Universidade Nacional da Irlanda em Galway -- Ciência sem Fronteiras PhD Project Template Use one form per project Please complete & submit to international@nuigalway.ie as soon as possible, and by 27/11/2012 In your email, begin the subject line with [SWB] (be sure to use square brackets) to ensure that your email is filed correctly. Emails will be automatically filed PI name & contact details: School: Dr. Harald Berresheim email: harald.berresheim@nuigalway.ie Tel: +353-91-495705 School of Physics Has project been agreed with head (or nominee) of proposed registration school? Yes Research Centre / group affiliation: Centre for Climate and Air Pollution Studies (C-CAPS) Research group / centre website: http://www.nuigalway.ie/c-caps/ PI website / link to CV: http://www.nuigalway.ie/physics/staff_pages/h_berresheim/index.html Brief summary of PI research / research group / centre activity (2 or 3 lines max): Previous work in Brazil: with Prof. Paulo Artaxo of Univ. Sao Paulo; INPA, and with FEEMA (Rio de Janeiro). Major research areas: atmospheric chemistry & physics, free radicals (OH), aerosol nucleation, aerosol composition, emissions from oceans, plants, and volcanoes, climate change. Title & brief description of PhD project (suitable for publication on web): Atmospheric oxidation of sulfur compounds in the marine environment Unique selling points of PhD project in NUI Galway: Biogenic, volcanic (from Iceland), and anthropogenic sulfur emissions contribute to transboundary air pollution over the NE Atlantic. Oxidation of major sulfur compounds such as SO2 and dimethylsulfide (DMS) by OH leads to formation of sulfuric and methanesulfonic acid which can significantly alter aerosol and cloud properties in the marine atmosphere. A chemical ionization mass spectrometry (CIMS) instrument will be used at Mace Head station to measure OH, H2SO4, and MSA at 30 sec time resolution. Aerosol sulfate and methanesulfonate ions are concurrently measured by aerosol mass spectrometry (HR-TOF-AMS). A fluorescent SO2 monitor shall be acquired for the project. We have recently discovered new oxidant species using CIMS which may compete with OH in removing sulfur and other pollutants in the marine atmosphere. The student shall Universidade Nacional da Irlanda em Galway -- Ciência sem Fronteiras operate the CIMS and establish a seasonal/multi-annual budget for H2SO4 and MSA based on the measurements. Furthermore, the project aims to identify the nature of the unknown oxidant species and assess their relative importance. Name & contact details for project queries, if different from PI named above: Please indicate the graduates of which disciplines that should apply: Physics, Chemistry, Atmospheric Sciences, Meteorology, Environmental Sciences, Ocean Sciences Ciência sem Fronteiras / Science Without Borders Priority Area: Please indicate the specific programme priority area under which the proposed PhD project fits- choose only one (tick box): Engineering and other technological areas Pure and Natural Sciences (e.g. mathematics, physics, chemistry) Health and Biomedical Sciences Information and Communication Technologies (ICTs) Aerospace Pharmaceuticals Oil, Gas and Coal Renewable Energy Minerals Biotechnology Nanotechnology and New Materials Technology of prevention and remediation of natural disasters Biodiversity and Bioprospection Marine Sciences Creative Industry New technologies in constructive engineering Please indicate which of the following applies to this project (referring to Science Without Borders arrangements): Suitable only as a Full PhD (Y/N): _ _Y___ Available to candidates seeking a Sandwich PhD arrangement (Y/N): _____ Suitable for either/Don’t know: _____