DAY 6 CHEMISTRY SUMMER SCIENCE INSTITUTE HOT RODS/COLD CUBES Locate the thermometer at the front of the lab. Record the temperature of the lab in both Centigrade and Fahrenheit degrees. 1. Temperature of room ______ oC ______ oF Find the mass of a metal cylinder on a digital balance. _________g Place the cylinder into a beaker of room temperature water then heat the beaker on a hot plate until the temperature of the water is 60o C. Be careful that the thermometer does not touch the bottom or sides of the beaker. Remove the cylinder with tweezers; dry it with a paper towel. Predict the mass of the cylinder at 60o C. ________g Why do you think so? Find the actual mass of the heated cylinder on the digital balance. Actual mass __________ g 2. Carefully and quickly find the mass of six ice cubes on the digital balance by first finding the mass of an empty 250mL beaker. Mass of empty beaker __________g Mass of beaker and cubes ________g Mass of cubes ________g Heat the beaker and cubes gently on a hot plate until approximately half the cubes are melted. Then re-mass the beaker. Mass of contents of beaker ________g What was the effect of adding heat to the mass of the contents of the beaker? Is heat a form of matter? ________ Why or why not? 1 DAY 6 CHEMISTRY SUMMER SCIENCE INSTITUTE COOL, COOL WATER On hot summer days, taking a dip in the ocean or a pool is a very inviting idea! Let’s see if we can figure out why. 1. The temperature of this room is likely to be about 72o F or 22o C. What is the likely temperature of the water that is sitting out in the beaker? Why do you think so? Place your fingers in the water and then remove them. How do your fingers feel? Is heat moving from the water to your fingers or from your fingers to the water? Why do you think so? Wave your hand around. How do your fingers feel now? What made the difference? What is happening to the water? What can you conclude about the relationship between change of state and heat? Can you explain why standing in front of a fan while you are wet cause chills? Can you explain why we perspire? 2 DAY 6 CHEMISTRY SUMMER SCIENCE INSTITUTE THINGS ARE HEATING UP 1. Place 10 ice cubes in a 400mL beaker and add just enough tap water to make the cubes float. Stir the mixture vigorously with a glass stirring rod and then take its temperature. It is important that the thermometer not touch the bottom or sides of the beaker (WHY?) Secure the thermometer to a ring stand by using a clamp secured to split rubber stopper that is on the thermometer. Lower the thermometer into the mixture and continue stirring as you take the temperature reading. Initial temperature of water and cubes ________oC. 2. Place the beaker on a hotplate which is on a medium setting and continue stirring (use a stirring rode). Record the temperature when approximately half the ice has melted. Temperature when half of the ice is melted ________ oC. Continue heating and stirring until all of the ice melts. What is the temperature of the water just as the last of the ice melts? Temperature of water as last of ice melts ________ oC. What do you think the heat was doing? Continue heating and stirring the water for one more minute. What is the temperature of the water? ________ oC. What do you think the heat is doing to the water? Which contains more heat, the ice or the water? How do you know? 3 DAY 6 CHEMISTRY SUMMER SCIENCE INSTITUTE 3. Put the beaker back on the hotplate, continue heating the water and take the temperature every 30 seconds until the water boils. Reading Time oC Reading Time oC ________ oC Take the temperature of the boiling water Continue boiling the water for one minute. Take the temperature of the boiling water. ________ oC. What was the effect of the heat on the water from the time the ice melted until boiling started? What was the effect of the heat on the water once boiling started? Make as many observations as you can as the water is boiling. 4 DAY 6 CHEMISTRY SUMMER SCIENCE INSTITUTE HOT AND COLD – BIG AND SMALL At this station, you will find two thermometers held by rubber stoppers and clamped to ring stands. There is a wire gauze on a ring below each thermometer. You will also have an empty small beaker and an empty large beaker on the table and two Bunsen burners. Fill each beaker about half-way with water from the tap. Place each beaker on the wire gauze and lower the thermometers into the water. Make sure the thermometers are not touching the sides or bottoms of the beakers. Read the temperature of each sample of water in Centigrade degrees. Small beaker ________ oC Big beaker ________ oC Light the Bunsen burners and place them under the wire gauze. Heat each beaker simultaneously until the temperature reaches 60oC. What is now the same about the two beakers? What was different about getting these beakers to that temperature? What can you say about the amount of heat in the big beaker as compared to the amount of heat in the small beaker? If two objects are at the same temperature does that mean that they contain the same amount of heat? If you were blindfolded and placed only a finger into each of the beakers, could you distinguish the large and small beakers? ______________ Is temperature a measure of the amount of heat of an object? What does temperature measure? Are there any questions you would like to ask? 5 DAY 6 CHEMISTRY SUMMER SCIENCE INSTITUTE ENERGETIC CHEMICALS 1. Caution – goggles must be worn! Place one Styrofoam cup into another. Use a graduated cylinder to measure 50mL of a 1M NaOH solution. Pour this solution (sodium hydroxide/lye) into the cup. Place a cardboard cover over the cup. Insert a thermometer through the center of the cardboard cover into the solution. Temperature of the NaOH solution ________o C. Measure 55mL of a 1M HC1 (hydrochloric acid) solution using the graduated cylinder and add the acid into the cup. Stir the chemicals with the thermometer, and take the temperature once a minute for the next 3 minutes. After 1 minute ________o C. After 2 minutes ________o C. After 3 minutes ________o C. What observation can you make? What conclusion can you make? Why do you think it was necessary to perform this experiment in the doubled-up Styrofoam cups instead of using a glass beaker? 2. In this activity, you will perform the same chemical reaction twice. The reaction is between iron (Fe) and copper Sulfate (CuSO4). CuSO4 is a solid, but the blue liquid on the lab table is a solution of CuSO4, or CuSO4 dissolved in water. In the first try at this reaction, you will put the two chemicals directly in contact with one another. Place about 1 inch of CuSO4 solution in a small beaker, then add the iron nail. Wait about 1 minute, and remove the nail with plastic tweezers and place it on a paper towel. Describe what you see on the nail. Where must this material have come from? 6 DAY 6 CHEMISTRY SUMMER SCIENCE INSTITUTE The chemical equation for what occurred is: Fe + CuSO4 → Cu + FeSO4 Now do you know the identity of the coating on the nail? _______________________ If you continuously scraped the coating off, more and more of it would reform until all of the blue color was removed from the solution or all, the nail was gone. Where would the iron be when the reaction was over? This reaction is an example of REDOX – or oxidation and reduction. The Fe, which is an uncharged element, forms the compound FeSO4 in which the iron has a charge of +2. Fe → Fe+2 Two electrons, 2e- , left the iron and this resulted in the +2 charge. The loss of e-’s is oxidation. Feo - 2e → Fe+2 In CuSO4, the Cu has a charge of +2, but when it became free elemental copper it has no charge. Cu+2 → Cuo Two electrons were added to the Cu+2 and this resulted in neutral Cuo . A gain of electrons is called reduction. Cu+2 + 2e → Cuo So in this redox reaction, electrons were exchanged; 2 were lost from the Fe (oxidation) and 2 were gained by Cu+2 (reduction). You will now perform this reaction again, but this time you will physically separate the chemicals and connect them to wires through which electrons can travel. 7 DAY 6 CHEMISTRY SUMMER SCIENCE INSTITUTE 3. See the following diagram which illustrates the set-up. Attach a wire to a clean Cu strip using an alligator clip and suspend the nail into a solution of CuSO4 in an unglazed porcelain cup. Attached a second wire to a nail and suspend the nail into a solution of FeSO4 in a large beaker. Connect the free ends of the wires to a DC voltmeter and watch what happens! In which direction along the wire do you think electrons are flowing? Why What is the name commonly given to a flow of electrons through a wire? Using this set up how could you get a small light bulb to light? Assuming that the filament in the bulb would not burn out, when would the bulb go out? 8