Silver Nano/Submicron paste

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Silver Nano/Submicron paste
Silver Nano Paste
Silk-Screen vs. Offset Printing
Offset
Silk Screen
Viscosity
(cPs)
Product Description
100,000~300,000
Curing temp
▪ Silver Nano Paste is made of silver nanoparticles,
(Printed by Nano)
10,000~20,000
Under150℃ x 30~60 min
which are uniformly dispersed in polar or non-polar
solvent with high solid content. The silver paste can be
well applied to conventional and new printing methods
such as silk screen, gravure, flexography, and micro-
Height
10~15um
≤ 1um
Specific
Resistivity
3 x 10-5 Ω.Cm
2~3 x 10-5Ω.Cm
contact printing methods. Printed fine electrodes offer
Length: 7.24 um
Height: 811 nm
bulk silver conductivity even at low temperature curing
conditions, which is essential for printed electronics.
Product Characteristics
▪ Nano silver particle offers excellent fine patterning
with superior process capability.
▪ Wide range of curing temperature for plastics & glass.
▪ Conductivity is as low as bulk silver offering high
conductivity even in micron scale patterned electrode.
▪ For conventional & cutting-edge printing Technologies.
(Silk-Screen, Gravure, Off-set, Micro contact printing )
Image
▪ Line width
: 60~70 um
▪ Design:
50um x 100um
SUS 400mesh
Product Specification
Product Categories(Silver Paste)
Nano
Properties
DGP
Silver Contents
DGH
Hybrid
DGP-TEN
DGP80TENS5050
70-80%
Viscosity (CPS)
Submicron
DGP80TESM8020
DGP80TES
80% (±5%)
100,000 ~ 300,000
Curing Condition
120~150℃
/30min
230~300℃
/30min
Specific Resistivity
(µΩ•cm)
10
2~3
Substrates
Plastic Film
Glass
Printing Method
Remark
Adjustable
120~150℃/ 30min
20~40
10~30
10~30
10~30
Depends on
Temp/Time
ITO Film & ITO Glass, Plastic Film, Bare Glass
Silk - Screen, Gravure, Off-Set , Micro stamping, etc.
Product Applications
▪ PDP (Plasma Display Panel) Electrodes ▪ RFID (Radio Frequency Identification)
▪ FPCB (Flexible Printed Circuit Board) ▪ EMI (electromagnetic interference)
▪ Solar Cell
▪ Other Flexible Display and Printed Electronics
Advanced Nano Product
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
Tel : 82-43-275-6966
Fax: 82-43-275-6960
Nano-silver Ink for inkjet printing
Silver Jet Ink
# TEM image of Silver ink.
Product Description
Silver ink Patterning image
Product Characteristics
Nano silver particles uniformly dispersed in polar or
• Excellent ink stability for long term storage.
non-polar solvent as high solid content with low
• Excellent conductivity as low as bulk silver.
viscosity for ink jet application.
• High solid % ink with superior jetting performance.
Printed fine electrodes offer bulk silver conductivity
• Approved jetting performance by most of major inkjet
even at low temperature curing conditions.
head makers (Dimatix, Xaar, Konica-Minolta Head)
• Good adhesion to plastic and glass substrates.
Product Specification
• Wide range of curing temperatures (150 oC-600 oC).
• Direct printing of fine patterning with low production cost.
Product Information
Product Categories
Properties
DGP
40LT-15C
DGP
40TE-20C
DGP
45HTG
DGH
55 LT-25C
DGH
55 HTG
53~60%
53~58%
Solid Content
30~35%
Viscosity (cPs)
10~17 (adjustable)
7~16
Surface Tension
35~38 (adjustable)
27~30
Solvent
TGME (Triethylene glycol monoethyl ether)
Tetradecane
Washing Solvents
Polar Solvents: Ethyl Alcohol, IPA etc.
Non-Polar Solvents: Xylene,
Hexane, Octane etc.
Curing Temp.
120~150℃
180~200 ℃
400℃~550℃
250℃
400℃~550℃
Specific Resistivity (µΩ•cm)
11~12
5~9
2~3
2.4~3.0
2.0~2.5
Substrate
Plastic films
ITO Glass
Bare Glass
ITO Glass
Bare Glass
Polyimide
film
ITO Glass
Bare Glass
※ Alcohol, Water also usable as dispersion solvent upon customer’s request.
Product Applications
※ Viscosity and surface tension can be modified upon customer’s request.
• Solar Cell Electrode • MLCC Electrode • PCB Board • RFID
• PDP Electrode • Other Plastic Electronics
Advanced Nano Product
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
Conductive Oxide Sputtering Target
ITO Sputtering Target & Tablet
ITO & IGZO Rotary Target
Max Length for 1pc: 380mm
Product Description
ANP has developed a high quality of ITO target for its
„ ITO Rotary Target Specification
Composition : In2O3 (90.0±0.5), SnO2 (10.0±0.5)
Actual Density : >7.0 g/㎤
(Above 98% of the theoretical material density )
Purity : Above 99.99%
typical applications of ITO-coated substrates include
electrodes for flat panel displays, touch panel contacts,
energy saving & automobile windows, optoelectronic
devices & solar panels, etc.
Product Specification
1. Composition
„ The standard spec is 90wt% In2O3 + 10 wt%SnO2,
but other compositions are available on request.
2. Density
„ Broad range of target density is available from low to
ultra high grade for the customers requirements.
„ ANP’s ultra high ITO yields the highest density of
99% of the theoretical material density
„IGZO Rotary Target Specification
Composition - In:Ga:Zn = 2:2:1 (ATOMIC RATIO)
Actual Density : >6.61 g/㎤
(Above 98% of the theoretical material density )
Purity : Above 99.99%
Product Characteristics
„ ANP’s ITO target has been made by utilizing its
specialized nano powder production including raw
material manufacturing process in house which
Density
(g/cm3)
Deposit
Method
Low
Density Tablet
4.4 ± 0.2
E-beam,
Ion Plating
„ High Conductivity : < ρ = 1.7×10-4 Ω·㎝
Super High
Density Target
≥ 7.1
Ion Plating,
Sputtering
„ No or Little Time Dependency of Physical Properties
Product
ensures customers a superior, high quality end
products
„ High Transparence : > 85%
„ No or Little Scattering Particles during Evaporation
„ Rare occurrence of crack development during evaporation
3. Purity :
Product Application Area
„ ≥ 99.99%
„ Transparent Conductive Electrode
4. Dimension
(LCD, Touch Panel Screen, PDP, Organic EL,
„ Different sizes and shapes for customer’s needs
Smart Windows, Solar Cell)
„ EMI Shield Coating
Advanced Nano Product
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
Transparent Conductive Zinc Oxide
T.C Zinc Oxide
3. T.C Zinc Coating Solution
With the continuous experiment ANP produced T.C.
ZnO by ANP-self. As a intensive method of NANO
technology T.C. ZnO can be applied for not only AntiReflection, Anti-Stastic, Low Reflection but also it has
great conductivity and transparency than the common
materials now using.
Test Items
Coating solution
Total solid contents (%)
20
Transmittance (%)
>90
(on TAC film)
Pencil hardness
>3H
(TAC,PET film)
Steel wool (300g)
OK
Adhesion(taping test)
PASS
Solvent
Ketone, Alcohol, etc.
Haze(%)
< 0.5
Surface Resistivity(Ω/□)
<108
Curing method
UV Curing
Applicable Substrate
PET, TAC, PMMA
Product Specification
1. T.C Zinc Powder
9000
8000
7000
I n te n s i ty
6000
5000
4000
3000
2000
0
20
30
40
50
60
70
80
2 th e ta
- Primary Particle Size : 15~20 nm
- Color : Light Blue
- BET : 65~70 m2/g
1. T.C Zinc Slurry
- PH (at 20℃) : 9~10
- Solid Contents : 20%
Transm ittance(% )
1000
100
90
80
70
60
50
40
30
20
10
0
300
800
- Particle size: (variable)
: <100 nm
- Viscosity (at 25℃) :
6~7cp
1300
1800
Wavelength(nm)
2300
* Coated on TAC film
-Remark : The Transmittance can be changed by Base Film’s
transmittance
- Haze(%) : <1.0
- Surface Resistivity(Ω/□)
: ≤106
Transmittance(%) : >90%
- Solvents : Water,
Product Applications
▪ Antistatic Coating/AR Coating for FPD
▪ Antistatic Coating on Plastic Sheets ▪ Others
Alcohols,
PGME, Toluene and etc.
Advanced Nano Product
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
Zirconia/Titania Colloid and Coating
Zirconium oxide and Titanium
Oxide nano particle in solvents
and/or in acrylate monomers for
high reflective index film and sheet
which applicable in Display and
Optics industry.
ANP ZrO2 Colloid and Coating
ANP TiO2 Colloid and Coating
Product Specification
Product Specification
1. TiO2 nano-Powder
1. ZrO2 nano-Powder
* TEM image
Intensity
- Size 5∼10nm (Primary Particle)
- Color: White
- BET: >40m2/g
- Size 2∼8nm (Primary Particle)
- Color: White
- BET: >40m2/g
* TEM image
9000
8000
7000
6000
5000
4000
3000
2000
1000
0
20
30
40
50
60
Wavelength(nm)
* XRD diffraction
70
80
2. ZrO2 nano-slurry
2. TiO2 nano-slurry
•Size : <15nm
•Size : <15nm
•pH(25℃) - 2~5
•pH(25℃) - 1~5
•Solvents - water, alcohol,
PGME, toluene and etc.
•Solvents - water, alcohol,
and etc.
ƒParticle size &
Distribution (UPA-150)
ƒParticle size &
Distribution (UPA-150)
3. ZrO2 dispersive in UV curable monomer
Test Item
Result
Remark
Color
Light yellow
*
*
Solvent
Water, alcohol and etc
*
>96%
Jasco V570
Solid contents(%)
30%
150°C for 2 hour
<1
TC-HⅢDPK
Particle size
<15nm
UPA-150
pH(25℃)
2~5
Fisher AP61
Test Item
Base
P.s
Solid contents
50%
*
Coating thickness
100µm
Transmittance(@550nm)
Haze
R.I
Liquid
1.632
Cured
1.651
Atago abbe.
Advanced Nano Product
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
Transparent Conductive Oxide Slurry
ITO(Indium Tin Oxide) Nano-Slurry
ATO(Antimony Tin Oxide) Powder/ Slurry
Product Description
Antimony-doped tin oxide nano particle and their
colloid for transparent antistatic coating.
Product Specification
1. ATO Nano-Powder: Size 5∼10nm (Primary Particle)
Color: Dark Blue
SnO2 : Sb2O4= 85:15 ∼ 97:3
BET: >40 m2/g
Specific Conductivity:
Product Description
< ρ = 1×10-2 Ω·㎝
ITO nanopowder and sol where
In2O3: SnO2 =
85:15 ∼ 95:5
2. ATO Nano-Slurry : Size <50 nm
▪ Types:
Yellow type powder
Blue type powder
Surface- modified powder
Mean Size: 27nm
Product Specification
1. ITO Nano-Powder: Size 10∼12nm
Color: Yellow or Green
In2O3: SnO2 = 85:15 ∼ 95:5
BET: >32 m2/g
Specific Conductivity:
< ρ = 1.7×10-4 Ω·㎝
2. ITO Nano-Slurry: Size <100nm, down to 50 nm
▪
▪
▪
▪
▪
▪
▪
pH (at 20℃) : 4 or 10
Solid Contents (wt%) :20.5±0.5
Particle size: down to 50 nm
Viscosity :1.35±0.15 mPa·s
Specific Gravity (at 25℃) :0.965±0.012
Zeta potential (20℃) :77.0±9.0
Solvents: water, alcohols, toluene and etc
Product Applications
▪ Transparent Conductive Coating
: Blue type, Yellow type
▪ AR Coating, IR coating
▪ ITO Target
Advanced Nano Product
pH (at 20℃) : 2-4
Solid Contents : 30%
Particle size:
(variable) > 30 nm
Viscosity : 2.4±0.15 mPa·s
Solvents : water, alcohols,
PGME, toluene and etc
3. ANP Antistatic Coating Solution (UV Curing Type)
Content
Test method
Properties
Surface
resistivity
ASTM D257
108 Ω/□
Charge
MIL-B_81705C
< 1 sec
5000V→0V
HAZE
ASTM D1003
<1%
VLT
ASTM D1003
>70%(blue tone)
Hot water
resistance
40℃ - 10hr
No change
Heat resistance
80℃ - 10hr
No change
-5℃
Weathering
Test
85℃
No change
100cycle
Product Applications
▪ Antistatic Coating/AR Coating for FPD
▪ Antistatic Coating on Plastic Sheets
▪ Others
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
Nano-Particle Slurry (Sol)
ANP Nano-Particle Slurry
Nano-Slurry for LCD BLU Coating
Y2O3 Slurry for Lamp /Phosphor Coating
Product Description
ANP is world leading company focusing its
business & research area on the manufacturing of
ceramic & metallic nano-powder applied products.
• Primary Particle Size: 2~30nm
• Dispersion particle Size: 10 ~100nm
Lamp Wall Coating
Phosphor Coating
• High Transparency
• High Packing Density
• Various Nano Slurry available
(Al2O3, Eu2O3, In2O3, La2O3 , MgO, SnO2, TiO2, Y2O3, ZnO,
ZrO2 and etc )
• Superior Properties for Coating and Abrasive
ANP Slurry Coating vs A Company (Japan) Slurry Coating
MgF2 Nano-Slurry (10 nm) for AR Coating
ANP MgF2 AR Coating
Transparancy
%
>96
Haze
%
<0.4
Reflectance
%
1.8
Reflective Index
Advanced Nano Product
1.38~1.4
Ceria Nano-Slurry for CMP Application
Other Nano-Slurry types
„ Al2O3, Eu2O3, In2O3, La2O3 , MgO, SnO2, TiO2, Y2O3,
ZnO, ZrO2 and etc
„ Most of metal oxides in the periodic table are
available for custom orders
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
Sputtering Target for Thin Film Solar Cell
AZO, ZnO, GZO Rotary Target
AZO, ZnO, GZO Targets
Max Length for 1pc: 380mm
Transparent conductive, aluminum-doped and undoped
AZO (ZnO) target for use in displays, touch screens, Solar
Cell, OLED and other thin film applications.
1. Product Application Area
„ AZO Rotary Target Specifiaction
Composition : 98wt% ZnO + 2wt% Al2O3
Actual Density : >5.5 g/㎤
(Above 99.5% of the theoretical material density )
5. Product Characteristics
„ Transparent Conductive Electrode for Thin Film Solar Cell „ ANP’s TCO targets for Thin Film Solar Cell has been made
by utilizing its specialized nano powder production including
2. Chemical Data
raw material manufacturing process in house which
ensures customers a superior, high quality end products
„ Composition
AZO target : Standard is 98wt% ZnO + 2wt% Al2O3,
(consistent to within± 0.5 wt%)
„ High Transparence : > 85%
„ No or Little Time Dependency of Physical Properties
„ No or Little Scattering Particles during Evaporation
ZnO target : ≥99.99wt% Zinc Oxide
„ Rare occurrence of crack development during evaporation
GZO Target : The ratio is flexible upon by Customer
6. Data of Sheet Resistance vs. Thickness for AZO*
„ Purity : ≥ 99.99%
3. Physical Data
„Density : ANP’s AZO & ZnO target has the high density
of >99.5% of the theoretical density
GZO Target has the high Density >99%
„ Appreance : Planar or Cylinder
„Size : Different sizes and Shapes for Customer’s needs
„Target Surface Resistivity : 5x10-3 Ω/square
4. Purity
„ Over 99.95% from high purity raw material (the impurities
does not exceed 100ppm)
Advanced Nano Product
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
Silver Paste for Solar Cell
Silver Paste
4. Firing Profile
ANP Ag paste is a front electrode for mono
and multi-crystalline silicon solar cell wafers.
Cond. 1
It easily penetrates the anti-reflective
(SiNx:H or TiO2-x) during the firing process
and provides low contact resistance.
Ag Paste can be co-fired with commercially
available backside Al and Ag-Al Pastes.
Cond. 2
1. Information of Silver Nano Paste
Properties
Silver Paste
for Solar Cells
Silver
Contents
86~92wt%
Viscosity
( cps )
260,000 ~ 330,000
Adjustable
Sheet
Resisitivity
≥ 6uΩ•㎝
High
Conductivity
Printing
325 Mesh Metallic or
Polymeric screen
Good
Printability
Drying
Range
200℃ within 2 ~ 3minutes
Peak Temp.
720 ~ 760℃
Remark
※ Despatch IR Furnace : CF-7210B
• Cond1. Set Temperatures
: 540/540/580/650/780/890℃ Î Peak Temp. - 731℃
• Cond2. Set Temperatures
: 480/500/510/580/800/950℃ Î Peak Temp. - 763℃
• Belt Speed : 210 IPM
5. Efficiency of Silver paste for Solar Cell
Good ohmic
contact.
※ Cell Efficiency is depend on Firing Temp. & Belt speed.
2. Silver Electrode Microscope Image
Finger Line
Bus Line
※ 5inch Mono crystalline wafer
• Emitter Resistance : 40Ω/□ /
• Average Efficiency : 17.6~17.7%
6. Contract Resistance
3. Comparison of Pastes after Firing.
• Ag Elctrode Width / Thickness : about 120um / 15~20um
• Low Shrinking & Crack-Free
ANP Paste
Other Paste
• Low ratio of pore & Shrinking compared to other paste
Advanced Nano Product
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
Transparent Ray Blocker Film
T.R.B. Paste
2. Spectroscopic transmissibility curve for
ANP’s TRB paste
Product Description
ANP produces the world best IR blocking film & coating
3. Structure of TRB film
solutions. TRB Paste is UV curable IR-shielding liquids
Scratch Resistant Layer
PET FILM
IR Cut Layer (TRB Paste)
containing ITO, ATO, & other ultrafine compounds (solar
control paste) with high Vis ray transparency as well as
high IR/ UV blocking properties and is applied to window
Adhesive Layer
film in automobiles and buildings.
Window Glass
• IR cut in adhesive layer
Product Specification
1. World best Transparent IR Blocking Film and
coating solutions by wet-coating method
Scratch Resistant Layer
PET FILM
Adhesive Layer
IR Cut Layer (TRB Paste)
PET FILM
Adhesive Layer
• IR cut in hard layer
Window Glass
• IR cut b/w 2 ply film
Product Categories
Properties
Solid contents
(%)
*1
Remark
TRBSH
TRBSM
TRBSR
TRBSL
40
50
45
45
Product Characteristics
• Highly conductive coating material
• High visible light transmission
• High IR / UV Blocking performance
VLT% (Visible
Light
Transmission)
70
IR shielding*1
(%)
90
70
70
65
UV/VIS
Haze (%)
< 1.2
< 1.0
< 1.2
< 1.0
ASTM
D1003
Hardness
3H
3H
3H
3H
ASTM
D1003
70
60
60
ASTM
D1003
: Properties changed by the coating method (e.g., Coating Bar#)
Advanced Nano Product
• High Energy efficient by heat insulation properties
• Low production cost compared to sputtering film
Product Applications
• Conductive coating materials & paste
• Heat Mirror glass & automobile, residential & office
building window glass film
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
UV Blocker Zinc Oxide Powder/Slurry
2. TEM Image
ANP’s ZnO Powder & Emulsion(Slurry)
ANP has developed a high purity of Zinc Oxide Powder
with ANP’s own hydrothermal technology. Also, It’s
uniformity is help to be a highly transparent Zinc Emulsion
with better properties than any other’s one for it’s
application of Electronic material and Cosmetic industry.
3. Particle Distribution & Cryo SEM
1. Specification
• Particle Distribution : 20~30nm
• High Purity : >99.9%
4. UV Graph of ZnO Coating Films
• High Transparency
90
- ANP
- J competitor
- K competitor
80
• UV Blocking
70
• High Stability
60
T%
50
• Variable Application with Diverse Coating Material.
- ANP
- Competitor
40
30
20
2. Physical Data
10
0
200
250
300
350
400
450
500
nm
1. XRD
5. ZnO Emulsion SPF & SPA
9000
Compitor
ANP
SPF
21.54
23.1
SPA
19.45
21.33
8000
7000
I n te n s i ty
6000
5000
4000
% Solids = 53.0% In Cyclo Siloxane
3000
2000
1000
3. Applications
0
20
30
40
50
2 theta
60
70
80
• LCD
• Optical Films
• Cosmetic Material
Advanced Nano Product
244, Buyong industrial complex, kumho-ri, Buyong-myeon,
Chungwon-kun, Chungcheongbuk-do, Korea 363-942
webadmin@anapro.com
Tel : 82-43-275-6966
Fax: 82-43-275-6960
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