Engineering 1 : Photovoltaic System Design What do you need to learn about? Gil Masters Terman 390 … but leaving town tonight feel free to email me anytime: gmasters@stanford.edu I. Very quick electricity review II. Photovoltaic systems III. PV technology IV. The solar resource V. Batteries VI. Load analysis I’m here to help... VII. PV Sizing VIII. Battery Sizing … all in one class !! ?? !! December 2, 2003 I. BASIC ELECTRICAL QUANTITIES Electric Charge q (Coulombs) 1 electron = 1.602 x10-19 C POWER Watts = P= Current ei + Voltage i ( Amps) = 1 Coulomb second Time (sec) dW dW dq = ⋅ dt dq dt Power is a RATE !! P=vi charge/time = current energy/charge =volts ENERGY ENERGY = POWER X TIME (watt-hrs, kilowatt-hours) “the push” energy W V= charge q watts dq …is the flow of charges i = dt Energy (W,joules) Watt hours = volts x amps x hours = volts x (amp-hours) 1 Joule 1 Volt = Coulomb Batteries ! 1 II. PV SYSTEM TYPES: 1. 2. GRID-CONNECTED PV SYSTEMS: • Simple, reliable, no batteries (usually), • ≈ $ 15,000 (less tax credits), A=200 ft2 for efficient house • Sell electricity to the grid during the day (meter runs backwards), buy it back at night. * Sizing is simple… how much can you afford? • But compete with “cheap” 10¢/kWh utility grid power A FULL-BLOWN HYBRID STAND-ALONE SYSTEM WITH BACKUP ENGINE-GENERATOR (“Gen-Set”) ….Not what you will design DC DC DC loads DC Fuse Box DC Batteries Charge Controller ..may want all DC, all AC, or mix of AC/DC DC PVs Generator Charger AC to DC AC Inverter DC to AC AC AC loads AC Fuse Box AC DC Power Conditioning Unit Inverter/Charger DC-to-AC to run AC loads some can do AC-to-DC to charge batteries Utility Grid AC PVs Complex, expensive, requires maintenance, tricky to design But… competes against $10,000/mile grid extension to your house or 40¢/kWh noisy, balky, fuel-dependent on-site generator …NOT what you are going to design TRADE-OFF BETWEEN DC AND AC SYSTEMS: 3. SIMPLER STAND-ALONE SYSTEMS: + - DC ALL DC Battery 3000 Wh/d = 3530 Wh/ d 0.85 ALL AC DC DC Batteries DC Inverter Example: h=0.85 DC Loads + Charge Controller DC Batteries DC Inverter AC (including a 1200 Wh/d AC fridge) INVERTER FOR AC AC 3000 Wh/d AC AC/DC DC DC Charge Controller Charge Controller DC DC Batteries Batteries DC DC Inverter Inverter AC DC ..YOU’LL DESIGN ONE OF THESE ! CHARGE CONTROLLER TO PROTECT BATTERIES AC DC Loads SOME AC, SOME DC (e.g. fridge) ..avoids some inverter losses ..smaller inverter saves $ ..but more $ for DC fridge ..but need AC and DC wiring, $ OR…Buy a more expensive, very efficient DC refrigerator that uses say 800 Wh/d instead of the 1200 Wh/d for an AC fridge 1800 Wh / d + 800 Wh/ d = 2920 Wh/d 0.85 0.85 DC Charge Controller DC Batteries DC Inverter AC DC Cheaper PVs, battery, inverter 1800 Wh/d AC 800 Wh/d DC More expensive fridge More expensive wiring 2 III. MOST SOLAR CELLS ARE MADE FROM SILICON.. PHOTOVOLTAIC TECHNOLOGY SO, HOW DO WE COLLECT SOLAR ENERGY? VALENCE valence ELECTRONS electrons +4 +4 +14 +14 (a) actual (a) actual QUARTZ TO SILICON… Si is ≈ 20% of the earth’s crust, usually as SiO2 ..an energy intensive process using an arc furnace converts it to pure silicon (b) simplified (b) simplified CZOCHRALSKI METHOD OF FORMING CRYSTALLINE WAFERS.. MELT the pure Si (1400 C) in a quartz crucible.. DIP, then withdraw, a “seed crystal” turning continuously so that each atom freezes in place in the crystal.. GET a cylindrical ingot (perhaps 1 m long, 20 cm diameter) Rock-like hunks of 99.9999% pure silicon.. SLICE the cylinder into wafers…. (same as integrated circuits) 3 IF A PHOTON HAS “ENOUGH” ENERGY, IT CAN BUMP AN ELECTRON INTO THE CONDUCTION BAND..leaving a positively charged “hole” behind CRYSTALLINE SILICON FORMS A TETRAHEDRAL STRUCTURE… Hole + silicon nucleus +4 +4 +4 +4 +4 +4 Free electron shared valence electrons tetrahedral a) (a) Tetrahedral Photon +4 Si (b) 2-D version b) 2-D version Max efficiency ≈ 50% Photons with TOO MUCH energy (l < 1.11 mm) waste 30.2% Photons with TOO LITTLE energy (l > 1.11 mm) lose another 20.2% SEPARATE HOLES AND ELECTRONS USING THE ELECTRIC FIELD CREATED IN A p-n JUNCTION Produces Direct Current (dc) Electrical contacts on top p-n junction creates an E electric field CELLS, MODULES AND ARRAYS... ARRAY wired in series and parallel for voltage and power Single CELL ≈ 0.5 V electrons - - - - n-type V + + + + p-type Load 5” - 8” diameter + MODULE, typically “12-V or 24V” Rated by peakwatts (e.g. 53 W) (≈ 1 m x 0.5 m) 36 cells wired in series Bottom contact Current I Trim edges 4 LOTS OF PHOTOVOLTAIC TECHNOLOGIES…. Thick Si 200 - 500 mm Multicrystalline Si 30% Homojunction CdTe CIS Example: AstroPower 7105: PR = 75W, IR =4.4A, VR = 17.0V, Isc = 4.8A, Voc = 21.0V Polycrystalline thin-film Si Amorphous Si 20% Ribbon Flat-plate 50% Short circuit current, Isc Open circuit voltage, Voc Current at “rated conditions” IR Voltage at maximum power point (rated voltage) VR Rated power (@1 kW/m2 solar insolation, 25oC cell temperature, at max pwr pt) PR Thin films 1 - 10 mm Heterojunction Single-crystal Si Czochralski CZ Manufacturer specification of photovoltaic module: PHOTOVOLTAICS Concentrator 4 GaAs InP 1 kW/m2 insolation (“1-sun”) 4.8A Maximum power point 4.4A x 17V = 75W 4.4A 3 Multijunction, Tandem cells I (amps) 2 2.4A 0.5 kW/m2 insolation 1/2 sun 1 12.7% 6.3% 0 0 IV. THE SOLAR RESOURCE…. kWh/ m2-day of insOlation * * * * Location Orientation of modules (due south generally best for U.S.) Tilt angle Fixed orientation vs 1-axis tracking vs 2-axis tracking 10 V (volts) 17.0 20 21.0 V THE KEY TRICK TO INTERPRETING INSOLATION DATA… “mid-day, clear day, normal to rays” “1-SUN” OF INSOLATION IS DEFINED TO BE 1 kW/m2 Summer Spring, Fall Winter tilt south AVERAGE DAILY INSOLATION EXPRESSED IN (KWh/m2-day) CAN BE INTERPRETED TO MEAN HOURS OF FULL SUN e.g. Boulder, CO in June, collector tilt = latitude sees 6.1 kWh/m2 of insolation “that’s like 6.1 hours/day of 1 kW/m2 “full sun” Tilt = Latitude gives perpendicular angle to sun at equinoxes at noon 5 GOOD SOURCE OF REAL DATA… SINGLE-AXIS TRACKER (East to West) kWh/m2 -day 1-axis tracker, tilt = lat Zomeworks: Passive single-axis tracker… on the roof since 1977 … IS IT WORTH THE EXTRA COST? INSOLATION IN BOULDER, CO.. 9 1-Axis Tracking (Annual 7.2 kWh/m2-d) INSOLATION (kWh/m2-day) 8 Lat - 15 (5.4 kWh) 7 6 Lat (5.5 kWh) 5 Lat + 15 (5.3 kWh) 4 3 2 1 0 JAN 2-AXIS TRACKER….. Not much better than 1-axis FEB MAR APR MAY JUN JLY AUG SEP OCT NOV DEC 30% extra insolation with 1-axis tracker (annual) 6 V. ENERGY STORAGE… Basic lead-acid battery... BATTERIES COMPRESSED AIR HYDROGEN FLYWHEELS, etc One Cell ≈ nominal 2 V 6-cells, “12-V battery” + CHARGED - + H+ Pb PbSO4 FOR NOW.. BATTERIES ARE IT.. Lead-Acid car batteries (SLI =Starter, Lighting, Ignition system)_ Designed for high current (400-600A), shallow discharge (20%), not so good for PV PbO 2 Lead-Acid “golf-cart” deep-cycle batteries… often used due to low cost, satisfactory performance H + = SO 4 DISCHARGED - PbSO4 H 2O True Deep-Cycle Lead-Acid batteries… very good, but expensive Nickel-Cadmium batteries… very expensive, great for very cold, harsh conditions, can take abuse Battery Lead-acid, SLI Lead-acid, golf cart Lead-acid, deep-cycle Nickel-cadmium Nickel-metal hydride Max Depth Discharge 20% 80% 80% 100% 100% Energy Density Wh/kg 50 45 35 20 50 Cycle life Calendar life cycles years 500 1-2 1000 3-5 2000 7-10 1000-2000 10-15 1000-2000 8-10 Efficiencies Ah % Wh % 90 75 90 75 90 75 70 60 70 65 Cost $/kWh 50 60 100 1000 1200 Rough comparison of battery characteristics Voltage can be used… (but battery needs to have been “at rest” for several hours to be accurate) 13.0 1.30 12.8 1.28 VOLTAGE (V) 1.22 12.0 1.20 SG 1.18 11.6 1.16 11.4 1.14 11.2 1.12 11.0 1.10 80 60 40 STATE OF CHARGE (%) 20 SPECIFIC GRAVITY 1.24 V 12.2 100 * Specific gravity of electrolyte drops (gives indication of state-of-charge) * More vulnerable to freezing…(charged freeze at -57oC; discharged at -8oC) BATTERY RATINGS…. * Voltage… for lead-acid about 2 V per cell. Typical “nominal voltage” for battery is 6 V or 12 V (3 or 6 cells per battery) * Voltage depends on state of charge and whether you are charging the battery or discharging it. Voltage can range from about 11 to 15 V 1.26 12.6 11.8 As battery discharges: * Plates coated with PbSO4 yields higher internal resistance, cell voltage drops STATE OF CHARGE (SOC) Hydrometer to measure specific gravity (but electrolyte may stratify with H2SO4 on bottom) 12.4 Figure 9.40 A lead-acid battery in its charged and discharged states. 0 * Energy stored = Volts x Amps x Hours = Watt-hours * With voltage varying all over the map, how do you describe the energy stored in a battery? Ans. Use “Amp-hours” @ nominal battery voltage as the measure of energy stored in battery ! A 12-V battery that reads only 12 V (at rest) is almost completely discharged… 7 BATTERY STORAGE IS DESCRIBED USING A NOMINAL VOLTAGE (2-V/cell) AND.. BUT… AMP-HOURS DEPENDS ON DISCHARGE RATE AND TEMPERATURE AMP-HOURS AT A CERTAIN DISCHARGE RATE C/T (…at a certain temperature) Means it can deliver 5 Amps for 20 hours (5A x 20h = 100 Ah) Energy stored ≈ Volts x Amps x Hours = 12 V x 100 A-hr =1.2 kWhr BATTERIES IN PARALLEL (Ah adds, V same); IN SERIES (Ah same, V adds) 24V, 200Ah 24V, 100Ah + 12V, 200Ah 12V 100Ah + + - - + 12V 100Ah - (a) Parallel, Amp-Hrs add 2.4 kWh + - + 12V 100Ah 12V 100Ah - (b) Series, Voltages add + + - - + + - - + 100 C/72 C/48 90 Nominal C/20 And 25oC C/20 80 C/10 70 C/5 60 50 40 30 20 -30 -20 -10 0 10 Battery Temperature (oC) 20 30 40 Example: A 100 Ah, C/20 battery discharged at C/10 (10A), 25o has ≈ 90 Ah of capacity - COLDER TEMPERATURE… less storage capacity Example: 100 Ah, C/20 battery when discharged at -20o C and C/10 has ≈ 55 Ah of capacity 4.8 kWh BUT YOU DON’T GET TO USE THE FULL AMP-HR STORAGE… * For reasonable battery life, don’t discharge a car SLI battery more than about 20% * You should use deep-cycle batteries, and discharge them no more than 80 % Usable Ah = 0.80 x nominal battery rated Ah of storage 110 DISCHARGE FASTER… less storage capacity (c) Series/Parallel 2.4 kWh 120 Capacity / (Rated Capacity) Example: A 12-volt golf-cart battery rated at 100 Amp-hours (Ah) when discharged over a 20-hour period of time (C/20) at 25oC … VI. LOAD ANALYSIS: How much energy do you “need?” Appliance Refrigerator, 19 cu. ft. Lights (6 @ 30 W) TV, 19-in., Active mode TV, 19-in., Standby mode Satellite, Active mode Satellite, Standby mode Cordless phone Well pump, 100 ft, 1.6 gpm Total Power (W) Hours 180 68 5.1 17 16 4 100 5 3 21 3 21 24 1.25 Watt-hrs/day 1,140 900 204 107 51 336 96 125 2,959 Percentage 39% 30% 7% 4% 2% 11% 3% 4% 100% 2/3rds of TV is standby! EXPRESS THE LOAD IN AMP-HOURS @ SYSTEM VOLTAGE (12V good for ≈ 1200 W) Batteries need to deliver = 2959 volts x amps x hours = 245 Ah/day 12 volts 8 LOAD ANALYSIS: How do you know how much power/energy an appliance uses? * Read the nameplate on a device (Watts) …is maximum power device uses so it is on the high side VII. BASIC PV SIZING.. kWh/m2 day (hrs/d @ 1-sun) DC * EPA appliance labels (kWh/yr) … refrigerators rated in 90oF kitchen (overestimate) DeRating “adjusted” PV output Ah/day * Measure it yourself ! - Battery Output Ah/day h ≈ 90% AC Inverter h ≈ 85% AC LOAD Ah/d @V Coulomb Efficiency h ≈ 90% Dirt..etc IR Amps @ 1-sun per module * Tables in Real Goods, on the web, and other places.. V + DC LOAD n modules in parallel (Ah/d) COULOMB EFFICIENCY = (AMP-HOURS OUT) / (AMP-HOURS IN) ≈ 0.90 (Hrs/d @ 1-sun) x IR (A/module) x n (modules) x 0.90 x 0.90 x 0.85 x V = Wh/day to load Rated power of module kWh/m2-d insolation VIII. HOW SIZE THE BATTERIES? 16 Days of Usable Storage n modules DC kWh/m2 day (hrs/d @ 1-sun) 14 DeRating Dirt..etc IR Amps @ 1-sun per module 10 99% Availability 8 6 * * * * 4 95% Availability 0 3 4 5 Peak Sun Hours 6 7 8 Example: With 3.1 “peak sun hours” in December To be 99% sure of having enough battery storage, provide about 12 days of storage, for 95% availability provide about 4.5 days of storage.. Example: “adjusted” PV output Ah/day 12 V + - h ≈ 90% 12 2 Inverter System voltage VII. BASIC BATTERY SIZING.. * How many days without sun do you want to provide for? * How important is it to be sure you have enough storage for those days? * Is there a backup generator? 2 Coulomb dirt Battery Output Inverter 84 Ah/day h ≈ 85% Coulomb Efficiency h ≈ 90% AC AC LOAD 850 Wh/d 71 Ah/d@12V Convert AC Wh/d load to Ah/d @ system voltage V Divide by inverter efficiency to get Ah/d from batteries Multiply by days of storage wanted Divide Ah by maximum discharge depth allowed •850 Wh/d AC load, 12-V system = 850/12 = 71 Ah/d •85% efficient inverter -- 71/0.85 = 84 Ah/d from batteries •2 days of storage -- 84 Ah/d x 2d = 168 Ah •80% maximum discharge -- 168 Ah/0.8 = 210 Ah Sandia: Standalone PV systems 9 BATTERY SIZING PROCEDURE (continued): Need more current or power?… add PV modules in parallel (currents add): * Wire batteries in series to get voltage * Wire batteries in parallel to get Ah needed + + I - - - EXAMPLE: •850 Wh/d AC load, 12-V system = 850/12 = 71 Ah/d 2-modules 1.0 1-module 0.0 0 + PV disconnect 20 AC DC Charge Controller -- 84 Ah/d x 2d = 168 Ah Inverter Fuse Box 12V, 200Ah •80% maximum discharge -- 168 Ah/0.8 = 210 Ah •6V 100 Ah batteries -- 2 batteries in series for 12V VB 10 A COMPLETE SYSTEM: •85% efficient inverter -- 71/0.85 = 84 Ah/d from batteries •2 days of storage + 2.0 6V, 100 Ah •2 strings would give 200 Ah… close enough 6V, 100 Ah + + - - + + - - + + 6V, 100 Ah Astro 7105 + - 6V, 100 Ah - 6V, 100 Ah + - - + + - - - Battery disconnect switch LOADS 10