Chapter 14 Summary: Soil Phosphorus and Potassium Phosphorus: Phosphorus in pant nutrition and soil fertility: Second most likely of essential elements to limit plant productivity. Commonly applied as fertilizer. Neither plants nor animals can live without phosphorus. Is an essential component of ATP (energy current), DNA, RNA, and phospholipids. Enhances the processes of photosynthesis, nitrogen fixation, flowering, fruiting, and maturation. Encourages root growth, strengthens structural tissues, and improves crop quality. Phosphorus-deficient plant is usually stunted, thin stemmed, and spindly and characterized by delayed maturity, sparse flowering, poor seed quality, yellowing and senescence of leaves. The Phosphorus problem in soil fertility: Total phosphorus content of soils is relatively low. Phosphorus compounds commonly found in soils are mostly unavailable to plants and highly insoluble. Soluble sources of phosphorus such as fertilizers and manures are fixed when added to the soil. Effects of phosphorus on environmental quality Land degradation caused by too little available phosphorus Accelerated eutrophication (nutrient enrichment of lakes, ponds and other waters leading to oxygen deficiency in the water body) caused by too much phosphorus. Phosphorus gains and losses: Gains: fertilizer, plant residues, manure, sludge. Losses: plant removal, erosion, surface runoff, and leaching. Organic and inorganic phosphorus in soils Organic: 1) inositol phosphates or phosphate esters of a sugar like compound 2) nucleic acids 3) phospholipids. Inorganic: 1) those containing calcium 2) those containing iron and aluminum. Practical control of phosphorus in soils: Neil Schibbelhute Enhance availability: adjust fertilizer application to soil, localized fertilizer placement, combine ammonium with phosphorus, cycling of organic matter, control of soil, and enhance mycorrizal symbiosis. Reduce losses to water: avoid excess accumulation, minimize loss in runoff and sediment, capture phosphorus from runoff and sediment, tie up phosphorus with inorganic amendments. Potassium: Nature and ecological roles: Third most likely of essential elements to limit plant productivity. Commonly applied as fertilizer. Present in the soil solution only as a positively charged cation, K+. Its behaviour in the soil is influenced by soil cation exchange properties and mineral weathering rather than by microbiological processes. No off-site environmental problems. Plant and Animal Nutrition: Activator of cellular enzymes. Is essential for photosynthesis, protein synthesis, nitrogen fixation in legumes, starch formation, and translocation of sugars. Especially important in helping plants adapt to environmental stresses. Improves flavour, colour and strengthens stems of flowers, fruits, and vegetables. The potassium problem in soil fertility: 1) A very large proportion is unavailable to plants ( held rigidly as part of primary material or fixed) Subject to leaching losses Removal by plants is high. Plants will take up far in excess of their needs if available (luxury consumption). Forms and availability of potassium in soils: K in primary mineral structure (unavailable). Nonexchangeable K in secondary minerals (slowly available). Exchangeable K on soil colloids and K solution in water (readily available). Factors affecting potassium fixation in soils: Four soil conditions that influence the amounts of potassium fixed: 1) the nature of soil colloids 2) wetting and drying 3) freezing and thawing 4) the presence of excess lime. Potassium gains and losses: Gains: plant residues, animal manures, atmospheric deposition, commercial fertilizers, slowly available potassium minerals. Losses: plant removal, leaching losses, erosion losses, fixation.