material safety data sheet insulating varnish

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Report Date : 06/03/2009
REVISION DATE: MARCH 2009
MATERIAL SAFETY DATA SHEET
INSULATING VARNISH
1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
INSULATING VARNISH
PRODUCT NO.
EMR8008
PRODUCT USE
Resin
HK WENTWORTH-AMERICA
7101 South Adams Street
Suite 8
Willowbrook, IL 60527
USA
Tel 630-323-5100
Fax: 630-323-5101
SUPPLIER
MANUFACTURER
EMERGENCY TELEPHONE
(415) 895 1316 Monday to Friday between 8.30 a.m. and 5 p.m.
IDENTIFICATION No.
1263
ELECTROLUBE. A division of HK
WENTWORTH LTD
KINGSBURY PARK, MIDLAND
ROAD
SWADLINCOTE
DERBYSHIRE, DE11 0AN
UNITED KINGDOM
+44(0)1283 222 111
+44(0)1283 550 177
info@hkw.co.uk
2 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Liquid Amber Stable under normal temperature conditions. Flammable. Irritant May cause sensitisation by skin contact.
Repeated exposure may cause skin dryness or cracking. Avoid contact with skin. Wear suitable gloves. Use only in
well-ventilated areas. Use appropriate containment to avoid environmental contamination. Avoid release to the environment.
Refer to special instructions/safety data sheets. In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or
label. Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical
attention. No hazard in normal industrial use.
ENVIRONMENT
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not empty into drains,
dispose of this material and its container at hazardous or special waste collection point. Dispose of waste and residues in
accordance with local authority requirements.
INHALATION
POTENTIAL HEALTH EFFECTS
Vapors may cause headache, fatigue, dizziness and nausea. High concentrations of vapors may irritate respiratory system
and lead to headache, fatigue, nausea and vomiting.
INGESTION
May cause stomach pain or vomiting.
SKIN CONTACT
May cause sensitization by skin contact. Prolonged or repeated exposure may cause severe irritation.
EYE CONTACT
Irritating to eyes.
CARCINOGENICITY
This substance has no evidence of carcinogenic properties.
3 COMPOSITION/INFORMATION ON INGREDIENTS
1
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Report Date : 06/03/2009
REVISION DATE: MARCH 2009
INSULATING VARNISH
Name
EC No.
CAS-No.
Weight
HYDROCARBON DISTILLATE
265-185-4
64742-82-1
30-60%
WHITE SPIRIT
265-151-9
64742-49-0
10-30%
XYLENE
215-535-7
1330-20-7
1-5%
A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE
OXIME)DIETHOXYSILANE
DEAROMATISED KEROSINE
202-496-6
96-29-7
1-5%
265-150-3
64742-48-9
1-5%
ETHYLBENZENE
202-849-4
100-41-4
<0.5%
4 FIRST-AID MEASURES
NOTES TO THE PHYSICIAN
Treat symptomatically
INHALATION
Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention.
INGESTION
DO NOT INDUCE VOMITING! If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Provide fresh air, warmth and rest, preferably in comfortable upright sitting position. Rinse mouth thoroughly. Get medical
attention.
SKIN CONTACT
Remove affected person from source of contamination. Promptly wash contaminated skin with soap or mild detergent and
water. Promptly remove clothing if soaked through and wash as above. Get medical attention if irritation persists after
washing.
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting
the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Use: Alcohol resistant foam. Powder. Dry chemicals, sand, dolomite etc.
SPECIAL FIRE FIGHTING PROCEDURES
Move container from fire area if it can be done without risk. Use water to keep fire exposed containers cool and disperse
vapors.
AUTO IGNITION TEMPERATURE
230 (446F)
(°C)
FLAMMABILITY LIMIT LOWER(%)
FLAMMABILITY LIMIT - UPPER(%)
FLASH POINT (°C)
0.9
8
38 (100.4F) CC (Closed cup).
6 ACCIDENTAL RELEASE MEASURES
SPILL CLEAN UP METHODS
Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers.
7 HANDLING AND STORAGE
HANDLING
Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is
above accepted level.
STORAGE
Store in tightly closed original container in a cool, dry well-ventilated place. Keep in original container.
STORAGE CLASS
Flammable liquid storage.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
2
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Report Date : 06/03/2009
REVISION DATE: MARCH 2009
INSULATING VARNISH
TWA (8-hrs)
COMPONENT
STD
DEAROMATISED KEROSINE
WEL
ETHYLBENZENE
ACGIH
100 ppm
ETHYLBENZENE
PEL
100 ppm
HYDROCARBON DISTILLATE
WEL
XYLENE
ACGIH
100 ppm
XYLENE
PEL
100 ppm
1000
mg/m3
STEL (15 min)
Notes
125 ppm
A3
150 ppm
A4
435 mg/m3
600 mg/m3
435 mg/m3
COMPONENT
IDLH
ETHYLBENZENE
800 ppm
XYLENE
900
ACGIH = American Conference of Governmental Industrial Hygienists.
PEL = Permissible Exposure Limit (Occupational and Safety Health Administration)
WEL = Workplace Exposure Limit.
A4 = Not Classified as a Human Carcinogen
A3 = Confirmed animal Carcinogen with unknown relevance to humans
PROTECTIVE EQUIPMENT
ENGINEERING MEASURES
Provide sufficient ventilation during operations which cause vapor formation.
RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection must be used if the general level exceeds the Recommended
Occupational Exposure Limit Use respiratory equipment with combination filter, type A2/P2.
HAND PROTECTION
Protective gloves must be used if there is a risk of direct contact or splash. The most suitable glove must be chosen in
consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Nitrile gloves are
recommended.
EYE PROTECTION
Wear approved safety goggles.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapor contact.
HYGIENE MEASURES
DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet.
Wash promptly with soap & water if skin becomes contaminated. When using do not eat, drink or smoke.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Liquid
COLOR
Clear Amber
ODOR
Characteristic
SOLUBILITY
Immiscible with water
BOILING POINT (°C)
VAPOR PRESSURE
FLASH POINT (°C)
152 - 198 (305.6 - 388.4F)
0.32 kPa @ 20 °c (68F)
38 (100.4F) CC (Closed
cup).
RELATIVE DENSITY
VISCOSITY
10 STABILITY AND REACTIVITY
STABILITY
Stable under normal temperature conditions.
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0.920 @ 20 °c (68F)
1500 - 2300 @ 25 °c (77F)
Report Date : 06/03/2009
REVISION DATE: MARCH 2009
INSULATING VARNISH
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition.
11 TOXICOLOGICAL INFORMATION
XYLENE
4300 mg/kg (oral rat)
WHITE SPIRIT
>5000 mg/kg (oral rat)
Name
Toxic Dose 1 - LD 50
Name
Toxic Dose 1 - LD 50
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Dangerous for the environment: May cause long-term adverse effects in the aquatic environment.
Name
XYLENE
LC 50, 96 hrs, Fish mg/l
2.6-8.4
EC 50, 48 hrs, Daphnia, mg/l
1.0-4.7
Name
WHITE SPIRIT
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
IDENTIFICATION No.
PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE
PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE
TUNNEL RESTRICTION CODE
1263
(D/E)
DOT PROPER SHIPPING NAME
TDG SHIPPING NAME
CEFIC TEC(R) NO.
30GF1-III, 30GF1-sp
DOT HAZARD CLASS
DOT PACKING GROUP
III
U.S DOT HAZARD LABEL
3
Flammable Liquid
UN NO. SEA
1263
IMDG CLASS
3
IMDG PACK GR.
III
EMS
F-E, S-E
MFAG
See Guide
MARINE POLLUTANT
N/A.
UN NO. AIR
1263
AIR CLASS
3
AIR PACK GR.
III
TDG CLASS
3
TDG LABEL(S)
3
DOT PACKING GROUP
III
15 REGULATORY INFORMATION
INVENTORIES
COMPONENT
CAN
US
EU
XYLENE
DSL
Yes
EINECS Yes
Yes
ETHYLBENZENE
DSL
Yes
EINECS Yes
Yes
A MIXTURE OF: BUTAN-2-ONE OXIME
SYN-O,O'-DI(BUTAN-2-ONE OXIME)DIETHOXYSILANE
HYDROCARBON DISTILLATE
DSL
Yes
DSL
Yes
EINECS Yes
DEAROMATISED KEROSINE
NDSL
Yes
EINECS Yes
WHITE SPIRIT
DSL
Yes
EINECS Yes
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AUS
JAP
KOR
Yes
CHN
PHLP
Report Date : 06/03/2009
REVISION DATE: MARCH 2009
INSULATING VARNISH
COMPONENT
TSCA 12(b) Export Notification
XYLENE
No
ETHYLBENZENE
No
A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE
OXIME)DIETHOXYSILANE
HYDROCARBON DISTILLATE
No
DEAROMATISED KEROSINE
No
WHITE SPIRIT
No
No
US FEDERAL REGULATIONS
COMPONENT
SARA 302-TPQ
CERCLA-RQ
SARA 313
XYLENE
100 lbs
1.0 %
ETHYLBENZENE
1 000 lbs
0.1 %
A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE
OXIME)DIETHOXYSILANE
HYDROCARBON DISTILLATE
No
Not Listed
No
DEAROMATISED KEROSINE
Not Listed
No
WHITE SPIRIT
Not Listed
No
CLEAN AIR ACT
COMPONENT
CAA Accidental Release Prevention
XYLENE
Not Listed
ETHYLBENZENE
Not Listed
A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE
OXIME)DIETHOXYSILANE
HYDROCARBON DISTILLATE
Not Listed
DEAROMATISED KEROSINE
Not Listed
WHITE SPIRIT
Not Listed
Not Listed
US STATE REGULATIONS
COMPONENT
CAS
CA
FL
MA
MN
NJ
PA
RI
XYLENE
1330-20-7
Yes
Yes
Yes
Yes
Yes
Yes
ETHYLBENZENE
100-41-4
Not
Liste
d
C
Yes
Yes
Yes
Yes
Yes
Yes
A MIXTURE OF: BUTAN-2-ONE OXIME
SYN-O,O'-DI(BUTAN-2-ONE OXIME)DIETHOXYSILANE
96-29-7
64742-82-1
DEAROMATISED KEROSINE
64742-48-9
WHITE SPIRIT
64742-49-0
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Yes
HYDROCARBON DISTILLATE
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not
Liste
d
Not Not
Liste Liste
d
d
Not Not
Liste Liste
d
d
Not Not
Liste Liste
d
d
REGULATORY STATUS (US)
SECTION 313: This product contains toxic chemical subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372. TSCA: The ingredients of this product are
on the TSCA Inventory.
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Report Date : 06/03/2009
REVISION DATE: MARCH 2009
INSULATING VARNISH
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM -WHMIS
LABEL(S) FOR SUPPLY
Flammable
Liquid.
16 OTHER INFORMATION
HAZARDOUS MATERIAL INFORMATION SYSTEM (HMIS)
HEALTH
1
FLAMMABILITY
2
PHYSICAL
0
PERSONAL PROTECTION
B
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
FIRE
(2)
HEALTH
(1)
(0)
INSTABILITY
SPECIAL
ISSUED BY
Pawel Zmarzly
REVISION DATE
MARCH 2009
VERSION No.
0
SDS NO.
10990
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or
in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
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