Session 15 Exploration, Discovery, and Mine Developments in China (SEG Sponsored Session) Close Close Chapter 15-1 15-1 Metallogeny and prospectivity of the Dayaoshan Region, Guangxi Province, China Cui Bin, Huang Huimin, Zhao Lei China University of Geosciences, Beijing, 100083, China Li Zhong Shijizhuang Railway Institute, Shijiazhuang, Hebei Province, China Keywords. Metallogenic series, ore-forming prognosis, granite, mantle plume, Dayaoshan Abstract The Dayaoshan region is located in the Qinzhou-Qiantang link-belt between the Yangtze plate and the South China plate. Following multistage geological reworking, the resulting structural pattern gave rise to the Dayaoshan belt which was surrounded by several basins. Since 1949 exploration aimed at gold, tungsten-tin and lead-zinc, and special scientific research have focused on in this area. Following a multi-scale study of the tectonics in the Nanling area, the authors put forward a model that proposes a mantle-plume existed which had played an important role in the metallogeny of the region. On the basis of geology, geophysics and geochemistry, it is considered that gold is located in the centre of the plume region, with tungsten, tin, lead and zinc in Dayaoshan region surrounding the core. Mineralization displays a strong spatial and temporal relationship with the origin and evolution of granites in the region. These granites represent two cycles of mantle-plume activity, and are accompanied by Caledonian Au-Cu deposit series and Yanshanian REE-W-Sn-Pb-Zn deposit series Close Close Chapter 15-2 15-2 The high-grade Baolun gold deposit, Hainan Island, China Shijiang Ding, Yangrong Fu Hainan Geological Survey, 88 Nansha Rd, Haikou, Hainan Province 570226, China Taihe Zhou, Guoyi Dong Sino-QZ Group Pty Limited, PO Box 2424 Mt Waverley, VIC 3149, Australia; and HT Mining (Beijing) Ltd, 22C-2, 2 Xinxi Rd, Shangdi Zone, Haidian District, Beijing 100085, China Abstract. The Baolun gold deposit has the highest grade ores among the new discoveries for gold in China. The lode-gold quartz vein systems are hosted in the Silurian low grade metamorphic rocks of sericite-quartz phyllite, carbonaceous phyllite and slate, and controlled by NNW-trending structures. Thirteen shear zones with alteration and mineralization have been identified in the Baolun area, and nineteen orebodies have been found within the shear zones 1 to 5. There is significant potential to find more high-grade large gold deposits in the surrounding areas. Keywords. Geological setting, high-grade ores, Baolun gold deposit, Hainan, China 1 Introduction The Baolun gold deposit in the Hainan province is one of the most significant discoveries for gold in China for the last decade. The identified and inferred resources are some 73 Mt ores averaging approximately 10.34g/t gold @ 3g/t cut off. The main orebody (V1-3) is estimated to contain some 20 tonnes of Au (643,000 oz Au) averaging 29.48 g/t Au (Ding et al. 2001), making it the highest grade deposit of new discoveries for gold in China. Approximately 50% of the gold is free-milling, coarse grained, and recovered by gravity circuit (water separation table). The mine grade was about 18 g/t (0.52 oz/t) with a total recovery of 97%, making it one of the most economically profitable mines in China. Thirteen alteration and mineralization zones have been identified in the Baolun area, and the exploration has been mainly concentrated in the fault zone 1 by far, therefore, there is significant potential to make new discoveries. Initiated by Sino-QZ Group, a Canadian and Chinese exploration JV project has been established in an area of approximately 53 km2 directly surrounding the 1.2 km2 Baolun Mine. This paper summarizes the geological setting and characteristics of the orebodies in the Baolun gold deposit. 2 Geological background Hainan is an island off the south coast of the mainland China in the South China Sea. The Baolun gold deposit is located in the southern part of the island, approximately 110km by road northwest of the city of Sanya. The mine site is located at an elevation of 220 to 500 meters above sea level. The topography is moderately rugged, with considerable tree and shrub cover. Access to the deposit is via the main road, which passes only 13km from the deposit. In general, there is lack of tectonic information and data about the Hainan Island. It was suggested that the Hainan Island was probably a part of the terranes derived from Gondwanaland in the Devonian (Metcalfe 1997, unpublished report, New England University). The major NE fold belts in the island may have been largely affected by the TriassicJurassic orogenic movement, the same time as the Ailaoshang – Red River fold belt in Yunnan. The island is close to the contact zone of the southern margin of the South China craton and the SE Asia block. The deposit is located along the Ledong basin margin between the regional E-W trending Jianfeng-Luodiao and Jiusuo-Lingshui faults. The major rock units in the area include the high grade metamorphic basement of the Mesoproterozoic Baoban Group of the Changcheng System, the Silurian low grade metamorphic rocks of the Tuolie Formation and the Cretaceous sedimentary covers, and some Indosinian (Triassic-Jurassic) and Yanshanian (late Mesozoic) granites. The basement metamorphic rocks only occur in the southwest corner of the Baolun district, and are composed of the migmatite, plagioclase gneiss and schists. The Silurian Tuolie Formation, which hosts the gold mineralisation, comprises sericite-quartz phyllite, carbonaceous phyllite and slate with the total thickness over 1200m. The Tuolie Formation is fault contacted with the underlying Mesoproterozoic Baoban Group in the southwest; fault contacted with Cretaceous sedimentary rocks in the southeast; and is intruded by the late Triassic Jianfeng granite in the northwest. The NE-trending Bahaoshan-Tiewanling thrust separates the Silurian Tuolie Formation and the Cretaceous sedimentary rocks in the southeast of the mining district. The NNW-trending shear zones, which directly host the ore bodies, are well developed near the hinge of the Haogangling anticline, which is about 1.5 km long and 0.8 km wide with its axial trace trending NNW. 3 The Baolun gold deposit Thirteen shear zones with alteration and mineralization have been found in the Baolun district. The zones are subparallel to each other, with individual zones 400 to 1300m Close 1522 Shijiang Ding · Yangrong Fu · Taihe Zhou · Guoyi Dong long and 10 to 30m wide (up to 80 m wide). In general, the shear zones trend 325-3550 and dip southwest at 55850. Nineteen orebodies have been identified within the shear zones 1 to 5. Among them, fourteen orebodies are located in the major shear zone 1. Occurrences of ore bodies are controlled by the shear zones, with high-grade auriferous veins in the middle and lower grade disseminated ores enveloping the veins. The orebodies are exposed from 270m to 510m above the sea level, and are controlled by the underground development from 320 to 130m above the sea level (25m below the sea level for the orebody V1-3). The orebodies are projected over a strike length of 160 to 1100m, with an average thickness of 0.454.86m for the individual orebodies. The average ore grades of the individual orebodies vary from 1.61 to 29.48g/t Au. Trenching in one of the mineralization/shear zones in the far southwest also indicates significant gold mineralisation of four possible orebodies grading from 2.3 to 29g/t Au. Exploration, development and production have been mainly concentrated in the shear zone 1, which is some 120m wide, and extends for several kilometres along the strike. Within the shear zone 1, the orebody V1-3, which is the principal orebody of the deposit, comprises mainly of high-grade (29.48 g/t Au) quartz vein type mineralization with lower grade (2.7 - 4.18 g/t Au) ores in the alteration zone enveloping the quartz veins. The orebody V1-3 is totally under overburden, trends 325-3450 and dips southwest (locally northeast) at 75-850. It has a controlled length of 310m, averaging 2.62m thick, up to 7.49m locally, and is confined to a depth of 415m downdip. The orebody V1-3 contains some 20t gold with average grade over 29.48 g/t, up to 282.70g/t. Visible gold is common in the major quartz vein orebody, and analysis results are often over 80 g/t. Approximately 50% of the gold is freemilling, coarse grained, and recovered by gravity circuit (water separation table). The mine grade was about 18 g/ t (0.52 oz/t) with a total recovery of 97%. The dominant ore minerals are pyrite, pyrrhotite and free gold, with subordinate amounts of arsenopyrite and minor nickelbearing pyrite, chalcopyrite, sphalerite, galena, native bismuth, maldonite, bismuthinite, and various Bi-Pbsulfosalts. The gold fineness varies from 921 to 968, and the gold mainly occurs as fracture filling within or between quartz and pyrite grains; or as tiny inclusions within pyrite, arsenopyrite, pyrrhotite, chalcopyrite, sphalerite and quartz. Alteration minerals include quartz, sericite, chlorite, carbonate and illite. 4 Discussion and conclusion The Baolun gold deposit is a quartz-vein-system deposit controlled by structures in metamorphosed Paleozoic sedimentary rocks. Its alteration, mineralization and structurecontrolling characterize an orogenic gold-only deposit (Groves et al. 1998; Zhou 1999; Zhou and Lu 2000; Zhou et al. 2002). A preliminary fluid inclusion study indicated that the main mineralization stage was formed in temperatures ranging from 240 to 3000C; and analysis on two samples of alteration illite gave the K-Ar ages of 216 Ma and 205 Ma, respectively (Ding et al. 2001), which may suggest Hainan Island could be originally from the Ailaoshan belt, although further detailed works are required. The multiple alteration/shear zones that hosting the highgrade gold quartz vein systems, the thickness of the slatephyllite belt along the major structures, and the orogenic gold nature of the Baolun deposit indicate the significant potential to find more high-grade large gold deposits in the corridor as well as in other belts in the Hainan Island. Acknowledgements We wish to thank many geologists and management staff of the Hainan Geological Survey and the Baolun Mine for sharing their experience and knowledge of the Baolun deposit and Hainan Island. We also appreciate the time and support provided to us by the staff from Fury Explorations and Eldorado Gold. In addition, we would like to extend our appreciations for assistance from staff of the Sino-QZ Group and HT Mining (Beijing), particularly Huijuan Wen and Junqi Yin. References Ding S, Huang X, Li Z, Fu Y, Dong X, Shu B, Zhang X (2001) Geological features and minieralization of the Baolun gold deposit, Hainan. Chinese Geology 28: 28-34 (in Chinese) Groves DI, Goldfarb RJ, Gebre-Mariam M, Hagemann SG, Robert F (1998) Orogenic gold deposits: A proposed classification in the context of their crustal distribution and relationship on other deposits. Ore Geology Reviews 13: 7-27 Zhou T (1999) Tectonics and gold mineralisation in East China, Proceedings of PACRIM 99, Bali, Indonesia, International Congress, Aust. IMM Publications 341-345. Zhou T, Lu G (2000) Tectonics, granitoids and Mesozoic gold deposits in East Shandong, China. Ore Geology Reviews 16: 71-90 Zhou T, Goldfarb RJ, Phillips GN (2002) Tectonics and distribution of gold deposits in China - An overview. Mineralium Deposita 37: 249-282 Close Chapter 15-3 15-3 Characteristics of rock-chip geochemical anomalies of No. 460 gold deposits in Gansu Province, China Wei-Xuan Fang, Zhuan-Ying Huang Beijing Geological Survey Institute of China Non-ferrous Metals Resource Geological Survey, Beiyuan No.5 Yuan, Chaoyangqu, Beijing 100012, and Open Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, No. 73 Guanshui Road Guiyang 550002, China Bin Zhou, Yun-Bing Nong, Tian-You Zheng Northwest Metallurgical Geological Survey Bureau, Xi’an City, China Abstract. The No. 460 Au deposits of Gansu province in China is located between the Tuwu-Yandong porphyry Cu-Mo deposits and the Oyu Tolgio porphyry Au-Cu-Mo deposit. Characteristics of rockchip geochemical anomaly were reported in this study, indicating it might be one of the most promising targets for Au mineralization in porphyry environments in the Late Silurian-Carboniferous magmatic arc. Keywords. Rock-chip geochemical anomaly, promising targets, porphyry environments 1 Introduction Gold and copper mineralization in porphyry and epithermal environments have become increasingly important exploration objectives during the last decade, mainly in response to discovery of world-class epithermal and porphyry Au-Cu-Mo deposits on the Pacific rim (Corbett and Richaeds 1990; Cooke and Bloom 1990; MacDonald and Arnold, 1994; Meldrum et al. 1994; Sillitoe 2000). Similarly, Au-Cu mineralizations in the central Asian orogen have been become hotspots nowadays because some world-class porphyry or skarn Au-Cu-Mo deposits were found, for example, Kalmakyr (Almalyk) porphyry Cu-Mo deposit in Uzbekistan, Borly and Aktogai porphyry Cu-Au-Mo deposit, Sayak skarn and epithermal deposits in Kazakhstan, Axi epithermal Au deposit, Tuwu-Yandong porphyry Cu-Mo deposits in the Tianshan in northwestern China (Feng et al. 1999; Qiu 1999; Zhuang 2003; Zhang et al. 2000), Oyu Tolgio porphyry Au-Cu and TsagaanSuvarga porphyry Cu-Mo (Lamb and Cox 1998; Watanabe and Stein 2000; Badarch et al. 2002) in south Mongolia. These world-class ore deposits might be closely related to the Late Silurian-Carboniferous magmatic arc which extended from Kazakhstan, past Tianshan and Beishan in northern China, via south Mongolia, onto Duobaoshan porphyry Au-Cu-Mo of Heilongjiang Province in northeastern China (Alexander et al. 2001). No. 460 Au deposits of Gansu province in China in this study is located between the Tuwu-Yandong porphyry CuMo deposits and the Oyu Tolgio porphyry Au-Cu-Mo deposit. Geological evolution of the Beishan area in the Late Paleozoic Era were possible dominated by the Kazakhstan- Tarim plate in the south and Siberian plate in the north. The accretion of magmatic arcs were matured and northward-directed migrated. 2 Location and physiography The study area is located in Gansu Province, the arid Gobi desert in northwestern China, with eastern longitude of 96°19’09” to 96°27’09” and northern latitude of 42°21’24” to 42°26’15”. It is less than 30 km south from the border between China and Mongolia. The Beishan Mountain with the typical wind-blown erosive rocky hills is at average elevation of 1695 m above sea level, with a maximum of 2583 m in the Ma’anshan peak. The region is characterized by the relatively flat to gently undulating topography of the rocky Gobi desert. The wind-blown fine-grained sand mounds around low bushes and grasses common in the region, indicating that fine-grained sands are transported material. Relative large-size rock-chips more than 3 cm in diameter are derived from weathering exposure of bedrocks at the surface, which provides a special geochemical landscape for rockchip geochemical reconnaissance (Fang 1986). 3 Methods Sampling grids of geochemical rockchip are 250 m × 25 m with sample spacing 25 m and without sampling within areas of the Quaternary sediments. Rockchip samples in the field were, generally, more than 2 cm × 2 cm in size, most of which were directly derived from outcrops of bedrocks. Weight of samples was more than 500 g at site sampling. Rock-chip samples were crushed 1–4 mm in a rollingball crusher, then quartered, and pulverized 80 g of the samples in a crusher to less than 0.095 mm in size. The samples were analyzed at the Analytic Laboratory of Northwest Geophysical and Geochemical Exploration Team, CNNC. The rock-chip samples collected for petrographical- geochemical survey were analysed quantitatively by chemical enrichment using spectrographic method for Au, and by AAF for As, and SG-4 for mercury, Close 1524 Wei-Xuan Fang · Zhuan-Ying Huang · Bin Zhou · Yun-Bing Nong · Tian-You Zheng and by semiquantitative emission spectrographic methods for Mo, Cu, Pb, Zn, Ag, Mn, Ba, Ni, Co, Cr, V, Ti, B, Sr and Sn. Duplicate samples and Chinese National Standard Gold Samples including GAu-1, GAu-2, GAu-3 and GAu-4 were inserted into each batch for data quality control. For statistical data on distributions of trace elements in different rocks and bedrock samples were collected separately from the special geochemical and geological profile surveyed and altered rocks observed were avoided during sampling. However, special attentions were paid on altered and fractured rocks observed and sampled respectively in order to better understand enrichments of trace elements in altered rocks. Two type samples were crushed separately so as to avoid from containments of each other. Correlation, cluster and factor analysis were employed to selected better indicator elements for gold deposits in the region. 4 Results 4.1 Indicator element associations Au, Ag, Hg, Cu and Mo are possible attached to the same cluster proved by factor analysis because these elements were put in the same area, indicating that associations of Au-Ag-Hg-Cu-Mo may be indicator element associations for this Au deposit. 4.2 Rock-chip geochemical anomalies The middle B belts of anomalies typified by Au, Cu, Mo, Ag, Hg and As may be yielded by auriferous quartz veins and porphyry gold mineralization occur in district of the No. 460 gold deposit along trends of the early Carboniferous Baishan Formation and in the middle-late Hercynian composite intrusions, with the length of more than 10 km in the NW trend and width of 1 to 3 km in the NS direction. Nos.1, 2 and 3 anomalies as presented in Table 1 characterize the middle B belts of rockchip geochemical anomalies, covering district of the No. 460 gold deposit in this study. No. 1 anomaly with Au-Cu-Mo-Ag-Hg-As associations is 3000m long in the NW trend and 1000 to 2000m wide in the SN direction, covering approximately 4.5 km2. The No. 1 anomaly is hosted in the middle-late Hercynian composite intrusions and altered andesite that it is attached to the middle part of the early Carboniferous Baishan Formation. There have four higher concentrations of Au-Cu-Mo-Ag-Hg-As associations, whereas one of them had been drilled in the former exploration activities, indicating it is difficulty only to be interpreted by the auriferous quartz veins observed up to now. Therefore, three higher concentrations of Au-Cu-Mo-Ag-HgAs associations are open to be tested in the future. Like No. 1 anomaly, there are two higher concentra- tions with associations of Au-Cu-Mo-Ag- Hg-As in the No.2 anomaly, which are much larger than those of the auriferous quartz veins observed. It can be believed that there are some rooms for follow-up explorations based on the rock-chip geochemical anomaly available in the study. Furthermore, No. 3 anomaly of Au-Cu-Mo-Ag- HgAs associations is more 2500 long in the NW trend and 1000 to 2500m wide in the SN direction, covering approximately more than 4.5 km2 due to its western part is still open. The No. 3 anomaly is dominant hosted by the middle-late Hercynian composite intrusions. Five higher concentrations of Au-Cu-Mo-Ag-Hg-As associations occur in the No.3 anomaly. Actually, the auriferous quartz veins observed are localized in the largest one, one of higher concentrations of Au-Cu-Mo-Ag-Hg-As associations. To sum up, 7 out of 11 higher concentrations of promising Au-Cu-Mo-Ag-Hg-As associations in Nos.1, 2 and 3 rock-chip geochemical anomalies are open to exploration for porphyry-style Au deposit (Fang 1986) to be tested in the future. 5 Discussion 5.1 A favorable geological environment for Au mineralization in porphyry The middle part of the early Carboniferous Baishan Formation comprise gray-green altered andesite with propylitization typified by chloritization, epidotization and calcitization, which are peripheral propylitic alteration, accompanying fractured altered rocks and fractures. These alterations around the middle-late Hercynian composite intrusions are generally extensive and cannot be readily distinguished from regional, low-grade metamorphism affecting the volcanic rocks and the post-mineral- Close Chapter 15-3 · Characteristics of rock-chip geochemical anomalies of No. 460 gold deposits in Gansu Province, China ization intrusions. However, regional, low-grade metamorphism of gray-green andesite is relatively weak compared to the former alteration halo. Stronger propylitic alteration halos, accompanying magnetite, sericitization and silicification occurred in the contract zone between graygreen altered andesites and middle-late Hercynian composite intrusions, and some of them directly being wall rocks of the auriferous quartz veins in the district of 460 gold deposit imply that there might be Au mineralization in porphyry environments with wallrocks of volcanic rocks. 5.2 Au mineralization possibly occurred in porphyry environment First of all, it is very useful to study on distributions of trace elements in different rocks without and with alterations and fractured for it can help us better understand enrichment and depletion regularities of trace elements during hydrothermal processes in the region, especially to better understand sources of gold metallogenic material. Actually, distributions gold concentrations in different rocks implied that Au mineralization in the study area possibly occurred in porphyry environment (Fang 1986). As presented in Figure 3, gold is predominant enriched in granodiorite porphyry, hematite, jaspilite, granodiorite and auriferous quartz veins. Firstly, the auriferous quartz veins were mined as gold ores all the time. Secondly, granodiorite (85 ppb Au) and hematite jaspilite (17 ppb Au) contain higher contents of gold, and they are supposed to be source rocks of gold metallogenic material in the region. On the other hand, Layers of hematite jaspilite from the Early Carboniferous Baishan Formation are of stable strata with 5 to 20 m thick and more than 1000 m long in the region, they have thick massive and laminated structures in red, brown-red or even grey colours. Hematite jaspilite contains quartz, chert, hema- 1525 tite and magnetite with minor pyrite and trivial chalcopyrite. However, layers of hematite jaspilite interlayered by andesitic lava and tuff were perhaps related to epithermal environment. Thirdly, it is very interesting that Au mineralization were found in the fractured and altered plagioclase granite. The middle Hercynian magmatic intrusions in study area comprise granodiorite and plagioclase granite at ages of 303 Ma dated by the U-Pb method of zircon (Cui and Chen, 1996). Plagioclase granite occurred as stocks with long axes of ellipse shape in the EW direction. Locally, it was fractured by late faulting and altered DP=diorite porphyry; FAGP=fractured and altered granite porphyry; DPH= diabase porphyrite; GD= granodiorite; GPD=granite porphyry dike; G=granite by late hydrothermal solutions. Therefore, K-silicate altered rocks in the fractured and altered plagioclase granite comprise K-feldspar, biotite, sericite, illite and kaolinite. Obviously, some of the auriferous quartz veins are hosted in the fractured and altered plagioclase granite. The fractured and altered plagioclase granite contain Au ranging 60 to more than 1000 ppb Au with a mean value of 102 ppb Au (Fig. 4) when extensive quartz- sericite- illite alteration occurs as fine-grained replacements of original rocks including granodiorite and plagioclase granite, and constituents without significant quartz-veinlets. However, advanced argillic alteration associations rich in kaolinite, dickite, micaceous sericite and illite are absent in the district. It is significant that diorite porphyry dikes in NW the trend contain a mean values of 155 ppb Au and ranges of 1.8 to more than 1000 ppb Au. Quartz-sericite-chlorite-pyrite alteration occurs as fine-grained replacements of original rock in the Au-bearing (> 1000 ppb Au) altered diorite porphyry that it is considered to be new mineralization, i.e., gold mineralization in porphyry environment in the district of 460 gold deposit. The diorite porphyry dike intruded in the granodiorite and plagioclase granite and was inter- Close 1526 Wei-Xuan Fang · Zhuan-Ying Huang · Bin Zhou · Yun-Bing Nong · Tian-You Zheng sected by veins of granite porphyry. Auriferous quartz veins occurred along the veins of granite porphyry that occurred as dykes along faults with EW trend. Diabase porphyrite occurred as dikes and emplaced in NE-trening and EWtrending faults, which can be one part of gold mineralization in porphyry environment in the study area when extensive chlorite-quartz-pyrite alteration appeared. Dikes of diorite porphyry, granite porphyry and diabase porphyrite are probable attached to the late Hercynian magmatic intrusions in the district of 460 gold deposit. 5.3 Known auriferous quartz veins The structure of the district is characterized by three major EW-trend faults although NE- and NW-trend are also present. Most of the auriferous quartz veins occurred in the EW-trend faults. Auriferous quartz veins at grades of 2.1-18.8 g/t Au in the 460 gold deposit are hosted in the middle-late Hercynian composite intrusions and the altered andesite attached to the upper part of the early Carboniferous Baishan Formation. The auriferous quartz veins were localized by faults trending EW direction, with dipping NE 30° to NW 350° at angle of 70° to 80°. The auriferous quartz veins occurred as veins, lenticular and dendritic shapes, which are general 200 to 400m long with maximum length of 900m and 1 to 2.5 m wide. Ore minerals comprise pyrite, chalcopyrite, magnetite, hematite, siderite and native gold. Gangue minerals include quartz, calcite, sericite and chlorite. Native gold occurred as grained, scaly, flaky and arborescent shapes in sizes of 0.1 to 0.6mm with maximum of 1.5 mm in margins or interstices of metal minerals and quartz. According to Cui and Chen’s (1996) study on the 460 auriferous quartz vein, its homogenization temperature of inclusions in quartz ranges from 110°C to 190°C with salinity range of 12.5 to 15 wt% NaCl eq.. metallogenic presses were from 163 to 174 × 105 Pa, implying that metallogenic depth might be from 700 m to 650 m deep. Acknowledgement Chinese State Key Project on Fundamental Research Planning (Grant No.2001CB409805), LODG Visiting Scholar Fund of Institute of Geochemistry of Chinese Academy of Sciences jointly provided financial support for this research project. We are particularly grateful to co-worker in No. 5 Geological Exploration Team of Northwest Metallurgical Bureau for assistance during the fieldwork. Close Chapter 15-4 15-4 Geological characteristics of the Yindonggou Ag-Au-Pb deposit and its mineralization model, East Qinling Baojian Guo, Jingwen Mao, Yongfeng Li, Changqing Zhang China University of Geosciences, 29 Xueyuan Road, Beijing 100083, China Zhiguang Wang Henan nonferrous metals Exploration Bureau, Zhengzhou 450052, China Huishou Ye, Mengwen Li Institute of Mineral Deposits, Chinese Academy of Geological Science, Beijing 100037, China Abstract. The Yindonggou Ag-Au-Pb deposit, located in the Erlangping Group of Palaeozoic age in the East Qinling orogen, south-western Henan, is a recently discovered, large structural alteration-type deposit. Its main veins are ca. two thousands meters long and extend to several hundreds meters at depth. It has an average grade of 333 g/t silver and contains multiple paragenetic metallic minerals. It may be the economically most potential deposit type in the area. In this paper we briefly describe the geological characteristics, ore-controlling factors, and propose a mineralization model. Keywords. Geological characteristics, mineralization model, Yindonggou, Erlangping, East Qinling 1 lntroduction The Yindonggou deposit is located 100 km northwest of the Nanyang city in south-western Henan. It occurs in the Erlangping terrane of the East Qinling west of the Nanyang basin (Fig. 1). The Erlangping Group consist of a set of volcanic-sedimentary associations up to several thousand meters thick. In the last century, several small to medium-sized porphyry and explosive breccia type CuMo deposits and VMS type Cu-Zn deposits and disseminated Au deposits were discovered in the terrane. The recent discovery of the large Yindonggou Ag-Au-Pb deposit by No. 3 Geological Party of the Henan Bureau of Nonferrous Metals Exploration suggests that the area has good prospects for further finding hydrothermal mineral deposits. 2 Geological setting The strata exposed in the area are mainly the Erlangping Group, which is distributed at Xixia, Neixiang, and Nanzhao counties, Henan Province, and is separated from the Qinling Group by the Zhuxia deep fault on the south and from the Kuanping Group by the Waxuezi-Qiaoduan deep fault on the north. Many geologists (Ren et al. 1980; Xu et al. 1986; Hu et al. 1988; Zhang et al. 2001) have argued that the fault hosts ophiolites and is closely related to the subduction of the Yangtze plate beneath the North China plate and their collision has great significance for the tectonic evolution of the East Qinling orogen. Although there are different views about the age of the Erlangping Group, most geologists assign it to Early Palaeozoic. In the area, this group can be divided into three formations; they are in ascending order the Damiao, Huoshenmiao, and Xiaozai formations. The Damiao Formation is composed mainly of siliceous slate, marble, metamorphosed tuffaceous sandstone, and quartz keratophyre with a thickness of 1134–1990 m. Its protoliths are an acid volcanic-terrestrial clastic sequence. The Huoshenmiao Formation consists predominantly of spilite and quartz keratophyre with lenses of carbonaceous and siliceous rocks and marble, with a thickness of 2004–5530 m. The ore deposits occurring in the formation are the Shuidongling and Xizhuanghe VMS Cu-Zn deposits, Xuyiaogou Au deposits, and some orebodies of the Yindonggou Ag-Au-Pb deposit. The Xiaozhai Formation is a thick association of carbonaceous sericite schist and sericite-quartz schist intercalated with volcanic rocks, having a thickness of 1617–2269 m. Its protoliths are sandstone and claystone, belonging to abyssal and bathyal turbidity current deposits with flysch characters (Luo et al. 1992). The main part of the Yindonggou deposit occurs in it. To the south of the Erlangping Group occurs the Palaeoproterozoic Qinling Group complex (Shi et al. 2004), whose protoliths are mainly neritic carbonate rocks with calcareous pelite. They formed in a short time in the continental-margin and rift environment and afterwards they underwent several strong metamorphism-deformation and thermal events (Zhang et al. 1994). To the north of the Erlangping Group there occurs the Mesoproterozoic Kuanping Group, which is composed mainly of two-mica-quartz schist and two-mica schist, with minor plagioclase-amphibole schist and carbonaceous mica-quartz schist. The protoliths are mainly a sequence of volcanic and terrigenous clastic rocks. The former was derived from the depleted mantle, while the latter from the Qinling Group to the south and Taihua Group to the north (Zhang et al. 1994; Zhang et al. 2002). The lineament in the area generally strikes NWW, and Close 1528 Baojian Guo · Jingwen Mao · Yongfeng Li · Changqing Zhang · Zhiguang Wang · Huishou Ye · Mengwen Li from north to south there occur the Waxuzi-Qiaoduan fault, Zhuyangguan-Xiaguan fault, and Zhengping fault successively. These faults are large in scale and have a longactive history. On both sides of these faults secondary faults occur, which are generally up to several kilometres wide. Due to the influence of regional faulting, NW- and NEtrending secondary faults are developed. They occur in swarms, extending nearly linearly, parallelly and discontinuously, and intersect with NWW-trending faults to form a network. All these faults exert a controlling effect on magmatic activities and mineralization in the area. Large-scale volcanic eruption and magmatic intrusion at different levels have occurred in the area. The Erlangping volcanic rocks are a suite of calc-alkaline basalts to alkaline tholeiite, which is considered to be the product of eruption and sedimentation in the back-arc basin (Zhang et al. 2002). The magmatic intrusion mainly took place in the Palaeozoic and Mesozoic, forming acid rocks (batholiths or large rock bodies) distributed in a nearly E-W-trending zone. Mesozoic magmatism generally occurred at the intersection sites of the NWW- and NE-trending faults and controls vein type mineralization surrounding them. For example, the Yindonggou Ag-AuPb deposit is controlled by a hidden rock body. 3 Geological characteristics of the Deposit The ore district is divided into the Yindonggou ore block, Zhouzhuan ore block and Tumuya ore block (Fig. 1). There are a total of 53 veins in the deposit, all of which occur in fractured zones surrounding the concealed rock body. The host rocks are sericite-quartz schist and metasandstone of the Xiaozhai Formation and metaspilite, spilite tuff and granite of the Huoshenmiao Formation. There are two groups of veins: the nearly N-S group and the NW group, with the former predominating. The veins are several hundred to several thousand meters long and thin and uniform with an average thickness of 0.73 m (Table 1). They contain many and rich useful components. The average grades are Ag 333 g/t, Au 4 g/t, Pb 2.78%, and Zn 1.90% and the ore reserves are Ag 1700 t, Au 12 t, and Pb+Zn 430,000 t. So far only the Yindonggou ore block has had a relatively high level of exploration and a small mine has been operated there; therefore the characteristics of the orebodies are clearer. The Yindonggou ore block is located in the eastern part of the deposit (Fig. 2), including 13 veins. The ore reserves are Ag 1250 t, Au 10 t, Pb 100,000 t, and Zn 50,000 Close Chapter 15-4 · Geological characteristics of the Yindonggou Ag-Au-Pb deposit and its mineralization model, East Qinling t. The host rocks are carbonaceous fine clastic rocks of the Xiaozhai Formation, marine mafic volcanic rocks of the Huoshenmiao Formation, and the late Palaeozoic Hercynian Lujiaping granite. The orebodies are not complex and mainly occur in bedded, bed-like, and podiform shapes. Polymetallic sulphide quartz veins occur (0.21.2 m thick generally) at the centre of the orebodies and grade into Ag-Au polymetallic sulphides and pyritizedsericitized rocks towards two sides, but the boundary of orebodies cannot be recognized before chemical analyses. The main orebody Y1, 2300 m long, occurs in carbonaceous fine clastic rocks of the Xiaozhai Formation and Hercynian Lujiaping biotite granite. The shapes of the orebody are simple, mainly bedded, bed-like or podiform. They strike N10°E and dip west at ~30° at the surface, and dip more steeply toward the depth. The thickness is generally about 0.6 to 0.9 m, with an average of 0.65 m. The averaging grades are Ag 466 g/t, Au 5.3 g/t, Pb 2.1%, and Zn 1.9%. The thickness and grade of the orebody increase at depth. The main metallic minerals include electrum, argentite, gold, galena, sphalerite, pyrite, chalcopyrite, and pyrrhotite; the gangue minerals include quartz, feldspar, sericite, chlorite and calcite. The ore exhibits euhedral to anhedral granular texture, cataclastic, interstitial, poikilitic, and replacement corrosion textures and spotted, disseminated, massive, banded, network, and breccia structures. The alteration types include silicification, pyritization, sericitization, chloritization, and carbonisation. The alteration zones, varying in thickness from ~5 to 10 m, generally are thicker in metamorphic rocks of the Erlangping Group and narrow in granite. There are three mineralization stages: (1) quartz-pyrite stage, which witnessed filling of quartz along cracks and ductile deformation; (2) quartz-polymetallic sulphide stage, which is the crucial mineralization stage; and (3) carbonate stage, in which mineralization was relatively weak. The mineralization and alteration exhibit apparent vertical zoning: carbonization and weak mineralization are pronounced at the top of the orebodies; pyrite, galena and silver increase in the middle; and at depth sphalerite, chalcopyrite and gold increase but silver decreases. 4 1529 Proposed mineralization model There is no direct and reliable evidence about the mineralization age so far, but it is inferred that the deposit probably formed in the Mesozoic. As the veins cut Hercynian granite and occur around the blind Mesozoic granite, the mineralization should occur later than Hercynian granite and even slightly later than Mesozoic granite. In addition, according to an analysis of the geological evolution, the Mesozoic, especially the period of Late Jurassic to Early Cretaceous, is the main mineralization age for most hydrothermal deposits in the East Qinling orogen. The ore-forming material might be derived from the Xiaozhai Formation. On the basis of dispersion train measurements of the Xiaozhai Formation by the No. 5 Geological Survey Party of the Henan Nonferrous Metals Exploration Bureau in the 1990s, the contents of the oreforming elements Au, Pb, Zn, As, Sb, Bi, Ba, and F and indictor elements are apparently higher than those in the underlying Damiao and Huoshengmiao formations, and the high contents of volatiles such as Ba and F suggest that the Xiaozhai Formation might be abyssal argillaceous, fine clastic rocks associated with hydrothermal sedimentation. The nearly N-S- and NE-striking ore-hosting faults exhibit the characteristics of multi-stage activities. They were ductile in the early stage and brittle in the mineralization stage. The ore-forming fluids are of Cl-Na type with Cl>F and Na>K, being mainly neutral, and became CO32- type in the late stage, showing the subalkaline character. Fluid inclusions show that they contain magmatic water and meteoric water. The variation in composition of the inclusions shows that more and more meteoric water entered into the ore-forming fluids with the evolution of mineralization (Zhang et al. 2004). The proposed mineralization is as follows: The subduction of the south China plate beneath the North China plate in the Early Palaeozoic resulted in the formation of the very thick Erlangping Group in a back-arc basin environment. The Xiaozhai Formation in this environment became the main ore source because of its high content of ore-forming material and feature of easy remobilisation. Close 1530 Baojian Guo · Jingwen Mao · Yongfeng Li · Changqing Zhang · Zhiguang Wang · Huishou Ye · Mengwen Li In the Triassic the North China plate and South China plate collided and were amalgamated, resulting in N-S compression and crustal shortening in the East Qinling (Zhang et al. 2001; Mao et al. 2003, 2005), and the high pressure and high temperature brought about partial melting of the lower crust. In the Late Jurassic to Early Cretaceous (at 140-120 Ma), lithospheric thinning and extension in eastern China resulted in upwelling of the asthenosphere and large-scale magma activities. Under the controls of the tectono-thermal event, magmatism, and magmatic fluids and later in the presence of meteoric water, ore-forming fluids extracted ore substances from the Xiaozhai Formation and unloaded them along the reactivated N-S- and NW-trending faults, thus forming the large Yindongou Ag-Au-Pb deposit. References Chu XC, Wang HZ, Sheng XG, Guo LF, Zhang JZ (1992) The geology and mineral resources of Henan province (in Chinese). Prospect Press of China, Beijing, 1-918 Deng JF, Zhao HL, Muo XX, Wu Z, Luo ZH (1996) Continental rootmantle tectonics in China: a key to continental dynamics (in Chinese). Geological Publishing House, Beijing, 449-356 Ren JS, Jiang CF, Zhang ZK (1980) The tectonics and evolution of China (in Chinese). Science and Technology Publishing House, Beijing, 1-124 Hu SX, Lin QL, Chen ZM, Sheng ZL, Li SM (1988) Nanjing University Press, Nanjing, 1-553. Jin SW (1988) Discussion on the aspects of Erlangping group. Henan. Geology 6(4):21-26 Luo MJ (1992) Henan gold deposits (in Chinese). Seismology Publishing House, Beijing, 1-442 Luo MJ, Li SM, Lu XX, Zheng DQ, Su ZB (2000) Metallogenesis and deposits series of main mineral resources of Henan province (in Chinese). Geological Publishing House of China, Beijing, 1-355 Mao JW, Xie GQ, Zhang ZC, Li XF, Wang YT, Zhang CQ, Li YF (2005) Mesozoic large-scale metallogenic pulses in north China and corresponding geodynamic settings (in Chinese). Acta Petrologica Sinica 21:169-188 Shi QZ, Yu XD, Li ML, Pang J (2004) The nappe and extentional structure of north margin of east Qinling, Henan province. Geological Publishing House of China, Beijing, 1-204 Xu ZQ (1986) The metamorphic charecteristics and tectonic evolution of east Qinling (in Chinese). Acta Geologica Sinaca 60:237-247 Wang Zg, Liu XD, Zhang ZB, Zhang YL, Xiang SH (2002) The oreforming environment of the silver polymetallic deposit in Erlangping group, east Qinling and its prospecting perspectives. Chinese Geology 28(7): 32-36 Zhang BR, Gao S, Zhang HF, Han YW (2002) Qinling orogenic belt geochemistry (in Chinese). Science Press of China, Beijing, 1-187 Zhang GW, Zhang BR, Yuan XC, Xiao QH (2001) Qinling orogenic belt and continental dynamics (in Chinese). Science Press of China, Beijing, 1-855 Zhang J, Cheng YJ, Li GP, Li ZL, Wang ZG (2004) Characteristics of ore geology and fluid inclusion of the Yindonggou silver deposit, Neixiang county, Henan province: implication for metallogenic type. Journal of Mineral and Petrology 24(3): 55-64 Zhang ZQ, Liu DY, Fu GM (1994) Isotopic research on the metamorphic strata of north Qinling (in Chinese). Geological Publishing House, Beijing, 1-191 Close Chapter 15-5 15-5 Mesozoic Au-Ag-Pb-Mo mineralization in the Xiong’ershan area, western Henan Province, China Baojian Guo, Jingwen Mao, Yongfeng Li, Fengmei Chai China University of Geosciences, 29 Xueyuan Road, Beijing 100083, China Huishou Ye, Mengwen Li Institute of Mineral Deposits, Chinese Academy of Geological Science, Beijing 100037, China Abstract. The Xiong’ershan district is located on the southern margin of the North China Craton and is the second largest Au area in Henan Province, China. It contains Mesozoic hydrothermal Au and Ag, Pb and Mo deposits. The deposits can be classified into different types: cryptoexplosive breccia type Au deposits, structural alteration type Au, Ag and Pb deposits, and porphyry type Mo deposits. The porphyry type Mo deposit formed earlier than other types of deposits. Various deposits formed in an extensional environment that resulted from rapid lithospheric thinning in eastern China during 140-120 Ma, and the combination of a tectono-thermal event and deep deep-seated magmagtic ore fluids and meteoric water that resulted in the formation of large-scale hydrothermal mineralization. Keywords. Deposit type, mineralization characteristics, metallogeny, mineralization model, Xiong’ershan 1 lntroduction The Xiong’ershan area islocated on the southern margin of the North China craton and is the second largest Au area in Henan Province, China (subsequent to the Xiaoqinling Au area). It extends 80 km from east to west and is 15 to 40 km wide, covering an area of ca.2000 km2. It is bounded on the north by the Luoning fault and on the south by the Machaoying fault (Fig. 1). A wealth of published data about this gold-polymetallic area is available (Chen and Fu 1992; Chu et al. 1992; Ren et al. 1996; Wang et al.1996; Zhang et al. 1996, 2001; Guo et al. 1997; Luo et al. 2000; Zhang et al. 2002; Mao et al. 2002a, b, 2003, 2005; Li et al. 2004a, b, 2005). Since the 1980s, many Au deposits and Ag- Pb-Mo deposits have been found and several state-owned gold mines developed. To date geological parties, state-owned gold mining enterprises, private companies and joint ventures have been successfully conducting exploration for Au, Ag, Mo and Pb resources in the area. Among the deposits, the Qiyugou cryptoexplosive breccia type gold deposit has attracted a good deal of attention of geologists for its specific geological characteristics. 2 Regional geological setting The North China and Yangtze blocks collided in the Tertiary, forming a unifying continent (Ames L et al. 1993; Zhang GW et al. 1996, 2001). Later, the Xiong’ershan area became an important component part of the Qinling orogen. The strata in the area are divided into three tectonic units: medium- and high-grade metamorphic basement rocks of the Neoarchean Taihua Group (green formation); low-grade metavolcanic rocks of the Mesoproterozoic cover Xiong’er Group, and littoral-neritic sedimentary rocks of the Guandaokou Group; and Meso-Cenozoic red clastic sedimentary rocks in the extensional downfaulted basins, including sandy conglomerate with mudstone of Late Cretaceous Qiuba Formation, lacustrine- dilluvial-shallow lakeswampy clastic deposits of Paleogene Gaoyugou, Dazhang and Tantou Formations from bottom upwards in the most developed Tantou basin (Chu et al. 1992). Of these the Taihua Group metamorphic rocks form the basement of the craton, overlain by the widespread Xiong’er Group volcanic rocks in west Henan and Guandaokou Group littoral-neritic sedimentary rocks. Both the Taihua and Xiong’er Groups are main host rocks for Au-Ag-Pb-Mo deposits in the area (Wang et al. 1996; Ren et al. 1996; Luo et al. 2000; Mao et al. 2002a). The metamorphic complex and detachment faults developed in the area are a record of Meso-Cenozoic extensional tectonic movement (Wang et al. 1996; Wang et al. 2002; Mao et al. 2005). The detachment fault extend along the unconformity between the metamorphic basement of the Neoarchean Taihua Group and the overlying Mesoproterozoic Xiong’er Group, and the north detachment fault is easier recognizable (Guo et al. 1997). The other important regional faults include the Luoning fault in the north and Machaoying faults in the south. There are four sets of ore-controlling faults in the area: NE-ENE, NNE, NNW and nearly E-W, which form the structural framework of the area. Among them, the NEENE trending faults are best developed, widespread and closely related to the common gold-silver-lead type-the structural alteration type deposits. Three periods of magmatism occur in the region: (1) Neoarchean magmatism appeared as intermediate -basic volcanic rocks of the Taihua Group, which were metamorphosed into various of gneiss in the late stage; (2) Mesoproterozoic magmatism mainly gave rise to rift-type intermediate-basic-acid volcanic rocks; and (3) Mesozoic magmatism which extensively and intensely occurred in Jurassic -Cretaceous age, forming abundant of granitoids. The Huashan granitic batholith is a representative com- Close 1532 Baojian Guo · Jingwen Mao · Yongfeng Li · Fengmei Chai · Huishou Ye · Mengwen Li posite in the area. In addition, intermediate -acid stocks and mafic dykes are also exposed. Spatially, mineralization in the area exhibits a close relation to Mesozoic granitoids, and most deposits occur around or within them (Wang et al. 1996; Mao et al. 2003). 3 Types of Au-Ag-Pb-Mo deposits The main hydrothermal mineralization includes structural alteration type, (which contains steeply dipping-subtype, e.g. the Shanggong Au, Gongyu Au, Kangshan Au, Tieluping Ag-Pb and Shagou Ag-Pb deposits, and gently dipping-subtype deposits, e.g. Qingangping Au and Luyuangou Au deposits), cryptoexplosive breccia type (Qiyugou Au deposit) and porphyry–type deposit (Leimengou Mo deposit). The location of various main deposits is shown in Figure 1 and their characteristics are given in Table 1. 4 Metallogeny of Mesozoic Au-Ag-Pb-Mo hydrothermal ore deposits In the Mesozoic eastern China underwent an event of prominent lithospheric thinning (Deng et al. 1996) and tectonic regime transition, thus resulting in strong magmatism and extensive mineralization (Mao et al. 2003, 2005). Magmatism and mineralization in this area mainly occurred at 140-120 Ma. The reliable ages obtained in recent years are as fellows: The Huashan granite batholith has a SHRIMP zircon U-Pb age of 132.0 ± 1.6 Ma, the Leimengou granite- porphyry has a SHRIMP zircon U-Pb age of 136.2 ± 1.5 Ma (Li 2005), the Mo deposit has a Re-Os model age of 132.4 ± 2.0 Ma (Li et al. 2004a), the Qiyugou Au deposit has a mineralization age of 125 Ma (Wang et al. 2001) and the Gongyu Au deposit has a mineralization age of 122 Ma (Li and Qi 2002). The ages show that: firstly, the Close Chapter 15-5 · Mesozoic Au-Ag-Pb-Mo mineralization in the Xiong’ershan area, western Henan Province, China granite-porphyry formed earlier than the Huashan granite batholith and secondly, the Leimengou porphyry Mo deposit formed earlier than structural alteration type deposits and crypoexplosive breccia type Au deposit. Spatially, various types of deposits occur in the same tectonic unit, reflecting that they are possibly correlated. The structural alteration type (including steeply dipping and gently dipping subtype) is directly controlled by faults and detachments, and the cryptoexplosive breccia type and porphyry type are mainly controlled by the intersection site of faults. Porphyry deposits generally occur in the granite porphyry stocks, while cryptoexplosive breccia type deposits mainly occur in the overlying country rocks of them. The porphyries related to the Mo deposit are mainly derived from the upper mantle and low crust represented by the metamorphic rocks of Neoarchean Taihua Group (Wang et al. 1986; Zhang et al. 2002; Li 2005), and the δ34S values for sulphide minerals from the main mineralization of Mo and Au deposits exhibit a narrow range of closing to naught, implying a deep origin of the ore substance which possibly derived from the Taihua Group green formation and upper mantle (Mao et al. 2002b; Li et al. 2004a). The Hydrogen-Oxygen, Helium-Argon and Nitrogen isotopes show the close relationship of the ore-forming fluids with the magmatic fluids, and in some deposits (e.g.Qiyugou and Gouyu gold deposits) the meteoric water participated in the hydrothermal mineralization system in late stage (Mao JW et al. 2002b; Li et al. 2004b). 5 Hydrothermal mineralization model The North China Block and Yangtze Block collided in the Triassic, resulting in extensive N-S compression and crustal shortening in the Qinling region (Zhang et al. 1996; Ren et al. 1998; Mao et al. 2003, 2005) including the Xiong’ershan area. High pressures and temperatures lead to partial remelting of the lower crust. Approximately in the Late Jurassic to Early Cretaceous (140-120 Ma), rapid lithospheric thinning in eastern China resulted in regional extension, upwelling of the asthenosphere and emplacement or eruption of voluminous magmas (ca.130 Ma). Under the combined controls of the tectono-thermal event and deep-seated magmatic ore fluids and late meteoric shallow fluids, large-scale mineralization occurred (Mao et al. 2003, 2005). Porphyry type Mo mineralization occurred earlier, and then cryptoexplosive breccia type Au mineralization and structural alteration type Au- polymetallic mineralization occurred. For the structural alteration type, the orecontrolling faults has the features of multi-stage activities: in the early stage they usually exhibited a thrust and mylonization; and during the mineralization stage, the principal stress was oriented in a NE-SW direction (Wang et al. 1996; Wan TF et al. 2002) and the faults of the simi- 1533 lar direction exhibited relatively extensional features, which lead to ascent and filling of ore fluids along them and formation of steeply dipping NE- and NNE-trending ore veins, which occur nearly parallelly in swarms and zones. There are also gently-dipping structural alteration gold deposits occurring within detachment faults (e.g. the Qingganping gold deposit). The early-formed ductile shear zones were superimposed by brittle faults and filling of hydrothermal ore fluids during the mineralization stage (Guo et al. 1997). In the Late Cretaceous some small extensional basins began to form in the surrounding area of the mining area. Piedmont and fluiviolacustrine sandy conglomerate with mudstone of the Late Cretaceous Qiuba formation are developed on the south slope of Xiong’ershan (Chu et al. 1992). The coarse sands and poorly-sorted gravels, are mainly derived form volcanic rocks of the Xiong’er Group rather than metamorphic rocks of the Neoarchean Taihua Group or Mesozoic Huashan granite, indicating that the Taihua Group and Huashan granite had not been exposed on the surface despite significant uplift at that time. Later, the deposits of the Paleogene Dazhang and Tantou Formations contain the gravels derived from the Neoarchean Taihua Group, suggesting that the Taihua Group was exposed on the surface at that time. Acknowledgements This study was supported by China Natural Science Foundation (Grant No.40434011). References Ames L, Tilton GR, Zhou G (1993) Timing of collision of the SinoKorean and Yangtze craton: U-Pb zircon dating of coesite-bearing eclogites. Geology 21:339-342 ChenYJ, Fu SG (1992) Mineralization of gold deposits in west Henan, Chin a (in Chinese). Seismology Press of China, Beijing, 1-209 Chu XC, Wang HZ, Sheng XG, Guo LF, Zhang JZ (1992) The geology and mineral resources of Henan province (in Chinese). Prospect Press of China, Beijing, 1-918 Deng JF, Zhao HL, Muo XX, Wu Z, Luo ZH (1996) Continental rootmantle tectonics in China: a key to continental dynamics (in Chinese). Geological Publishing House, Beijing, 449-356 Guo BJ, Dai TG, Xu ML, Wang ZG (1997) Geochemical features along detachment fault zone and its relationship with Au-Ag mineralization in north hillside of the Xiong’er mountain (in Chinese). Mineral Resources and Geology 11(1): 20-25 Li L, Qi JZ (2002) The geological characteristics and genesis of the Gongyu quartz-vein type gold deposit (in Chinese). Mineral Deposits 21(supp): 625-628 Li YF, Mao JW, Guo BJ, Shao YJ, Fei HC, Hu HB (2004a) Re-Os dating of molybdenite from Nannihu Mo (-W) orefield in east Qinling and its geodynamic significance. Acta Geologica Sinica 78: 463-470 Li YF, Mao JW, Guo BJ, Hu HB, Bai FJ (2004b) Geology, geochemistry and genesis of Gongyu structural alteration type gold deposit in western Henan province (in Chinese). Mineral Deposits 23: 61-66 Close 1534 Baojian Guo · Jingwen Mao · Yongfeng Li · Fengmei Chai · Huishou Ye · Mengwen Li Li YF (2005) The Temporal-spatial evolution of Mesozoic granitoids in Xiong’ershan area and their relationships to molybdenum-gold mineralization—A dissertation submitted to China University of Geosciences (Beijing) for doctoral degree (in Chinese) 1-125 Luo MJ, Li SM, Lu XX, Zheng DQ, Su ZB (2000) Metallogenesis and deposits series of main mineral resources of Henan province (in Chinese). Geological Publishing House of China, Beijing, 1-355 Mao JW, Goldfarb RJ, Zhang ZH, Xu WY, Qiu YM, Deng J. (2002 a) Gold deposits in the Xiaoqinling-Xiong’ershan region, Qinling Mountains, central China. Mineralium Deposita 37: 306-325 Mao JW, Zhang ZH, Wang YT, Jia YF, Kerrich R (2002b) Nitrogen isotope and content record of Mesozoic orogenic gold deposits surrounding the North China craton (in Chinese). Sciences of China, Series D 32: 705-716 Mao JW, Li XF, Zhang ZH, Wang YT, Li HM, Hu HB (2003) Geology, distribution, types and tectonic settings of Mesozoic epithermal gold deposits in east China (in Chinese). Geological Journal of China Universities 9: 620-637 Mao JW, Xie GQ, Zhang ZH, Li XF, Wang YT, Zhang CQ, Li YF (2005) Mesozoic large-scale metallogenic pulses in North China and corresponding geodynamic settings (in Chinese). Acta petrologica Sinica 21: 169-188 Ren FG, Li WM, Li ZH, Zhao JN, Ding SY, Gao YD, Wang GF, Wang ZY, Bai WC, Lei SB (1996) Ore-forming geological conditions and models for ore searching and ore evaluation of gold deposit in Xiong’ershan-Xiaoshan area (in Chinese). Geological Publishing House, Beijing, 1-121 Ren JS, Niu BG, He ZJ (1988) Tectonic framework and geodynamic evolution of east China (in Chinese). In Ren JS, Yang WR (eds.). Composition, Structure, Evolution and Environment of Continental Lithosphere of China. Atomic Energy Press of China, Beijing, 1-12 Wan TF, Zhu H (2002) Tectonics and environment change of MesoCenozoic in China continent and its adjacent areas (in Chinese).Geosciences 16: 107-120 Wang XX, Jiang CY, An SY (1986) Characteristics and significance of Two-pyroxene granulite in enclave in small intermediate-acid porphyry rock body (in Chinese). Journal of Xi’an College of Geology 8 (2): 16-21 Wang YT, Mao JW, Lu XX (2001) The 40Ar-39Ar chronology evidence for the mineralization age of the Qiyugou gold deposit (in Chinese). Geological Review 47: 551-555 Wang YT, Mao JW, Lu XX, Ye AW (2002) 40Ar-39Ar dating and geological implication of the auriferous altered rocks from the middle-deep section of the Q875 gold-quartz vein in the Xiaoqinling area, Henan, China (in Chinese). Chinese Science Bulletin 47: 1750-1755 Wang ZG, Cui B, Xu ML, Zheng SM, Wang FG, Lv X, Zhang L, Cheng G G (1996) The tectonic evolution and mineralization in the south margin of north China block (in Chinese). Metallurgy Industry Press of China, Beijing, 1-297 Zhang BR, Gao S, Zhang HF, Han YW (2002) Qinling orogenic belt geochemistry (in Chinese). Science Press of China, Beijing, 1187 Close Chapter 15-6 15-6 The significance of the early deformation architecture in localizing “Carlin-like” gold mineralisation at the Jianchaling Gold deposit, Shaanxi province, Peoples Republic of China Andrew. P. Ham SRK Consulting, Level 26, 44 Market St, Sydney, NSW 2000, Australia Fan Kaiqiang Sino Mining Shaanxi Limited, Jianchaling Mine, XQG Village Hejiayan Township, Lueyang County, Shaanxi Province, 724308, China R. Corben, P.J. Uttley Sino Gold Limited, Level 8, 17 Bridge St, Sydney, NSW 2000, Australia Abstract. The Jianchaling (JCL) deposit is located on the northern edge of the South China Craton and is separated from the North China Craton by the ESE-WNW trending Qinling-Dabie orogenic belt. A recent structural geology study established a new deformation framework for the local mine area. Structural controls on the distribution of Carlin-style mineralisation developed during early ductile deformation that preceded gold mineralisation. Early ductile deformation saw the rotation of early shallow dipping thrust faults to upright attitudes during regional folding. Subsequent extension or gravitational collapse folded bedding and the F145 fault asymmetrically about shallow dipping axial planes, whereby one limb maintained a shallow north dip. These deformation events produced the critical structural architecture for the gold mineralising event. “Carlin type” gold mineralisation was synchronous with late reverse movement along the F145 fault that locally brecciated the shallow north dipping “heterogeneities” in the F145 fault geometry. These heterogeneities were a product of early folding of the F145 fault. The shallow dipping heterogeneities provided the zones of maximum dilation and fracture during the gold mineralising stage, resulting in shallow plunging ore shoots. Steeply plunging ore shoots developed at the intersections of cross cutting gold stage NW and NE striking faults with the ESE striking F145 fault. The Jianchaling mine provides an example where the early deformation history was vital to developing “traps” for mineralisation. In the absence of early recumbent folding, only small, steeply plunging ore shoots would have developed along the F145 fault. Keywords. China, Jianchaling, structure, Carlin type, cleavage asymmetry 1 Introduction The Jianchaling (JCL) gold mine is located along the southern border of the Qinling-Dabei orogenic belt, and on the northern edge of the South Chian Craton in southwest Shaanxi Province of the Peoples Republic of China. It is the first mine designed, constructed, financed and operated to western standards in China, with a pre-mined resource of 1.6 Mt @ 9.85 g/t gold (Vielreicher et al., 2003; Erceg et al., 2004). An ongoing drilling program is cur- rently looking to expand the resource of the nearby Zhangjianshan (ZJS) deposit, as reserves at JCL are almost exhausted. In the mine region, gold is located at the contact of Proterozoic ultramafic and dolomite units that are separated by steeply dipping ESE-WNW trending faults. Within the Jianchaling mine, the most voluminous zone of gold mineralisation occurs along shallow north dipping portions of the ESE trending F145 fault; where the bulk of gold mineralisation is hosted within the footwall ultramafic sequence with minor occurrences of economic gold in the hanging wall dolomite sequence. Gold mineralisation is submicron sized and generally occurs in arsenic-rich rims of finely disseminated sulfides, particularly pyrite, and is constrained within dark grey dolomite-quartz-pyrite alteration selvedge’s in veins and fractures that have formed late in the deformation history. The strong element association of the Au-As-Hg and the alteration and mineralisation assemblages led Erceg et al. (2004), to classify the deposit as “Carlin type”. Two types of ore shoots are found within the deposit. The most voluminous high-grade ore domains are shallow ESE plunging ore shoots that are located along shallow north dipping portions of the F145 fault. Thinner by volume are ore domains that occur at intersections of steeply dipping NW-SE to NE-SW trending faults with the F145 fault. These ore shoots typically have steep east plunges, as the F145 fault has a steep NNE dip. JCL and ZJS are both structurally controlled “Carlintype” gold deposits, where gold is sub-micron sized and generally occurs in arsenic-rich rims of finely disseminated pyrite crystals. To optimize exploration programs, a joint study with staff from Sino Gold and SRK Consulting was initiated to identify testable structural models for the localisation of mineralisation in the Sino Gold mine lease and exploration licence areas. Close 1536 Andrew. P. Ham · Fan Kaiqiang · R. Corben · P.J. Uttley 2 Local geology and geometry of the deposit Gold mineralisation at the Jianchaling deposit is hosted in the steeply north dipping F145 fault and it is the most prominent fault in the mine area. The F145 fault separates metasedimentary rocks in the hanging wall from metamorphosed ultramafic (dunite, harzburgite - Vielreicher 2001) rocks in the footwall, and can be traced along strike for about 5.5km (Fig. 1). The ultramafic footwall rocks consist of variably metasomatised serpentinites and gabbroic rocks (Vielreicher et al. 2003), and are believed to be mid to late Proterozoic in age. The serpentinized footwall sequence adjacent to the F145 fault has been primarily altered to fine grain talc schists, talc-magnesite schists, or massive magnesite rocks with minor quartz-carbonate alteration The footwall ultramafics were overlain by a hanging wall sequence that consists of highly fractured, weakly metamorphosed, recrystallised, massive to well bedded limestone and dolomite. Adjacent to the F145 fault, the carbonate rocks are highly fractured and recrystallised, with variable amounts of silicification. To the north, the hanging wall carbonates are separated from a thick sequence of phyllites and graphitic slates by a steep ESE striking fault, referred to as the F146 fault. Bedding is generally steeply north dipping and it is sub-parallel to the F145 fault geometry. Within the main ore zone at JCL, the F145 fault and bedding have been rotated asymmetrically to shallow north-northeast dips. In long section the main ore zone has a shallow plunge along strike that is intersected by both steep NE and NW striking faults that are SE and NE dipping respectively. The intersections of these faults produce moderate to steep east pitching ore shoots. However along the main ore zone, there are NE to NW striking faults that dip shallowly from the NW to SE, cross cut the F145 fault and locally have increased volumes of ore in the footwall of these faults. Displacement along the cross cutting NE and NW faults is usually small with the majority offsets less than 15m. Whilst the minor shallow faults (or splays) locally produce shallow plunging ore domains, the overall shallow geometry of the main ore zone is continuous for more than 500m along strike (Fig. 2). In cross section the main ore zone ranges up to 100m wide along the shallow northdipping portion of the fault, in areas where shallow north dipping faults are absent. Therefore the overall shallow north dipping ore geometry along the F145 fault must be a product of deformation that preceded mineralisation. Thus to understand the localisation of ore along the F145 fault, necessitated an investigation into the deformation events that initiated the fault and subsequently modified its shape. Close Chapter 15-6 · The significance of the early deformation architecture in localizing “Carlin-like” gold mineralisation at the Jianchaling Gold deposit 3 Summary of the deformation history Structural mapping of the surface and underground exposures, as well as logging of drill core, provided a new deformation framework of the local mine area. Extensional deformation in the time period between the mid to late Proterozoic saw the extrusion of the footwall ultramafics, which precipitated sub-economic nickel mineralisation. Circulation of seafloor hydrothermal fluids synchronous with the extrusion serpentinised the ultramafic rocks. This was followed by the deposition of the hanging wall sequences of the Duan Tou Yan formation in a progressively deepening ocean. Compressional deformation (D1) which was approximately N-S directed, affected these sequences late in the Phanerozoic by initiating thrusting along ESE striking faults, including the F145 fault. Regional upright folding followed during approximately NNE-SSW bulk shortening (D2). During D2, bedding and ESE striking faults within the mine area were rotated from shallow to steep dips. This deformation event records near peak metamorphic conditions and produced the dominant differentiated crenulation cleavage in the region. Reverse faulting along the ESE striking faults late in D2 enhanced the penetration of CO2 rich fluids that metasomatised both the ultramafic and sedimentary sequences. Recumbent folding during D3 locally rotated bedding and early deformation fabrics and faults from steep to shallow dips. Deformation during D3 is possibly the consequence of orogenic collapse of the orogen between shifts in the direction of bulk shortening. Strain was accommodated along the F145 fault by folding during D3 rather than by shearing, and deflected the geometry of portions of the fault from steep to shallow dips. NE over SW displacement was recorded by bedding, the S2 foliation and the folded portions of the F145 fault. Folding of the F145 fault created heterogeneities in the average fault dip that focussed deformation and mineralisation during D4. Renewed horizontally directed NE-SW shortening transpired during D4. Exhumation of the rocks during D3 had elevated the rock package to higher crustal levels, where brittle deformation dominated. Reactivated sinistral reverse (mostly reverse) faulting along the ESE striking F145 fault saw strain accommodated across shallow dipping portions of the fault by fracture and brecciation. Enhanced fluid flux in to these zones of brecciation advanced the precipitation of gold. Reactivated reverse shear along the long limbs of the folded fault propagated new hanging wall faults. Steep NW striking mostly reverse faults disrupted the F145 faults and locally precipitated narrow, steep plunging ore shoots. Small offsets (<10m) of the F145 fault along steep NNE and NNW striking faults post date gold mineralisation during D5. Bulk shortening during this phase of deformation was E-W directed whereby only minor fractures and faults developed. 4 1537 Significance of early ductile deformation to mineralisation The early ductile deformation at Jianchaling has controlled the architecture of the F145 fault for later gold mineralisation. A key to recognising the importance of the early ductile deformation was found in the differentiation asymmetry of cleavage in phyllites and slates found in the hanging wall of the F146 fault, which is located parallel to and north of the F145 fault. The hanging wall of the F146 fault hosts an anticline where on the northern side of the anticline, the differentiated cleavage S2 is steeper than bedding and is sub-parallel to the axial plane. Vergence from both the differentiation asymmetry and bedding cleavage relationships indicates an anticline to the south. On the southern limb of the anticline, the S2 cleavage has a shallower dip than bedding and the differentiation asymmetry indicates a syncline to the north. This indicates that the S2 cleavage was not axial planar to the hanging wall fold and that the geometric relationship is only possibly if the S2 differentiated cleavage has been folded with bedding. Asymmetries from weaker fabrics developed during D3 and D4 suggest that folding in the hanging wall of the F146 fault was a two-stage process. Initially steeply dipping beds and cleavage were rotated to shallower dips during D3, which then exposed both bedding and cleavage to upright folding during D4. Deformation in the hanging wall carbonate rocks could not be accommodated by folding in the same way as the ‘weaker’ phyllites and slates within the hanging wall of the F146 fault during D4. Instead, deformation was effectively partitioned coarsely between the two steeply dipping ESE striking faults during D4 and was mostly accommodated by reactivation of these faults. This partitioning of strain was crucial in localising brecciation along the F145 fault during mineralisation. Reactivation of the F145 fault, however, was not enough to localise of economic gold mineralisation. It was the shear of the irregular geometries within the gross F145 fault shape during reactivation that allowed mineralisation to be localised into an economic gold deposit. The geometry of the F145 fault has followed a similar path to bedding in the hanging wall phyllites. After initial thrusting, the F145 fault rotated to a steep north dip during regional upright folding, where the regional fold axis is located more than a kilometre to the SSW of the mine. Ductile deformation during D3 folded the F145 fault about shallow dipping axial planes with a NE over SW sense of shear. These folded portions of the F145 fault are heterogeneities within the gross fault geometry that enabled fracturing and brecciation to be localised during reactivation of the F145 fault during D4. Shallow dipping splay faults initiated along the folded portions of the F145 fault to accommodate the mostly reverse movement of the F145 fault. Close 1538 Andrew. P. Ham · Fan Kaiqiang · R. Corben · P.J. Uttley Consistent shallow southwest dipping sheeted mineralised veins/fractures sets developed in response to the movement along these splays and the F145 fault. In contrast, steep NW striking reverse faults that intersect the F145 fault and were active during gold mineralisation (Vielreicher et al. 2003) produced steeply plunging but thin ore zones. In the absence of the heterogeneities along the F145 fault that developed during D3 folding; only thin, steeply plunging, sub-economic mineralised zones could form. Therefore the deformation during both D2 and D3 has been crucial to creating heterogeneities along the F145 fault that subsequently localised gold mineralisation. 5 Conclusion Transporting metals in a hydrothermal system typically requires large fluid fluxes due to the low solubility of metals. The percolation of a significant volume of fluid to precipitate an ore deposit requires enhanced permeability particularly in low permeable rocks. Fractured rocks in fault zones create zones of high permeability for hydrothermal fluids to flow. However, the fault zone must be active, as any precipitation of minerals from the hydrothermal fluid, such as quartz, will reduce the fault zones permeability. Heterogeneities within active fault zones are locations where rock fracture intensifies, as the rock has to accommodate deformation around the heterogeneity. Zones of intense fracture or brecciation increase fluid flow into these zones and the enhanced porosity locally reduces the fluid pressure and thereby promotes mineral precipitation. The Jianchaling deposit is an excellent example where the early ductile deformation was critical in developing heterogeneities within the F145 fault that subsequently localised gold mineralisation. Gold mineralisation has developed late in the deformation history and has “Carlin like” affinities, with strong element associations of the Au-AsHg as well as the alteration and mineralisation assemblages. However without the structural “traps” that developed during early ductile deformation, gold mineralisation at the JCL deposit, “Carlin-like” or otherwise, would have only developed smaller ore bodies. Acknowledgements Paul Martin of GeoPres Pty Ltd is thanked for his redrafting of the figures. Yang Aidong, the General Manager of the Jianchaling mine is thanked for his support of the project. Close Chapter 15-7 15-7 Source of fluids in the Longquanzhan gold deposits in the Yishui area, Shandong, China Huabin Hu, Shuyin Niu, Baode Wang, Aiqun Sun, Chuanshi Xu The Shijiazhuang University of Economics, 302 Huainan Road, Shijiazhuang, China Yongfeng Li, Mengwen Li China University of Geosciences, 29 Xueyuan Road, Beijing, China Abstract. The Longquanzhan gold deposit, hosted in Archean gneiss is located along the Tanlu fault zone, on the southeastern margin of the North China craton. The orebodies occur as veins striking 15°- 18° and dipping SE at 35°–62°. Wall rock alteration types include silicification, pyritization, and sericitization, and chloritization, calcitization. Metallic minerals in ores are dominated by pyrite. Gold occurs mainly in the form of electrum. All inclusions are two-phase (L+V) NaCl- H2O type. The inclusions generally range in diameter from 2 to 8 µm with a vapour/liquid ratio of 5–90% and mainly 5– 10%. The homogenization temperatures of fluid inclusions in the Longquanzhan gold deposit are between 108 and 300°C. The icemelting temperatures vary from –2.0 to –8.6°C, at a peak of –2.5 to –7.0°C. The salinities determined from the ice-melting point of the fluid inclusions range from 3.39 to 12.39 wt.% NaCl equiv. According to isotope fractionation equation and mean homogenization temperatures, the δ18O values of the mineralizing fluids are calculated, ranging from –0.28‰ to +4.07‰, showing mixing of oreforming fluids and meteoric waters. The 3He/4He ratios of fluid inclusions in pyrite are 0.14–0.24 Ra, suggesting the crustal source of ore-forming fluid. The assemblage of alteration minerals, the characteristics of fluid inclusions and stable isotopes indicate that the Longquanzhan gold deposit belongs to epithermal type deposit. Keywords. Longquanzhan gold deposit, inclusion, stable isotope, source of fluid, China 1 Introduction The Longquanzhan gold deposit is situated approximately 20 km south of Yishui County, Shandong, located tectonically in the Tanlu fault zone in the southeastern margin of the North China craton. The gold deposit, discovered by the Institute of Shandong Geology and Mineral Resources in 2002, is now being prospected. The previous work of the gold deposit was scarce. This paper describes the metallogenic setting and geological characteristics of the gold deposit. Fluid inclusion investigations, S, O and H stable isotope data and He and Ar isotope data from fluid inclusions are presented. These data form the basis for an assessment of possible sources of the ore-forming fluids. 2 Regional geological setting The strata of the region consist of the basement and cover strata. The basement rocks are composed of the MesoArchean Yishui Group with a residual zircon SHRIMP U- Pb age ranging from 2.82 to 3.07Ga (Shen et al 2004), the Neoarchean Taishan Group-complex with an age range from 2767 to 2490Ma (Jahn et al. 1988) and trondhjemitetonalite-granodiorite suite (TTG) and Paleopro- terozoic orogenic granites (Fletcher et al. 1995). The Taishan Groupcomplex is composed dominantly of amphibolite and biotite granulite (leptite) with minor TTG gneisses, which suffered from medium- to low-grade metamorphism. The cover rocks comprise the Neoproterozoic Tumen Group and its overlying Paleozoic strata, lithologically including carbonate rocks and clastic rocks (Shen et al. 2000; Hu et al. 2004). Tan-Lu fault zone, which extends NNE for more than 3000 km, constitutes a conspicuous tectonic belt along the northeastern margin of the Asia continent. In Shandong province, the Tan-Lu fault zone strikes at 10°to 25° for about 330 km, can subdivided from west to east into Tangwu-Gegou fault, Yishui- Tangtou fault, AnqiuJuxian fault and Changyi-Dadian fault. The Tan-Lu fault zone is a sinistral shear zone with a slip about 540 km and repeated extension (Okay and Sengor 1992; Yin and Nie 1993). The age of the Tan-Lu fault is open to debate, assigning to Precambrian (Fletcher et al. 1995), Paleozoic (Yin and Nie 1993), and Mesozoic (Xu et al. 1987; Okay and Sengor 1992). Mesozoic potassium-rich volcanic rocks are distributed mostly in terrestrial down-faulted volcanic-sedimentary basins. They consist predominantly of subalkalineintermediate-basic pyroclastic rocks and lava, as well as trachybasalt, shoshonitic rocks, determined to be 40Ar/ 39Ar plateau ages varying from 114.8 ± 0.6 to 124.3 ± 0.6 Ma (Qiu et al. 2001). 3 Geology of gold deposit The strata exposed in the Longquanzhan ore district include Cretaceous volcanic- clastic rocks, Neoarchean gneiss and granite with zircon SHRIMP U-Pb ages ranging from 2.51 to 2.62Ga(Shen et al 2004). The gold deposit hosts in the Neoarchean gneiss in the bottom wall of the Yishui- Tangtou fault (Fig. 1). Up to now, two orebodies referred to as the No. I and No. II have been discovered. Orebody No. I strikes 15° and dips at 35-50°, with ~1600m long and 0.5-3m thick. Its grades range from Close 1540 Huabin Hu · Shuyin Niu · Baode Wang · Aiqun Sun · Chuanshi Xu · Yongfeng Li · Mengwen Li 2.05 to 15.3g/t, with a mean of 4.52g/t. Orebody No. II strikes 18° and dips at 48°–62°, with ~1200m long and 0.84-4.62m thick. Its grades range from 1.08 to 5.48g/t, with a mean of 1.75g/t (Li et al. 2004). Wall rock alteration types include silicification, pyritization, sericitization, chloritization, and calcitization, of which silicification, pyritization, sideritization are closely associated with the gold mineralization. Metallic minerals in ores are dominated by pyrite, accounting for 5-15%, with minor chalcopyrite and galena. Gangue minerals comprise chlorite, quartz, sericite and plagioclase. Gold occurs mainly in the form of electrum, and minor native gold. Gold mineral is gold-yellow in colour, with a strong metallic lustre, and mainly occurs as grains, ranging from 0.003 to 0.18mm in size. Microprobe analysis gave the following composition (%) of electrum: Au 67.97, Ag 30.92, Cu 0.59, Fe 0.52. 4 Fluid Inclusion studies 4.1 Samples and analytical methods Microthermometric measurements were carried out on a Linkam THMSG 600 programmable heating- freezing stage (-196 to +600ºC) at the Laboratory of the Faculty of Geosciences and Mineral Resources, China University of Geosciences, Beijing. The heating rate was 0.1 to 1 ºC/ min below 10 ºC, whereas the heating rates were about 3 to 5ºC/min at 10 to 31ºC, with a reproducibility of ± 0.1ºC. The heating rate was 5 and 10ºC/min at higher temperatures (>100ºC), with a reproducibility of ± 2ºC. 4.2 Inclusion types and characteristics Fluid inclusions were examined in 10 samples from the gold deposit. There were abundant fluid inclusions in quartz and calcite of alteration minerals. Measurements in transparent minerals were typically restricted to primary or pseudosecondary inclusions. All inclusions are two-phase (L+V)NaCl- H2O type, consisting of aqueous liquid and vapor bubbles, with a vapor/liquid ratio of 5– 90% and mainly 5–10%. The inclusions generally range in diameter from 2 to 8 µm, and in a few individual cases may reach a maximum of 18µm. Most inclusions have elliptical, rounded, elongated and irregular shapes. 4.3 Microthermometric results The homogenization temperatures of fluid inclusions in the Longquanzhan gold deposit are between 108 and 300°C. The ice-melting temperatures vary from -2.0 to 8.6ºC, at a peak of -2.5 to -7.0°C. The salinities determined from the ice-melting point of the fluid inclusions range from 3.39 to 12.39 wt.% NaCl equiv (Bodnar 1992). We obtained corresponding fluid densities between 0.708 and 0.981 g/cm3 by consulting the table of Liu and Shen (1999) according to the homogenization temperatures and salinities of the aqueous fluid inclusions. 5 Stable isotope studies 5.1 Samples and analytic methods Four fresh pyrite samples were collected for sulphur isotope measurements, which were selected under the binocular microscope to ensure their purities were over 99%. Cu2O was used as the oxidizer for the preparation of sulphide samples. Sulphate minerals were purified to pure BaSO4 by the carbonate-zinc oxide semi-melt method, and then SO2 was prepared by the V2O5 oxide method. The SO2 released was measured for sulphur isotopes. Four samples were selected for helium and argon isotope measurements. Each pyrite sample was picked using a binocular microscope and its purity was over 99%. Helium and argon isotopes were analyzed at the Stable Isotope Laboratory, Institute of Mineral Resources, Chinese Academy of Geological Sciences. The analytical procedure is as follows (Mao et al. 2002a). Close Chapter 15-7 · Source of fluids in the Longquanzhan gold deposits in the Yishui area, Shandong, China For analysis of hydrogen isotope, the water in fluid inclusion was released by decrepitation method. Then the water was reacted with Zn at 400ºC to produce H 2 (Coleman et al. 1982), which was collected in sample tube with activated charcoal at liquid N2 temperature (Mao et al. 2002b). All SO 2, CO2, and H 2 were analyzed in a Finningan MAT 251 mass spectrometer, at the Stable Isotope Laboratory of the Institute of Mineral Resources, Chinese Academy of Geological Sciences. Analytical reproducibility in this study is ± 0.2‰ for S, O and C isotopes, and ± 2‰ for H isotopes. 1541 matic water and meteoric water and have a tendency to “drift” to the meteoric water line, showing mixing of oreforming fluids and meteoric waters. The 3He/4He ratios of fluid inclusions in pyrite are 0.140.24 Ra, which are 5-10 times higher than that of the crust (0.01-0.05 Ra) (Stuart et al. 1995) but 20-40 times lower than that of the mantle (6-9 R/Ra), suggesting the oreforming fluid from crust source. The lower 3He/4He ratios of the ore are obviously different from those (3.59.8Ra) from the Wangu gold deposit adjacent to the TanLu fault (Mao et al 2002c), and from those (0.5-5.2Ra) from the Dongping gold deposit (Mao et al 2003), which are reported to have involved some mantle-derived fluids during mineralization. 40Ar/36Ar ratios are 289-482, slightly higher than those of the atmosphere (40Ar/ 36 Ar=295.5), indicating the existence of a small amount of excess argon produced probably by higher radiogenic 40Ar. Therefore, The assemblage of alteration minerals, the characteristics of fluid inclusions and stable isotopes suggest that the Longquanzhan deposit belongs to epithermal gold deposit (Lindgren, 1922). The sulfur, hydrogen and oxygen, and helium and argon isotopic compositions indicate that ore-forming fluid originated from lower crust and mixed with deeply circulating meteoric water. Acknowledgements This study was supported by the National Natural Science Foundation of China (No. 40272088). 5.2 Results and discussion The δ34S values of pyrite range from -4.2 to 4.4‰ with a mean of 1.55‰, suggesting a mantle or lower crust source of sulphur in the ores. In the Longquanzhan gold deposit, δ18O values of alteration minerals range from 8.3 to 12.0‰ . The mean homogenization temperature of 290? was obtained by averaging homogenization temperatures of 58 inclusions in quartz from the Longquanzhan gold deposit. According to the quartz-water isotope fractionation equation 1000 ln α = 3.42 × 106 T–2 – 2.86‰ (Zhang et al. 1989, the δ18O values of the mineralizing fluids were calculated ranging from 1.77 to 4.07). The mean homogenization temperatures of 190? were obtained by averaging homogenization temperatures of 90 inclusions in calcite. Using the calcite-water isotope fractionation equation 1000 ln α = 2.78 × 106 T –2 – 2.89 (O’Neil et al. 1969), the δ18O values of the mineralizing fluids are calculated, ranging from -0.28 to 1.78‰. The δ18Ofluid values of ore fluids of the Longquanzhan gold deposit are relatively low, from -0.28‰ to +4.07‰, being notably deviated from the δ18O fluid range (5.5 to 9.5‰) of magmatic water defined by Sheppard (1986). In the δD vs. δ18Ofluid diagram (Fig. 2), five data points are plotted between mag- References Bodnar R (1992) The system H2O-NaCl. PACROFIIV, Program and Abstracts 108-111 Coleman, ML, Sheppard, TJ, Durham, JJ, Rouse, JE, Moore. GR (1982). Reduction of water with zinc for hydrogen isotope analysis. Analytical Chemistry 54: 993-995 Fletcher CJN, Fitcher WR, Rundle CC, Evans JA (1995) Geological and isotopic constraints on the timing of movement in the TanLu fault zone, northeastern China. 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Geological Publishing House, Beijing, 1-179 (in Chinese with English abstract) Shen Q, Song B, Xu H, Geng Y (2004) Emplacement and metamorphism ages of the Caiyu and Dashan igneous bodies, Yishui county, Shandong province: zircon SHRIMP chronology. Geological Review 50(3): 275-284(in Chinese with English abstract) Sheppard SMF (1986) Characterization and isotopic variations in natural waters. Rev Mineral 16: 165-183 Stuart FM, Burnard PG, Taylor RP, Turne G (1995) Resolving mantle and crustal contribution to ancient hydrothermal fluids: He-Ar isotopes in fluid inclusions from Dae Hwa W-Mo mineralisation, South Korea. Geochimica et Cosmochimica Acta 59: 4663-4673 Xu J, Zhu G, Tong W, Cui K, Liu Q (1987) Formation and evolution of the Tancheng- Lujiang wrench fault system: a major shear system to the northwest of the Pacific ocean. Tectonophysics 134: 273-310 Yin A., Nie S (1993) An indentation model for the north and south China collision and the development of the Tan-Lu and Honam fault systems, eastern Asia. Tectonics 12(4): 801-813 Zhang L (1989) Petrogenetic and minerogenetic theories and prospecting. Press of Beijing Technological University, Beijing, 1-267 (in Chinese) Close Chapter 15-8 15-8 The Jinfeng gold deposit: A new mine leading the way for foreign investment in Guizhou Province, China Robert P. Ilchik, Phillip J. Uttley, Ross Corben Sino Gold Limited, Level 8, 17 Bridge St, Sydney, NSW 2000, Australia Alex Yongming Zhang Sino Guizhou Jinfeng Mining Limited, Level 11, 1 Yan’an Zhong Road, Guiyang, China Andrew P. Ham, Paul Hodkiewicz SRK Consulting, Level 26, 44 Market Street, Sydney, NSW 2000, Australia Abstract. The Jinfeng is the largest known Carlin-type gold deposit in the Peoples Republic of China, with an identified mineral resource of at least 3.5 m oz of contained gold. Jinfeng is a structurally controlled deposit within Triassic turbiditic sediments that overly Permian limestone. This sequence has a multi-phase deformational history dominated by NE-SW compression and to a lesser degree NWSE compression. These events have produced a complex series of gentle to tight folds, and reactivated thrust and transfer faults. This provided the setting for gold mineralisation, which occurred late in the deformational history and is mainly confined to second-order faults F3 and F2. Gold mineralisation occurs in carbonate- and clayrich rocks. Alteration accompanying gold mineralisation includes replacement of carbonate minerals by quartz, and deposition of arsenical pyrite rims to primary pyrite and arsenopyrite. Late in the mineralisation cycle orpiment and native arsenic were deposited with minor calcite. Gold is found mainly in the arsenical pyrite rims and a lesser amount in arsenopyrite. The June 2004 total Mineral Resource estimate, using a 2gpt Au cut-off, is 20.9 million tonnes at 5.1gpt Au and the total Proved and Probable Ore Reserves are estimated at 11.6 million tonnes at 5.5gpt Au. The project will support annual gold production of approximately 180,000 ounces once full production is achieved in 2006. Both open cut and underground mines will be operated, with initial ore production coming from the open cut. The designed treatment rate is 1.2 million tpa, with provision for expansion. The ore at Jinfeng is refractory but responds well to bio-oxidation and Sino Gold has opted for a BIOX® circuit to treat a flotation concentrate prior to standard CIL leaching to recover the difficult to liberate gold. Overall gold recovery is expected to be 85%. The pre-production capital costs for the project are estimated at approximately US$70 million. Keywords. China, Jinfeng, gold, sediment hosted, Carlin type. 1 The area may have been first exploited last century as a mercury and arsenic mine for Chinese medicines. Jinfeng was discovered in 1986 by Brigade 117 of the provincial Bureau of Geology and Mineral Resources (BGMR) following up on a stream geochemical anomaly. BGMR subsequently drilled approximately 20 km of diamond core and drove 8 km of underground heading to delineate the deposit, but beneficiation of the sulphide ore proved problematic. Starting in 2002, Sino Gold began an exploration program that included more than 45 km of diamond drilling and more than doubled the previous resource. 2 Geological setting Jinfeng, often referred to as Lannigou, is situated in SW Guizhou Province, an agrarian area of steep hills and narrow valleys with elevations between 400 and 800 m adjoining rugged limestone karst country. Rifting of the Yangtze craton during the Precambrian to Cambrian produced a sedimentary basin which now hosts numerous Carlin-type deposits. Locally, Triassic turbidites host the vast majority of gold mineralization. These rocks overly Carboniferous through Early Triassic limestone which core the N-S elongate Laizhishan dome less than 1 km to the west. The sequence has a multi-phase deformational history dominated by NE-SW compression and to a lesser degree NW-SE compression. These events have produced a complex series of gentle to tight folds and thrust and transfer faults, and provided the setting for gold mineralization (Fig. 2). Introduction 3 The Jinfeng is the largest known Carlin-type gold deposit in the Peoples Republic of China, with an identified mineral resource of at least 3.5 m oz of contained gold (Fig. 1). It is currently being explored and developed by Sino Gold Ltd. Sino Gold holds 82% equity in the Sino-Foreign joint venture with Chinese partners. Development began in early 2005, and full production is scheduled for mid-2006. Open-pit and underground operations will produce approximately 180,000 ounces annually from refractory ore using the BIOX® process. Gold mineralisation Gold mineralisation occurred late in the deformational history and is tightly confined to second-order faults, known locally as the F3 and F2, which cut the turbidites. These faults were warped during deformation. The main F3 orebody is a moderately- to steeply-dipping shear zone with several rolls along the 800 vertical meters it has been explored to date (Fig. 3). This orebody trends N73W, and in long section plunges moderately-steeply to the ESE. Several important ore domains are present where splays de- Close 1544 Robert P. Ilchik · Phillip J. Uttley · Ross Corben · Alex Yongming Zhang · Andrew P. Ham · Paul Hodkiewicz veloped off the F3 late in the deformational history. Mineralization in the F3 is open to the E and at depth. The F2 (N20E, 85E) crosscuts the F3, and is only mineralized near this intersection. Further to the W, only scattered bits of mineralization are encountered in local shear zones. Gold mineralization occurs in carbonate- and clay-rich fine sand facies turbidite rocks. Carbonate minerals, both cements and veins that formed earlier in the deformational history, were replaced by quartz. Accompanying this main stage is the deposition of arsenian pyrite rims to primary pyrite and arsenopyrite. Late in the mineralization cycle orpiment and native arsenic were deposited with minor calcite. Gold is found mainly in the arsenian pyrite rims and a lesser amount in arsenopyrite. Gold and mercury are tightly confined to fluid conduits, whereas arsenic and antimony are disseminated up to 30m from these structures. Host rocks contain high concentrations of reactive iron, suggesting that sulphidation was the main mechanism for gold precipitation. 4 Resource development Drilling, completed since the June 2004 resource estimate, continued to produce new intercepts that fall within the open cut design. These intercepts are related to both foot- wall and hanging wall splay faults not intersected by previous drilling (e.g. 21.7m @ 7.6gpt Au down-hole in HDDS101). Additional drilling is expected to increase the amount of gold that is recoverable from the designed open cut. Since acquiring the project, Sino Gold has spent over US$10 million in drilling and underground exploration of the deposit to produce Mineral Resource and Ore Reserve estimates in accordance with JORC, in preparing a Bankable Feasibility Study and completing an Optimization Study. It has taken almost four years for Sino Gold to successfully progress the world-class Jinfeng Project to the construction and development stage. Construction earthworks began in March 2005. Sino Gold is committed to integrating safety and environmental considerations into all phases of the project: its design, its construction, its operation and its ultimate closure. The utmost priority is placed on the safety and health of employees, contractors and visitors and the protection of the natural environment. The promotion of safe work habits receives the highest priority. In early 2004, a commitment was made to compensate residents living in the proposed mine area for relocating. A new village area and market place is being built by Sino Gold to replace the existing facility that was also affected by the mine’s construction. Close Chapter 15-8 · The Jinfeng gold deposit: A new mine leading the way for foreign investment in Guizhou Province, China Regular meetings were held with community leaders in the Sino Gold community centre and in the local villages to explain the progress and impact of the operation and to receive feedback on community concerns. A water supply was provided to the nearby Lannigou village. In total, 360 local people will be trained in technical and administrative skills over a 12-month period. County and Prefecture government officials have been very supportive of the project and were instrumental in undertaking land measurement for compensation for the 70 hectares of land required by the operation. The Jinfeng Bankable Feasibility Study was completed in March 2004, but exploration drilling continued to discover additional mineralisation and is having a significant effect on the project evaluation. Subsequently, an Optimization Study was completed following an update of the Mineral Resources estimate in June 2004. Using this resources estimate, the Optimization Study estimated Ore Reserves from mining and treatment operations using a gold price of US$350/oz. The June 2004 total Mineral Resource estimate, using a 2gpt Au cut-off, is 20.9 million tonnes at 5.1gpt Au and 1545 is more than double the original Chinese resource estimate at the time Sino Gold became involved with the project. Total Proved and Probable Ore Reserves are estimated at 11.6 million tonnes at 5.5gpt Au. The project will support annual gold production of approximately 180,000 ounces once full production is achieved in 2006. At this rate, the operation’s life will be at least 12 years with cash operating costs estimated to be approximately US$183/oz. Both open cut and underground mines will be operated, with initial ore production coming from the open cut. Having a 6-year life, with additional drilling, the open cut is expected to produce 6.5 million tonnes at 5.1gpt Au at a strip ratio of approximately 13:1. The underground mine is scheduled to begin ore production in the latter part of 2012 and is expected to produce 6.9 million tonnes at 5.7gpt Au in total. The designed treatment rate is 1.2 million tpa, with provision for expansion. The ore at Jinfeng is refractory with most of the gold locked up with pyrite. It responds well to bio-oxidation and Sino Gold has opted for a BIOX® circuit to treat a flotation concentrate prior to standard CIL leaching to recover the difficult to liberate gold. Overall gold recovery is expected to be 85%. The pre-production capital costs for the project are estimated at approximately US$70 million, with a more precise estimate being prepared as a result of the design work done by Ausenco and NERIN. The underground workings will not be accessed from the open cut and this allows the option of accelerating development of the underground mine. As Sino Gold has a very positive view on the geological endowment of the Jinfeng area, a scoping study was completed for a Phase 2 expansion to 1.8 million tonnes per annum, adding 50% to the treatment capacity. This scoping study suggests expansion capability to approximately 300,000 ounces per annum with mining of the underground and open pit occurring in parallel. The estimated capital cost for this expansion is approximately US$14 million. Ongoing exploration activity at Jinfeng is being directed at locating resources within trucking distance of the future Jinfeng plant to supplement ore supplies and sustain a Phase 2 expansion. Now that construction has commenced, site activity will rapidly increase during 2005 as China’s second largest gold mine is built. Sino Gold is eagerly anticipating 2006, which will be the year when gold production commences. Acknowledgements The contributions of all the other geologists who have worked on Jinfeng are acknowledged. Sino Gold Limited is thanked for permission to publish. Paul Martin of GeoPres Pty Ltd is thanked for his redrafting of the figures. Close 1546 Robert P. Ilchik · Phillip J. Uttley · Ross Corben · Alex Yongming Zhang · Andrew P. Ham · Paul Hodkiewicz References Hofstra AH, Leventhal JS, Northrop HR, Landis GP, Rye RO, Birak DJ, Dahl AR (1991) Genesis of sediment-hosted disseminated-gold deposits by fluid mixing and sulfidization: Chemical-reactionpath modeling of ore-depositional processes documented in the Jerritt Canyon District, Nevada: Geology 19: 36-40. Ilchik RP, Barton M (1997) An amagmatic origin of Carlin-type gold deposits: Economic Geology 92: 269-288. Li Z, Peters SG (1998) Comparative geology and geochemistry of sedimentary-rock-hosted (Carlin-type) gold deposits in the People’s Republic of China and in Nevada, USA: USGS Open-File Report 98-446, 157 p. Peters SG (2002) Geology, geochemistry, and geophysics of sedimentary-hosted Au deposits in P.R. China: USGS Open-File Report: 02–131, 403 p. Seward TM (1973) Thiocomplexes of gold and the transport of gold in hydrothermal ore solutions: Geochimica et Cosmochimica Acta 37: 379-399. Woitsekhowskaya MB, Peters SG (1998) Geochemical modeling of alteration and gold deposition at the Betze deposit, Eureka county, Nevada: in Tosdal, R.M. (ed), Contributions to the gold metallogeny of Northern Nevada, USGS Open-File Report 98338, p. 211-222. Zhang X (1997) The geology and hydrothermal evolution of sediment-hosted gold deposits in Southwest Guizhou Province, PRC: Imperial College, London, unpublished Ph.D. dissertation, 273 p. Zhang X, Spiro B, Halls C, Stanley CJ, Yang K (2003) Sediment-Hosted Disseminated Gold Deposits in Southwest Guizhou, PRC: Their Geological Setting and Origin in Relation to Mineralogical, Fluid Inclusion, and Stable-Isotope Characteristics: International Geology Review, vol. 45, pp. 407-470(64) Close Chapter 15-9 15-9 An overview of diamond exploration in the North China Craton Michael Michaud China Diamond Corp.1724 Hyde Park Road,London, Ontario,N6H 5L7 Canada Keywords. Diamond exploration, kimberlite, North China Craton 1 Introduction China’s history of diamond exploration and production extends over 40 years, initially concentrating on the discovery of alluvial deposits and later the kimberlitic sources. Diamond production from China currently totals 90,000 carats/ annum from one kimberlite diamond mine, namely China Diamond Corp.’s 701 Changma Mine in Shandong Province that has operated for the past 34 years. Previously, between 1987 and 2002, additional kimberlite diamond production came from the Wafangdian Mine in Liaoning Province, producing approximately 60,000 carats/annum. To date, over 20 diamondiferous kimberlite deposits have been discovered, several of which have been mined on a very small scale. China is underlain by three large Archean cratons, namely the North China Craton, also known as the Sino-Korean Craton, and the Yangtze and Tarim Cratons. In all three of the cratons, several alluvial diamond deposits have been discovered; however, to date, only two diamondiferous kimberlite deposits have realized commercial production, those being located in the North China Craton (Fig. 1). This is due in part to the difficult terrain, lack of adequate access, and extensive soil cover in the Yangtze and Tarim Cratons, comparatively. The North China Craton is considered prospective for diamonds due to the fact that Ordovician-aged kimberlites have traversed the Archean mantle with the potential to be laden with diamonds. However, numerous tectonic episodes have modified the underlying lithosphere since the Ordovician emplacement of the kimberlites, so that selected geophysical data would be misleading as a prospecting tool to identify regions with cratonic physical properties. 2 Regional geology All the so-called cratons in China are not strictly cratons; since they have undergone multiple tectonism since the late Paleozoic. The tectonic framework of China is dominated by three global orogenic systems, the Central-Asian or PaleoTethyan, the Circum-Pacific and the Tethys–Himalaya systems. The Mesozoic–Cenozoic Circum-Pacific orogenic belt in eastern China and the Tethys–Himalaya system in southwestern China are the products of the subduction of the Pacific Ocean floor beneath China, and the indentation of the Indian continent into Eurasia, respectively. The area is underlain by numerous fold belts that are dominantly products of subduction and accretion of oceanic complexes, and were the focus of deformation in Paleozoic–Mesozoic cratonic collisions during final ocean closures. The North China Craton is comprises early Archean to Early Proterozoic basement rocks overlain by Middle Proterozoic to Cenozoic cover. The three major cratons in China (North China, Tarim, and Yangtze) underwent at least three orogenies during the Archean, widely-termed the Qianxian (ca. 3.2 Ga), Fuping (ca. 2.8 Ga), and Wutai (ca. 2.5 Ga). During these orogenies, rock units experienced extensive greenschist to granulite facies metamorphism, intensive migmatization, and widespread magmatism. Subsequently, the Precambrian sequences were locally uplifted and exposed, especially along the margins of the North China Craton during a series of Phanerozoic orogenies. The primary orogenies are defined as between 600 and 405 Ma as Caledonian, 405 and 270 Ma as Variscan, 270 and 208 Ma as Indosinian, 208 and 90 Ma as Yanshanian, and <90 Ma as Himalayan. These collisions may have coincided with development of the Tanlu fault system, extending over 4,000 kilometers, which was continually active along the eastern margin of China during the middle and late Mesozoic Yanshanian orogeny. The Tanlu fault is considered by many to have resulted in a 500 kilometer displacement of the Wafangdian Mine (Fuxian kimberlite field) from the 701 Mine (Mengyin kimberlite field). In the Yanshanian (210–90 Ma) and Himalayan (<90 Ma), the oblique subduction of the Izanagi–Pacific basin plates under the eastern edge of China led to the formation of the NNE-trending Yanshanian magmatic belts and faults along the Pacific continental margin, considered to one the of the most important metalogenic orogenies in China. A comprehensive study using “4-D lithosphere mapping” was completed by Griffin, et. al. in 1997. The main results of this study are summarized as follows: The Lithosphere-Asthenosphere Boundary about 500 Ma ago was at ~180-200 kilometers deep; An Archean lithosphere ~200 km thick existed under the eastern Sino-Korean Craton up to Late Ordovician allowing the emplacement of diamondiferous kimberlite pipes and dikes; Close 1548 Michael Michaud Geophysical data show a present-day thin lithosphere (60 -120 km) and high geothermal gradient under the North China Craton implying the replacement of 80 140 kilometer thick section of the Archean lithosphere with “oceanic” lithosphere since the Ordovician; The replacement of the lithosphere is interpreted to be a result of thermal erosion of the lithosphere linked to two episodes of basin development and rifting associated with subduction. 3 The kimberlitic bodies are typically characterized by porphyritic kimberlite with a matrix of serpentinized olivine and phlogopite and phenocrysts of olivine, biotite and pyrope. The accessory minerals include ilmenite, chromite, and chrome diopside. The breccia rock fragments include local country rock inclusions of limestone and gneiss, and mantle eclogite and garnet lherzolite. The mineral resources for different deposits, and for that matter between different pipes within a deposit, varies considerably in grade, diamond size distribution and quality, as indicated in Table 1. Kimberlite emplacement 4 The emplacement of the kimberlite pipes and dikes in the North China Craton occurred at several times, ranging from 450- 480Ma in age to a much later Tertiary age, the former being diamondiferous and include the kimberlites at the 701 Mine and Wafangdian Mine. The kimberlitic bodies appear to be related to deep mantle structures that have been further controlled by near-surface crustal faults. Many of the kimberlite pipes and dikes in the area occur at or near the intersection of major westnorthwest and north-northeast trending geological structures along the Tanlu Fault trend. The kimberlites form both narrow and often discontinuous dikes that are connected to larger, more ellipsoidal pipes (Figure 2). Discussion The North China Craton is considered prospective for diamonds due to the fact that Ordovician-aged kimberlites have traversed the Archean mantle with the potential to be laden with diamonds. However, numerous tectonic episodes have modified the underlying lithosphere since the Ordovician resulting in the replacement of an approximately 80-140 kilometer thick section of the Archean lithosphere with “oceanic” lithosphere. The Ordovician is related to several episodes of basin development and rifting associated with plate subduction. The thinning of the crust in the North China Craton has important implications for diamond exploration. Geo- Close Chapter 15-9 · An overview of diamond exploration in the North China Craton physical data would be of little use as a prospecting tool to identify regions with cratonic physical properties, and also, in the determination of the age of kimberlites that had the potential to “tap” Archean lithosphere. Great care must be taken to unravel the timing and nature of these tectonic events in order to assist any exploration efforts. 1549 Reference Griffin WL, Andi Z, O’Reilly SY, Ryan CG (1997) Phanerozoic evolution of the lithosphere beneath the Sino-Korean Craton. In: Mantle Dynamics and Plate Interactions in East Asia (Flower, M., Chung, S.L., Lo, C.H. and Lee, T. Y. eds) American Geophysical Union Spec. Publ., in press 7/96 Close Close Chapter 15-10 15-10 Metallogenic dynamics and model of cobalt deposition in the eastern Kunlun Orogenic Belt, Qinghai Province Tong Pan Qinghai Bureau of Nonferrous Metals Exploration, 5 Jianguo Road, Xining 81007, China Caisheng Zhao Institute of Mineral Resources, Chinese Academy of Geological Sciences, 26 Baiwanzhuang Road, Beijing 100037, China Fengyue Sun College of Earth Sciences, Jilin University, 2199 Jianshe Road, Changchun 130026, China Keywords. Metallogenic dynamics, model of cobalt deposit, Eastern Kunlun orogenic belt, Qinghai Province 1 Introduction Recently discovered cobalt is an important mineral species in the eastern Kunlun Orogenic Belt and has shown favorable prospecting prospects, high tenor and large scale reserves. To date, three cobalt deposits have been discovered: that is, Kendekeke and its periphery cobalt-bismuthgold deposit, Tuolugou cobalt-gold deposit and Dulenggou copper-cobalt deposit. Cobalt has the characteristics of being heat-resistant, wear-resistant, high strength and strong magnetism. Furthermore, its alloy and alloy steel are important additives which are indispensable to aviation, electrical appliances and the chemical industry. There are associated cobalt deposit and independent cobalt deposit in this orogenic belt. What are the ore-controlling characteristics and how about their ore-forming metallogenic dynamic mechanism and geology of mineral deposit? The dissertation briefly discusses these scientific problems. 2 Regional geology of the eastern Kunlun Orogenic Belt The eastern Kunlun Orogenic Belt represents the western part of China’s central orogen, and is located in the southern margin of Qaidam massif. The belt has undergone polycyclic complex orogenic processes, polycyclic ocean-continent transition and complex intercontinental evolution after the collision. As a result, typical structure-magma-sedimentation occurred. From north to south, the eastern Kunlun orogenic belt can be divided into the Kunbei back-arc basin, Kunzhong basement uplift and granitic belt and Kunnan composite belt. The predominant strata include the Precambrian, Ordovician, Carboniferous-Permian and Triassic. E-W fracture zones have formed in the eastern Kunlun orogenic belt since the Paleozoic due the influence of three regional faults. Extensive magmatism developed and different epoch rock assemblages demonstrate the plate subduction-collision and evolution of a polycyclic ocean. Metamorphism drove element redistribution and enrichment in the eastern Kunlun orogenic belt. For the significant contribution of metamorphism to mineral deposit is that it can supply metamorphic fluids, remobilize the mineral elements and extract the mineral elements from source beds. Regional gravity and aeromagnetic anomaly present the N-W orientation in the Western part, E-W orientation in Middle part and N-E orientation in Eastern part. Gravity anomaly reflects E-W and N-W orientation gradient belt and mineral resources of non-ferrous metal have close relationship with the N-W orientation gravity and aeromagnetic anomaly. Along the gravity gradient belt and periphery of the aeromagnetic anomaly, some commercial nonferrous metal deposits have been discovered. Ore bodies are commonly hosted in anomaly intersections. Eastern Kunlun mineralized belt is located in an active fractured zone, lithospheric thinning and has a coincident relationship with strong earthquake centers. Mineral deposits formed along the low velocity zone and the transitional belt between the high velocity zone and low velocity zone. Volcanic rocks of Eastern Kunlun orogenic belt can be divided into four series: pre-Xingkai, Caledonian, Variscan and Indosinian-Yanshanian. Pre-Xinkai volcanic rocks are composed of basaltic lava of Wanbaogou group. Chemical components of volcanic rocks wholly belonged to subalkalic series. Characteristics of geochemistry and sedimentation formation indicated that the forming environment was oceanic volcanic island. Caledonian volcanic rocks include Nachitai group and Tanjianshan group. Furthermore, volcanic rocks of Tanjianshan group are bimodal volcanic rocks composed of basic basalts and intermediate-acidic basalts. Geochemistry shows the Tanjianshan group developed in a back-arc basin tectonic Close 1552 Tong Pan · Caisheng Zhao · Fengyue Sun environment. Nachitai group contributed some limestone and siliceous rocks that formed in deep water. Variscan volcanic rocks are composed of the Maoniushan, Dagangou, Halaguole and Haoteluowa group. Calcalkalic volcanic rocks of early Carboniferous Halaguole group are rocks developed in an island arc or active continental margin. Halaguole group of Kunnan composite belt develop tholeiitic basalt series and Calcalkalic series characterized by magmatic arc showing its formation have genetic relation with the northward subduction of Bayan Har ocean. Exhalative sedimentation formations are developed extensively in Eastern Kunlun orogenic belt. Because of the influence of the different metallogenic geological-structural setting, some special submarine hydrothermal exhalation sedimentation formations were formed. For example, Kendekeke ore district located in Qimantage aulacogen developed siliceous rocks-bearing Sedex formation. However, Tuolugou ore district located extensional oceanic setting developed siliceous albitite-bearing volcanic clastic debris sedimentation formation. Dulenggou copper deposit is formed in a subduction back-arc of Bayan Har ocean and developed Calcalkalic series magmatic arc. 3 Geodynamic evolution of the eastern Kunlun Orogenic Belt Based on observations made by previous researchers and our own investigations, the geological history of the orogen can been divided into three stages, i.e. pre-Caledonian, Caledonian and Indochinese-Himalayan. Pre-Caledonian evolution includes formation of Precambrain platform, breakup and convergence of Proterozoic paleocontinent. Wanbaogou oceanic bassalts, which are important to understand the tectonic evolution, were formed in late Proterozoic. The ocean plate of the ProtoTethys began to be consumed by northward subduction to Qaidam massif along the location of the present Kunzhong falut in early Paleozoic, and the structural framework of Kunbei and Kunnan formed. With the development of the subduction, a trench formed in the sourthern margin of Qaidam massif. Active continent margin was formed between the Kunzhong fault and Kunbei fault, but a back arc basin formed in Kunbei belt. Bimodal volcanic rocks were distributed extensively. By that time, a trench-arc-basin system was developed in the southern edge of Qaidam massif.Nachitai group, which is composed of volcanic clastic rocks and carbonatite formation was formed in the basalt plateau after formation of the Wanbaogou oceanic basalt and before collision with Qaidam massif. In early middle Silurian, siliceous albitite formed in extensional tectonic setting of Wanbaogou oceanic basalt plateau. In late Caledonian, Wanbaogou plateau basalts were collaged to the Qaidam massif. According to Luo et al. (1990), the late Paleozoic volcanic rocks formed in an Andean-type continental mag- matic arc. The oceanic crust was directly subducted downward to the continent without island arc formation The Hercynian batholiths, are the most widely developed intrusives in the orogenic while early Indochinese granites are mostly stock-shaped and mainly distributed in Kunnan belt. Based on petrochemical data, it is recognized that the granites of this stage belong to subduction and syncollisional types. Since the late Indochinese stage, intensive crustal-mantle reaction occurred, which lead to the formation of a series of widely distributed mafic-ultramafic intrusives. The tectonic regime transformed from compressional orogeny to extensional liosphere thinning, which coincided with the beginning of the breaking up of the supercontinent Pangea. The tectonic regime transformation controlled the formation of mantle-derived, mantle-crustal hybrid magmatic activities and a large number of hydrothermal ore deposits in late Indochinese. 4 Characteristics and model of cobalt deposition in the eastern Kunlun Orogenic Belt Kendekeke Co, Bi and Au deposit: This deposit developed in the early Paleozoic back-arc basin of the Kunbei fracture zone. With the northward subduction of seamounts, the back-arc basin and submarine hydrothermal exhalation sedimentation ore-bearing formation formed. Submarine hydrothermal exhalation sedimentation formed siliceous rocks together with pyrites, pyrrhotites, gel pyrites and other Co, Bi, Au and Cu multiple ore-forming elements. Because of the short life of the active basin, thermal influence was relatively minor; the hydrothermal sedimentation provided important oreforming materials for the later mineralization. Hercynian orogenic activities enriched the mineral elements again. Large scale mineralization developed in Mesozoic era and is the predominant mineralization stage for the Kendekeke deposit. Indosinian-Yanshanian magma brought strong thermodynamics condition and hydrothermal replacement. Tuolugou Co deposit: Bayan Har Ocean was located in the southern part of Eastern Kunlun orogenic belt entered the oceanic subduction phase after the Paleozoic extension. Metallic elements were accumulated by hydrothermal activities caused by seeping of seawater and formations bearing Co and Au. Modified mineralizations and deformation of fold and shear developed during Yanshanian-Himalayan thrusting. There were extensive structural deformation and replacement and no large scale magmatic intrusions in Kunnan belt similar to the paleozoic Kunzhong belt. Primary stratifications were replaced by penetrative foliations. Mineralized siliceous albitite were deformed and reoriented and characteristics of veinlike deposits were generated. Later phase structures developed intensively and cut the original mineralization belt and formed diverse uplift and denudation. Close Chapter 15-10 · Metallogenic dynamics and model of cobalt deposition in the eastern Kunlun Orogenic Belt, Qinghai Province An oceanic basalt plateau was produced by a mantle plume in the Pro-Tethys ocean in the Precambrian and hydrothermal activities developed extensively. With the rift extending downward to the deep crust or upper mantle, basic vocanics were deposited widely. Large scale hydrothermal sedimentation and submarine exhalation were active for a long time. Co, Cu and others metalic elements from Archean formations were remobilised into the sea basin and accumulated and deposited in the hydrothermal vents. Acknowledgements This study is financially supported by China Geological Survey project (200110200021 and 200310200012). 1553 References Kuang J, Sun FY, Chen GH (2003) Geological features and genetic type of Kendekeke Co,Bi,Au deposit in Qinghai Province[J]. Jouranal of Jilin University(Earth Science Edition) 33(supp.): 4752 (in Chinese with English abstract) Pan T, Ma MS, Kang XR (2001) Implication of ore prospecting breakthrough for Co and polymetal deposit in Kendekeke and its periphery, Eastern Kunlun[J]. Chinese Geology 28(2): 17-21 Pan T, Sun FY (2003) The mineralization characteristic and prospecting of Kendekeke Co-Bi-Au deposit in Dunkunlun, Qinghai Province [J]. Geology and Prospecting 39(1): 18-22 (in Chinese with English abstract) Qian ZZ, Tang ZL, Li WY (2003) Metallogenic regularity of QinlingQilian-Kunlun metallogenic domain in Paleozoic[J]. Northwestern Geology 36(1): 34-40 (in Chinese with English abstract) Close Close Chapter 15-11 15-11 A review of gold exploration in the Tulasi Area, Xinjiang Uygur Autonomous Region, China Peng Zhang WMC Resources (China) Pty Limited, Beijing, China Keywords. WMC, gold exploration, activity, Tulasi, Xinjiang Abstract In August 1997 WMC Resources Limited (“WMC”) entered into a joint venture agreement (WMC 75%, Chinese partner 25%) with No. 1 Exploration Party of Xinjiang BGMR and the National 305 Project, thus establishing the Xinjiang Hua Ao Exploration and Mining Venture (Hua Ao JV). The objective of the joint venture was to explore for a world class gold deposit in the Tulasi area, north of the city of Yining in the Xinjiang Uygur Autonomous Region. Covering 715 km2, the Tulasi project area is host to significant epithermal mineralisation associated with termination of an Early Carboniferous continental margin magmatic arc. Numerous occurrences of gold mineralisation, and some of base metal (Ag-Pb-Zn) mineralisation, are distributed throughout the area. In two areas excised from the centre of the project area, significant deposits of low sulphidation epithermal style mineralisation, known as the Arxi gold deposit and the Towerbeck gold prospect, have been previously discovered. On Hua Ao JV tenements, the only significant low sulphidation epithermal system recognised was the base metal rich (Ag-Pb-Zn), but gold poor, Tulasu vein. The majority of known mineralisation on Hua Ao JV tenements is of medium-high sulphidation epithermal style according to PIMA analysis, represented by Jinxi-Yelmand prospect which hosts broad zones of low grade gold mineralisation (tens of metres thick and with potential for continuity on the scale of >1km). Mineralisation is hosted by shallow-dipping clastic units, dominantly conglomerate and sandstone, that lie above a series of Ordovician and Devonian carbonate units, and below a felsic pyroclastic unit. The greater permeability of the clastic units has favoured channelling of hydrothermal fluids along this horizon. The first exploration stage was to conduct project-scale systematic exploration in search of major zones of mineralisation that may have escaped previous recognition. This exploration, comprising targeting, stream sediment geochemistry, reconnaissance geologic mapping and rockchip sampling and soil geochemistry, identified coincident geochemical, geophysical and geological anomalies. The second exploration stage was to advance prospectscale exploration at the Jinxi-Yelmand prospect in expec- tation of making a quick discovery of a world class gold deposit. Detailed mapping, dipole-dipole IP geophysics, and diamond drilling were undertaken at the JinxiYelmand prospect. This work indicated that the mineralised system is extensive, possibly extending over an area of 14km2, with a “high grade” core possessing dimensions of about 1.5km by 1km. Gold grades in this “high grade” core appear to average only about 1.0 g/t, and metallurgical testing indicates that the ores are refractory and not amenable to simple heap leach gold extraction. The grades are well below the 3.5-3.8 g/t required to make this prospect a world-class opportunity by economic modelling. Life of the Tulasi project covered five years in four stages: reconnaissance stage 1997-1998; diamond drilling stage 1999; retargeting stage of the project area in 2000 and the project termination stage in 2001. Despite the conclusion that the Tulasi project area does not contain a world class opportunity for the Hua Ao JV, it was regarded as having been technically successful. As the first foreign-Sino exploration cooperation between WMC and the local partners in the Xinjiang Uygur Autonomous Region, it was a new experience for all parties. Excellent cooperation, modern technology and milestone-driven approach enabled the systematic evaluation of the Tulasi project area. References Begg GC (2001) Tulasi Project Targeting Exercise, March 2000. Unpublished WMC Report Begg, GC, Carver R, Zhang P, Wang LP, Cui MP (2001) Final Technical report on Tulasi Project, Xinjiang Autonomous Region Of China, unpublished WMC report Hayward N, Zhang G (1998) Structure Interpretation for the Tulasi Project, NW China. Unpublished WMC Report. Mu R, Tian C, Yang F (1995) Mineralisation patterns and targeting in flanking regions of Arxi gold deposit in Yilin, Xinjiang: Publication of 305 Project Office of Xinjiang Uygur Autonomous Region, 248 Qi Shu-ji (1999) The Tectonic Characteristics Of Tulasu Vocanic Basin in Yining and its relation to gold mineralization, Xinjiang Geology, Jun 1999, vol.17. No.2, p121-128 Sengor AMC, Natal’in BA, Burtman VS (1993) Evolution of the Altaid tectonic collage and Palaeozoic crustal growth in Eurasia. Nature, v.364, pp.299-307 Xiao L (2000) A Study of Fractal Nature of Gold Deposits Distribution and Gold Metallogenesis of Jinxi-Yelmand Prospect, Tulasi Basin, North-western Tianshan Belt. Unpublished PhD thesis. China University of Geosciences (Wuhan) Close Close Chapter 15-12 15-12 Analyzing metallogenic conditions and exploration in the Mian-Lue-Kang tectonic belt, Shannxi and Sichuan provinces, China Ren Xiaohua Faculty of Geosciences and Land Resources, Chang’an University, Xi’an 710054; and Bureau of geological exploration for nonferrous metals in northwest China, Xi’an 710054, China Wang Ruiting Bureau of geological exploration for nonferrous metals in northwest china, Xi’an 710054; and Faculty of geosciences and resources, China University of Geosciences, Beijing, 100083, China Li Furang, Wang Junyi Bureau of geological exploration for nonferrous metals in northwest china, Xi’an 710054, China Mao Jingwen Faculty of Geosciences and Resources, China University of Geosciences, Beijing, 100083; and Institute of mineral resources, Chinese Academy of Geological Sciences, Beijing, 100037, China Wang Xiaohong Faculty of Geosciences and Land Resources, Chang’an University, Xi’an 710054, China Keywords. Mian-Lue-Kang tectonic belt, ophiolite, tectonic mélange, metallogenic condition, exploration prospect The Mian-Lue-Kang tectonic mélange belt is located in Mianxian County, Lueyang County in Shannxi Province, and Kangxian County in Gansu Province. It represents an important part of a plate suture belt recently revealed in the south margin of Qinling orogenic belt. It forms a narrow belt 85 km from east to west, and 10 to 15 km from south to north. The belt extends to Wenxian County in the west and reaches Animaqing; it also approaches Fangxian County Hubei Province through Gaochuan to the east, and forms a divisional regional tectonic belt for Qinling area that is parallel with Shangdan ophiolite stucture melange in the northern Qinling. With the recent development of multi-discipline studies on Qinling orogenic belt, basic research about the MianLue-Kang tectonic belt has made considerable progress in aspects of composition, tectonic nature, temporal and spatial evolution regularities, and its dynamic character (Zhang et al. 1996, 2001). Metallogenic geological understanding for the belt has also improved but some issues regarding metallogenic conditions and metal ore-forming processes for this anomalous region remain unresolved. Following exploration achievements through recent land and resources surveying in the belt, this paper analyzes primarily the metallogenic conditions and exploration potential for Mian-Lue-Kang tectonic belt, combined with geological reconnaissance practise. The tectonic belt comprises of a series of parallel, different character faults, with all microlithons divided by nappe shear faults and decollement faults to form a tectonic network that extends in east west direction (Fig. 1). Schistosity zones dominated by S1 deformation foliation mainly exist in volcanic sedimentary rocks. Shear deformation between hard and soft rock interfaces plays an important role in multi-metals mineralization. Besides a divsion of stratigraphy in the Archean Group (Yudongzi microlithon), the Sinian system (Xianggongshan microlithon) was deformed during the Indosinian-Yanshan main orogenic period, with sedimentary rocks from Paleozoic era metamorphosed to phyllite, and greenschist in epimetamorphic phase (Tao et al. 1993). Mian-Lue-Kang tectonic belt underwent an evolution of extensional splitting in initial stages and subduction and collision in later stages. Under the conditions of primary extension, a deep tectonic system generated extensive volcanics that contained metallogenic materials to supply abundant sources for subsequent ore-forming processes. About 90 forming processes. percent of host wall rocks for gold and multi-metals deposits are volcanic rock, which shows the influence of the extensional rift structure on ore. The formation of tectonically altered rock typed gold deposit relates to stripping the shear belt between basement and overburden of Archean and Proterozoic groups; syntectonic ultrabasic and basic intrusion activity are the main thermodynamic conditionss for metallogenesis for gold formation (for example Jianchaling gold deposit; Wang et al. 1996, 2000). Metallogenic elements (As, Sb and Pb) anomalies and brittle and ductile shear structures are geochemical and tectonic marks for metal deposits emplaced in the belt. Close 1558 Ren Xiaohua · Wang Ruiting · Li Furang · Wang Junyi · Mao Jingwen · Wang Xiaohong Mian-Lue-Kang tectonic belt also hosts tectonic ophiolite belts through the evolution of a Paleozoic rift to limited ocean basin to converging orogeny. The composition of ophiolites chiefly include epidote albite schist, chlorite sericite schist (phyllite), chlorite actinolite schist, quartz sericite phyllite, silic rock, slate, serpentinite, mafic magnesite rock, talc magnesite rock, diabase, and gabbro, which constitute different nature tectonic microlithon in big and small hybrid ways. On the basis of petrologic results of volcanic rock microlithons, the geochemistry and petrochemical features of Jinjiahe microlithon indicate that its protolith was a island arc volcanic rock. The content of SiO 2 (Ø(SiO2) = 46.65) and A12O3 (A12O3)=15.38) are lower than that of MORB, and its ω(TiO2), ω (Fe2O3), and ω(FeO) are also low, moreover, low K2O content reflects Jinjiahe microlithon formed in an island arc environment. REE analysres for basic and intermediate basic volcanic rock of Jinjiahe and Guandimen microlithons indicate that there exist two types rock, one depleted REE, its (La/Yb) value is 0.3 to 0.36, (Ce/Yb) 0.33 to 0.42 (La/Sm) 0.55 to 0.83, and ΣNd(t) 6, which approach that of N-typed MORB, the other enriched LREE, its (La/Yb) value is 1.84 to 4. 70, (Ce/Yb) 1.82 to 3.38, (La/Sm) 2.79 to 4.75, which have the character of typical VBA basalt. The belt is an important section with anomalies of Au, Ag, Pb, Zn, Cu, As, and Sb in Mian-Lue-Yang metal de- posit cluster field, where Au distributes in the west and Ag (Pb - Zn) in the east. There are six 10 km long stream sediment anomalies of Au and associated As, Sb, and Hg in Ganheba-Jinjiahe region. Three parallel mineralized strips have been delineated by ravine soil secondary halo densified method in Ganheban anomaly, and a 30 t gold resource has been identified in the centre mineralized strip; at the same time, the other two mineralized strips still have good prospecting potential. References Tao HX, He YY, Wang QQ (1993) Tectonic evolution history of north margin in Yangzi plate. Xi’an: Northwest university press, 1-133 Wang RT, He Y, Wang X (2000) Probe into the metallogenic mechanism of Jianchaling large gold ore deposit. Northwest Geoscience 21(1): 19-26(in Chinese with English abstract) Wang X, Tang RY, Li Shi (1996) Qinling orogeny and metallogenesis. Beijing: Metallurgical Industry Press, 12-31(in Chinese with English abstract) Zhang BR, Luo TC, Gao S (1994) Geochemical study on lithosphere struture and metallogenic regularity of Qinba region. Wuhan: China University of geosciences Press, 257-311 (in Chinese with English abstract) Zhang GW, Meng QR, Yu Z (1996) Orogenisis and dynamics of the Qinling Orogen. Science in China(Series D) 39(3): 225-234 Zhang GW, Zhang BR, Yuan XC (2001) Qinling orogenic belt and continental dynamics. Beijing: Science Press, 702-705(in Chinese with English abstract) Close Chapter 15-13 15-13 Zhengguang: A potentially large, high-grade epithermal gold deposit in the Duobaoshan metallogenic belt, Heilongjiang, northeastern China Zhang Baolin, Wang Jie, Liang Guanghe, Xiao Qibin, Cai Xinping, Song Baochang Key Laboratory of Mineral Resources Institute of Geology and Geophysics, Chinese Academy of Sciences, Qijiahuozi, Beijing 100029, China Zheng Qingdao Heilongjiang Bureau of Geology and Moneral Resources, Zhongshan Road, Harbin 151000, China Abstract. Traditional ideas and methods are of limited use in deep prospecting in plant and volcanic-covered areas in Heilongjiang Province. The application of the authors’ ‘three-field anomaly interrestrain’ theory and a new geological-geophysical-geochemical prospecting technique combination has helped the local geological team to learn more about ore-controlling structural and metallogenic information under the cover. Subsequent drilling programs have revealed and assessed a potential large high-grade epithermal gold deposit in the southeastern part of the important porphyry copper belt. Keywords. Zhengguang, epithermal, Duobaoshan, Heilongjiang The Duobaoshan copper deposit in Heilongjiang Province was found and exploited in the 1970s. From then on, the area has been considered as an important Paleozoic porphyry copper zone. Although there is a very large reserve of 2.4 million tons of copper in the deposit, the very low grade (aregage 0.45%) of copper ores has limited its development. In recent years, a potential large high-grade epithermal gold deposit was discovered and quickly assessed in its southeastern part, which may supply us with some new understanding of the particular region. From 2000, through geochemical survey of stream sediments, the Zhengguang gold prospect was discovered by Qiqihaer minerals exploration team of the Heilongjiang BGMR. After trenching work, altered diorite and andesite were found in the area. Via a series of surface geological and geochemical exploration, geologists have delineated some discrete ore bodies with relatively high-grade of over 100g/t. However, due to the thick cover of plants and soils in the region, they could not learn more deep information by traditional prospecting methods. Therefore, the relationship between ore bodies and ore-controlling structures could not be inferred correctly. In the autumn of 2002, the authors commenced deep predictive work by means of a combined prospecting technique which consists of metallogenic fluid structural analysis, reflection wave seismic exploration, MT survey (equipped with high frequency sensor), deep penetrating geochemical survey and ground gama survey. Through combined field observation, survey and data processing, the complicated folding system, potential breccia pipe and magmatic intrusions have been identified from the profiles. We have inferred that Zhengguang should be a Mesozoic crypto-explosive breccia-type gold deposit. With the help of a new positioning predictive theory termed ‘three field (geological- geophysical-geochemical) interrestrain’, favorable metallogenic structural positions (targets or potential mineralization zone) were predicted under the cover (Zhang et al. 2002). In 2003, local geological teams finished two 500 meterdepth test drill holes which intersected seven ore zones in depths of between 20 and 400 meter. The high-grade ores develop the strong veinlet-type alteration of silicification-pyritization-epidotization. The highest grade is in excess of 30g/t of gold. In addition, the drill holes intersected very thick alteration zones under the cover which extended over 500m in the depth. From the preliminary result, the authors have inferred that there should be a potential large gold deposit under the cover (Zhang, 2004a, b). In 2004, the Black Dragon Joint Venture which was established by the Heilongjiang BGMR and Leyshon Resources Limited of Australia carried out a 4500 meter diamond drill program in the target zone. The 30 drill holes with the average depth of 150 meters and horizontal spacing 50 meters were arranged within the strong alteration area. Finally, thick (up to 44 meters) ore bodies of high grade (up to 580g/t) were intersected in the depth. Among them, Hole ZGD029 recorded 24 meters @ 28.6g/t Au, includeing 6 meters @ 93.0 g/t Au at about 90 meters below the surface. The estimated gold reserve of the explored area is more than 20 tons (Leyshon Resources Limited, 2004a, b, c, 2005). The discovery of the Zhengguang gold deposit has further confirmed the existence of a major epithermal gold mineralization belt in the Mesozoic volcanic areas along the Heilongjiang River bordering Far East Russia. Therefore, a significant number of prospecting targets is likely to be delineated in the near future (Zhang et al. 2004). Close 1560 Zhang Baolin · Wang Jie · Liang Guanghe · Xiao Qibin · Cai Xinping · Song Baochang · Zheng Qingdao References Leyshon Resources Limited (2004a). Significant first drill results from Zheng Guang gold project, northeast China. In: http://www.asx. com.au (July.15) Leyshon Resources Limited (2004b). First Quarter Activities& Cashflow Report. In: http://www.asx. com.au (Oct.29) Leyshon Resources Limited (2004c). New High Grade Drill Results-Zheng Guang Gold Project China. In: http://www.asx.com.au (Nov.15) Leyshon Resources Limited (2004d). MD Presentation to the China Mining Conference. In: http://www.asx. com.au (Nov.16) Leyshon Resources Limited (2005). Second Quarter Activities & Cashflow Report. In: http://www.asx. com.au (Jan.28) Zhang Baolin (2004a) Application and result of the new predictive theory of “three-field anomaly inter-restrain” and related techniques in rapidly selecting exploration targets in blind areas. Journal of Gold Science and Technology, 12(5): 48 (in Chinese) Zhang Baolin (2004b) Zhengguang—a newly discovered highgrade epithermal gold deposit in the northern part of Heilongjiang. Journal of Gold Science and Technology, 12(6): 46, 14 (in Chinese) Zhang Baolin, Cai Xinping, Liang Guanghe, Xiao Qibin, Wang Jie, Xu Xingwang, Song Baochang, Qi Min (2004c) The positioning predictive theory, and techniques of the “threefield (geological- geophysical-geochemical) anomalies interrestrain” and their application in blind areas. Bulletin of Mineralogy, Petrology and Geochemistry, 23 (supp): 151 (in Chinese) Zhang Baolin, Wang Jie, Cai Xinping, Liang Guanghe, Xiao Qibin, Song Baochang, Qi Min, Zhang Chengyu, Wang Baoiquan, Lu Bingyan (2002) Summary of predictive work in 2002 and design of testing drill holes (Report of Scientific Project “Deep prospecting prediction of Zhengguang lode gold target in Nenjiang county, Heilongjiang”) (in Chinese) Close Chapter 15-14 15-14 An under-recognized mineralization style along the northern margin of the North China craton: Potential for discovery of large-tonnage disseminated and stockwork-style gold deposits T. Zhou, G. Dong Sino-QZ Group Pty Limited, PO Box 2424, Mt Waverley, VIC 3149, Australia, and HT Mining (Beijing) Limited, 22C-2, 2 Xinxi Rd, Shangdi Zone, Haidian District, Beijing 100085, China Abstract. Based on recent field investigations of a number of the important gold deposits along the northern margin of the North China craton, it is argued that broad zones of disseminated and stockwork– style mineralization in some of the deposits have far greater importance than previously recognized. On a regional scale, the intersection of the major NNE/NE- and E-W-trending structures, products of Mesozoic Pacific margin oblique subduction and Paleozoic-early Mesozoic craton collision, respectively, is a key to localization of the ores. Keywords. Disseminated and stockwork–style ores, large-tonnage, gold deposits, North China craton 1 Introduction The northern margin of the North China craton has been attracting much attention from both academic researchers and mining industry personnel in the past decade, as it has undergone perhaps the most lengthy, complex tectonic history in China, as well as hosting a resource of approximately 800-900t Au (Zhou 1999; Zhou and Lu 2000; Hart et al. 2002; Zhou et al. 2002). In the past, much of the exploration work in the region has focused on finding gold vein style mineralization; this style of deposit has been well described in various recent research papers (e.g. Miller et al. 1998; Ao et al. 2002; Hart et al. 2002; Zhou et al. 2002; Jin 2003). In the past couple of years, we visited many of the important gold deposits in this region, and have gained extensive and updated geological data through our exploration and mining projects along the craton margin. Our observations indicate a much greater importance for broad zones of disseminated and stockwork–style mineralization in some of the deposits than was previously recognized. We will attempt here to share our experience in developing these newly identified targets with other explorationists, particularly those from western countries who have been actively involved in, or intend to step into, gold exploration and mining in China. 2 Broad zones of disseminated and stockworkstyle mineralization The northern margin of the North China craton underwent several orogenic events as the result of the collision of the North China craton with the Siberia and South China cratons, and subduction of the Izanagi/Pacific oceanic plates. The E-W structures that dominate the area were caused by the convergence between the North China and Siberia cratons from late Paleozoic through Early Jurassic time, with the closure of the Solonkar Ocean occurring between the two blocks. In the eastern part of this area, the E-W structures were overprinted by NNENE structures that developed as a result of the NW-directed, oblique subduction of the Izanagi/Pacific plates under the eastern margin of China. In the western part of the northern craton margin, such as in the Wulashan goldfield (i.e., Hadamengou and Wulanbulang gold deposits, approx. 20 km west of Baotou City, Inner Mongolia), the majority of gold deposits belong to the well-described, gold-bearing quartz veins, which are mostly about 1-1.5 m in width. In some favorable structural intersections and possibly favorable rock types, however, relatively high-grade and wider veins may be found. From the city of Zhangjiakou (Hebei province) eastwards, an area containing the Dongping and Xiaoyingpan (also called Zhangjiakou) gold deposits, the influence of the NNE-NE structure is significant. Importantly, broad zones of disseminated and stockwork-style mineralization have been recently identified throughout this region. For example, a 70- to 130-m-wide zone of disseminated and stockwork style ore was found to average 5-6 g/t Au near the contact of a middle Paleozoic alkalic intrusive complex and Late Archean gneiss/amphibolite at Dongping. Similar looking disseminated and stockworkstyle ore zones have also been observed at properties throughout Kuancheng, Qinglong and Pingquan counties, which include parts of eastern Hebei province and adjacent Liaoning province, where the two major E-W and NNE-trending structural corridors intersect. At the Huajian-Niuxinshan deposit (about 200 km northeast of Beijing), underground development intersected an over 35-m-wide disseminated and stockwork style ore zone averaging 4.5 g/t Au, hosted in a silica-sericite-pyrite altered syenite dyke. Additionally, disseminated ores in Close 1562 T. Zhou · G. Dong sericite-pyrite altered Mesozoic granite, with grades as high as 7.5 g/t Au, are mined by local workers from several adits driven into the Niuxinshan granite. The extent of the gold mineralization in the granite is still unknown. Only about 20 km north of the Huajian-Niuxinshan deposit, gold mineralization at the Yuerya deposit occurs as both quartz veins and disseminated/stockwork style ores within the Mesozoic Yuerya Granite. Most mineralization occurs near the contact of the granite and Middle Proterozoic carbonate rocks. The disseminated/stockwork ores have accounted for almost 25% of the production to date. Recent underground exploration identified a 30-m-thick disseminated/stockwork ore zone averaging 4 g/t Au. Further to the north, the Dongliang deposit and its extension within Pingquan county (Liaoning province) are characterized by similar high-grade zones of stockwork and disseminated style gold ores over widths of 10-20 m. Further east, at the Baizhangzi deposit, a broad zone of disseminated/stockwork ores, 20- to 50-m-wide and with a grade >5-6 g/t Au, has been identified along the margin of a Mesozoic granite that intrudes Middle Proterozoic metasedimentary rocks. Although local controlling factors for these broad zones of disseminated and stockwork style ore require further investigation, a regional control appears to be the intersection of major NNE- to NE-trending structures with the older E-W structures. In these areas of intersection of structural domains, the competent margins of Paleozoic-Mesozoic igneous bodies are particularly favorable hosts for development of gold-rich stockworks and disseminations. These areas within the northern margin of the North China craton are the key targets for western companies who are seeking large-tonnage gold deposits in China. ferent government organization. Once mining commenced, workers usually tried to extract the already recognized and easily accessible ores as thoroughly as possible, and neglected the importance of further exploration, particularly drilling to depth to enlarge the resource. In fact, the majority of the mines in the region had never been subjected to any underground drilling since the mining operations started. As a result, after a few years of mining activities, a mine was quite often defined as “the mine in crisis” due to apparent depletion of the remaining resource. However, many mines have been revived after new underground exploration and subsequent identification of additional resources. For example, the Dongping deposit was given the status of “mine in crisis” before May, 1999. However, further underground development guided by experienced mine geologists has identified significant new gold resources at depth. As a result, the Dongping deposit today remains as one of largest active gold mines in China. Similar experiences have characterized development of many existing mines including the Yuerya, Baizhangzi, and Niuxinshan deposits. It is also worth noting that the broad zones of disseminated and stockwork-style gold ores usually do not appear in outcrop and often occur solely in the subsurface. Above these broad ore zones, mineralization may occur as narrow, auriferous quartz veins, e.g., at Dongping, Baizhangzi and Niuxinshan. Therefore, during due diligence review for acquisition of mining projects in China, explorationists from the western countries may need to realize when considering the remaining resource numbers that these may be somewhat deflated, and they should not under-estimate the potential for finding more resource at depth in many of the already active gold mines across northern China. 3 4 Issues relating to remaining resource/reserve in existing gold mines To correctly assess the remaining resource/reserve in existing gold mines, one must first fully understand the common practices in the Chinese exploration and mining industry. Traditionally, geological brigades under various ministries of the State Council were assigned to conduct regional geological and geochemical reconnaissance surveys, followed by preliminary and detailed exploration projects that included trenching, limited underground development, and some drilling. Generally, the footage of each drill hole was in the range of 100 to 200 m, with only a few extending to depths of 300 m or more, and the majority of the drill holes were sub-vertical. By the end of a detailed exploration project, each brigade would submit a geological report with indicated and inferred resource (in Chinese categories C and D, but occasionally B), and all data would be transferred to the mining sector representatives, who were usually administered by dif- Concluding remarks The northern margin of the North China craton is one of the major gold provinces in China. However, most exploration and mining companies from the western countries appear to be perplexed when it comes to exploration in this area, as the deposits there were traditionally described as narrow gold –bearing quartz veins, normally only 1to 2-m-wide, and, therefore, would not be suitable for largescale mining. Our recent work suggests that significant potential exists for the discovery of broad zones of disseminated and stockwork-style gold mineralization in the subsurface beneath known vein systems. On a regional scale, the intersection of the major NNE/NE- and E-Wtrending structures, products of Mesozoic Pacific margin oblique subduction and Paleozoic-early Mesozoic craton collision, respectively, is a key to localization of the ores. This particularly characterizes the North China craton margin to the east of Zhangjiakou. Because these broad zones of disseminated and stockwork style gold ores typi- Close Chapter 15-14 · An under-recognized mineralization style along the northern margin of the North China craton cally occur at depth, and giving the common practices in the Chinese exploration and mining industry, one should not under-estimate the significant potential in finding multiple Moz gold resources during evaluation of exploration properties and existing gold mines. Acknowledgements We wish to thank many mine geologists and management staff for sharing their experience and knowledge in Chinese exploration and mining industry, particularly those from CNGC and its gold mines; Dongping Mine; CITIC Gold; and government administration of Kuancheng County, Qinglong County and Chongli County. We also appreciate the time and support provided to us by the staff from Eldorado Gold, Hunter Dickinson, Noranda, Ivanhoe, Gold Fields, Planet Explorations, Fury Explorations, and Anglo American during our joint field investigations. Richard Goldfarb of US Geological Survey is thanked for review and editing of the manuscript. We also would like to extend our appreciations for assistance and support from staff of the Jinyou Exploration, Sino-QZ Group and HT Mining, particularly Zhigang Yang, 1563 Renzhao Zhou, Guowei Lei, Guanglan Wang, Pencheng Zhang, Huijuan Wen and Junqi Yin. References Ao Y, Ren J, Ji X, Fu Q (2002) Geological characters of Baizhangzi gold deposit, west-Liaoning area. Non-ferrous Mining and metallurgy, v. 18, no. 4, pp. 1-4 (in Chinese with English abstract) Hart CJ, Goldfarb RJ, Qiu Y, Snee L, Miller LG, Miller ML (2002) Gold deposits of the northern margin of the North China Craton: multiple late Paleozoic-Mesozoic mineralizing events. Mineralium Deposita 37: 326-351 Jin T (2003) Ore control structure of Yuerya gold deposit and deep prediction, Hebei. Gold Geology, v. 9, no. 4, pp. 19-22 (in Chinese with English abstract) Miller LD, Goldfarb RJ, Nie FJ, Hart CJR, Miller ML, Yang YQ, Liu YQ (1998) North China gold - a product of multiple orogens. SEG Newslett 33: 1-12 Zhou T (1999) Tectonics and gold mineralisation in East China, Proceedings of PACRIM 99, Bali, Indonesia, International Congress, Aust. IMM Publications pp. 341-345 Zhou T, Lu G (2000) Tectonics, granitoids and Mesozoic gold deposits in East Shandong, China. Ore Geology Reviews 16: 71-90 Zhou T, Goldfarb RJ, Phillips GN (2002) Tectonics and distribution of gold deposits in China - an overview. Mineralium Deposita 37:249-282 Close Close