Chapter 8 Answers 1 a) dimethylamine Marks 1 b) nucleophilic substitution 5 c) 2 quaternary ammonium salt surfactant / detergent / fabric softener or conditioner/ hair conditioner 2 a) Sn or Fe/HCl 2 Sn or Fe/H2SO4 or H2/Ni can be used as the reducing agent. b) AQA Chemistry A2 © Nelson Thornes Ltd 2009 Examiner’s tips 1 The curly arrow must be from the lone pair. Marks 1 and 2 are for the curly arrows if shown (M1 and M2). Mark 3 is for the structure of the intermediate. Mark 4 is to show the removal of the H+. You do not need to show the reagent here. Final mark is for the name of the mechanism. Do not accept dilute or conc. for these 2 acids or you cannot have HNO3 at all. Do not accept NaBH4/ LiAlH4 or Na/C2H5OH. NH3+ is also acceptable. 1 Chapter 8 Answers c) Marks G Examiner’s tips 2 Do not accept the correct answers incorrectly labelled. 5 Mark 1, Mark 2 and Mark 4 are for the curly arrows (M1, M2 and M4). Mark 3 is for the structure of cation. Final mark is for the name of the mechanism. 3 Do not accept HCN here. Accept 4[H] instead of 2H2. H 3 a) Nucleophilic substitution b) Step 1: CH3CH2CH2Br + KCN → CH3CH2CH2CN + KBr (or CN–) (or Br–) Step 2 CH3CH2CH2CN + 2H2 → CH3CH2CH2CH2NH2 c) i) You can have 4[H] instead of 2H2. There is a lone pair (on N); 2 R group increases electron density on N / has positive inductive effect; d) CH3CH2N(CH3)2 1 4 a) CH3CH2CH2Br 1 b) CH3CH2CN 1 AQA Chemistry A2 © Nelson Thornes Ltd 2009 Allow Cl instead of Br. 2 Chapter 8 Answers Marks Examiner’s tips c) nucleophilic substitution or from CH3CH2CH2Br gives less pure produce because further substitution occurs The impurity can be any one of (CH3CH2CH2)2NH (CH3CH2CH2)3N (CH3CH2CH2)4N+ Br− 3 Also accept ‘have salts including NH4Br as impurities’. 5 a) i) 1 Don’t forget to show both charges. ii) 1 The acid part reacts with the alcohol to form an ester. 1 Allow COO− But don’t allow O-Na since this would look covalent. 1 Allow N protonated. 1 There are 2 N atoms which can be protonated. b) AQA Chemistry A2 © Nelson Thornes Ltd 2009 3 Chapter 8 Answers Marks Examiner’s tips c) 1 or 6 a) 2-aminopropanoic acid 1 b) i) 1 Do not accept –CONH− or −COHN− since you would not be showing how the link bonded. ii) 1 Do not accept C3H7 but is acceptable. iii) 2 (nucleophilic) addition–elimination AQA Chemistry A2 © Nelson Thornes Ltd 2009 4 Chapter 8 Answers c) Marks i) X 1 ii) Y 1 7 Structure 1 = 2 Examiner’s tips You cannot have a polypeptide since the question asked for a dipeptide. Structure 2 = either 8 a) 1 b) ionic bonding in aminoethanoic acid AQA Chemistry A2 © Nelson Thornes Ltd 2009 1 Do not accept ‘stronger hydrogen bonding in aminoethanoic acid.’ This can only be gained if you have shown that there is ionic bonding in the solid or stronger attractions than hydrogen bonding in hydroxyethanoic acid. 5 Chapter 8 Answers 9 a) 2-aminobutanoic acid Marks 1 b) 1 10 a) 1 b) 1 c) hydrogen bonding In acid solution the amino acid acts as a base and picks up a proton. This must be a dipeptid and not a polymer. 1 11 a) molecules with same structural formula but with bonds arranged differently in space 2 b) plane polarised light rotated equally in opposite directions 2 AQA Chemistry A2 © Nelson Thornes Ltd 2009 Examiner’s tips Also accept ‘atoms’ arranged differently in space. 6