LOYOLA COLLEGE (AUTONOMOUS), CHENNAI – 600 034 B.Sc. DEGREE EXAMINATION – CHEMISTRY FIRST SEMESTER – NOVEMBER 2012 MT 1102 - MATHEMATICS FOR CHEMISTRY Date : 03/11/2012 Time : 1:00 - 4:00 Dept. No. Max. : 100 Marks Part A Answer ALL questions: (10 x 2 =20) −1 1. Differentiate 𝑒 𝑠𝑖𝑛 𝑥 with respect to 𝑠𝑖𝑛−1 𝑥. 2. Find the slope of the tangent at (2,4) to the curve 𝑦 = 10 − 4𝑥 + 10𝑥 2 𝑎 3. Change the limits of 𝐼 = ∫−𝑎 𝑓(𝑥) 𝑑𝑥 as lower limit to 0 and upper limit to 𝑎. 4. Solve 𝑑2 𝑦 𝑑𝑥 2 𝑑𝑦 − 5 𝑑𝑥 + 4𝑦 = 0. 5. 6. 7. 8. 9. State Binomial theorem. Solve the partial differential equation 𝑝 = 𝑦 2 𝑞 2 . State DeMoivre’s theorem. Show that cos ℎ2 𝑥 + 𝑠𝑖𝑛ℎ2 𝑥 = cos ℎ2𝑥. From a well-shuffled pack of 52 cards, one card is drawn at random. What is the probability that it will be (i) a jack (ii) a spade? 10. Define Normal distribution. Part B Answer any 5 questions: (5 x8 = 40) 11. Find the angle of intersection of the cardioids 𝑟 = 𝑎(1 + cos 𝜃) and 𝑟 = 𝑏(1 − cos 𝜃). 12. If 𝑦 = 𝑐𝑜𝑠ℎ−1 𝑥 , then show that 𝑦 = log(𝑥 + √𝑥 2 − 1). 13. Evaluate: (i) x 2e x dx , using Bernoulli’s formula. (ii) Evaluate: 2 1 (sin x) 2 (sin x) 0 1 2 1 (cos x) 2 dx. . (4+4) 14. Solve the differential equation (3𝐷2 + 𝐷 − 14)𝑦 = 13𝑒 2𝑥 . 15. Find the sum of the series 1 + 1+3 2! + 1+3+32 3! 𝑢 + 1+3+32 +33 4! sin 2𝑥 +⋯ ∞ 16. If tan(𝑥 + 𝑖𝑦) = 𝑢 + 𝑖𝑣, then show that 𝑣 = sinh 2𝑦 17. Obtain the expansion of tan 𝑛𝜃. 18. Find the maxima and minima of the function 2𝑥 3 − 3𝑥 2 − 36𝑥 + 10. Part C Answer any TWO questions: (2 x 20 = 40) 19. (i) Evaluate: ∫(log 𝑥)2 𝑑𝑥. 𝜋 𝜋 1 (ii) Prove that ∫02 log sin 𝑥 𝑑𝑥 = 2 log(2). (10+10) 20. (i)Obtain the characteristic roots and the associated characteristic vectors of the 6 −2 2 matrix = [−2 3 −1] . 2 −1 3 (ii) Solve the partial differential equation with usual notations 𝑝 + 𝑞 = 𝑥 + 𝑦. (15+5) 1 21. Given that 𝑓(𝑥) = 2 (𝜋 − 𝑥) in the interval 0 to 2𝜋. Find the Fourier coefficients 𝑎𝑛 and 𝑏𝑛 .Hence 1 1 1 𝜋 deduce that 1 − 3 + 5 − 7 + ⋯ = 4 . 22. (i)Expand 𝑠𝑖𝑛4 𝜃. 𝑐𝑜𝑠 2 𝜃 in series of cosines of multiples of 𝜃. (ii)The mean mark of 100 students were found to be 40. Later it was observed that a score of 53 was misread as 83. Find the correct mean using the correct score. (14+6)