UV metal-semiconductor-metal detectors J.-L. Reverchon, M. Mosca N. Grandjean, F. Omnès, F. Semond, J.-Y. Duboz CRHEA-CNRS, rue Bernard Gregory, Sophia Antipolis 06560 Valbonne, France DCO - 10/04/00 L. Hirsch 1 IXL-CNRS-ENSEIRB, University of Bordeaux I 33405 Talence, France THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Thales Corporate Research Laboratory 91404 Orsay Cedex, France Specifications for UV detection Combustion optimization Medical: UVA / UVB control Air contamination control Fire / Flame detection Solar blind missile launching detection (λ<300nm) DCO - 10/04/00 Specifications 2 Dark current: as small as possible Low noise: smallest (avoid 1/f) Spectral selectivity: huge rejection Responsivity: as large as possible Linearity: photocurrent proportional to incident power Time response: reasonably fast, 50Hz THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Applications AlGaN for UV detection Physical properties => UV detection Difficulties with AlGaN Difficulties for n and p doping with high aluminum contents Almost no GaN substrate =>Lattice and thermal expansion mismatches DCO - 10/04/00 =>Strain, dislocations, defects… 3 =>Traps, recombination centers THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 AlGaN is a III-V direct band gap semiconductor Band gap from 3.43 eV (GaN) to 6.2 eV (AlN) Metal-semiconductor-metal detectors characteristics Photoconductors: large responsivity : R ~ µτlife Photovoltaic detectors: (p.i.n., Schottky diodes, MSM) Small responsivity (η < 1) DCO - 10/04/00 But low noise => High 4 detectivity p.i.n.: p doping of AlGaN difficult Schottky diodes MSM detectors => this study THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 large mobility, controlled lifetime ? => Detectivity limited by 1/ f noise (I2/f), large Idark Structures for MSM detectors block ∆V Photovoltaic detectors Efficiency < 1 ⇒ responsivity < 0.23 A/W @286 nm Schottky contacts ⇒ Idark limited DCO - 10/04/00 Short time response: transit time 5 Lower parasitic effects on responsivity THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 hν Table of contents •Material growth Choice of nucleation layer MBE grown samples Band gap versus stress and Al content Samples grown on Al2O3 Activity of cracks DCO - 10/04/00 Band edge absorption broadening 6 •Transport properties •Technological optimization •Performances THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Samples structure for UV detection MOCVD grown samples Samples structures for UV detection Thick Al.3Ga.7N layer on Al2O3 Al2O3 •Thick layer => less dislocations Idark< 10 pA @ 100 V -1 10 -2 10 -3 10 -4 10 -5 100V 10V 3.0 DCO - 10/04/00 •Rejection rate: 5 decades 7 •No surface effect But front side illumination ! THALES Research & Technology 3.5 4.0 Energy (eV) 4.5 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Responsivity (A/W) Al.3Ga.7N 1.2µm 10 Samples structures for UV detection Al.3Ga.7N / Al.4Ga.6N on Al2O3 1 Al.4Ga.6N Active layer Al.3Ga.7N 0.35µm Window layer Al.4Ga.6N 1 µm Al2O3 Transmission (a.u.) 6 4 2 0.1 6 4 2 0.01 Al.3Ga.7N + Al.4Ga.6N 6 4.0 •Rejection rate: 5 decades DCO - 10/04/00 •Back side illumination 8 (Readout circuit on front side) Band gap has to be adjusted THALES Research & Technology Responsivity (A/W) •Low dislocation density 10 -1 10 -2 10 -3 10 -4 10 -5 4.1 4.2 4.3 Energy (eV) 4.4 Back Front Bias 15V 3.0 3.5 4.0 Energy (eV) 4.5 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Read Out Integrated Circuit Band gap measured by reflectivity or transmission (α= 3x104 cm-1) 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 300 K 3.44+1.633x+1.09x2 but bowing=0.66 if AlN excluded 0 10 20 30 40 50 DCO - 10/04/00 % Al 9 For 286 nm (solar blind) => 42% in active layer THALES Research & Technology 60 70 80 90 100 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Sample grown by: MBE MOCVD Gap energy (eV) Band gap versus Al content AlGaN 45% 0.3 µm AlGaN 45% 0.3 µm AlGaN 45% 0.3 µm AlGaN 55% 1µm AlGaN 60% 1 µm AlGaN 65% 1 µm sapphire sapphire sapphire Band gap of active layer increases with Al content in window layer DCO - 10/04/00 Active layer compressed by window layer 10 deformation potential of 9.5 eV Longueur d'onde AlGaN (nm) 279 278 277 276 275 274 273 54 56 58 60 62 64 Composition fenêtre xAl (%) THALES Research & Technology 66 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Effects of strain on band gap Samples grown by MOCVD GaN buffer layer Growth chamber Aixtron low pressure AIX200 RF V/III ratio: between 2000 and 3100 NH3 flux: 2l/min; Total flux: 5l/min P = 20 mbar (Low to avoid parasitic reaction between NH3 and TMAl) TAlGaN= 1180 °C Growth rate: 1 µm/h (Al.65Ga 35N); 1.8 µm/h (Al.5Ga 5N) DCO - 10/04/00 Choice of nucleation layer: GaN or AlN ? 11 F. Omnes, J. of Appl. Phys. 86, 5286 (1999) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Conditions: Samples grown by MOCVD Choice of buffer layer: GaN buffer layer 0.6 0.4 0.2 X593 : GaN buffer X584 : AlN buffer X583 : AlN buffer Transmission AlN buffer layer 0.0 200 DCO - 10/04/00 •T=890°C, 10 nm •no deep levels •no sub band gap absorption 12 THALES Research & Technology 400 600 Wave length (nm) 800 GaN buffer layer •T=525°C, 25 nm •deep levels in AlGaN ⇓ Non ideal features This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Transmission 0.8 Effects of deep levels in AlGaN Non ideal effects 1 Tunneling + hν + DCO - 10/04/00 Parasitic effects of traps 13 THALES Research & Technology Tunneling in contacts Sub-band gap response Persistent photoconduction Non linearity Long non exponential response transient This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 ∆V Sub band gap response Effects of deep levels in AlGaN Non ideal effects 2 3 10 MOCVD buffer GaN 80 Hz, 2 V 80 Hz, 20 V 0 Hz, 20 V 2 10 1 10 0 10 10 -1 10 -2 0.32 0.36 Wavelength(µm) DCO - 10/04/00 0.28 14 THALES Research & Technology 0.40 0 10 10 -1 10 -2 10 -3 10 -4 MOCVD buffer GaN 80 Hz 30 V 1V 0.28 0.32 0.36 Wavelength (µm) 0.40 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Responsivity (A/W) 4 10 Normalized responsivity (u.a.) Spectral responsivity change with voltage and chopper frequency Samples grown by MOCVD Choice of buffer layer: AlN buffer layer DCO - 10/04/00 15 10 -2 10 -3 10 -4 10 -5 10 -6 MOCVD / X584 Buffer AlN 5V 0 Hz 8 Hz 80 Hz 190 Hz 0.28 0.32 0.36 Wavelength (µm) THALES Research & Technology 0.40 Responsivity (A/W) Responsvity (A/W) •Spectral responsivity constant with chopper frequency •Dynamics: 4 / 5 orders of magnitude 10 -2 10 -3 10 -4 10 -5 10 -6 MOCVD X584 finger width 2 µm spacing 4 µm 80 Hz 0.28 0.32 0.36 Wavelength (µm) 20 V 10 V 5V 2V 0.40 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 AlN buffer layer (T=890°C, 10 nm) => No deep levels in AlGaN Samples grown by MBE 1 Sample grown by MBE on sapphire 2 0.1 0.01 4 2 Buffer AlN Buffer GaN DCO - 10/04/00 4 GaN or AlN buffer layer ? 3.2 3.6 4.0 Energie (eV) AlN: Transparent to UV (6.2eV) Less known / bad electrical properties GaN: small band edge absorption @ 3.4 eV ? 16 4.4 GaN chosen for MBE N. Grandjean, J. Appl. Phys. 83, 1379 (1998) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Transmission RIBER chamber NH3 as N source Tgrowth = 800°C / 850°C 4 Increasing Al content… AlGaN layer grown at 850°C by MBE AlGaN 45% 0.3µm AlGaN 45% 0.3µm AlGaN 45% 0.3µm AlGaN 45% 0.3µm AlGaN 65% 0.8µm AlGaN 55% 1µm AlGaN 60% 1µm AlGaN 65% 1µm AlN 0.3µm saphir saphir saphir DCO - 10/04/00 More cracks with increasing Al content Strain relaxation 17 THALES Research & Technology saphir This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 AlGaN 55% 0.2µm Increasing Al content… Cracks and dark current 18 •No crack: •1 shallow crack: •1 deep crack: •more cracks: THALES Research & Technology ~10 pA @ 30 V ~10 pA @ 30 V Idark>100 pA @ 30 V Idark>100 pA @ 30 V This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 DCO - 10/04/00 Cracks Increasing Al content… •Insertion of a 100 nm AlN buffer (compression of window layer) •Lower growth temperature: 800°C (thermal expansion difference reduced) •Reduced thickness of the window layer: 0.85 µm (total elastic energy reduced) AlGaN (45%) 0.4 µm [Tg=800°C] AlGaN (65%) 1 µm NO CRACKS DCO - 10/04/00 AlN 100 nm 19 GaN 25 nm Sapphire c THALES Research & Technology F. Natali, Appl. Phys. Lett. 82, 499 (2003) This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 AlGaN layer grown at 800°C by MBE Band edge absorption broadening Ultimate band edge absorption broadening in AlGaN ? 0.8 0.6 0.4 Main reason: Alloy fluctuations 0.2 0.0 4.00 4.05 4.10 4.15 4.20 4.25 DCO - 10/04/00 Energie (eV) 20 THALES Research & Technology Attention : active layer thickness This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Absorption (u.a.) 1.0 Band edge absorption broadening Statistical fluctuations in AlxGa1-xN N III elements in excitonic volume Vexc Probability to find n Al among N: p ( n ) = C x (1 − x ) n N a N −n Low excitonic distance in AlxGa1-xN : libre exc r = ε mr m0 rexcitAlN ~ 1.5 nm DCO - 10/04/00 rexcitGaN ~ 3 nm ⇒ 21 aB THALES Research & Technology h rexcitonique e- This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 N Ga Al Band edge absorption broadening Schubert, PRB (1984) Baranowski, SPS (1978) 100 Experiment Model 80 60 40 20 0 0 80 20 40 60 80 Aluminum content(%) 100 60 40 20 AlxGa1-xN 0 0.0 0.2 0.4 0.6 0.8 Composition DCO - 10/04/00 Plus LO phonon @ 300 K : σ=[502+252]1/2=56 meV 22 Broadening close to statistical fluctuations for solar blind THALES Research & Technology 1.0 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 120 50 meV @ 45% Bandgap broadening (meV) Band gap broadening (meV) 40 meV @ 45% Alloy fluctuations and spectral response 4 T40% ~ e 2 Active layer 2 Band gap distribution A30% ~ 1 − e Al.3Ga.7N / Al.4Ga.6N 4.1 4.2 4.3 Energy (eV) 1.0 0.8 0.6 0.2 0.1 4.0 4.1 4.2 4.3 4.4 Energy (eV) 0.2 0.0 3.9 Simulation Experiment 0.3 0.0 3.9 Al.3Ga.7N 0.4 0.4 4.4 −α hν − E30% d30% Al.4Ga.6N 4.0 4.1 4.2 4.3 Energy (eV) THALES Research & Technology 4.4 Absorption spectra modeled with band gap fluctuations This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 4 4.0 DCO - 10/04/00 −α hν − E40% d 40% 0.1 0.01 23 Window layer Al.4Ga.6N Response (u.a.) Transmission 1 Band edge absorption broadening Active layer thickness 100 A = (1 − e −α d ) α= 3.10-4 cm-1 => active layer: 0.4 µm (plus contribution of back reflection on metal contact) Sigma=50 meV Eg0=4eV α(gap)=3e.10cm-1 T 10-1 10-2 d=1 µm -3 10-3 3.8 4 Energy (eV) 1 1 d=1 DCO - 10/04/00 T 24 d=1 T 0.5 0.5 d=0.1 0 4 4.2 4.5 Energy 42 % / 62 % THALES Research & Technology d=0.1 5 0 4 4.5 Energy 42 % / 57 % 5 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Sharpness of cutoff increases with thickness d: d=0.1 µm Table of contents Sub micronic MSM by E-beam lithography IBICC measurements Electrode Characteristics DCO - 10/04/00 •Technological optimization •Performances 25 THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 •Material growth •Transport properties Heterostructures on Si(111) substrate 10 -1 10 -2 10 -3 10 -4 10 -5 Al.5Ga.5N / AlN / GaN / AlN / Si(111) C(V) measurements => 2DEG (AlN / GaN) Capacitive coupling of GaN =>transitory only with AC flux 3.2 3.4 3.6 3.8 4.0 Energy (eV) E DCO - 10/04/00 ∂E I =ε ∂t 26 Buffer AlN Pt /Au THALES Research & Technology AlGaN AlN GaN This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Responsivity (A/W) Problem of capacitive coupling Sub-micronic MSM by E-beam lithography Geometrical effects 2 µm 0.6 µm Reduce Finger area => Reduced capacity DCO - 10/04/00 Reduce Finger spacing: Reduce bias for a same polarization Electric field confined in AlGaN 27 2D solver :Altlas-Silvaco This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Advantages of sub-micronic MSM E beam lithography: 0.4-1 µm J.Y. Duboz, J. Appl. Phys. 92 5602 (2002) THALES Research & Technology Sub-micronic MSM by E-beam lithography Response and dynamic 0.35 Response (A/W) 0.30 .6µm 2µm .6µm simul. 2µm simul. 0.25 0.20 0.15 0.10 0.05 DCO - 10/04/00 0.00 28 0 20 40 Voltage (V) 60 10 -2 10 -3 10 -4 10 -5 10 -6 2µm, 20V .6µm, 15V 3.2 3.6 4.0 4.4 Energie (eV) 4.8 High response at lower voltage Simulation: R~V0.7 (collection if Field>Eloc/Ldiff) Rejection rate > 5 decades Responsivity: 0.044 A/W @ 40V => η=20% J.Y. Duboz, J. Appl. Phys. 92 5602 (2002) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Responsivity (A/W) Al.45Ga.55N / AlN / GaN / AlN / Si(111) IBICC measurements Anode Cathode IBICC 4He+ 2MeV => 1µm² spot size Anode Cathode (a) (b) DCO - 10/04/00 40 µm 29 40 µm L. Hirsch, J. Appl. Phys. .91 6095 (2002) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Al.45Ga.55N / AlN / GaN / AlN / Si(111) IBICC measurements Atlas-Silvaco: Field electric @ 0, 25, 50 and 75 V ∆V Charge (10 -15 C) 20 15 75 60 50 40 30 V V V V V 10 DCO - 10/04/00 Cathode 30 Anode 5 Attenuation length ~ 5 µm 0 5 10 15 20 25 30 d (µm) Electron-hole better collected at cathode than anode L. Hirsch, J. Appl. Phys. .91 6095 (2002) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 4He+ Metal Semiconductor Metal detectors MOCVD: X584 AlGaN (50%) 0.4 µm AlGaN (65%) 0.85 µm AlN 100 nm Sapphire -6 2.5x10 2.0 1.5 1.0 90 µm 40 µm 25 µm 20 µm 0.5 0 5 10 15 20 15 µm 10 µm 5 µm 2 µm 25 Voltage (V) DCO - 10/04/00 Saturation at V > 15 V Photo response increases with fingers width 31 Width from 2 to 90 µm / Spacing constant: 4 µm Metal must cover a surface as large as possible THALES Research & Technology 30 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 -2 Photocurrent density (A/cm ) Response and electrodes area Metal Semiconductor Metal detectors Inter-digitized fingers spacing 2500 AlGaN (45%) 0.4 µm AlGaN (65%) 1 µm AlN 100 nm MSM MBE 1-level detectors 80 Hz - 270 nm 2000 1500 1000 width 5 µm - spacing 4 µm width 5 µm - spacing 10 µm 500 width 2 µm - spacing 4 µm width 2 µm - spacing 10 µm GaN 25 nm 0 Sapphire c 5 10 15 20 bias voltage (V) 25 30 DCO - 10/04/00 Saturation at V > 10 V: all carriers collected 32 Photocurrent increases with electrodes area and decreases with finger spacing THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 photocurrent (pA) MBE: N695 •Material growth •Transport properties •Technological optimization Metal deposition Choice of dielectric Geometrical optimization •Performance 33 THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 DCO - 10/04/00 Table of contents Metal Semiconductor Metal detectors Schottky contact 2.0 Schottky barrier (eV) 1.8 1.6 DCO - 10/04/00 1.4 34 •Processing Clean HCl 1’ + rinse 4’ Evaporation of Pt / Au (100 Å / 1000 Å) Annealing at 400°C 10’ (mechanical adherence) THALES Research & Technology 1.2 1.0 0 10 20 30 Aluminum content (%) This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 •High value for Schottky barrier ⇓ Advantage for low Idark Metal Semiconductor Metal detectors Two level process 1 2-level metallization Spacing: 2-10 µm Finger width: 2-5 µm metal dielectric Active area: 100 µm ×100 µm DCO - 10/04/00 Contact pads 35 THALES Research & Technology Contact reporting This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 AlGaN Metal Semiconductor Metal detectors Two level process 2 • SiO2 (300 nm) PECVD 300°C • BCB (1500 nm) dark current (nA) (spin-coated and annealed in vacuum at 250°C for 30 min) 10 5 10 3 10 finger width 5 µm spacing 8 µm dielectric: SiO2 1-level 2-levels 1 -1 10 -3 DCO - 10/04/00 10 36 -30 -20 -10 0 10 bias voltage (V) 20 30 M. Mosca, MRS proceeding (2003) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 • Si3N4 (300 nm) PECVD 300°C Metal Semiconductor Metal detectors Dielectric optimization no dielectric SiO2 Si3N4 BCB 10 0 N695 100x100 µm² finger width 2 µm spacing 4 µm -10 -20 -20 -10 0 Bias voltage (V) 10 DCO - 10/04/00 1-level detector: 15 fA at –10 V! 2-levels detectors: 37 Currents in fA range up to 13 V (Si3N4) and 15.5 V (SiO2)!!! Except BCB (Modification of AlGaN surface, dielectric stress) M. Mosca, MRS proceeding (2003) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Dark current (fA) 20 Metal Semiconductor Metal detectors Dark current and perimeter Dark current increases with perimeter If dark current can be measured ! Idark(µA) 1200 800 Idark 30V Idark 15V 400 400 600 800 1000 1200 DCO - 10/04/00 Perimeter (µm) 38 •Low dark current •High responsivity THALES Research & Technology => low number of fingers => low spacing / large fingers This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 1600 Metal Semiconductor Metal detectors 10 -1 10 -2 10 -3 10 -4 10 -5 X584 finger width 2 µm spacing 4 µm 0 Hz - 20 V DCO - 10/04/00 @ lower bias: •Charges not efficiently collected from pads •1-level ~ 2-level 39 responsivity (A/W) 0.28 10 -2 10 -3 10 -4 10 -5 10 -6 0.32 X584 finger width 2 µm spacing 4 µm 0 Hz - 2 V 0.28 SiO2 BCB Si3N4 no dielectric 0.36 0.40 SiO2 BCB Si3N4 no dielectric 0.32 0.36 wavelength (µm) 0.40 M. Mosca, MRS proceeding (2003) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 responsivity (A/W) Contribution of contact pads in the 1-level detector •Material growth •Transport properties •Technological optimization •Performances Dark current Detectivity Time response Comparisons with Schottky photodiodes 40 THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 DCO - 10/04/00 Table of contents Performances Dark current 0 X584 no dielectric -20 -30 finger width 2 µm spacing 4 µm N695 no dielectric N695 - SiO2 -40 -40 -30 -20 bias voltage (V) -10 0 DCO - 10/04/00 Very high quality of samples: Dark current in fA range up to –35 V!!! 41 M. Mosca, MRS proceeding (2003) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 dark current (fA) -10 Performances Dynamic No crack with different techniques of growth MBE: N695 AlGaN (50%) 0.4 µm AlGaN (65%) 0.85 µm AlN 100 nm 10 -2 10 -3 10 -4 10 -5 42 finger width 2 µm spacing 4 µm 0 Hz X584 / MOCVD N695 / MBE AlGaN (45%) 0.4 µm AlGaN (65%) 1 µm AlN 100 nm GaN 25 nm DCO - 10/04/00 Sapphire Responsivity (A/W) MOCVD: X584 Sapphire 0.28 THALES Research & Technology 0.32 0.36 Wavelength (µm) 0.40 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Responsivity ~ 0.06 A/W (η=25 %) Performances Noise & Detectivity V>20V: 1/2 Idark > 10pA 1/f noise filtered by capacitive coupling (2DEG and AlGaN) => 1/fγ with γ>1 PSD= βI²/f with Ln (Noise(A/Hz )) -26 β=5.10-5 -28 -30 -32 -34 DCO - 10/04/00 -2 43 THALES Research & Technology 1.39 -50V 1/f 1.2 -80V 1/f 1.2 -100V 1/f -1 0 1 2 Ln(Frequency (Hz)) 3 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Al.5Ga.5N / AlN / GaN / AlN / Si(111) Performances 10 -10 10 -11 10 -12 10 -13 10 -14 0.12 Detectivity (Hz /W) 1/2 DCO - 10/04/00 10 44 THALES Research & Technology Idark Noise 2kHz Response 0.10 0.08 0.06 0.04 0.02 0 PSD=2eI+βI²/f with β=5.10-5 NEP=0.3 pW at 50 Hz 0.16 0.14 -9 20 40 60 Bias (V) 80 100 6 4 2 12 6 4 0 20 40 Bias (V) 60 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 1/2 V<20V: Noise < measurement limit Noise extrapolated using 10 Responsivity (A/W) Al.5Ga.5N / AlN / GaN / AlN / Si(111) Noise(A/Hz ) et Idark (A) Noise & detectivity Performances Estimation of noise & detectivity at very low current Johnson noise 4kT/R: I²/f Noise βI²/f with β=5 × 10-5: Shot noise 2eI: ~ 10-18 A/Hz1/2 ~ 10-17 A/Hz1/2 ~ 2.10-17 A/Hz1/2 Response: 0.05 A/W DCO - 10/04/00 Detectivity: 4 × 1014 W-1 @ 100 Hz / NEP = 2.5 fW 45 500 photons / second / pixel (100 x100 µm²) THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Samples with Idark~1 fA @10 V Noise < measurements capability Performances Response time / linearity =>Response time < 1 ms (chopper limited) =>No deep levels 10 -2 0 Hz 8 Hz 30 Hz 80 Hz 190 Hz -3 10 -4 10 -5 N695 finger width 2 µm spacing 4 µm 5V 0.26 0.28 0.30 0.32 0.34 wavelength (µm) 0.36 0.38 DCO - 10/04/00 •Linearity on several orders of magnitude 46 still to verify @ low flux THALES Research & Technology Photocurrent (a.u.) 4 2 1 4 2 0.1 4 2 2 4 2 4 1 10 100 Optical flux (a.u.) 0.40 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Response is not a function of chopper frequency responsivity (A/W) •Response time 10 Performances Comparisons with Schottky photodiodes MBE / MSM MBE / Schottky MOCVD / MSM MOCVD / MSM MOCVD / Schottky 0.01 0.001 0.0001 DCO - 10/04/00 MBE / MSM MBE / Schottky MOCVD / MSM MOCVD / MSM MOCVD / Schottky 0.4 0.2 0.0 200 47 0.6 300 400 500 600 Wave length (nm) 700 800 200 300 400 500 600 Wave length (nm) Schottky vs MSM: Equivalent for sub band gap / dynamics Responsivity ? Dark current with bias ? THALES Research & Technology 700 800 This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 0.1 Transmission Transmission 0.8 Conclusion Al content adapted to UV solar blind detection MSM with very low Idark: fA regime up to 35 V Huge spectral selectivity: 5 orders of magnitude UV / visible Huge detectivity: up to 4 × 1014 W-1 @ 100 Hz DCO - 10/04/00 Key point: Readout Integrated Circuits 48 Low flux and currents 10 V for bias THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 From 200 to 300 nm Acknowledgment One author (MM) wishes to acknowledge financial support from a Curie Research Grant (G5TR-CT-2001-00064) DCO - 10/04/00 ONERA (France) for technical support 49 THALES Research & Technology This document and any data included are the property of THALES. They cannot be reproduced, disclosed or used without THALES' prior written approval. ©THALES 2003. Template trtco V 6.0.0 Work partially supported by DGA (contract N° 00-34-068)