PHYS-4420 THERMODYNAMICS & STATISTICAL MECHANICS SPRING 2006 Class Activity - Class 20 April 4, 2006 Name_____________SOLUTION_____________ Two different solids consist of the same number of atoms, and the speed of sound is the same in both. However, the spacing between atoms in solid A is twice as great as the spacing between atoms in solid B. According to the Debye model: a) For which solid will the Debye temperature be greater? (Circle the correct answer.) SOLID A SOLID B THEY ARE EQUAL By what factor will it be greater? 1/3 D c 2 N D 6 . If the distance between atoms in A is twice as big as in B, and k k V each has the same number of atoms, the volume of the solid A will be larger than the volume 1 N N of solid B by a factor of 2³ = 8. Then, . V A 8 V B D, A c 2 N 6 k V A 1/ 3 c 2 1 N 6 k 8 V B 1/ 3 1 c 2 N 6 2 k V B 1/ 3 1 D ,B 2 D,B is larger. D,B = 2D,A Factor = _____2___________ b) At low temperatures, which solid will have the greater heat capacity? (Circle the correct answer.) SOLID A SOLID B THEY ARE EQUAL By what factor will it be greater? 12 Nk 4 T In class you saw that the heat capacity at low temperatures equaled, CV . 5 3 12 Nk 4 T 5 D, A 3 3 C D , B 23 8 Then, V , A 3 CV , B 12 Nk 4 T D, A 5 D, B Factor = _____8___________