Thermal Analysis & Rheology THERMAL APPLICATIONS NOTE Literature Values For Water Specific Heat Capacity Specific heat capacity measurements by DSC require the use of well-characterized reference material (usually sapphire) to obtain results. However, when analyzing liquids, suitable sized sapphire reference material may be difficult to obtain. One alternative is to use purified water. The table below summarizes specific heat capacity data (literature valures) for water as a function of temperature. Temperature °C ______ 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 Specific Heat cal./g/°C _______ J/g/°C ______ 1.00738 1.00652 1.00571 1.00499 1.00430 1.00368 1.00313 1.00260 1.00213 1.00170 1.00129 1.00093 1.00060 1.00029 1.00002 0.99976 0.99955 0.99933 0.99914 0.99897 0.99883 0.99869 0.99857 0.99847 0.99838 0.99828 0.99821 0.99814 0.99809 4.2177 4.2141 4.2107 4.2077 4.2048 4.2022 4.1999 4.1977 4.1957 4.1939 4.1922 4.1907 4.1893 4.1880 4.1869 4.1858 4.1849 4.1840 4.1832 4.1825 4.1819 4.1813 4.1808 4.1804 4.1800 4.1796 4.1793 4.1790 4.1788 Temperature °C ______ 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 Specific Heat cal./g/°C _______ J/g/°C _______ 0.99804 0.99802 0.99799 0.99797 0.99797 0.99795 0.99795 0.99797 0.99797 0.99799 0.99802 0.99804 0.99807 0.99811 0.99816 0.99819 0.99826 0.99830 0.99835 0.99842 0.99847 0.99854 0.99862 0.99871 0.99878 0.99885 0.99895 0.99905 0.99914 4.1786 4.1785 4.1784 4.1783 4.1783 4.1782 4.1782 4.1783 4.1783 4.1784 4.1785 4.1786 4.1787 4.1789 4.1791 4.1792 4.1795 4.1797 4.1799 4.1802 4.1804 4.1807 4.1810 4.1814 4.1817 4.1820 4.1824 4.1828 4.1832 TN-15 Temperature °C ______ 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 Specific Heat cal./g/°C _______ J/g/°C ______ 0.99924 0.99933 0.99943 0.99955 0.99964 0.99976 0.99988 1.00000 1.00014 1.00026 1.00041 1.00053 1.00067 1.00081 1.00096 1.00112 1.00127 1.00143 1.00160 1.00177 1.00194 4.1836 4.1840 4.1844 4.1849 4.1853 4.1858 4.1863 4.1868 4.1874 4.1879 4.1885 4.1890 4.1896 4.1902 4.1908 4.1915 4.1921 4.1928 4.1935 4.1942 4.1949 Temperature °C ______ 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 Specific Heat cal./g/°C _______ J/g/°C _______ 1.00213 1.00229 1.00248 1.00268 1.00287 1.00308 1.00327 1.00349 1.00370 1.00392 1.00416 1.00437 1.00461 1.00485 1.00509 1.00535 1.00561 1.00588 1.00614 1.00640 1.00669 1.00697 4.1957 4.1964 4.1972 4.1980 4.1988 4.1997 4.2005 4.2014 4.2023 4.2032 4.2042 4.2051 4.2061 4.2071 4.2081 4.2092 4.2103 4.2114 4.2125 4.2136 4.2148 4.2160 REFERENCE: Osborne, Stimson, and Ginnings, B. of S. Jour. Res., 23, 238 (1939) in Handbook of Chemistry and Physics, 53rd ed., Cleveland, Ohio, D128 (1972-1973). For more information or to place an order, contact: TA Instruments, Inc., 109 Lukens Drive, New Castle, DE 19720, Telephone: (302) 427-4000, Fax: (302) 427-4001 TA Instruments S.A.R.L., Paris, France, Telephone: 33-01-30489460, Fax: 33-01-30489451 TA Instruments N.V./S.A., Gent, Belgium, Telephone: 32-9-220-79-89, Fax: 32-9-220-83-21 TA Instruments GmbH, Alzenau, Germany, Telephone: 49-6023-30044, Fax: 49-6023-30823 TA Instruments, Ltd., Leatherhead, England, Telephone: 44-1-372-360363, Fax: 44-1-372-360135 TA Instruments Japan K.K., Tokyo, Japan, Telephone: 813-5434-2771, Fax: 813-5434-2770 Internet: http://www.tainst.com TN-15A Thermal Analysis & Rheology A SUBSIDIARY OF WATERS CORPORATION