Diodes Properties of SWNT Networks Bryan Hicks Diodes and Transistors An ever increasing number in an ever decreasing area Why Carbon Nanotubes? • Ballistic transport –Low power • No chemical passivation necessary allows for a variety of different insulators • Current densities of 109 A/cm2 vs. 103 A/cm2 for silicon • Huge mobility for high speed devices • Can be semi-conducting or metallic Carbon Nanotube Networks • Random networks of tubes • Low resistance at CNT junctions • No processing necessary • 1/3 metallic 2/3 semiconducting • Have properties of both metals and semiconductors Fabrication Process • Deposit Al and Au electrodes on to a Si02/Si chip with SWNT networks • Wire bond the electrodes to a chip carrier Actual Devices Current Rectification Properties Maximum Current Capacities: Device 1: 8 μA & Device 2: 22 μA On/off ratios: Device 1: 20 & Device 2: 5 Devices 1 and 2 Current (µA) 25 20 15 10 5 0 -5 -10 Device 1 Device 2 -4 -2 0 Voltage (V) 2 4 Current Rectification Properties Device 3 Current (µA) 800 600 400 200 0 -200 -4 -2 0 Voltage (V) 2 Maximum Current Capacities: 678.9 μA On/off ratios: 27 4 Current Rectification Properties Device 4 1000 Current (µA) 800 600 Trial 1 Trial 2 400 200 0 -200 -4 -2 0 2 4 Voltage (V) Maximum Current Capacities: 840 μA On/off ratios: 108 Current Rectification Properties Device 5 Current (uA) 1000 500 0 -500 -1000 -4 -2 0 Voltage (V) 2 Maximum Current Capacities: 840 μA On/off ratios: ?? 4 Gate Voltage Characterization Gate Voltage Dependence Current (nA) 650 550 450 350 250 -12 -8 -4 0 4 Gate Voltage (V) •Current decreases as carriers are removed •Current increases as carriers are introduced •The hysteresis seen is due to trapping seen in other CNT transistors as well 8 12 Summary • Carbon Nanotube Networks present an economic way to incorporate CNT properties into macroelectronics • Current Rectification seems to be a product of contact resistance and is often lost when various scans are made. Sources • C. Lu, L. An, Q. Fu, J. Liua, H. Zhang and J. Murduck. Appl. Phys. Lett. 88, 133501 (2006) • P. Avouris, J. Appenzeller, Richard Martel, And S. J. Wind. Proceedings of the IEEE. 91, 11 (2003)