PCB Surface Treatments Definition of surface finish A surface finish can be defined as a coating, g, either metallic or organic g in nature, which is applied to a PCB in order to assure solderability of the metal underneath after various time of storage / conditions. paste or wave Most of the surface treatment dissolves into the solder p solder during the soldering process and the solder joint is forming between the solder and the copper. p is ENIG / Immersion Gold where the solder dissolves the One exception thin layer of gold and forms a joint with the underlying nickel phosphorous alloy. Definition of surface finish There are actually only two different types of surface finishes for PCB. Below is the most common on the market market. Organic Metals • • • • • • • • OSP HASL (leaded and lead-free) Immersion Sn Immersion Ag ENIG ENEPIG ASIG ENEG Definition of surface finish OSP is more like a lacquer, q that p prohibits oxygen yg attacking g the copper pp underneath. All other are coating are metals and they may be applied using one of two different methods = either electroless or immersion. There is a big g difference between these two p processes for metallic coatings and it is important to be aware of these differences as we discuss finishes. Definition of surface finish Electroless or Autocatalytic systems, both work in the same fashion in that they use an reducing agent inside the bath itself. This means that Thi th t the th metal t l thickness thi k increases during the whole period that the PCB is in contact with the solution. Electroless process Ni2+ eReducing Agent Ni2+ Ni2+ Ni2+ Ni Ni Ni Ni Nickel in ENIG Silver Sil iin ASIG or ESM100 Gold in Electroless gold Reducing Agent e- Ni2+ e- e- Ni2+ Cu Ni Cu Ni Cu Ni Cu Ni Cu Ni Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu Definition of surface finish Immersion systems, This process uses a chemical displacement reaction to deposit a metal layer onto the exposed metal surface of the PCB. The base metal donates the electrons that reduce the positively charged metal ions present in solution. Immersion layer will continue to grow, however as the thickness of deposit increases the rate of deposition falls increases, falls. Therefore the process is self-limiting. Tin in Immersion Tin Silver in Immersion Ag Gold in ENIG ENIG Gold bath + Au Ni3+ + Au Ni3+ + Au Ni3+ + Au Ni3+ Au Ni Au Ni Au Ni Au Ni Au Ni Ni Ni Ni Ni Ni Cu Ni Cu Ni Cu Ni Cu Ni Cu Ni Cu Cu Cu Cu Cu Cu Cu Cu Cu Cu + Au Ni3+ General recommendation Handling g/ Storage condition / Time A. Handling Recommendations: It is recommended that gloves are used for handling panels/circuits during all assembly processes. Or O att the th VERY least, l t handle h dl the th boards without touching the surfaces. Salts/acids from fingerprints will have a negative affect on the solderability. solderability B. Storage condition and time The storage environment should not to exceed 30C and 75% RH (except immersion tin). Boards should be stored in original vacuum packaging to g the surface, and the board. limit air accessing General recommendation Baking g C. Baking Recommendations: Th purpose with The ith baking b ki iis tto reduce d th the risk i k off out-gassing, t i measling li or delamination, by eliminating moisture or solvents within the laminate structure/board prior to soldering. Temperature and time of baking is to be determined on an individual basis. The time between baking and solderability testing should be kept to a minimum (not more than 24 hours) in order to prevent re-absorption of moisture into the laminate structure. Baking should be kept to a minimum, adhering to the production procedure, to prevent excessive oxidation and intermetallic growth. General recommendation Baking g D. Baking Recommendations given by NCAB Baking can be advantageous and may be employed before any type of soldering operation. The recommended conditions are 120oC for 2 hours Oven conditions Baking needs to take place in clean oven to prevent any form of contamination during the baking process. The boards should also be placed in the oven in such a way that the air can circulate freely around the boards during the baking time time. All baking can be considered as advanced ageing and therefore may affect the solderability negatively. As such the time and temperature referenced above must be seen only y as recommendations – the customer must take responsibility to approve processes. http://www.ncab-pcb.com/pub/1332/Baking%20Flex_rigida%20kort%202.pdf HASL ((Hot Air Solder Level)) Lead-Free Typical Thickness: 1-40µm ADVANTAGES DISADVANTAGES + “Nothing Solders Like Solder” - Huge Co-Planarity Difference + Easily Applied - Not Suited for High Aspect Ratios + Long Industry Experience - Not Suited for < 20 Mil pitch SMT and BGA + Easily Reworked - PWB Dimensional Stability Issues + Multiple Thermal Excursions - Bridging Problems on Fine Pitch Assemblies + Good Bond Strength + Long Shelf Life + Easy Visual Inspection + Low Cost - Inconsistent Coating Thicknesses - High Process Temperature 260-270 deg C - Not Suitable For HDI Products Short p process description p HASL (Leaded and Lead-Free) micro-etch—overflow rinsing—clean water rinsing—blowing— flux coating—hot air solder leveling—cooling—hot water rinsing—soft brush scrubbing scrubbing—DI DI water rinsing—strong rinsing strong air blowing—hot blowing hot air drying Storage g condition / time / handling g HASL (Leaded and Lead-Free) HASL is the most robust of all treatments if applied under correct conditions, however there are still reasons to be careful: A. Handling g Recommendations Whilst the surface treatment is rather robust, general recommendations should be followed. B. Storage condition and time General recommendations must be followed. If nothing else is specified, specified IPC6012 sets the storage time according to JST-STD-003 Category 2 in other words a coating durability up to 6 months, NCAB recommends the category is set to JST-STD-003 Category 3 (6 months+) Baking g / Temporary p y masking g HASL (Leaded and Lead-Free) C. Baking. C B ki HASL can withstand baking with maintains its solderability well as long as the deposit is not too thin. See general recommendations for baking recommendations. recommendations D. Temporary masking / Peelable mask Since the HASL treatment is a rather robust treatment and not so sensible to contamination, nearly all types of maskings (such as Peelable mask, Kapton tape etc.) are acceptable. Available standards and test methods HASL (Leaded and Lead-Free) IPC-6012 IPC 6012 “Coverage & solderable”. The coating durability category shall be specified on the master drawing according to J-STD-003, if the category is not specified the category shall be set to class 2 2. J-STD-003 There are 5+5 5 5 difference methods described as t0 how to test the solderability of the PCB. The two listed below are the most common if nothing else is specified A – Edge Dip Test (3sec dwell time) C – Solder Float Test (5sec floating time) Leaded solder - Sn60/Pb40 - 235±5° C Lead-free f solder - SAC305 S C - 255±5°° C Design aspects HASL (Leaded and Lead-Free) There are not so many design concerns for this surface treatment. A. Small pitches QFP < 0.50mm & BGA < 0.80mm On very small pitch the co-planarity will become an issue and it will be difficult to assemble due to surplus of solder on the tiny SMD features. B. HFFR4 & High Tg FR4 coated with lead-free HASL. We have, from NCAB point of view, seen a problem with increased cases off measling li and d copper peeling li on hi high h copper thi thicknesses k (≥3Oz) and the possible root cause is low peel strength of the foil for such materials, also the CTE difference between copper and substrate and finally the temperature shock as a result of the HASL process itself itself. Design aspects HASL (Leaded and Lead-Free) There is not so much design concerns about this surface treatment. C. Solder balls. Holes plugged from only one side (partially plugged) with soldermask can entrap solder that the air-knives cannot remove from the surface (f (force it into i t the th partially ti ll plugged l dh hole). l ) Th These solder ld b balls ll may b become dislodged and re-deposit onto the surface during the reflow operations D. Edge plating on thick boards D We have experienced issues on thicker boards with edge plating, where the edge plating has been found to become loose after the lead-free HASL process. Quality aspects HASL (Leaded and Lead-Free) With lead-free ead ee solder so de ,qua ,qualityy control co o is s more o e ccritical ca that a with traditional ad o a SnPb HASL. A. Control the alloy. It is critical to have good control over the alloy so all elements are within limits, the new Pb-F alloys dissolve more copper from the boards. B. U B Use good d fl flux. Many of the low cost fluxes struggle with the heat and may perform badly. C. Maintenance on machinery C The Pb-F HASL’s are more challenging to wet on the surface and are also much more easily to ‘blow off’ during processing so that thin layers provide insufficient pure tin and limits storage time and solder cycles OSP (Organic Solderability Preservative) Typical Thickness: 0.15-0.30µm ADVANTAGES DISADVANTAGES + Flat, Coplanar pads - Difficult to Inspect + Reworkable (at PCB Fabricator) - Question Remains Over Reliability of + Doesn’t D ’t Affect Aff t Finished Fi i h d Hole H l Si Size E Exposed dC Copper Aft After Assembly A bl + Short, Easy Process - Limited Thermal Cycles + Low Cost - Can not be Reworked at EMS/OEM; Sensitive to Solvent Used for Misprint Cleaning + Good Soldermask Integrity + Environmental friendly + Clean process - Limited Shelf life - Easy to scratch Short process description OSP (Organic Solderability Preservative) OSP is thin layer of either Benzimidazole or imidazole lacquer lacquer. Degrease—overflow rinsing—micro-etch—overflow DI rinsing-OSP—DI rinsing—strong air blowing--hot air drying Storage g condition / time / handling g OSP (Organic Solderability Preservative) Since OSP is a rather thin organic and sensitive deposit deposit, these recommendations should be followed. A. Handling Recommendations: Since the deposited layer is so thin and soft, it is important to handle the boards with care. B. S B Storage condition di i and d time i General recommendation needs to be followed. If nothing else is specified, IPC6012 sets the storage time according to JST-STD-003 JST STD 003 Category 2 in other words a coating durability up to 6 months, NCAB recommends the category is set to JSTSTD-003 Category 3 (6 months+) Baking / Temporary masking / Others OSP (Organic Solderability Preservative) C. Baking. Baking with OSP will have a negative effect on the solderability. So the customer custo e must ust e evaluate a uate the t e baking ba g p process. ocess D. Temporary masking / Peelable mask It is not recommended to use peelable mask on OSP treatment since the chemicals inside these masking material will/can a negative effect on the solderability. E. Cl E Cleaning i off Misprinted Mi i t d Solder S ld Paste P t The OSP coating is soluble to varying degrees in most solvents, acidic materials. Any solvent used to clean solder paste will dissolve some OSP E. Process time The time between first and last soldering should be as short as possible, preferable within 8-12 hours. Available standards and test methods OSP (Organic (O i Solderability S ld bilit Preservative) P ti ) We have same lack of a available standards as for HASL IPC-6012 “Coverage & solderable”. The coating durability category shall be specified on the master drawing according to J-STD-003, if the category is not specified ifi d the h category shall h ll be b set to class l 2 2. J-STD-003 There are 5+5 difference methods described as to how to test the solderability of the PCB. The two listed below are the most common if nothing else is specified A – Edge Dip Test (3sec dwell time) C – Solder Float Test (5sec floating time) Leaded solder - Sn60/Pb40 - 235±5° C Lead-free solder - SAC305 - 255±5° C Design aspects OSP (Organic Solderability Preservative) There are some design concerns about OSP as a surface treatment. A. ICT test points It can become on issue that there is problems for test pins to penetrate the rather thin but hard layer y of OSP and get g connection with the test p points. But there have been a lot of studies about this and the problem can be overcome with correct test pins and pressure. B. Single sided plugged holes close to SMD pads. There is a big risk the chemistry get trapped in these hole and contaminate the surface. C. Multiple solder operations. Even if OSP can handle multiple solder operations, the surface finish have it limitations and solderability can become on issue issue. Immersion Sn ((Immersion Tin)) Typical Thickness: 1.00-1.20μm ADVANTAGES DISADVANTAGES + Soldering direct to copper - Handling Concerns + Good for Fine Pitch Product - Contains Thiourea, Which Is + Good Solderability Carcinogenic + Planar Surface - Difficult To Rework + Eliminates Nickel - Growth G th off Intermetallic I t t lli Concerns C + Mid Expensive - Whiskers concerns + Popular for press fit / backplanes - Aggressive gg against g soldermask Short p process description p Immersion Tin degrease overflow rinsing—micro-etch—overflow degrease—overflow rinsing micro etch overflow DI rinsing—pre-dip— rinsing pre dip immersion Sn—post-dip—alkali rinsing—double DI rinsing—hot air rinsing—drying board Storage condition / time / handling Immersion Tin Immersion Tin is excellent surface treatment, but also rather sensitive so extra concern need to be addressed at the handling A. Handling Recommendations: It is i important i t t that th t gloves l are used d ffor allll assembly bl steps. t B. Washing of boards. No washing is recommended either prior to / between any soldering step step. C. Storage condition and time The storage environment should not to exceed 25C 25 C and 50% RH. Baking g / Temporary p y masking g Immersion Tin Immersion Tin is excellent surface treatment treatment, but also rather sensible so extra concern need to be addressed at the handling D. Baking. Baking before soldering will have a negative effect on the solderability and also ‘consumes’ storage time since baking will trigger the growth of th IMC between the b t the th tin ti and d copper – reducing d i usable tin. E. Temporary masking / Peel able mask E It is not recommended to use peelable mask on Immersion Tin, since it is an immersion surface with a porous structure, structure all masking can easily lead to contamination. Available standards and test methods Immersion Tin There are available Th il bl standards t d d that th t define d fi both b th th the thi thickness, k appearance and performance of immersion tin. A. IPC IPC-6012 6012 “Solderable”. IPC-6012 has not been updated yet with the reference to IPC-4554. B. IPC-4554 A complete spec for the finishes with clear demand on the thickness, performance and appearance. For solderability test it refers to J-STD-003 C. J-STD-003 Defines how the solderability test should be performed. Available standards and test methods Immersion Tin IPC-4554 Key point from the standard standard. A. Thickness Minimum 1µm measured with XRF Min 0.4µm of usable tin for Category 1 boards Min 0.5µm 0 5µm of usable tin for Category 2 boards Min 0.6µm of usable tin for Category 3 boards B. Visual Uniform plating and complete coverage of surface to be plated. Key y points p with Immersion Tin Immersion Tin Thickness is the number one factor when it comes to being able to provide a good soldering result. The finish always requires at least 0.2µm fresh tin on top of the IMC layer. Topography of IMC after aging Key y points p with Immersion Tin Immersion Tin The graph shows how much fresh tin remains after 3 reflow cycles and also after accelerated aging. Quality aspects Immersion Tin As mentioned the thickness in number one to have a good working finish that can withstand multiple p soldering g operation. p A. Control the IMC layer. It is important for the supplier, to have control over there process so the IMC layer is as thin as possibly when they dispatch the boards. B. Use good chemistry. There are many bad vendors of immersion tin chemistry, so it wise to approve famous brands (Atotech, Enthone etc) C. Specify the thickness or refer to IPC C IPC-4554 4554 Since the immersion tin is the most aggressive of all available finishes, many Asian factories only deposit around 0.7-0.8µm as standard because some soldermask can not withstand any thicker deposit deposit, due to undercut problem (see right hand image) Design g aspects p Immersion Tin Th There are some design d i concerns about b t this thi surface f ttreatment. t t A. Contamination Since this treatment is very sensitive to contamination, holes plugged from one side (partially plugged) are not recommended. See right g hand image. g Also holes very close to SMD pads are not recommended, since the plating solution will be trapped inside and can contaminate and destroy the solderability. Design g aspects p Immersion Tin Th There are some design d i concerns about b t this thi surface f ttreatment. t t B. Soldermask bridges between SMD pads. pads Since this treatment is very aggressive to the soldermask, there is need for larger soldermask bridges. Normally we can produce 3-4mil bridges. But with immersion tin 5mil is the minimum required. DFM Soldermask openings I Sn There is an risk that via holes close to SMD pads will become partially exposed during production. This will lead to two issues: 1.Solder paste ‘escaping’ into the via hole during soldering. 2. Chemistry becomes trapped i id the inside h via i h hole l d during i production and it can lead to corrosion and contaminations problems. problems Immersion Ag (Immersion Silver) Typical Thickness: 0.05-0.40μm 0 05-0 40μm ADVANTAGES DISADVANTAGES + Good for Fine Pitch Product - Some systems cannot throw Into + Planar Surface + Inexpensive + Short, Easy Process Cycle + Eliminates Nickel + Doesn’t D ’t Aff Affectt Hole H l Size Si + Medium Shelf-Life + Can be reworked/Re-Applied by the PCB Fabricator µvias with aspect ratios > 1:1 - Tarnishing must be controlled Short p process description p Immersion Ag (Immersion Silver) degrease—overflow rinsing—micro-etch—overflow DI rinsing—pre-dip— immersion Ag—DI rinsing—strong air blowing--hot air drying Storage g condition / time / handling g Immersion Ag (Immersion Silver) Immersion silver, is an immersion finish and also rather sensitive to contamination. Silver is also sensitive to sulphur and chlorides A. Handling Recommendations: It is important that gloves is used for all assembly steps. B. Process time Immersion silver finish also contains OSP inside that works to prohibit tarnishing, and since this is consumed during g the first reflow cycle, it is therefore important to keep the cycle time as short as possible, 8-12 hours. To prevent or limit tarnishing Storage g condition / time / handling g Immersion Ag (Immersion Silver) C. Storage condition and time C 1. Immersion silver boards should be packaged as soon as possible, to prevent exposure to chlorides and sulfides in the air. 2. Use sulfur free, pH neutral paper to wrap stacks and then plastic wrap. Storage should be in sealed bags to eliminate direct contact with air. 3. Adhesive tape / labels, stamps, markers and rubber bands are forbidden on silver boards. 4 If the 4. th original i i l package k iis opened d and d nott allll of the boards consumed at the EMS/OEM during the build, they should be re-wrapped as soon as possible possible. Storage g condition / time / handling g Immersion Ag (Immersion Silver) C. Storage condition and time General recommendation needs to be followed. If nothing else is specified, IPC6012 sets the storage time according to JST-STD-003 Category 2 in other words a coating durability up to 6 months, NCAB recommends the category is set to JST-STD003 Category 3 (6 months+) Baking / Temporary masking Immersion Ag (Immersion Silver) Immersion Silver is sensitive treatment and it recommended to be careful when it comes to baking. D. Baking. Baking always is recommended before soldering soldering, but on silver boards this can have a negative effect on the solderability. As stated, within the immersion silver formulation there is also a mix of OSP to prohibit tarnishing. g So the EMS/OEM customer must approve pp any y baking gp process so solderability is not destroyed. NCAB have carried out practical tests and can achieve good solderability after baking – but care must be taken here. E. Temporary masking / Peel able mask It is not recommended to use peelable mask on Immersion silver product as allll masking ki can easily il llead d tto contamination. t i ti Available standards and test methods I Immersion i Silver Sil There are available standard that define both the thickness, appearance and performance of immersion silver A. IPC-6012 “Solderable”. The IPC-6012 amendment 1 is referring to spec IPC-4553 for th performance the f off immersion i i silver il B. IPC-4553 A complete p specification p with clear demands on thickness,, p performance and appearance. For solderability test it refers to J-STD-003 IMMERSION SILVER DEPOSIT The minimum thickness shall be 0 0.12 12 μm with a maximum of 0 0.4um 4um C. J-STD-003 Defines how the solderability test should be performed. Design g aspects p Immersion Silver There are some design aspects that should be considered for silver silver. A. Contamination As with immersion tin, the treatment is very sensitive / susceptible to contamination. Via holes plugged from one side (partially plugged) are not recommended. Also via holes very close to SMD pads are not recommended, since the plating solution may become ‘trapped’ ‘ inside the hole and potentially contaminate or destroy the solderability. ENIG (Electroless Nickel/Immersion Gold) Typical Thickness: 3-6µm 3 6µm Ni / 0.050 05 0.125μm Au ADVANTAGES DISADVANTAGES + Planar Surface - Expensive + Consistent Thicknesses - Black Pad Issues on BGA + Multiple Thermal Cycles - Waste Treatment of Nickel + Long Shelf Life - Cannot be Reworked at PCB Fabricator + Solders Easily - Not Optimal for Higher Speed Signals + Good for Fine Pitch Product - Complex process requires good control + Al Wire-Bondable - Not soldering direct onto surface copper Short process description Electroless Nickel Immersion Gold degrease—double rinsing—micro etching—overflow rinsing—DI rinsing— pre-dip—Pd activation—double DI rinsing—immersion Nickel—double DI rinsing—immersion Au—double DI rinsing—drying board Storage g condition / time / handling g Electroless Nickel Immersion Gold Electroless Nickel Immersion Gold is an excellent surface treatment and also rather robust against treatment/handling A. Handling g Recommendations: The surface treatment is rather robust, but general recommendations should always be followed. B. Storage condition and time General recommendation needs to be followed. If nothing thi else l is i specified, ifi d IPC6012 sets t the th storage t time ti according di to JST-STD-003 Category 2 in other words a coating durability up to 6 months, NCAB recommends the category is set to JST-STD003 Category 3 (6 months+) Baking g / Temporary p y masking g Electroless Nickel Immersion Gold C. Baking. ENIG can withstand baking whilst maintaining solderability. See general recommendation for details. D. Temporary masking / Peelable mask Since the ENIG treatment is a rather robust treatment and not so sensitive/susceptible iti / tibl tto contamination, t i ti nearly l allll ttypes off maskings ki are acceptable - such as Peelable soldermask, Kapton tape, etc. Available standards and test methods Electroless Nickel Immersion Gold There are available standard that define both the thickness thickness, appearance and performance of Electroless Nickel Immersion Gold A. IPC-6012 R f tto IPC-4552 Refer IPC 4552 for f the th demands. d d Th The coating ti d durability bilit category t shall h ll be specified on the master drawing according to J-STD-003, if the category is not specified the category shall be set to class 2. B. IPC 4552 A complete spec for the finishes with clear demand on the thickness, performance and appearance. For solderability test it refers to J J-STDSTD 003 C. J-STD-003 Defines how the solderability test should be performed and judged. Available standards and test methods Electroless Nickel Immersion Gold IPC-4552 K point Key i t ffrom the th standard: t d d A. Thickness Minimum 2,54µm 2 54µm Nickel (100µ (100µ”)) measured with XRF Minimum 0,05µm Gold (2µ”) measured with XRF B. Visual Uniform plating g and complete coverage g of surface to be plated. Design aspects Electroless Nickel Immersion Gold There are rather few design concerns associated wit ENIG, however: A. Soldermask defined BGA pad Soldermask defined BGA pads should be avoided, due to the risk of brittle joint and also the risk of black pads since the chemistry has less possibility to be rinsed, especially on smaller BGA pads pads. See graphic graphic. B. Single sided plugged via holes. As with most finishes finishes, via holes plugged from one side (partially plugged) are not recommended. Also holes very close to SMD pads are not recommended, since the plating solution can become ‘trapped’ inside and may contaminate or reduce the solderability solderability. PCB C. Soldermask bridges between SMD pads. As with immersion tin, this treatment is aggressive towards the soldermask, therefore larger soldermask bridges may be necessary with some factories factories. Quality aspects El Electroless l Nickel Ni k l Immersion I i Gold G ld There are two quality aspects that are worth highlighting: A. Black Pad. This is the result of a lack of balance within the ENIG plating chemistry. In principle it is either caused by a too aggressive immersion gold deposition process OR an overly active nickel surface. Whatever the cause, the result is overetching of the nickel (uncontrolled gold immersion reaction) which leads to an enrichment of phosphorus in the upper most Ni layer layer. Since the gold immersion reaction makes the Ni atoms go into solution it leaves the P atoms on the surface. B. Brittle fractures. Recent studies have shown that brittle solder-joints may form on an ENIG surface even if there is no black pad defect. The brittle fractures occurs in the Inter Metallic Compound (IMC) that is formed when soldering against Ni.