Steven T. Shipman Curriculum Vitae Education University of California, Berkeley Ph.D. in Physical Chemistry, December 2005. Berkeley, CA Rice University B.A. in Chemistry and Biochemistry, May 1999. Houston, TX Professional Experience Associate Professor of Physical Chemistry 2013–present Assistant Professor of Physical Chemistry 2008–2013 Division of Natural Sciences, New College of Florida. Research interests: Microwave spectroscopy as a probe of chemical dynamics Postdoctoral Research Associate 2006–2008 Department of Chemistry, University of Virginia. Principal Investigator: Prof. Brooks H. Pate Ultrafast vibrational energy flow in gas and solution phases Development and applications of chirped-pulse microwave spectroscopy Graduate Research Assistant Department of Chemistry, UC Berkeley. Principal Investigator: Prof. Charles B. Harris Ultrafast electron dynamics in thin molecular films 2002–2005 Graduate Research Assistant Department of Chemistry, UC-Berkeley. Principal Investigator: Prof. Herbert L. Strauss Infrared spectral holeburning in hydrogen-bonded molecular crystals 1999-2002 Teaching Experience Courses Taught at New College of Florida • General Chemistry I • General Chemistry II • Compressed Chemistry I • Compressed Chemistry II • Environmental Chemistry • Physical Chemistry I - Quantum Mechanics • Physical Chemistry II - Thermodynamics of Biomolecular Systems • Physical Chemistry Lab Selected Tutorials Sponsored at New College of Florida • Astrochemistry and Microwave Spectroscopy • Computational Chemistry 1 • Genetic Algorithms with Applications to Spectroscopy • Gender in Science • History of Chemistry • Physical Properties of Carbon Nanotubes • Practical Applications of Microcontrollers • Spatial Reasoning Skills • Statistical Mechanics Selected ISPs Sponsored at New College of Florida • Astrobiology: The Evolution and Architecture of Life • Chemiluminescence in Glowsticks • Circuits and Microprocessors in Fencing • Computational Chemistry of Organic Reations • Landfills and Soil Chemistry • Minimizing Gen Chem Lab Waste • Simple Sugars in Interstellar Space • The Chemistry of Art Conservation • The Chemistry of Photography • Using Arduino Technology to Detect and Respond to Dolphins Senior Theses Supervised at New College of Florida Lauren Bernier (2014) “Design and evaluation of a chirped-pulse millimeter-wave Fourier transform spectrometer operating from 110 to 170 GHz” Erin Kent (2014) “Methods development for spectral simplification of room-temperature rotational spectra” Morgan McCabe (2014) “Chirped-pulse microwave spectroscopy of small molecules” Suzanne Setti (2014) “Selective extraction of the herbicide prometon using magnetic molecularly imprinted nanoparticles” Kenneth Wang (2014) “Enzymatic catalysis in beta-lactamases: Protonation states of the catalytic triad” Brittany Gordon (2013) “Waveguide chirped-pulse Fourier transform microwave spectroscopy of small alkylthiols” Christian Metzger (2013) “Rotational spectroscopy of trans-isopropylamine and 2-(methoxy-13 C)-ethanol” Maria Phillips (2013) “Pruning interstellar space: The rotational spectra of small organic molecules” Benjaminm Rooks (2013) “Theoretical kinetics calculations on reactions in the interstellar medium” Noah Anderson (2012) “Guerrilla clusters for science: The application of genetic algorithms to spectroscopy” 2 Ian Finneran (2011) “Microwave spectroscopy of small molecules with methyl rotors” Kaitlin Lovering (2011) “Mn-doped (CdS)ZnS quantum dots as sensitizers for sensitized solar cells” Benjamin Reinhold (2010) “Microwave spectroscopy of mono-substituted benzenes at room temperature” Publications (Asterisks denote undergraduate authors.) Nguyen, H.V.L.; Kleiner, I.; Shipman, S.T.; Mae, Y.; Hirose, K.; Hatanaka, S.; Kobayashi, K. “Extension of the Measurement, Assignment, and Fit of the Rotational Spectrum of the Two-Top Molecule Methyl Acetate”, J. Mol. Spec., 2014, 299, 17. Kolesniková, L.; Tercero, B.; Cernicharo, J.; Alonso, J.L.; Daly, A.M.; Gordon, B.P.*; Shipman, S.T.; “Spectroscopic characterization and detection of Ethyl Mercaptan in Orion”, Astrophys. J. Lett., 2014,784, L7. Kroll, J.A.*; Shipman, S.T.; Widicus Weaver, S.L. “The rotational spectrum of methyl ethyl ketone in its ground vibrational state”, J. Mol. Spec., 2014,295, 52. Finneran, I.A.*; Shipman, S.T.; Widicus Weaver, S.L. “Rotational spectroscopy of 2-methylfuran from 8.7 to 960 GHz”, J. Mol. Spec., 2012, 280, 27. Reinhold, B.*; Finneran, I.A.*; Shipman, S.T. “Room temperature chirped-pulse Fourier transform microwave spectroscopy of anisole”, J. Mol. Spec., 2011, 270, 89. Neill, J.L.; Shipman, S.T.; Alvarez-Valtierra, L.; Lesarri, A.; Kisiel, Z.; Pate, B.H. “Rotational spectroscopy of iodobenzene and iodobenzene-neon with a direct digital 2-8 GHz chirped-pulse Fourier transform microwave spectrometer”, J. Mol. Spec., 2011, 269, 21. Shipman, S.T. and Pate, B.H. “New Techniques in Microwave Spectroscopy” in M. Quack & F. Merkt (Eds.), Handbook of High-Resolution Spectroscopy (Wiley), 2011, 801. Shipman, S.T.; Neill, J.L.; Suenram, R.D.; Muckle, M.T.; Pate, B.H. “Structure Determination of Strawberry Aldehyde by Broadband Microwave Spectroscopy: Conformational Stabilization by Dispersive Interactions”, J. Phys. Chem. Lett., 2011, 2, 443. Lesarri, A.; Shipman, S.T.; Neill, J.L.; Brown, G.G.; Suenram, R.D.; Kang, L.; Caminati, W.; Pate, B.H. “Interplay of phenol and isopropyl isomerism in propofol from broadband chirped-pulse microwave spectroscopy,” J. Am. Chem. Soc., 2010, 132, 13417. Kisiel, Z.; Dorosh, O.; Maeda, A.; Medvedev, I.R.; De Lucia, F.C.; Herbst, E.; Drouin, B.J.; Pearson, J.C.; Shipman, S.T. “Determination of precise relative energies of conformers of n-propanol by rotational spectroscopy,” Phys. Chem. Chem. Phys., 2010, 12, 8329. Kisiel, Z.; Krasnicki, A.; Pszczolkowski, L.; Shipman, S.T.; Alvarez-Valtierra, L.; Pate, B.H. “Assignment and analysis of the rotational spectrum of bromoform enabled by broadband FTMW spectroscopy” J. Mol. Spec., 2009, 257, 177. 3 Suenram, R.D.; Pate, B.H.; Lessarri, A.; Neill, J.L.; Shipman, S.; Holmes, R.A.*; Leyden, M.C.*; Craig, N.C. “Semiexperimental equilibrium structure for the C6 backbone of cis-1,3,5-hexatriene; Structural evidence for greater π-electron delocalization with increasing chain length in polyenes” J. Phys. Chem. A, 2009, 113, 1864. Brown, G.G.; Dian, B.C.; Douglass, K.O.; Geyer, S.M.*; Shipman, S.T. and Pate, B.H. “A broadband Fourier transform microwave spectrometer based on chirped pulse excitation” Rev. Sci. Inst., 2008, 79, 053103. Yang, A.; Shipman, S.T.; Garrett-Roe, S.; Johns, J.; Strader, M.L.; Szymanski, P.; Muller, E.; Harris, C. “Two-photon photoemission of ultrathin film PTCDA morphologies on Ag(111)” J. Phys. Chem. C, 2008, 112, 2506. Strader, M.L.; Garrett-Roe, S.; Szymanski, P.; Shipman, S.T.; Johns, J.E.; Yang, A.; Muller, E.; Harris, C.B. “The ultrafast dynamics of image potential state electrons at the dimethylsulfoxide/Ag(111) interface” J. Phys. Chem. C, 2008, 112, 6880. Shipman, S.T.; Douglass, P.C.; Yoo, H.S.; Hinkle, C.E.*; Mierzejewski, E.L.*; and Pate, B.H. “Vibrational dynamics of carboxylic acid dimers in gas and dilute solution” Phys. Chem. Chem. Phys., 2007, 9, 4572. Shipman, S.T.; Garrett-Roe, S.; Szymanski, P.; Yang, A.; Strader, M.L.; and Harris, C.B. “Determination of band curvatures by angle-resolved two-photon photoemission in thin films of C60 on Ag(111)” J. Phys. Chem. B, 2006, 110, 10002. Garrett-Roe, S.; Shipman, S.T.; Szymanski, P.; Strader, M.L.; Yang, A.; and Harris, C.B. “Ultrafast electron dynamics at metal interfaces: Intraband relaxation of image state electrons as friction” J. Phys. Chem. B, 2005, 109, 20370. Published as Steven T. Robertson Robertson, S.T. and Strauss, H.L. “Assignment of invisible combination bands in ammonium zinc Tutton salt by infrared hole burning” J. Phys. Chem. A 2003, 107, 4226. Prilliman, S.G.; Kavanagh, A.M.; Scher, E.C.; Robertson, S.T.; Hwang, K.S.; and Colvin, V.L. “An in-situ hot stage for temperature-dependent tapping-mode(TM) atomic force microscopy” Rev. Sci. Inst. 1998, 69, 3245. Oral Presentations Bernier, L.* and Shipman, S. “Chirped-pulse spectroscopy from 110 - 170 GHz with real-time digitizers” Southeast Regional Meeting of the American Chemical Society, Atlanta, GA, November 2013. Shipman, S.T. “Chirped-Pulse Fourier Transform Microwave Spectroscopy with Real-Time Digitizers” From Stars to Life, Gainesville, FL, April 2013. Shipman, S.T. “Techniques for Automated Analysis of Complex Spectra” Pittcon 2013, Philadelphia, PA, March 2013. Shipman, S.T.; Finneran, I.A.*; Widicus Weaver, S.L.; van Wijngaarden, J. “Rotationally Resolved Spectra of 2-methylfuran from the cm-wave to the far IR” 67th International Symposium on Molecular Spectroscopy, Columbus, OH, June 2012. 4 Shipman, S.T.; Anderson, N.H.*; Finneran, I.A.* “Dealing with Complexity in Rotational Spectroscopy” Florida Annual Meeting and Exposition 2012, Innisbrook, FL, May 2012. Shipman, S.T. “Dealing with Complexity in Rotational Spectroscopy” Department of Chemistry Seminar, Amherst College, Amherst, MA, February 24, 2012. Shipman, S.T.; Kent, E.B.*; McCabe, M.N.*; Phillips, M.A.*; Gordon, B.P.* “Waveguide Chirped-Pulse Fourier Transform Microwave (CP-FTMW) Spectrum of Allyl Chloride” 66th International Symposium on Molecular Spectroscopy, Columbus, OH, June 2011. Shipman, S.T.; Finneran, I.A.* “Waveguide Chirped-Pulse Fourier Transform Microwave (CP-FTMW) Spectrum of Ortho-Fluorotoluene” 66th International Symposium on Molecular Spectroscopy, Columbus, OH, June 2011. Shipman, S.T.; Anderson, N.A.*; Finneran, I.A.*; McDonald, P.T. “Automating spectral assignment of room-temperature microwave spectra” Florida Annual Meeting and Exposition 2011, Innisbrook, FL, May 2011. Shipman, S.T. “Chirped-Pulse Fourier Transform Microwave (CP-FTMW) Spectroscopy from 2 to 298 K” Department of Chemistry Seminar, University of Florida, Gainesville, FL, October 12, 2010. Shipman, S.T.; Reinhold, B.*; Kriegel, B.M.*; Finneran, I.A.*; Lang, S.L.* “Roomtemperature chirped-pulse Fourier transform microwave spectroscopy: Rotational spectra of molecules in excited vibrational states” American Chemical Society National Fall Meeting, Boston, MA, August 2010. Shipman, S.T.; Reinhold, B.*; Kriegel, B.M.*; Finneran, I.A.* “Chirped-pulse Fourier transform microwave spectroscopy: Rotational spectra of molecules in excited vibrational states” Florida Annual Meeting and Exposition 2010, Innisbrook, FL, May 2010. Shipman, S.T. “Chirped-Pulse Fourier Transform Microwave (CP-FTMW) Spectroscopy from 2 to 298 K” Department of Chemistry Seminar, University of Manitoba, Winnipeg, Manitoba, Canada, October 16, 2009. Shipman, S.T.; Neill, J.L.; Muckle, M.T; Suenram, R.D.; Pate, B.H. “Chirped pulse-Fourier transform microwave spectroscopy of ethyl 3-methyl-3-phenylglycidate (strawberry aldehde)” 64th International Symposium on Molecular Spectroscopy, Columbus, OH, June 2009. Shipman, S.T.; Nugent, K.M.*; Raud, R.* “Chirped-pulse Fourier transform microwave spectroscopy: Variable temperature and pressure rotational spectroscopy of methanol” Florida Annual Meeting and Exposition 2009, Kissimmee, FL, May 2009. Shipman, S.T.; Alvarez-Valtierra, L.; Neill, J.L.; Pate, B.H.; Lesarri, A.; and Kisiel, Z. “Design and performance of a direct digital chirped-pulse Fourier transform microwave (CP-FTMW) spectrometer operating in the 2 - 8 GHz frequency range” 63rd International Symposium on Molecular Spectroscopy, Columbus, OH, June 2008. Shipman, S.T.; Kroncke, B.; Pate, B.H.; Groner, P. “Waveguide chirped-pulse Fourier transform microwave spectroscopy” 63rd International Symposium on Molecular Spectroscopy, Columbus, OH, June 2008. 5 Shipman, S.T.; Brown, G.G.; and Pate, B.H. “Vibrational anharmonic calculations in electronic structure packages for applications in intramolecular dynamics” 62nd International Symposium on Molecular Spectroscopy, Columbus, OH, June 2007. Shipman, S.T. and Pate, B.H. “Flow of vibrational energy in polyatomic molecules: Using acetylenic anharmonic couplings to follow vibrational dynamics” 62nd International Symposium on Molecular Spectroscopy, Columbus, OH, June 2007. Shipman, S.T.; Douglass, P.C.; Mierzejewski, E.L*; Dian, B.C.; Hinkle, C.E.*; Yoo, H.S.; and Pate, B.H. “Vibrational dynamics of cyclic acid dimers: trifluoroacetic acid in gas and dilute solutions” 61st International Symposium on Molecular Spectroscopy, Columbus, OH, June 2006. Poster Sessions Shipman, S.T.; Douglass, P.C.; Mierzejewski, E.L.*; and Pate, B.H. “IVR and VER at high state densities: Ultrafast transient absorption spectroscopy of vibrational overtones” American Chemical Society National Meeting, San Francisco, CA, September 10, 2006. Shipman, S.T.; Douglass, P.C.; Mierzejewski, E.L.*; and Pate, B.H. “Ultrafast hydrogen bond disruption of acid dimers” American Chemical Society National Meeting, San Francisco, CA, September 10, 2006. Shipman, S.T.; Douglass, P.C.; Mierzejewski, E.L.*; and Pate, B.H. “Vibrational dynamics of cyclic acid dimers: Trifluoroacetic acid and formic acid in gas and dilute solutions” Gordon Research Conference on Vibrational Spectroscopy, Portland, ME, July 2, 2006. Shipman, S.T.; Szymanski, P.; Garrett-Roe, S.; Yang, A.; Strader, M.L.; and Harris, C.B. “Femtosecond two-photon photoemission studies of C60 /Ag(111)” American Chemical Society National Meeting, San Diego, CA, March 15, 2005. Funding “Next Generation Spectrometers for Rapid Analysis of Complex Mixtures” Office of Naval Research, $260,032, December 2012 - December 2013. “RUI: Pruning Interstellar Weeds with Room Temperature Chirped-Pulse Fourier Transform Microwave (CP-FTMW) Spectroscopy” National Science Foundation, $93,000, July 2011 - July 2014. “MRI-R2: Development of a Cyber-enabled Third Generation Chirped-Pulse Fourier Transform Microwave (CP-FTMW) Spectrometer” National Science Foundation, submitted with B.H. Pate (lead PI) and D.W. Pratt (co-PI), $1,345,087, January 2010 - January 2013. “Room-Temperature Chirped-Pulse Fourier Transform Microwave Spectroscopy for the Study of Radical Reaction Dynamics” American Chemical Society Petroleum Research Fund - Undergraduate New Investigator (ACS-PRF-UNI) Award, $50,000, May 2009 - August 2011. “Multi-Dimensional Rotational Spectroscopy of Molecules at Room Temperature” Research Corporation Cottrell College Science Award, $46,546, May 2009 - August 2011. Service Committees at New College of Florida 6 • Institutional Review Board (IRB) (Fall 2009 - Present) • Gender Studies Steering Committee (Fall 2012 - Present) • Natural Sciences Budget Committee (Fall 2012 - Present) • Search committee, Visiting Assistant Professor in Computational Science (Fall 2013 - Spring 2014) • Search committee, Assistant Professor in Bioinformatics (Fall 2012) • Search committee, Assistant Professor in Computational Science (Fall 2012) • Search committee, Visiting Assistant Professor in Computer Science (Fall 2011 - Spring 2012) • Search committee, Chemistry and Biology Lab Technicians (Fall 2009) • Search committee, Visiting Assistant Professor in Physics (Spring 2009) External Service Session chair, 66th and 69th annual meetings of the International Symposium on Molecular Spectroscopy (2011, 2014) Member of organizing committee for workshop, “Molecular Spectroscopy in the Era of Far-IR Astronomy,” October 2012 at Emory University Grant Reviewer • National Science Foundation • Department of Energy • American Chemical Society Petroleum Research Fund • Research Corporation for Science Advancement Peer Reviewer • Chemical Physics • IEEE Transactions on Microwave Theory and Techniques • Journal of Molecular Spectroscopy • Journal of Physical Chemistry A • Journal of Physical Chemistry Letters • Physical Review Letters • Physical Review B 7