump performance to quantify the power requirements. Also, mechanical performance was quantified, including vibration, temperatures and seal flows. Technology Today • Winter 2011 Questions about this article? Contact Moore at (210) 522-5812 or jeff.moore@swri.org. Acknowledgments The authors would like to thank the U.S. Department of Energy National Energy Technology Laboratory for providing the majority of the funding for this work, and Dresser-Rand and BP for additional co-funding. Machining of the compressor diaphragm components by Supervisor Robert Rendon and Staff Craft Technician Marc Johnson in SwRI’s Space Science and Engineering Division also is acknowledged. Thanks also to Principal Technicians Brian Moreland and Richard Skinner, both of the Mechanical Engineering Division, for the detail design of the cooled diaphragms and fabrication of the pump loop, respectively. 9