Silver Nano/Submicron paste Silver Nano Paste Silk-Screen vs. Offset Printing Offset Silk Screen Viscosity (cPs) Product Description 100,000~300,000 Curing temp ▪ Silver Nano Paste is made of silver nanoparticles, (Printed by Nano) 10,000~20,000 Under150℃ x 30~60 min which are uniformly dispersed in polar or non-polar solvent with high solid content. The silver paste can be well applied to conventional and new printing methods such as silk screen, gravure, flexography, and micro- Height 10~15um ≤ 1um Specific Resistivity 3 x 10-5 Ω.Cm 2~3 x 10-5Ω.Cm contact printing methods. Printed fine electrodes offer Length: 7.24 um Height: 811 nm bulk silver conductivity even at low temperature curing conditions, which is essential for printed electronics. Product Characteristics ▪ Nano silver particle offers excellent fine patterning with superior process capability. ▪ Wide range of curing temperature for plastics & glass. ▪ Conductivity is as low as bulk silver offering high conductivity even in micron scale patterned electrode. ▪ For conventional & cutting-edge printing Technologies. (Silk-Screen, Gravure, Off-set, Micro contact printing ) Image ▪ Line width : 60~70 um ▪ Design: 50um x 100um SUS 400mesh Product Specification Product Categories(Silver Paste) Nano Properties DGP Silver Contents DGH Hybrid DGP-TEN DGP80TENS5050 70-80% Viscosity (CPS) Submicron DGP80TESM8020 DGP80TES 80% (±5%) 100,000 ~ 300,000 Curing Condition 120~150℃ /30min 230~300℃ /30min Specific Resistivity (µΩ•cm) 10 2~3 Substrates Plastic Film Glass Printing Method Remark Adjustable 120~150℃/ 30min 20~40 10~30 10~30 10~30 Depends on Temp/Time ITO Film & ITO Glass, Plastic Film, Bare Glass Silk - Screen, Gravure, Off-Set , Micro stamping, etc. Product Applications ▪ PDP (Plasma Display Panel) Electrodes ▪ RFID (Radio Frequency Identification) ▪ FPCB (Flexible Printed Circuit Board) ▪ EMI (electromagnetic interference) ▪ Solar Cell ▪ Other Flexible Display and Printed Electronics Advanced Nano Product 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 Tel : 82-43-275-6966 Fax: 82-43-275-6960 Nano-silver Ink for inkjet printing Silver Jet Ink # TEM image of Silver ink. Product Description Silver ink Patterning image Product Characteristics Nano silver particles uniformly dispersed in polar or • Excellent ink stability for long term storage. non-polar solvent as high solid content with low • Excellent conductivity as low as bulk silver. viscosity for ink jet application. • High solid % ink with superior jetting performance. Printed fine electrodes offer bulk silver conductivity • Approved jetting performance by most of major inkjet even at low temperature curing conditions. head makers (Dimatix, Xaar, Konica-Minolta Head) • Good adhesion to plastic and glass substrates. Product Specification • Wide range of curing temperatures (150 oC-600 oC). • Direct printing of fine patterning with low production cost. Product Information Product Categories Properties DGP 40LT-15C DGP 40TE-20C DGP 45HTG DGH 55 LT-25C DGH 55 HTG 53~60% 53~58% Solid Content 30~35% Viscosity (cPs) 10~17 (adjustable) 7~16 Surface Tension 35~38 (adjustable) 27~30 Solvent TGME (Triethylene glycol monoethyl ether) Tetradecane Washing Solvents Polar Solvents: Ethyl Alcohol, IPA etc. Non-Polar Solvents: Xylene, Hexane, Octane etc. Curing Temp. 120~150℃ 180~200 ℃ 400℃~550℃ 250℃ 400℃~550℃ Specific Resistivity (µΩ•cm) 11~12 5~9 2~3 2.4~3.0 2.0~2.5 Substrate Plastic films ITO Glass Bare Glass ITO Glass Bare Glass Polyimide film ITO Glass Bare Glass ※ Alcohol, Water also usable as dispersion solvent upon customer’s request. Product Applications ※ Viscosity and surface tension can be modified upon customer’s request. • Solar Cell Electrode • MLCC Electrode • PCB Board • RFID • PDP Electrode • Other Plastic Electronics Advanced Nano Product 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960 Conductive Oxide Sputtering Target ITO Sputtering Target & Tablet ITO & IGZO Rotary Target Max Length for 1pc: 380mm Product Description ANP has developed a high quality of ITO target for its ITO Rotary Target Specification Composition : In2O3 (90.0±0.5), SnO2 (10.0±0.5) Actual Density : >7.0 g/㎤ (Above 98% of the theoretical material density ) Purity : Above 99.99% typical applications of ITO-coated substrates include electrodes for flat panel displays, touch panel contacts, energy saving & automobile windows, optoelectronic devices & solar panels, etc. Product Specification 1. Composition The standard spec is 90wt% In2O3 + 10 wt%SnO2, but other compositions are available on request. 2. Density Broad range of target density is available from low to ultra high grade for the customers requirements. ANP’s ultra high ITO yields the highest density of 99% of the theoretical material density IGZO Rotary Target Specification Composition - In:Ga:Zn = 2:2:1 (ATOMIC RATIO) Actual Density : >6.61 g/㎤ (Above 98% of the theoretical material density ) Purity : Above 99.99% Product Characteristics ANP’s ITO target has been made by utilizing its specialized nano powder production including raw material manufacturing process in house which Density (g/cm3) Deposit Method Low Density Tablet 4.4 ± 0.2 E-beam, Ion Plating High Conductivity : < ρ = 1.7×10-4 Ω·㎝ Super High Density Target ≥ 7.1 Ion Plating, Sputtering No or Little Time Dependency of Physical Properties Product ensures customers a superior, high quality end products High Transparence : > 85% No or Little Scattering Particles during Evaporation Rare occurrence of crack development during evaporation 3. Purity : Product Application Area ≥ 99.99% Transparent Conductive Electrode 4. Dimension (LCD, Touch Panel Screen, PDP, Organic EL, Different sizes and shapes for customer’s needs Smart Windows, Solar Cell) EMI Shield Coating Advanced Nano Product 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960 Transparent Conductive Zinc Oxide T.C Zinc Oxide 3. T.C Zinc Coating Solution With the continuous experiment ANP produced T.C. ZnO by ANP-self. As a intensive method of NANO technology T.C. ZnO can be applied for not only AntiReflection, Anti-Stastic, Low Reflection but also it has great conductivity and transparency than the common materials now using. Test Items Coating solution Total solid contents (%) 20 Transmittance (%) >90 (on TAC film) Pencil hardness >3H (TAC,PET film) Steel wool (300g) OK Adhesion(taping test) PASS Solvent Ketone, Alcohol, etc. Haze(%) < 0.5 Surface Resistivity(Ω/□) <108 Curing method UV Curing Applicable Substrate PET, TAC, PMMA Product Specification 1. T.C Zinc Powder 9000 8000 7000 I n te n s i ty 6000 5000 4000 3000 2000 0 20 30 40 50 60 70 80 2 th e ta - Primary Particle Size : 15~20 nm - Color : Light Blue - BET : 65~70 m2/g 1. T.C Zinc Slurry - PH (at 20℃) : 9~10 - Solid Contents : 20% Transm ittance(% ) 1000 100 90 80 70 60 50 40 30 20 10 0 300 800 - Particle size: (variable) : <100 nm - Viscosity (at 25℃) : 6~7cp 1300 1800 Wavelength(nm) 2300 * Coated on TAC film -Remark : The Transmittance can be changed by Base Film’s transmittance - Haze(%) : <1.0 - Surface Resistivity(Ω/□) : ≤106 Transmittance(%) : >90% - Solvents : Water, Product Applications ▪ Antistatic Coating/AR Coating for FPD ▪ Antistatic Coating on Plastic Sheets ▪ Others Alcohols, PGME, Toluene and etc. Advanced Nano Product 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960 Zirconia/Titania Colloid and Coating Zirconium oxide and Titanium Oxide nano particle in solvents and/or in acrylate monomers for high reflective index film and sheet which applicable in Display and Optics industry. ANP ZrO2 Colloid and Coating ANP TiO2 Colloid and Coating Product Specification Product Specification 1. TiO2 nano-Powder 1. ZrO2 nano-Powder * TEM image Intensity - Size 5∼10nm (Primary Particle) - Color: White - BET: >40m2/g - Size 2∼8nm (Primary Particle) - Color: White - BET: >40m2/g * TEM image 9000 8000 7000 6000 5000 4000 3000 2000 1000 0 20 30 40 50 60 Wavelength(nm) * XRD diffraction 70 80 2. ZrO2 nano-slurry 2. TiO2 nano-slurry •Size : <15nm •Size : <15nm •pH(25℃) - 2~5 •pH(25℃) - 1~5 •Solvents - water, alcohol, PGME, toluene and etc. •Solvents - water, alcohol, and etc. Particle size & Distribution (UPA-150) Particle size & Distribution (UPA-150) 3. ZrO2 dispersive in UV curable monomer Test Item Result Remark Color Light yellow * * Solvent Water, alcohol and etc * >96% Jasco V570 Solid contents(%) 30% 150°C for 2 hour <1 TC-HⅢDPK Particle size <15nm UPA-150 pH(25℃) 2~5 Fisher AP61 Test Item Base P.s Solid contents 50% * Coating thickness 100µm Transmittance(@550nm) Haze R.I Liquid 1.632 Cured 1.651 Atago abbe. Advanced Nano Product 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960 Transparent Conductive Oxide Slurry ITO(Indium Tin Oxide) Nano-Slurry ATO(Antimony Tin Oxide) Powder/ Slurry Product Description Antimony-doped tin oxide nano particle and their colloid for transparent antistatic coating. Product Specification 1. ATO Nano-Powder: Size 5∼10nm (Primary Particle) Color: Dark Blue SnO2 : Sb2O4= 85:15 ∼ 97:3 BET: >40 m2/g Specific Conductivity: Product Description < ρ = 1×10-2 Ω·㎝ ITO nanopowder and sol where In2O3: SnO2 = 85:15 ∼ 95:5 2. ATO Nano-Slurry : Size <50 nm ▪ Types: Yellow type powder Blue type powder Surface- modified powder Mean Size: 27nm Product Specification 1. ITO Nano-Powder: Size 10∼12nm Color: Yellow or Green In2O3: SnO2 = 85:15 ∼ 95:5 BET: >32 m2/g Specific Conductivity: < ρ = 1.7×10-4 Ω·㎝ 2. ITO Nano-Slurry: Size <100nm, down to 50 nm ▪ ▪ ▪ ▪ ▪ ▪ ▪ pH (at 20℃) : 4 or 10 Solid Contents (wt%) :20.5±0.5 Particle size: down to 50 nm Viscosity :1.35±0.15 mPa·s Specific Gravity (at 25℃) :0.965±0.012 Zeta potential (20℃) :77.0±9.0 Solvents: water, alcohols, toluene and etc Product Applications ▪ Transparent Conductive Coating : Blue type, Yellow type ▪ AR Coating, IR coating ▪ ITO Target Advanced Nano Product pH (at 20℃) : 2-4 Solid Contents : 30% Particle size: (variable) > 30 nm Viscosity : 2.4±0.15 mPa·s Solvents : water, alcohols, PGME, toluene and etc 3. ANP Antistatic Coating Solution (UV Curing Type) Content Test method Properties Surface resistivity ASTM D257 108 Ω/□ Charge MIL-B_81705C < 1 sec 5000V→0V HAZE ASTM D1003 <1% VLT ASTM D1003 >70%(blue tone) Hot water resistance 40℃ - 10hr No change Heat resistance 80℃ - 10hr No change -5℃ Weathering Test 85℃ No change 100cycle Product Applications ▪ Antistatic Coating/AR Coating for FPD ▪ Antistatic Coating on Plastic Sheets ▪ Others 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960 Nano-Particle Slurry (Sol) ANP Nano-Particle Slurry Nano-Slurry for LCD BLU Coating Y2O3 Slurry for Lamp /Phosphor Coating Product Description ANP is world leading company focusing its business & research area on the manufacturing of ceramic & metallic nano-powder applied products. • Primary Particle Size: 2~30nm • Dispersion particle Size: 10 ~100nm Lamp Wall Coating Phosphor Coating • High Transparency • High Packing Density • Various Nano Slurry available (Al2O3, Eu2O3, In2O3, La2O3 , MgO, SnO2, TiO2, Y2O3, ZnO, ZrO2 and etc ) • Superior Properties for Coating and Abrasive ANP Slurry Coating vs A Company (Japan) Slurry Coating MgF2 Nano-Slurry (10 nm) for AR Coating ANP MgF2 AR Coating Transparancy % >96 Haze % <0.4 Reflectance % 1.8 Reflective Index Advanced Nano Product 1.38~1.4 Ceria Nano-Slurry for CMP Application Other Nano-Slurry types Al2O3, Eu2O3, In2O3, La2O3 , MgO, SnO2, TiO2, Y2O3, ZnO, ZrO2 and etc Most of metal oxides in the periodic table are available for custom orders 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960 Sputtering Target for Thin Film Solar Cell AZO, ZnO, GZO Rotary Target AZO, ZnO, GZO Targets Max Length for 1pc: 380mm Transparent conductive, aluminum-doped and undoped AZO (ZnO) target for use in displays, touch screens, Solar Cell, OLED and other thin film applications. 1. Product Application Area AZO Rotary Target Specifiaction Composition : 98wt% ZnO + 2wt% Al2O3 Actual Density : >5.5 g/㎤ (Above 99.5% of the theoretical material density ) 5. Product Characteristics Transparent Conductive Electrode for Thin Film Solar Cell ANP’s TCO targets for Thin Film Solar Cell has been made by utilizing its specialized nano powder production including 2. Chemical Data raw material manufacturing process in house which ensures customers a superior, high quality end products Composition AZO target : Standard is 98wt% ZnO + 2wt% Al2O3, (consistent to within± 0.5 wt%) High Transparence : > 85% No or Little Time Dependency of Physical Properties No or Little Scattering Particles during Evaporation ZnO target : ≥99.99wt% Zinc Oxide Rare occurrence of crack development during evaporation GZO Target : The ratio is flexible upon by Customer 6. Data of Sheet Resistance vs. Thickness for AZO* Purity : ≥ 99.99% 3. Physical Data Density : ANP’s AZO & ZnO target has the high density of >99.5% of the theoretical density GZO Target has the high Density >99% Appreance : Planar or Cylinder Size : Different sizes and Shapes for Customer’s needs Target Surface Resistivity : 5x10-3 Ω/square 4. Purity Over 99.95% from high purity raw material (the impurities does not exceed 100ppm) Advanced Nano Product 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960 Silver Paste for Solar Cell Silver Paste 4. Firing Profile ANP Ag paste is a front electrode for mono and multi-crystalline silicon solar cell wafers. Cond. 1 It easily penetrates the anti-reflective (SiNx:H or TiO2-x) during the firing process and provides low contact resistance. Ag Paste can be co-fired with commercially available backside Al and Ag-Al Pastes. Cond. 2 1. Information of Silver Nano Paste Properties Silver Paste for Solar Cells Silver Contents 86~92wt% Viscosity ( cps ) 260,000 ~ 330,000 Adjustable Sheet Resisitivity ≥ 6uΩ•㎝ High Conductivity Printing 325 Mesh Metallic or Polymeric screen Good Printability Drying Range 200℃ within 2 ~ 3minutes Peak Temp. 720 ~ 760℃ Remark ※ Despatch IR Furnace : CF-7210B • Cond1. Set Temperatures : 540/540/580/650/780/890℃ Î Peak Temp. - 731℃ • Cond2. Set Temperatures : 480/500/510/580/800/950℃ Î Peak Temp. - 763℃ • Belt Speed : 210 IPM 5. Efficiency of Silver paste for Solar Cell Good ohmic contact. ※ Cell Efficiency is depend on Firing Temp. & Belt speed. 2. Silver Electrode Microscope Image Finger Line Bus Line ※ 5inch Mono crystalline wafer • Emitter Resistance : 40Ω/□ / • Average Efficiency : 17.6~17.7% 6. Contract Resistance 3. Comparison of Pastes after Firing. • Ag Elctrode Width / Thickness : about 120um / 15~20um • Low Shrinking & Crack-Free ANP Paste Other Paste • Low ratio of pore & Shrinking compared to other paste Advanced Nano Product 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960 Transparent Ray Blocker Film T.R.B. Paste 2. Spectroscopic transmissibility curve for ANP’s TRB paste Product Description ANP produces the world best IR blocking film & coating 3. Structure of TRB film solutions. TRB Paste is UV curable IR-shielding liquids Scratch Resistant Layer PET FILM IR Cut Layer (TRB Paste) containing ITO, ATO, & other ultrafine compounds (solar control paste) with high Vis ray transparency as well as high IR/ UV blocking properties and is applied to window Adhesive Layer film in automobiles and buildings. Window Glass • IR cut in adhesive layer Product Specification 1. World best Transparent IR Blocking Film and coating solutions by wet-coating method Scratch Resistant Layer PET FILM Adhesive Layer IR Cut Layer (TRB Paste) PET FILM Adhesive Layer • IR cut in hard layer Window Glass • IR cut b/w 2 ply film Product Categories Properties Solid contents (%) *1 Remark TRBSH TRBSM TRBSR TRBSL 40 50 45 45 Product Characteristics • Highly conductive coating material • High visible light transmission • High IR / UV Blocking performance VLT% (Visible Light Transmission) 70 IR shielding*1 (%) 90 70 70 65 UV/VIS Haze (%) < 1.2 < 1.0 < 1.2 < 1.0 ASTM D1003 Hardness 3H 3H 3H 3H ASTM D1003 70 60 60 ASTM D1003 : Properties changed by the coating method (e.g., Coating Bar#) Advanced Nano Product • High Energy efficient by heat insulation properties • Low production cost compared to sputtering film Product Applications • Conductive coating materials & paste • Heat Mirror glass & automobile, residential & office building window glass film 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960 UV Blocker Zinc Oxide Powder/Slurry 2. TEM Image ANP’s ZnO Powder & Emulsion(Slurry) ANP has developed a high purity of Zinc Oxide Powder with ANP’s own hydrothermal technology. Also, It’s uniformity is help to be a highly transparent Zinc Emulsion with better properties than any other’s one for it’s application of Electronic material and Cosmetic industry. 3. Particle Distribution & Cryo SEM 1. Specification • Particle Distribution : 20~30nm • High Purity : >99.9% 4. UV Graph of ZnO Coating Films • High Transparency 90 - ANP - J competitor - K competitor 80 • UV Blocking 70 • High Stability 60 T% 50 • Variable Application with Diverse Coating Material. - ANP - Competitor 40 30 20 2. Physical Data 10 0 200 250 300 350 400 450 500 nm 1. XRD 5. ZnO Emulsion SPF & SPA 9000 Compitor ANP SPF 21.54 23.1 SPA 19.45 21.33 8000 7000 I n te n s i ty 6000 5000 4000 % Solids = 53.0% In Cyclo Siloxane 3000 2000 1000 3. Applications 0 20 30 40 50 2 theta 60 70 80 • LCD • Optical Films • Cosmetic Material Advanced Nano Product 244, Buyong industrial complex, kumho-ri, Buyong-myeon, Chungwon-kun, Chungcheongbuk-do, Korea 363-942 webadmin@anapro.com Tel : 82-43-275-6966 Fax: 82-43-275-6960