Chapter 2 – Atoms, Molecules, and Ions Prof. Kweyete 1. Determine the number of protons, electrons, and neutrons in the followings: a) 65 Zn => 30p, 35n, 30eb) cobalt-60 => 27p, 33n, 27ec) sodium => 11p, 12n, 11e52 3+ d) Cr => 24p, 28n, 21e130 e) I => 53p, 77n, 54e2. For each of the following elements, write its chemical symbol or name, and indicate the type and group to which it belongs: a) potassium K, metal, group 1 b) arsenic As, semimetal, group 5 c) iodine I, nonmetal, group 7 d) iron Fe, metal, transition metal e) Ca Calcium, metal, group 2 3. Determine the empirical formulas for the following compounds: a) C6H10O2 C3H5O b) Si3O9 SiO3 c) N2O4 NO2 e) CH4 CH4 f) S4N4 SN 4. Predict the a) Al b) OH c) O d) SO4 e) HSO3 f) ClO charges of the ions of the followings: (+3) (-1) (-2) (-2) (-1) (-1) 5. Predict the empirical formula for the ionic compounds formed by following: a) Ca2+ , PO43Ca3(PO4)2 + b) K , NO3 KNO3 3+ c) Al , OH Al(OH)3 2+ d) Ba , HCO3 Ba(HCO3)2 6. Predict whether each of the following compound is molecular (M) or ionic (I): a) NaClO (I) e) AlN (I) b) NOCl (M) c) CoCO3 (I) d) SCl2 (M) 7. Give names or chemical formulas for the following acids: a) H2S hydrosulfuric acid b) Nitric acid HNO3 c) perbromic acid HBrO4 d) HI hydroiodic acid e) H2SO3 Sulfurous acid g) Acetic acid HC2H3O2 f) HClO2 h) HCN Chlorous acid hydrocyanic acid 8. Provide names or chemical formulas for the following: a) Cr(NO3)3 Chromium(III)nitrate c) Cr2O3 Chromium(III) oxide e) Lead(IV) acetate Pb(C2H3O2)4 g) S4N4 tetrasulfur tetra nitride b) silver nitrate AgNO3 d) Fe(NO2)2 Iron(II) nitrite f) dinitrogen trioxide N 2O 3 h) KClO potassium hypochlorite 9. Give a chemical formula or name for the followings: a) chlorate ion ClO3b) oxide ion O-2 c) barium ion Ba+2 d) hydrogencarbonate ion HCO3e) HSO3bisulfite ion f) S2- sulfide ion g) Fe3+ Iron(III) ion h) H3O+ hydronium ion 10. Naturally occurring magnesium has the following isotopic abundances: Isotope Abundance Mass Mg-24 78.70% 23.98504 Mg-25 10.13% 24.98584 Mg-26 11.17% 25.98259 Calculate the average atomic mass of magnesium. (0.787)(23.98504) + (0.1013)(24.98584) + (0.1117)(25.98259) = 24.31 amu 11. What is the difference between hydroacid and oxyacid? Give two examples of each. Hydroacids do not have oxygen in their formula (HCl, HBr) Oxyacids contain oxygen in their formula (HNO3, H2SO4)