DR
Page 1/4
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
1 Identification of substance
· Product details
· Trade name
Okamul PU-K Comp.A
· Manufacturer/Supplier:
Kiesel Bauchemie GmbH & Co. KG
Wolf-Hirth-Str. 2
D-73730 Esslingen
Tel.: +49 (0)711/93134-0
Fax: +49 (0)711/93134-140
e-Mail: info@kiesel.com
· Informing department:
during the normal hours of business: export Tel.: +49 (0)711/93134134
· Emergency information:
Off the labour times: Kiesel Bauchemie GmbH & C0.KG
Tel.: +49(0)151/16353675
e-Mail: sucker@kiesel.com
2 Hazards identification
· Information pertaining to
particular dangers for man and
environment
· GHS label elements
void
Void
3 Composition/information on ingredients
· Description:
Fillers in dressing of polyolen.
· Dangerous components:
Void
4 First aid measures
· General information
· After skin contact
· After eye contact
· After swallowing
No special measures required.
Instantly wash with water and soap and rinse thoroughly.
Rinse opened eye for several minutes under running water.
In case of persistent symptoms consult doctor.
5 Fire fighting measures
· Suitable extinguishing agents
· For safety reasons unsuitable
extinguishing agents
· Special hazards caused by the
material, its products of
combustion or flue gases:
· Protective equipment:
CO2, extinguishing powder or water jet. Fight larger fires with water jet
or alcohol-resistant foam.
Water with a full water jet.
Formation of toxic gases is possible during heating or in case of fire.
In case of fire wear self-contained breathing equipment.
6 Accidental release measures
· Person-related safety precautions: Not required.
· Measures for environmental
protection:
Do not allow product to reach sewage system or water bodies.
· Measures for cleaning/collecting: Take-up with liquid binding material (sand, diatomaceous earth, acid
binding agent, universal binding agent).
(Contd. on page 2)
GB
DR
Page 2/4
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
Trade name Okamul PU-K Comp.A
(Contd. of page 1)
· Additional information:
See Section 13 for information on disposal.
7 Handling and storage
· Handling
· Information for safe handling:
· Information about protection
against explosions and fires:
No special measures required.
No special measures required.
· Storage
· Requirements to be met by
storerooms and containers:
Protect from water.
· Information about storage in one
common storage facility:
Store away from foodstuffs.
· Further information about
storage conditions:
Keep container tightly sealed.
8 Exposure controls and personal protection
· Additional information about
design of technical systems:
· Personal protective equipment
· General protective and hygienic
measures
· Breathing equipment:
· Protection of hands:
· Eye protection:
No further data; see item 7.
Wash hands during breaks and at the end of the work.
Take off soiled soaked clothing.
Not required.
Protective gloves.
Safety glasses recommended during refilling.
9 Physical and chemical properties:
· General Information
Form:
Colour:
Smell:
Pasty
Beige
Characteristic
· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
n.d.
n.d.
· Flash point:
> 200°C
· Self-inflammability:
Product is not selfigniting.
· Danger of explosion:
Product is not explosive.
· Steam pressure at 20°C:
< 1 mbar
· Density at 20°C
1.58 g/cm3
· Solubility in / Miscibility with
Water:
not miscible
· Viscosity:
dynamic at 25°C:
3.500 Pas
Brookfield, Spindel RV 7, RPM 1
(Contd. on page 3)
GB
DR
Page 3/4
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
Trade name Okamul PU-K Comp.A
(Contd. of page 2)
· Additional information
The physical data are average values.
10 Stability and reactivity
· Dangerous reactions
· Dangerous products of
composition:
No dangerous reactions known
None known.
11 Toxicological information
· Acute toxicity:
· Primary irritant effect:
· on the skin:
· on the eye:
· Additional toxicological
information:
Irritation of the skin and mucous membranes is possible.
Irritation possible.
When used and handled according to specifications, the product does
not have any harmful effects according to our experience and the
information provided to us.
12 Ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
Do not allow product to reach ground water, water bodies or sewage
system.
13 Disposal considerations
· Product:
· Recommendation
· Uncleaned packagings:
· Recommendation:
Must not be disposed of together with household garbage. Do not allow
product to reach sewage system.
Disposal must be made according to official regulations.
14 Transportinstruction
· Transport/Additional
information:
Not classified as dangerous in the meaning of transport regulations.
15 Regulatory information
· Designation according to EC
guidelines:
The product is not subject to identification regulations under EC
Directives and the Ordinance on Hazardous Materials (GefStoffV).
· National regulations
· Decree to be applied in case of
technical fault:
n.a.
· Technical instructions (air):
· Class Share in %
n.a.
(Contd. on page 4)
GB
DR
Page 4/4
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
Trade name Okamul PU-K Comp.A
(Contd. of page 3)
· Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
Chapters which have been revised from the previous issue are marked "*".
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the (in
this sense consult information on use and on product), but to liberation of major amounts in case of
accidents and irregularities.
(n.a. - not applicable, n.d. - not determined)
This information describes exclusively the safety requirements for the product(s) and is based on the
present level of our knowledge. It does not constitute a legal warranty regulations. The delivery
specifications are contained in the corresponding product sheet.
· Abbreviations and acronyms:
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
GB
DR
Page 1/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
1 Identification of substance
· Product details
· Trade name
Okamul PU-K Comp.B
· Manufacturer/Supplier:
Kiesel Bauchemie GmbH & Co. KG
Wolf-Hirth-Str. 2
D-73730 Esslingen
Tel.: +49 (0)711/93134-0
Fax: +49 (0)711/93134-140
e-Mail: info@kiesel.com
· Informing department:
during the normal hours of business: export Tel.: +49 (0)711/93134134
· Emergency information:
Off the labour times: Kiesel Bauchemie GmbH & C0.KG
Tel.: +49(0)151/16353675
e-Mail: sucker@kiesel.com
2 Hazards identification
· Hazard designation:
· Information pertaining to
particular dangers for man and
environment
· GHS label elements
Xn Harmful
R 20
Harmful by inhalation.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 42
May cause sensitization by inhalation.
Contains isocyanates. See information supplied by the manufacturer.
Danger
3.4/1 - May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
3.2/2 - Causes skin irritation.
3.3/2A - Causes serious eye irritation.
Warning
· Prevention:
· Response:
· Storage:
3.1/4 - Harmful if inhaled.
3.8/3 - May cause respiratory irritation.
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face
protection.
In case of inadequate ventilation wear respiratory protection.
IF ON SKIN: Wash with plenty of soap and water.
IF INHALED: Remove to fresh air and keep at rest in a position
comfortable for breathing.
IF INHALED: If breathing is difficult, remove to fresh air and keep at
rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Call a POISON CENTER or doctor/physician if you feel unwell.
Specific treatment (see label).
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
If experiencing respiratory symptoms: Call a POISON CENTER or
doctor/physician.
Take off contaminated clothing and wash before reuse.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
(Contd. on page 2)
GB
DR
Page 2/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
Trade name Okamul PU-K Comp.B
(Contd. of page 1)
· Disposal:
Dispose of contents/container in accordance with local/regional/
national/international regulations.
3 Composition/information on ingredients
· Dangerous components:
4,4'-Diphenylmethandiisocyanat, Isomere, Homologe und Mischungen
50-100%
Xn,
Xi; R 20-36/37/38-42/43
Danger:
3.4.R/1, 3.2/2, 3.3/2A, 3.4.S/1
Warning:
3.1.I/4, 3.8/3
· Additional information
Have also a look to point 8 "Exposure controls and personalprotection"
4 First aid measures
· General information
· After inhalation
· After skin contact
· After eye contact
· After swallowing
· Information for doctor
Immediately remove contaminated clothing.
Keep patient calm, remove to fresh air, summon medical help.
Symptoms can appear later.
Instantly wash with water and soap and rinse thoroughly.
Rinse immediately and thoroughly with eyelids open for 15 minutes
under running water, consult eye specialist.
Rinse out the mouth immediately and consume large amounts of water,
prevent vomiting, seek medical advice.
Treat according to symptoms (decontamination, vital functions), no
known specific antidote, administer dexamethasone aerosol to prevent
pulmonary odema.
5 Fire fighting measures
· Suitable extinguishing agents
· Special hazards caused by the
material, its products of
combustion or flue gases:
· Protective equipment:
· Additional information
Dry extinguishing agent, foam, carbon dioxide (CO2), sprayed water
(large amounts).
Carbon monoxide, carbon dioxide (CO2), oxides of nitrogen, hydrogen
cyanide, diphenylmethane-4,4'-diisocyanate.
Wear non-circulation breathing equipment and chemical-protective
clothing. Do not inhale explosion gases or fire fumes.
Cool endangered containers with water. Gaseous products from
decomposition may be liberated from overheated materials, danger of
bursting. Collect residues from fires and contaminated extinguishing
water separately, may not be discharged into drainage or into sewage
water.
6 Accidental release measures
· Person-related safety precautions: Ensure adequate ventilation
In the event of liberated gases/vapors: full chemical-protective clothing,
breathing equipment.
· Measures for environmental
protection:
Do not allow product to reach sewage system or water bodies.
· Measures for cleaning/collecting: For liquid product: hold back larger quantities and pump into
containers. Collect the remainder using adsorbent material and dispose
of in accordance with procedures.
Smaller
quantities: cover with sand, sweep together and dispose.
Solid
material: sweep together and dispose.
Do nit seal container gas-tight.
Recommended cleaning agent: preparation of: water, wetting agent
(Contd. on page 3)
GB
DR
Page 3/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
Trade name Okamul PU-K Comp.B
(Contd. of page 2)
(1%)
7 Handling and storage
· Handling
· Information about protection
against explosions and fires:
· Storage
· Requirements to be met by
storerooms and containers:
Ensure adequate extraction/ventilation when emptying or cleaning
processing machinery. Good extraction and ventilation of storage areas
and workplaces. Avoid inhalation of vapors. Breathing equipment
required when handling the product at elevated temperatures.
Keep away from sources of ignition - No smoking.
Keep tightly sealed, store in a cool, dry and well ventilated place.
Development of excess CO2 pressure in isocyanate containers on
contact with moisture.
· Information about storage in one
common storage facility:
Do not store together with: acids, amines or products containing
amines, products which contain groups with active hydrogen.
Stock/store/load away from foodstuffs, feed and semi-luxury foods/
tabacco.
· Further information about
storage conditions:
Storage temperature: min. 15°C; storage temperature: max. 25°C.
8 Exposure controls and personal protection
· Additional information about
design of technical systems:
· Personal protective equipment
· General protective and hygienic
measures
· Breathing equipment:
· Protection of hands:
· Eye protection:
· Body protection:
(See item 7)
Keep away from foodstuffs, beverages and food.
Do not eat, drink or smoke while working.
Avoid contact with skin, eyes or clothing.
Instantly remove any soiled and impregnated garments.
Wash hands and/or face prior to breaks and finishing work.
Ensure skin cleaning and skin care after working.
Breathing equipment required in the event of inhalable dust,
insufficient ventilation and elevated temperatures.
Rubber or plastic gloves, impermeable gloves made of synthetic rubber,
polybutadiene.
Not to be used: gloves made of PVC, polyethylene.
Tightly sealed safety glasses.
Safety shoes, sealed working clothing.
9 Physical and chemical properties:
· General Information
Form:
Colour:
Smell:
· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
Fluid
Brown
Odor: earthy, stale
n.d.
>200°C ((DIN))
(Contd. on page 4)
GB
DR
Page 4/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
Trade name Okamul PU-K Comp.B
(Contd. of page 3)
· Flash point:
>200°C ((DIN))
· Ignition temperature:
>530°C ((DIN))
· Critical values for explosion:
Lower:
Upper:
nicht anwendbar Vol %
nicht anwendbar Vol %
· Steam pressure at 25°C:
<0.0001 mbar ((DIN))
· Density at 25°C
1.23 g/cm3
· Solubility in / Miscibility with
Water:
· pH-value:
not miscible
Reacts slowly with water at the surface thereby liberating CO2
to give an insoluble high-melting poly-urea product.
n.a.
· Segregation coefficient (n-octanol/water): n.a.
· Viscosity:
dynamic at 25°C:
· Additional information
200.000 mPas
Brookfield, Spindel RV 7, RPM 10
keine
10 Stability and reactivity
· Materials to be avoided:
· Dangerous reactions
· Dangerous products of
composition:
acids, water
Dangerous reaction from action with: amines or product containing
amines, salts of heavy metals, substances which contain groups with
active hydrogen.
No decomposition if stored and handled correctly.
11 Toxicological information
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
4,4'-Diphenylmethandiisocyanat, Isomere, Homologe und Mischungen
Oral
LD50
>5000 mg/kg (rat)
Inhalative LC50/4 h ca. 0.4 mg/l
· Subacute to chronic toxicity:
Duration of trials: 2 years:
Application: inhalative/rats/>0.2,<1 mg/m3/ aerosol (PMDI) Result: by
inhalative adsorption, the substance causes extensive local irritation in
rats with epithelial damage. In addition to this, local tumors developed
following this damage in some animals.
· Experience with humans:
Can lead to strong irritation of the eyes and respiratory tract, depending
on the concentration. Irritation of the skin and mucous membranes can
occur in cases of prolonged action by the product. A delay in the
occurrence of symptoms is possible, e.g. coughing, difficulties in
breathing, feeling of confinement in the chest.
Sensitization: a sensitization of the skin cannot be ruled out for persons
of over-sensitivity. Danger of sensitization for repeated contact with the
skin. Can cause sensitization of the respirator tract in cases of allergy.
Avoid inhalation and contact with the skin. Experience at the workplace
indicates that there are no known carcinogenic effects on humans.
(Contd. on page 5)
GB
DR
Page 5/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
Trade name Okamul PU-K Comp.B
(Contd. of page 4)
· Additional toxicological
information:
Detrimental effects from handling the product in accordance with
procedures are not known to date.
12 Ecological information:
The product contains diphenylmethane-4,4'-diisocyanate, for which the following information is
applicable:
· Information about elimination
(persistence and degradability):
· Ecotoxical effects:
· Additional ecological
information:
Evaluation:
Reacts slowly with water at the surface thereby liberating CO2 to give an
insoluble highmelting poly-urea product. According to previous
experience, this product is inert and not degradable.
Daphnia toxicity (acute): EC/LC50 ( h): >1000 mg/l
Bacterial toxicity: EC/LC0 ( h): > 10 000 mg/l
Fish toxicity: EC/LC0 ( 96 h): > 10 000 mg/l
The product may not enter waters without prior treatment (biological
water treatment plant). Prevent penetration into the earth and waters.
13 Disposal considerations
· Product:
· Uncleaned packagings:
· Recommendation:
Must be forwarded for special treatment in accordance with local
authority regulations, e.g. suitable incineration plant.
Disposal must be made according to official regulations.
14 Transportinstruction
· Transport/Additional
information:
Not classified as dangerous in the meaning of transport regulations.
15 Regulatory information
· Designation according to EC
guidelines:
· Code letter and hazard
designation of product:
The product has been classified and labelled in accordance with EC
Directives / Ordinance on Hazardous Materials (GefStoffV)
Xn Harmful
· Risk phrases:
20
Harmful by inhalation.
36/37/38 Irritating to eyes, respiratory system and skin.
42
May cause sensitization by inhalation.
· Safety phrases:
2
26
28
38
45
Keep out of the reach of children.
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
After contact with skin, wash immediately with plenty of ... .
In case of insufficient ventilation, wear suitable respiratory
equipment.
In case of accident or if you feel unwell, seek medical advice
immediately.
(Contd. on page 6)
GB
DR
Page 6/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 08.10.2008
Revision: 08.10.2008
Trade name Okamul PU-K Comp.B
(Contd. of page 5)
· Special designation of certain
preparations:
Contains isocyanates. See information supplied by the manufacturer.
· National regulations
· Decree to be applied in case of
technical fault:
n.a.
· Water hazard class:
Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
Chapters which have been revised from the previous issue are marked "*".
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the (in
this sense consult information on use and on product), but to liberation of major amounts in case of
accidents and irregularities.
(n.a. - not applicable, n.d. - not determined)
This information describes exclusively the safety requirements for the product(s) and is based on the
present level of our knowledge. It does not constitute a legal warranty regulations. The delivery
specifications are contained in the corresponding product sheet.
· Relevant R-phrases
20
Harmful by inhalation.
36/37/38 Irritating to eyes, respiratory system and skin.
42/43
May cause sensitisation by inhalation and skin contact.
· Abbreviations and acronyms:
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
GB