Report Date : 06/03/2009 REVISION DATE: MARCH 2009 MATERIAL SAFETY DATA SHEET INSULATING VARNISH 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME INSULATING VARNISH PRODUCT NO. EMR8008 PRODUCT USE Resin HK WENTWORTH-AMERICA 7101 South Adams Street Suite 8 Willowbrook, IL 60527 USA Tel 630-323-5100 Fax: 630-323-5101 SUPPLIER MANUFACTURER EMERGENCY TELEPHONE (415) 895 1316 Monday to Friday between 8.30 a.m. and 5 p.m. IDENTIFICATION No. 1263 ELECTROLUBE. A division of HK WENTWORTH LTD KINGSBURY PARK, MIDLAND ROAD SWADLINCOTE DERBYSHIRE, DE11 0AN UNITED KINGDOM +44(0)1283 222 111 +44(0)1283 550 177 info@hkw.co.uk 2 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Liquid Amber Stable under normal temperature conditions. Flammable. Irritant May cause sensitisation by skin contact. Repeated exposure may cause skin dryness or cracking. Avoid contact with skin. Wear suitable gloves. Use only in well-ventilated areas. Use appropriate containment to avoid environmental contamination. Avoid release to the environment. Refer to special instructions/safety data sheets. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. No hazard in normal industrial use. ENVIRONMENT Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Dispose of waste and residues in accordance with local authority requirements. INHALATION POTENTIAL HEALTH EFFECTS Vapors may cause headache, fatigue, dizziness and nausea. High concentrations of vapors may irritate respiratory system and lead to headache, fatigue, nausea and vomiting. INGESTION May cause stomach pain or vomiting. SKIN CONTACT May cause sensitization by skin contact. Prolonged or repeated exposure may cause severe irritation. EYE CONTACT Irritating to eyes. CARCINOGENICITY This substance has no evidence of carcinogenic properties. 3 COMPOSITION/INFORMATION ON INGREDIENTS 1 /6 Report Date : 06/03/2009 REVISION DATE: MARCH 2009 INSULATING VARNISH Name EC No. CAS-No. Weight HYDROCARBON DISTILLATE 265-185-4 64742-82-1 30-60% WHITE SPIRIT 265-151-9 64742-49-0 10-30% XYLENE 215-535-7 1330-20-7 1-5% A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE OXIME)DIETHOXYSILANE DEAROMATISED KEROSINE 202-496-6 96-29-7 1-5% 265-150-3 64742-48-9 1-5% ETHYLBENZENE 202-849-4 100-41-4 <0.5% 4 FIRST-AID MEASURES NOTES TO THE PHYSICIAN Treat symptomatically INHALATION Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. INGESTION DO NOT INDUCE VOMITING! If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position. Rinse mouth thoroughly. Get medical attention. SKIN CONTACT Remove affected person from source of contamination. Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if soaked through and wash as above. Get medical attention if irritation persists after washing. EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Use: Alcohol resistant foam. Powder. Dry chemicals, sand, dolomite etc. SPECIAL FIRE FIGHTING PROCEDURES Move container from fire area if it can be done without risk. Use water to keep fire exposed containers cool and disperse vapors. AUTO IGNITION TEMPERATURE 230 (446F) (°C) FLAMMABILITY LIMIT LOWER(%) FLAMMABILITY LIMIT - UPPER(%) FLASH POINT (°C) 0.9 8 38 (100.4F) CC (Closed cup). 6 ACCIDENTAL RELEASE MEASURES SPILL CLEAN UP METHODS Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. 7 HANDLING AND STORAGE HANDLING Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. STORAGE Store in tightly closed original container in a cool, dry well-ventilated place. Keep in original container. STORAGE CLASS Flammable liquid storage. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 2 /6 Report Date : 06/03/2009 REVISION DATE: MARCH 2009 INSULATING VARNISH TWA (8-hrs) COMPONENT STD DEAROMATISED KEROSINE WEL ETHYLBENZENE ACGIH 100 ppm ETHYLBENZENE PEL 100 ppm HYDROCARBON DISTILLATE WEL XYLENE ACGIH 100 ppm XYLENE PEL 100 ppm 1000 mg/m3 STEL (15 min) Notes 125 ppm A3 150 ppm A4 435 mg/m3 600 mg/m3 435 mg/m3 COMPONENT IDLH ETHYLBENZENE 800 ppm XYLENE 900 ACGIH = American Conference of Governmental Industrial Hygienists. PEL = Permissible Exposure Limit (Occupational and Safety Health Administration) WEL = Workplace Exposure Limit. A4 = Not Classified as a Human Carcinogen A3 = Confirmed animal Carcinogen with unknown relevance to humans PROTECTIVE EQUIPMENT ENGINEERING MEASURES Provide sufficient ventilation during operations which cause vapor formation. RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection must be used if the general level exceeds the Recommended Occupational Exposure Limit Use respiratory equipment with combination filter, type A2/P2. HAND PROTECTION Protective gloves must be used if there is a risk of direct contact or splash. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Nitrile gloves are recommended. EYE PROTECTION Wear approved safety goggles. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapor contact. HYGIENE MEASURES DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap & water if skin becomes contaminated. When using do not eat, drink or smoke. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Liquid COLOR Clear Amber ODOR Characteristic SOLUBILITY Immiscible with water BOILING POINT (°C) VAPOR PRESSURE FLASH POINT (°C) 152 - 198 (305.6 - 388.4F) 0.32 kPa @ 20 °c (68F) 38 (100.4F) CC (Closed cup). RELATIVE DENSITY VISCOSITY 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions. 3 /6 0.920 @ 20 °c (68F) 1500 - 2300 @ 25 °c (77F) Report Date : 06/03/2009 REVISION DATE: MARCH 2009 INSULATING VARNISH CONDITIONS TO AVOID Avoid heat, flames and other sources of ignition. 11 TOXICOLOGICAL INFORMATION XYLENE 4300 mg/kg (oral rat) WHITE SPIRIT >5000 mg/kg (oral rat) Name Toxic Dose 1 - LD 50 Name Toxic Dose 1 - LD 50 12 ECOLOGICAL INFORMATION ECOTOXICITY Dangerous for the environment: May cause long-term adverse effects in the aquatic environment. Name XYLENE LC 50, 96 hrs, Fish mg/l 2.6-8.4 EC 50, 48 hrs, Daphnia, mg/l 1.0-4.7 Name WHITE SPIRIT 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION IDENTIFICATION No. PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE TUNNEL RESTRICTION CODE 1263 (D/E) DOT PROPER SHIPPING NAME TDG SHIPPING NAME CEFIC TEC(R) NO. 30GF1-III, 30GF1-sp DOT HAZARD CLASS DOT PACKING GROUP III U.S DOT HAZARD LABEL 3 Flammable Liquid UN NO. SEA 1263 IMDG CLASS 3 IMDG PACK GR. III EMS F-E, S-E MFAG See Guide MARINE POLLUTANT N/A. UN NO. AIR 1263 AIR CLASS 3 AIR PACK GR. III TDG CLASS 3 TDG LABEL(S) 3 DOT PACKING GROUP III 15 REGULATORY INFORMATION INVENTORIES COMPONENT CAN US EU XYLENE DSL Yes EINECS Yes Yes ETHYLBENZENE DSL Yes EINECS Yes Yes A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE OXIME)DIETHOXYSILANE HYDROCARBON DISTILLATE DSL Yes DSL Yes EINECS Yes DEAROMATISED KEROSINE NDSL Yes EINECS Yes WHITE SPIRIT DSL Yes EINECS Yes 4 /6 AUS JAP KOR Yes CHN PHLP Report Date : 06/03/2009 REVISION DATE: MARCH 2009 INSULATING VARNISH COMPONENT TSCA 12(b) Export Notification XYLENE No ETHYLBENZENE No A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE OXIME)DIETHOXYSILANE HYDROCARBON DISTILLATE No DEAROMATISED KEROSINE No WHITE SPIRIT No No US FEDERAL REGULATIONS COMPONENT SARA 302-TPQ CERCLA-RQ SARA 313 XYLENE 100 lbs 1.0 % ETHYLBENZENE 1 000 lbs 0.1 % A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE OXIME)DIETHOXYSILANE HYDROCARBON DISTILLATE No Not Listed No DEAROMATISED KEROSINE Not Listed No WHITE SPIRIT Not Listed No CLEAN AIR ACT COMPONENT CAA Accidental Release Prevention XYLENE Not Listed ETHYLBENZENE Not Listed A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE OXIME)DIETHOXYSILANE HYDROCARBON DISTILLATE Not Listed DEAROMATISED KEROSINE Not Listed WHITE SPIRIT Not Listed Not Listed US STATE REGULATIONS COMPONENT CAS CA FL MA MN NJ PA RI XYLENE 1330-20-7 Yes Yes Yes Yes Yes Yes ETHYLBENZENE 100-41-4 Not Liste d C Yes Yes Yes Yes Yes Yes A MIXTURE OF: BUTAN-2-ONE OXIME SYN-O,O'-DI(BUTAN-2-ONE OXIME)DIETHOXYSILANE 96-29-7 64742-82-1 DEAROMATISED KEROSINE 64742-48-9 WHITE SPIRIT 64742-49-0 Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Yes HYDROCARBON DISTILLATE Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Liste d Not Not Liste Liste d d Not Not Liste Liste d d Not Not Liste Liste d d REGULATORY STATUS (US) SECTION 313: This product contains toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372. TSCA: The ingredients of this product are on the TSCA Inventory. 5 /6 Report Date : 06/03/2009 REVISION DATE: MARCH 2009 INSULATING VARNISH WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM -WHMIS LABEL(S) FOR SUPPLY Flammable Liquid. 16 OTHER INFORMATION HAZARDOUS MATERIAL INFORMATION SYSTEM (HMIS) HEALTH 1 FLAMMABILITY 2 PHYSICAL 0 PERSONAL PROTECTION B NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) FIRE (2) HEALTH (1) (0) INSTABILITY SPECIAL ISSUED BY Pawel Zmarzly REVISION DATE MARCH 2009 VERSION No. 0 SDS NO. 10990 DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 /6