Secondary Operations Chapter 9 Professor Joe Greene CSU, CHICO 1 MFGT 144 Chapter 9 Topics Need for Secondary Operations • • Assembly Operations – Ultrasonic welding; Hot-gas welding – Induction bonding; Spin (Friction) welding; Adhesive bonding • Machining Operations – Drilling and tapping; Reaming; Turning and milling • Automatic Shape Cutting – Water jet; Laser cutting • Surface Finishes and Decorating Procedures – Surface Prep: Flame, plasma process, acid etch • Applied Finishes – Painting;Electroplating; Vacuum Metallizing; Hot stamping – Pad printing and screen printing – Molded-in-color and symbols 2 Need for Secondary Operations • Secondary operations – Any operation to a molded part that occurs after the part is made. • Painting, trimming, drilling, fasteners, assembly – Should be minimized through injection molding design – Will generally be more expensive than molded-in features. • When to consider secondary operations – – – – When volumes are small When tooling costs are excessive When time to build mold jeopardizes sales schedules 3 When a labor is available from other sources in company Assembly Operations • Ultrasonic welding (Figure 9-1) – Uses high frequency mechanical vibrations (20 to 40 kHz per second transmitted through thermoplastic parts. – Vibrations generate friction between the plastic parts which leads to melting of the plastic. – The two plastic parts melt and fuse together as bond. – Can be used for staking, surface vibration welding, spot welding, and inserting metal inserts. • Thermoplastic materials can be welded – Amorphous materials are easy to ultrasonically weld. – Crystalline materials require greater amounts of energy 4 and are much more sensitive to joint design and fixturing Ultrasonic Welding • Parameter Effects – – – – – Materials: crystalline versus amorphous Melt temperature Melt index and viscosity Material stiffness Chemical makeup of plastic: Some dissimilar amorphous plastics can be welded. • Energy Directors (Fig 9-2) – Purpose- direct energy from the horn of machine to the desired point of welding. – Focuses the ultrasonic energy to the point and causes the 5 material to melt Ultrasonic Welding • Ease of welding – Table IX-2 and IX-2 for Amorphous and Crystalline – Function of joint design, part geometry, energy requirements, amplitude, and fixturing. – Based on near field welding, welding joint within 0.25 inches of horn contact surface – Frequency is usually 20 kHz versus 40 kHz (20% of jobs) – Vibration welding is lower frequency: 250 to 300 Hz • automotive bumpers, or materials that are damaged by high Hz 6 Ultrasonic Welding • Variables that Influence Ultrasonic Welding – Polymer structure • Amorphous- molecules are random arrangement. – Efficiently transmit ultrasonic vibrations and can be welded under a wide range of force-amplitude combinations • Crystalline- molecules are are spring-like in solid state. – Internally absorb a percentage of the high-frequency mechanical vibrations of the ultrasonic generator reducing efficiency of transmitting to joint interface. – Requires a higher amplitude – Melt temperature • Higher melt temperature more energy required. – Stiffness (modulus of elasticity) • Higher stiffness the better the transmission of the ultrasonic 7 energy to the joint interface. Ultrasonic Welding • Variables that Influence Ultrasonic Welding – Moisture content • Hygroscopic materials- nylon, ABS, PC, Psulfone, PET, PBT • Higher moisture content the lower the bonding efficiency • Moisture turns into steam during welding step and creates porosity in part and degrade resin at the joint interface. • Molded parts should be dried prior to welding. – Flow rates or viscosity • Rate at which material flows when it becomes molten. • Different materials should have similar viscosities or melt index – Mold release agents • Added to increase release of part from mold. • Higher mold release the lower the bond strength. 8 Ultrasonic Welding • Variables that Influence Ultrasonic Welding – Plasticizers • High temperature boiling liquids or low temperature melting plastics added to increase flexibility and elongation • Higher plasticiser amount results in lower bond strength. • Plasticizers interfere with a resin’s ability to transmit vibrations. • Plasticizers swell polymer like a sponge. – Flame retardants • Inhibits ignition or modifies burning chacteristics • Generally inorganic oxides or halogenated organics – Aluminum, antimony, boron, chlorine, bromine, sulfer, nitrogen, – Typically, 1% to 2% – not weldable 9 • Higher flame retardant amounts results in lower bond strength Ultrasonic Welding • Variables that Influence Ultrasonic Welding – Regrind • Regrind is added to reduce cost of part • Regind reduces melt temperature and reduces bond strength – Colorants • Generally do not inhibit weld strength unless greater that 5% – Resin grade • Different resin grades can have different melt temperatures and molecular weights. • Different weld grades are weldable if the two resins have similar molecular weights and the melt temperatures should be within 40°F of each other. 10 Ultrasonic Welding • Variables that Influence Ultrasonic Welding – Fillers • Added to reduce the price of the polymer and increase (Slightly stiffness) and reduce CLTE – talc, calcium carbonate, kaolin, organic fillers, silica, micas, etc. • Enhance some plastics ability to transmit ultrasonic energy by imparting higher stiffness. (For up to 35% filler) • Are very abrasive and can cause excessive wear on surface. • Require use of hardened steel or carbide-coated titanium horns – Reinforcements • Added to increase strength and stiffness and reduce CLTE – glass fiber, carbon fiber, aramid fiber. • Enhance the weldability of resin – Short fibers result in better welds – Long fibers clump at gate and reduce weldability 11 Hot-gas Welding • Similar to metal welding – Welding rod composed of same material being welded is placed along a beveled joint area. – Heat is applied to the area by hot gas (air or nitrogen) – Hot plastic melts the plastic and welding rod – PVC (rigid) is most common material hot-gas welded – Figure 9-3 12 Induction (Electromatic) Bonding • Figure 9-4 (Time required = less than 10 seconds) – Process consists of activating an electrodynamic field to excite a conductive bonding agent (metal wire strands) – Heat is absorbed by the plastic components that surround the bonding agent, causing the plastic to melt. – Melted plastics fuse together and to the bonding agent. – Slight pressure is applied during welding. 13 Spin (Friction) Welding • Figure 9-5 (Time required = less than 2 seconds) – Process consists of one part spinning at speeds of 100 to 1000 RPM located near second part. – The spinning produces friction & heat when parts touch. – Slight pressure is applied during welding. – Can produce weld with drill press or lathe. – Can be used with most hard plastics. – Requires part to be cylindrical. 14 • Adhesive Bonding Figure 9-6 (Time required = 10 seconds to minutes) – Process consists of one adding a thermoset material – The thermoset material (urethane and epoxy polymers) – Ashland Chemical PLIOGRIP (Modified urethane) • Acrylics, Phenolic resins, Structural Adhesive, Welding Adhesives, Roofing Adhesives, Wood Bonding Adhesives • Structural Adhesives – Solventless PLIOGRIP®, AROWELDTM and AROGRIP® structural adhesives bond reinforced thermosetting composites, thermoplastics, metals and other substrates 15 Machining Operations • Drilling and Tapping Thermoplastics – Carbide drills are most suitable – Carbide tipped or diamond-tipped drills for mirror finish – Flutes should be highly polished and drill cutting surfaces should be chrome plated or nitrided to reduce wear • • • • • Details of drill dimensions are shown in Fig 9-7 drill land, L, should be 1/16 in or less Helix angle should be 30° to 40° Point angle should be 60° to 90° Drill feed should be approximately 0.0005 per revolution of drill bit • Drill speeds should range from 5000 rpm to 1000 rpm 16 • Thermosets are more abrasive and require special bit Machining Operations • Reaming Thermoplastics and Thermosets – Reamers should be fluted for best surface finish – Reamer feeds and speeds should approximate those of drilling operations. – Water soluble coolants should be used to reduce heat generation by friction. • Turning and Milling – Lath and mill cutters should be tugsten carbide or diamond-tipped with negative back rake and front clearance (Figure 9-8) 17 Automated Shape Cutting • Water Jet Cutting – Most popular automated cutting process in industry – Employs a force of a thin stream of water pressure (20 kpsi to 50kpsi) to create a powerful cutting point. – Pierces plastic or composite material cleanly. – Dust and chips are non-existent – Used for flat sheet stock mostly but can with the use of three and five axis machines cut complex parts 18 Automated Shape Cutting • Laser Cutting – Used when a fine polished finish on plastic edge is required, such as on the edges of an acrylic sign. – Laser cuts by focusing its concentrated beam at the exact point of the cut, which causes the plastics to melt, vaporize, and solidify, thus producing a smooth finish. – Advantages • • • • • Straight, burr-free cuts Narrow cutting-width Oxidation-free cuts, Smooth profile High cutting speeds 19 http://www.lmclaser.com.au/ Surface Finishes and Decorating Procedure • Preparation of Surface – Products that require postmold painting or decorating need clean surface to ensure proper adhesion to paint or bond. – Flame treatment • Most common method of preparing polyolefins and acetals • These materials are slippery in nature and resistant to paints • Flame treatment consists of passing the molded product through a flame – Causes the surface to oxidize and making it receptive to paints – Surface is oxidized without charring surface. – Corona Discharge • Surface oxidation of plastic is achieved by passing the plastic over an insulated metal cylinder beneath a high voltage conductor. • An electric discharge strikes the surface of the plastic causing plastic to oxidize 20 Surface Finishes and Decorating Procedure • Preparation of Surface – Plasma Process • Low pressure air is directed through an electrical discharge and expand into a vacuum chamber containing the plastic. • Nitrogen and oxygen gases are partially disassociated radicals in air react with the surface – Acid Etch • Some plastics, e.g., PC and ABS, need additional surface preparation • Acid wash attacks surface of the plastic and creates microscopic craters of exposed resin. • Craters will physically capture the decorative coating and lock it to the plastic surface. 21 Surface Finishes and Decorating Procedure • Applied Finishes – Painting • • • • Applied with brushing, spraying, rolling, or dipping Manually, mechanically, or robotically Most are sprayed with standard spray process (Fig 9-9) Need proper surface prep, primer, oven Temp – Plating (Electroplating) • Requires plastic to be made conductive • Apply conductive base metal to plastic surface. • Metallic plating is used for decorative or functional – plumbing fixtures, jewelry, circuit board traces, EMI shields, corrosion resistant surfaces 22 Surface Finishes and Decorating Procedure • Applied Finishes – Vacuum Metallizing (Deposition) Figure 9-10 • Plastic is coated with lacquer base coat. • Then placed on a rack inside a vacuum chamber along with small clips of the metal to be deposited, • The metal clips are heated to the point of vaporizing • Depoited on all line-of sight surfaces due to vacuum • Gives bright metallic finish • Less expensive than electroplating 23 Surface Finishes and Decorating Procedure • Applied Finishes – Hot Stamping (Fig 9-11) • Three methods of hot stamping – Roll-on decorating: (Fig 9-12) » Ideal for applying rolls or preprinted heat transfers to part surfaces » Silicone rubber roller applies heat and pressure to release the print medium onto the plastic substrate. – Peripheral marking (Figure 9-13) » Ideal for periphery of cylindrical or slightly conical parts » Plastic product is rolled under a flat stamping die to release the print medium onto plastic substrate – Vertical Stamping (Fig 9-14) » Ideal for small areas of flat or slightly crowned products » Silicone rubber die is mounted to the heated head of a vertical machine and positioned directly over the part to be decorated » Rubber die contains raised graphics to be stamped and is heated 24 » Rubber die is powered and pushes the foil against the plastic Surface Finishes and Decorating Procedure • Applied Finishes – Pad Printing (Fig 9-15) • Done like printing paper on a press – A pad of rubber is inked with the image that is pressed onto a steel or nylon plate on which the image is etched with ink screened into that image. – Ink pad is brought to the plastic surface and pressed. – Screen Printing (Fig 9-16) • Ink or paint is forced through a mesh of a plastic or a metal screen by pulling a squeegee across a screen that is placed against the surface of the plastic. 25