CONCRETE LIBRARY OF JSCE NO. 18, DECEMBER 1991 CHANGE IN MICRO-STRUCTURE OF CONCRETE DUE TO CARBONATION (Reprint from Transaction of JSCE, Vol.420/V-13,Aug.1990) Tatsuhiko Saeki Hiroyuki Ohga Shigeyoshi Nagataki SYNOPSIS Micro-structure of concrete is changed due to carbonation and the change in micro-structure affects properties of concrete. An accelerated carbonation test and a wet-dry test are performed to investigate the change in micro-structure of mortar considering water-cement ratio and initial curing condition. The depth of carbonation, the amount of calcium hydroxide and calcium carbonate, pore volume, pore size distribution, and the weight of mortar are measured. The change in pore volume and pore size distribution due to carbonation depends on water-cement ratio and initial curing period. Pore volume in the carbonated portion is decreased in the case of the continuous carbonation test. Denseness of structure induced by carbonation affects a subsequent carbonation process. T.Saeki is a research associate of Department of Civil Engineering at Niigata University, Niigata, Japan. He received his master of engineering degree from Tokyo Institute of Technology in 1989. His research has been on carbonation of concrete. He is a member of JSCE and JCI. H.Ohga is a research associate of Institute of Industrial Science at the University of Tokyo, Tokyo, Japan. He received his doctor of engineering degree from Tokyo Institute of Technology in 1991. His recent research has 1xxn1 on properties of concrete containing mineral admixtures, and durability of concrete. He is a member of ACI, JSCE and JCI. S.Nagataki is a professor of Department of Civil Engineering at Tokyo Institute of Technology, Tokyo, Japan. He received his doctor of engineering degree from the University of Tokyo in 1966. His research interests cover properties of high strength concrete, effective use of industrial by-products in concrete, durability of concrete. He received a fellow of ACI in 1986. He is a member of ACI, ASCE, JCI, JSMS and RILEM. __Z_