◘ Product Name: EFIRON® UVF
MATERIAL SAFETY DATA SHEET
1. Chemical Product and Company Identification
PRODUCT NAME: EFIRON® UVF
PRODUCT IDENTIFICATION NUMBER(S)
WR-346
SUPPLIER/MANUFACTURER'S NAME:
Company Name: SSCP CO., LTD.
Address: 403-2, Moknae-Dong, Danwon-Ku, Ansan-Si, Kyonggi-Do, Korea, Korea
Telephone number: +82-31-490-3600 / Fax Number: +82-31-492-0450
PREPARATION DATE:
November 19, 2007 REVISED:
November 19, 2008
2. Composition/Information on Ingredients
Chemical name
CAS RN.
Contents (%)
2-Propenoic acid, 2-methyl-, 3,3,4,4,5, 5,6,6,7,7,8,
1996-88-9
5 – 10
13048-33-4
20 – 40
Methanone, (1-hydroxycyclohexyl)phenyl-
947-19-3
1–4
Phenol, 2,6-bis(1,1-dimethylethyl)-4-methyl-
128-37-0
1–2
Ingredients determined not to be hazardous
-
30 – 50
4098-71-9
< 0.1
8,9,9,10, 10,10-heptadecafluorodecyl ester
2-Propenoic acid, 1,6-hexanediyl ester
Isophorone diisocyanate (impurity)
Description
Multifunctional prepolymer.
3. Hazards Identification
EMERGENCY OVERVIEW
Suspect eye, skin and inhalation irritation hazard.
Do not get in eyes, on skin, on clothing. Do not take internally. In case of contact with
eyes, rinse immediately with plenty of water and seek medical advice. After contact
with skin, wash immediately with plenty of soap and water.
EYE CONTACT:
Suspect slight eye irritation hazard
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◘ Product Name: EFIRON® UVF
SKIN CONTACT:
Non Irritant as solid form
Suspect skin sensitization hazard. Prolonged skin contact may cause skin irritation.
INHALATION:
Suspect respiratory tract irritation hazard.
INGESTION:
Not a likely route of exposure. May harmful if swallowed.
CARCINOGENICITY:
None of the substances in this product are listed as human carcinogens by the International
Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), the American
Conference of Governmental Industrial Hygienists (ACGIH) or the Industrial Safety and
Health Law (Industrial Safety Health Law in Korea).
4. First Aid Measures
INHALATION:
Move to fresh air in case of accidental inhalation of vapors. If symptoms persist, call a
physician.
SKIN CONTACT:
Wipe or blot away excess material with clean cloth or paper towel. Wash affected areas
thoroughly with water.
For a large splash, flood body under a shower. If symptoms
develop, seek medical advice.
SWALLOWING:
Give some glasses of water. Induce vomiting. Seek medical advice immediately.
EYE CONTACT:
Immediately flush eye with water for at least 15minutes while holding eyelids open. If
symptoms develop, seek medical advice.
NOTES TO PHYSICIAN:
Based on the individual reactions of the patient, the physician's judgment should be
used to control symptoms and clinical condition.
5. Firefighting Measures
Flash point: 113C
Auto-Ignition Temperature: No data available.
UEL/LEL: No data available.
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◘ Product Name: EFIRON® UVF
FIRE AND EXPLOSION HAZARD:
High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or
oxidizers may cause spontaneous polymerizing reaction generating heat / pressure.
Closed containers may rupture or explode during runaway polymerization.
EXTINGUISHING MEDIA:
Regular dry chemical, carbon dioxide, water and regular foam.
FIREFIGHTING:
Wear self-contained breathing apparatus and protective suit.
HAZARDOUS COMBUSTION PRODUCTS:
May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of
nitrogen (NOx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
Fire fighters should wear NIOSH approved self-contained breathing apparatus and full
protective clothing.
6. Accidental Release Measures
PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete. Stop or
reduce any leaks if it is safe to do so. Avoid contact with skin, eyes and clothing. Do not
touch spilled material. Use personal protective equipment recommended in Section 8
(Exposure Controls/Personal Protection).
ENVIRONMENTAL PRECAUTIONS:
Notify fire authorities and appropriate federal, state, and local agencies. Prevent the
product from spreading into the environment. Avoid direct discharge into drains. It
should not be directly discharged into lakes, ponds, waterways or public water supplies.
METHODS FOR CLEANING UP:
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable,
covered, properly labeled container. Wash affected area.
LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by
diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean
contaminated surfaces with water or aqueous cleaning agents. Contact an approved
waste hauler for disposal of contaminated recovered material. Dispose of all
contaminated materials in accordance with current local regulations.
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◘ Product Name: EFIRON® UVF
7. Handling and Storage
PRECAUTIONS TO BE TAKEN IN HANDLING:
Avoid contact with eyes. Do not take internally. Avoid the formation of mists in the
atmosphere. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
PRECAUTIONS TO BE TAKEN IN STORAGE:
Store in suitable labeled containers. Keep containers closed. Keep away from heat
sources. Keep away from combustible and explosive incompatible materials.
8. Exposure Controls/Personal Protection
INTRODUCTORY REMARKS:
These recommendations provide general guidance for handling this product. Because
specific work environments and material handling practices vary, safety procedures
should be developed for each intended application.
OCCUPATIONAL EXPOSURE LIMITS:
ACGIH/TLV:
- ISOPHORONE DIISOCYANATE
TWA 0.005 ppm
STEL
-
- BUTYLATED HYDROXYTOLUENE (BHT)
TWA 21 mg/m3
STEL
-
ENGINEERING MEASURES:
If vapor or mist is generated when the material is heated or handled, adequate
ventilation in accordance with good engineering practice must be provided to maintain
concentrations above the specified exposure or flammable limits.
RESPIRATORY PROTECTION:
If significant mists, vapors or aerosols are generated an approved respirator is
recommended. An organic vapor cartridge with dust/mist prefilter may be used. If
respiratory protection is required, institute a complete respiratory protection program
including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION:
Wear appropriate chemical resistant gloves.
SKIN PROTECTION:
Wear appropriate chemical resistant clothing. Remove any chemical soaked clothing
immediately.
EYE PROTECTION:
Wear splash resistant safety goggles with a face shield.
HYGIENE RECOMMENDATIONS:
Use good work and personal hygiene practices to avoid exposure. Consider the
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◘ Product Name: EFIRON® UVF
provision in the work area of a safety shower and eyewash. Always wash thoroughly
after handling chemicals. When handling this product never eat, drink or smoke.
9. Physical and Chemical Properties
APPEARANCE:
Liquid, clear
ODOR:
Odorless
SOLUBILITY:
Soluble in organic solvents.
pH:
No data available.
VISCOSITY:
No data available.
FLASH POINT:
113C
Auto-Ignition Temperature:
No data available.
UEL/LEL:
No data available.
BOILING POINT:
No data available.
MELTING POINT:
No data available.
SPECIFIC GRAVITY:
1.43 @ 20℃ (water=1)
VAPOR PRESSURE:
No data available.
VAPOR DENSITY:
No data available.
Octanol/water partition coefficient:
No data available.
MOLECULAR FORMULA:
Not applicable.
Note: These physical properties are typical values for this product and are subject to
change.
10. Stability and Reactivity
STABILITY:
Stable under normal conditions.
Hazardous reactions:
Hazardous polymerization will not occur.
CONDITIONS TO AVOID:
Avoid overheating and flames.
Strong alkaline compounds (alkaline hydroxide, ammonia, and non-aqueous alkalis).
Lewis acid (AlCl3, SbF5, CoF3) above 100°C.
CHEMICAL TO AVOID:
Contact with strong acids and strong base.
HAZARDOUS DECOMPOSITION PRODUCTS:
Acrid smoke-fumes/carbon monoxide/carbon dioxide and perhaps other toxic vapors
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◘ Product Name: EFIRON® UVF
may be released during a fire involving this product.
11. Toxicological Information
ACUTE ORAL TOXICITY:
Rat (LD50) : > 2,000 mg/kg
ACUTE DERMAL TOXICITY:
Rat (LD50) : > 2,000 mg/kg
CARCINOGENICITY:
None of the substances in this product are listed as human carcinogens by the
International Agency for Research on Cancer (IARC), the National Toxicology Program
(NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
Other:
Moderately Toxic: ingestion. Slightly Toxic: dermal absorption.
Skin (rabbits): Non-Irritant as article
Intravenous / intraperitoneal (mouse): No mortality or evidence of systemic toxicity from
the extracts as article [Test facility: MAMSA, Test method: USP guidelines].
12. Ecological Information
ECOTOXICOLOGICAL EFFECTS: No data available.
Possibly hazardous short term degradation products are not likely. However, long term
degradation products may arise.
MOBILITY: No data available.
BIODEGRADABILITY: No data available.
BIOACCUMULATION: No data available.
13. Disposal Considerations
REGULATORY INFORMATION:
All disposals must comply with federal, state, and local regulations. The material, if
spilled or discarded, may be a regulated waste. Refer to state and local regulations.
METHODS OF DISPOSAL:
NATIONAL REGULATIONS, CHINA
Comply with local regulations.
NATIONAL REGULATIONS, INDIA
Dispose of unused product in accordance with the "Hazardous Wastes (Management
and Handling) Rules 1989" and local and State legislation, as applicable.
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◘ Product Name: EFIRON® UVF
NATIONAL REGULATIONS, INDONESIA
Dispose of unused product in accordance with "Government Regulation No.19/1994
On the Treatment of Dangerous And Toxic Waste" (and amendments) as applicable.
NATIONAL REGULATIONS, KOREA
Waste disposal should comply with the Waste Control Act.
NATIONAL REGULATIONS, MALAYSIA
Dispose of in accordance with the Environmental Quality (Scheduled Wastes)
Regulation 1989 and other guidelines issued by DOE and/or local authorities.
NATIONAL REGULATIONS, PHILIPPINES
Dispose of in accordance with Presidential Decree No. 984-1976 ("The Pollution
Control Law"); DENR Department Administrative Order No.29-92 ("The Implementing
Rules or Regulations of RA6969") and Presidential Decree No.825.
NATIONAL REGULATIONS, SINGAPORE
Dispose of waste in accordance with the Environmental Health Act (Chapter 95, Rg 11),
Environmental Public Health (Toxic Industrial Waste) Regulations 1990 Ed.
NATIONAL REGULATIONS, THAILAND
Dispose of hazardous waste in accordance with the "The Notification of the Ministry of
Industry No. 6B.E. 2450, subject: Disposal of Wastes or Unusable Materials ", "The
Notification of the Ministry of Industry No. 1B.E. 2451, subject : Disposal of Wastes or
Unusable Materials ".
14. Transport Information
INTERNATIONAL REGULATIONS:
The information in this section is for reference only and should not take the place of a
shipping paper specific to an order. Please note that the proper Shipping Name /
Hazard Class may vary by packaging, properties, and mode of transportation.
LAND TRANSPORT:
Proper Shipping Name: Not classified.
AIR TRANSPORT (ICAO/IATA):
Proper Shipping Name: Not classified.
MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name: Not classified.
TRANSPORT INFORMATION:
Keep containers tightly closed. Not hazardous product according to these transport
classifications.
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◘ Product Name: EFIRON® UVF
15. Regulatory Information
₪ Regulation under Industrial Safety and Health Law in Korea: Not regulated.
₪ Korean Toxic Chemicals Control Law (TCCL)
All components of this product are listed, or are exempt from listing, on the
Korean Existing Chemicals List (ECL).
Chemicals Prohibited or Restricted from Manufacturing, Importing or Using None of the components of this product are regulated by this section of TCCL.
Observational Chemicals List - None of the components of this product are
regulated by this section of TCCL.
Toxic Chemicals List - None of the components of this product are regulated by
this section of TCCL.
₪ INVENTORIES:
₪ TSCA: Substances in this product are included on or exempted from the TSCA 8(b)
Inventory (40 CFR 710).
₪ EUROPE: Substances in this product have been reviewed for compliance with the
EINECS or ELINCS inventories.
₪ AUSTRALIA: Substances in this product comply with the National Industrial
Chemicals Notification & Assessment Scheme (NICNAS) and are listed on the
Australian Inventory of Chemical Substances (AICS).
₪ CHINA: Substances in this product comply with the Chemical Control Law and are
listed on the Inventory of Existing Chemical Substances China (IECSC).
₪ JAPAN: Substances in this product comply with the Law Regulating the Manufacture
and Importation of Chemical Substances and are listed on the Ministry of Economy,
Trade and Industry (METI).
₪ Chemical Weapons Convention (CWC)
This product does not contain any chemicals listed under the Chemical Weapons.
₪ EPCRA (SARA Title III) Section 302 Extremely Hazardous Substance (EHS) (40
CFR 355, Appendix A)
CAS RN: 4098-71-9
Name: ISOPHORONE DIISOCYANATE
The EHS Reportable Quantity (RQ) is 100 lbs.
Threshold Planning Quantity is 500 lbs.
Note(s): 40 CFR 355, App. A & B. Final rule at 68 Fed. Reg. 52978 (9/8/2003);
effective date 10/8/2003. Raised the threshold planning quantity to 500 pounds
(formerly 100 pounds).
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◘ Product Name: EFIRON® UVF
₪ U.S. EPCRA (SARA Title III) Section 313 Toxic Chemical (Reporting Form R
Instructions for 2004, as amended by 70 FR 37698, 6/30/2005)
CAS RN: 4098-71-9
Name: ISOPHORONE DIISOCYANATE
De Minimis Concentration for Section 313 is 1.0 %.
De Minimis Concentration for Section 313 is 1.0 %.
Note(s): SARA Section 313 requires reporting this substance as a member of
the category, 'Diisocyanates'. 40 CFR 372.27. Final rule at 59 Fed. Reg. 61488
(11/30/94). The EPA established an alternative EPCRA sec. 313 reporting
threshold for covered facilities with low annual releases of toxic chemicals. A
facility which estimates that its annual reportable amount of a toxic chemical
does not exceed 500 pounds may apply an alternate 'manufacture, process, or
otherwise use' threshold of 1 million pounds to that chemical, provided that
certain conditions in the rule are met. Eligible facilities submit a special
certification under 40 CFR 372.95 in lieu of a report under 40 CFR 372.30. 40
CFR 372.27 and 327.95 contain information collection and recordkeeping
requirements and will not become effective until approval has been given by
OMB.
₪ US Federal Regulations:
California. Air Toxics Hot Spots Information and Assessment Act, Emission Inventory
Criteria and Guidelines Report, Appendix A, July 1996.
CAS RN: 4098-71-9 regulated as a member of the Generics group for CAS
RN: SEQ500457
Generics group name: ISOCYANATES
Listed in Appendix A-I (Substances For Which Emissions Must Be Quantified)
California Air Resources Board Emittent Code: 1125
Applicable degree of accuracy: 0.05 pounds/year.
California Hazardous Substances List ('Director's List') (Calif. Admin. Code, tit. 8, sec.
339)
CAS RN: 128-37-0
Name: 2,6-DI-TERT-BUTYL-P-CRESOL
Citation codes: Exempt when used in foods and feeds as a preservative.
Illinois Toxic Substances Disclosure to Employees Act (Ill. Rev. Stat. ch. 48, para. 1403)
CAS RN: 4098-71-9
Name: ISOPHORONE DIISOCYANATE
CAS RN: 128-37-0
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◘ Product Name: EFIRON® UVF
Name: 2,6-DITERT. BUTYL-P-CRESOL
Massachusetts Right-to-Know Substance List (Mass. Gen. Laws Ann. ch. 111F)
CAS RN: 4098-71-9
Name: ISOPHORONE DIISOCYANATE
MA Extraordinarily Hazardous Substance (1 ppm threshold)
CAS RN: 128-37-0
Name: 2,6-DITERT. BUTYL-P-CRESOL
Note(s): Mass. Regs. Code tit. 105, sec. 670.000, app. A. Final rule at 706
Mass. Reg. 58 (2/12/93). Source list, hazard, and/or footnote designations
previously assigned to this chemical substance were "corrected" by the State
effective 4/24/93.
Minnesota Hazardous Substances List (Minn. Rules 5206.0400) (05/01/2000)
CAS RN: 4098-71-9
Name: ISOPHORONE DIISOCYANATE
MN skin designation applies
North Carolina Exposure Limits for Air Contaminants (N.C. Administrative Code, Title
13, Subchapter 7F, Section 0101, Table Z-1, Limits for Air Contaminants)
CAS RN: 4098-71-9
Name: ISOPHORONE DIISOCYANATE
Skin Designation
TWA is 0.005 ppm.
STEL is 0.02 ppm.
New Jersey Community Right-to-Know Survey 2001, Table A: N.J. Environmental
Hazardous Substances (EHS) List (N.J. Admin. Code tit. 7, sec. 1G-2.1)
CAS RN: 4098-71-9
Name: ISOPHORONE DIISOCYANATE
NJ Substance Number 1068
NJ Assigned DOT Number 2290
NJ Reporting Threshold is: 100 lbs.
New Jersey Right-to-Know Substances (N.J. Stat. Ann. Section 34:5A-5)
CAS RN: 128-37-0
Name: 2,6-DITERT. BUTYL-P-CRESOL
NJ Substance Number 0814
Pennsylvania Right-to-Know Hazardous Substances (34 Pa. Code Chap. 301-323)
CAS RN: 4098-71-9
Name: CYCLOHEXANE, 5-ISOCYANATO-1-(ISOCYANATOMETHYL)-1,3,3-
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◘ Product Name: EFIRON® UVF
TRIMETHYLPA Environmental Hazard (subject to release reporting)
CAS RN: 128-37-0
Name: PHENOL, 2,6-BIS(1,1-DIMETHYLETHYL)-4-METHYLMinnesota Hazardous Substances List (Minn. Rules 5206.0400) (05/01/2000)
CAS RN: 3290-92-4
Name: TRIMETHYLOLPROPANE TRIMETHACRYLATE
IARC. Overall Evaluations of Carcinogenicity
CAS RN: 128-37-0
Name: BUTYLATED HYDROXYTOLUENE (BHT)
IARC Overall Evaluation is 3 (not classifiable as to carcinogenicity in humans)
Citations: IARC Monographs on the Evaluation of Carcinogenic Risks to
Humans, Overall Evaluations of Carcinogenicity: An Updating of Vols. 1 to 42,
Supplement 7, 1987.
IARC. Evidence of Carcinogenicity
CAS RN: 128-37-0
Name: BUTYLATED HYDROXYTOLUENE (BHT)
Citations: V40, S7
IARC Evidence of Carcinogenicity in Humans is: N (No data)
IARC Evidence of Carcinogenicity in Animals is: L (Limited data)
₪ CANADAN
Canada. WHMIS Ingredient Disclosure List (Can. Gaz., Part II, Vol.122, No.2, January
20, 1988)
CAS RN: 4098-71-9
Name: ISOPHORONE DIISOCYANATE
Canada's WHMIS item number from English Ingredient Disclosure List is: 900
Canada's WHMIS Concentration Threshold is 0.1 %.
CAS RN: 128-37-0
Name: BUTYLATED HYDROXYTOLUENE (BHT)
Canada's WHMIS item number from English Ingredient Disclosure List is: 238
Canada's WHMIS Concentration Threshold is 1 %.
₪ Mexico. Hazard Identification Guidance List (NOM-018-STPS-2000)
CAS RN: 4098-71-9
Name: DIISOCIANATO DE ISOFORONA
Diamond Label Health Hazard: 2
Diamond Label Flammability Hazard: 1
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◘ Product Name: EFIRON® UVF
Diamond Label Reactivity Hazard: 1
Diamond Label Special Hazard (see notes): W
Rectangular Label Health Hazard: 2
Rectangular Label Flammability Hazard: 1
Rectangular Label Reactivity Hazard: 1
Rectangular Label PPE Code (see notes): B
CAS RN: 128-37-0
Name: DITERBUTIL-P-CRESOL, 2,6Diamond Label Health Hazard: 2
Diamond Label Flammability Hazard: 1
Diamond Label Reactivity Hazard: 0
Rectangular Label Health Hazard: 4
Rectangular Label Flammability Hazard: 1
Rectangular Label Reactivity Hazard: 0
Rectangular Label PPE Code (see notes): F
NOTE: The regulatory information given above only indicates the principal regulations
specifically applicable to the product described in the Safety Data Sheet. The user's
attention is drawn to the possible existence of additional provisions which complete
these regulations. Refer to all applicable national, international and local regulations or
provisions.
16. Other Information
This above information is believed to be correct but does not propose to be all inclusive
and shall be used only as a guide. LUVANTIX CO., LTD. shall not be held liable for any
damage resulting from handling or from contact with the above product. Each individual
should make a determination as to the suitability of the information for their particular
purpose(s). Various government agencies may have specific regulations regarding the
transportation, handling, storage, use, or disposal of this product which may not be
covered by this MSDS. The user is responsible for full compliance.
* Technical Support on MSDS Preparation: RGB Chemicals (http://rgbchemicals.com)
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