AP Chemistry Schrodinger Wave Equation – The Highlights Schrodinger Wave Equation (SWE):

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AP Chemistry Schrodinger Wave Equation – The Highlights

Schrodinger Wave Equation (SWE):

 A very complex differential equation that describes the behavior of an electron in the atom as wave-like.

 Solutions to the SWE are themselves equations, referred to as wave functions (  , psi).

 Each unique electron has its own wave function  , thus theoretically there are 110 (?) current possible solutions to the SWE.

  describes the state of an electron by providing information about it, doing so in the form of Quantum

Numbers. Thus,  provides QUANTUM NUMBERS (n, l, m l

) describing the behavior of the electron.

 If one squares  (  2 ), a function describing the probability of finding the electron about the nucleus is formed. This function is what we call an ORBITAL and is best represented graphically below. Thus,  2

provides ORBITALS describing the probability of finding the electron in the atom.

(a)  2

1s

(the 1s orbital for hydrogen)

(b) The Radial probability graph for the 1s orbital of hydrogen. max. away from nucleus

 As the electron increases in energy, its  2 distributions increase in complexity, giving rise to orbitals of different shapes and an increase of zero probability regions (nodes) in the orbital

90% boundary:

Inside this lies

90% of the probability nodes

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