Hi everyone, Here are some quick references: My website: http://www.colgate.edu/facultysearch/facultydirectory/dkeller How to supercool water: http://chemistry.about.com/od/chemistryhowtoguide/a/how-to-supercool-water.htm video website links: Water to ice: http://www.youtube.com/watch?v=3Qasw7lb2UM One I didn't have time to show you that you might like for general reference/interactive exercises: http://www.learner.org/interactives/rockcycle/diagram.html Sediment transport: http://www.youtube.com/watch?NR=1&v=O9GVRKnMch8&feature=endscreen Making evaporites: http://www.youtube.com/watch?v=QwiPplYoH7Q&feature=related I also was thinking that somebody may want to know how for instance, sulfur the mineral is different from sulfur the element. Minerals follow the definition guidelines so the sulfur atoms would need to arrange themselves in the specific atomic arrangement that is characteristic of the mineral sulfur to be a mineral whereas sulfur the element just needs to have the necessary 16 protons in its nucleus. Lastly – I wish I could have given you more sets of minerals, rocks and fossils for your classrooms but just remember, you can find some for yourselves, just like I did by collecting the schists & phyllites when my sister and I visited a beach near her house in CT., and like we all did with the fossils. At the Herkimer Diamond Mine, you can not only find quartz crystals but also calcite, dolomite (usually opaque white, pale orange or pale pink) and celestite (light blue). Local rocks include shale, graywacke, quartz sandstone, limestone. If you go to the Adirondacks you can find gneiss, marble, gabbro (high peaks. This gabbro is actually a rock that is more specifically called "anorthosite" which is composed of almost all Ca-feldspar. There are also amphibolites that are mostly all hornblende. So keep an eye open for some good finds! Happy Hunting! - Di Rocks vs. Minerals What's the Difference? Minerals • naturally occurring, inorganic, crystalline solid • ordered atomic arrangement • definite chemical composition 2 minerals can have: or same composition but different structures ex., Graphite & Diamond (C) same structure but different compositions rhodochrosite MnCO3 Photo Copyright © 2007 Michael C. Roarke calcite CaCO3 http://images.tutorvista.com siderite FeCO3 BUT no 2 minerals have the same combination Rocks Aggregates of minerals & Minerals • naturally occurring • inorganic • crystalline solid = ordered atomic arrangement • definite chemical composition Aggregates of elements Quartz SiO2 K-feldspar KAlSi3O8 Hornblende (Ca,Na)2-3 (Mg,Al,Fe)5Si6 (Si,Al)2O22(OH)2 "Reading Rocks" "Reading from the Great Stone Book" Rocks = "sentences" Minerals = "words" Periodic Table of the Elements = the "alphabet" (but actually only 8-10 very common elements) Quartz SiO2 K-feldspar KAlSi3O8 Hornblende (Ca,Na)2-3 (Mg,Al,Fe)5Si6 (Si,Al)2O22(OH)2 8 Elements make up 98.6% of Earth’s crust O Al Si Na Mg K Ca Fe Others Si & O account for 74.3% Al Si & O Common Mineral Classes (based on anions in formula) Si & O account for 74.3% Silicates are the most abundant Chemical formula contains Si & O Native Elements- formula contains one element Oxides - formula contains O (but no Si, C, S) Hydroxides - formula contains OH Carbonates - formula contains CO3 Sulfides - formula contains S Sulfates - formula contains SO4 Phosphates - formula contains PO4 Halides - formula contains Cl, F, I, or Br (halogen elements) Common Mineral Classes (based on anions in formula) Examples of Silicates: Chemical formula contains Si & O The most common mineral: Quartz SiO2 The most common group of minerals: Feldspars: Orthoclase KAlSi3O8 Albite NaAlSi3O8 Anorthoclase CaAl2Si2O8 Examples of Other Common Mineral Classes Native Elements - formula contains one element common mineral in pencils: Graphite C Oxides - formula contains O (but no Si, C, S) common mineral in rust: Hematite Fe2O3 Hydroxides - formula contains OH also common in rust: Goethite FeO(OH) Carbonates - formula contains CO3 most common, many shells: Calcite CaCO3 Sulfides - formula contains S fool’s gold: Pyrite FeS2 Sulfates - formula contains SO4 used for plaster: Gypsum CaSO4•2H2O Phosphates - formula contains PO4 common mineral in teeth: Apatite Ca5(PO4)3(OH) Halides - formula contains Cl, F, I, or Br table salt: Halite NaCl Minerals • naturally occurring, inorganic, crystalline solid • ordered atomic arrangement • definite chemical composition 2 minerals can have: or same composition but different structures ex., Graphite & Diamond (C) same structure but different compositions rhodochrosite MnCO3 Photo Copyright © 2007 Michael C. Roarke calcite CaCO3 http://images.tutorvista.com siderite FeCO3 BUT no 2 minerals have the same combination Minerals • naturally occurring, inorganic, crystalline solid • ordered atomic arrangement • definite chemical composition give rise to CHARACTERISTIC PHYSICAL PROPERTIES that are used to ID them LUSTER CLEAVAGE & FRACTURE HARDNESS STREAK SPECIAL SPECIFIC GRAVITY COLOR Crystal Habit = Growth shape Cleavage & Fracture = Breakage Style Cleavage = Planar Breakage ex. 1 direction Fracture = NONPlanar Breakage irregular = rough surfaces ex. 3 directions at 90˚ hackly = pointy surfaces conchoidal = curved surfaces ex. 4 directions Hardness = Resistance to Scratching Mohs Hardness Scale 1 2 3 4 5 6 7 8 9 rather than having a Fingernail = 2½ Penny = 3½ Glass = 5½ 10 Rocks Aggregates of minerals & Minerals • naturally occurring • inorganic • crystalline solid = ordered atomic arrangement • definite chemical composition Aggregates of elements Quartz SiO2 K-feldspar KAlSi3O8 Hornblende (Ca,Na)2-3 (Mg,Al,Fe)5Si6 (Si,Al)2O22(OH)2 3 Main Rock Types: Igneous, Sedimentary, Metamorphic http://explore.ecb.org Igneous Rocks & Minerals Crystallize from a melt Making Igneous Rocks… ~1400˚C ~700˚C http://www.youtube.com/watch?v=3Qasw7lb2UM Rocks with different compositions can be produced because different minerals melt or crystallize at different temperatures ** BOWEN’S REACTION SERIES ** Making Different Igneous Rocks… Different substances melt or crystallize at different temperatures Composition Cooling Temperature Igneous Rock Classification is based on Composition and Texture Igneous “Texture” Grain size Cool quickly ⇒ no time to grow Cool near/at surface “Aphanitic” “not seen” Cool slowly ⇒ time to grow Cool deep ⇒ insulated http://www.windows2universe.org/ Texture Cooling Rate “Phaneritic” “seen” Igneous Rock Classification is based on Composition and Texture "Igneous" Minerals Minerals from Bowen's Series Cleavage & Fracture = Breakage Style Cleavage = Planar Breakage ex. 1 direction Fracture = NONPlanar Breakage irregular = rough surfaces ex. 3 directions at 90˚ hackly = pointy surfaces conchoidal = curved surfaces ex. 4 directions Igneous Rock Classification is based on Composition and Texture Most abundant in Earth's crust: O Si Al Fe Ca Na K Mg 74.3% 8.2% Silicates ~92% 12% Quartz GRANITE 36.9% 12% K-feldspar 40% plagioclase feldspar 17.5% 11% pyroxene BASALT 42.5% Making Different Igneous Rocks… Different substances melt or crystallize at different temperatures Two Processes differentiate rocks: 1. Partial Melting Different substances melt at different temperatures Two Processes differentiate rocks: 1. Partial Melting chocolate chips vanilla ice cream Starting with solid Oceanic Crust is made of BASALT Silly Putty-like solid Ultramafic composition Oceanic Crust is made of BASALT Two Processes differentiate rocks: 2. Fractional Crystallization Starting with melt chocolate chips vanilla ice cream Two Processes differentiate rocks: 1. Fractional Crystallization Crystallization Order chocolate chips vanilla ice cream periods of crystallization over time Continental Crust is mostly made of GRANITE thicker Continental crust is and than oceanic crust magma stalls longer below continental crust. undergoes more fractional crystallization Different minerals melt & crystallize at different temperatures Chocolate chips ⇔ dark, mafic minerals Vanilla ice cream ⇔ light, felsic minerals Most abundant in Earth's crust: 92% = igneous & metamorphic rocks GRANITE 36.9% BASALT 42.5% 8% = sedimentary rocks SHALE 50% CARBONATES 25% SANDSTONES 25% BUT... 95% of surface rocks are SEDIMENTARY Sedimentary Rocks & Minerals Made of sediment: crushed up bits (clasts) dissolved bits (ions in solution) Sediments are materials weathered from pre-existing rocks Weathering Erosion http://www.learner.org/interactiv es/rockcycle/diagram.html Transport Deposition Burial Compaction Cementation Harden into rock http://www.learner.org/interactives/rockcycle/diagram.html LITHIFICATION 4 WAYS TO TRANSPORT SEDIMENT: WIND and WATER Typically: ~ Well Sorted Rounded Layered GRAVITY and GLACIERS Typically: UNsorted UNrounded UNlayered Sorting – Waterlain Deposits Very well sorted Not so well sorted Reworked http://www.maine.gov/doc/nrimc/mgs/explore/bedrock/fact s/nov06-5.htm Deposited without reworking CLASTIC SEDIMENTS in CLASTIC ROCKS Grains become more rounded during transport angular edges break off as grains bounce and roll along http://www.youtube.com/watch?NR=1&v=O9GVRKnMch8&feature=endscreen CLASTIC SEDIMENTS in CLASTIC ROCKS Grain sizes that get deposited become smaller with distance from source. Competence: maximum grain size that can be carried controlled by energy of flow controlled by slope slope decreases downstream CLASTIC SEDIMENTS in CLASTIC ROCKS Weak minerals disintegrate so only strong minerals remain Minerals low on Bowen’s Series • form at temperatures that are closer to those at Earth’s surface, so they are more stable on the surface than minerals formed at higher temperatures • are more silica-rich, resulting in structures in which the silica bonds together in strong frameworks. Weathering Products ex., rust (hematite), clays Sedimentary Rocks 2 General Types Terrigenous Clastic from land broken bits Biochemical precipitated from dissolved ions often with the help of organisms crushed up bits (clasts) + dissolved bits (ions in solution) cement dissolved bits (ions in solution) COMMON TERRIGENOUS CLASTIC ROCKS • grain size decreases • rounding increases • weak minerals disintegrate Increasing distance from source COMMON TERRIGENOUS CLASTIC ROCKS BIOCHEMICAL MINERALS (precipitated from dissolved ions) CALCITE (CaCO3) commonly: associated with marine settings secreted as shells or feces EVAPORITES micoorganisms: forams, coccolithophores HALITE (NaCl) typically : form in shallow basins with periodic influxes of seawater followed by evaporation of water, leaving GYPSUM (CaSO4•2H2O) CHERT (SiO2) solids behind commonly: precipitated by sponges and micoorganisms: diatoms, radiolaria or directly from seawater http://www.youtube.com/watch?v=QwiPplYoH7Q&feature=related BIOCHEMICAL ROCKS CALCITE EVAPORITES (CaCO3) HALITE (NaCl) GYPSUM (CaSO4•2H2O) LIMESTONE ROCK SALT ROCK GYPSUM CHERT (SiO2) How would you test for limestone? Metamorphic Rocks & Minerals "Meta" = change "Morph" = form METAMORPHISM OCCURS IN 3 DIFFERENT WAYS: 1.) RECRYSTALLIZATION: Crystals grow larger 2.) FOLIATION: preferential alignment of crystals, metamorphic layering 3.) NEOMORPHISM: existing minerals become unstable and are reconfigured as new minerals, such as garnet, kyanite or sillimanite. http://www.youtube.com/watch?v=bxpOBVAcMHI&feature=related Metamorphism occurs through increased temperature &/or pressure THERE ARE TWO MAIN TYPES OF METAMORPHISM CONTACT METAMORPHISM from Subduction zones & ContinentContinent Convergent Boundaries are increased temperatures occurs around any magma chamber areas of REGIONAL METAMORPHISM METAMORPHIC ROCK TYPES THAT CONTAIN PLATY MINERALS ARE DISTINGUISHED BY THEIR FOLIATION: "Before" "Rock" PROTOLITH SHALE QUARTZ SANDSTONE LIMESTONE 3 Main Rock Types: Igneous, Sedimentary, Metamorphic The Rock Cycle & Tectonics http://eo.ucar.edu/kids/green/cycles8.htm 3 Main Rock Types: Igneous • interlocking crystals • no layers Metamorphic • interlocking crystals • layers Sedimentary • cemented grains (gritty feel common) • layers • may contain fossils Rocks as seen through a microscope (plane light) (x-polars) MELTING A ROCK 1. CHANGES IN TEMPERATURE OR PRESSURE 2. ADDITION OF WATER (from dewatering of minerals) LIQUID Low pressure favors the less dense state Pressure pushes atoms together X X High pressure favors the more dense state SOLID Heat = Energy Energy excites atoms so pushes atoms apart High temperature favors the less dense state LIQUID Water lowers the melting temperature of minerals & rocks