Spiral Notes Periodic Table Trends 1. Valence electrons are located in the outermost energy level (P.E.L) 2. Atomic Radius: size of atom 3. Ionization Energy (I.E.): energy required to lose 1st e- from neutral atom 4. Electron Affinity (E.A.): energy required to gain an e- to a neutral atom (sometimes energy is given off) 5. Electronegativity (E.A.): the tendency to attract e- (a scale from 0.0 “Fr” 4.0 “F” ) Linus Pauling developed this scale not from research Stability of e- configuration Least stable Most Stable p.1 any e- configuration Half full S.L. s1, p3, d5, f7 Full sublevel s2, p6 ,d10, f14 Full outer level s2p6 d10, f14 Important Factors for Ion Formation I.E.&E.A. 1. + - Attraction or repulsion (-,-) or (+,+) 2. e- shielding: # electrons between nucleus & outer valence electrons 3. Radius: distance from nucleus; different 3 of Energy Levels 4. Most stable sublevels: full or ½ full Coulomb’s Law F= q1q2 d2 F = Force of attraction or repulsion d= distance between particles q= charge of particle Atomic Radius (A.R.) Radius of a neutral atom = Atomic radius 1. Size of the atom – defined as ½ distance between nuclei of identical atoms joined in a molecule (nucleus is 1/10,000 diameter of the atom) 2. A.R. decreases across the period because more (+protons nucleus) & more electrons in the same E.L. (Group I to Group VIII in a period) Reason: Attraction increases at same E.L. pulling atom more tightly together 3. A.R. increases down group Trend Reason: adding E.L. therefore valence electrons further away from the nuclear Pull or Attraction Decreasing across period Increasing down family p.2 Cl Cl F Cl p.3 H F Ionic Radius 1. Radius of a charged atom =Ionic Radius (charge must be specified) Ionization Energy (I.E.) 1. I.E. opp. Trend from A.R. Across period I.E. increases Reason: because e- held more tightly closer to nucleus and more difficult to remove from atom 2. I.E. decreases down the group because e- further away from nucleus i.e. pull of attraction; easier to remove an e- from atom 3. I.E. + A 1e- + A+ A+ is a Cation + 4. The energy required to remove 1e- from an atom p.2 1st I.E graph 2nd I.E. 3rd I.E. p.4 Electron Affinity (E.A.) 1. Electron Affinity is an amount of energy 2. Energy added or released Endo or Exo 3. A+ e- Aforms an anion 4. Elements in Groups VA Have an attraction for e- VIA VIIA High E.A. The Goal of ion formation is to reach a N.G. e- configuration __________________________________________________ Which is larger, the Atom or the Ion? Cl or Cl-1 uses E.A. Energy because __________________________________ Na or Na+1 I.E. (costs energy) ___________________________________________ p.5 Electronegativity Ionization Energy Atomic Radius Metallic Character Nonmetallic Character Trend s Across Period D o w n Summary Periodic Trends A.R. Greater Radius Smaller Radius Lower I.E. E.A. E.N. scale Greater I.E. E.A. E.N. scale p. 6