Name of Partner: Name: Date Completed: Block / Period: Date Due: Teacher: Mr. Bannister Exploring Colligative Properties Introduction / Background: Colligative properties are physical characteristics than can be altered and manipulated by introducing a solute to the substance. This new solution now will have its own unique set of physical properties, differing from those exhibited by the parent solvent. The effect of the addition of the solute on the solvent depends on the quantity solute and the extent of the dissociated process that takes place. As the number of particles in solution (i.e. ions or molecules) increases, the amount per volume of solvent will decrease, creating a lower quantity of liquid molecules able to vaporize and enter the gaseous phase. This, in turn, will create a lower vapor pressure, one of several examples of a colligative property. Additional properties include osmotic pressure, boiling point elevation, and freezing point depression. In freezing point depression, the normal freezing point of a solvent is decreased by adding a solute, in the case of this lab, a salt, to a sample of water. Purpose: The purpose of this lab is to experiment with solutions to observe freezing point depression first hand. Water will normally freeze / melt at 0°C, however this point will decrease when a solute is added, creating a colder solution. This colder solution will allow the chemicals to quickly solidify, synthesizing the desired product. PreLab Questions: Answer the following questions thoroughly prior to the experiment. 1. What determines the extent of the effect the solute will have on the solvent? 2. Would ordinary table sugar have a similar effect as an ionic salt? Why or why not? EXPLORING COLLIGATIVE PROPERTIES BANNISTER 3. When considering solutions, what effect does crushing up the solute have on the solubility? What effect does temperature have? What is the reason behind stirring or shaking a solution? Define the following terms: Colligative Property – Solution – Solute – Solvent – Physical Property – Vapor Pressure – Boiling Point Elevation – Freezing Point Depression – Osmotic Pressure – EXPLORING COLLIGATIVE PROPERTIES BANNISTER Materials: 2 Zipping Containment vessels 54.0 grams Cup C6H12O6 100 mL Concentrated Bovine Udder Secretion 100 mL 2% Bovine Udder Secretion 1 mL Vanilla (use marked pipette) 103.7 grams Cup NaCl or MgCl2 Thermometer Solidified, low-entropy H2O Rolling Barrel Additional Garnishing (i.e. Cocoa enriched dairy colloid, ground legume paste, billowy whipped mammal secretion, etc.) Procedure: 1. Combine together 54.0 grams C6H12O6, 100 mL bovine udder secretion, 100 mL concentrated bovine udder secretion, and 1 mL vanilla to a single zipping containment vessel, sealing it securely. 2. Fill a rolling barrel about one quarter of the way full with solidified H2O, adding more when deemed necessary. 3. Use a thermometer to measure and record the temperature of the ice in the rolling barrel. 4. Add approximately 104 grams of NaCl to the barrel of ice. Add increments of 52 grams when needed. 5. Place the sealed containment vessel inside the rolling barrel with the ice and sodium chloride. Be sure to replace the cap onto the barrel securely. 6. GENTLY rock the barrel from side to side. It is best to roll the barrel gently as you do not want to break open the inside vessel nor do you want the salty solution to enter through. Caution: Be sure to switch off with partners and / or cover your skin. The resulting solution will become cold enough to potentially damage your skin. 7. Continue to rock the barrel for 10-15 minutes or until the contents of the internal vessel have solidified into the desired product. 8. Using a thermometer, record the temperature of the H2O · NaCl solution inside the rolling barrel. 9. Remove the containment vessel(s) and apply any additional condiments. Data: **Be sure to keep track and record any additions added along the way DATA TABLE 1: Quantity of NaCl used: (rough estimate) Temperature of initial ice solution Temperature of the °C EXPLORING COLLIGATIVE PROPERTIES NaCl · H2O solution °C BANNISTER Discussions / Conclusions: During phase changes such as what was observed with the ice melting to form liquid water, energy is either released or absorbed. When energy is absorbed, the sample will get warmer and increase in temperature. However, energy may be transferred and yet no temperature increase or decrease is observed. Explain this phenomenon. What is losing energy? What is gaining energy? Why is this important for the ultimate objective of this experiment? What impact did adding more salt have on the physical change’s process? Why? What could be used to radically decrease the temperature more than what was observed using our salt? EXPLORING COLLIGATIVE PROPERTIES BANNISTER