University of Wollongong Research Online University of Wollongong Thesis Collection University of Wollongong Thesis Collections 2013 Second generation high-temperature superconducting solenoid coils and energy storage Hanan Tahir Baiej University of Wollongong Recommended Citation Baiej, Hanan Tahir, Second generation high-temperature superconducting solenoid coils and energy storage, Master of Science thesis, Institute for Superconducting and Electronic Materials, University of Wollongong, 2013. http://ro.uow.edu.au/theses/3867 Research Online is the open access institutional repository for the University of Wollongong. For further information contact the UOW Library: research-pubs@uow.edu.au Institute for Superconducting and Electronic Materials Faculty of Engineering Second Generation High-Temperature Superconducting Solenoid Coils and Energy Storage Hanan Tahir Bashir Baiej “This thesis is presented as part of the requirements for the award of the Degree of Master of Science Of the University of Wollongong January, 2013 1 Candidate’s Certificate This is to certify that the work presented in this thesis is original and that it was carried out by the candidate in the Institute for Superconducting and Electronic Materials at the University of Wollongong, NSW, Australia, and has not been submitted elsewhere for any award. Where other sources of information have been used, they have been acknowledged. Hanan Baiej 2 Acknowledgements I am gratefull to all members of the Institute for Superconducting and Electronic Materials, as well as all members of the School of Physics. First and foremost I offer my sincerest gratitude to my supervisor, Prof Alexey Pan, who has supported me throughout my thesis with his patience and knowledge. I attribute the level of my Master’s degree to his encouragement and effort and without him this thesis, too, would not have been completed or written. Finally, I wish to thank my husband, ALI NURI for his encouragement, patience and support, as well as my mother, my brothers, and my sisters, who have always supported me throughout all my studies at university and encouraged me with their best wishes, I also thank my daughter for bringing me a great deal of happiness during this work. 3 Table of Contents Candidate’s certificate………………………………………………………………2 Acknowledgements………………………………………………………………….3 Table of contents…………………………………………………………………….4 Abstract ……………………………………………………………………………..6 List of figures………………………………………………………………………..8 List of tables………………………………………………………………………..10 Chapter 1. Introduction…………………………………………………………….11 1.1 Background…………………………………………………………….11 1.2 Thesis outline…………………………………………………………..15 Chapter 2. Superconductivity, electromagnetism………………………………….18 2.1 Introduction……………………………………………………………18 2.2 Meissner effect………………………………………………………...19 2.3 Vortex lattice or Abrikosov lattice…………………………………….23 2.4 Pinning properties……………………………………………………. 28 Critical currents in high temperature superconductors……………….30 2.5 Applications of superconductor (SCs) and future developments……..31 Chapter 3. Superconducting magnetic energy storage…………………………….34 3.1 Introduction……………………………………………………………34 3.2 Magnets………………………………………………………………..34 Superconducting magnets………………………………………………35 Superconducting coil……………………………………………………35 Power conditioning system (PCS)………………………………………36 4 Refrigerator …………………………………………………………………….36 Charging system…………………………………………………………37 3.3 The modeling of an HTS pancake coil…………………………………39 3.4 Thermal stability in superconducting materials………………………...43 3.5 Applications of SMES………………………………………………….45 3.6 Ongoing SMES development…………………………………………..50 3.7 Comparison of SMES and batteries……………………………………53 3.8 Summary………………………………………………………………..58 Chapter 4. Optimum design of superconducting solenoid coil for a SMES unit….59 4.1 Introduction…………………………………………………………….59 4.2 Calculation results………………………………………………………63 4.3 Field-dependent current performances………………………………….69 4.4 Maximum energy storage……………………………………………….70 Optimization of inner diameter of coil………………………………….76 Optimization of outer diameter of coil………………………………….78 Parameters of one desk lamp……………………………………………..80 4.5 Summary………………………………………………………………..85 Chapter 5. Conclusion……………………………………………………………...87 REFERENCE……………………………………………………………………...89 5 Abstract One of the most promising applications of superconductors is in Superconducting Magnetic Energy Storage (SMES) systems, which are becoming the enabling engines for improving the capacity, efficiency, and reliability of electrical systems. The use of superconductivity reduces the loss of energy and makes magnetic energy storage systems more powerful. Superconducting magnetic energy storage systems store energy in a superconducting coil in the form of a magnetic field. The magnetic field created by the flow a direct current (DC) through the coil. Superconducting magnetic energy storage systems have many advantages compared to other energy storage systems: high cyclic efficiency, fast response time, deep discharge and recharge ability, and a good balance between power density and energy density. Based on these advantages, superconducting magnetic energy systems will play an indispensable role in improving power qualities integration renewable energy sources and energizing transportation systems. This thesis investigates the application of superconducting pancake coils that are wound using second-generation (2G) HTS materials in power system and provides an analysis of superconducting magnetic energy storage system for potential development and implementation in a range of applications. Specifically, it designs and calculates the energy storage in an SMES system using HTS thin films. Second-generation, high temperature superconducting coils have drawn great attention in recent years, owing to the highly developed fabrication technology for 2G, HTS, and coated conductors. Their potential operation at relatively high temperature makes them good candidates for power applications. 6 With the growing availability of “YBCO-based” second-generation high-temperature superconductor (2G HTS), the fabrication technologies for 2G HTS wires have been progressing dramatically, with remarkable advancements in the critical current, wire length, magnetic-field performance, and production throughput and cost. This study will highlight recent developments in the fabrication of 2G HTS wire and prototype devices using YBCO-based wire with high field critical currents, as well as related magnet technology developments, to design a small closed system of superconducting HTS thin film solenoid coil, through selection of the optimization parameters for this coil to store large amounts of magnetic energy, and then to link this system with one of renewable energy sources. 7 List of Figures Figure Description Page Figure 2.1 The Meissner effect 20 Figure 2.2 Type I and II superconductor behavior 22 Figure 2.3 Magnetic field and current density around the vortex 25 Figure 2.4 Schematic E-J characteristic for liner flux flow 28 Figure 2.5 Future development of superconductors 32 Figure 3.1 Magnetic field current density in SMES coil 41 Figure 3.2 SMES coil design 42 Figure 3.3 SMES unit applicable for damping system oscillations 46 Figure 3.4 Types of SMES applications for power systems 48 Figure 3.5 Components of existing SMES system 52 Figure 4.1 Solenoid model for analysis 61 Figure 4.2 Calculation inductance of HTS solenoid versus size ration α and β 68 Figure 4.3 Location of maximum flux density Bm in solenoid 70 Figure 4.4 Calculated maximum energy storage of solenoid versus size ration, α 8 75 Figure 4.5 Calculated energy storage versus height H when inner diameter Di and critical current Ic are constant Figure 4.6 78 Calculated energy storage versus height H when inner diameter Do and critical current Ic are constant 80 Figure 4.7 Model of coil using to stored energy for one lamp 82 Figure 4.8 Relationship between β and energy storage 84 9 List of Tables Table Description Page Table 3.1 Advantage and disadvantage of SMES and BES 57 Table 4.1 Characteristics of YBCO tapes 65 Table 4.2 Specification of the YBCO coil for the HTS SMES magnet 65 Table 4.3 THS solenoid coil design 81 10 Chapter 1. Introduction: 1.1 Background Superconductivity is a common property seen in materials that are commonly used in magnetic field; at low temperatures many metals, alloys, and compounds are found to show no resistance to flow of an electric current and to exclude magnetic flux completely, when a superconductor is cooled below its critical temperature. This property of superconductivity is in fact quantum mechanical, and it is highly pertinent for current and future power system applications. Therefore, it is important that superconducting materials play a greater role in the magnetic domain. One of the most promising applications of superconductors is in Superconducting Magnetic Energy Storage (SMES) systems, which are becoming the enabling engines for improving the capacity, efficiency, and reliability of electrical systems. The use of superconductivity reduces the loss of energy and makes magnetic energy storage systems more powerful. Because no conversion of energy to other forms is involved in the storing process, their efficiency can be very high. Moreover, SMES uses clean and recyclable, non-flammable liquid nitrogen as a cryogen (or even cryogen-free technologies) to maintain its operating temperature; thus, SMES has a semi-permanent lifetime and does not cause environmental problems (Tixador et al. 2005). Superconducting magnetic energy storage systems store energy in a superconducting coil in the form of a magnetic field. The magnetic field is created by the flow of a direct 11 current (DC) through the coil. Over the past 30 years, SMES technology has become one of the most active research areas in applied superconductivity, especially since the High Temperature Superconducting (HTS) materials were discovered in 1986 (Ju Wen et al. 2007). Since this time, research on SMES has been further promoted, and the technology has progressed significantly. According to Wen et al. (2007), SMES technology outperforms other energy storage devices and methods because: the current density of an SMES coil is about 10 to 100 times larger than that of a common coil; it has virtually no resistive losses; the efficiency of SMES can reach as high as 95 %. It is able to supply high quantities of energy in time intervals of milliseconds; it can be easily controlled with well-developed power electronic technology; and it can enhance power system stability and improve the power quality through active and reactive power compensation and a good balance between power density and energy density. Energy storage is used widely in industry to supply energy where the storage of energy reduces the time and rate mismatch between energy supply and energy demand. Energy can be generated and stored when the demand is low, and this stored energy can be used when there is a demand for it. This helps reduce pollution and the cost of production. Based on these advantages, SMES systems will play an indispensable role in improving power quality and the integration of renewable energy sources with the energizing of transportation systems (Dincer et al). Previously, the magnet for a SMES system was produced from a low temperature superconducting (LTS) material such as NbTi or Nb3Sn; however, more recently, high temperature superconducting magnets have been adopted. This is because the HTS 12 superconductors, such as YBa2Cu3O7-x (YBCO) thin film, can show excellent performance under high magnetic field compared with that of LTS, and improves the stability of magnets (Park et al. 2007). This thesis investigates the application of superconducting pancake coils that are wound using second-generation (2G) HTS materials in power systems and provides an analysis of superconducting magnetic energy storage systems for potential development and implementation in a range of applications. Specifically, it designs and calculates the energy storage in an SMES system using HTS thin films. Second-generation, high temperature superconducting coils have drawn great attention in recent years, owing to the highly developed fabrication technology for 2G HTS, and coated conductors. Their potential operation at relatively high temperature makes them good candidates for power applications. Since long-length second-generation high temperature (2G HTS) superconductors have become commercially available, it is now possible to wind SMES coils from 2G HTS conductors. Two major advantages of the 2G technology over the first generation 1G HTS wires are the potential for lower cost and the ability to tailor wire dimensions for specific applications (Weijia Yuan et al. 2010). Since a superconductor is much more expensive than normal conductors, it is important that the energy stored in a superconducting coil is maximized; the most suitable commercially available high-temperature superconductor (HTS) is YBCO tape. The high critical temperature superconductors enable operation at higher temperature, making the cryocooling easier, decreasing the cryogenic investment cost, and improving the coil stability. For a thin tape conductor, a solenoid is a relatively straightforward coil to 13 construct, and another significant advantage of the coated conductors such as YBCO tape is their possible lower cost. The decrease in the conductor cost is associated with the reduced cryogenic cost due to the higher operation temperature, which is fundamental for the SMES to be widely commercialized. Optimization for superconducting solenoid designs has been studied for decades (Hoon et al. 2005). With the growing availability of “YBCO-based” second-generation high-temperature superconductors (2G HTS), the fabrication technologies for 2G HTS wires have been progressing dramatically, with remarkable advancements in the critical current, wire length, magnetic-field performance, and production throughput and costs. This study will highlight recent developments in the fabrication of 2G HTS wire and prototype devices using YBCO-based wires with high field critical currents as well as related magnet technology developments. The HTS thin films used in this study are just one type of the many possible high temperature materials that could be used. YBCO coated conductors (CC) multifilamentary wires have been proposed for superconducting power apparatus such as generators, motors, transformers, and magnets. The nature of thin films makes the design both difficult and expensive, as it is hard to make long CC tape with high and uniform critical current density using the present processing techniques, so joint techniques are required to design double pancake coils for superconducting magnetic energy storage (SMES). They make it possible to not only reduce power transmission losses significantly and improve power system stability, but also to alleviate global environmental problems and allow more efficient use of energy resources (So Noguchi et al. 2003). 14 The aim of this research is to design a small closed system of superconducting HTS thin film solenoid coil, through selection of the optimization parameters for this coil to store large amounts of magnetic energy, and then to link this system with one of renewable energy sources such as the wind or sun. It is necessary to calculate the amount of energy that can be stored for use in the absence of an energy source, for example during the night, and whether the amount of energy stored is enough to supply or support one lamp, house, city, etc. In this study, the necessary energy to be stored is calculated, and this energy is used to supply or support one desk lamp to work for about 10 hours. This will be achieved by using the Origin software program and the energy storage equation E = (½) LI2, where L is the equivalent self-inductance of the superconductor system, and I is that current flows through the winding, the critical current which requires the calculation of inductance according to length of the tape, the coil parameters, and the size and nature of cryocooler, as well as the calculation of the current according to the width and thickness of the wire, and the critical current density of the wire. In the future, it is supposed that these applications will be able to provide energy when necessary. 1.2Thesis Outline This thesis is organized as follows: Chapter 2 discusses superconductivity and electromagnetism. Section 2.2 provides more detail on the properties of superconductors in magnetic field, such as zero resistance and the Meissner effect, the latter of which is one of the most important properties of superconductors. Sections 2.3 and 2.4 describe and explain the vortex lattice and pinning properties in type II superconductors, and also describe the critical currents in high temperature superconductors. Section 2.5 discusses 15 applications of superconductivity, such as power system applications and possible future developments. Chapter 3 explains the superconducting magnetic energy storage system and other commonly used materials in real time applications. Section 3.2 introduces the properties and benefits of using superconducting magnets, then defines the superconducting magnetic energy storage system, and describes the superconducting coil, power conditioning systems and refrigerators used in superconducting magnets. It also discusses thin film, coated conductors wire usage for energy storage and gives more detail on the properties and application of YBCO, NbTi and MgB2. Section 3.3 discusses the modeling of the HTS pancake coil. Section 3.4 explains how thermal stability in superconducting materials is important for their intended performance in magnetic energy storage. Sections 3.5 and 3.6 describe the applications of SMES that have wide applicability in the field of electrical power supply devices, and ongoing SMES developments that can overcome the existing design constraints and enhance the effectiveness and efficiency of the system. Section 3.7 presents a broader overview on the working of batteries. The energy storage systems that are commonly used for various applications are further discussed, out of which SMES and batteries are chosen for comparison. The results are presented in Chapter 4. This study is focused on the relationship between the geometrical parameters and the magnetic field, and the design optimization for a superconducting solenoid coil made of HTS tape for energy storage purposes is discussed. Section 4.2 describes the design of a coil made for maximum stored energy and explains the factors that affect this energy. Section 4.3 shows the calculation results 16 and the parameters for the design of a solenoid coil made of HTS tape. Section 4.4 gives more detail on the parameters that need to be considered while deciding the features of the optimal design. Section 4.5 presents the results and show the relation between maximum energy storage and every parameter used to calculate this energy whether these parameters are constant or variable. Chapter 5 contains the conclusion of this thesis. 17 Chapter2. Superconductivity, electromagnetism: 2.1 Introduction In this Chapter, superconductivity will be discussed in relation to the concepts of superconducting magnets, critical temperature, heat capacity, critical magnetic field, applications, and superconducting materials. It is evident that superconductivity depends on the value of the critical temperature (đťc); this factor is one of the most important in the development and deployment of applications. A perfect superconductor is a material that exhibits two characteristic properties, namely zero electrical resistance and perfect diamagnetism, when it is cooled below a particular temperature Tc, called the critical temperature. Below the superconducting transition temperature, the resistivity of a material is exactly zero. At zero resistance, the material conducts current perfectly. This is incomprehensible because the flaws and vibrations of the atoms should cause resistance in the material when the electrons flow through it. In a superconductor, however, the electrical resistance is equal to zero although the flaws and vibrations still exist (W. Buckel. 1999). Below Tc, superconductors exhibit perfect electrical conductivity and also perfect or quite pronounced diamagnetism. Perfect diamagnetism, the second characteristic property, means that a superconducting material does not permit an externally applied magnetic field to penetrate into its interior. When the temperature is reduced to below the critical temperature, the superconductor will push the field out of itself. It does this by creating surface currents which produces a magnetic field exactly countering the external field. The superconductor becomes perfectly diamagnetic, canceling all magnetic flux in its interior. This perfect diamagnetic property 18 is perhaps the most fundamental macroscopic property of a superconductor. Flux exclusion is due to what is referred to as the Meissner effect (Poole. 2007). 2.2 Meissner effect Walter Meissner and Robert Ochsenfeld discovered a magnetic phenomenon that showed that superconductors are not just perfect conductors. Figure 2.1 illustrates a thought experiment that highlights this difference. Imagine that both an ideal conductor and a superconductor are above their critical temperature. That is, they both are in a normal conducting state and have electrical resistance. A magnetic field đľa is then applied. The threshold or critical value of the applied magnetic field for the destruction of superconductivity is denoted by Hc(T) and is a function of the temperature . At the critical temperature the critical field is zero: Hc(Tc) = 0. This results in the field penetrating both materials. Both samples are then cooled so that the ideal conductor now has zero resistance. It is found that the superconductor expels the magnetic field from inside it, while the ideal conductor maintains its interior field. Note that energy is needed by the superconductor to expel the magnetic field. This energy comes from the exothermic superconducting transition (Atznony et al. 1995). 19 (a) B = 0 (b) B = Bapp, T > Tc (c) B =Bapp, T < Tc Figure 2.1: The Meissner effect (Joe Khachan). Part (b) of the figure above, shows that cooling a superconductor to above its critical temperature in a uniform magnetic field leads to a situation where the uniform field is maintained within the material. If the applied field is then removed, the field within the conductor remains uniform, and the continuity of magnetic field lines means there is a field in the region around the perfect conductor. Whether a material is cooled below its superconducting critical temperature in zero fields, as in Fig. 2.1 (c), the magnetic field within a superconducting material is always zero. The magnetic field is expelled from the superconductor. This is achieved spontaneously by producing currents on the surface of the superconductor. The direction of the currents is such as to create a magnetic field that exactly cancels the applied field in the superconductor. In its normal state, the conductivity of this material is inversely proportional to its resistivity; however, when the 20 temperature of the material is lowered, its resistivity also decreased, and it becomes zero at the superconducting transition. Thus, zero resistance and zero magnetic field are the two key characteristics of superconductivity (Kittel, 8th ed. 2005). In general, the superconductors are classified into two types, Type I and Type II, depending on various criteria. Type I superconductors have low critical field, the current only flows through the surface, and these superconductors lose their superconductivity very easily when placed in the external magnetic field compared to superconductors, as shown in Figure 2.2 . type II This is largely due to the difference in superconducting materials. For example, type I superconductors tend to be made of Tin, or Aluminum, which are sometimes called “soft” superconductors, and the values of Hc are always too low for type I superconductors to have application in coils for superconducting magnets. Type II, on the other hand, tend to consist of materials such as Niobium Titanium and Yttrium Barium Copper Oxide, which have much higher critical fields and start to lose their superconductivity at a lower critical magnetic field, while they completely lose their superconductivity at the upper critical magnetic field. Type II superconductors are used for strong field superconducting magnets, as shown in Figure 2.2. Increasing the applied field from zero results in two critical fields, đľc1and đľc2; at đľc1the applied field begins to partially penetrate the interior of the superconductor. The superconductivity is maintained at this point, however. The superconductivity vanishes above the second, much higher, critical field, đľđ2. For applied field between đľđ1and đľđ2, the applied field is able to partially penetrate the superconductor, so the Meissner effect is incomplete, allowing the superconductor to tolerate very high magnetic fields. In the region between đľ and đľ the superconductor is threaded by flux lines and is said to be 21 in the vortex state. Type II superconductors are the most technologically useful because the second critical field can be quite high, enabling high field electromagnets to be made out of superconducting wire. This makes them useful for applications requiring high magnetic field, such as Magnetic Resonance Imaging (MRI) machines (Yi et al. 2005). Figure 2.2: Type I and II superconductor behavior (Joe Khachan). Since the discovery of superconductivity, there have been a number of efforts devoted to establishing new applications for it, as well as explaining it theoretically. The discovery of the Meissner effect led to the phenomenological theory of superconductivity of Fritz and Heinz London in 1935. This theory explained resistance-less transport and the Meissner effect, and allowed the first theoretical predictions to be made for superconductivity. However, this theory only explained experimental observations. It did not allow the microscopic origins of the superconducting properties to be identified. This was done successfully by the Bardeen Cooper Schrieffer (BCS) theory in 1957, from which the microscopic origins of the penetration depth and the Meissner effect are explained. 22 Since then, several scientists have come forward with new theories and ideas, as the power of superconductors has been observed and increasingly understood (kittel, 8th ed. 2005). 2.3 Vortex lattice or Abrikosov lattice Stable levitation of a permanent magnet above a small and flat superconductor only occurs for type II superconductors. Certainly, levitation occurs when using type I superconductors, but in a type II superconductor, the levitation is particularly stable and robust. The answer lies in the properties of type II superconductors for an applied magnetics field between two critical fields, Bc1 and Bc2. These normal regions allow the penetration of the magnetic field in the form of thin filaments, usually called flux lines, fluxoids or vortices. Such vortices lattices are named after their discoverer Abrikosov, the Noble prize winning physicist. The super-currents circulate around the normal nonsuperconducting core of each vortex; the core has a size ζ. Around the normal core, there is a circulating super current. The direction of circulation is such that the direction of magnetic field created by this current coin sides with the direction of external magnetic field. The size of the region where the super current circulates λ, from the core of the vortex lattice. The circulating super-currents induce magnetic flux that is equal to the magnetic flux quantum. This Abrikosov vortex is also termed a fluxon. The average vortex lattice density is proportional to the flux density of the applied magnetic field. Once the theory of type II superconductors was developed, this led to the commercial development of strong-field superconducting magnets. Consider the interface between a 23 region in the superconducting state and a region in the normal state. The interface has a surface energy that may be positive or negative and that decreases as the applied magnetic field is increased. A type I superconductor has positive free energy of the superconductor-normal metal boundary, and the coherence length ζ (length over which superconductivity changes) is bigger than the penetration depth λ. A superconductor is type II if the surface energy becomes negative as the magnetic field is increased and the coherence length is shorter than the penetration depth. Then it is energetically favourable for vortices to form. Figure 2.3 show the magnetic field and current density around a vortex. At the vortex there is one magnetic flux quantum ( ) that enters the superconductor. Around the vortex superconducting current are trying to keep the field out. The magnetic field decreases exponentially from the center of the vortex. In the center of the vortex the superconducting order parameter Δ goes to zero. This means that in this region the metal is no longer a shorter than the penetration depth λ this defines a type II superconductor and makes the formation of vortices favourable (Poole. 2007). 24 Figure 2.3: Magnetic field and current density around the vortex (Poole. 2007). The free energy of a bulk superconductor is increased when the magnetic field is expelled. Only a part of the flux is expelled, and the energy of the superconducting film will increase only slowly as external magnetic field is increased. This causes a large increase in the field intensity required for the destruction of superconductivity. The film has the usual energy gap and will be resistance less, and the film results show that under suitable conditions superconductivity can exist in high magnetic field (Kittel, 8th ed. 2005). There is no chemical or crystallographic difference between the normal and the superconducting regions in the vortex state. The vortex state is stable when the penetration of the applied field into the superconducting material causes the surface energy to become negative (Eskidsen. 2011). In principle, the motion of a levitating permanent magnet will cause these vortices to move. In practice, real materials (such as high Tc superconductors) have defects (missing or misplaced atoms, impurity atoms) in their crystal lattices. They are also composed of 25 many crystals, all bound together, resulting in many crystal boundaries. The crystal defects and boundaries stop the motion of the vortices, which is known as flux pinning. This provides the stability of a levitating magnet. Pinning can only occur in type II superconductors. This demonstration with high temperature superconductors indicates that they are of type II. The number of vortices representing the best compromise for a superconductor depends on both the temperature and the applied magnetic field. However, vortices are not always very mobile; their mobility depends on how the superconducting material was manufactured. When the vortices can easily move in and out of the superconductor, pinning is very weak. When the vortices are completely frozen in their position, though, pinning is very strong. Multiple factors determine the pinning force of vortices: the presence of impurities, flaws, the crystallographic quality of the material, the value of the critical current. 2.4 Pinning properties Flux pinning is the phenomenon in which the magnetic flux lines do not move and become trapped (or pinned) in spite of the Lorentz force acting on them inside a currentcarrying Type II superconductor. In flux pinning, some of the magnetic field lines have penetrated the sample and are trapped in defect and grain boundaries in the crystals. The phenomenon cannot occur in type I superconductors, since these cannot be penetrated by magnetic fields. Flux pinning is possible when there are defects in the crystalline structure of the superconductor (usually resulting from grain boundaries or impurities, or lattice distortions). 26 There are several methods for inducing flux pinning in superconducting materials – such as the inclusion of nano-composite material in the superconductor; These inclusions act as pinning centers, and their design and introduction are also termed as Artificial Pinning Center technology (APC); The introduction of Cu-Sn nanometric pinning centers into the Nb3Sn phase has been performed through successive binding and deformations, leading to Cu (Sn) deformation centers as small as 40 nm. The results of critical currents analyzed through these techniques are found to be much higher than for stoichiometric Nb3Sn superconducting magnets (Rodrigues. 2007). There have been further investigations of incorporation of components such as Nb in NbTi material to study the flux pinning behavior in the superconducting material, and a greater increase in the pinning forces and critical current densities in these materials, was demonstrated. The effect was further improved by heat treatment methods (Okuba. 2000). There is evidence of improved flux pinning by nano-particle inclusions in thin film superconductors, it was experimentally proved for high field applications that MgO inclusions in MgB2 thin films contributed to improved core pinning (Sung et al. 2003). Nano-metric Cu inclusions in Nb phase on the order of 43 nm contributed to greater improvement in critical current density in Cu-Nb composite superconducting materials. This was realized by increasing the pinning centre density in the composite superconducting material. Pancake vortices, one extreme case of type II superconductor vortices (approximated by many cuprates), consist of a stack of two-dimensional superconducting layers. Coupling 27 in a pancake vortex is confined to one layer and is so called because its extent in that layer is much larger than the layer spacing. Despite the lack of phase coherence, the magnetic energy suffices to align the vortex positions in adjacent layers (at T = 0). Otherwise, flux must travel horizontally between the layers connecting one vortex to the next. When there are thermal or pinning fluctuations, however, and a high vortex density, it may no longer be possible to say which vortex in one layer corresponds to which one in the next layer (Buzdin et al. 2002). Flux vortex is subject to a Lorentz force per unit length current density, = is a unit vector along the flux line and , where is the is the flux quantum. Averaging over a number of vortices gives the Lorentz force density. (2.1) This force tends to move flux lines in direction perpendicular to that of the current flow, inducing an electric field normal to both the movement and the field direction. The value of the electric field is given by: (2.2) Where is the velocity of the moving flux line. A simple model of flux flow considers a viscous drag coefficient η, such that the viscous force per unit length on a vortex moving with velocity is - η . Then a simple force balance equation is: (2.3) 28 and the flux flow resistivity, defined by = is given by (2.4) This flux flow resistivity is related approximately to the normal state resistivity , and the upper critical field đľ , by (2.5) In order that dissipation by flux flow does not begin as soon as vortices enter a type II superconductor, it is necessary that there is a force opposing the Lorentz force to the vortices in place. Such vortex pinning sites provided by defects in superconductor which act as energetically favourable sites at which a flux line can reside. The presence of such favourable sites for pinning creates an average pinning force for flux line lattice, which opposes the Lorentz force. Hence there is a finite critical current density, , as shown in figure 2.4: 29 đ¸ đ Figure 2.4: Schematic đ đ characteristic for linear flux flow. Critical currents in high temperature superconductors In high Tc materials, thermal effects tend to dominate the early stages of dissipation due to the fact that the activation energy is smaller than for conventional type II materials and also because they are usually used at higher temperature, so the thermal energy is greater. This causes a significant curvature of the E-J characteristic around the critical current density Jc. This is quantified by the “n-value” of the transition, where E= . The flux flow regime is difficult to access experimentally, as it only becomes dominant at high electric field, although, importantly, it has been shown to be the mechanism of dissipation at grain boundaries, where the local electric field can be as high as 3 V cm-1. The irreversibility field, Hirr, is the field above which flux pinning becomes ineffective and flux line flow causes dissipation. The irreversibility line, which describes the variation of Hirr with temperature, is concave, unlike the upper and lower critical fields and its position depends not only on the level of pinning, but more importantly, on the degree of 30 coupling between CuO2 planes, for example, in a cuprate superconductor. Hence, for poorly coupled materials such as bismuth strontium calcium copper oxide (BSCCO), the irreversibility line is much lower than for materials such as YBCO (Dew-Hughes, 2001). 2.5 Applications of superconductor (SCs) and future developments Due to the continuous efforts made by the researchers towards expanding superconductor usage, future developments are going to be numerous. Promising applications of superconductors for the near future include: ďˇ Electric power transmission systems ďˇ Electric motors (possibly including application in ship and vehicles propulsion systems such as are commonly found in maglev trains or in vactrains). ďˇ Transformers. ďˇ Smart grids. ďˇ Nanotechnology (in nanoscopic materials). ďˇ Superconducting magnetic refrigeration systems. Recent research on the nature and potential of superconducting magnets has revealed that the superconductors exhibit distinct properties that could be applied in several other applications. There are greater prospects if superconductors are applied to industrial processing, instrumentation, high-end computing, and cryogenics (CSC. 2009). When future developments are evaluated based on their industry wide classification, Figure 2.5: makes it clear that the electronics industry is going to make the widest use of 31 superconductors. In second place, it is the energy industry that is about to make wide use of superconductors in its energy storage and maintenance systems. Figure (2.5): Future developments of superconductors. Retrieved from http://global-sei.com/super/about_e/application.html The graph on the right of Fig. 2.5 shows that the world is bound to make huge use of superconductors in the near future. The first in the order of highest usage would be USA, followed by Japan and finally, Europe. Future developments are not restricted to the ones mentioned above. Superconductors can also be used in propulsion systems, and these applications now exist in several countries around the world. Superconductors can also be used to make a device known as a superconducting quantum interference device (SQUID). This is incredibly sensitive to small magnetic fields so that it can detect the magnetic fields from the heart (10-10 Tesla) and even the brain (10-13 Tesla). For comparison, the Earth’s magnetic field is about 10-4 Tesla. As a result, 32 SQUIDs are used in non-intrusive medical diagnostics on the brain (Yuichi Yamada et al, 2007). On the other hand, applications are now used commonly in hybrid automobiles. Advances are now taking place in the application of HTS wires. Magnetocardiography (MCG) works with the help of sensitive SQUIDs. MCG produces unprecedented accuracy. The future of superconductors will lead to increased usage in the healthcare sector, in addition to the transportation and automobile sector because superconductors are expected to reduce the health care costs. One use of large and powerful superconducting electromagnets is in a possible future energy source known as nuclear fusion. When two light nuclei combine to form a heavier nucleus, the process is called nuclear fusion. This results in the release of large amounts of energy without any harmful waste. Two isotopes of hydrogen, deuterium and tritium, will fuse to release energy and helium. Deuterium is available in ordinary water and tritium can be made during the nuclear fusion reactions from another abundantly available element, lithium. For this reason it is called clean nuclear energy. For this reaction to occur, as a result, they must be heated to millions of degrees so that they become fully ionized. As a result, they must be confined in space so that they do not escape while being heated. Large and powerful electromagnets made from superconductors are capable of confining these energetic ions. An international fusion energy project, known as the International Thermonuclear Experimental Reactor (ITER) is currently being built in the south of France that will use large superconducting magnets 33 and is due for completion in 2017. Large mass density is also important for nuclear fusion, achieving of which requires strong magnetic fields. It is expected that this will demonstrate energy production using nuclear fusion (Okuno et al. 2004). 34 Chapter 3 Superconducting Magnetic Energy Storage: 3.1 Introduction Energy storage systems using superconducting magnets could store significantly more energy than other technologies. The conductor for carrying the current operates at cryogenic temperatures where it is a superconductor and thus has virtually no resistive losses as it produces the magnetic field. The overall technology of cryogenics and superconductivity today is such that the components of a SMES device are well defined and can be constructed. Magnetic energy storage systems have been under development for some time; however, past devices were designed to supply power only for short durations generally less than a few minutes. SMES systems would deliver the stored energy at very low cost that is competitive with other technologies SMES is the only technology based on superconductivity that is applicable to electric utilities and commercially available today. 3.2 Magnets Magnets form the basis of the superconducting magnetic energy storage system (SMES). These are superconducting magnets, but there are also magnets used for magnetic energy storage that are not of the superconducting type (Boom and Peterson, 1972). In general, magnets are classified depending on their strengths. Of late, this categorization has enabled people to identify the right set of magnets that would be suitable for the application. These magnets are widely used in energy storage and maintenance systems. 35 Superconducting magnets Superconducting magnets have the ability to overcome electrical resistance so long as they are kept cold enough. These magnets are generally used in magnetic resonance imaging (MRI) machines. Researchers have found that superconducting magnets also have a wide range of applications in levitating trains. Furthermore, they are also used in superconducting magnetic energy storage systems where the magnet enables storage and maintenance of the energy within the system. There are three components that form a complete SMES system. These include: Superconducting coil Refrigerator that is set at cryogenically cooled temperature Power conditioning system Perhaps, it is the superconducting magnet that is fundamental to the system. Superconducting coil The coil is set at a cryogenically cooled temperature and is allowed to charge completely. As soon as it has attained complete charge, the current flowing through the coil will never decay, and thus, the storage of magnetic energy is feasible over a longer time. The main purpose of the superconducting coil is to store the energy and to discharge it as and when required. This implies that the superconducting coil allows the release of the stored energy to the SMES network (Padimiti. 2007). A SMES coil can be constructed in many different configurations. One of the most common types is the solenoid-type winding. For 36 a solenoid the stored energy per unit length of superconductor is roughly twice as high as for a trous. Since the superconductor losses are proportional to the length of the superconducting cable. A single solenoid model causes a lot of stray field effects, and hence a large number of small size solenoids can be constructed, although they end up using more conductor material (Kim et al. 2005). The toroidal type SMES coil reduces stray field effects to a large extent, but the magnetic force is increased and more superconducting material is required. Toroidal SMES systems suffer from considerably higher superconductor losses. However if the solenoid is pool cooled, the benefit of fewer superconductor losses decreases. Power conditioning system (PCS) The power conditioning system (PCS) comprises an inverter or rectifier which is meant to support the conversion between alternating and direct currents. It can be either from AC to DC or DC to AC. A PCS consists of a dc-dc chopper and a 3 phase voltage source converter (VSC). Using the voltage- angle control strategy, both the active and reactive power can be controlled. A dc-dc chopper is mainly used to keep the current through the SMES coil constant and to transfer the power to the VSC through the dc-link capacitor. The SMES coil along with a dc-dc chopper is connected to the VSC through a dc-link capacitor. This capacitor acts as a temporary dc voltage source for the VSC to inject active/reactive power into the grid. During the flow of energy, the inverter permits an energy loss of about 2-3% in every direction. This is definitely a method meant for energy storage; this system is found to be the most capable one because it loses only a very small portion of the energy (Molina et al. 2011). 37 Refrigerator The cryogenic system forms the most vital part of the SMES system. Superconducting magnets have to be kept in the required temperature range to maintain their superconducting nature and carry high current which create strong magnetic field. This component is especially intended to moderate the temperature within the system. The magnet operates at a cryogenically cooled temperature in order to store and discharge energy with greater efficiency and minimum loss. This component ensures that the temperature is set perfectly for the energy to flow accordingly (Ise et al. 1994). Charging system The operation of the superconducting magnet involves a power supply for operation on persistent mode. The changes that are made on the current via the magnet must be done in a slow manner because of the large voltage spike that might be caused between the windings due to abrupt changes. The operation of the superconductor in persistent mode enables stability within the magnetic field. Also, there will be control of the energy consumption. Quench is a sudden end of operation, which generally takes place when a section of the coil becomes resistive. This can occur because the field inside the magnet is too large, the rate of change of field is too large, or a combination of the two. More rarely, a defect in the magnet can cause a quench. When this happens, that particular spot is subject to rapid joule heating, which raises the temperature of the surrounding regions. When the operation becomes normal all of a sudden, this might be the result of such a defect and requires replacement of the magnets that are being used at the moment (Rao. 2008). 38 In this research system, most of the volume is occupied by the refrigeration system, which depends on cryogenic liquids and evacuated spaces, as in a thermos bottle. The actual magnet coils are located in the lower part of the system, and the bore is used for samples to be studied under the very high magnetic field produced by the magnet. Scientists are currently working on superconducting magnets where the fields are set even higher (up to 38 tesla). Superconducting wires The majority of superconducting magnets are wound with conductors (for instance, niobium – titanium alloy in a copper matrix). Including these conductors in the superconducting magnets stabilizes the charging and discharging process within the energy system (Yuan et al. 2010). The other commonly used materials in real time applications are: Niobium – Tin conductor – These conductors are used together with niobium – titanium single filaments. This type of conductor is generally expensive, tough to wind and costlier than NbTi for magnets. SMES systems that use NbTi coils are cooled with liquid helium (LHe). Using LHe is impediment from the cooling system point of view because LHe itself is very expensive compared to liquid nitrogen (L ) and LHe requires heavy installation. This feature of cryocoolers is important; the operating temperature range of an NbTi coil will be between 10 K and 20 K to increase the critical current for the coil (Venkataratnam et al.1999). Yttrium-barium copper oxide or YBCO (thin film, coated conductor), is a crystalline chemical compound. It is regarded as a high temperature superconductor and 39 is still identified as the first material that achieved superconductivity above 77 K, which is the boiling point of liquid nitrogen. YBCO is highly applicable for energy storage purposes. YBCO single crystals possess high critical current density. The poly-crystals, however, exhibit a low value of critical current density. Generally, YBCO is deposited on flexible metal tapes. The result of this process is termed “coated conductor”. The multilayered structure of YBCO helps in the improvement of current-carrying capacity (Pan et al. 2006). An YBCO SMES is smaller than an Nb-Ti SMES and can function under higher temperature, owing to its high Ic/Jc -B properties. Because of their different electrical properties, YBCO SMES and Nb-Ti SMES must have different types of systems (Fujiwara et al. 2010). Magnesium diboride (Mgđľ ) is a simple ionic binary compound that has proven to be an inexpensive and useful superconducting material. The highest superconducting transition temperature is 39 K, which means that MgB2 based systems can be cooled by modern cryocooling device, without the costly problematic and hazardous use of liquid helium. The most important difference between MgB2 and other practical superconductors is that it has two superconducting gaps originating from two different bands. Tuning the scattering rates between the two bands improves the superconducting properties and the practical applicability of MgB2 (Vinod et al. 2006). 3.3 The modeling of an HTS pancake coil Superconducting magnetic energy storage (SMES) systems possess greater cyclic efficiency and quick response time. The development of such a system is based on several parameters. The superconducting tape for the system has to be first chosen. 40 This could vary in terms of its thickness and diameter (Yuan et al. 2010). For an SMES system, the inductively stored energy (E in Joules) and the rated power (P in Watts) are the commonly given specifications for SMES devices, and can be expressed as follows: Stored energy = , (3.1) Where L is the inductance of the coil, I is the dc current flowing through the coil, and V is the voltage across the coil. The coil for maximum energy storage is not the same as the coil for maximum inductance (L max) for superconductors. This is due to the fact that maximum inductance leads to higher field (above the critical field) at lower coil-current (which cannot be increased beyond the reduced critical current of the conductor) (Rao. 2008). This configuration of the stacked pancake coil is illustrated in Figure 3.1. The most important step in the entire development process lies in the modelling. Superconductors need to be handled very carefully, as they have distinct properties that should never be affected by any sort of external factors, and they are also intrinsically expensive (Choi et al. 2009). The modeling function starts with the basic assumption that the distribution of current density covers the cross-sectional area of every tape. To develop a superconducting magnetic energy storage system, it is important to classify the coil into two different regions, namely the critical and the sub-critical regions, which are presented in Figure 3.1, with the regions highlighted. The critical regions are constrained by a curve rather than a straight line. The critical region Jc (x,z) depends on the local Bz (x,z), as the perpendicular magnetic field has a much larger effect on the 41 critical current of coated conductors than the parallel magnetic field: | | (Bo is a material constant). This important stage of modeling also influences the performance of the coil (Yuan et al. 2010). Figure 3.1: Magnetic field and current density in SMES coil (Yuan et al. 2010) In this configuration, 2a is the width of the tape, the thickness of each tape is D, and the height of the stack is 2b, so therefore there are 2b/D tapes in the stack to order the magnetic flux within the system. The magnetic flux lines that surround the critical region support the operations performed using the coil. Since the tapes form tightly packed pancakes in the coil, the flux lines cannot penetrate into the tapes and hence have to be parallel to the surface of each tape. This means that there is no perpendicular magnetic field in the sub-critical region. The current density in each tape in the sub-critical region will therefore be constant, which is needed to guarantee that transport current carried by each tape is the same. It is necessary to search for the critical boundaries that make the perpendicular magnetic field nearly zero in the sub-critical region, as well as determining 42 the magnetic field and current density distribution across the coil. Figure 3.2 illustrates the model. The critical boundaries are two symmetric parabolas The critical current density . flows in the critical region while a smaller current density flows in the sub-critical region. Yet another important step in the development of the SMES coil lies in the shielding of the center tapes. This is helpful for the transport current circulation. This particular step of the development process also helps in the management of the operation current as well as control of AC losses (Yuan et al. 2009). There are several ways to construct an SMES coil. Modular shaped construction of the toroidal type SMES coil is one possibility. The solenoid type winding is another method that is commonly used. As coils play greater roles in energy storage systems, the design and development of coil stages should be given greater significance. Soon after the example coil has been divided into regions, it is separated into six different segments. This coil is then further sectioned based on its operations. The charging and discharging operations take place within the SMES coil, with the current passed on to the other parts of the energy storage system (Padimiti et al. 2007). 43 Figure (3.2): SMES coil design (Padimiti et al. 2007). 3.4 Thermal stability in superconducting materials Stability is one of the key issues in the design of a superconductor, and indeed deserves much attention in magnet design and analysis. Thermal stability of superconducting material is general studied by applying over-currents or heat pulses to the conductor and analyzing the electric field and temperature profiles along the conductor. This experiment simulate the behavior of the superconducting conductor during a fault in different applications and allows the determination of parameters such as the minimum quench energy, quench propagation velocity, quench current, etc. (Martinez et al. 2010). Intrinsic thermal stability is where the superconductor carries operating current without resistance at all times after the localized release of thermal energy. The thermal stability criteria are different from the cryogenic stability criteria for magnets and have particular relevance to thin film superconducting materials. Crystals of ceramic high temperature 44 super-conductors are likely to exhibit anistropic thermal conductivity, which was found to have a high influence on their thermal stability (Flik et al. 1990). Several studies have been conducted on the thermal stability in multifilamentary connected super-conducting materials – as long as the filling factor is constant, there was no effect found on the thermal stability of the superconducting materials, irrespective of the superconductor location in the strand. The filling factor is the ratio of the superconductor volume to the coil volume. YBCO coated conductors have been the subject of intense research activities in recent years due to their promising properties for use in electric power applications, such as cables, magnets, motors, generators, and superconducting fault current limiters (SFCL). In most applications the nominal current is below the critical current , and therefore the dissipation in the superconducting material is only generated by the AC losses. In contrast, SFCLs, especially the resistive type, are based on the superconducting. To normal transition induced by a current higher than Martinez et al. 2010). To study the micro structure and superconducting properties of YBCO films irradiated by nanosecond pulsed excimer lasers, superconducting YBCO thin films were deposited in situ on (100) LaAl03 substrates using the pulsed laser evaporation technique. These films are found to exhibit excellent thermal stability. Also, there is improvement in the Jc of the films due to the low energy density irradiation; however, for energy densities above the melt threshold, the Jc values decreased sharply (Bhattacharya et al. 1991). 45 Under cryocooled conditions, when the thermal stability of reinforced Nb3Sn composite superconducting materials are analyzed, it is found that the thermal stability is a function of the thermal conductivity of the reinforced materials and hence affects the thermal stability of the composite superconducting material. Sputtering of amorphous-based thin film superconductors that contained a certain volume percentage of metalloids was found to lead to good thermal stability after annealing (Kondo. 1992). Other issues that are considered in the thermal stability and related performance design of the superconductor are the transient temperature response of the conducting material in the vicinity of a quench, quench propagation time and minimum energy relations during the temperature disturbance, etc. All these studies are required in the effective design of the thermal stability of the superconductor (Johnstone et al. 2005). 3.5 Applications of SMES The economic use of superconducting magnetic energy storage (SMES) will be most likely attained by applying it simultaneously over a wide spread field of different tasks. The first application is for a thermonuclear reactor. The second application is for large particle accelerators, and the third application is for utility network conditioning. Despite these potential applications, SMES imposes certain restrictions on the structure and operation. One of the operating procedures for SMES states the need to maintain the permanent current that is being circulated within the closed circuit. In this case, resistance 46 has to be low, and the closed circuit has to be developed from superconducting materials (Masuda and Shintomi. 1977). A superconducting magnetic energy storage (SMES) unit is a device for efficiently storing energy in a magnetic field. it offers very fast exchange of power between the AC power system and the superconducting coil. The potential applications of SMES in power systems have been studied since the early 1970s. The 30 MJ SMES unit installed in the Bonneville Power Administration (BPA) at1983 proved that an SMES has the capability to improve damping of generators and augment dynamic stability. SMES permits fast independent regulation of active and reactive power in four quadrants (Zheng Li et al. 2000). The wide range of benefits that the superconducting magnetic energy storage systems offer makes them widely applicable in various industries. Currently, SMES devices are used in energy storage and power system applications. Modern power systems are very dependent on stabilizing devices in order to ensure reliability as well as stability in their operations. These also provide sufficient damping in the system (Xue et al. 2005). The damping takes place during the transient period when line switching, fault clearance, and load changes take place. Power system stability limitations are often characterized by low frequency oscillations (0.5 Hz) following a major system disturbance. Power transfers are often limited to prevent growing oscillations from occurring, following the loss of a single major transmission line or generator. When the long-term stability is limited, the transmission capacity can by increased by providing active damping of these oscillations. SMES can actively damp these system oscillations through modulation of both real and reactive power. Because SMES can modulate real power, as well as reactive power, it can 47 be much more effective and smaller in size, than other technologies. This damping is represented in the following figure. Figure 3.3: SMES unit applicable for damping system oscillations (Xue et al. 2005). Superconducting coils which are cooled to a temperature below the superconducting critical temperature are used to store energy – in systems which are often termed as SMES – will take in direct current – which will be later stored in these coils in the form of magnetic energy, and the energy contained in these coils can be later retrieved by the use of rectifiers for several energy applications; They promise high quality power supply with several advantages over conventional systems and find are finding application in many domains requiring a varying range of capacities. The next application is the usage of SMES systems in applications/systems requiring voltage stability. These SMES systems ensure better efficiency in applications that require their power outputs to be improved. The ability of the SMES systems to compensate for fluctuating loads and enhance flexible AC transmission system (FACTS) 48 performance has extended domains of application (Xue et al. 2005). In the case of power systems, the SMES applications are listed below: Figure 3.4: Types of SMES applications for power systems (Xue et al. 2005). SMES systems have wide applicability in the field of electrical power supply device. The mechanical properties and AC loss characteristics that characterize second generation HTS wires help in the enhancement of performance. Such SMES applications are listed below: ďˇ Turbine systems. ďˇ Applications demanding control of AC losses. ďˇ Optimization of energy based storage system. 49 ďˇ Electrical power applications. ďˇ Power transmission systems. ďˇ Load leveling applications. The Distributed Superconducting Magnetic Energy Storage (D-SMES) System is an innovative new application of proven SMES technology that provides two critical capabilities. One is real energy storage through the use of superconductors, and the other is instantaneous response through the use of power electronics. Superconductivity makes it possible, by eliminating resistive losses within the magnetic coil, to store and instantaneously discharge large quantities of power. The power electronics module, which consists of an insulated-gate bipolar transistor (IGBT)-based voltage source inverter system, uses advanced power electronics to detect voltage sags and to inject precise quantities of real and reactive power to boost voltage on the transmission system within a fraction of a cycle. D-SMES devices are most effective in addressing voltage stability problems. They can be used for other applications, however, such as flicker correction, capacitor bank switching, and other power quality solutions for both utility and industrial applications. Some of the benefits of using the D-SMES device are: faster voltage recovery when compared to other similar devices, distributed sources, low cost when compared to traditional solutions, quick and easy installation with short lead times, modular design to meet future load growth, and portability in case it has to be moved to other locations (Kolluri. 2002). Another application of zero–resistance or highly efficient energy conversion systems containing high temperature superconducting units is in creating magnetic energy for 50 magnetic levitation for usage in high speed trains – which has been found to be highly successful. 3.6 Ongoing SMES development There are measures that are already being taken to restrain the costs to affordable values. Plans that might improve the market for SMES systems include: ďˇ Cost reduction by the use of high temperature superconducting coils. The commercialization of high-Tc superconducting (HTc) tapes has excited worldwide research interest in power applications, because the use of superconductors can increase the efficiency, and reduce the volume and weight of the power equipment because its performance offers high current-density and low power loss. This is especially true for superconducting power devices, such as HTS cable and high Tc superconducting magnetic energy storage. It is expected that superconducting technologies will play an important role in the future smart grid, because the application of superconductor technologies in the power grid can decrease power losses, relieve overload, avoid higher levels of transmission voltage, increase power transmission capacity and improve power quality and grid stability (Zhang et al. 2011). ďˇ Reduction of costs for the conductor material and also for the refrigeration system might directly reduce energy storage costs in SMES. A low temperature SMES requires liquid helium for its operation, which makes it expensive to operate, particularly because of the cryogenic system. With the availability 51 of a high temperature superconducting coil, only liquid nitrogen is required, which is readily available and much cheaper than liquid helium. With higher temperatures come not only reduced refrigeration costs but also enhanced reliability (Sutanto et al. 2009). ďˇ Reduction of the cost of the power conditioning unit is likely in the future. ďˇ Prices can be reduced generally if research continues. Currently, there is considerable research going on in improving the feasibility of high temperature (Tc) superconductors in normal and high field applications (stronger magnetic field applications). Also, in recent times, a great amount of work on very high field superconductors has been carried out in many projects worldwide. These systems are highly reliable and very efficient, and hence, are particularly popular for specific applications requiring high quality power and also for the general energy applications. High quality power applications such as chip manufacturing systems are dependent on SMES as well as general applications such as (solar and, wind energy) are dependent on SMES to deal with the intermittency problem. Also, SMES system is finding applications in pulsed back-up utilities (short time back-up). A superconducting coil exhibits-zero resistance for dc current ďˇ Future SMES systems will involve cost effective technology. There are several R&D plans that are intended to widen the potential of superconductors and superconducting magnetic energy storage systems (Rupich et al. 2010). Ongoing SMES development demands the following: ďˇ Reducing the stress related issues. 52 ďˇ Increasing the thickness of wires. ďˇ Control of the thickness. ďˇ Improved dynamic performance. The existing design of an SMES system is presented below: Note that PCS is the power conditioning system, SCM is the superconducting coil with the magnet, and, CS is the cryogenics of the system. Figure 3.5: Components of existing SMES system, (Xue et al. 2005). Ongoing SMES development demands development of an optimal design that can also overcome the existing design constraints and enhance the effectiveness and efficiency of the system. 53 SMES also, has the ability to manage the spinning reserve and establish tie-line control among the utility control areas. The power quality improvement feature of SMES has made it viable for various lighting applications. In addition to these benefits, there are certain secondary benefits offered by the superconducting coils (Ali. 2010). These might include backup power supply, deferral of new capacity for transmission, extension of available generating units, adherence to environmental regulations, and better applications and lower use of energy resources. 3.7 Comparison of SMES and batteries At the present stage, there are several applications making use of energy storage systems. These energy storage systems are particularly meant to store the energy for a specific period of time and discharge energy as and when required. In this process, there are several constraints involved, such as design constraints, operation constraints and budget constraints. Superconducting magnetic energy storage (SMES) systems are widely used in various large-scale and power applications. On the other hand, batteries serve as a great source for energy storage and generation. The working techniques in these systems differ to a greater extent. This section presents a broader overview on the working of batteries. Furthermore, the energy storage systems that are commonly used for various applications are discussed, out of which, SMES and batteries are chosen for comparisons. The comparisons are made on various aspects in order to gain insight into the implications and applications of these systems along with the nature of their potential. The research on the energy storage 54 systems has indicated that these systems could be applied in applications used in day–to– day life. Energy storage refers to the process of storing energy in order to enable the device to carry out useful operations in the future. These systems are often denoted as accumulators, due to their basic function. The energy being stored is either potential or kinetic in nature (Connolly. 2010). Recently, there has been a demand for storing energy from the non-renewable sources (exhaustible sources) of energy. Hence, system development for the purpose of energy storage is continuing and is expected to be applied over a wide range of domains. The battery is used as an electrochemical storage system, although it has limited capacity. The new technologies that have been developed for the battery, however, have improved its load leveling capacity and energy storage functionalities. In certain cases, such as the alternating current (AC) systems, electrical energy cannot be stored electrically. Yet, it has to be generated as and when there is a demand in the market. For this case, energy storage systems are required, and the energy is stored electromagnetically or kinetically, or electrochemically. The energy conversion technique in every energy storage technology is based on the requirement or purpose. The energy conversion unit is meant to convert the energy to a different form and back again. In other words, it is a process of charging and discharging the energy from the storage system. The potential application of these systems include dynamic voltage stability, load leveling, sub–synchronous resonance damping, spinning reserve for the short term, and power quality improvement (Connolly. 2010). 55 Both, the Battery Energy Storage (BES) system and the Superconducting Magnetic Energy Storage (SMES) system have multiple similarities as well as differences. Their applications in the utility field are enormous, and their potential growth has been quite evident. The operation of a BES system is quite similar to any other energy storage system. There are a few constraints in terms of cost and maturity levels. For instance, the lead acid battery can be used only for specific applications. The environmental tolerance for some of the batteries is a major constraint. This does not happen in the case of the SMES system, however. The similarity between these systems lies in the basic characteristics that they are dependent on. These include round trip efficiency, charging rate, discharging rate, energy density, and performance. The following table 3.1 lists the differences in terms of the suitability of these systems for utility applications (Akhil et al. 1993). The comparison is made for both the current technologies and advanced technologies. In the case of SMES, the systems in the current technologies employ low temperature superconductors, while the advanced technologies are employing high temperature superconductors. These classifications are not present in the case of BES. The batteries differ in terms of their material, but are not based on any critical factors such as temperature. This is one major difference between these two types of energy storage systems. The BES could meet the basic performance requirements for the majority of applications. Utilities generally are too concerned about reliability, energy density, and life span. In case of SMES systems, they were able to meet the performance requirements only in those systems with charging and discharging. The majority of the SMES systems 56 operating with high temperature superconductors led to the demand for more development. The basic requirement for a storage system to become a utility is quite simple. The similarity is that the requirement is the same for both types of systems (Therond et al. 1993). There is a need for an interface to be established between the grid and the storage device. This interface is meant to act as a power conversion subsystem. The advantage of BES over SMES lies in the storage capacity of the former. The storage capacity is enormous and flexible in case of BES. Therefore, this could be applied easily for largescale applications too. Here is a broad classification between the two types of systems in terms of their advantages and disadvantages. These differences have differentiated their application and developments (Therond et al. 1993). Superconducting magnetic energy storage (SMES) has a faster response and is more economical, and environment-friendly than an uninterruptible power supply (UPS) using batteries. Also, the SMES not only has the ability to control active and reactive power simultaneously, but also has a long life-time because the superconducting magnet does not have a degradation problem like the battery. Therefore, the SMES is a superior candidate to the UPS using the battery. The SMES needs a cryogenic system without exception. A conduction cooling system that has a simple, light and small structure is well adapted to high temperature superconducting (HTS) SMES (Yeom et al. 2007). 57 Table 3.1: Advantages and disadvantages of SMES and BES. Advantages BES SMES Convenient size Enormous capabilities that have surpassed other energy storage systems Convenient voltage tenets Quality design that Viable for short term power encourages widespread applications usage Quick charging and discharging Disadvantages Limited cycle life High initial cost Voltage limitations Requires development considerable Current limitations Less storage capacity Environmental hazards In the current scenario, there are various sources of energy where it is rather important to store energy in order to use it for the future purposes. SMES systems function mainly in high inductance magnetic fields but the BES systems are in demand for DC currents. There are other systems such as flywheels that vary in their functions depending on the input loads. Most importantly, the systems do not differ in their operations, but in their materials, design, and development and application stages. From the differences stated in the above table, it is evident that SMES systems are still in their developmental stages when compared to the usage level and applications of BES systems. 58 Throughout, this chapter, the evaluations have been presented for each system in terms of its present stage, as well as future developments. These are meant to assess the areas where both systems fall short. The advantages and disadvantages are also classified. For the SMES systems to become practical, it is important to overcome the technical challenges. Likewise, BES systems need to improve their maturity level in order to improve its practicality. With these broad differences and similarities, this chapter has analyzed and given an overview of the two major energy storage systems that are now used in every part of the world, ranging from short-term to long-term applications. This chapter will also be helpful in identifying the potential areas that can be improved to provide greater benefits in the near future. 3.8 Summary The main purpose of using SMES devices is to store electrical energy in the magnetic field of a large coil so that it can be used whenever it is needed. They are mainly used to supply large, repetitive power pulses, and for load leveling applications. They can also be used in power systems in order to increase the power quality. In this study, an attempt his been made to make this coil small by using an HTS coil, which can store a large amount of energy in a small coil because the amount of energy stored depends on the critical current flowing through the coil, and the parameter of the thin film such as thickness and width of the tape. 59 Chapter 4 Optimum Design of Superconducting Solenoid Coil for a SMES Unit: 4.1 Introduction In the previous chapter, the superconducting magnetic energy storage system was explained. In this chapter, the design optimization for a superconducting solenoid coil made of HTS tape for the purpose of energy storage is described. In this study, the relationship between the geometrical parameters and the magnetic field are considered, as well as various practical issues regarding the choice of a design for a prototype. The design optimization for a superconducting solenoid coil in this study will use second generation high-temperature superconducting wire (2G HTS), namely đđľđ2 đ˘3đ7−đż (YBCO) coated conductor. The most significant benefit from the use of 2G HTS wire in real-world applications is energy savings from improved efficiency (Xie et al. 2009). There are three separate elements that have to be considered when designing a HTS SMES coil the properties of the wire, the total length of the wire, and the stray fields. The second and third elements are somewhat interrelated and are considered in the optimization process at the same time. Depending on the shape and manufacturing process, HTS wire acquires severely anisotropic characteristics according to the direction of the external magnetic field. The configuration of the coil needs to be considered in terms of its place of installation. There are three types of coils that may be considered. The solenoid coil is easy to build, but the stray field is too high to be viable in a densely populated area. Multiple solenoid 60 coils can be easily built with an even number of solenoid coils, but they require significantly more conductor than simple solenoids. The toroid coil is ideal from the stray field point of view, but it is hard to wind with tape-shaped HTS wires. The design of a magnet coil also depends on the purpose for which it is going to be used. For example, a highly uniform field is required for maximum stored energy and minimum cost. The design in this research of the HTS SMES solenoid coil is aimed at maximizing the stored energy (Chen et al. 2006). The energy (đ¸) stored in the magnetic field of an inductor is proportional to its inductance ( ) and to the square of the current flowing through its windings ( ). To calculate this energy we use Equation (3.1) (section 3.3). It is obvious that if large currents flow through the windings of an inductor, a significant amount of energy can be stored in its magnetic field. In the case of a superconducting conductor, to store more energy, it is necessary to cause a larger current density to flow in the coated conductor. The critical current density (Jc) is however, dependent on the magnitude and orientation of the external magnetic field applied to the surface of the coated conductor. Therefore, a design which yields the maximum value of is also the design for maximum stored energy. An optimal solenoid has to be designed to have the maximum inductance for a given length of conductor at its operating current. Since the inductance of a solenoid is determined by the number of turns and the overall dimensions of the winding, designing an optimal solenoid requires finding the number of turns and the overall dimensions to achieve the maximum inductance for a given length of conductor (So Noguchi et al. 2010). 61 For analytical purposes, a solenoid made of a given length of thin tape conductor (such as YBCO tape) can be considered as a stack of pancake (or double pancake) coils of the same size that are made from the same piece of thin tape conductor. The YBCO coated conductor is more promising than alternatives as a wire for application, owing to its high n-value and low dependence of the critical current on the external magnetic field (Hazelton et al. 2009). Figure 4.1 shows the cross-section of a solenoid coil made from stacked pancake layers. The number of turns in each pancake coil can be expressed as: = (4.1) For each single pancake, the length of tape conductor can be expressed as: đđ = (4.2) Where, Do and đˇi are the outer and inner diameters of the solenoid, d is the thickness of the tape conductor and h is the width of the tape conductor. H đˇ đˇ h Figure 4.1: Solenoid model for analysis. 62 For a stack of pancakes: H = nph (4.3) Where H is the height of the coil, np is the number of pancake layers and h is the width of the tape conductor. To get the maximum stored energy, we need to increase both L (the inductance of the coil) and I (the current through the coil). The maximum current will be the critical current of the tape, which is determined by the perpendicular magnetic field and the temperature of the tape. When designing an HTS solenoid, the other factor that needs to be considered is the flux density. This is because the critical current of an HTS varies with the external magnetic field. Normally, the higher the flux density is, the lower the critical current. There are many different formulas and charts published for the calculation of the inductance of a solenoid with given dimensions. The inductance L will be determined as by Welsby (1960), and can be expressed as follows: = Where (4.4) is the number of turns of the solenoid, and Where α = ( ), β = ( ) đ are size ratios. (4.5) As the inductance of a solenoid is determined by the number of turns and the overall dimensions of the winding to achieve the maximum inductance, to calculate the number of turns N, the thickness d and width h of the tape must be known, because the number of turns N is determined by: 63 N= Where (4.6) number of turns in each pancake and number of pancake layers. The number of turns in each pancake can be calculated from Equation (4.1) and number of pancake layers determined by: (4.7) =H/ h 4.2 Calculation results: In this study, we will calculate the energy that can be stored in the solenoid coil, with the winding of this coil made from thin film tapes (coated conductor). To design the coil, we have identified the parameters of the coil that are sufficient to store the amount of energy required to supply and support one desk lamp with power of about 40 watts. This means calculating the energy needed for this lamp to work for 10 hours straight, as an example. After calculating this energy and estimating the parameters of the coil, we can estimate and design coils that have the ability to store enough energy to support and provide more energy, such as to a house, city. etc. To calculate this energy, the following equation is used: (4.8) đ¸ Where đ¸ is the energy in joules So, 10 hours corresponds to 1.44 is the power in watts and, is the time in seconds, (4.9) 106J 64 The inductance of the solenoid coil also needs to be calculated. The designed solenoid coil is made from HTS (YBCO). The parameters required for calculation include the inner and outer diameter, height of coil, number of turns in each pancakes, number of pancake layers, and number of turns of the solenoid. In the case of the coated conductors, the ultimate goal is to obtain YBCO coatings with high total critical current: (4.10) Where is the critical current in (Amperes), is the critical current density in ( ⁄ ) and A is the area through which current flows with, (4.11) Where and are the width and thickness of the YBCO coating, respectively. Where the dimensions of the tape used in this study are width of the tape is 4 mm, and tape thickness is 5 µm (Yuan et al. 2011). In this study, different parameter values are used to achieve different critical current densities of đ . The parameters are used to calculate different values of the current density and compared with each other to obtain the best results. Table 4.1 gives the details of the tape: 65 Table 4.1. Characteristics of YBCO tapes. Tape configuration quantity Tape width 4 mm Thickness of the tape 5µm Critical current densities (Jc1, Jc2) and (Jc3) đ Critical currents (Jc@77 K) 12 A, 24 A, and 50 A After using Equation (4.11) to calculate the area through which the current flows, Equation (4.10) is used to calculate the current flow. These results are then used to calculate the amount of energy. In order to calculate the inductance of the designed solenoid coil using YBCO tape to store energy, its parameters are given different values to calculate inductance from Equation (4.4). Table 4.2 gives the details of the parameters of the YBCO coil: Table (4.2) Specification of the YBCO coil for the HTS SMES magnet. Parameters Specifications Inner diameter Di (m) 0.060-0.360 m Outer diameter Do (m) 0.400m Height of the coil H (m) (stack of 0.008-0.060 m pancakes) 66 In the calculation, the parameters of the tape and the outer diameter of the coil remain constant, while different values are given to the inner diameter and height of the coil. This calculation is used to observe the effects of variations in these parameters on inductance and energy storage. Figure 4.2 shows the calculated inductance of the solenoid plotted against with inner diameter and size ratios, , respectively. Note that increasing the inner diameter while the outer diameter remains constant leads to a decrease in the thickness of the coil, and decreases the number of turns in each pancake from Equation (4.1). The number of pancake layers in each curve remains constant because, depends on the height of coil from Equation (4.7). The width and thickness of the tape conductor are 4 mm and 5µm respectively. It is assumed that the solenoid has an outer diameter of 0.400 m and is made of a number of double-pancake windings. The calculation has been repeated for a solenoid made up of various numbers of double-pancake windings. Since inductance (L) depends on many variables equation (4.4): α, β, Di, Do, H and N, where Do constant and α and β depend on Di and H, this means that L depends on Di, H and N. Figure 4.2 (a) shows the calculated inductance of the solenoid plotted against its inner diameter . It can be seen that in every curve increasing inner diameter while the outer diameter and height of the coil remain constant leads to a decrease in the inductance, with the maximum inductance appearing near Di= 0.060 m. The inductance then begins to decline, while any increase in the height of the coil results in an increase in the value of the inductance. Figure 4.2(b) shows the relationship between α and L. Note that the shape of the first curve will be flat when H= 0.008 m and np= 2 from Equation (4.3). Therefore, increasing the height of the coil each time leads to increase the number of pancake layers in and increase the inductance. 67 Where there is a large increase in the value of the inductance, as in comparison between the first and the last curve, this is because any increase in the number of pancake layers means an increase in the number of turns in each pancake coil, height of the coil, and length of the tape. Equation (4.5) is used to calculate both α and β by setting different values to the inner diameter and height of the coil, where α and β inversely proportional to Di. Therefore when designing a coil for the purpose of obtaining a high value to inductance, we want to know effect of each variable on inductance. In this case, the solenoid with the maximum inductance has the following specifications: inner diameter (given) = 0.060 m; outer diameter = 0.400 m, height = 0.060 m, number of pancake layers = 15, number of turns in each pancake coil = 34000, number of turns of the solenoid= 510000, and inductance = 40534.2henry. On a practical level, the coil can be a single solenoid wound layer by layer, or a stack of pancake windings connected in series. 68 (a): relationship between inductance and inner diameter. (b): relationship between inductance and size ratio . Figure 4.2: Calculated inductance of HTS solenoid versus inner diameter (a), and size ratios, 69 (b), from Eq. (4.4) 4.3 Field-dependent current performance There are several parameters that need to be considered when deciding the features of the optimal design. The main parameter is the current bearing capability, since it is essential to raise this capability as much as possible. This is generally implemented through the binding conditions, because the current bearing capability of a second generation superconducting solenoid coil is directly dependent on the distribution and direction of the magnetic field, the calculation of its induction should involve both magnetic and geometrical parameters (Feng, 1988). The optimization of the design of a second generation superconducting solenoid coil has been attempted using two different methods, an analytical method and a mathematical model. The latter tends to be more cost efficient. This can help in achieving the expected level of optimization. Like its low-temperature counterpart, an HTS needs cooling. At a particular temperature (77 K in liquid nitrogen), the critical current of an HTS varies with the external magnetic field. Normally, the higher the flux density is, the lower the critical current becomes. An HTS solenoid should be designed to ensure that the maximum flux density at the winding is within the critical flux density of HTS performance at the operation temperature. Otherwise, the solenoid will not be superconducting. 70 H đľ đľ Di Di Do Figure 4.3: Location of maximum flux density Bm in solenoid (Feng, 1988). To demonstrate the design process for an HTS solenoid, the maximum flux density versus the operation current of a number of HTS solenoids with different sizes was calculated. It should be noted that the maximum flux density đľ in a solenoid is not the center flux density đľ . đľ is located at the indicated circle on the central plane of the solenoid and Bm at its inner cylindrical surface (Figure 4.3) (Feng, 1988). 4.4 Maximum energy storage The above design considerations are suitable for designing an HTS solenoid of a certain inductance for a given operation current. For energy storage purposes in this study, an alternative method of design optimization will be used to obtain the maximum energy storage for a given superconductor. 71 Taking the same pancake approach as shown in Figure 4.1, and performing the inductance calculation for solenoids of various size ratios to be constructed from an YBCO tape, whose width and thickness are 4 mm and 5µm, respectively, the inductances and the critical (maximum) operation current corresponding to the critical current performance of the HTS tape at 77 K were found, and hence the critical (maximum) energy storage of this coil was obtained using Eq. (4.1). Figure 4.4 shows the maximum energy storage plotted against the size ratios and inner diameter when the critical current ⁄ density approximates ⁄ when and , when the critical current is = 24 A @ 77 K; and when = 50 A @77 K. We note that when the value of = 2.5 12 A @ 77 K; ⁄ and increases, the value of the stored energy increases, when the other parameters of the coil remain constant. Figure 4.4(a) shows the relationship between energy stored E, and inner diameter Di, and size ratio We note that when the values of , H, and L increase, the stored energy increase. Because the energy stored depends on both the critical current and on the inductance when the critical current remains fixed, in this case, the energy depends on the inductance. It increases with inductance and reaches a maximum value when the inductance reaches a maximum value. We also note that when the value of Di increases, the value of energy storage decreases. In the case of = 12 A, the maximum energy storage is đ¸ J, as shown in Figure 4.4(a). If we assume that we have one lamp (40 watts) and use Equation (4.8) where đ¸ đ 72 This means, after we have designed and determine the parameters of the solenoid pancake coil as illustrated in Figure 4.4(a) and passed a current of about 12 A through this coil, the stored energy in this case can provide two lamp with enough energy to work for about 10 hours. In the case of = 24 A and energy storage is E = 1.167 = 50 A, as in Figure 4.4(b) and 4.4(c), where the maximum J and E = 5.066 J, respectively, then this energy is enough to make about 8 lamps and 35 lamps work for 10 hours respectively. So, this means that the value of energy storage depends on the value of critical current passing through the coil, where an increase in the amount of current leads to an increase in the amount of energy storage. The critical current in this case depends on the critical current density because the width and thickness of the tape are constant. Therefore, we note that the increase in critical current density is due to the increase in the dc current flowing through the coil and leads to the increase in the amount of stored energy in the coil. 73 (a) Ic=12A 74 (b) Ic=24A 75 (c) Ic=50A Figure 4.4: Calculated maximum energy storage of solenoid versus inner diameter Di, and size ratio, α. 76 Optimization of inner diameter of coil Figure 4.5 indicates the relationship between height H and E the maximum energy storage in the coil, when the inner diameter of the coil (Di) is constant and is increased by different values for different curves. For each of these values, the inductance of the coil was calculated using Equation (4.5), and the amount of the energy stored was calculated using Equation (4.1). This was achieved using the Origin software program to graph the relationship between H and E, when the outer diameter đˇ and Di were held constant and the only variable in the equation was the height of the coil It should be noted that energy storage increases as the height of the coil increases. It is also the case that increasing the inner diameter leads to decrease energy stored. Therefore, we can calculate the maximum energy that can be stored in the coil by determining the value of because đˇ and Di is constant. Once this calculation has been done, any further increase in Ic will be increase in the level of energy stored in the coil. Figure 4.5: shows the relationship between height of the coil and maximum energy storage when đˇ and, Di is constant and is variable. 77 3000000 Di=0.060m Di=0.110m Energy storage (J) 2500000 Di=0.160m Di=0.210m 2000000 Di=0.260m Di=0.310m 1500000 Di=0.360m Do=0.400m, Ic=12A 1000000 H=0.008-0.060m 500000 0 0.00 0.01 0.02 0.03 0.04 0.05 0.06 0.05 0.06 Height (m) 12000000 Di=0.060m Di=0.110m Energy storage (J) 10000000 Di=0.160m Di=0.210m 8000000 Di=0.260m Di=0.310m 6000000 Di=0.360m Do=0.400m, Ic=24A 4000000 H=0.008-0.060m 2000000 0 0.00 0.01 0.02 0.03 0.04 Height (m) 78 50000000 Di=0.060m Di=0.110m Energy storage (J) 40000000 Di=0.160m Di=0.210m 30000000 Di=0.260m Di=0.310m Di=0.360m 20000000 Do=0.400m, Ic=50A H=0.008-0.060m 10000000 0 0.00 0.01 0.02 0.03 0.04 0.05 0.06 Height (m) Figure 4.5: Calculated energy storage versus height H when inner diameter đˇ and critical current Ic are constant. Optimization of outer diameter of coil Figure 4.6 shows the relationship between height H and E the maximum energy storage in the coil, when the outer diameter of the coil Do is constant and is increased by different values for different curves. For each of these values, the amount of the energy stored was calculated. It should be noted that energy storage increases as the height of the coil increases and outer diameter increases, we note that when decreases outer diameter the energy stored is almost stable, when increases outer diameter the stored energy is becoming a significant increase as shown in figure 4.6. 79 2500000 Do=0.160m Do=0.200m Do=0.240m Energy storage (J) 2000000 Do=0.280m Do=0.320m Do=0.360m 1500000 Do=0.400m Di=0.145m, Ic=12A H=0.008-0.060m 1000000 500000 0 0.00 0.01 0.02 0.03 0.04 0.05 0.06 0.04 0.05 0.06 height (m) 11000000 10000000 Energy storage (J) 9000000 Do=0.160m Do=0.200m Do=0.240m 8000000 Do=0.280m 7000000 Do=0.320m 6000000 Do=0.360m 5000000 4000000 Do=0.400m Di=0.145m, Ic=24A H=0.008-0.060M 3000000 2000000 1000000 0 -1000000 0.00 0.01 0.02 0.03 height (m) 80 50000000 Do=0.160m Do=0.200m 40000000 Do=0.240m Do=0.280m Energy storage (J) Do=0.320m Do=0.360m 30000000 Do=0.400m Di=0.145m, Ic=50A H=0.008-0.060m 20000000 10000000 0 0.00 0.01 0.02 0.03 0.04 0.05 0.06 height (m) Figure 4.6: Calculated energy storage versus height H when outer diameter Do and critical current Ic are constant. Parameters of one desk lamp In specific we calculate that if we have one lamp (40 watts) and need to support this lamp to work for about 10 hours, this means that we need energy of about design a coil to store this energy, the parameters of this coil are given in Table 4.3: 81 J. To Table 4.3. HTS solenoid parameters. Specifications Design @Ic = 12 A Design @Ic = 24 A Design@ Ic = 50 A α 2.75 3.36 1.76 β 0.303 0.168 0.0531 đˇ (m) 0.145 0.119 0.226 đˇ (m) 0.400 0.400 0.400 H (m) 0.044 0.020 0.012 N (turns) 28050 140500 52200 21819.07 22896.7 17101.06 HTS length in each single pancake (m) The model of the solenoid coil used to store the energy for one lamp is presented in Figure 4.6. The parameters of this coil are shown in the Figure, and the length of thin tape conductor (YBCO) can be considered as a stack of pancakes; however, for each single pancake, the length of tape conductor can be calculated from Equation (4.2). In this case the length of YBCO thin tape in each single pancake đ turns in each pancakes coil can be determined from Equation (4.1) to be the number of pancake layers is from Equation (4.7). 82 the number of and đˇ =0.400m đˇ =0.145m H=0.044m Figure 4.7: Model of coil used to stored energy for one lamp. From the above results, for the specific desired stored energy (1.44 J) occurs when the inner diameter of the coil Di=0.145 m. The energy at this inner diameter can be compared with the energy when the height of the coil is 0.044m, through graphing the relationship between size ratio β and the energy stored (E). We note that when the inner diameter of the coil is fixed, the amount of energy stored in the coil is increasing when β increases (Figure 4.8(a)). We also note that when the height of the coil fixed, the amount of energy stored is increasing (Figure 4.8(b)). To design solenoid coil that stores a large amount of energy, we need to have a small inner diameter, a large coil height and a large outer diameter. Increasing the height of the coil leads to increase in the number of pancake layers, the number of turns in each pancake coil and the length of the tape, because the length of the tape depends on the number of pancake layers when the inner and outer diameter are fixed: 83 đ Length of the tape= 2500000 Energy storage (J) 2000000 Di=0.145m, Do=0.400m H=0.008-0.060m, Ic=12A 1500000 1000000 500000 0 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 ď˘ď˝H/Di (a) Di constant 1800000 Energy storage (J) 1600000 1400000 1200000 1000000 800000 600000 Di=0.060-0.360m 400000 Do=0.400m, Ic=12A 200000 H=0.044m 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 ď˘=Do/Di (b) H constant Figure 4.8: Relationship between β and energy storage. 84 It can be concluded that the energy is stored to a maximum value when a height of the coil is large. In the case of a coil where the coil height which is associated with the maximum stored energy given the fixed parameters or the length of the coil required for the specific energy storage has been determined, further increasing the height of the coil would lead to increased energy storage. This is because the relationship between the height of coil (H) and size ratio β is a positive relationship, and the relationship between the inner diameter (Di) and size ratios α and β an inverse relationship. The relationship between the critical current and size ratio α is an inverse relationship and depends on the amount of current flowing through the coil. When more current is applied, it reduces the size ratio and increases the energy storage. 4.5 Summary In conclusion, second-generation high temperature superconducting (2G HTS) wire made from YBCO coated conductor has great potential for commercialization and utilization as an engineering conductor for many real world applications. This study presents the design of a solenoid YBCO pancake coil; this design gives the maximum stored energy in the coil. We have calculated this energy through using the energy storage equation, after determining the parameters of this coil, such as, outer and inner diameters of the coil, height of the stack of pancakes, and number of turns of the coil, by calculating the number of pancake layers and the number of the turns in each pancake, along with the maximum inductance of the coil. Also, the critical current 85 flowing through the coil was calculated by determining the critical current density and parameters of the tape width and thickness. In this thesis, this design for a pancake coil is capable of storing energy of about 1.4 MJ, and this energy is sufficient to power one desk lamp (40 watts) working for about 10 hours straight. The parameters of this coil are as follows: outer diameter (Do) = 0.400 m, inner diameter (Di) = 0.145 m, height of stack of pancake (H) = 0.044 m, number of turns of solenoid (N) = 280500, number of turns in each pancake = 25500, number of pancake layers = 11 For an HTS solenoid for energy storage purposes, the method of design optimization is to obtain the maximum energy storage for a given length of superconductor. In this case the length of tape in each single pancake was about 21819.07 m, and the critical current at 77 K, self- field was 12 A. When designing an optimization solenoid coil to store a large amount of energy, this energy will depends on critical current and inductance. If the critical current value is selected and installed, thus, the value of the energy stored depends on the inductance, which depends on the parameters of the solenoid coil. Figure 4.2(b) shown the best α range for this optimization is probably somewhere between 1.5-3, the energy stored at these values are increasing , after that the energy begins to stabilize and any increase in any parameters do not have a significant impact in the energy levels. Also, if Do and Di are decreasing, while H is increasing, there would be optimal values for H and Do and Di providing the highest stored energy as shown in figure 4.5 and 4.6 respectively. When the value of Do and Di are small, the amount of energy stored in the coil remains the same. Therefore, the optimal values for H are between 0.020 m and 0.060m. Also, in figure 4.8 the best β range for this optimization is between 0.15 and 0.40. 86 Future work includes testing this coil at liquid nitrogen temperature, in addition to studying the cooling system (refrigeration) and cost efficiency of this system. 87 Chapter 5 Conclusion. Smaller HTS SMES have been found to be successful in meeting specific applications in several areas such as ground based power supply sources in difficult areas such as the Arctic for air force applications, etc. Also, the cost of these SMES systems has been drastically pulled down by using applications such as liquid nitrogen based refrigeration systems rather than expensive helium based refrigerator systems. They are now available in smaller sizes such as 1 kWh to 1 MWh and are successfully being used. This thesis presents a SMES solenoid coil which has been designed for a closed system. The design gives the maximum stored energy in the coil, which has been wound from a certain length of second-generation high-temperature superconductor (2GHTS) YBCO coated conductor. Design optimization for the solenoid constructed from HTS thin film can be achieved theoretically. A solenoid pancake coil offers the maximum inductance for a given length of HTS. The energy storage of a solenoid constructed a given length of HTS can also be maximized by choosing the proper size ratios. The dimensional outcome, however, will depend on the critical current performance of the HTS in external magnetic field at the operation temperature. For some HTS operating at certain temperatures, the optimal design could be impractical, and a compromise solution can be found by balancing various practical factors. SMESs, which are a non-negligible force in national economic development, are now smaller in size and more flexible in form, and can rapidly respond to market changes to meet the ever-growing and diversified social consumption demands, while promoting the coordination of large-scale social production based on specialization. Moreover, SMESs 88 could drive the high-speed development of municipal economies and play a unique role in creating jobs, invigorating markets, improving people's lives, and maintaining social stability. 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