5/1/2016 Chapter 28 Lecture Nuclear Physics Becquerel and the emissions from uranyl crystals Becquerel found that uranium crystals that had not been exposed to sunlight formed images on photographic plates. The uranium emitted radiation without an external source of energy. Rutherford and experiments investigating the charge of emitted particles Rutherford covered a uranium sample with thin aluminum sheets to investigate how metal layers affected the amount of radiation. Pierre and Marie Curie and the particles responsible for Becquerel's rays Chemical changes or changes in the amount of light shining on a sample did not lead to changes in the amount of radiation produced by uranium salts. These findings suggested that the electrons in the atoms were not responsible for the rays. Marie and Pierre Curie concluded that the Becquerel rays must come from the nuclei of atoms. Rutherford’s Testing experiment Radiation emanating from radioactive sample passes through a B field pointing into the page. A scintillating screen (which glows when hit with radiation) is in the plane perpendicular to the beam. 1 5/1/2016 Rutherford’s Testing experiment If the radiation contains positively charged particles, then according to the right-hand rule, the magnetic field should deflect upward with respect to the original direction. Rutherford’s Testing experiment The scree glowed in three places: one straight down, one deflected up, and one deflected down. The location of the downward-deflected radiation was much farther from the original beam than for the upward-deflected radiation. The early model of the nucleus The nucleus of an atom is made of positively charged alpha particles and negatively charged electrons. When a nucleus contains a large number of alpha particles, they start repelling each other more strongly than the electrons can attract them, and the alpha particles leave the nucleus. This leaves behind electrons that repel each other; thus beta rays are emitted. The nucleus is left in an excited state and emits a high-energy photon, a gamma ray. Rutherford’s Testing experiment If the radiation contains negatively charged particles, then according to the right-hand rule, the magnetic field should deflect downward with respect to the original direction. Alpha particles, beta rays, and gamma rays Rutherford found positively charged particles with a mass-to-charge ratio twice that of a hydrogen ion; they were called alpha rays or alpha particles. Negatively charged particles had the same mass-to-charge ratio as that of the electron; they were called beta rays. Neutral radiation was thought to consist of highenergy electromagnetic waves, called gamma rays. Problem with the early model of the nucleus A hydrogen atom is lighter than an alpha particle. What, then, is the composition of its nucleus? 2 5/1/2016 Size of the nucleus: Too small for an electron We can use the uncertainty principle and the size of the nucleus to show that our current models would result in atoms that rapidly lose their electrons. The search for a neutral particle An alpha particle has the charge of two protons but four times the mass of a proton; thus it cannot be made of two protons. In 1920, Rutherford suggested a neutral particle with the approximate mass of a proton. In 1928, Bothe and Becker took the initial step in this search. The neutral radiation is not a gamma-ray photon By comparing the energies and momenta of the particles knocked out of different atoms, Chadwick determined that the particles were uncharged particles with a mass approximately equal to that of the proton. ISOTOPES Carbon ions are accelerated to high speeds by letting them pass through a region with high potential difference and then pass them through a magnetic field, observing the paths the take. Atoms of a single chemical element take different paths. Revising ideas of the structure of the nucleus • A new model of nuclear constituents evolved that involved protons and neutrons. – The protons accounted for the electric charge of the nucleus. – The uncharged neutrons accounted for the extra mass. Centripetal Force = Magnetic Force FC FB m v2 Bvq R v BqR m 3 5/1/2016 Change in Energy = Kinetic Energy Whiteboard: Write an expression for “R” BqR m v U E q V KE q V v 2 q V m R 2 m V B2 q m v2 q V 2 v 2 q V m ISOTOPES R Isotopes 2 m V B2 q Radius of the circle does depend on the mass Atoms of a single chemical element with the same atomic number have different masses. Thus, different atoms must have a different number of neutrons in the nucleus. Representing the nucleus symbolically Total number of nucleons (protons + neutrons) (A = Z + N) Atoms of a particular element with different numbers of neutrons are called isotopes of that element. The electronic structure of an element's isotopes is the same, which means their chemical behaviors are almost identical. However, the nuclei behave quite differently. Isotopes of carbon are: 12 13 6 6 C C 14 6 C WHITEBOARD Determine the number of protons and neutrons in each of the following nuclei: U 238 92 Element symbol Number of protons (Z) 6 3 Li 16 8 O 27 13 Al Z = 92 Z=3 Z=8 Z = 13 N = 146 N=3 N=8 N = 14 N = 238 – 92 = 146 4 5/1/2016 WHITEBOARD Nuclear and Quantum Physics Determine the number of protons and neutrons in each of the following nuclei: 56 26 Fe 64 30 Zn 107 47 Question the very structure and behavior of matter itself. Although sought after for thousands of years, this knowledge has just started to present itself to the human race through modern physics experiments of the past 120 years. Ag Z = 26 Z = 30 Z = 47 N = 30 N = 34 N = 60 Structure of the Nucleus Coulomb repulsion is not the whole story! There are four fundamental forces that we know of that govern the interactions of the universe. Gravitational Force A concentrated sphere of protons and neutrons that makes up 99.9% of an atom’s mass. Although consistent with experiments throughout the early 1900s, this model was met with much skepticism. Electromagnetic Force Weak Nuclear Force Strong Nuclear Force With all of the electric repulsion between protons, how could this arrangement possibly be stable? The strong nuclear force Attractive force between protons and protons, protons and neutrons, neutrons and neutrons. Nuclear force and binding energy How can protons stay bound together when they repel each other so strongly? Very strong (100 times stronger than Coulomb force), but only at very short range (< 1 × 10-15 m). Basically disappears at distances greater than 3 × 10-15 m. Cannot be expressed algebraically – only with multivariable differential equations. Study more physics to learn how it works in detail! 5 5/1/2016 How are nuclei born? Nuclear force Some attractive force must balance this electrical repulsive force and must attract neutrons as well; it has to be an attractive force for both protons and neutrons. We call this attractive force a nuclear force. The nuclear force must weaken to nearly zero extremely rapidly with increasing distance between nucleons. If it didn't, then nuclei of nearby atoms would be attracted to each other, clumping together into ever-larger nuclei. At a distance, the strong nuclear force is negligible, so Coulomb repulsion dominates proton-proton interaction. d >> 1 × 10-15 m However, if the protons are forced to get close enough to one another by some immense external pressure (like it in a star)… d < 1 × 10-15 m Felectric << Fnuclear now the strong nuclear force dominates, and a nucleus is born. (Usually some neutrons will also be there to increase stability) Nuclear binding energy The binding energy of the nucleus is the energy that must be added to the nucleus to separate it into its component protons and neutrons. Felectric >> Fnuclear Wacky Units! In nuclear and atomic physics, we use some seemingly strange units for mass and energy. Don’t be afraid! Just know what they are and how/when to convert them! Mass The nucleus is a bound system, so its nuclear potential energy plus electric potential energy plus kinetic energy of the protons and neutrons must be negative. 1 atomic mass unit (amu) = 1 u = 1.660539 × 10-27 kg Proton mass = 1.007 u Neutron mass = 1.009 u Energy 1 electron-volt (eV) is the amount of energy gained by an electron that moves through a potential difference of 1 Volt. Ue = qΔV 1 eV = 1.6 × 10-19 J 6 5/1/2016 One atomic mass unit (u) Total number of nucleons (protons + neutrons) (A = Z + N) 12 6 What is the rest energy (in J, eV, and MeV) of 1 atomic mass unit (u) ? C E = mc2 One atomic mass unit equals one-twelfth of the mass of a carbon atom with six protons and six neutrons, including the six electrons in the atom. In terms of kilograms. EXPERIMENT 211H + 1 atomic mass unit (amu) = 1 u = 1.660539x10-27 kg Element symbol Number of protons (Z) + WHITEBOARD E = 934.1 MeV E = 931.5 MeV MASS DEFECT (m) The mass defect of a certain type of nucleus is the difference in mass between the constituents (as Hydrogen atoms and neutrons) and the mass of the atom itself = 201n E = 1.4945x10-10 J E = 9.3409x108 eV = 4 2 He m = [Zmhydrogen atom + (A - Z)mneutron] – matom mHydrogen = 2(1.007825 u) = 2.01565 u mNeutron = 2(1.008665 u) = 2.01733 u mHelium = 4.03298 u mHelium = 4.002602 u Binding energy (BE) The binding energy of a nucleus is the rest energy equivalent of its mass defect: Mass-Energy Equivalence Matter is energy. BE mc 2 BE = mc2 If mass is “lost” in a nuclear reaction, then its energy must be have been converted to another form. This is almost always in the form of kinetic energy and electromagnetic waves (light energy). The binding energy represents the total energy needed to separate the nucleus into its component nucleons. During a nuclear explosion, the tremendous and rapid conversion of mass energy to kinetic energy can cause surrounding particles to recoil with high velocities. Also, the light produced by this conversion of matter to energy is often of high-frequency (UV, X-ray and Gamma), making it very dangerous to surrounding organisms. 7 5/1/2016 Binding Energy When nuclei form, they are bound together by the strong force. In order to break the nucleus apart, you need to put energy into the system. This means that the system has negative potential energy. Similar to the negative energy between two particles that attract electrically, but now the attraction is caused by the strong nuclear force. Example: The nucleus shown above (a Helium nucleus) has a binding energy of -931.5 MeV. This means that you would need to put 931.5 MeV of energy into the nucleus to separate it into two free protons and two free neutrons. Binding energy per Nucleon The binding energy per nucleon is the binding energy BE of the atom divided by the number of nucleons A in the atom’s nucleus: Binding energy per nucleon = BE/A How to use BE mc 2 Speed of light in a vacuum (3 × 108 m/s) Law of Conservation of Energy: Total energy before = Total energy after Just apply this using E = mc2 to determine how much mass-energy is converted to other forms, or vice versa. Always use mass in kilograms when using c! Representing nuclear reactions The advantage of writing nuclear reactions as shown here is that atomic masses (found in atomic mass tables) can be used to analyze the energy transformations that occur during the reactions: The binding energy per nucleon is a good indicator of the stability of a nucleus; the larger the binding energy per nucleon the more stable is the nucleus. Rules for nuclear reactions (1/3) Rules for nuclear reactions (2/3) RULE 1: ELECTRIC CHARGE CONSERVATION. RULE 2: NUCLEON NUMBER CONSERVATION. The total electric charge of the reacting nuclei and particles equals the total charge of the nuclei and particles produced by the reaction. This condition is satisfied if the total atomic number Z of the reactants equals the total atomic number of the products including Z=-1 for free electrons The total number of nucleons A (protons + neutrons) of the reactants always equals the total number for the products. 8 5/1/2016 Solution WHITEBOARD In the alpha decay of a Radium nucleus, the following is known. 226 88 During an alpha decay, the total number of nucleons must add up before and after, and the total number of protons must add up before and after. Ra ® 24 He +? 226 88 Ra ® ? + 24 He 226 = X + 4 88 = A + 2 What is the missing product? WHITEBOARD WHITEBOARD Determine the missing products in the following reactions: 1 1 1 1 H 1 0 n 94 38 Sr 137 56 Ba WHITEBOARD SOLUTION 1 1 H 37Li 24He 24He kinetic energy a. b. c. d. Find Find Find Find the the the the mass of the reactants. mass of the products mass defect (m) rest energy of the mass defect (in MeV) mReactants = 8.023828 u mproducts = 8.005204 u m = 0.018624 u Q = 17.35 MeV H 37Li 24He 24He kinetic energy m Li 7.016003 u m He 4.002602 u m 11 H 1.007825 u 7 3 4 2 Rules for nuclear reactions (3/3) RULE 3: ENERGY CONSERVATION The rest energy of the reactants equals the rest energy of the products plus any change in kinetic energy of the system. (mc2)reactants = (mc2)products + Q Q, the reaction energy can be either positive (if the products’ rest energy is less that that of the reactants) or negative (if the products’ rest energy is greater) 9 5/1/2016 Binding energy and energy release The higher the binding energy per nucleon, the more energy needed to split the nucleus into its constituent protons and neutrons. Fusion and chemical elements Two or more small nuclei fuse together, forming a larger nucleus and releasing huge amounts of energy. Takes place in stars like the Sun. Fusion occurs naturally in stars; it requires high heat and high pressure to overcome the repulsion from the electric charges. Binding energy and energy release The graph predicts: When two small nuclei combine, energy should be released. When a large nucleus breaks apart, energy should be released. Fusion and chemical elements Supernova explosions contribute to the chemical composition of the universe. The elements lighter than iron that are produced in stars' cores before the explosion are ejected into space. The elements heavier than iron that are produced during the explosion are then ejected into space. WHITEBOARD Fission and nuclear energy The energy released by the Sun comes from several sources, including the proton-proton chain of fusion reactions: Determine the energy released in this chain of reactions in MeV. Use the masses , , and to determine the rest energy converted to other forms. Q = 28.29711 MeV 10 5/1/2016 Fission and nuclear energy Fission and nuclear energy Fission and nuclear energy Fission and nuclear energy Nuclear Reactions Fission - Chain Reaction! Nuclear fission – a large nucleus splits into two or more smaller nuclei. Takes place in nuclear power plants and bombs. Nuclear fusion – two or more small nuclei fuse together, forming a larger nucleus and releasing huge amounts of energy. Takes place in stars like the Sun. A neutron is absorbed by a heavy nucleus, making it unstable. The unstable nucleus splits into two smaller nuclei, releasing some energy and more neutrons in the process. These neutrons go on to get absorbed by other nuclei, sparking a chain reaction that grows exponentially. This is a nuclear explosion. 11 5/1/2016 In a nuclear power plant, these are absorbed by water to prevent meltdown. In a nuclear power plant, most of the released neutrons are absorbed by water molecules to control the rate of fission and prevent the reaction from “going critical” (becoming a nuclear bomb) WHITEBOARD Determine the energy in the fission reaction. One neutron collides with and joins momentarily with the U-235atomic nucleus to form an excited U-236, which quickly splits into Ba-141, Kr-92 an 3 neutrons. 1 0 n1.008665u U 235.043924u 235 92 92 36 141 56 Kr 91.926156u Ba140.914411u Bohr's liquid drop model of the nucleus Frisch and Meitner decided that Bohr's liquid drop model of a nucleus could explain the observation of fission. Surface tension holds a water drop together; likewise, the nuclear forces hold the nucleons together. The protons repel each other and overwhelm the effect of the "surface tension." The nucleus can then stretch itself and divide into two smaller pieces. Q = 173 MeV The Three Types of Nuclear Decays Alpha decay, Beta decay, and Gamma decay. Alpha decay When one of the alpha particles leaves, this emission reduces the number of protons in the original nucleus as well as the electric repulsion between the remaining protons. All three of these decays obey the three conservation laws of the universe. Conservation of Energy Conservation of Momentum Conservation of Charge 12 5/1/2016 α-decay WHITEBOARD A parent nucleus releases an alpha particle (Helium nucleus), and recoils in the process. 4 2 He Alpha particle – two protons and two neutrons bound together (a Helium nucleus) To analyze an alpha decay, you must use momentum conservation and energy conservation. Beta decay During beta decay, a particular element is transformed into an element with a Z number that is larger by 1. Determine the kinetic energy of the product nuclei when polonium-212 undergoes alpha decay. The masses of the nuclei involved in the decay are m = 0.0097 u Q = 9.03555 MeV β-decay Within the nucleus, a neutron decays into a proton, while emitting an electron (beta particle). The most important part about beta decay is that it obeys the Law of Conservation of Charge. The Law of Conservation of Charge In all chemical and nuclear reactions, electric charge must be conserved. Beta minus decay: Beta plus decay 1 0 n11p 10e Neutral Positive + Negative 1 1 Problems with beta decay The problem with spin conservation: In beta decay, the spin quantum number was not conserved. The problem with energy conservation: The total energy of the products was always observed to be less than the total energy of the reactants. p 01n 10e Positive Neutral + positive 13 5/1/2016 Beta decay Beta-minus and beta-plus decay Wolfgang Pauli proposed an explanation for beta decay that did not require abandoning energy conservation or spin number conservation. He hypothesized that some unknown particle carried away the missing energy and accounted for the discrepancy in spin number. This particle had zero electric charge, zero mass, and a spin number of either +1/2 or –1/2. Enrico Fermi called the particle a neutrino, meaning "little neutral one." Gamma decay γ-decay • After alpha or beta decay, the nucleus can be left in an excited state from which it then emits one or more photons to return to its ground state. An excited nucleus emits a photon (gamma ray), and decreases its state of vibration in the process. WHITEBOARD The following nuclei undergo different types of radioactive decay. Determine the daughter nucleus for each and write an equation representing each decay reaction. WHITEBOARD The following nuclei undergo different types of radioactive decay. Determine the daughter nucleus for each and write an equation representing each decay reaction. beta-minus decay alpha decay 239 94 4 Pu 235 92 U 2 He energy 144 58 0 Ce144 59 Pr -1 e v energy 14 5/1/2016 Whiteboard! WHITEBOARD The following nuclei undergo different types of radioactive decay. Determine the daughter nucleus for each and write an equation representing each decay reaction. 65 30 beta-plus decay (produces a positron) Zn Cu e v energy 65 29 0 1 The following nuclear decay occurs spontaneously. U 238 92 Th 234 90 4 2 3.6 x 105 m/s He ? m = 4.00 u m = 234.04 u m = 238.05 u a) What type of decay is this? b) What is the speed of the recoiling Helium nucleus? c) What is the combined kinetic energy (MeV) of the two nuclei after the decay? (Without using your answer from b) 1 u = 1.660539 × 10-27 kg U 238 92 Th 234 90 3.6 x 105 m/s 4 2 He U 238 92 Th 234 90 4 2 He pi = 0 m = 4.00 u m = 234.04 u m = 238.05 u Conservation of Momentum Spi = Sp f vα = 2.11 x Conservation of Energy BE mc 2 A typical momentum problem! 0 = mThvTh + ma va 107 m = 4.00 u m = 234.04 u m = 238.05 u m/s The alpha particle has much less mass, so it will recoil with much greater velocity! (Note: Don’t need to convert to kg in this part, as you are working with the same units on both sides of the eqn.) Half-life Using a particle detector such as a Geiger counter, we can measure the number of nuclei that decay in a short time interval and determine the number N of radioactive nuclei that remain in the sample as a function of time. First, convert the masses into kilograms. Then subtract to find out how much mass is “lost” (converted to KE). Finally, use BE = mc2 to find that the energy released in the decay is m = 0.01 u Q = 9.315 MeV Observational experiment Number N of radioactive nuclei Clock reading t [min] N0 0 0.5 N0 1 0.25 N0 2 0.125 N0 3 0.0625 N0 4 0.03125 N0 5 0.015625 N0 6 Undetectable 10 15 5/1/2016 Observational experiment Number N of radioactive nuclei Clock reading t [min] 102400 0 51200 1 25600 2 12800 3 6400 4 3200 5 1600 6 800 10 N/N0 Half-life (N/N0) In terms of 1/2 The half-life T of a particular type of radioactive nucleus is the time interval during which the number of nuclei in a given sample is reduced by one-half. After n-lives, the fraction of radioactive nuclei that remain is N 1 n N0 2 Ratio of decays t nT Time (expressed in half-lives) Half-life Half-life Half-life y 102400 e 0.693 x N vs. Time N 100000 90000 80000 N 1 n N0 2 t nT N N 0 e t 70000 60000 y = 102400e-0.693x 50000 40000 30000 N 102400 e 0.693t 20000 10000 0 0 2 3 4 5 6 7 8 9 10 11 12 t (min) N Number of radioactive nuclei N0 Number of radioactive nuclei at t = 0 s (N0 = 102400) Decay constant ( = - 0.693 s-1) Euler number e Half-lives and decay constants of some common nuclei 1 Euler number n 1 1 1 1 1 n! 0! 1! 2! 3! ... n 0 T n 1 n! 2.71828182845905 n 0 n 1 n! e n 0 e 2.71828182845905 e 2.71 16 5/1/2016 EXPONENTIAL RELATIONSHIP N N0 e EXPONENTIAL RELATIONSHIP t N vs. Time Ln N Ln N Lne Ln N Ln N 0 e t t 0 90000 80000 70000 60000 y = 102400e-0.693x 50000 40000 30000 20000 10000 0 0 Ln N Ln N 0 t Lne How do we solve for t? Ln N Ln N 0 t 1 2 3 4 5 6 7 8 9 10 11 12 11 10 9 8 7 6 5 4 3 2 1 0 12 y = -0.6931x + 11.537 0 1 2 3 4 5 6 7 8 9 10 11 12 y 0.6931x 11.537 y 102400 e 0.693 x N N0 e Ln N t Ln N 0 Ln(N) vs. Time 100000 Ln N Ln N 0 t t LnN Ln102400 0.6931t LnN 0.6931 t 11.537 N 102400 e 0.693t EXPONENTIAL RELATIONSHIP N vs. Time 105000 100000 Ln(N) vs. Time 12 11 10 9 8 7 6 5 4 3 2 1 0 95000 90000 y = -0.6931x + 11.537 85000 Number of radioactive nuclei First half-life 80000 75000 70000 65000 Decay constant 60000 55000 0 1 2 3 4 5 6 7 8 9 10 11 Second half-life 50000 12 45000 Ln N Ln N 0 t t Ln N Ln N 0 1 2n N N 0 e t N0 Ln N 0 Ln N 30000 1 N 0 e T 2 1 e T 2 N N 0 e t 25000 20000 N Ln N0 t 15000 10000 5000 0 0 1 2 3 4 5 6 7 8 9 10 11 12 Decay rate and half-life At time t = T (one half-life), the number N of radioactive nuclei remaining is one-half the number N0 at time zero: 1 Ln Ln e T 2 t nT n 1 t T y = 102400e-0.693x 35000 N 1 n N0 2 N N0 t 40000 1 Ln Ln e T 2 1 Ln T 2 1 Ln 2 T T 0.693 If the decay constant is large, then the material decays rapidly and consequently has a short halflife T. 17 5/1/2016 WHITEBOARD WHITEBOARD (SOLUTION) Radium-226, a waste product of nuclear reactors, has a half-life of 1600 years. Find the decay constant of the () Radium-226 Use two different methods to determine the fraction of radium-226 remaining in a reactor fuel rod 8000 years after it is removed from the reactor. t nT N e t N0 N 1 n N0 2 t nT n 0.693 0.693 T t T 8000 1600 n T 4.33125 x10 4 yr 1 N e t N0 n5 WHITEBOARD (SOLUTION) 4.33125 x10 4 yr 1 N 1 n N0 2 N e t N0 N 1 5 N0 2 N 0.03125 N0 4 1 N e 4.33125 x10 yr 8000 yr N0 N 0.03127 N0 DECAY RATE AND HALF LIFE T 0.693 0.693 T N N 0 e t N e t N0 N Ln e t Ln N0 N t Ln N0 N 1 n N0 2 WHITEBOARD Strontium-90, has a half-life of 28.9 years. Find the decay constant of the () Strontium-90 Use two different methods to determine the fraction of Strontium-90 remaining after 101.15 years. n t n 3.5 T 0.693 T 0.023979 yr 1 N 1 n N0 2 N 0.08839 N0 N N 0.08843 e t N0 N0 Radioactive dating Archeologists and geologists are interested in determining the age of a radioactive sample from the known fraction N/N0 of radioactive nuclei that remain in the sample: N 0.693 Ln t T N0 N T t Ln N 0 0.693 In this equation, T is the half-life of the radioactive material and t is the sample's age when N radioactive nuclei remain. 18 5/1/2016 Carbon dating Any plant or animal that metabolizes carbon incorporates about one carbon-14 atom into its structure for every 1012 carbon-12 atoms it metabolizes. Carbon is no longer metabolized by the organism after death, so the carbon-14 starts to transform into nitrogen-14. After 5730 years, the carbon-14 concentration decreases by one-half. A measurement of the current carbon-14 concentration indicates the age of the remains. WHITEBOARD WHITEBOARD The ratio of carbon-14 in an old bone compared to the number in a fresh bone of the same mass is 0.050. Determine the age of the bone. N T t Ln N 0 0.693 t Ln0.05 5730 years 0.693 Tcarbon = 5730 years t 24769.9 years Radioactive decay series A bone found by an archeologist contains a small amount of radioactive carbon-14. The radioactive emissions from the bone produce a measured decay rate of 3.3 decays/s. The same mass of fresh cow bone produces 30.8 decays/s. Estimate the age of the sample. N T t Ln N 0 0.693 3.3 5730 years t Ln 0.693 30.8 Tcarbon = 5730 years t 18468 years 19