6.2.1 Elements on Planet Earth The Science of Elements….. • Has progressed from the “earth, air, water, fire” theory proposed by the ancient Greeks to the current idea that elements are composed of atoms. • Here we will put the early theory into a modern context as we look at the elements found in air (the atmosphere), water (the hydrosphere) and Earth (the crust or lithosphere). Air: Elements in the Atmosphere The Atmosphere usually refers to a gaseous envelope surrounding a planet. The earth's atmosphere is a very thin layer wrapped around a very large planet. Two gases make up the bulk of the earth's atmosphere: nitrogen (N2 ), which comprises 78% of the atmosphere, and oxygen (O2 ), which accounts for 21%. Various trace gases make up the remainder. Air: Elements in the Atmosphere Earth has a radius of some 6400 km. Ninety-nine percent of the earth's atmosphere is contained within a layer approximately 50 km thick. Life on earth inhabits a layer no more than 9 km thick, extending from a bare few kilometers above sea level (airborne organisms and life on mountains) to a few kilometers below (deep ocean basin creatures and subterranean microbial communities). Air: Elements in the Atmosphere The biosphere is the portion of earth in which all known life forms exist. It occupies a thin layer of air (atmosphere), water (hydrosphere), and land (lithosphere). Air: Elements in the Atmosphere The thin envelope of air that surrounds our planet is a mixture of gases, each with its own physical properties. The mixture is far from evenly divided. Two elements, nitrogen and oxygen, make up 99% of the volume of air. The other 1% is composed of "trace" gases, the most prevalent of which is the inert gaseous element argon. The rest of the trace gases, although present in only minute amounts, are very important to life on earth. Two in particular, carbon dioxide and ozone, can have a large impact on atmospheric processes. Air: Elements in the Atmosphere Photosynthesis and Respiration make use of the elements, hydrogen, oxygen, and carbon, cycling them through the atmosphere. Respiration: glucose + oxygen carbon dioxide + water + energy Photosynthesis: sunlight + carbon dioxide + water glucose + oxygen Water: Elements in the Hydrosphere Hydrosphere refers to all the water that occurs at the Earth’s surface. Water, in its different forms, cycles continuously through the lithosphere, hydrosphere, atmosphere, and biosphere. Water evaporates into the atmosphere from the land and the sea. Plants and animals use and reuse water and release water vapour into the air. Once in the air, water vapour circulates and can condense to form clouds and precipitation, which fall back to earth. At one time or another, all of the water molecules on earth have been in an ocean, a river, a plant, an animal, a cloud, a raindrop, a snowflake, or a glacier! Water: Elements in the Hydrosphere The water cycle Water is essential for life on earth. It is recycled through the water or hydrologic cycle, which involves the following processes: Evaporation, Condensation, Sublimation, Precipitation, Transpiration, Surface runoff, Infiltration, and Percolation. Earth: Elements in the Crust Lithosphere: • The outermost layer of the Earth's crust consisting of a mosaic of rigid plates of granite type rock. These plates float upon a solid, but plastic layer of rock called the asthenosphere. • The Lithosphere varies in depth from approximately 10 km under the oceans to 30 km under the continents. • The Lithosphere includes all land surface and soil, but not the organisms. Also includes the ocean bottom, but not organisms. Earth: Elements in the Crust The lithosphere contains all of the cold, hard solid land of the planet's crust (surface), the semi-solid land underneath the crust, and the liquid land near the centre of the planet. Elements found in the earth’s crust are O, Si, H, Cl, P, C, S, Ar, N, and F Different Kinds of Elements • Metals, most of the elements in the periodic table. E.g., C,O,N, F,S,…. • Non-metals, over half of the non-metals are gases at room temperature. E.g., Al, Fe, Ca, Na, K, Mg, Ti, Mn,…. • Metalloids, the transition from metal to nonmetal on the periodic table is not sharp. Some of the elements along the border have properties that are intermediate between metals and non-metals. E.g., B, Si, Ge, As, Sb, Te,….. State Appearance Metals • solids at room temperature, except for mercury (a liquid) • shiny lustre NonMetals • some gases • not very at room shiny temperature • some solids • only one liquid (bromine) Metalloids • solids at room temperature • can be shiny or dull Conductivity Malleabiility and Ductility • good conductors of heat and electricity • malleable • ductile • poor conductors of heat and electricity • brittle • not ductile • may conduct electricity • poor conductors of heat • brittle • not ductile