Substance Non polar covalent (Molecular) Ionic character 0 Bond type Non polar Polar Covalent (molecular) .4-1.7 ( below .4 are considered weakly polar) 0-.4 Polar Non polar or weakly polar covalent Large covalent network crystal IONIC Above 1.7 none METALLIC “sea of electrons” 0 none None- exists as solid crystal lattice or as ions in solution. None-metallic ions in sea of electrons Electrostatic (ionic) Forms solid crystal lattice Van Der Waals, strong in the heavier metals Co-ordinate Covalent Graphite Varies covalent Dipole 0 covalent Most are polar polyatomic ions Network crystal GENERAL Subtract electronegativity of the two atoms in the bond or crystal Ionic character Does it form independent molecular units Determined by bonds Covalent Network Crystal Molecule type Non Polar, includes symmetrical with polar bond Asymmetrical with polar bond Attractions Van Der Waals Properties Examples Very low N2, O2, CO2, M.P./B.P., soft,non CH4, CF4 conductor Dipole, H-Bonding if H is present. Most have none, actual covalent bonding. Low M.P./B.P. Soft Non conductors Very High M.P./B.P. Nonconductors Very Hard High M.P/B.P Liquid, aqueous conductors. Hard Solid state conductors Ductable,malleable Lustrous As in polar covalent Strong covalent sheets, attracted by van der walls attractions Determined by attractions (M.P./B.P.) and electron mobility. Van Der Waals H2O, NH3, CCL3F, H2S Diamond SiO2 (glass) -Group one salts -Active metal with active nonmetal Au, Fe, Ag, group 1 etc, Metals on periodic table NH4+ Only covalent solid state conductor