Announcements 9/13/10 5 students still haven’t registered their clickers. Be sure to register them via the course website. a. Check your scores via the course website! – Make sure you have scores listed under the “Clicker Quizzes” category. Mathematica T-shirt today in honor of the first Mathematica problem due tonight. Mathematica is available in N212, N337, and possibly other computer labs. a. To get into those two rooms, you need the combination from dept secretary Diann. b. To use the computers in those rooms, you need a departmental computer account (form on dept website, under “computer support”). I will hold my office hours in N337 today, and will go over the “Basic commands of Mathematica” handout from course website. Hopefully several computers will be available. TA’s office hours still in underground lab. Quick Writing In light of what we discussed last lecture, how would you describe temperature on the microscopic level? Height Histogram (made up data): Total students = 49 Round heights to closest integer, plot histogram What is the combined area of all bars? If I pick a student at random, what are chances he/she will be 68 inches tall? What is the area of the bar at 68 inches divided by the total area? How many students will be exactly 68.000000 inches tall? If I pick a student at random, what are chances he/she will be 61.5-64.5 inches tall? What is average height of all students? (At least, how would you figure that out?) 7 6 Number of students 5 4 3 2 1 0 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 Height (inches) “Normalized” Histogram: Total students = 49 Y-axis now divided by total # of students. What is combined area of all bars? If I pick a student at random, what are chances he/she will be 61.5-64.5 inches tall? (At least, how would you figure that out?) How many students have heights between 61.5 and 64.5 inches? What is average height of all students? 0.14 0.12 #students / total # students 0.10 0.08 0.06 0.04 0.02 0.00 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 Height (inches) Probability Distribution Function 0.10 #students / total # students 0.08 0.06 0.04 0.02 0.00 50 55 60 65 70 75 80 Height (inches) Imagine total # =10 billion. Tiny “bins”. Connect peaks of curve with line… becomes a function What is combined area of all bars? If I pick a person at random, what are chances he/she will be 63.6-67.2 inches tall? How many people have heights between 63.6 and 67.2 inches? What is average height of all people? (If a non-symmetric curve, this is not just the peak of the curve.) Velocity Distribution: “Maxwell-Boltzmann” f (v) v e 2 12 mv2 kBT Where does this eqn come from? Wait a few weeks. 300 K # molecules / total # molecules 0.0020 0.0015 600 K 900 K 0.0010 0.0005 0.0000 0 200 400 600 800 1000 speed (m/s) 1200 1400 1600 with some constants out in front to normalize it How many molecules with speeds between 200 and 300 m/s? What is “vmost probable”? What is “vaverage”? What is “vrms”? How many molecules are at exactly the “most probable” velocity? Calvin and Hobbes, Bill Watterson Calvin and Hobbes, Bill Watterson Calvin and Hobbes, Bill Watterson Calvin and Hobbes, Bill Watterson Thought question An ideal gas has a mixture of heavy and light monatomic molecules at the same temperature. Which molecules will have the most kinetic energy (on average)? a. heavy b. light c. same Heat = not a fluid! Sir Benjamin Thompson, Count Rumford, 1753-1814 a. Boiling water with a cannon Image credit: Wikipedia James Joule, 1818-1889 Image credit: Wikipedia Demo/Video Demo: Boiling water with a vacuum Video: Boiling water in a paper cup Reading Quiz What name do we give to the heat capacity per unit mass? a. entropy b. internal energy c. mass-pacity d. normalized heat capacity e. specific heat Specific Heat Q=mcDT Thought Question If you add 500 J of heat to a mass of water, and 500 J of heat to the same mass of copper, which one increases the most in temperature? a. Water b. Copper c. Same Reading Quiz Thermal energy that is used to melt or freeze something is called: a. latent heat b. mass heat c. melty-freezy heat d. molar heat e. specific heat Phase Changes Water boiling 100o C Water boils T Ice melting 0o C Ice melts Heat energy added (Q) Ice warming Water warming Steam warming Latent Heats Thought Question If you want to melt a cube of ice that’s initially at -40 C, which part takes the most energy? a. Raising the temperature b. Converting from solid to liquid phase c. Same Calorimetry Worked problem (class designed): ____ grams of hot iron at _____ C is added to ____ g of water at _____ C in a styrofoam insulated container. What is the final temperature of the mixture? (Neglect the container.) ciron = 448 J/kgC cwater = 4186 J/kgC Lwater-steam = 2.26 106 J/kg