SUMMARY GUIDANCE ON SOIL SCREENING LEVELS Version 1 - December 2013 SOIL SCREENING LEVELS This guidance addresses the selection and use of “screening levels” in prioritising contaminated sites for remediation efforts. KEY POINTS a. Soil Screening Levels (SSLs) are used in remediation programmes and projects to provide a reference point for priority setting in relation to possible interventions. They are used to “screen out” sites (or areas within sites) which are a low priority in terms of risk. b. There are a number of well established SSL systems internationally, all in industrialised countries. They are based on similar approaches: health data for a particular chemical is combined with assumptions about typical exposures and with policy judgements about acceptable levels of risk, to provide guidance on acceptable levels of contaminants in soils. c. The range of systems and SSLs has been reviewed by Blacksmith Institute, in the context of updating the priority ranking component of the Toxic Sites Identification Program (TSIP). There is a very wide variation in the values adopted in different systems and the spread of SSL values does not allow “consensus” values to be identified. d. The USEPA system is comprehensive and has been rationalised and updated relatively recently. It has a high degree of credibility, given the scientific expertise and decades of experience which underlie it. It has therefore been used as the basis for the SSLs applied to the Toxic Sites Identification Program. e. In order to derive a system that is more widely applicable in the global context of TSIP, some adjustments were made to the EPA values, particularly in relation to a number of substances categorised as possible carcinogens, where the high risk factors applied in the USA result in stringent levels that may not be as appropriate in other countries. f. For agricultural use of land, where USEPA SSLs are not available, relevant values from Canadian and UK systems have been used. Work continues to developed more detailed guidance on pesticide screening levels. g. It is a long and complicated process to develop a new set of SSLs. In the absence of national values, authorities who are responsible for remediation efforts may wish to use the values assembled here in their initial screening or may adopt values from one of the established systems. It is important to ensure that any such use takes full account of national and local conditions and circumstances. h. On this basis, SSLs for the most frequently occurring substances in the toxic sites work are provided in this Guidance Note (see Table in Annex). Links are provided to the systems referenced. GAHP Guidance Notes provide information on international good practices and regulations in remediation. They are prepared to assist GAHP members in dealing with practical problems of remediation of polluted sites and are intended to assist readers to identify key points that should be taken into account in reviewing or approving any proposal. Guidance notes reflect the views of individual GAHP specialists and of invited outside experts and do not necessarily represent the views of any specific government or agency. Additional background and material may be found on the GAPH website. SOIL SCREENING LEVELS Version 1 - December 2013 CONTEXT The context for this guidance is support for the implementation of national or sub-national remediation programmes, based on the identification of contaminated sites and the setting of priorities for remediation interventions. Remediation programmes typically use risk based approaches, given the high costs of major remediation projects and the limited human, technical and financial resources that are normally available. Essential first stages in a remediation effort are to build of a list of potentially contaminated sites and to establish a process to identify which sites should be priorities for investigation and intervention. The list and the priorities will continue to evolve as more and better information is obtained and as experience is gained in the process. Guidance Notes are intended to be used in a dialogue between GAHP members and the agencies involved in remediation programmes and projects. Further context on the purpose and development of these Guidance Notes is provided on the GAHP website. SCREENING AS PART OF PRIORITY SETTING Decisions on which interventions to undertake are almost always based on a “triage” process: immediate attention has to be given to sites which are clearly high priority (based on aspects such as visibility, public concern, and health impacts); sites presenting little risk are excluded from short term consideration; and the remaining sites have to be investigated further. Screening “Screening” is the process of quickly identifying those sites which pose little or no risk, so that they can be given low priority in the remediation programme. Such “screening out” usually involves simple sampling/testing for key pollutants and comparison with defined “screening values” or “screening levels”. Soil Screening Levels (SSLs), as discussed and presented here, are intended to help identify those sites which can be considered low risk in terms of health and pollution impacts and which can therefore be given lower priority in initial remediation efforts. Screening values, in the present context, are established on the basis of health effects data and of assumptions about soil conditions and possible pathways, together with policy positions and assumptions related to acceptable levels of risk. The approach is to set out the levels of contamination in the soil below which there is an acceptably low risk of health impacts, using clear assumptions about the use of the land and the typical exposure patterns for people on and around the site. (Screening values can also be developed on the basis of ecological effects but that approach is probably not relevant at present for most developing economy governments.) Development of screening values from scratch is a long process, requiring considerable amounts of local data and high levels of relevant expertise. A number of countries/agencies around the world have established different screening systems and levels. They are specific to the individual country circumstances and conditions and they vary considerably. They are subject to revision as data improves or as assumptions are refined. The differences in various systems, which reflect individual circumstances, mean that there is no clear set of “consensus” values and it is not appropriate to simply adopt a set of external values without careful review. Nevertheless, reference to such existing systems can be a practical approach for countries which have not yet developed their own systems. Focus of sampling/screening The basic risk model is based on the concept of Source-Pathway-Receptor. The screening process normally is focused on the source: the contaminant must be present in quantities and concentrations sufficient to GAHP Guidance Notes provide information on international good practices and regulations in remediation. They are prepared to assist GAHP members in dealing with practical problems of remediation of polluted sites and are intended to assist readers to identify key points that should be taken into account in reviewing or approving any proposal. Guidance notes reflect the views of individual GAHP specialists and of invited outside experts and do not necessarily represent the views of any specific government or agency. Additional background and material may be found on the GAPH website. 2 SOIL SCREENING LEVELS Version 1 - December 2013 present a hazard. Sampling and screening are carried out at the source: if the source is not significant, in relation to established screening levels, then the overall risk is inherently low. Sampling at the receptor, where the contamination may come into contact with people, is not necessarily part of the screening stage. In the context of contaminated or polluted sites, the main focus is usually the level of contamination in the soil and how this may impact people on or close to the site. For this reason, this Guidance is focused on soil parameters and on direct pathways that impact people. Another common area of high concern is the impact on groundwater. This may require more extensive consideration and investigation of the site than is assumed here, which would normally be carried out once the overall level of contamination at a site is determined to be serious. Range of parameters In order to have a practical and low cost screening system, the set of parameters to be used must be limited and easy/inexpensive to sample and test. It is better to have screening values for groups of similar compounds, or for representative compounds, wherever possible. The requirements of the screening process have to match the personnel and the facilities that are available for implementing the process. Sampling and testing procedures Clear and consistent analytical procedures are required for sampling and testing, in order to ensure consistent results, within resource constraints. It is not within the scope of this Guidance Note to address such procedures. It is important that the sampling procedures define how the number and location of samples is to be established, for different sizes and categories of sites. Prior information on the past use and the extent of the site should inform the type and number of samples to be collected and the contaminants for which the samples are to be tested. Given the costs of testing, the requirements should be narrowed as far as is reasonable, at the screening stage. Clear Quality Assurance and Quality Control (QA/QC) protocols should be applied to both sampling and testing. Laboratories used for testing should be certified for working at the level of accuracy and consistency required. EXISTING SOIL SCREENING SYSTEMS Screening systems with specific values to address soil contamination have been developed in a number of countries including the Netherlands, the USA, Canada, Australia, the UK and Brazil. (The European Union is still in the process of developing a common approach.) The Netherlands (Dutch) system provides both Target Values based on background and potential risks to ecosystems and Intervention Values for sites based on risks to humans. In federal systems, individual states/provinces have sometimes taken the lead in developing and implementing systems. In the US many states have local systems, with the EPA more recently establishing consistent standards for federal application. In Canada, the systems were mainly developed at Provincial level, with some Canada-wide values. In Australia, there are national values which are broadly used by the States. In Brazil, the state of Sao Paulo has adopted standards ahead of the Federal Government. All these systems are based on the same approach: use of scientific data on acceptable levels of uptake of chemicals by people, animals and plants, combined with structured scenarios for typical exposure levels of humans in different contexts (residential, industrial, etc.) and with relevant risk factors established for protection of health and environment.. However, there are many differences between the parameters and values used across the systems. In some cases, there are formulas given for developing the site specific values, rather than specific numbers. The actual values for any given parameter can vary by up to two orders or magnitude (or even more). This demonstrates both the inherent variability in geological conditions and in health status between countries and also the effects of different detailed assumptions and approaches. GAHP Guidance Notes provide information on international good practices and regulations in remediation. They are prepared to assist GAHP members in dealing with practical problems of remediation of polluted sites and are intended to assist readers to identify key points that should be taken into account in reviewing or approving any proposal. Guidance notes reflect the views of individual GAHP specialists and of invited outside experts and do not necessarily represent the views of any specific government or agency. Additional background and material may be found on the GAPH website. 3 SOIL SCREENING LEVELS Version 1 - December 2013 SELECTING SOIL SCREENING VALUES A detailed comparison of values for the most common chemical contaminants has been carried out by Blacksmith Institute for the purpose of defining soil screening values for use in the Toxic Site Identification Programme (TSIP), which is supported by GAHP. The systems included in the review were the US EPA, Canada, Australia, the Netherlands and UK. Annex 1 and additional information on the GAHP website provide details of the specific sets of values examined. The review compiled the published screening values for about 90 contaminants which have been reported in the TSIP process, looking separately at values for residential, industrial and agricultural land use. Not all the systems had values for all of the contaminants and all of the uses. In a few cases, especially for complex organics, the values in the systems for the different chemical forms are not readily comparable. This review confirmed the variation across systems, with no consistent pattern which might reflect a more or less conservative approach. There is little clustering about a central values for any contaminant, which might have reflected consensus about appropriate values for a given substance. From the point of view of finding an international point of reference for screening levels, the most comprehensive system is that of the US EPA. This has a strong analytic base, wide coverage (in terms of the substances included) and it has recently been reviewed and revised in order to achieve consistency across the different EPA Regions. These “Regional Screening Levels” (RSLs) are a very good starting point for any other system. As a result, Blacksmith Institute has adopted for its own use a hierarchy of references, starting with values from the published USEPA RSL tables (with one exception, as discussed below), and then using Canadian data or UK data for substances where there is not a relevant USEPA value. The US, Canadian and UK data were developed in the specific context of their national systems and regulations. Care must be taken in adapting them for use in other systems. However, they are based on careful science and rigorous analysis and therefore provide a very good basis from which to work. One notable adjustment applied in this Guidance to the published RSL values is in relation to possibly carcinogenic contaminants. The RSLs specifically reflect US conditions and approaches and use a relatively conservative “one in one-million additional case” risk criterion for a wide range of possibly carcinogenic substances. This results in relatively stringent screening values for such substances. Blacksmith Institute follows this approach for substances which are clearly established as carcinogenic. The criterion used is that the cancer based SSLs are used for those substances categorised by the International Agency for Research on Cancer (IARC – part of WHO) as human carcinogens (“Group 1”) or probable human carcinogens (“Group 2A”). However, for other substances, including those categorised lower on the IARC listings, the relevant non-carcinogen hazard value is adopted. In practice, this distinction applies to a limited number of substances but does resolve some of the apparent major inconsistencies between values in different country systems. The main set of compounds for which this distinction is relevant are pesticides. Many of the pesticides covered in this Guidance are in IARC Group 3 - "not classifiable as to its carcinogenicity to humans". This category is used for agents for which IARC deems there is not adequate evidence on carcinogenicity, noting that further research may be needed. Selection of Screening Levels for pesticides can be complex, given the variety of chemicals used in pesticide formulations and the range of degradation products that can occur in the soil over time. Work continues under GAHP to address these concerns and updated or separate guidance will be provided in due course. Contamination of agricultural land is outside the scope of the RSLs and therefore soil screening values from other systems have been selected for addressing agricultural land. These values are generally from Canadian systems, with UK values used in a cases where no Canadian values are quoted. These values as used here are intended for localised areas contaminated by a specific source and are not intended to apply GAHP Guidance Notes provide information on international good practices and regulations in remediation. They are prepared to assist GAHP members in dealing with practical problems of remediation of polluted sites and are intended to assist readers to identify key points that should be taken into account in reviewing or approving any proposal. Guidance notes reflect the views of individual GAHP specialists and of invited outside experts and do not necessarily represent the views of any specific government or agency. Additional background and material may be found on the GAPH website. 4 SOIL SCREENING LEVELS Version 1 - December 2013 to apply to broad areas of land affected by non-point or distributed pollution. (Some national systems, such as China, do address in detail quality standards for agricultural soils of different types and in different uses.) Work continues under GAHP to identify practical and efficient approaches to screening sites which have been contaminated by pesticides. Selected values On the basis of the above approach a set of SSLs have been selected for use in the Toxic Site Identification Program (TSIP) which is supported by GAHP. These SSLs cover the most common pollutants identified in the TSIP work and provide reference values for different current uses of the land. This compilation has been prepared by GAHP staff on the basis of published information from different sources. They are tabulated in Annex 2. Screening values are given for different current uses of a site. The different values reflect the exposure patterns associated with these different uses. Where there is effectively unrestricted access to a site, then the residential values should be used. Where the site is not open to widespread use by the public, then the industrial values are normally more appropriate. BEYOND SCREENING For those sites with contamination levels which are above the screening level, further decisions have to be taken about the priority of each site for remediation. Conceptually, it would be helpful to have a set of “Response Levels” above which remediation had to be undertaken. However, this concept is not easy to operationalise. Three broad approaches are possible. o Action Levels: This would be a set of values which represent an unacceptable level of risk and which allow a decision to be made, on the basis of the limited initial data, that short-term actions had to be taken to reduce the risk. There are serious practical difficulties in defining, in a simple but fully analytic manner, the specific levels at which the risk posed by a site would be unacceptable. o Multiples of Screening Levels: This approach would use a multiple of the screening level as a threshold to require remediation to be undertaken. The approach is heuristic rather than analytical and therefore simpler to establish but has little real justification, especially since dose response relationship are not the same for all substances. In practice, however, most decision makers would understand higher multiples as inherently riskier. Pragmatic assumptions (such as 3-10 times the Screening Level) are sometimes used to guide priorities for more detailed investigations. o Hazard Ranking: This could be done simply in terms of the multiples of the Screening Level (i.e. highest multiple has highest priority) but this again does not take into account the differences in contaminants and in the site circumstances. A number of simplified forms of a Hazard Ranking System have been developed (e.g. the Blacksmith Index), which take into account both the source and the population at risk. These can provide a more objective basis for setting relative priorities across a number of sites. GAHP Guidance Notes provide information on international good practices and regulations in remediation. They are prepared to assist GAHP members in dealing with practical problems of remediation of polluted sites and are intended to assist readers to identify key points that should be taken into account in reviewing or approving any proposal. Guidance notes reflect the views of individual GAHP specialists and of invited outside experts and do not necessarily represent the views of any specific government or agency. Additional background and material may be found on the GAPH website. 5 SOIL SCREENING LEVELS Version 1 - December 2013 ANNEX 1 Soil Screening Levels considered. The reviews on which this Guidance Note are based examined the specific screening values of national authorities in USA, The Netherlands, Canada, United Kingdom, and Australia. Links to the original sources for these values are provided on the GAHP website, under Technical Advisory Group Guidances. A number of other systems were also reviewed in less detail, including other European countries, New Zealand, China and sub-national authorities in USA, Canada, Australia, and Brazil. EPA source documents The latest version of the USEPA tables of values used in the GAHP Guidance Note are provided at: http://www.epa.gov/reg3hwmd/risk/human/rb-concentration_table/Generic_Tables/ That page presents several tables based on different target risk figures and have been developed in the context of specific EPA regulations. The guidance and caveats provided with these tables should be reviewed carefully before using values for screening. Canada Guidance has been developed mainly at the Provincial level, with the national guidance for a limited set of substances at: http://www.ccme.ca/publications/ceqg_rcqe.html United Kingdom Soil Guideline Values for a small number of substances and a framework and calculation model to assist in assessments are available at: http://www.environment-agency.gov.uk/research/planning/33714.aspx GAHP Guidance Notes provide information on international good practices and regulations in remediation. They are prepared to assist GAHP members in dealing with practical problems of remediation of polluted sites and are intended to assist readers to identify key points that should be taken into account in reviewing or approving any proposal. Guidance notes reflect the views of individual GAHP specialists and of invited outside experts and do not necessarily represent the views of any specific government or agency. Additional background and material may be found on the GAPH website. 6 SOIL SCREENING LEVELS Version 1 - December 2013 ANNEX 2 - SOIL SCREENING LEVELS FOR SELECTED COMMON CONTAMINANTS (in ppm unless otherwise defined) The substances tabulated are those occurring most commonly in the GAHP data. For substances not listed, the references in Annex 1 can be consulted. Pollutant Residential Industrial Agric. 0.61 2.4 12 Cadmium 70 800 1.4 Chromium - Total 64 87 64 Chromium - Hex 0.29 5.6 0.4 Lead 400 800 70 Mercury - Elemental 10 43 26 Mercury - Inorganic 23 310 6.6 Mercury - Methyl 7.8 100 Uranium (soluble salts) 230 3,100 23 Asbestos 1% in soil 1 % in soil 1% in soil Cyanide 22 140 0.9 Dioxin - mixed 9.4x10-5 3.9x10-4 4x10-6 Dioxin - 2,3,7,8-TCDD 4.5x10-6 1.8x10-5 Fluoride 3,100 41,000 200 PCBs - "high risk" 0.22 0.74 0.50 18,000 180,000 3.8 0.06 1.7 0.029 1.0 Chlordane 35 40 DDT 36 430 Dieldrin 3.1 31 Endosulfan 370 3,700 Endrin 18 180 Hexachlorobenzene (Benzene Hexachloride) 49 490 Lindane (Gamma Hexachlorocyclohexane) 21 240 1,200 12,000 Methyl bromide (bromomethane) 7.3 32 Methylparathion 15 150 METALS Arsenic NON-METALS Phenol Vinyl Chloride PESTICIDES Aldrin Malathion GAHP Guidance Notes provide information on international good practices and regulations in remediation. They are prepared to assist GAHP members in dealing with practical problems of remediation of polluted sites and are intended to assist readers to identify key points that should be taken into account in reviewing or approving any proposal. Guidance notes reflect the views of individual GAHP specialists and of invited outside experts and do not necessarily represent the views of any specific government or agency. Additional background and material may be found on the GAPH website. 7 SOIL SCREENING LEVELS Version 1 - December 2013 Parathion 370 3,700 Toxaphene 0.44 1.6 0.015 0.21 1.1 5.4 12,000 120,000 Hexane 570 2,600 Trichloroethylene (TCE) 0.91 6.40 0.01 22 110 0.1 5,000 45000 120 PAHs Benzo[a]pyrene ORGANICS Benzene Formaldehyde Perchloroethylene/ tetrachloroethylene (PCE) Toluene 0.07 NOTES TO TABLE: o The values are based on protection of human health. Values for ecological objectives are likely to be different. o The values are based on the assumption of one dominant contaminant. Where multiple contaminants exist, it may be appropriate to adjust individual component screening values downwards to allow for possible synergistic or cumulative effects. o High precision in values is not appropriate: these values are generally rounded to two significant figures. GAHP Guidance Notes provide information on international good practices and regulations in remediation. They are prepared to assist GAHP members in dealing with practical problems of remediation of polluted sites and are intended to assist readers to identify key points that should be taken into account in reviewing or approving any proposal. Guidance notes reflect the views of individual GAHP specialists and of invited outside experts and do not necessarily represent the views of any specific government or agency. Additional background and material may be found on the GAPH website. 8